TY  - JOUR
AU  - Stojmenović, Marija
AU  - Nišić, Neda
AU  - Žunić, Milan
AU  - Basoli, Francesco
AU  - Gulicovki, Jelena
AU  - Ristović, Ivica
AU  - Kragović, Milan M.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10622
AB  - Nanosized multi-doped ceria with composition Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-δ (CNSGDY) as perspective solid ionic conductor was obtained by modified glycine-nitrate procedure (MGNP) and room temperature self-propagating reaction (SPRT). The pressed pellets of both powders were sintered at 1550°C for 2 h in an air atmosphere. The obtained sintered samples were characterized by XRPD, Raman spectroscopy, FESEM, EDS and EIS methods. Despite a high temperature of sintering, XRPD and FESEM analyses of the samples confirmed appropriate dimensions of grains with fluorite structure. Overall concentration of introduced dopants (x = 0.2) in the structure of CeO2 after the sintering process was confirmed by EDS analysis. After sintering, Raman spectroscopy confirmed retention of the oxygen vacancies in the ceria lattice, which is in accordance with the improvement of ionic conductivity of solid ionic conductors. The highest value of total conductivity was obtained for the sintered MGNP sample at 700°C (4.22 × 10−2 S cm−1), with the corresponding activation energy of 0.26 eV.
T2  - Processing and Application of Ceramics
T1  - Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs
VL  - 16
IS  - 4
SP  - 391
EP  - 401
DO  - 10.2298/PAC2204391S
ER  - 

@article{
author = "Stojmenović, Marija and Nišić, Neda and Žunić, Milan and Basoli, Francesco and Gulicovki, Jelena and Ristović, Ivica and Kragović, Milan M.",
year = "2022",
abstract = "Nanosized multi-doped ceria with composition Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-δ (CNSGDY) as perspective solid ionic conductor was obtained by modified glycine-nitrate procedure (MGNP) and room temperature self-propagating reaction (SPRT). The pressed pellets of both powders were sintered at 1550°C for 2 h in an air atmosphere. The obtained sintered samples were characterized by XRPD, Raman spectroscopy, FESEM, EDS and EIS methods. Despite a high temperature of sintering, XRPD and FESEM analyses of the samples confirmed appropriate dimensions of grains with fluorite structure. Overall concentration of introduced dopants (x = 0.2) in the structure of CeO2 after the sintering process was confirmed by EDS analysis. After sintering, Raman spectroscopy confirmed retention of the oxygen vacancies in the ceria lattice, which is in accordance with the improvement of ionic conductivity of solid ionic conductors. The highest value of total conductivity was obtained for the sintered MGNP sample at 700°C (4.22 × 10−2 S cm−1), with the corresponding activation energy of 0.26 eV.",
journal = "Processing and Application of Ceramics",
title = "Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs",
volume = "16",
number = "4",
pages = "391-401",
doi = "10.2298/PAC2204391S"
}

Stojmenović, M., Nišić, N., Žunić, M., Basoli, F., Gulicovki, J., Ristović, I.,& Kragović, M. M.. (2022). Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs. in Processing and Application of Ceramics, 16(4), 391-401.
https://doi.org/10.2298/PAC2204391S

Stojmenović M, Nišić N, Žunić M, Basoli F, Gulicovki J, Ristović I, Kragović MM. Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs. in Processing and Application of Ceramics. 2022;16(4):391-401.
doi:10.2298/PAC2204391S .

Stojmenović, Marija, Nišić, Neda, Žunić, Milan, Basoli, Francesco, Gulicovki, Jelena, Ristović, Ivica, Kragović, Milan M., "Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs" in Processing and Application of Ceramics, 16, no. 4 (2022):391-401,
https://doi.org/10.2298/PAC2204391S . .