TY  - JOUR
AU  - Kabtamu, Daniel Manaye
AU  - Wu, Yi-nan
AU  - Chen, Qian
AU  - Zheng, Lu
AU  - Otake, Ken-ichi
AU  - Matović, Ljiljana
AU  - Li, Fengting
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9716
AB  - The recycling of heavy metals from solid wastes and transforming these metals into useful materials, such as metal oxides, nanocomposites, and metal–organic frameworks (MOFs), are beneficial for both sustainable development and environmental protection. MOFs are promising for adsorptive desulfurization, owing to their extremely high surface areas and tunable structures. In this paper, for the first time, MIL-53(Cr) was successfully fabricated from electroplating sludge (EPS) as a metal source through a facile hydrothermal method with and without HF. Our synthetic method is novel, green, scalable, and time-efficient. The obtained MIL-53(Cr) was employed as an adsorbent for adsorptive dibenzothiophene removal from liquid fuel. MIL-53(Cr) with HF exhibits a higher desulfurization capacity (40.11 mg g–1) than that of MIL-53(Cr) without HF (32.80 mg g–1). The improved adsorption performance of MIL-53(Cr) with HF is attributed to adding a small amount of HF, which produces highly crystalline and relativity pure MIL-53(Cr) microrods with a high surface area and porosity, and is due to a robust metal–sulfur interaction. Furthermore, the regenerated adsorbent can retain 94% of its initial sulfur adsorption capability even after 5 cycles, implying that MIL-53(Cr) prepared from Cr-EPS is an efficient adsorbent for fuel desulfurization. This study provides new insight for the production of high-value-added MOF materials from solid wastes following the principle of “resource reuse”.
T2  - ACS Sustainable Chemistry and Engineering
T1  - Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization
VL  - 8
IS  - 33
SP  - 12443
EP  - 12452
DO  - 10.1021/acssuschemeng.0c03110
ER  - 

@article{
author = "Kabtamu, Daniel Manaye and Wu, Yi-nan and Chen, Qian and Zheng, Lu and Otake, Ken-ichi and Matović, Ljiljana and Li, Fengting",
year = "2020",
abstract = "The recycling of heavy metals from solid wastes and transforming these metals into useful materials, such as metal oxides, nanocomposites, and metal–organic frameworks (MOFs), are beneficial for both sustainable development and environmental protection. MOFs are promising for adsorptive desulfurization, owing to their extremely high surface areas and tunable structures. In this paper, for the first time, MIL-53(Cr) was successfully fabricated from electroplating sludge (EPS) as a metal source through a facile hydrothermal method with and without HF. Our synthetic method is novel, green, scalable, and time-efficient. The obtained MIL-53(Cr) was employed as an adsorbent for adsorptive dibenzothiophene removal from liquid fuel. MIL-53(Cr) with HF exhibits a higher desulfurization capacity (40.11 mg g–1) than that of MIL-53(Cr) without HF (32.80 mg g–1). The improved adsorption performance of MIL-53(Cr) with HF is attributed to adding a small amount of HF, which produces highly crystalline and relativity pure MIL-53(Cr) microrods with a high surface area and porosity, and is due to a robust metal–sulfur interaction. Furthermore, the regenerated adsorbent can retain 94% of its initial sulfur adsorption capability even after 5 cycles, implying that MIL-53(Cr) prepared from Cr-EPS is an efficient adsorbent for fuel desulfurization. This study provides new insight for the production of high-value-added MOF materials from solid wastes following the principle of “resource reuse”.",
journal = "ACS Sustainable Chemistry and Engineering",
title = "Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization",
volume = "8",
number = "33",
pages = "12443-12452",
doi = "10.1021/acssuschemeng.0c03110"
}

Kabtamu, D. M., Wu, Y., Chen, Q., Zheng, L., Otake, K., Matović, L.,& Li, F.. (2020). Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization. in ACS Sustainable Chemistry and Engineering, 8(33), 12443-12452.
https://doi.org/10.1021/acssuschemeng.0c03110

Kabtamu DM, Wu Y, Chen Q, Zheng L, Otake K, Matović L, Li F. Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization. in ACS Sustainable Chemistry and Engineering. 2020;8(33):12443-12452.
doi:10.1021/acssuschemeng.0c03110 .

Kabtamu, Daniel Manaye, Wu, Yi-nan, Chen, Qian, Zheng, Lu, Otake, Ken-ichi, Matović, Ljiljana, Li, Fengting, "Facile Upcycling of Hazardous Cr-Containing Electroplating Sludge into Value-Added Metal–Organic Frameworks for Efficient Adsorptive Desulfurization" in ACS Sustainable Chemistry and Engineering, 8, no. 33 (2020):12443-12452,
https://doi.org/10.1021/acssuschemeng.0c03110 . .