TY  - JOUR
AU  - Šojić Merkulov, Daniela V.
AU  - Lazarević, Marina J.
AU  - Đorđević, Aleksandar N.
AU  - Náfrádi, Máté
AU  - Alapi, Tünde
AU  - Putnik, Predrag
AU  - Rakočević, Zlatko Lj.
AU  - Novaković, Mirjana M.
AU  - Miljević, Bojan
AU  - Bognár, Szabolcs
AU  - Abramović, Biljana F.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9588
AB  - Nowadays, great focus is given to the contamination of surface and groundwater because of the extensive usage of pesticides in agriculture. The improvements of commercial catalyst TiO2 activity using different Au nanoparticles were investigated for mesotrione photocatalytic degradation under simulated sunlight. The selected system was 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) that was studied by transmission electron microscopy and ultraviolet-visible (UV-Vis) spectroscopy. It was found that TiO2 particles size was ~20 nm and ~50 nm, respectively. The Au nanoparticles were below 10 nm and were well distributed within the framework of TiO2 . For 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L), band gap energy was 2.45 eV. In comparison to the pure TiO2, addition of Au nanoparticles generally enhanced photocatalytic removal of mesotrione. By examining the degree of mineralization, it was found that 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) system was the most efficient for the removal of the mesotrione and intermediates. The effect of tert-butanol, NaF and ethylenediaminetetraacetic acid disodium salt on the transformation rate suggested that the relative contribution of various reactive species changed in following order: h+ >•OHads >•OHbulk. Finally, several intermediates that were formed during the photocatalytic treatment of mesotrione were identified. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
T2  - Nanomaterials
T1  - Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight
VL  - 10
IS  - 8
SP  - 1
EP  - 15
DO  - 10.3390/nano10081591
ER  - 

@article{
author = "Šojić Merkulov, Daniela V. and Lazarević, Marina J. and Đorđević, Aleksandar N. and Náfrádi, Máté and Alapi, Tünde and Putnik, Predrag and Rakočević, Zlatko Lj. and Novaković, Mirjana M. and Miljević, Bojan and Bognár, Szabolcs and Abramović, Biljana F.",
year = "2020",
abstract = "Nowadays, great focus is given to the contamination of surface and groundwater because of the extensive usage of pesticides in agriculture. The improvements of commercial catalyst TiO2 activity using different Au nanoparticles were investigated for mesotrione photocatalytic degradation under simulated sunlight. The selected system was 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) that was studied by transmission electron microscopy and ultraviolet-visible (UV-Vis) spectroscopy. It was found that TiO2 particles size was ~20 nm and ~50 nm, respectively. The Au nanoparticles were below 10 nm and were well distributed within the framework of TiO2 . For 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L), band gap energy was 2.45 eV. In comparison to the pure TiO2, addition of Au nanoparticles generally enhanced photocatalytic removal of mesotrione. By examining the degree of mineralization, it was found that 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) system was the most efficient for the removal of the mesotrione and intermediates. The effect of tert-butanol, NaF and ethylenediaminetetraacetic acid disodium salt on the transformation rate suggested that the relative contribution of various reactive species changed in following order: h+ >•OHads >•OHbulk. Finally, several intermediates that were formed during the photocatalytic treatment of mesotrione were identified. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.",
journal = "Nanomaterials",
title = "Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight",
volume = "10",
number = "8",
pages = "1-15",
doi = "10.3390/nano10081591"
}

Šojić Merkulov, D. V., Lazarević, M. J., Đorđević, A. N., Náfrádi, M., Alapi, T., Putnik, P., Rakočević, Z. Lj., Novaković, M. M., Miljević, B., Bognár, S.,& Abramović, B. F.. (2020). Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight. in Nanomaterials, 10(8), 1-15.
https://doi.org/10.3390/nano10081591

Šojić Merkulov DV, Lazarević MJ, Đorđević AN, Náfrádi M, Alapi T, Putnik P, Rakočević ZL, Novaković MM, Miljević B, Bognár S, Abramović BF. Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight. in Nanomaterials. 2020;10(8):1-15.
doi:10.3390/nano10081591 .

Šojić Merkulov, Daniela V., Lazarević, Marina J., Đorđević, Aleksandar N., Náfrádi, Máté, Alapi, Tünde, Putnik, Predrag, Rakočević, Zlatko Lj., Novaković, Mirjana M., Miljević, Bojan, Bognár, Szabolcs, Abramović, Biljana F., "Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight" in Nanomaterials, 10, no. 8 (2020):1-15,
https://doi.org/10.3390/nano10081591 . .

TY  - JOUR
AU  - Pezo, Milada L.
AU  - Pezo, Lato
AU  - Jovanović, Aca
AU  - Terzić, Anja
AU  - Andrić, Ljubiša
AU  - Lončar, Biljana
AU  - Kojić, Predrag
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0032591018304480
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7719
AB  - In this paper, five types of horizontal single-pitch screw conveyors with modified geometry, with three different lengths (400, 600 and 800 mm) were investigated for transport and auxiliary mixing action of two materials: natural zeolite and quartz aggregate (sand) with particle sizes 3, 4 and 5 mm. The geometry of the screw transporter is changed by welding three additional helices oriented in the same or the opposite direction from screw cutting edges, enabling the premixing of materials, during the transport. The proper mixing of the observed materials provides an adequate disposition of zeolite particles within the composite and prevents agglomeration and interference with cement hydration. Zeolite application as a binder in a building material is a possible solution to environmental pollution problems caused by cement production. The influences of screw length, particle diameter, the studied geometry variations of screw design, on the mixing performances of the screw conveyor-mixer during material transport were explored. All investigations were performed experimentally and numerically, by using Discrete Element Method (DEM). The experimental results and the results of the DEM investigation were used for the development of mathematical models for the prediction of mixing quality, which are presented in the form of second order polynomial and artificial neural network model.
T2  - Powder Technology
T1  - Discrete element model of particle transport and premixing action in modified screw conveyors
VL  - 336
SP  - 255
EP  - 264
DO  - 10.1016/j.powtec.2018.06.009
ER  - 

@article{
author = "Pezo, Milada L. and Pezo, Lato and Jovanović, Aca and Terzić, Anja and Andrić, Ljubiša and Lončar, Biljana and Kojić, Predrag",
year = "2018",
abstract = "In this paper, five types of horizontal single-pitch screw conveyors with modified geometry, with three different lengths (400, 600 and 800 mm) were investigated for transport and auxiliary mixing action of two materials: natural zeolite and quartz aggregate (sand) with particle sizes 3, 4 and 5 mm. The geometry of the screw transporter is changed by welding three additional helices oriented in the same or the opposite direction from screw cutting edges, enabling the premixing of materials, during the transport. The proper mixing of the observed materials provides an adequate disposition of zeolite particles within the composite and prevents agglomeration and interference with cement hydration. Zeolite application as a binder in a building material is a possible solution to environmental pollution problems caused by cement production. The influences of screw length, particle diameter, the studied geometry variations of screw design, on the mixing performances of the screw conveyor-mixer during material transport were explored. All investigations were performed experimentally and numerically, by using Discrete Element Method (DEM). The experimental results and the results of the DEM investigation were used for the development of mathematical models for the prediction of mixing quality, which are presented in the form of second order polynomial and artificial neural network model.",
journal = "Powder Technology",
title = "Discrete element model of particle transport and premixing action in modified screw conveyors",
volume = "336",
pages = "255-264",
doi = "10.1016/j.powtec.2018.06.009"
}

Pezo, M. L., Pezo, L., Jovanović, A., Terzić, A., Andrić, L., Lončar, B.,& Kojić, P.. (2018). Discrete element model of particle transport and premixing action in modified screw conveyors. in Powder Technology, 336, 255-264.
https://doi.org/10.1016/j.powtec.2018.06.009

Pezo ML, Pezo L, Jovanović A, Terzić A, Andrić L, Lončar B, Kojić P. Discrete element model of particle transport and premixing action in modified screw conveyors. in Powder Technology. 2018;336:255-264.
doi:10.1016/j.powtec.2018.06.009 .

Pezo, Milada L., Pezo, Lato, Jovanović, Aca, Terzić, Anja, Andrić, Ljubiša, Lončar, Biljana, Kojić, Predrag, "Discrete element model of particle transport and premixing action in modified screw conveyors" in Powder Technology, 336 (2018):255-264,
https://doi.org/10.1016/j.powtec.2018.06.009 . .

TY  - JOUR
AU  - Terzić, Anja
AU  - Đorđević, Nataša
AU  - Mitrić, Miodrag
AU  - Marković, Smilja
AU  - Dordevic, Katarina
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1512
AB  - Due to pozzolanic characteristics, fly ash is commonly used as a cement replacement in construction composites. Addition of natural clays with sorption ability (i.e. zeolite and bentonite) in to the fly ash based construction materials is of both scientific and industrial interest. Namely, due to the application of sorptive clay minerals, it is possible to immobilize toxic heavy metals from the composite structure. The thermal compatibility of fly ash and zeolite, as well as fly ash and bentonite, within the composite was observed during sintering procedure. The starting components were used in 1: 1 ratio and they were applied without additional mechanical treatment. The used compaction pressure for the tablets was 2 t.cm(-2). The sintering process was conducted at 1000 degrees C and 1200 degrees C for two hours in the air atmosphere. The mineralogical phase composition of the non-treated and sintered samples was analyzed using X-ray diffraction method. Scanning electron microscopy was applied in the analysis of the microstructure of starting and sintered samples. The thermal behavior was observed via DTA method. The influence of temperature on the properties of fly ash-zeolite and fly ash-bentonite composites was investigated.
T2  - Science of Sintering
T1  - Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials
VL  - 49
IS  - 1
SP  - 23
EP  - 37
DO  - 10.2298/SOS1701023T
ER  - 

@article{
author = "Terzić, Anja and Đorđević, Nataša and Mitrić, Miodrag and Marković, Smilja and Dordevic, Katarina and Pavlović, Vladimir B.",
year = "2017",
abstract = "Due to pozzolanic characteristics, fly ash is commonly used as a cement replacement in construction composites. Addition of natural clays with sorption ability (i.e. zeolite and bentonite) in to the fly ash based construction materials is of both scientific and industrial interest. Namely, due to the application of sorptive clay minerals, it is possible to immobilize toxic heavy metals from the composite structure. The thermal compatibility of fly ash and zeolite, as well as fly ash and bentonite, within the composite was observed during sintering procedure. The starting components were used in 1: 1 ratio and they were applied without additional mechanical treatment. The used compaction pressure for the tablets was 2 t.cm(-2). The sintering process was conducted at 1000 degrees C and 1200 degrees C for two hours in the air atmosphere. The mineralogical phase composition of the non-treated and sintered samples was analyzed using X-ray diffraction method. Scanning electron microscopy was applied in the analysis of the microstructure of starting and sintered samples. The thermal behavior was observed via DTA method. The influence of temperature on the properties of fly ash-zeolite and fly ash-bentonite composites was investigated.",
journal = "Science of Sintering",
title = "Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials",
volume = "49",
number = "1",
pages = "23-37",
doi = "10.2298/SOS1701023T"
}

Terzić, A., Đorđević, N., Mitrić, M., Marković, S., Dordevic, K.,& Pavlović, V. B.. (2017). Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials. in Science of Sintering, 49(1), 23-37.
https://doi.org/10.2298/SOS1701023T

Terzić A, Đorđević N, Mitrić M, Marković S, Dordevic K, Pavlović VB. Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials. in Science of Sintering. 2017;49(1):23-37.
doi:10.2298/SOS1701023T .

Terzić, Anja, Đorđević, Nataša, Mitrić, Miodrag, Marković, Smilja, Dordevic, Katarina, Pavlović, Vladimir B., "Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials" in Science of Sintering, 49, no. 1 (2017):23-37,
https://doi.org/10.2298/SOS1701023T . .

TY  - JOUR
AU  - Hadnadjev-Kostic, M.
AU  - Vulic, T.
AU  - Ranogajec, J.
AU  - Marinkovic-Neducin, R.
AU  - Radosavljević-Mihajlović, Ana S.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5260
AB  - The development of nanocomposite photocatalyst based on layered double hydroxides (LDHs) associated with TiO2 was the subject of this research. The thermally activated Zn-Al LDHs were selected as catalyst support precursor because of their proven photocatalytic activity and therefore their possible contribution to overall activity of novel Ti-Zn-Al nanocomposite. The catalyst precursor (Zn-Al LDH) was synthesized by low supersaturation coprecipitation method, and its association with active TiO2 component targeting the formation of novel Ti-Zn-Al nanocomposite was achieved by wet impregnation. Simultaneous thermal analysis (TG-DTA) was used to investigate the thermal behavior of Zn-Al LDH and Ti-Zn-Al LDHs. Complementary, morphology, texture, and structure characterization was carried out. The photocatalytic test reaction was performed under UV light using the methylene blue degradation. The results confirmed a successful impregnation of TiO2 on catalyst support precursor Zn-Al-LDH followed by considerable change in morphology and structure of Zn-Al LDH precursor. It was concluded that the synergic effect between TiO2 and Zn-Al LDH precursor contributes to the overall photocatalytic activity.
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Thermal and photocatalytic behavior of Ti/LDH nanocomposites
VL  - 111
IS  - 2
SP  - 1155
EP  - 1162
DO  - 10.1007/s10973-012-2226-5
ER  - 

@article{
author = "Hadnadjev-Kostic, M. and Vulic, T. and Ranogajec, J. and Marinkovic-Neducin, R. and Radosavljević-Mihajlović, Ana S.",
year = "2013",
abstract = "The development of nanocomposite photocatalyst based on layered double hydroxides (LDHs) associated with TiO2 was the subject of this research. The thermally activated Zn-Al LDHs were selected as catalyst support precursor because of their proven photocatalytic activity and therefore their possible contribution to overall activity of novel Ti-Zn-Al nanocomposite. The catalyst precursor (Zn-Al LDH) was synthesized by low supersaturation coprecipitation method, and its association with active TiO2 component targeting the formation of novel Ti-Zn-Al nanocomposite was achieved by wet impregnation. Simultaneous thermal analysis (TG-DTA) was used to investigate the thermal behavior of Zn-Al LDH and Ti-Zn-Al LDHs. Complementary, morphology, texture, and structure characterization was carried out. The photocatalytic test reaction was performed under UV light using the methylene blue degradation. The results confirmed a successful impregnation of TiO2 on catalyst support precursor Zn-Al-LDH followed by considerable change in morphology and structure of Zn-Al LDH precursor. It was concluded that the synergic effect between TiO2 and Zn-Al LDH precursor contributes to the overall photocatalytic activity.",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Thermal and photocatalytic behavior of Ti/LDH nanocomposites",
volume = "111",
number = "2",
pages = "1155-1162",
doi = "10.1007/s10973-012-2226-5"
}

Hadnadjev-Kostic, M., Vulic, T., Ranogajec, J., Marinkovic-Neducin, R.,& Radosavljević-Mihajlović, A. S.. (2013). Thermal and photocatalytic behavior of Ti/LDH nanocomposites. in Journal of Thermal Analysis and Calorimetry, 111(2), 1155-1162.
https://doi.org/10.1007/s10973-012-2226-5

Hadnadjev-Kostic M, Vulic T, Ranogajec J, Marinkovic-Neducin R, Radosavljević-Mihajlović AS. Thermal and photocatalytic behavior of Ti/LDH nanocomposites. in Journal of Thermal Analysis and Calorimetry. 2013;111(2):1155-1162.
doi:10.1007/s10973-012-2226-5 .

Hadnadjev-Kostic, M., Vulic, T., Ranogajec, J., Marinkovic-Neducin, R., Radosavljević-Mihajlović, Ana S., "Thermal and photocatalytic behavior of Ti/LDH nanocomposites" in Journal of Thermal Analysis and Calorimetry, 111, no. 2 (2013):1155-1162,
https://doi.org/10.1007/s10973-012-2226-5 . .