@conference{
author = "Đustebek, Jasmina B. and Cvetićanin, Jelena M. and Đorđević, Vesna R. and Veličković, Sava J. and Veljković, Miomir V. and Nešković, Olivera M.",
year = "2006",
abstract = "Mass spectral studies (both TIMS – thermal ionization and MALDI TOF – matrixassisted laser desorption time-of-flight mass spectrometry) of the endohedral metallofullerenes, 99mTc@C60 and 99mTc@C70, provided detailed structural and reactivity information about these unusual species. MS experiment revealed that both fullerenes and endohedral metallofullerenes fragment by multiple C2 loss. However, a difference in the terminal fragmentation products was observed for metallofullerene relative to C60, suggesting that the encapsulation metal strongly impacts the fragmentation product. Singly charged cations of the metallofullerenes (M@Cn + ) were completely unreactive in the gas phase with oxygenated compounds such as ethylene oxide: however, the corresponding neutral species appear to react readily with oxygenated species. Collisional dissociation of the ionized endohedral fullerenes listed above revealed multiple C2 loss (either as sequential C2 loss or larger C2n eliminations) to generate similar terminal fragmentation products, which might be predicted due to the similar ionic radii of the encapsulated metals. The observed ionization energies of endohedral molecules were, 5.1 ± 0.1 eV and 5.3 ± 0.1 eV, respectively.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2006: 8th international conference on fundemental and applied aspract of physical chemistry",
title = "Tims and maldi tof of endohedral 99mTc@C60 metallofullerene",
pages = "504-506",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9449"
}