Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites

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Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (en)
Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (sr)
Uticaj veličine, oblika i strukture nanočestica na njihova svojstva i svojstva nanokompozita (sr_RS)
Authors

Publications

PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix

Pavlović, Vera P.; Tošić, Dragana; Dojčilović, Radovan; Dudić, Duško; Dramićanin, Miroslav; Medić, Mina; McPherson, Michael M.; Pavlović, Vladimir B.; Vlahović, Branislav; Đoković, Vladimir

(2021)

TY  - JOUR
AU  - Pavlović, Vera P.
AU  - Tošić, Dragana
AU  - Dojčilović, Radovan
AU  - Dudić, Duško
AU  - Dramićanin, Miroslav
AU  - Medić, Mina
AU  - McPherson, Michael M.
AU  - Pavlović, Vladimir B.
AU  - Vlahović, Branislav
AU  - Đoković, Vladimir
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9563
AB  - Na0.25K0.25Bi0.5TiO3 (NKBT) perovskite particles are synthesized by solid-state method and used as a filler for polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer. X-ray diffraction analysis of NKBT powders shows that the particles have a rhombohedral perovskite crystal structure (R3c symmetry). Raman spectroscopy reveals that the co-polymer crystallizes predominantly into the mixture of polar β- and γ-crystals, while there is also a contribution of the non-polar α-crystal phase. The introduction of the NKBT into the PVDF-HFP results with an increase in effective dielectric permittivity and this effect depends on the inorganic content in the composite. The most interesting result of the present study is that the introduction of NKBT particles induces the appearance of an additional transition peak in the dielectric spectra of the co-polymer matrix. At the fixed frequency of ~2 kHz, the observed process appears at ~10 °C (about 45° above the glass transition temperature) and its magnitude strongly depends on the amount of the NKBT in the composite. Dielectric spectroscopy measurements of the composites are carried out in the wide range of frequencies (from 0.1 Hz to 1 MHz) and temperatures (from −100 to 100 °C). They reveal that the novel process can be clearly distinguished in the frequency range between 160 Hz and ~50 kHz. © 2021 The Authors
T2  - Polymer Testing
T1  - PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix
VL  - 96
SP  - 107093
DO  - 10.1016/j.polymertesting.2021.107093
ER  - 
@article{
author = "Pavlović, Vera P. and Tošić, Dragana and Dojčilović, Radovan and Dudić, Duško and Dramićanin, Miroslav and Medić, Mina and McPherson, Michael M. and Pavlović, Vladimir B. and Vlahović, Branislav and Đoković, Vladimir",
year = "2021",
abstract = "Na0.25K0.25Bi0.5TiO3 (NKBT) perovskite particles are synthesized by solid-state method and used as a filler for polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) co-polymer. X-ray diffraction analysis of NKBT powders shows that the particles have a rhombohedral perovskite crystal structure (R3c symmetry). Raman spectroscopy reveals that the co-polymer crystallizes predominantly into the mixture of polar β- and γ-crystals, while there is also a contribution of the non-polar α-crystal phase. The introduction of the NKBT into the PVDF-HFP results with an increase in effective dielectric permittivity and this effect depends on the inorganic content in the composite. The most interesting result of the present study is that the introduction of NKBT particles induces the appearance of an additional transition peak in the dielectric spectra of the co-polymer matrix. At the fixed frequency of ~2 kHz, the observed process appears at ~10 °C (about 45° above the glass transition temperature) and its magnitude strongly depends on the amount of the NKBT in the composite. Dielectric spectroscopy measurements of the composites are carried out in the wide range of frequencies (from 0.1 Hz to 1 MHz) and temperatures (from −100 to 100 °C). They reveal that the novel process can be clearly distinguished in the frequency range between 160 Hz and ~50 kHz. © 2021 The Authors",
journal = "Polymer Testing",
title = "PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix",
volume = "96",
pages = "107093",
doi = "10.1016/j.polymertesting.2021.107093"
}
Pavlović, V. P., Tošić, D., Dojčilović, R., Dudić, D., Dramićanin, M., Medić, M., McPherson, M. M., Pavlović, V. B., Vlahović, B.,& Đoković, V.. (2021). PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix. in Polymer Testing, 96, 107093.
https://doi.org/10.1016/j.polymertesting.2021.107093
Pavlović VP, Tošić D, Dojčilović R, Dudić D, Dramićanin M, Medić M, McPherson MM, Pavlović VB, Vlahović B, Đoković V. PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix. in Polymer Testing. 2021;96:107093.
doi:10.1016/j.polymertesting.2021.107093 .
Pavlović, Vera P., Tošić, Dragana, Dojčilović, Radovan, Dudić, Duško, Dramićanin, Miroslav, Medić, Mina, McPherson, Michael M., Pavlović, Vladimir B., Vlahović, Branislav, Đoković, Vladimir, "PVDF-HFP/NKBT composite dielectrics: Perovskite particles induce the appearance of an additional dielectric relaxation process in ferroelectric polymer matrix" in Polymer Testing, 96 (2021):107093,
https://doi.org/10.1016/j.polymertesting.2021.107093 . .
1

Nano-silica-based urea–formaldehyde composite with some derivates of coumarin as formaldehyde scavenger: hydrolytical and thermal stability

Jovanović, Vojislav; Samaržija-Jovanović, Suzana; Petković, Branka B.; Jovanović, Slaviša; Marković, Gordana; Porobić, Slavica; Marinović-Cincović, Milena

(2021)

TY  - JOUR
AU  - Jovanović, Vojislav
AU  - Samaržija-Jovanović, Suzana
AU  - Petković, Branka B.
AU  - Jovanović, Slaviša
AU  - Marković, Gordana
AU  - Porobić, Slavica
AU  - Marinović-Cincović, Milena
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8907
AB  - The hydrolytic stability of two nano-SiO2-based UF composites with derivates of coumarin (names as K-1 and K-2) was investigated. K-1 is 3-nitro-4-(p-tolylamino)-2H-chromen-2-one and K-2: 4-((3-nitro-2-oxo-2H-chromen-4-yl)amino)benzenesulfonamide. Two types of nano-silica-based urea–formaldehyde (UF), composite materials with a formaldehyde-to-urea (F/U) ratio of 0.8, were synthesized (UF/K-1/SiO2, and UF/K-2/SiO2). The hydrolytic stability of modified UF composite was determined by measuring the mass loss and liberated formaldehyde concentration of modified UF composite after acid hydrolysis. Obtained results showed that the hydrolytic stability of modified resins with derivates of coumarin was enhanced. The formaldehyde emission of modified UF/K-1/SiO2 composite is lower compared with UF/K-2/SiO2 composite. The thermal behavior of materials was studied by non-isothermal thermo-gravimetric analysis and differential thermal gravimetry supported by data from ATR-IR spectroscopy. The shift of temperature values for selected mass losses (T5%) to a high temperature indicates the increase in thermal stability of samples based on UF resin modified with K-2. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - Polymer Bulletin
T1  - Nano-silica-based urea–formaldehyde composite with some derivates of coumarin as formaldehyde scavenger: hydrolytical and thermal stability
VL  - 78
IS  - 1
SP  - 399
EP  - 413
DO  - 10.1007/s00289-020-03114-6
ER  - 
@article{
author = "Jovanović, Vojislav and Samaržija-Jovanović, Suzana and Petković, Branka B. and Jovanović, Slaviša and Marković, Gordana and Porobić, Slavica and Marinović-Cincović, Milena",
year = "2021",
abstract = "The hydrolytic stability of two nano-SiO2-based UF composites with derivates of coumarin (names as K-1 and K-2) was investigated. K-1 is 3-nitro-4-(p-tolylamino)-2H-chromen-2-one and K-2: 4-((3-nitro-2-oxo-2H-chromen-4-yl)amino)benzenesulfonamide. Two types of nano-silica-based urea–formaldehyde (UF), composite materials with a formaldehyde-to-urea (F/U) ratio of 0.8, were synthesized (UF/K-1/SiO2, and UF/K-2/SiO2). The hydrolytic stability of modified UF composite was determined by measuring the mass loss and liberated formaldehyde concentration of modified UF composite after acid hydrolysis. Obtained results showed that the hydrolytic stability of modified resins with derivates of coumarin was enhanced. The formaldehyde emission of modified UF/K-1/SiO2 composite is lower compared with UF/K-2/SiO2 composite. The thermal behavior of materials was studied by non-isothermal thermo-gravimetric analysis and differential thermal gravimetry supported by data from ATR-IR spectroscopy. The shift of temperature values for selected mass losses (T5%) to a high temperature indicates the increase in thermal stability of samples based on UF resin modified with K-2. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "Polymer Bulletin",
title = "Nano-silica-based urea–formaldehyde composite with some derivates of coumarin as formaldehyde scavenger: hydrolytical and thermal stability",
volume = "78",
number = "1",
pages = "399-413",
doi = "10.1007/s00289-020-03114-6"
}
Jovanović, V., Samaržija-Jovanović, S., Petković, B. B., Jovanović, S., Marković, G., Porobić, S.,& Marinović-Cincović, M.. (2021). Nano-silica-based urea–formaldehyde composite with some derivates of coumarin as formaldehyde scavenger: hydrolytical and thermal stability. in Polymer Bulletin, 78(1), 399-413.
https://doi.org/10.1007/s00289-020-03114-6
Jovanović V, Samaržija-Jovanović S, Petković BB, Jovanović S, Marković G, Porobić S, Marinović-Cincović M. Nano-silica-based urea–formaldehyde composite with some derivates of coumarin as formaldehyde scavenger: hydrolytical and thermal stability. in Polymer Bulletin. 2021;78(1):399-413.
doi:10.1007/s00289-020-03114-6 .
Jovanović, Vojislav, Samaržija-Jovanović, Suzana, Petković, Branka B., Jovanović, Slaviša, Marković, Gordana, Porobić, Slavica, Marinović-Cincović, Milena, "Nano-silica-based urea–formaldehyde composite with some derivates of coumarin as formaldehyde scavenger: hydrolytical and thermal stability" in Polymer Bulletin, 78, no. 1 (2021):399-413,
https://doi.org/10.1007/s00289-020-03114-6 . .

Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization

Janković, Marija M.; Janković, Bojan Ž.; Marinović-Cincović, Milena; Porobić, Slavica; Krneta-Nikolić, Jelena D.; Sarap, Nataša

(2020)

TY  - JOUR
AU  - Janković, Marija M.
AU  - Janković, Bojan Ž.
AU  - Marinović-Cincović, Milena
AU  - Porobić, Slavica
AU  - Krneta-Nikolić, Jelena D.
AU  - Sarap, Nataša
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8905
AB  - Simultaneous thermal analysis (TG–DTA) of low-rank coals from different annual periods (2015 and 2018) which originate from Kolubara and Nikola Tesla A (TENT A) coal-fired power plants was studied to identify their combustion characteristics and self-ignition risks. In order to investigate kinetics of thermo-oxidative degradation, model-free models including the Friedman and Kissinger–Akahira–Sunose methods were applied. In accordance with obtained kinetic results, numerical optimization of combustion process was implemented. Homogeneous and heterogeneous types of ignition were identified for the tested coals, and factors that affect their occurrence are the used heating rate and volatile matter content. From thermal susceptibility graph, it was found that the tested coals expand in a wide range of self-ignition risk, depending on their coal rank. The youngest coal (TENT A (2018)) has the largest propensity to self-ignite among high-ranking coals. It was found that less tendency of 2018 coals to show true isokinetic temperature in comparison with 2015 coals is a consequence of intraparticle diffusion limitations, and change of char properties, at higher conversion values. Gamma spectrometry analysis of coals showed that higher concentration of 40K radionuclide (which is in mineral composition) may contribute through its deposition on available sites, decreasing surface area for reaction with oxidizing species. © 2020, Akadémiai Kiadó, Budapest, Hungary.
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization
VL  - 142
IS  - 2
SP  - 547
EP  - 564
DO  - 10.1007/s10973-020-09288-5
ER  - 
@article{
author = "Janković, Marija M. and Janković, Bojan Ž. and Marinović-Cincović, Milena and Porobić, Slavica and Krneta-Nikolić, Jelena D. and Sarap, Nataša",
year = "2020",
abstract = "Simultaneous thermal analysis (TG–DTA) of low-rank coals from different annual periods (2015 and 2018) which originate from Kolubara and Nikola Tesla A (TENT A) coal-fired power plants was studied to identify their combustion characteristics and self-ignition risks. In order to investigate kinetics of thermo-oxidative degradation, model-free models including the Friedman and Kissinger–Akahira–Sunose methods were applied. In accordance with obtained kinetic results, numerical optimization of combustion process was implemented. Homogeneous and heterogeneous types of ignition were identified for the tested coals, and factors that affect their occurrence are the used heating rate and volatile matter content. From thermal susceptibility graph, it was found that the tested coals expand in a wide range of self-ignition risk, depending on their coal rank. The youngest coal (TENT A (2018)) has the largest propensity to self-ignite among high-ranking coals. It was found that less tendency of 2018 coals to show true isokinetic temperature in comparison with 2015 coals is a consequence of intraparticle diffusion limitations, and change of char properties, at higher conversion values. Gamma spectrometry analysis of coals showed that higher concentration of 40K radionuclide (which is in mineral composition) may contribute through its deposition on available sites, decreasing surface area for reaction with oxidizing species. © 2020, Akadémiai Kiadó, Budapest, Hungary.",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization",
volume = "142",
number = "2",
pages = "547-564",
doi = "10.1007/s10973-020-09288-5"
}
Janković, M. M., Janković, B. Ž., Marinović-Cincović, M., Porobić, S., Krneta-Nikolić, J. D.,& Sarap, N.. (2020). Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization. in Journal of Thermal Analysis and Calorimetry, 142(2), 547-564.
https://doi.org/10.1007/s10973-020-09288-5
Janković MM, Janković BŽ, Marinović-Cincović M, Porobić S, Krneta-Nikolić JD, Sarap N. Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization. in Journal of Thermal Analysis and Calorimetry. 2020;142(2):547-564.
doi:10.1007/s10973-020-09288-5 .
Janković, Marija M., Janković, Bojan Ž., Marinović-Cincović, Milena, Porobić, Slavica, Krneta-Nikolić, Jelena D., Sarap, Nataša, "Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization" in Journal of Thermal Analysis and Calorimetry, 142, no. 2 (2020):547-564,
https://doi.org/10.1007/s10973-020-09288-5 . .
3
2
3

Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures

Papan, Jelena; Ristić, Zoran; Ćirić, Aleksandar; Kuzman, Sanja; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Papan, Jelena
AU  - Ristić, Zoran
AU  - Ćirić, Aleksandar
AU  - Kuzman, Sanja
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8901
AB  - The red phosphor Y2Mo4O15:Eu3+ calcined at different temperatures is obtained by a solid-state method, and is investigated in this article. Usage of solid-state method with the combination of five different calcination temperatures (500, 550, 600, 650, and 700 °C) leads to the formation of pure monoclinic phase in all samples apart from the one calcined at the lowest temperature. Crystallite size obtained by Rietveld refinement is in the range of 38–55 nm. Scanning electron microscopy analysis confirms the presence of agglomerates. Luminescence emission spectra and emission decay curves are measured for all pure samples, and parameters derived from these measurements are used for Judd–Ofelt analysis. International commission on illumination (CIE) chromaticity diagram confirms the presence of pure red emission and high quantum efficiency. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - Physica Status Solidi. B: Basic Research
T1  - Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures
VL  - 257
IS  - 8
SP  - 1900454
DO  - 10.1002/pssb.201900454
ER  - 
@article{
author = "Papan, Jelena and Ristić, Zoran and Ćirić, Aleksandar and Kuzman, Sanja and Dramićanin, Miroslav",
year = "2020",
abstract = "The red phosphor Y2Mo4O15:Eu3+ calcined at different temperatures is obtained by a solid-state method, and is investigated in this article. Usage of solid-state method with the combination of five different calcination temperatures (500, 550, 600, 650, and 700 °C) leads to the formation of pure monoclinic phase in all samples apart from the one calcined at the lowest temperature. Crystallite size obtained by Rietveld refinement is in the range of 38–55 nm. Scanning electron microscopy analysis confirms the presence of agglomerates. Luminescence emission spectra and emission decay curves are measured for all pure samples, and parameters derived from these measurements are used for Judd–Ofelt analysis. International commission on illumination (CIE) chromaticity diagram confirms the presence of pure red emission and high quantum efficiency. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "Physica Status Solidi. B: Basic Research",
title = "Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures",
volume = "257",
number = "8",
pages = "1900454",
doi = "10.1002/pssb.201900454"
}
Papan, J., Ristić, Z., Ćirić, A., Kuzman, S.,& Dramićanin, M.. (2020). Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures. in Physica Status Solidi. B: Basic Research, 257(8), 1900454.
https://doi.org/10.1002/pssb.201900454
Papan J, Ristić Z, Ćirić A, Kuzman S, Dramićanin M. Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures. in Physica Status Solidi. B: Basic Research. 2020;257(8):1900454.
doi:10.1002/pssb.201900454 .
Papan, Jelena, Ristić, Zoran, Ćirić, Aleksandar, Kuzman, Sanja, Dramićanin, Miroslav, "Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures" in Physica Status Solidi. B: Basic Research, 257, no. 8 (2020):1900454,
https://doi.org/10.1002/pssb.201900454 . .
1
1
1

Simulated solar light driven performance of nanosized ZnIn2S4/dye system: decolourization vs. photodegradation

Savić, Tatjana D.; Carević, Milica V.; Mitrić, Miodrag; Kuljanin-Jakovljević, Jadranka Ž.; Abazović, Nadica; Čomor, Mirjana

(2020)

TY  - JOUR
AU  - Savić, Tatjana D.
AU  - Carević, Milica V.
AU  - Mitrić, Miodrag
AU  - Kuljanin-Jakovljević, Jadranka Ž.
AU  - Abazović, Nadica
AU  - Čomor, Mirjana
PY  - 2020
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8617
AB  - Hexagonal ZnIn2S4 is synthesized by simple and low-cost hydrothermal route. TEM images revealed formation of nanosheets. The estimated band-gap energy of synthesized sample is in the visible spectral region and has a value of about 2.25 eV. Photocatalytic properties of synthesized sample are probed in photocatalytic degradation of three selected dyes different in nature and structure, Rhodamine B (RhB), Methylene blue (MB) and Methyl orange (MO), under the illumination with simulated Solar light. Obtained results revealed that photocatalytic degradation of RhB and MO is mainly result of synergic effect of photogenerated holes and oxygen, while primary effect in ZnIn2S4/MB system is bleaching of the dye, but no photodegradation was observed. © 2019 Elsevier B.V.
T2  - Journal of Photochemistry and Photobiology A: Chemistry
T1  - Simulated solar light driven performance of nanosized ZnIn2S4/dye system: decolourization vs. photodegradation
VL  - 388
SP  - 112154
DO  - 10.1016/j.jphotochem.2019.112154
ER  - 
@article{
author = "Savić, Tatjana D. and Carević, Milica V. and Mitrić, Miodrag and Kuljanin-Jakovljević, Jadranka Ž. and Abazović, Nadica and Čomor, Mirjana",
year = "2020",
abstract = "Hexagonal ZnIn2S4 is synthesized by simple and low-cost hydrothermal route. TEM images revealed formation of nanosheets. The estimated band-gap energy of synthesized sample is in the visible spectral region and has a value of about 2.25 eV. Photocatalytic properties of synthesized sample are probed in photocatalytic degradation of three selected dyes different in nature and structure, Rhodamine B (RhB), Methylene blue (MB) and Methyl orange (MO), under the illumination with simulated Solar light. Obtained results revealed that photocatalytic degradation of RhB and MO is mainly result of synergic effect of photogenerated holes and oxygen, while primary effect in ZnIn2S4/MB system is bleaching of the dye, but no photodegradation was observed. © 2019 Elsevier B.V.",
journal = "Journal of Photochemistry and Photobiology A: Chemistry",
title = "Simulated solar light driven performance of nanosized ZnIn2S4/dye system: decolourization vs. photodegradation",
volume = "388",
pages = "112154",
doi = "10.1016/j.jphotochem.2019.112154"
}
Savić, T. D., Carević, M. V., Mitrić, M., Kuljanin-Jakovljević, J. Ž., Abazović, N.,& Čomor, M.. (2020). Simulated solar light driven performance of nanosized ZnIn2S4/dye system: decolourization vs. photodegradation. in Journal of Photochemistry and Photobiology A: Chemistry, 388, 112154.
https://doi.org/10.1016/j.jphotochem.2019.112154
Savić TD, Carević MV, Mitrić M, Kuljanin-Jakovljević JŽ, Abazović N, Čomor M. Simulated solar light driven performance of nanosized ZnIn2S4/dye system: decolourization vs. photodegradation. in Journal of Photochemistry and Photobiology A: Chemistry. 2020;388:112154.
doi:10.1016/j.jphotochem.2019.112154 .
Savić, Tatjana D., Carević, Milica V., Mitrić, Miodrag, Kuljanin-Jakovljević, Jadranka Ž., Abazović, Nadica, Čomor, Mirjana, "Simulated solar light driven performance of nanosized ZnIn2S4/dye system: decolourization vs. photodegradation" in Journal of Photochemistry and Photobiology A: Chemistry, 388 (2020):112154,
https://doi.org/10.1016/j.jphotochem.2019.112154 . .
1
1
1

Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol

Carević, Milica V.; Savić, Tatjana D.; Abazović, Nadica; Mojović, Miloš D.; Novaković, Tatjana B.; Čomor, Mirjana

(2020)

TY  - JOUR
AU  - Carević, Milica V.
AU  - Savić, Tatjana D.
AU  - Abazović, Nadica
AU  - Mojović, Miloš D.
AU  - Novaković, Tatjana B.
AU  - Čomor, Mirjana
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8807
AB  - Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline phases; monoclinic and tetragonal (g 4.8 and g 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol. © 2019 Elsevier Ltd and Techna Group S.r.l.
T2  - Ceramics International
T1  - Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol
VL  - 46
IS  - 5
SP  - 6820
EP  - 6827
DO  - 10.1016/j.ceramint.2019.11.175
ER  - 
@article{
author = "Carević, Milica V. and Savić, Tatjana D. and Abazović, Nadica and Mojović, Miloš D. and Novaković, Tatjana B. and Čomor, Mirjana",
year = "2020",
abstract = "Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline phases; monoclinic and tetragonal (g 4.8 and g 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol. © 2019 Elsevier Ltd and Techna Group S.r.l.",
journal = "Ceramics International",
title = "Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol",
volume = "46",
number = "5",
pages = "6820-6827",
doi = "10.1016/j.ceramint.2019.11.175"
}
Carević, M. V., Savić, T. D., Abazović, N., Mojović, M. D., Novaković, T. B.,& Čomor, M.. (2020). Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol. in Ceramics International, 46(5), 6820-6827.
https://doi.org/10.1016/j.ceramint.2019.11.175
Carević MV, Savić TD, Abazović N, Mojović MD, Novaković TB, Čomor M. Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol. in Ceramics International. 2020;46(5):6820-6827.
doi:10.1016/j.ceramint.2019.11.175 .
Carević, Milica V., Savić, Tatjana D., Abazović, Nadica, Mojović, Miloš D., Novaković, Tatjana B., Čomor, Mirjana, "Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol" in Ceramics International, 46, no. 5 (2020):6820-6827,
https://doi.org/10.1016/j.ceramint.2019.11.175 . .
4
3
3

Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer

Matijević, Milica; Nakarada, Đura; Liang, Xinyue; Korićanac, Lela; Rajsiglova, Lenka; Vannucci, Luca; Nešić, Maja D.; Vranješ, Mila; Mojović, Miloš D.; Mi, Lan; Estrela-Lopis, Irina; Böttner, Julia; Šaponjić, Zoran; Petković, Marijana; Stepić, Milutin

(2020)

TY  - JOUR
AU  - Matijević, Milica
AU  - Nakarada, Đura
AU  - Liang, Xinyue
AU  - Korićanac, Lela
AU  - Rajsiglova, Lenka
AU  - Vannucci, Luca
AU  - Nešić, Maja D.
AU  - Vranješ, Mila
AU  - Mojović, Miloš D.
AU  - Mi, Lan
AU  - Estrela-Lopis, Irina
AU  - Böttner, Julia
AU  - Šaponjić, Zoran
AU  - Petković, Marijana
AU  - Stepić, Milutin
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9058
AB  - TiO2 prolatenanospheroids (PNSs) may be photosensitizers (PSs), which act by catalyzation of hydroxyl radical (∙OH) formation upon light illumination. ∙OH might, in turn, contribute to killing of cancer cells. On the other hand, there is great concern about toxicity in the dark of TiO2 nanoparticles in general. In this work, we have investigated the biocompatibility of TiO2 PNSs of the anatase crystal form (length between 100 and 300 nm and width 50 nm) in the dark with immune cells and light-induced cytotoxicity on several cancer cell lines. The effects of the treatment of different cell lines with several concentrations of TiO2 PNSs suspensions showed the specifics of cells’ viability and the intracellular localization. The results of in vitro studies obtained by cytotoxicity assays adjusted to individual cell lines’ metabolism point towards the biocompatibility of TiO2 PNSs at low and moderate concentrations in the dark, which neither kill the cells, nor induce activation of the immune system cells. Laser scanning confocal microscopy revealed that PNSs are taken up by cells, and insight into the intracellular distribution was obtained in this study.
T2  - Journal of Nanoparticle Research
T1  - Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer
VL  - 22
IS  - 7
SP  - 175
DO  - 10.1007/s11051-020-04899-3
ER  - 
@article{
author = "Matijević, Milica and Nakarada, Đura and Liang, Xinyue and Korićanac, Lela and Rajsiglova, Lenka and Vannucci, Luca and Nešić, Maja D. and Vranješ, Mila and Mojović, Miloš D. and Mi, Lan and Estrela-Lopis, Irina and Böttner, Julia and Šaponjić, Zoran and Petković, Marijana and Stepić, Milutin",
year = "2020",
abstract = "TiO2 prolatenanospheroids (PNSs) may be photosensitizers (PSs), which act by catalyzation of hydroxyl radical (∙OH) formation upon light illumination. ∙OH might, in turn, contribute to killing of cancer cells. On the other hand, there is great concern about toxicity in the dark of TiO2 nanoparticles in general. In this work, we have investigated the biocompatibility of TiO2 PNSs of the anatase crystal form (length between 100 and 300 nm and width 50 nm) in the dark with immune cells and light-induced cytotoxicity on several cancer cell lines. The effects of the treatment of different cell lines with several concentrations of TiO2 PNSs suspensions showed the specifics of cells’ viability and the intracellular localization. The results of in vitro studies obtained by cytotoxicity assays adjusted to individual cell lines’ metabolism point towards the biocompatibility of TiO2 PNSs at low and moderate concentrations in the dark, which neither kill the cells, nor induce activation of the immune system cells. Laser scanning confocal microscopy revealed that PNSs are taken up by cells, and insight into the intracellular distribution was obtained in this study.",
journal = "Journal of Nanoparticle Research",
title = "Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer",
volume = "22",
number = "7",
pages = "175",
doi = "10.1007/s11051-020-04899-3"
}
Matijević, M., Nakarada, Đ., Liang, X., Korićanac, L., Rajsiglova, L., Vannucci, L., Nešić, M. D., Vranješ, M., Mojović, M. D., Mi, L., Estrela-Lopis, I., Böttner, J., Šaponjić, Z., Petković, M.,& Stepić, M.. (2020). Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer. in Journal of Nanoparticle Research, 22(7), 175.
https://doi.org/10.1007/s11051-020-04899-3
Matijević M, Nakarada Đ, Liang X, Korićanac L, Rajsiglova L, Vannucci L, Nešić MD, Vranješ M, Mojović MD, Mi L, Estrela-Lopis I, Böttner J, Šaponjić Z, Petković M, Stepić M. Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer. in Journal of Nanoparticle Research. 2020;22(7):175.
doi:10.1007/s11051-020-04899-3 .
Matijević, Milica, Nakarada, Đura, Liang, Xinyue, Korićanac, Lela, Rajsiglova, Lenka, Vannucci, Luca, Nešić, Maja D., Vranješ, Mila, Mojović, Miloš D., Mi, Lan, Estrela-Lopis, Irina, Böttner, Julia, Šaponjić, Zoran, Petković, Marijana, Stepić, Milutin, "Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer" in Journal of Nanoparticle Research, 22, no. 7 (2020):175,
https://doi.org/10.1007/s11051-020-04899-3 . .
1
1
1

The properties of elastomeric composites based on three network precursors

Jovanović, Vojislav; Jovanović, Slaviša; Marković, Gordana; Samaržija‐Jovanović, Suzana; Porobić, Slavica; Budinski-Simendić, Jaroslava K.; Marinović‐Cincović, Milena

(2019)

TY  - JOUR
AU  - Jovanović, Vojislav
AU  - Jovanović, Slaviša
AU  - Marković, Gordana
AU  - Samaržija‐Jovanović, Suzana
AU  - Porobić, Slavica
AU  - Budinski-Simendić, Jaroslava K.
AU  - Marinović‐Cincović, Milena
PY  - 2019
UR  - https://onlinelibrary.wiley.com/doi/abs/10.1002/pc.24854
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8138
AB  - The powder recycled rubber (PRR) can be used as a filler and a modifier for elastomeric materials and asphalt. Composites based on elastomers and recycled rubber powders are a serious challenge for the environment. The main goal of this paper was to study the effect of rubber powder on the mechanical properties of elastomeric composites based on three precursors of the network. Triple blends were prepared using non-polar natural rubber (NR), polyisoprene rubber (BR), and styrene-butadiene rubber (SBR) (mass ratio 40/40/20). In all rubber compounds, the carbon black (CB)/PRR mass ratio is constant (60). Samples were prepared using two roll mill. The characteristics of hardening (optimum cure time, scorch time, minimum and maximum torque) of rubber mixtures were tested. Tensile strength, modulus at 100% elongation and elongation at break are decreasing with PRR ratio is increasing. It is due to poor adhesion of PRR into NR/BR/SBR/CB matrix. The thermal degradation temperature shifts to a higher temperature up to 5 phr of PRR in NR/BR/SBR/CB rubber blends. Fourier-transform infrared spectra of NR/BR/SBR/CB/PRR samples show that the absorption bands shifted 7–15 cm−1 to higher wavenumbers and confirmed rubber–filler interaction. Morphology was assessed by scanning electron microscopy. POLYM. COMPOS., 40:1307–1314, 2019. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers
T2  - Polymer Composites
T1  - The properties of elastomeric composites based on three network precursors
VL  - 40
IS  - 4
SP  - 1307
EP  - 1314
DO  - 10.1002/pc.24854
ER  - 
@article{
author = "Jovanović, Vojislav and Jovanović, Slaviša and Marković, Gordana and Samaržija‐Jovanović, Suzana and Porobić, Slavica and Budinski-Simendić, Jaroslava K. and Marinović‐Cincović, Milena",
year = "2019",
abstract = "The powder recycled rubber (PRR) can be used as a filler and a modifier for elastomeric materials and asphalt. Composites based on elastomers and recycled rubber powders are a serious challenge for the environment. The main goal of this paper was to study the effect of rubber powder on the mechanical properties of elastomeric composites based on three precursors of the network. Triple blends were prepared using non-polar natural rubber (NR), polyisoprene rubber (BR), and styrene-butadiene rubber (SBR) (mass ratio 40/40/20). In all rubber compounds, the carbon black (CB)/PRR mass ratio is constant (60). Samples were prepared using two roll mill. The characteristics of hardening (optimum cure time, scorch time, minimum and maximum torque) of rubber mixtures were tested. Tensile strength, modulus at 100% elongation and elongation at break are decreasing with PRR ratio is increasing. It is due to poor adhesion of PRR into NR/BR/SBR/CB matrix. The thermal degradation temperature shifts to a higher temperature up to 5 phr of PRR in NR/BR/SBR/CB rubber blends. Fourier-transform infrared spectra of NR/BR/SBR/CB/PRR samples show that the absorption bands shifted 7–15 cm−1 to higher wavenumbers and confirmed rubber–filler interaction. Morphology was assessed by scanning electron microscopy. POLYM. COMPOS., 40:1307–1314, 2019. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers",
journal = "Polymer Composites",
title = "The properties of elastomeric composites based on three network precursors",
volume = "40",
number = "4",
pages = "1307-1314",
doi = "10.1002/pc.24854"
}
Jovanović, V., Jovanović, S., Marković, G., Samaržija‐Jovanović, S., Porobić, S., Budinski-Simendić, J. K.,& Marinović‐Cincović, M.. (2019). The properties of elastomeric composites based on three network precursors. in Polymer Composites, 40(4), 1307-1314.
https://doi.org/10.1002/pc.24854
Jovanović V, Jovanović S, Marković G, Samaržija‐Jovanović S, Porobić S, Budinski-Simendić JK, Marinović‐Cincović M. The properties of elastomeric composites based on three network precursors. in Polymer Composites. 2019;40(4):1307-1314.
doi:10.1002/pc.24854 .
Jovanović, Vojislav, Jovanović, Slaviša, Marković, Gordana, Samaržija‐Jovanović, Suzana, Porobić, Slavica, Budinski-Simendić, Jaroslava K., Marinović‐Cincović, Milena, "The properties of elastomeric composites based on three network precursors" in Polymer Composites, 40, no. 4 (2019):1307-1314,
https://doi.org/10.1002/pc.24854 . .

Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles

Periša, Jovana; Lenhardt Acković, Lea; Jovanović, Dragana J.; Dramićanin, Miroslav

(2019)

TY  - JOUR
AU  - Periša, Jovana
AU  - Lenhardt Acković, Lea
AU  - Jovanović, Dragana J.
AU  - Dramićanin, Miroslav
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0925346719300345
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8043
AB  - EuPO4 and Eu3+-activated REPO4 (RE = La, Dy, Er) ultrasmall fluorescent nanoparticles (NPs) with an average diameter of 2.1 nm were prepared via colloidal synthesis and tested for sensing Cu2+ and other heavy-metal ions. The pure monoclinic monazite crystal structure (space group P121/n1) of the synthesized particles was confirmed using X-ray diffraction measurements, and transmission electron microscopy images showed round particles with a narrow particle-size distribution. The NPs exhibited intense red emission, which is characteristic of the f-f electronic transition of Eu3+, and the quenching of their emission in the presence of heavy-metal ions was revealed by dispersing colloidal particles in a TRIS buffer and then performing photoluminescence measurements. Strong quenching of the emission (at a rate of 0.195 μM−1) was observed upon the addition of Cu2+ ions over the concentration range of 0–10 μM with a limit of detection of 60 nM for Cu2+. The recovery of nearly 90% of the original emission intensity of the probe was achieved via the addition of ethylendiaminetetraacetic acid and was possible in five quenching/recovery cycles. © 2019
T2  - Optical Materials
T1  - Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles
VL  - 89
SP  - 142
EP  - 148
DO  - 10.1016/j.optmat.2018.12.059
ER  - 
@article{
author = "Periša, Jovana and Lenhardt Acković, Lea and Jovanović, Dragana J. and Dramićanin, Miroslav",
year = "2019",
abstract = "EuPO4 and Eu3+-activated REPO4 (RE = La, Dy, Er) ultrasmall fluorescent nanoparticles (NPs) with an average diameter of 2.1 nm were prepared via colloidal synthesis and tested for sensing Cu2+ and other heavy-metal ions. The pure monoclinic monazite crystal structure (space group P121/n1) of the synthesized particles was confirmed using X-ray diffraction measurements, and transmission electron microscopy images showed round particles with a narrow particle-size distribution. The NPs exhibited intense red emission, which is characteristic of the f-f electronic transition of Eu3+, and the quenching of their emission in the presence of heavy-metal ions was revealed by dispersing colloidal particles in a TRIS buffer and then performing photoluminescence measurements. Strong quenching of the emission (at a rate of 0.195 μM−1) was observed upon the addition of Cu2+ ions over the concentration range of 0–10 μM with a limit of detection of 60 nM for Cu2+. The recovery of nearly 90% of the original emission intensity of the probe was achieved via the addition of ethylendiaminetetraacetic acid and was possible in five quenching/recovery cycles. © 2019",
journal = "Optical Materials",
title = "Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles",
volume = "89",
pages = "142-148",
doi = "10.1016/j.optmat.2018.12.059"
}
Periša, J., Lenhardt Acković, L., Jovanović, D. J.,& Dramićanin, M.. (2019). Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles. in Optical Materials, 89, 142-148.
https://doi.org/10.1016/j.optmat.2018.12.059
Periša J, Lenhardt Acković L, Jovanović DJ, Dramićanin M. Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles. in Optical Materials. 2019;89:142-148.
doi:10.1016/j.optmat.2018.12.059 .
Periša, Jovana, Lenhardt Acković, Lea, Jovanović, Dragana J., Dramićanin, Miroslav, "Detection of Cu2+ ions in aqueous solution via emission quenching of colloidal EuPO4 ultrasmall nanoparticles" in Optical Materials, 89 (2019):142-148,
https://doi.org/10.1016/j.optmat.2018.12.059 . .
7
7
6

Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study

Papan, Jelena; Jovanović, Dragana J.; Sekulić, Milica; Glais, Estelle; Dramićanin, Miroslav

(2019)

TY  - JOUR
AU  - Papan, Jelena
AU  - Jovanović, Dragana J.
AU  - Sekulić, Milica
AU  - Glais, Estelle
AU  - Dramićanin, Miroslav
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0032591019301093
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8057
AB  - Defect-fluorite structured Eu 3+ -doped Y 2 Sn 2 O 7 nanoparticles (30–40 nm) were successfully prepared through a facile co-precipitation method without any organic additives or templates followed by calcination in air. Luminescent properties of the as-prepared Y 2-x Eu x Sn 2 O 7 (0.02 ≤ x ≤ 0.6) nanophosphors were fully characterized from an experimental and theoretical point of view (excitation, emission, lifetime, critical concentration, temperature-dependent luminescence and thermal stability, type of interactions and the Judd-Ofelt analysis). The nanophosphors showed relatively sharp excitation bands from 360 to 530 nm and exhibited characteristic emission bands with the most intensive emission centered at 612 nm. In addition, Gd 1.98 Eu 0.02 Sn 2 O 7 and Lu 1.98 Eu 0.02 Sn 2 O 7 samples were prepared in order to study how substitution of RE 3+ (Y 3+ with Gd 3+ and Lu 3+ ions) influences on luminescent properties of RE 1.98 Eu 0.02 Sn 2 O 7 and thermal stability of their luminescence. In order to understand better luminescent properties, the Judd–Ofelt analysis was applied to all the synthesized powders. The highest value of quantum efficiency, ~96%, was estimated for Lu 1.98 Eu 0.02 Sn 2 O 7 . To assess potential application in high-power LEDs, the temperature-dependent emission spectra of Y 1.98 Eu 0.02 Sn 2 O 7 , Gd 1.98 Eu 0.02 Sn 2 O 7 and Lu 1.98 Eu 0.02 Sn 2 O 7 nanophosphors were studied. © 2019 Elsevier B.V.
T2  - Powder Technology
T1  - Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study
VL  - 346
SP  - 150
EP  - 159
DO  - 10.1016/j.powtec.2019.02.013
ER  - 
@article{
author = "Papan, Jelena and Jovanović, Dragana J. and Sekulić, Milica and Glais, Estelle and Dramićanin, Miroslav",
year = "2019",
abstract = "Defect-fluorite structured Eu 3+ -doped Y 2 Sn 2 O 7 nanoparticles (30–40 nm) were successfully prepared through a facile co-precipitation method without any organic additives or templates followed by calcination in air. Luminescent properties of the as-prepared Y 2-x Eu x Sn 2 O 7 (0.02 ≤ x ≤ 0.6) nanophosphors were fully characterized from an experimental and theoretical point of view (excitation, emission, lifetime, critical concentration, temperature-dependent luminescence and thermal stability, type of interactions and the Judd-Ofelt analysis). The nanophosphors showed relatively sharp excitation bands from 360 to 530 nm and exhibited characteristic emission bands with the most intensive emission centered at 612 nm. In addition, Gd 1.98 Eu 0.02 Sn 2 O 7 and Lu 1.98 Eu 0.02 Sn 2 O 7 samples were prepared in order to study how substitution of RE 3+ (Y 3+ with Gd 3+ and Lu 3+ ions) influences on luminescent properties of RE 1.98 Eu 0.02 Sn 2 O 7 and thermal stability of their luminescence. In order to understand better luminescent properties, the Judd–Ofelt analysis was applied to all the synthesized powders. The highest value of quantum efficiency, ~96%, was estimated for Lu 1.98 Eu 0.02 Sn 2 O 7 . To assess potential application in high-power LEDs, the temperature-dependent emission spectra of Y 1.98 Eu 0.02 Sn 2 O 7 , Gd 1.98 Eu 0.02 Sn 2 O 7 and Lu 1.98 Eu 0.02 Sn 2 O 7 nanophosphors were studied. © 2019 Elsevier B.V.",
journal = "Powder Technology",
title = "Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study",
volume = "346",
pages = "150-159",
doi = "10.1016/j.powtec.2019.02.013"
}
Papan, J., Jovanović, D. J., Sekulić, M., Glais, E.,& Dramićanin, M.. (2019). Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study. in Powder Technology, 346, 150-159.
https://doi.org/10.1016/j.powtec.2019.02.013
Papan J, Jovanović DJ, Sekulić M, Glais E, Dramićanin M. Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study. in Powder Technology. 2019;346:150-159.
doi:10.1016/j.powtec.2019.02.013 .
Papan, Jelena, Jovanović, Dragana J., Sekulić, Milica, Glais, Estelle, Dramićanin, Miroslav, "Photoluminescence properties and thermal stability of RE2-xEuxSn2O7 (RE = Y3+, Gd3+, Lu3+) red nanophosphors: An experimental and theoretical study" in Powder Technology, 346 (2019):150-159,
https://doi.org/10.1016/j.powtec.2019.02.013 . .
8
8
8

Structure, morphology, and luminescent behavior of RE3+-doped GdVO4 thin films

Antić, Željka; Prashanthi, Kovur; Jovanović, Dragana J.; Thundat, Thomas; Dramićanin, Miroslav

(2019)

TY  - JOUR
AU  - Antić, Željka
AU  - Prashanthi, Kovur
AU  - Jovanović, Dragana J.
AU  - Thundat, Thomas
AU  - Dramićanin, Miroslav
PY  - 2019
UR  - http://link.springer.com/10.1007/s00339-019-2703-9
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8205
AB  - This report focuses on fabrication, characterization, and fundamental optical properties of Eu 3+ - and Sm 3+ -doped GdVO 4 luminescent thin films. Films were uniformly grown on three different substrates: single crystal sapphire (0001), thermally grown silicon oxide (Si/SiO 2 ~ 500 nm) on silicon and fused quartz using pulsed laser deposition technique. Thin films’ structure, morphology, and photoluminescent properties were investigated by X-ray diffraction, atomic force and scanning electron microscopy, diffuse reflectance and photoluminescence spectroscopy. Thin films’ structure characterized by X-ray diffraction showed that for all substrates highly crystalline, zircon-type pure phase films were formed. Films’ thickness and internal morphology were determined by cross-sectional scanning electron microscopy showing completely dense, pore-free film with an average thickness of ~ 390 nm. Atomic force microscopy revealed that the average crystallite size of both Eu 3+ - and Sm 3+ -doped GdVO 4 thin films deposited on fused quartz is higher as compared to the single crystal sapphire (0001) and thermally grown silicon oxide (Si/SiO 2 ~ 500 nm) and that the surface roughness increases with the increase in the grain size. Energy band gap values, estimated from diffuse reflectance spectra were 3.57 and 3.53 eV for Eu 3+ - and Sm 3+ -doped GdVO 4 thin films, respectively. Photoluminescent properties were investigated in detail in both steady state and lifetime domain. The emission spectra show clear orange–red emission in the Sm 3+ -doped GdVO 4 thin films and red emission in Eu 3+ -doped ones. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - Applied Physics A
T1  - Structure, morphology, and luminescent behavior of RE3+-doped GdVO4 thin films
VL  - 125
IS  - 6
SP  - 410
DO  - 10.1007/s00339-019-2703-9
ER  - 
@article{
author = "Antić, Željka and Prashanthi, Kovur and Jovanović, Dragana J. and Thundat, Thomas and Dramićanin, Miroslav",
year = "2019",
abstract = "This report focuses on fabrication, characterization, and fundamental optical properties of Eu 3+ - and Sm 3+ -doped GdVO 4 luminescent thin films. Films were uniformly grown on three different substrates: single crystal sapphire (0001), thermally grown silicon oxide (Si/SiO 2 ~ 500 nm) on silicon and fused quartz using pulsed laser deposition technique. Thin films’ structure, morphology, and photoluminescent properties were investigated by X-ray diffraction, atomic force and scanning electron microscopy, diffuse reflectance and photoluminescence spectroscopy. Thin films’ structure characterized by X-ray diffraction showed that for all substrates highly crystalline, zircon-type pure phase films were formed. Films’ thickness and internal morphology were determined by cross-sectional scanning electron microscopy showing completely dense, pore-free film with an average thickness of ~ 390 nm. Atomic force microscopy revealed that the average crystallite size of both Eu 3+ - and Sm 3+ -doped GdVO 4 thin films deposited on fused quartz is higher as compared to the single crystal sapphire (0001) and thermally grown silicon oxide (Si/SiO 2 ~ 500 nm) and that the surface roughness increases with the increase in the grain size. Energy band gap values, estimated from diffuse reflectance spectra were 3.57 and 3.53 eV for Eu 3+ - and Sm 3+ -doped GdVO 4 thin films, respectively. Photoluminescent properties were investigated in detail in both steady state and lifetime domain. The emission spectra show clear orange–red emission in the Sm 3+ -doped GdVO 4 thin films and red emission in Eu 3+ -doped ones. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "Applied Physics A",
title = "Structure, morphology, and luminescent behavior of RE3+-doped GdVO4 thin films",
volume = "125",
number = "6",
pages = "410",
doi = "10.1007/s00339-019-2703-9"
}
Antić, Ž., Prashanthi, K., Jovanović, D. J., Thundat, T.,& Dramićanin, M.. (2019). Structure, morphology, and luminescent behavior of RE3+-doped GdVO4 thin films. in Applied Physics A, 125(6), 410.
https://doi.org/10.1007/s00339-019-2703-9
Antić Ž, Prashanthi K, Jovanović DJ, Thundat T, Dramićanin M. Structure, morphology, and luminescent behavior of RE3+-doped GdVO4 thin films. in Applied Physics A. 2019;125(6):410.
doi:10.1007/s00339-019-2703-9 .
Antić, Željka, Prashanthi, Kovur, Jovanović, Dragana J., Thundat, Thomas, Dramićanin, Miroslav, "Structure, morphology, and luminescent behavior of RE3+-doped GdVO4 thin films" in Applied Physics A, 125, no. 6 (2019):410,
https://doi.org/10.1007/s00339-019-2703-9 . .
1
1

Synthesis and thermal properties of arylazo pyridone dyes

Porobić, Slavica; Krstić, Aleksandar D.; Jovanović, Dragana J.; Lađarević, Jelena M.; Katnić, Đurica B.; Mijin, Dušan Ž.; Marinović-Cincović, Milena

(2019)

TY  - JOUR
AU  - Porobić, Slavica
AU  - Krstić, Aleksandar D.
AU  - Jovanović, Dragana J.
AU  - Lađarević, Jelena M.
AU  - Katnić, Đurica B.
AU  - Mijin, Dušan Ž.
AU  - Marinović-Cincović, Milena
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0143720819310551
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8228
AB  - Thermal degradation properties of 5-(4-substitutedphenylazo)-3-amido-6-hydroxy-4-methyl-2-pyridones and 5-(4-substitutedphenylazo)-3-cyano-6-hydroxy-4-methyl-2-pyridones dyes, differing in electron withdrawing and electron donating substituents in para-position of diazo components were examined. The structure of the synthesized compounds has been confirmed by 1H NMR,13C NMR, FTIR, UV–Vis and XRD analysis techniques. The results obtained with thermogravimetric analysis (TGA) – derivative thermogravimetry (DTG) and differential thermal analysis (DTA) were combined with GC-mass spectral fragmentation to obtain thermal decomposition mechanism. Non-isothermal kinetics were monitored by application of TGA-DTG-DTA. For Kinetic behavior of the investigated dyes during their degradation in an inert atmosphere, Kissinger, Ozawa, Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) isoconversional (model-free) methods were applied. It was found that different thermal stabilities of investigated dyes are the consequence of their different chemical structures, including diverse substituents. © 2019
T2  - Dyes and Pigments
T1  - Synthesis and thermal properties of arylazo pyridone dyes
VL  - 170
SP  - 107602
DO  - 10.1016/j.dyepig.2019.107602
ER  - 
@article{
author = "Porobić, Slavica and Krstić, Aleksandar D. and Jovanović, Dragana J. and Lađarević, Jelena M. and Katnić, Đurica B. and Mijin, Dušan Ž. and Marinović-Cincović, Milena",
year = "2019",
abstract = "Thermal degradation properties of 5-(4-substitutedphenylazo)-3-amido-6-hydroxy-4-methyl-2-pyridones and 5-(4-substitutedphenylazo)-3-cyano-6-hydroxy-4-methyl-2-pyridones dyes, differing in electron withdrawing and electron donating substituents in para-position of diazo components were examined. The structure of the synthesized compounds has been confirmed by 1H NMR,13C NMR, FTIR, UV–Vis and XRD analysis techniques. The results obtained with thermogravimetric analysis (TGA) – derivative thermogravimetry (DTG) and differential thermal analysis (DTA) were combined with GC-mass spectral fragmentation to obtain thermal decomposition mechanism. Non-isothermal kinetics were monitored by application of TGA-DTG-DTA. For Kinetic behavior of the investigated dyes during their degradation in an inert atmosphere, Kissinger, Ozawa, Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) isoconversional (model-free) methods were applied. It was found that different thermal stabilities of investigated dyes are the consequence of their different chemical structures, including diverse substituents. © 2019",
journal = "Dyes and Pigments",
title = "Synthesis and thermal properties of arylazo pyridone dyes",
volume = "170",
pages = "107602",
doi = "10.1016/j.dyepig.2019.107602"
}
Porobić, S., Krstić, A. D., Jovanović, D. J., Lađarević, J. M., Katnić, Đ. B., Mijin, D. Ž.,& Marinović-Cincović, M.. (2019). Synthesis and thermal properties of arylazo pyridone dyes. in Dyes and Pigments, 170, 107602.
https://doi.org/10.1016/j.dyepig.2019.107602
Porobić S, Krstić AD, Jovanović DJ, Lađarević JM, Katnić ĐB, Mijin DŽ, Marinović-Cincović M. Synthesis and thermal properties of arylazo pyridone dyes. in Dyes and Pigments. 2019;170:107602.
doi:10.1016/j.dyepig.2019.107602 .
Porobić, Slavica, Krstić, Aleksandar D., Jovanović, Dragana J., Lađarević, Jelena M., Katnić, Đurica B., Mijin, Dušan Ž., Marinović-Cincović, Milena, "Synthesis and thermal properties of arylazo pyridone dyes" in Dyes and Pigments, 170 (2019):107602,
https://doi.org/10.1016/j.dyepig.2019.107602 . .
6
6
6

GdVO4:Er3+/Yb3+ nanocrystalline powder as fluorescence temperature sensor. Application to monitor the temperature of an electrical component

Paz-Buclatin, Franzette; Rivera-López, Fernando; González, Oswaldo; Martín, Inocencio R.; Martin, Leopoldo L.; Jovanović, Dragana J.

(2019)

TY  - JOUR
AU  - Paz-Buclatin, Franzette
AU  - Rivera-López, Fernando
AU  - González, Oswaldo
AU  - Martín, Inocencio R.
AU  - Martin, Leopoldo L.
AU  - Jovanović, Dragana J.
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8521
AB  - The temperature sensing properties of an Er3+/Yb3+ co-doped GdVO4 nanocrystalline powder were studied. The down-conversion emission spectrum of the sample was observed under excitation at 457 nm. Two methods were used to calibrate the temperature of the sample: one based on the Fluorescence Intensity Ratio (FIR) technique and the other using the fluorescence lifetime of the thermally-coupled energy levels of Er3+. The relative sensitivities for each method were calculated and it was found out that the FIR-based temperature sensor has higher sensitivity (1.17% K−1) than the lifetime-based sensor (0.24% K−1). Furthermore, a temperature uncertainty of 0.37 K was obtained for the FIR-based sensor. The GdVO4 nanoparticles were also used to study the change in temperature of an electrical component when it is operating and not. © 2019 Elsevier B.V.
T2  - Sensors and Actuators A: Physical
T1  - GdVO4:Er3+/Yb3+ nanocrystalline powder as fluorescence temperature sensor. Application to monitor the temperature of an electrical component
VL  - 299
SP  - 111628
DO  - 10.1016/j.sna.2019.111628
ER  - 
@article{
author = "Paz-Buclatin, Franzette and Rivera-López, Fernando and González, Oswaldo and Martín, Inocencio R. and Martin, Leopoldo L. and Jovanović, Dragana J.",
year = "2019",
abstract = "The temperature sensing properties of an Er3+/Yb3+ co-doped GdVO4 nanocrystalline powder were studied. The down-conversion emission spectrum of the sample was observed under excitation at 457 nm. Two methods were used to calibrate the temperature of the sample: one based on the Fluorescence Intensity Ratio (FIR) technique and the other using the fluorescence lifetime of the thermally-coupled energy levels of Er3+. The relative sensitivities for each method were calculated and it was found out that the FIR-based temperature sensor has higher sensitivity (1.17% K−1) than the lifetime-based sensor (0.24% K−1). Furthermore, a temperature uncertainty of 0.37 K was obtained for the FIR-based sensor. The GdVO4 nanoparticles were also used to study the change in temperature of an electrical component when it is operating and not. © 2019 Elsevier B.V.",
journal = "Sensors and Actuators A: Physical",
title = "GdVO4:Er3+/Yb3+ nanocrystalline powder as fluorescence temperature sensor. Application to monitor the temperature of an electrical component",
volume = "299",
pages = "111628",
doi = "10.1016/j.sna.2019.111628"
}
Paz-Buclatin, F., Rivera-López, F., González, O., Martín, I. R., Martin, L. L.,& Jovanović, D. J.. (2019). GdVO4:Er3+/Yb3+ nanocrystalline powder as fluorescence temperature sensor. Application to monitor the temperature of an electrical component. in Sensors and Actuators A: Physical, 299, 111628.
https://doi.org/10.1016/j.sna.2019.111628
Paz-Buclatin F, Rivera-López F, González O, Martín IR, Martin LL, Jovanović DJ. GdVO4:Er3+/Yb3+ nanocrystalline powder as fluorescence temperature sensor. Application to monitor the temperature of an electrical component. in Sensors and Actuators A: Physical. 2019;299:111628.
doi:10.1016/j.sna.2019.111628 .
Paz-Buclatin, Franzette, Rivera-López, Fernando, González, Oswaldo, Martín, Inocencio R., Martin, Leopoldo L., Jovanović, Dragana J., "GdVO4:Er3+/Yb3+ nanocrystalline powder as fluorescence temperature sensor. Application to monitor the temperature of an electrical component" in Sensors and Actuators A: Physical, 299 (2019):111628,
https://doi.org/10.1016/j.sna.2019.111628 . .
4
3
2

Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior

Vranješ, Mila; Kuljanin-Jakovljević, Jadranka Ž.; Milošević, Milica V.; Ćirić-Marjanović, Gordana N.; Stoiljković, Milovan; Konstantinović, Zorica; Pavlović, Vladimir B.; Milivojević, Dušan; Šaponjić, Zoran

(2019)

TY  - JOUR
AU  - Vranješ, Mila
AU  - Kuljanin-Jakovljević, Jadranka Ž.
AU  - Milošević, Milica V.
AU  - Ćirić-Marjanović, Gordana N.
AU  - Stoiljković, Milovan
AU  - Konstantinović, Zorica
AU  - Pavlović, Vladimir B.
AU  - Milivojević, Dušan
AU  - Šaponjić, Zoran
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S1293255818312226
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8358
AB  - Hydrothermal synthesis of Mn2+ doped titanate nanotubes (TNTs), which exhibited room temperature ferromagnetism (RTFM), is reported. Dispersions of 1 and 5 at.% Mn2+ doped anatase TiO2 nanocrystals were used as precursors. Size and shape of Mn2+ doped TNTs and precursor nanocrystals were studied by transmission electron microscopy (TEM). The relatively uniform size distribution of transverse dimension of nanotubes of about 10 nm was observed while their lengths varied up to few hundred nanometers. The X-Ray Diffraction (XRD) analysis and Raman spectroscopy of resultant powder confirmed the hydrogen dititanate (H2Ti2O5 x H2O) crystal phase of Mn2+ doped TNTs with the presence of small amount of sodium titanates. Electron paramagnetic resonance (EPR) experiments were performed to probe the local atomic and electronic structure of Mn in the nanotubes. Room temperature ferromagnetic ordering with saturation magnetic moment (Ms) in the range of 0.6–1.5 μB per Mn atom was observed. © 2019 Elsevier Masson SAS
T2  - Solid State Sciences
T1  - Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior
VL  - 94
SP  - 155
EP  - 161
DO  - 10.1016/j.solidstatesciences.2019.06.008
ER  - 
@article{
author = "Vranješ, Mila and Kuljanin-Jakovljević, Jadranka Ž. and Milošević, Milica V. and Ćirić-Marjanović, Gordana N. and Stoiljković, Milovan and Konstantinović, Zorica and Pavlović, Vladimir B. and Milivojević, Dušan and Šaponjić, Zoran",
year = "2019",
abstract = "Hydrothermal synthesis of Mn2+ doped titanate nanotubes (TNTs), which exhibited room temperature ferromagnetism (RTFM), is reported. Dispersions of 1 and 5 at.% Mn2+ doped anatase TiO2 nanocrystals were used as precursors. Size and shape of Mn2+ doped TNTs and precursor nanocrystals were studied by transmission electron microscopy (TEM). The relatively uniform size distribution of transverse dimension of nanotubes of about 10 nm was observed while their lengths varied up to few hundred nanometers. The X-Ray Diffraction (XRD) analysis and Raman spectroscopy of resultant powder confirmed the hydrogen dititanate (H2Ti2O5 x H2O) crystal phase of Mn2+ doped TNTs with the presence of small amount of sodium titanates. Electron paramagnetic resonance (EPR) experiments were performed to probe the local atomic and electronic structure of Mn in the nanotubes. Room temperature ferromagnetic ordering with saturation magnetic moment (Ms) in the range of 0.6–1.5 μB per Mn atom was observed. © 2019 Elsevier Masson SAS",
journal = "Solid State Sciences",
title = "Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior",
volume = "94",
pages = "155-161",
doi = "10.1016/j.solidstatesciences.2019.06.008"
}
Vranješ, M., Kuljanin-Jakovljević, J. Ž., Milošević, M. V., Ćirić-Marjanović, G. N., Stoiljković, M., Konstantinović, Z., Pavlović, V. B., Milivojević, D.,& Šaponjić, Z.. (2019). Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior. in Solid State Sciences, 94, 155-161.
https://doi.org/10.1016/j.solidstatesciences.2019.06.008
Vranješ M, Kuljanin-Jakovljević JŽ, Milošević MV, Ćirić-Marjanović GN, Stoiljković M, Konstantinović Z, Pavlović VB, Milivojević D, Šaponjić Z. Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior. in Solid State Sciences. 2019;94:155-161.
doi:10.1016/j.solidstatesciences.2019.06.008 .
Vranješ, Mila, Kuljanin-Jakovljević, Jadranka Ž., Milošević, Milica V., Ćirić-Marjanović, Gordana N., Stoiljković, Milovan, Konstantinović, Zorica, Pavlović, Vladimir B., Milivojević, Dušan, Šaponjić, Zoran, "Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior" in Solid State Sciences, 94 (2019):155-161,
https://doi.org/10.1016/j.solidstatesciences.2019.06.008 . .
6
5
6

Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles

Marković, Darka; Ašanin, Jelena; Nunney, Tim; Radovanović, Željko; Radoičić, Marija B.; Mitrić, Miodrag; Mišić, Dušan; Radetić, Maja M.

(2019)

TY  - JOUR
AU  - Marković, Darka
AU  - Ašanin, Jelena
AU  - Nunney, Tim
AU  - Radovanović, Željko
AU  - Radoičić, Marija B.
AU  - Mitrić, Miodrag
AU  - Mišić, Dušan
AU  - Radetić, Maja M.
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8669
AB  - This study discusses the possibility of fabrication of textile nanocomposites with antimicrobial activity against antibiotics-resistant bacterial strains and yeast. Modification of cotton fabric with oxalic acid solutions of different concentrations provided free carboxyl groups for binding of Cu2+ -ions from copper (II) sulfate solution which were further reduced with sodium borohydride in alkaline solution. An increase in the concentration of applied oxalic acid resulted in larger amounts of free carboxyl groups on the cotton fibers, Cu2+ -ions uptake and total amounts of Cu-based nanoparticles after reduction. XPS and XRD analyses suggested that nanoparticles mainly consisted of CuO with fractions of Cu2O. Fabricated textile nanocomposites ensured maximum reduction of Gram-negative E. coli ATCC 25922, E. coli NCTC 13846, E. coli ATCC BAA-2469, K. pneumoniae ATCC-BAA 2146 and P. aeruginosa ATCC 27853, Gram-positive bacteria S. aureus ATCC 25923 and S. aureus ATCC 43300 and yeast C. albicans ATCC 24433. Additionally, controlled release of Cu2+ -ions from fabrics into the physiological saline solution was obtained within 24 hours. © 2019, The Korean Fiber Society.
T2  - Fibers and Polymers
T1  - Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles
VL  - 20
IS  - 11
SP  - 2317
EP  - 2325
DO  - 10.1007/s12221-019-9131-5
ER  - 
@article{
author = "Marković, Darka and Ašanin, Jelena and Nunney, Tim and Radovanović, Željko and Radoičić, Marija B. and Mitrić, Miodrag and Mišić, Dušan and Radetić, Maja M.",
year = "2019",
abstract = "This study discusses the possibility of fabrication of textile nanocomposites with antimicrobial activity against antibiotics-resistant bacterial strains and yeast. Modification of cotton fabric with oxalic acid solutions of different concentrations provided free carboxyl groups for binding of Cu2+ -ions from copper (II) sulfate solution which were further reduced with sodium borohydride in alkaline solution. An increase in the concentration of applied oxalic acid resulted in larger amounts of free carboxyl groups on the cotton fibers, Cu2+ -ions uptake and total amounts of Cu-based nanoparticles after reduction. XPS and XRD analyses suggested that nanoparticles mainly consisted of CuO with fractions of Cu2O. Fabricated textile nanocomposites ensured maximum reduction of Gram-negative E. coli ATCC 25922, E. coli NCTC 13846, E. coli ATCC BAA-2469, K. pneumoniae ATCC-BAA 2146 and P. aeruginosa ATCC 27853, Gram-positive bacteria S. aureus ATCC 25923 and S. aureus ATCC 43300 and yeast C. albicans ATCC 24433. Additionally, controlled release of Cu2+ -ions from fabrics into the physiological saline solution was obtained within 24 hours. © 2019, The Korean Fiber Society.",
journal = "Fibers and Polymers",
title = "Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles",
volume = "20",
number = "11",
pages = "2317-2325",
doi = "10.1007/s12221-019-9131-5"
}
Marković, D., Ašanin, J., Nunney, T., Radovanović, Ž., Radoičić, M. B., Mitrić, M., Mišić, D.,& Radetić, M. M.. (2019). Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles. in Fibers and Polymers, 20(11), 2317-2325.
https://doi.org/10.1007/s12221-019-9131-5
Marković D, Ašanin J, Nunney T, Radovanović Ž, Radoičić MB, Mitrić M, Mišić D, Radetić MM. Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles. in Fibers and Polymers. 2019;20(11):2317-2325.
doi:10.1007/s12221-019-9131-5 .
Marković, Darka, Ašanin, Jelena, Nunney, Tim, Radovanović, Željko, Radoičić, Marija B., Mitrić, Miodrag, Mišić, Dušan, Radetić, Maja M., "Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles" in Fibers and Polymers, 20, no. 11 (2019):2317-2325,
https://doi.org/10.1007/s12221-019-9131-5 . .
5
4
3

Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics

Marković, Darka; Jokić, Bojan M.; Radovanović, Željko; Ašanin, Jelena; Radoičić, Marija B.; Mitrić, Miodrag; Mišić, Dušan; Radetić, Maja M.

(2019)

TY  - JOUR
AU  - Marković, Darka
AU  - Jokić, Bojan M.
AU  - Radovanović, Željko
AU  - Ašanin, Jelena
AU  - Radoičić, Marija B.
AU  - Mitrić, Miodrag
AU  - Mišić, Dušan
AU  - Radetić, Maja M.
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8517
AB  - The antioxidant properties of cool-climate Regent wines from Podkarpacie region, Poland were investigated. Total polyphenols, total flavonoids, total monomeric anthocyanins, trans-resveratrol concentration, radical scavenging ability using 1,1-diphenyl-2-picryl-hydrazyl (DPPH) and total antioxidant capacity with TEAC and FRAP methods were measured. The average contents of the compounds determined for Regent wines were comparable to the respective data available in literature found for warm-climate wines. Correspondence Analysis of the data revealed the relation of total polyphenols content and antioxidant capacity and radical scavenging ability of studied wines, and in lesser extent correlation with total flavonoids content. The total monomeric anthocyanins content and resveratrol concentration were poorly related to the total polyphenols content and antioxidant capacity.
T2  - Cellulose Chemistry and Technology
T1  - Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics
VL  - 53
IS  - 7-8
SP  - 805
EP  - 813
DO  - 10.35812/CelluloseChemTechnol.2019.53.79
ER  - 
@article{
author = "Marković, Darka and Jokić, Bojan M. and Radovanović, Željko and Ašanin, Jelena and Radoičić, Marija B. and Mitrić, Miodrag and Mišić, Dušan and Radetić, Maja M.",
year = "2019",
abstract = "The antioxidant properties of cool-climate Regent wines from Podkarpacie region, Poland were investigated. Total polyphenols, total flavonoids, total monomeric anthocyanins, trans-resveratrol concentration, radical scavenging ability using 1,1-diphenyl-2-picryl-hydrazyl (DPPH) and total antioxidant capacity with TEAC and FRAP methods were measured. The average contents of the compounds determined for Regent wines were comparable to the respective data available in literature found for warm-climate wines. Correspondence Analysis of the data revealed the relation of total polyphenols content and antioxidant capacity and radical scavenging ability of studied wines, and in lesser extent correlation with total flavonoids content. The total monomeric anthocyanins content and resveratrol concentration were poorly related to the total polyphenols content and antioxidant capacity.",
journal = "Cellulose Chemistry and Technology",
title = "Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics",
volume = "53",
number = "7-8",
pages = "805-813",
doi = "10.35812/CelluloseChemTechnol.2019.53.79"
}
Marković, D., Jokić, B. M., Radovanović, Ž., Ašanin, J., Radoičić, M. B., Mitrić, M., Mišić, D.,& Radetić, M. M.. (2019). Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics. in Cellulose Chemistry and Technology, 53(7-8), 805-813.
https://doi.org/10.35812/CelluloseChemTechnol.2019.53.79
Marković D, Jokić BM, Radovanović Ž, Ašanin J, Radoičić MB, Mitrić M, Mišić D, Radetić MM. Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics. in Cellulose Chemistry and Technology. 2019;53(7-8):805-813.
doi:10.35812/CelluloseChemTechnol.2019.53.79 .
Marković, Darka, Jokić, Bojan M., Radovanović, Željko, Ašanin, Jelena, Radoičić, Marija B., Mitrić, Miodrag, Mišić, Dušan, Radetić, Maja M., "Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics" in Cellulose Chemistry and Technology, 53, no. 7-8 (2019):805-813,
https://doi.org/10.35812/CelluloseChemTechnol.2019.53.79 . .

Gold nanorod-polyaniline composites: Synthesis and evaluation as anode electrocatalysts for direct borohydride fuel cells

Milikić, Jadranka; Stamenović, Una; Vodnik, Vesna; Ahrenkiel, Scott Phillip; Šljukić, Biljana

(2019)

TY  - JOUR
AU  - Milikić, Jadranka
AU  - Stamenović, Una
AU  - Vodnik, Vesna
AU  - Ahrenkiel, Scott Phillip
AU  - Šljukić, Biljana
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8609
AB  - Two gold nanorod-polyaniline (Au-PANI) composites with different contents of Au were prepared by two methods. An ex situ method, in the presence of preformed gold nanorods (AuNRs) and in situ one, when an AuNRs and PANI matrix is produced simultaneously, were used. Both methods were performed in immiscible water/toluene biphasic system as a simple interfacial polymerization process. Optical, structural and morphological characteristics of the formed nanocomposites were identified. It was found that AuNRs are embedded in the conducting emeraldine salt form of PANI. Nanocomposites containing 2.0 and 28.9 wt% of Au were subsequently systematically studied for borohydride oxidation reaction (BOR) for potential application in direct borohydride-peroxide fuel cell (DBPFC). Reaction parameters: number of electrons exchanged, order of reaction and activation energy, were evaluated. Both Au-PANI nanocomposites showed activity for BOR. A laboratory DBPFC was tested reaching specific peak power density of 184 Wg(-1) at 65 degrees C with Au-PANI 1 nanocomposite (containing only 2.0 wt% of Au) as anode.
T2  - Electrochimica Acta
T1  - Gold nanorod-polyaniline composites: Synthesis and evaluation as anode electrocatalysts for direct borohydride fuel cells
VL  - 328
SP  - 135115
DO  - 10.1016/j.electacta.2019.135115
ER  - 
@article{
author = "Milikić, Jadranka and Stamenović, Una and Vodnik, Vesna and Ahrenkiel, Scott Phillip and Šljukić, Biljana",
year = "2019",
abstract = "Two gold nanorod-polyaniline (Au-PANI) composites with different contents of Au were prepared by two methods. An ex situ method, in the presence of preformed gold nanorods (AuNRs) and in situ one, when an AuNRs and PANI matrix is produced simultaneously, were used. Both methods were performed in immiscible water/toluene biphasic system as a simple interfacial polymerization process. Optical, structural and morphological characteristics of the formed nanocomposites were identified. It was found that AuNRs are embedded in the conducting emeraldine salt form of PANI. Nanocomposites containing 2.0 and 28.9 wt% of Au were subsequently systematically studied for borohydride oxidation reaction (BOR) for potential application in direct borohydride-peroxide fuel cell (DBPFC). Reaction parameters: number of electrons exchanged, order of reaction and activation energy, were evaluated. Both Au-PANI nanocomposites showed activity for BOR. A laboratory DBPFC was tested reaching specific peak power density of 184 Wg(-1) at 65 degrees C with Au-PANI 1 nanocomposite (containing only 2.0 wt% of Au) as anode.",
journal = "Electrochimica Acta",
title = "Gold nanorod-polyaniline composites: Synthesis and evaluation as anode electrocatalysts for direct borohydride fuel cells",
volume = "328",
pages = "135115",
doi = "10.1016/j.electacta.2019.135115"
}
Milikić, J., Stamenović, U., Vodnik, V., Ahrenkiel, S. P.,& Šljukić, B.. (2019). Gold nanorod-polyaniline composites: Synthesis and evaluation as anode electrocatalysts for direct borohydride fuel cells. in Electrochimica Acta, 328, 135115.
https://doi.org/10.1016/j.electacta.2019.135115
Milikić J, Stamenović U, Vodnik V, Ahrenkiel SP, Šljukić B. Gold nanorod-polyaniline composites: Synthesis and evaluation as anode electrocatalysts for direct borohydride fuel cells. in Electrochimica Acta. 2019;328:135115.
doi:10.1016/j.electacta.2019.135115 .
Milikić, Jadranka, Stamenović, Una, Vodnik, Vesna, Ahrenkiel, Scott Phillip, Šljukić, Biljana, "Gold nanorod-polyaniline composites: Synthesis and evaluation as anode electrocatalysts for direct borohydride fuel cells" in Electrochimica Acta, 328 (2019):135115,
https://doi.org/10.1016/j.electacta.2019.135115 . .
11
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8

Developing an advanced electrocatalyst derived from triangular silver nanoplates@polyvinylpyrrolidone-polyaniline nanocomposites

Stamenović, Una; Vodnik, Vesna; Gavrilov, Nemanja M.; Pašti, Igor A.; Otončar, Mojca; Mitrić, Miodrag; Škapin, Srečo Davor

(2019)

TY  - JOUR
AU  - Stamenović, Una
AU  - Vodnik, Vesna
AU  - Gavrilov, Nemanja M.
AU  - Pašti, Igor A.
AU  - Otončar, Mojca
AU  - Mitrić, Miodrag
AU  - Škapin, Srečo Davor
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8512
AB  - There is a need for developing new and perspective materials for oxygen reduction reaction (ORR) as one of the most essential reactions in the life processes, energy storage, and conversion, in order to exchange the most often used materials based on platinum supported/unsupported substrates, especially carbon supports. Herein, we present low-cost alternative electrode materials consisting of two silver@polyvinylpyrrolidone-polyaniline (Ag@PVP-PANI) nanocomposites that showed great potential as Pt-free ORR electrocatalysts. Simple and effective polymerization processes of aniline in the methanol, using PVP as shape-mediated stabilizator and stimulator of its oxidation by silver ions, led to the formation of nanocomposites with truncated triangular silver nanoparticles dispersed throughout granular and wrinkle-like surfaces of PANI matrix. The behavior of PVP chains in acidic conditions showed great influence on nanocomposites’ conductivities, regardless of the high silver content. Electrocatalytic survey of nanocomposites examined in alkaline media toward ORR pointed out their appreciable activities with high ORR onset potentials. Moreover, for the nanocomposite with lower silver content (18.9 wt. %), the four-electron ORR pathway was evidenced. © 2019 Elsevier B.V.
T2  - Synthetic Metals
T1  - Developing an advanced electrocatalyst derived from triangular silver nanoplates@polyvinylpyrrolidone-polyaniline nanocomposites
VL  - 257
SP  - 116173
DO  - 10.1016/j.synthmet.2019.116173
ER  - 
@article{
author = "Stamenović, Una and Vodnik, Vesna and Gavrilov, Nemanja M. and Pašti, Igor A. and Otončar, Mojca and Mitrić, Miodrag and Škapin, Srečo Davor",
year = "2019",
abstract = "There is a need for developing new and perspective materials for oxygen reduction reaction (ORR) as one of the most essential reactions in the life processes, energy storage, and conversion, in order to exchange the most often used materials based on platinum supported/unsupported substrates, especially carbon supports. Herein, we present low-cost alternative electrode materials consisting of two silver@polyvinylpyrrolidone-polyaniline (Ag@PVP-PANI) nanocomposites that showed great potential as Pt-free ORR electrocatalysts. Simple and effective polymerization processes of aniline in the methanol, using PVP as shape-mediated stabilizator and stimulator of its oxidation by silver ions, led to the formation of nanocomposites with truncated triangular silver nanoparticles dispersed throughout granular and wrinkle-like surfaces of PANI matrix. The behavior of PVP chains in acidic conditions showed great influence on nanocomposites’ conductivities, regardless of the high silver content. Electrocatalytic survey of nanocomposites examined in alkaline media toward ORR pointed out their appreciable activities with high ORR onset potentials. Moreover, for the nanocomposite with lower silver content (18.9 wt. %), the four-electron ORR pathway was evidenced. © 2019 Elsevier B.V.",
journal = "Synthetic Metals",
title = "Developing an advanced electrocatalyst derived from triangular silver nanoplates@polyvinylpyrrolidone-polyaniline nanocomposites",
volume = "257",
pages = "116173",
doi = "10.1016/j.synthmet.2019.116173"
}
Stamenović, U., Vodnik, V., Gavrilov, N. M., Pašti, I. A., Otončar, M., Mitrić, M.,& Škapin, S. D.. (2019). Developing an advanced electrocatalyst derived from triangular silver nanoplates@polyvinylpyrrolidone-polyaniline nanocomposites. in Synthetic Metals, 257, 116173.
https://doi.org/10.1016/j.synthmet.2019.116173
Stamenović U, Vodnik V, Gavrilov NM, Pašti IA, Otončar M, Mitrić M, Škapin SD. Developing an advanced electrocatalyst derived from triangular silver nanoplates@polyvinylpyrrolidone-polyaniline nanocomposites. in Synthetic Metals. 2019;257:116173.
doi:10.1016/j.synthmet.2019.116173 .
Stamenović, Una, Vodnik, Vesna, Gavrilov, Nemanja M., Pašti, Igor A., Otončar, Mojca, Mitrić, Miodrag, Škapin, Srečo Davor, "Developing an advanced electrocatalyst derived from triangular silver nanoplates@polyvinylpyrrolidone-polyaniline nanocomposites" in Synthetic Metals, 257 (2019):116173,
https://doi.org/10.1016/j.synthmet.2019.116173 . .
3
3
1

Radiation stability and thermal behaviour of modified UF resin using biorenewable raw material-furfuryl alcohol

Samaržija-Jovanović, Suzana; Jovanović, Vojislav; Petković, Branka B.; Jovanović, Slaviša; Marković, Gordana; Porobić, Slavica; Marinović-Cincović, Milena

(2019)

TY  - JOUR
AU  - Samaržija-Jovanović, Suzana
AU  - Jovanović, Vojislav
AU  - Petković, Branka B.
AU  - Jovanović, Slaviša
AU  - Marković, Gordana
AU  - Porobić, Slavica
AU  - Marinović-Cincović, Milena
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S1359836818325174
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7997
AB  - The thermal stability of organic-inorganic nano-composites prepared by a two-stage polymerization of urea-formaldehyde resin (UF) with furfuryl alcohol (FA) and TiO2 before and after irradiation has been researched. The two resins of urea-formaldehyde–TiO2 composites, named: UF/TiO2 and UF/TiO2/FA, were synthesized. The thermal stability of obtained materials was studied by non-isothermal thermo-gravimetric analysis (TG), differential thermal gravimetry (DTG) and differential thermal analysis (DTA). UF hybrid composites have been irradiated (50 kGy) and after that their radiation stability was evaluated on the basis of thermal behavior. The free formaldehyde (HCOH) percentage in all prepared samples was determined. The minimum percentage values of free formaldehyde (0.04% and 0.03%) for UF/TiO2 and UF/TiO2/FA, respectively, after irradiation dose of 50 kGy are detected. The shift of temperature values for selected mass losses (T10%) to a high temperature indicates the increase in thermal stability of samples based on UF resin modified with FA.
T2  - Composites Part B: Engineering
T1  - Radiation stability and thermal behaviour of modified UF resin using biorenewable raw material-furfuryl alcohol
VL  - 167
SP  - 161
EP  - 166
DO  - 10.1016/j.compositesb.2018.12.024
ER  - 
@article{
author = "Samaržija-Jovanović, Suzana and Jovanović, Vojislav and Petković, Branka B. and Jovanović, Slaviša and Marković, Gordana and Porobić, Slavica and Marinović-Cincović, Milena",
year = "2019",
abstract = "The thermal stability of organic-inorganic nano-composites prepared by a two-stage polymerization of urea-formaldehyde resin (UF) with furfuryl alcohol (FA) and TiO2 before and after irradiation has been researched. The two resins of urea-formaldehyde–TiO2 composites, named: UF/TiO2 and UF/TiO2/FA, were synthesized. The thermal stability of obtained materials was studied by non-isothermal thermo-gravimetric analysis (TG), differential thermal gravimetry (DTG) and differential thermal analysis (DTA). UF hybrid composites have been irradiated (50 kGy) and after that their radiation stability was evaluated on the basis of thermal behavior. The free formaldehyde (HCOH) percentage in all prepared samples was determined. The minimum percentage values of free formaldehyde (0.04% and 0.03%) for UF/TiO2 and UF/TiO2/FA, respectively, after irradiation dose of 50 kGy are detected. The shift of temperature values for selected mass losses (T10%) to a high temperature indicates the increase in thermal stability of samples based on UF resin modified with FA.",
journal = "Composites Part B: Engineering",
title = "Radiation stability and thermal behaviour of modified UF resin using biorenewable raw material-furfuryl alcohol",
volume = "167",
pages = "161-166",
doi = "10.1016/j.compositesb.2018.12.024"
}
Samaržija-Jovanović, S., Jovanović, V., Petković, B. B., Jovanović, S., Marković, G., Porobić, S.,& Marinović-Cincović, M.. (2019). Radiation stability and thermal behaviour of modified UF resin using biorenewable raw material-furfuryl alcohol. in Composites Part B: Engineering, 167, 161-166.
https://doi.org/10.1016/j.compositesb.2018.12.024
Samaržija-Jovanović S, Jovanović V, Petković BB, Jovanović S, Marković G, Porobić S, Marinović-Cincović M. Radiation stability and thermal behaviour of modified UF resin using biorenewable raw material-furfuryl alcohol. in Composites Part B: Engineering. 2019;167:161-166.
doi:10.1016/j.compositesb.2018.12.024 .
Samaržija-Jovanović, Suzana, Jovanović, Vojislav, Petković, Branka B., Jovanović, Slaviša, Marković, Gordana, Porobić, Slavica, Marinović-Cincović, Milena, "Radiation stability and thermal behaviour of modified UF resin using biorenewable raw material-furfuryl alcohol" in Composites Part B: Engineering, 167 (2019):161-166,
https://doi.org/10.1016/j.compositesb.2018.12.024 . .
3
2
3

Hybrid materials based on rubber blend nanocomposites

Porobić, Slavica; Marković, Gordana; Ristić, Ivan; Samaržija‐Jovanović, Suzana; Jovanović, Vojislav; Budinski‐Simendić, Jaroslava; Marinović‐Cincović, Milena

(2019)

TY  - JOUR
AU  - Porobić, Slavica
AU  - Marković, Gordana
AU  - Ristić, Ivan
AU  - Samaržija‐Jovanović, Suzana
AU  - Jovanović, Vojislav
AU  - Budinski‐Simendić, Jaroslava
AU  - Marinović‐Cincović, Milena
PY  - 2019
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/8466
AB  - In this applicative work, two types of silica filler were used to increase the adhesion strength between steel and elastomeric hybrid materials based on chlorosulfonated polyethylene rubber (CSM) and polychloroprene rubber (CR) as network precursors. Precipitated silica (PS) with the average size of primary particles 15 nm and diatomaceous earth (DE) with the average size of primary particles 28 μm were used to ascertain differences in metal-elastomer compounds adhesion strength caused by different particle size. The ratio of network precursors in CSM/CR rubber blends was 50:50 (w/w). The filler loading was in the range of 0–35 phr. Characteristics of the obtained composites were examined by combining the cure kinetics, adhesion strength and the dynamic mechanical properties. The viscoelasticity of obtained hybrid materials was assessed by the mechanical spectrometer (in a single cantilever bending mode) in the temperature range from −50 °C to 150 °C using multifrequency mode. POLYM. COMPOS., 2018. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers
T2  - Polymer Composites
T1  - Hybrid materials based on rubber blend nanocomposites
VL  - 40
IS  - 8
SP  - 3056
EP  - 3064
DO  - 10.1002/pc.25150
ER  - 
@article{
author = "Porobić, Slavica and Marković, Gordana and Ristić, Ivan and Samaržija‐Jovanović, Suzana and Jovanović, Vojislav and Budinski‐Simendić, Jaroslava and Marinović‐Cincović, Milena",
year = "2019",
abstract = "In this applicative work, two types of silica filler were used to increase the adhesion strength between steel and elastomeric hybrid materials based on chlorosulfonated polyethylene rubber (CSM) and polychloroprene rubber (CR) as network precursors. Precipitated silica (PS) with the average size of primary particles 15 nm and diatomaceous earth (DE) with the average size of primary particles 28 μm were used to ascertain differences in metal-elastomer compounds adhesion strength caused by different particle size. The ratio of network precursors in CSM/CR rubber blends was 50:50 (w/w). The filler loading was in the range of 0–35 phr. Characteristics of the obtained composites were examined by combining the cure kinetics, adhesion strength and the dynamic mechanical properties. The viscoelasticity of obtained hybrid materials was assessed by the mechanical spectrometer (in a single cantilever bending mode) in the temperature range from −50 °C to 150 °C using multifrequency mode. POLYM. COMPOS., 2018. © 2018 Society of Plastics Engineers. © 2018 Society of Plastics Engineers",
journal = "Polymer Composites",
title = "Hybrid materials based on rubber blend nanocomposites",
volume = "40",
number = "8",
pages = "3056-3064",
doi = "10.1002/pc.25150"
}
Porobić, S., Marković, G., Ristić, I., Samaržija‐Jovanović, S., Jovanović, V., Budinski‐Simendić, J.,& Marinović‐Cincović, M.. (2019). Hybrid materials based on rubber blend nanocomposites. in Polymer Composites, 40(8), 3056-3064.
https://doi.org/10.1002/pc.25150
Porobić S, Marković G, Ristić I, Samaržija‐Jovanović S, Jovanović V, Budinski‐Simendić J, Marinović‐Cincović M. Hybrid materials based on rubber blend nanocomposites. in Polymer Composites. 2019;40(8):3056-3064.
doi:10.1002/pc.25150 .
Porobić, Slavica, Marković, Gordana, Ristić, Ivan, Samaržija‐Jovanović, Suzana, Jovanović, Vojislav, Budinski‐Simendić, Jaroslava, Marinović‐Cincović, Milena, "Hybrid materials based on rubber blend nanocomposites" in Polymer Composites, 40, no. 8 (2019):3056-3064,
https://doi.org/10.1002/pc.25150 . .
2
2
2

Synthesis, structure and spectroscopic properties of luminescent GdVO4:Dy3+ and DyVO4 particles

(2018)

TY  - JOUR
PY  - 2018
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7585
AB  - In this work, we focused on the syntheses, structure and spectroscopic properties of GdVO4:Dy3+ and DyVO4 (nano)particles of different sizes and shapes (spherical nanoparticles of 2 nm, 4 nm, and 20 nm in size, nanorods with a few nanometers in diameter and up to 10-20 nm in length and microparticles of 1 -8 mu m) obtained by four synthetic methods. The size effect on the structure, Raman active modes, and photoluminescence emission intensities was analyzed by X-ray diffraction, Raman and photo-luminescence spectroscopy, scanning and transmission electron microscopy, and diffuse reflection spectroscopy. All X-ray diffraction patterns clearly indicated presence of a single tetragonal zircon-type phase; absence of impurity phases indicate that the dopant Dy3+ ions were successfully and uniformly incorporated into the GdVO4 host lattice due to the equal valence and similar ionic radii. Micro-Raman measurements support the XRD measurements and showed Raman-active modes of the REVO4 systems (RE = Gd, Dy). The difference between the two hosts in the diffuse reflectance spectra was observed and it could be attributed to more effective Gd3+ ions on the charge transfer bands and different polarization (compared to bulk material) in smaller nanoparticles. Photoluminescence spectroscopy showed several bands in the visible and near-infrared regions which can be exclusively attributed to the f-f transitions of Dy3+ ions. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Synthesis, structure and spectroscopic properties of luminescent GdVO4:Dy3+ and DyVO4 particles
VL  - 76
SP  - 308
EP  - 316
DO  - 10.1016/j.optmat.2017.12.046
ER  - 
@article{
year = "2018",
abstract = "In this work, we focused on the syntheses, structure and spectroscopic properties of GdVO4:Dy3+ and DyVO4 (nano)particles of different sizes and shapes (spherical nanoparticles of 2 nm, 4 nm, and 20 nm in size, nanorods with a few nanometers in diameter and up to 10-20 nm in length and microparticles of 1 -8 mu m) obtained by four synthetic methods. The size effect on the structure, Raman active modes, and photoluminescence emission intensities was analyzed by X-ray diffraction, Raman and photo-luminescence spectroscopy, scanning and transmission electron microscopy, and diffuse reflection spectroscopy. All X-ray diffraction patterns clearly indicated presence of a single tetragonal zircon-type phase; absence of impurity phases indicate that the dopant Dy3+ ions were successfully and uniformly incorporated into the GdVO4 host lattice due to the equal valence and similar ionic radii. Micro-Raman measurements support the XRD measurements and showed Raman-active modes of the REVO4 systems (RE = Gd, Dy). The difference between the two hosts in the diffuse reflectance spectra was observed and it could be attributed to more effective Gd3+ ions on the charge transfer bands and different polarization (compared to bulk material) in smaller nanoparticles. Photoluminescence spectroscopy showed several bands in the visible and near-infrared regions which can be exclusively attributed to the f-f transitions of Dy3+ ions. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Synthesis, structure and spectroscopic properties of luminescent GdVO4:Dy3+ and DyVO4 particles",
volume = "76",
pages = "308-316",
doi = "10.1016/j.optmat.2017.12.046"
}
(2018). Synthesis, structure and spectroscopic properties of luminescent GdVO4:Dy3+ and DyVO4 particles. in Optical Materials, 76, 308-316.
https://doi.org/10.1016/j.optmat.2017.12.046
Synthesis, structure and spectroscopic properties of luminescent GdVO4:Dy3+ and DyVO4 particles. in Optical Materials. 2018;76:308-316.
doi:10.1016/j.optmat.2017.12.046 .
"Synthesis, structure and spectroscopic properties of luminescent GdVO4:Dy3+ and DyVO4 particles" in Optical Materials, 76 (2018):308-316,
https://doi.org/10.1016/j.optmat.2017.12.046 . .
13
13
14

High resolution luminescence spectroscopy and thermoluminescence of different size LaPO4:Eu3+ nanoparticles

Gavrilović, Tamara V.; Laganovska, Katrina; Zolotarjovs, Aleksejs; Smits, Krisjanis; Jovanović, Dragana J.; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Gavrilović, Tamara V.
AU  - Laganovska, Katrina
AU  - Zolotarjovs, Aleksejs
AU  - Smits, Krisjanis
AU  - Jovanović, Dragana J.
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S0925346718303136
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7690
AB  - Nanoparticles (5 nm) and nanorods (2 nm × 15 nm and 4 nm × 20 nm) of monoclinic monazite LaPO4:Eu3+were prepared by reverse micelle and co-precipitation techniques. Effects of the particle size and surface defects on the intensity of luminescence and the emission spectrum shapes were analyzed by high resolution spectroscopy under laser (266 nm) and X-rays excitation. All synthesized LaPO4:Eu3+samples showed similar spectral features with characteristic Eu3+ions emission bands:5D0→7F0centered at 578.4 nm, magnetic-dipole transition5D0→7F1at 588–595 nm, electric-dipole transition5D0→7F2at 611.5–620.5 nm,5D0→7F3at (648–652 nm) and5D0→7F4at (684–702.5 nm), with the most dominant electric-dipole5D0→7F2transition. Additionally, the thermally stimulated luminescence was studied for the most dominant peak at 611.5 nm. It was shown that the Eu3+doping creates traps in all samples. Two prominent and well resolved glow peaks at 58.7 K and 172.3 K were detected for 5 nm nanoparticles, while low-intensity glow-peaks at 212.1 K and 212.2 K were observed in the X-rays irradiated nanorods. Displayed glows could be attributed to free and bound electrons and holes or to the recombination of electrons of ionized oxygen vacancies with photogenerated holes. To obtain information about the processes and specific defect type it is necessary to carry out additional analysis for all synthesized samples. The glow curves were analyzed and trap parameters were estimated and discussed throughout the paper.
T2  - Optical Materials
T1  - High resolution luminescence spectroscopy and thermoluminescence of different size LaPO4:Eu3+ nanoparticles
VL  - 82
SP  - 39
EP  - 46
DO  - 10.1016/j.optmat.2018.05.042
ER  - 
@article{
author = "Gavrilović, Tamara V. and Laganovska, Katrina and Zolotarjovs, Aleksejs and Smits, Krisjanis and Jovanović, Dragana J. and Dramićanin, Miroslav",
year = "2018",
abstract = "Nanoparticles (5 nm) and nanorods (2 nm × 15 nm and 4 nm × 20 nm) of monoclinic monazite LaPO4:Eu3+were prepared by reverse micelle and co-precipitation techniques. Effects of the particle size and surface defects on the intensity of luminescence and the emission spectrum shapes were analyzed by high resolution spectroscopy under laser (266 nm) and X-rays excitation. All synthesized LaPO4:Eu3+samples showed similar spectral features with characteristic Eu3+ions emission bands:5D0→7F0centered at 578.4 nm, magnetic-dipole transition5D0→7F1at 588–595 nm, electric-dipole transition5D0→7F2at 611.5–620.5 nm,5D0→7F3at (648–652 nm) and5D0→7F4at (684–702.5 nm), with the most dominant electric-dipole5D0→7F2transition. Additionally, the thermally stimulated luminescence was studied for the most dominant peak at 611.5 nm. It was shown that the Eu3+doping creates traps in all samples. Two prominent and well resolved glow peaks at 58.7 K and 172.3 K were detected for 5 nm nanoparticles, while low-intensity glow-peaks at 212.1 K and 212.2 K were observed in the X-rays irradiated nanorods. Displayed glows could be attributed to free and bound electrons and holes or to the recombination of electrons of ionized oxygen vacancies with photogenerated holes. To obtain information about the processes and specific defect type it is necessary to carry out additional analysis for all synthesized samples. The glow curves were analyzed and trap parameters were estimated and discussed throughout the paper.",
journal = "Optical Materials",
title = "High resolution luminescence spectroscopy and thermoluminescence of different size LaPO4:Eu3+ nanoparticles",
volume = "82",
pages = "39-46",
doi = "10.1016/j.optmat.2018.05.042"
}
Gavrilović, T. V., Laganovska, K., Zolotarjovs, A., Smits, K., Jovanović, D. J.,& Dramićanin, M.. (2018). High resolution luminescence spectroscopy and thermoluminescence of different size LaPO4:Eu3+ nanoparticles. in Optical Materials, 82, 39-46.
https://doi.org/10.1016/j.optmat.2018.05.042
Gavrilović TV, Laganovska K, Zolotarjovs A, Smits K, Jovanović DJ, Dramićanin M. High resolution luminescence spectroscopy and thermoluminescence of different size LaPO4:Eu3+ nanoparticles. in Optical Materials. 2018;82:39-46.
doi:10.1016/j.optmat.2018.05.042 .
Gavrilović, Tamara V., Laganovska, Katrina, Zolotarjovs, Aleksejs, Smits, Krisjanis, Jovanović, Dragana J., Dramićanin, Miroslav, "High resolution luminescence spectroscopy and thermoluminescence of different size LaPO4:Eu3+ nanoparticles" in Optical Materials, 82 (2018):39-46,
https://doi.org/10.1016/j.optmat.2018.05.042 . .
2
2
2

Up-conversion luminescence of GdVO4:Nd3+/Er3+ and GdVO4:Nd3+/Ho3+ phosphors under 808 nm excitation

Jovanović, Dragana J.; Gavrilović, Tamara V.; Dolić, Slobodan D.; Marinović-Cincović, Milena; Smits, Krisjanis; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Jovanović, Dragana J.
AU  - Gavrilović, Tamara V.
AU  - Dolić, Slobodan D.
AU  - Marinović-Cincović, Milena
AU  - Smits, Krisjanis
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S0925346718303045
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7691
AB  - © 2018 Elsevier B.V. In recent years, there exists a tendency in research of up-conversion materials to shift excitation from 980 nm to shorter wavelengths. Here, in order to produce up-conversion luminescence emission of GdVO4-based materials under 808 nm excitation, polycrystalline powders of GdVO4:Er3+/Nd3+and GdVO4:Ho3+/Nd3+were successfully prepared by a high-temperature solid-state reaction technique. The prepared powders were highly crystalline with a single-phase zircon-type GdVO4structure and consisted of micrometer-sized irregular spherical particles (2–6 μm in diameter). In all studied samples, visible up-conversion luminescence was successfully achieved under 808 nm illumination. Near-infrared pumping produced emission bands in the green, yellow-orange and green regions of the visible spectrum. The bands in the green and red regions of GdVO4: Er3+/Nd3+as well as GdVO4:Ho3+/Nd3+were, respectively, characteristic of Er3+and Ho3+ions. The dominant band originating from the4G7/2→4I11/2transition in Nd3+ions was observed around 597 nm in all samples.
T2  - Optical Materials
T1  - Up-conversion luminescence of GdVO4:Nd3+/Er3+ and GdVO4:Nd3+/Ho3+ phosphors under 808 nm excitation
VL  - 82
SP  - 1
EP  - 6
DO  - 10.1016/j.optmat.2018.05.033
ER  - 
@article{
author = "Jovanović, Dragana J. and Gavrilović, Tamara V. and Dolić, Slobodan D. and Marinović-Cincović, Milena and Smits, Krisjanis and Dramićanin, Miroslav",
year = "2018",
abstract = "© 2018 Elsevier B.V. In recent years, there exists a tendency in research of up-conversion materials to shift excitation from 980 nm to shorter wavelengths. Here, in order to produce up-conversion luminescence emission of GdVO4-based materials under 808 nm excitation, polycrystalline powders of GdVO4:Er3+/Nd3+and GdVO4:Ho3+/Nd3+were successfully prepared by a high-temperature solid-state reaction technique. The prepared powders were highly crystalline with a single-phase zircon-type GdVO4structure and consisted of micrometer-sized irregular spherical particles (2–6 μm in diameter). In all studied samples, visible up-conversion luminescence was successfully achieved under 808 nm illumination. Near-infrared pumping produced emission bands in the green, yellow-orange and green regions of the visible spectrum. The bands in the green and red regions of GdVO4: Er3+/Nd3+as well as GdVO4:Ho3+/Nd3+were, respectively, characteristic of Er3+and Ho3+ions. The dominant band originating from the4G7/2→4I11/2transition in Nd3+ions was observed around 597 nm in all samples.",
journal = "Optical Materials",
title = "Up-conversion luminescence of GdVO4:Nd3+/Er3+ and GdVO4:Nd3+/Ho3+ phosphors under 808 nm excitation",
volume = "82",
pages = "1-6",
doi = "10.1016/j.optmat.2018.05.033"
}
Jovanović, D. J., Gavrilović, T. V., Dolić, S. D., Marinović-Cincović, M., Smits, K.,& Dramićanin, M.. (2018). Up-conversion luminescence of GdVO4:Nd3+/Er3+ and GdVO4:Nd3+/Ho3+ phosphors under 808 nm excitation. in Optical Materials, 82, 1-6.
https://doi.org/10.1016/j.optmat.2018.05.033
Jovanović DJ, Gavrilović TV, Dolić SD, Marinović-Cincović M, Smits K, Dramićanin M. Up-conversion luminescence of GdVO4:Nd3+/Er3+ and GdVO4:Nd3+/Ho3+ phosphors under 808 nm excitation. in Optical Materials. 2018;82:1-6.
doi:10.1016/j.optmat.2018.05.033 .
Jovanović, Dragana J., Gavrilović, Tamara V., Dolić, Slobodan D., Marinović-Cincović, Milena, Smits, Krisjanis, Dramićanin, Miroslav, "Up-conversion luminescence of GdVO4:Nd3+/Er3+ and GdVO4:Nd3+/Ho3+ phosphors under 808 nm excitation" in Optical Materials, 82 (2018):1-6,
https://doi.org/10.1016/j.optmat.2018.05.033 . .
7
7
7

Multicolor-tunable emissions of YOF: Ln 3+ /Yb 3+ (Ln 3+ = Ho 3+ , Er 3+ , Tm 3+ ) nanophosphors

Periša, Jovana; Papan, Jelena; Dolić, Slobodan D.; Jovanović, Dragana J.; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Periša, Jovana
AU  - Papan, Jelena
AU  - Dolić, Slobodan D.
AU  - Jovanović, Dragana J.
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S0143720818303577
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7754
AB  - Color tuning of down-shifting and up-conversion emissions of YOF:Ln(3+)/Yb3+ (Ln(3+) = Er3+, Tm3+) nanophosphors is demonstrated. Nanophosphors were prepared by the modified sol-gel Pechini method and characterized by the X-ray diffraction, transmission electron microscopy, and photoluminescence spectroscopy. Samples consist of 20 nm particles crystallized in the rhombohedral crystal structure. Depending on the Ln(3+) / Yb3+ concentration ratio and the type of excitation (UV/VIS or NIR) color of the particles emission varied from the blue to red. Commission Internationale de L'Eclairage chromaticity coordinates of emission colors are given for the range of Ln(3+)/Yb3+ concentration ratios for both down-shifting and up-conversion luminescence. We showed that the emission color of these nanophosphors may be additional tuned by simultaneous excitation with UV-VIS and NIR radiation (in different proportion) which yields unique color labels for the anti-counterfeit and security applications.
T2  - Dyes and Pigments
T1  - Multicolor-tunable emissions of YOF: Ln 3+ /Yb 3+ (Ln 3+ = Ho 3+ , Er 3+ , Tm 3+ ) nanophosphors
VL  - 155
SP  - 233
EP  - 240
DO  - 10.1016/j.dyepig.2018.03.047
ER  - 
@article{
author = "Periša, Jovana and Papan, Jelena and Dolić, Slobodan D. and Jovanović, Dragana J. and Dramićanin, Miroslav",
year = "2018",
abstract = "Color tuning of down-shifting and up-conversion emissions of YOF:Ln(3+)/Yb3+ (Ln(3+) = Er3+, Tm3+) nanophosphors is demonstrated. Nanophosphors were prepared by the modified sol-gel Pechini method and characterized by the X-ray diffraction, transmission electron microscopy, and photoluminescence spectroscopy. Samples consist of 20 nm particles crystallized in the rhombohedral crystal structure. Depending on the Ln(3+) / Yb3+ concentration ratio and the type of excitation (UV/VIS or NIR) color of the particles emission varied from the blue to red. Commission Internationale de L'Eclairage chromaticity coordinates of emission colors are given for the range of Ln(3+)/Yb3+ concentration ratios for both down-shifting and up-conversion luminescence. We showed that the emission color of these nanophosphors may be additional tuned by simultaneous excitation with UV-VIS and NIR radiation (in different proportion) which yields unique color labels for the anti-counterfeit and security applications.",
journal = "Dyes and Pigments",
title = "Multicolor-tunable emissions of YOF: Ln 3+ /Yb 3+ (Ln 3+ = Ho 3+ , Er 3+ , Tm 3+ ) nanophosphors",
volume = "155",
pages = "233-240",
doi = "10.1016/j.dyepig.2018.03.047"
}
Periša, J., Papan, J., Dolić, S. D., Jovanović, D. J.,& Dramićanin, M.. (2018). Multicolor-tunable emissions of YOF: Ln 3+ /Yb 3+ (Ln 3+ = Ho 3+ , Er 3+ , Tm 3+ ) nanophosphors. in Dyes and Pigments, 155, 233-240.
https://doi.org/10.1016/j.dyepig.2018.03.047
Periša J, Papan J, Dolić SD, Jovanović DJ, Dramićanin M. Multicolor-tunable emissions of YOF: Ln 3+ /Yb 3+ (Ln 3+ = Ho 3+ , Er 3+ , Tm 3+ ) nanophosphors. in Dyes and Pigments. 2018;155:233-240.
doi:10.1016/j.dyepig.2018.03.047 .
Periša, Jovana, Papan, Jelena, Dolić, Slobodan D., Jovanović, Dragana J., Dramićanin, Miroslav, "Multicolor-tunable emissions of YOF: Ln 3+ /Yb 3+ (Ln 3+ = Ho 3+ , Er 3+ , Tm 3+ ) nanophosphors" in Dyes and Pigments, 155 (2018):233-240,
https://doi.org/10.1016/j.dyepig.2018.03.047 . .
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A comparative study of photocatalytically active nanocrystalline tetragonal zyrcon-type and monoclinic scheelite-type bismuth vanadate

Dolić, Slobodan D.; Jovanović, Dragana J.; Smits, Krisjanis; Babić, Biljana M.; Marinović-Cincović, Milena; Porobić, Slavica; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Dolić, Slobodan D.
AU  - Jovanović, Dragana J.
AU  - Smits, Krisjanis
AU  - Babić, Biljana M.
AU  - Marinović-Cincović, Milena
AU  - Porobić, Slavica
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0272884218317176
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7816
AB  - Monoclinic scheelite-type BiVO4 is currently considered as one of the most promising non-titania photocatalysts, wheras tetragonal zircon-type BiVO4 is still poorly understood. Herein, a new and simple synthetic approach was applied and nanostructured single-phase zircon-type BiVO4 was successfully prepared by a controllable ethylene-glycol colloidal route. In addition, nanostructured monoclinic scheelite-type BiVO4 powders were also fabricated through annealing of the as-prepared samples. A comparative study of the two BiVO4 polymorphs was conducted and it turned out that the novel synthetic approach had a significant impact on porosity and photocatalytic performance of zircon-structured BiVO4. All the prepared materials, as-prepared and annealed, were mesoporous, while measured values of specific surface area of some zircon-structured samples (∼34 m2/g) were ∼7 times higher than those reported thus far for this phase. Interestingly, for the first time, zircon-type BiVO4, previously considered to be a poor photocatalyst, exhibited a better overall performance in degradation of methyl orange compared to monoclinic scheelite-type BiVO4. Hence, it could be expected that the here-presented synthesis and observations will both arouse interest in scarcely studied tetragonal zircon-type BiVO4 and facilitate as well as speed up further research of its properties. © 2018 Elsevier Ltd and Techna Group S.r.l.
T2  - Ceramics International
T1  - A comparative study of photocatalytically active nanocrystalline tetragonal zyrcon-type and monoclinic scheelite-type bismuth vanadate
VL  - 44
IS  - 15
SP  - 17953
EP  - 17961
DO  - 10.1016/j.ceramint.2018.06.272
ER  - 
@article{
author = "Dolić, Slobodan D. and Jovanović, Dragana J. and Smits, Krisjanis and Babić, Biljana M. and Marinović-Cincović, Milena and Porobić, Slavica and Dramićanin, Miroslav",
year = "2018",
abstract = "Monoclinic scheelite-type BiVO4 is currently considered as one of the most promising non-titania photocatalysts, wheras tetragonal zircon-type BiVO4 is still poorly understood. Herein, a new and simple synthetic approach was applied and nanostructured single-phase zircon-type BiVO4 was successfully prepared by a controllable ethylene-glycol colloidal route. In addition, nanostructured monoclinic scheelite-type BiVO4 powders were also fabricated through annealing of the as-prepared samples. A comparative study of the two BiVO4 polymorphs was conducted and it turned out that the novel synthetic approach had a significant impact on porosity and photocatalytic performance of zircon-structured BiVO4. All the prepared materials, as-prepared and annealed, were mesoporous, while measured values of specific surface area of some zircon-structured samples (∼34 m2/g) were ∼7 times higher than those reported thus far for this phase. Interestingly, for the first time, zircon-type BiVO4, previously considered to be a poor photocatalyst, exhibited a better overall performance in degradation of methyl orange compared to monoclinic scheelite-type BiVO4. Hence, it could be expected that the here-presented synthesis and observations will both arouse interest in scarcely studied tetragonal zircon-type BiVO4 and facilitate as well as speed up further research of its properties. © 2018 Elsevier Ltd and Techna Group S.r.l.",
journal = "Ceramics International",
title = "A comparative study of photocatalytically active nanocrystalline tetragonal zyrcon-type and monoclinic scheelite-type bismuth vanadate",
volume = "44",
number = "15",
pages = "17953-17961",
doi = "10.1016/j.ceramint.2018.06.272"
}
Dolić, S. D., Jovanović, D. J., Smits, K., Babić, B. M., Marinović-Cincović, M., Porobić, S.,& Dramićanin, M.. (2018). A comparative study of photocatalytically active nanocrystalline tetragonal zyrcon-type and monoclinic scheelite-type bismuth vanadate. in Ceramics International, 44(15), 17953-17961.
https://doi.org/10.1016/j.ceramint.2018.06.272
Dolić SD, Jovanović DJ, Smits K, Babić BM, Marinović-Cincović M, Porobić S, Dramićanin M. A comparative study of photocatalytically active nanocrystalline tetragonal zyrcon-type and monoclinic scheelite-type bismuth vanadate. in Ceramics International. 2018;44(15):17953-17961.
doi:10.1016/j.ceramint.2018.06.272 .
Dolić, Slobodan D., Jovanović, Dragana J., Smits, Krisjanis, Babić, Biljana M., Marinović-Cincović, Milena, Porobić, Slavica, Dramićanin, Miroslav, "A comparative study of photocatalytically active nanocrystalline tetragonal zyrcon-type and monoclinic scheelite-type bismuth vanadate" in Ceramics International, 44, no. 15 (2018):17953-17961,
https://doi.org/10.1016/j.ceramint.2018.06.272 . .
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