New approach in designing materials for energy conversion and energy storage systems

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New approach in designing materials for energy conversion and energy storage systems (en)
Нов приступ дизајнирању материјала за конверзију и складиштење енергије (sr)
Nov pristup dizajniranju materijala za konverziju i skladištenje energije (sr_RS)
Authors

Publications

Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite

Pantović Pavlović, Marijana R.; Pavlović, Miroslav M.; Eraković, Sanja; Barudžija, Tanja; Stevanović, Jasmina S.; Ignjatović, Nenad L.; Panić, Vladimir V.

(2019)

TY  - JOUR
AU  - Pantović Pavlović, Marijana R.
AU  - Pavlović, Miroslav M.
AU  - Eraković, Sanja
AU  - Barudžija, Tanja
AU  - Stevanović, Jasmina S.
AU  - Ignjatović, Nenad L.
AU  - Panić, Vladimir V.
PY  - 2019
UR  - https://www.shd-pub.org.rs/index.php/JSCS/article/view/8524
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8671
AB  - The optimization of the anodization process of Ti substrate for in situ synthesis of hydroxyapatite/titanium oxide composite coatings on titanium substrate was accomplished. The anodization was performed under 30, 60 and 90 V cell voltage, and the morphology of treated surface, as well as linear and surface roughness, were analysed by field emission-scanning electron micro­scopy, atomic force microscopy and roughness tester. It was shown by linear and surface roughness analyses that titanium anodized under 60 V has the high­est roughness, whereas at 90 V the flattening of the surface occurs. As the highest surface roughness results emerged at 60 V, the novel process of com­po­site anHAp/TiO2 coating synthesis, which comprises simultaneous processes of TiO2 formation and HAp deposition, as well as HAp impregnation within TiO2 surface layer, was performed at this voltage. Ti substrate surface was completely covered by composite coating, with no visible cracks. The adhesion quantified according to ASTM D3359-02 standard is considerably improved with respect to the coatings obtained by cathaphoretic processes, with no need of subsequent sintering.
T2  - Journal of the Serbian Chemical Society
T1  - Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite
VL  - 84
IS  - 11
SP  - 1305
EP  - 1318
DO  - 10.2298/JSC190730105P
ER  - 
@article{
author = "Pantović Pavlović, Marijana R. and Pavlović, Miroslav M. and Eraković, Sanja and Barudžija, Tanja and Stevanović, Jasmina S. and Ignjatović, Nenad L. and Panić, Vladimir V.",
year = "2019",
abstract = "The optimization of the anodization process of Ti substrate for in situ synthesis of hydroxyapatite/titanium oxide composite coatings on titanium substrate was accomplished. The anodization was performed under 30, 60 and 90 V cell voltage, and the morphology of treated surface, as well as linear and surface roughness, were analysed by field emission-scanning electron micro­scopy, atomic force microscopy and roughness tester. It was shown by linear and surface roughness analyses that titanium anodized under 60 V has the high­est roughness, whereas at 90 V the flattening of the surface occurs. As the highest surface roughness results emerged at 60 V, the novel process of com­po­site anHAp/TiO2 coating synthesis, which comprises simultaneous processes of TiO2 formation and HAp deposition, as well as HAp impregnation within TiO2 surface layer, was performed at this voltage. Ti substrate surface was completely covered by composite coating, with no visible cracks. The adhesion quantified according to ASTM D3359-02 standard is considerably improved with respect to the coatings obtained by cathaphoretic processes, with no need of subsequent sintering.",
journal = "Journal of the Serbian Chemical Society",
title = "Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite",
volume = "84",
number = "11",
pages = "1305-1318",
doi = "10.2298/JSC190730105P"
}
Pantović Pavlović, M. R., Pavlović, M. M., Eraković, S., Barudžija, T., Stevanović, J. S., Ignjatović, N. L.,& Panić, V. V.. (2019). Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite. in Journal of the Serbian Chemical Society, 84(11), 1305-1318.
https://doi.org/10.2298/JSC190730105P
Pantović Pavlović MR, Pavlović MM, Eraković S, Barudžija T, Stevanović JS, Ignjatović NL, Panić VV. Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite. in Journal of the Serbian Chemical Society. 2019;84(11):1305-1318.
doi:10.2298/JSC190730105P .
Pantović Pavlović, Marijana R., Pavlović, Miroslav M., Eraković, Sanja, Barudžija, Tanja, Stevanović, Jasmina S., Ignjatović, Nenad L., Panić, Vladimir V., "Relationship between the properties of an interlayer formed by in situ Ti anodization and anaphoretically deposited hydroxyapatite" in Journal of the Serbian Chemical Society, 84, no. 11 (2019):1305-1318,
https://doi.org/10.2298/JSC190730105P . .
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Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide

Eraković, Sanja; Pavlović, Miroslav M.; Stopić, Srećko; Stevanović, Jasmina; Mitrić, Miodrag; Friedrich, Bernd; Panić, Vladimir

(2019)

TY  - JOUR
AU  - Eraković, Sanja
AU  - Pavlović, Miroslav M.
AU  - Stopić, Srećko
AU  - Stevanović, Jasmina
AU  - Mitrić, Miodrag
AU  - Friedrich, Bernd
AU  - Panić, Vladimir
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8470
AB  - Considerable promotion of RuO2 hosted by perovskite-like structure of rare earth–CoO3 composite and vice versa supercapacitive performances is reported. Spherical, sub-μm-sized, regular spheres of La0.6Sr0.4CoO3 (LSCO), were synthesized by ultrasonic spray pyrolysis. The sphere surface was subsequently hydrothermally doped by RuO2. LSCO and LSCO/RuO2 composites were investigated for their supercapacitive performances in alkaline solution. Microstructure and surface morphology were studied by SEM and XRD. It was found that amorphous Ru species decorate LSCO surface, and possibly incorporate partially into B-site of the LSCO lattice. Electrochemical characterization by cyclic voltammetry (CV), galvanostatic charge-discharge (G-C/DC) and electrochemical impedance spectroscopy (EIS) clearly revealed that capacitive performances of LSCO are considerably improved by addition of 20 mass. % of RuO2. The registered capacitance for LSCO/RuO2 reaches the values of pure RuO2, which reveals the promoting influence of LSCO on RuO2 pseudocapacitance. The EIS analysis showed that RuO2 catalyzes the redox transition of Co species, with simultaneous proportional increase in pseudocapacitive RuO2 abilities while being hosted by LSCO. This intrinsic interactive promotion introduces LSCO/RuO2 composite as unique supercapacitive material. G-C/DC curves showed that LSCO/RuO2 is of modest cyclability with respect to pure LSCO and RuO2, although the capacitance losses with cycling are acceptably low. © 2019 Elsevier Ltd
T2  - Electrochimica Acta
T1  - Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide
VL  - 321
SP  - 134721
DO  - 10.1016/j.electacta.2019.134721
ER  - 
@article{
author = "Eraković, Sanja and Pavlović, Miroslav M. and Stopić, Srećko and Stevanović, Jasmina and Mitrić, Miodrag and Friedrich, Bernd and Panić, Vladimir",
year = "2019",
abstract = "Considerable promotion of RuO2 hosted by perovskite-like structure of rare earth–CoO3 composite and vice versa supercapacitive performances is reported. Spherical, sub-μm-sized, regular spheres of La0.6Sr0.4CoO3 (LSCO), were synthesized by ultrasonic spray pyrolysis. The sphere surface was subsequently hydrothermally doped by RuO2. LSCO and LSCO/RuO2 composites were investigated for their supercapacitive performances in alkaline solution. Microstructure and surface morphology were studied by SEM and XRD. It was found that amorphous Ru species decorate LSCO surface, and possibly incorporate partially into B-site of the LSCO lattice. Electrochemical characterization by cyclic voltammetry (CV), galvanostatic charge-discharge (G-C/DC) and electrochemical impedance spectroscopy (EIS) clearly revealed that capacitive performances of LSCO are considerably improved by addition of 20 mass. % of RuO2. The registered capacitance for LSCO/RuO2 reaches the values of pure RuO2, which reveals the promoting influence of LSCO on RuO2 pseudocapacitance. The EIS analysis showed that RuO2 catalyzes the redox transition of Co species, with simultaneous proportional increase in pseudocapacitive RuO2 abilities while being hosted by LSCO. This intrinsic interactive promotion introduces LSCO/RuO2 composite as unique supercapacitive material. G-C/DC curves showed that LSCO/RuO2 is of modest cyclability with respect to pure LSCO and RuO2, although the capacitance losses with cycling are acceptably low. © 2019 Elsevier Ltd",
journal = "Electrochimica Acta",
title = "Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide",
volume = "321",
pages = "134721",
doi = "10.1016/j.electacta.2019.134721"
}
Eraković, S., Pavlović, M. M., Stopić, S., Stevanović, J., Mitrić, M., Friedrich, B.,& Panić, V.. (2019). Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide. in Electrochimica Acta, 321, 134721.
https://doi.org/10.1016/j.electacta.2019.134721
Eraković S, Pavlović MM, Stopić S, Stevanović J, Mitrić M, Friedrich B, Panić V. Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide. in Electrochimica Acta. 2019;321:134721.
doi:10.1016/j.electacta.2019.134721 .
Eraković, Sanja, Pavlović, Miroslav M., Stopić, Srećko, Stevanović, Jasmina, Mitrić, Miodrag, Friedrich, Bernd, Panić, Vladimir, "Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide" in Electrochimica Acta, 321 (2019):134721,
https://doi.org/10.1016/j.electacta.2019.134721 . .
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A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields

Cvetković, Vesna S.; Vukićević, Nataša M.; Nikolić, Nebojša D.; Baščarević, Zvezdana D.; Barudžija, Tanja; Jovićević, Jovan N.

(2019)

TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Vukićević, Nataša M.
AU  - Nikolić, Nebojša D.
AU  - Baščarević, Zvezdana D.
AU  - Barudžija, Tanja
AU  - Jovićević, Jovan N.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S1572665719303315
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8176
AB  - The processes of electrodeposition from magnesium nitrate hexahydrate melt by galvanostatic regime of electrolysis have been analyzed. The structure of the formed particles was examined by X-ray diffraction (XRD), which revealed formation of MgO/Mg(OH)2 mixture by molten salt electrolysis. Morphologies of the produced deposits were characterized by scanning electron microscopy (SEM)technique. The flower-like forms constructed from very thin needles with sharp tips were predominately formed by electrodeposition at various current densities and with various amounts of electricity. Aside from that, holes formed from detached hydrogen bubbles of various shapes and sizes, from dish-like holes to those resulting in honeycomb-like structures were also observed. Mechanism of formation of the flower-like forms has been elucidated applying the general theory of disperse deposits formation which is based on the concept of local (spherical and cylindrical)diffusion fields. It is shown that the growth of the needles occurs under the conditions of predominant spherical diffusion control, while the contribution of the cylindrical diffusion to the final shapes was negligible. Comparison with morphologies of deposits obtained by electrodepositions from aqueous magnesium salt electrolytes was also made and discussed. © 2019 Elsevier B.V.
T2  - Journal of Electroanalytical Chemistry
T1  - A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields
VL  - 842
SP  - 168
EP  - 175
DO  - 10.1016/j.jelechem.2019.04.067
ER  - 
@article{
author = "Cvetković, Vesna S. and Vukićević, Nataša M. and Nikolić, Nebojša D. and Baščarević, Zvezdana D. and Barudžija, Tanja and Jovićević, Jovan N.",
year = "2019",
abstract = "The processes of electrodeposition from magnesium nitrate hexahydrate melt by galvanostatic regime of electrolysis have been analyzed. The structure of the formed particles was examined by X-ray diffraction (XRD), which revealed formation of MgO/Mg(OH)2 mixture by molten salt electrolysis. Morphologies of the produced deposits were characterized by scanning electron microscopy (SEM)technique. The flower-like forms constructed from very thin needles with sharp tips were predominately formed by electrodeposition at various current densities and with various amounts of electricity. Aside from that, holes formed from detached hydrogen bubbles of various shapes and sizes, from dish-like holes to those resulting in honeycomb-like structures were also observed. Mechanism of formation of the flower-like forms has been elucidated applying the general theory of disperse deposits formation which is based on the concept of local (spherical and cylindrical)diffusion fields. It is shown that the growth of the needles occurs under the conditions of predominant spherical diffusion control, while the contribution of the cylindrical diffusion to the final shapes was negligible. Comparison with morphologies of deposits obtained by electrodepositions from aqueous magnesium salt electrolytes was also made and discussed. © 2019 Elsevier B.V.",
journal = "Journal of Electroanalytical Chemistry",
title = "A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields",
volume = "842",
pages = "168-175",
doi = "10.1016/j.jelechem.2019.04.067"
}
Cvetković, V. S., Vukićević, N. M., Nikolić, N. D., Baščarević, Z. D., Barudžija, T.,& Jovićević, J. N.. (2019). A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields. in Journal of Electroanalytical Chemistry, 842, 168-175.
https://doi.org/10.1016/j.jelechem.2019.04.067
Cvetković VS, Vukićević NM, Nikolić ND, Baščarević ZD, Barudžija T, Jovićević JN. A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields. in Journal of Electroanalytical Chemistry. 2019;842:168-175.
doi:10.1016/j.jelechem.2019.04.067 .
Cvetković, Vesna S., Vukićević, Nataša M., Nikolić, Nebojša D., Baščarević, Zvezdana D., Barudžija, Tanja, Jovićević, Jovan N., "A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields" in Journal of Electroanalytical Chemistry, 842 (2019):168-175,
https://doi.org/10.1016/j.jelechem.2019.04.067 . .
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Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts

Cvetković, Vesna S.; Vukićević, Nataša M.; Nikolić, Nebojša D.; Branković, Goran O.; Barudžija, Tanja; Jovićević, Jovan N.

(2018)

TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Vukićević, Nataša M.
AU  - Nikolić, Nebojša D.
AU  - Branković, Goran O.
AU  - Barudžija, Tanja
AU  - Jovićević, Jovan N.
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7641
AB  - The processes of electrochemical deposition of magnesium oxide/hydroxide on glassy carbon (GC) electrode from magnesium nitrate hexahydrate melt have been investigated. A novel procedure predicting a possibility of direct formation of magnesium oxide during electrodeposition from the nitrate melt used is reported. XRD analysis of the obtained deposits showed the formation of magnesium oxide along with magnesium hydroxide. The electrodeposition of magnesium oxide/hydroxide commences in magnesium underpotential (UPD) and continues through the magnesium overpotential (OPD) region. Network of individual or intertwined very thin needles as well as those grouped in flower-like aggregates or honeycomb-like structures were formed in both magnesium UPD and OPD regions. Formation of the long needles was explained through theories of mechanisms of dendrite formation. Hydrogen evolution commences in the magnesium OPD region and increases with the applied overpotential. Holes observed in the deposit originated from the detached hydrogen bubbles. The number, shape and size of the hole strongly depended on both the applied cathodic potential and the hold time of electrodeposition. Magnesium oxides/hydroxides syntheses taking part simultaneously at various applied potentials are a result of reactions between magnesium cations and products of water and nitrate anions reduction processes. Chemical reactions responsible for direct formation of magnesium oxide observed are those of magnesium ions and oxygen ions, formed by nitrate reduction taking part in the close vicinity of the working electrode. (C) 2018 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts
VL  - 268
SP  - 494
EP  - 502
DO  - 10.1016/j.electacta.2018.02.121
ER  - 
@article{
author = "Cvetković, Vesna S. and Vukićević, Nataša M. and Nikolić, Nebojša D. and Branković, Goran O. and Barudžija, Tanja and Jovićević, Jovan N.",
year = "2018",
abstract = "The processes of electrochemical deposition of magnesium oxide/hydroxide on glassy carbon (GC) electrode from magnesium nitrate hexahydrate melt have been investigated. A novel procedure predicting a possibility of direct formation of magnesium oxide during electrodeposition from the nitrate melt used is reported. XRD analysis of the obtained deposits showed the formation of magnesium oxide along with magnesium hydroxide. The electrodeposition of magnesium oxide/hydroxide commences in magnesium underpotential (UPD) and continues through the magnesium overpotential (OPD) region. Network of individual or intertwined very thin needles as well as those grouped in flower-like aggregates or honeycomb-like structures were formed in both magnesium UPD and OPD regions. Formation of the long needles was explained through theories of mechanisms of dendrite formation. Hydrogen evolution commences in the magnesium OPD region and increases with the applied overpotential. Holes observed in the deposit originated from the detached hydrogen bubbles. The number, shape and size of the hole strongly depended on both the applied cathodic potential and the hold time of electrodeposition. Magnesium oxides/hydroxides syntheses taking part simultaneously at various applied potentials are a result of reactions between magnesium cations and products of water and nitrate anions reduction processes. Chemical reactions responsible for direct formation of magnesium oxide observed are those of magnesium ions and oxygen ions, formed by nitrate reduction taking part in the close vicinity of the working electrode. (C) 2018 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts",
volume = "268",
pages = "494-502",
doi = "10.1016/j.electacta.2018.02.121"
}
Cvetković, V. S., Vukićević, N. M., Nikolić, N. D., Branković, G. O., Barudžija, T.,& Jovićević, J. N.. (2018). Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts. in Electrochimica Acta, 268, 494-502.
https://doi.org/10.1016/j.electacta.2018.02.121
Cvetković VS, Vukićević NM, Nikolić ND, Branković GO, Barudžija T, Jovićević JN. Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts. in Electrochimica Acta. 2018;268:494-502.
doi:10.1016/j.electacta.2018.02.121 .
Cvetković, Vesna S., Vukićević, Nataša M., Nikolić, Nebojša D., Branković, Goran O., Barudžija, Tanja, Jovićević, Jovan N., "Formation of needle-like and honeycomb-like magnesium oxide/hydroxide structures by electrodeposition from magnesium nitrate melts" in Electrochimica Acta, 268 (2018):494-502,
https://doi.org/10.1016/j.electacta.2018.02.121 . .
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Formation of the honeycomb-like MgO/Mg(OH)2 structures with controlled shape and size of holes by molten salt electrolysis

Vukićević, Nataša M.; Cvetković, Vesna S.; Nikolić, Nebojša D.; Branković, Goran O.; Barudžija, Tanja; Jovićević, Jovan N.

(2018)

TY  - JOUR
AU  - Vukićević, Nataša M.
AU  - Cvetković, Vesna S.
AU  - Nikolić, Nebojša D.
AU  - Branković, Goran O.
AU  - Barudžija, Tanja
AU  - Jovićević, Jovan N.
PY  - 2018
UR  - http://www.doiserbia.nb.rs/Article.aspx?ID=0352-51391800084V
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8019
AB  - Synthesis of the honeycomb-like MgO/Mg(OH)2 structures, with controlled shape and size of holes, by the electrolysis from magnesium nitrate hexahydrate melt onto glassy carbon is presented. The honeycomb-like structures were made up of holes, formed from detached hydrogen bubbles, surrounded by walls, built up of thin intertwined needles. For the first time, it was shown that the honeycomb-like structures can be obtained by molten salt electrolysis and not exclusively by electrolysis from aqueous electrolytes. Analogies with the processes of the honeycomb-like metal structures formation from aqueous electrolytes are presented and discussed. Rules established for the formation of these structures from aqueous electrolytes, such as the increase of number of holes, the decrease of holes size and coalescence of neighbouring hydrogen bubbles observed with increasing cathodic potential, appeared to be valid for the electrolysis of the molten salt used. © 2018 The Korean Physical Society. All rights reserved.
AB  - Представљено је формирање MgO/Mg(OH)2 структура облика пчелињег саћа контролисаног облика и величине рупа, процесом електролизе растопљеног магнезијум-
-нитрата-хексахидрата на стакластом угљенику. Добијене структуре пчелињег саћа су се
састојале од рупа, формираних одвајањем мехурова водоника, окружених зидом од
танких испреплетаних игала. По први пут је показано да се структуре пчелињег саћа
могу добити не само електролизом из водених електролита, већ такође и електролизом
из растопа. Аналогије са процесима формирања талога облика пчелињег саћа из водених раствора су изнесене и продискутоване. Све законитости утврђене за формирање
ових структура из водених електролита, као што су повећање броја рупа, смањење величине рупа и сједињавање суседних мехурова водоника посматраних са повећањем катодног потенцијала, важе и за електролизу из растопа.
T2  - Journal of the Serbian Chemical Society
T1  - Formation of the honeycomb-like MgO/Mg(OH)2 structures with controlled shape and size of holes by molten salt electrolysis
VL  - 83
IS  - 12
SP  - 1351
EP  - 1362
DO  - 10.2298/JSC180913084V
ER  - 
@article{
author = "Vukićević, Nataša M. and Cvetković, Vesna S. and Nikolić, Nebojša D. and Branković, Goran O. and Barudžija, Tanja and Jovićević, Jovan N.",
year = "2018",
abstract = "Synthesis of the honeycomb-like MgO/Mg(OH)2 structures, with controlled shape and size of holes, by the electrolysis from magnesium nitrate hexahydrate melt onto glassy carbon is presented. The honeycomb-like structures were made up of holes, formed from detached hydrogen bubbles, surrounded by walls, built up of thin intertwined needles. For the first time, it was shown that the honeycomb-like structures can be obtained by molten salt electrolysis and not exclusively by electrolysis from aqueous electrolytes. Analogies with the processes of the honeycomb-like metal structures formation from aqueous electrolytes are presented and discussed. Rules established for the formation of these structures from aqueous electrolytes, such as the increase of number of holes, the decrease of holes size and coalescence of neighbouring hydrogen bubbles observed with increasing cathodic potential, appeared to be valid for the electrolysis of the molten salt used. © 2018 The Korean Physical Society. All rights reserved., Представљено је формирање MgO/Mg(OH)2 структура облика пчелињег саћа контролисаног облика и величине рупа, процесом електролизе растопљеног магнезијум-
-нитрата-хексахидрата на стакластом угљенику. Добијене структуре пчелињег саћа су се
састојале од рупа, формираних одвајањем мехурова водоника, окружених зидом од
танких испреплетаних игала. По први пут је показано да се структуре пчелињег саћа
могу добити не само електролизом из водених електролита, већ такође и електролизом
из растопа. Аналогије са процесима формирања талога облика пчелињег саћа из водених раствора су изнесене и продискутоване. Све законитости утврђене за формирање
ових структура из водених електролита, као што су повећање броја рупа, смањење величине рупа и сједињавање суседних мехурова водоника посматраних са повећањем катодног потенцијала, важе и за електролизу из растопа.",
journal = "Journal of the Serbian Chemical Society",
title = "Formation of the honeycomb-like MgO/Mg(OH)2 structures with controlled shape and size of holes by molten salt electrolysis",
volume = "83",
number = "12",
pages = "1351-1362",
doi = "10.2298/JSC180913084V"
}
Vukićević, N. M., Cvetković, V. S., Nikolić, N. D., Branković, G. O., Barudžija, T.,& Jovićević, J. N.. (2018). Formation of the honeycomb-like MgO/Mg(OH)2 structures with controlled shape and size of holes by molten salt electrolysis. in Journal of the Serbian Chemical Society, 83(12), 1351-1362.
https://doi.org/10.2298/JSC180913084V
Vukićević NM, Cvetković VS, Nikolić ND, Branković GO, Barudžija T, Jovićević JN. Formation of the honeycomb-like MgO/Mg(OH)2 structures with controlled shape and size of holes by molten salt electrolysis. in Journal of the Serbian Chemical Society. 2018;83(12):1351-1362.
doi:10.2298/JSC180913084V .
Vukićević, Nataša M., Cvetković, Vesna S., Nikolić, Nebojša D., Branković, Goran O., Barudžija, Tanja, Jovićević, Jovan N., "Formation of the honeycomb-like MgO/Mg(OH)2 structures with controlled shape and size of holes by molten salt electrolysis" in Journal of the Serbian Chemical Society, 83, no. 12 (2018):1351-1362,
https://doi.org/10.2298/JSC180913084V . .
2
2
2

Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers

Mijailović, Daniel M.; Vukčević, Marija M.; Stević, Zoran M.; Kalijadis, Ana; Stojanović, Dušica B.; Panić, Vladimir V.; Uskoković, Petar S.

(2017)

TY  - JOUR
AU  - Mijailović, Daniel M.
AU  - Vukčević, Marija M.
AU  - Stević, Zoran M.
AU  - Kalijadis, Ana
AU  - Stojanović, Dušica B.
AU  - Panić, Vladimir V.
AU  - Uskoković, Petar S.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1583
AB  - Activated carbons with high specific surface area (even above 2000 m(2) g(-1)) and pronounced microporosity are prepared in two-stage process involving conventional carbonization of waste hemp fibers and subsequent activation by potassium hydroxide. Samples with considerably different surface and intrinsic micro-and mesoporous properties are obtained at different carbonization and activation conditions. The improvements of the capacitive properties are found upon increase in carbonization temperature, since it considerably influenced the specific surface area and the content of surface oxygen groups. Cyclic voltammetry experiments reveal the dependence of specific capacitance on the sweep rate due to the characteristic porous structure of the samples. The highest measured value in 1 M H2SO4 solution is 122 F g(-1). The electrochemical impedance data indicates eight-branch transmission line equivalent electric behavior of activated carbons. (C) 2017 The Electrochemical Society. All rights reserved.
T2  - Journal of the Electrochemical Society
T1  - Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers
VL  - 164
IS  - 6
SP  - A1061
EP  - A1068
DO  - 10.1149/2.0581706jes
ER  - 
@article{
author = "Mijailović, Daniel M. and Vukčević, Marija M. and Stević, Zoran M. and Kalijadis, Ana and Stojanović, Dušica B. and Panić, Vladimir V. and Uskoković, Petar S.",
year = "2017",
abstract = "Activated carbons with high specific surface area (even above 2000 m(2) g(-1)) and pronounced microporosity are prepared in two-stage process involving conventional carbonization of waste hemp fibers and subsequent activation by potassium hydroxide. Samples with considerably different surface and intrinsic micro-and mesoporous properties are obtained at different carbonization and activation conditions. The improvements of the capacitive properties are found upon increase in carbonization temperature, since it considerably influenced the specific surface area and the content of surface oxygen groups. Cyclic voltammetry experiments reveal the dependence of specific capacitance on the sweep rate due to the characteristic porous structure of the samples. The highest measured value in 1 M H2SO4 solution is 122 F g(-1). The electrochemical impedance data indicates eight-branch transmission line equivalent electric behavior of activated carbons. (C) 2017 The Electrochemical Society. All rights reserved.",
journal = "Journal of the Electrochemical Society",
title = "Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers",
volume = "164",
number = "6",
pages = "A1061-A1068",
doi = "10.1149/2.0581706jes"
}
Mijailović, D. M., Vukčević, M. M., Stević, Z. M., Kalijadis, A., Stojanović, D. B., Panić, V. V.,& Uskoković, P. S.. (2017). Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers. in Journal of the Electrochemical Society, 164(6), A1061-A1068.
https://doi.org/10.1149/2.0581706jes
Mijailović DM, Vukčević MM, Stević ZM, Kalijadis A, Stojanović DB, Panić VV, Uskoković PS. Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers. in Journal of the Electrochemical Society. 2017;164(6):A1061-A1068.
doi:10.1149/2.0581706jes .
Mijailović, Daniel M., Vukčević, Marija M., Stević, Zoran M., Kalijadis, Ana, Stojanović, Dušica B., Panić, Vladimir V., Uskoković, Petar S., "Supercapacitive Performances of Activated Highly Microporous Natural Carbon Macrofibers" in Journal of the Electrochemical Society, 164, no. 6 (2017):A1061-A1068,
https://doi.org/10.1149/2.0581706jes . .
11
5
9

TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications

Košević, Milica; Šekularac, Gavrilo; Živković, Ljiljana; Panić, Vladimir; Nikolić, Branislav Ž.

(2017)

TY  - JOUR
AU  - Košević, Milica
AU  - Šekularac, Gavrilo
AU  - Živković, Ljiljana
AU  - Panić, Vladimir
AU  - Nikolić, Branislav Ž.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1836
AB  - TiO2 powder was synthesized by a forced hydrolysis process and used for the synthesis of Pt/TiO2 composite that is to be foreseen as an advanced electrode material. Pt was incorporated into the synthesized TiO2 from a Pt colloidal dispersion as a precursor prepared by a microwave- assisted polyol process. Physicochemical properties of TiO2 and TiO2- supported Pt were investigated by scanning electron microscopy, dynamic light scattering and X- ray spectroscopy and diffraction techniques. The properties of Pt/TiO2 composite are correlated to the basic voltammetric response of its thin-layer form. It was found that subsequent thermal treatment of synthesized TiO2, which caused crystallization into mainly rutile phase, is required for appropriate Pt incorporation. Although being appropriately loaded by Pt, and the voltammetric response is typical for Pt-based material, the voltammetry of Pt/TiO2 corresponded to much lower loadings.The possibility for Pt particles to be trapped inside TiO2 agglomerates is indicated. The catalyst usage from the synthesized Pt/TiO2 was found quite moderate due to this trapping.
T2  - Croatica Chemica Acta
T1  - TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications
VL  - 90
IS  - 2
SP  - 251
EP  - 258
DO  - 10.5562/cca3175
ER  - 
@article{
author = "Košević, Milica and Šekularac, Gavrilo and Živković, Ljiljana and Panić, Vladimir and Nikolić, Branislav Ž.",
year = "2017",
abstract = "TiO2 powder was synthesized by a forced hydrolysis process and used for the synthesis of Pt/TiO2 composite that is to be foreseen as an advanced electrode material. Pt was incorporated into the synthesized TiO2 from a Pt colloidal dispersion as a precursor prepared by a microwave- assisted polyol process. Physicochemical properties of TiO2 and TiO2- supported Pt were investigated by scanning electron microscopy, dynamic light scattering and X- ray spectroscopy and diffraction techniques. The properties of Pt/TiO2 composite are correlated to the basic voltammetric response of its thin-layer form. It was found that subsequent thermal treatment of synthesized TiO2, which caused crystallization into mainly rutile phase, is required for appropriate Pt incorporation. Although being appropriately loaded by Pt, and the voltammetric response is typical for Pt-based material, the voltammetry of Pt/TiO2 corresponded to much lower loadings.The possibility for Pt particles to be trapped inside TiO2 agglomerates is indicated. The catalyst usage from the synthesized Pt/TiO2 was found quite moderate due to this trapping.",
journal = "Croatica Chemica Acta",
title = "TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications",
volume = "90",
number = "2",
pages = "251-258",
doi = "10.5562/cca3175"
}
Košević, M., Šekularac, G., Živković, L., Panić, V.,& Nikolić, B. Ž.. (2017). TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications. in Croatica Chemica Acta, 90(2), 251-258.
https://doi.org/10.5562/cca3175
Košević M, Šekularac G, Živković L, Panić V, Nikolić BŽ. TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications. in Croatica Chemica Acta. 2017;90(2):251-258.
doi:10.5562/cca3175 .
Košević, Milica, Šekularac, Gavrilo, Živković, Ljiljana, Panić, Vladimir, Nikolić, Branislav Ž., "TiO2 From Colloidal Dispersion as Support in Pt/TiO2 Nanocomposite for Electrochemical Applications" in Croatica Chemica Acta, 90, no. 2 (2017):251-258,
https://doi.org/10.5562/cca3175 . .
5
2
5

Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium

Gulicovski, Jelena J.; Bajat, Jelena B.; Jokić, Bojan M.; Panić, Vladimir; Mišković-Stanković, Vesna B.; Milonjić, Slobodan K.

(Springer, 2016)

TY  - JOUR
AU  - Gulicovski, Jelena J.
AU  - Bajat, Jelena B.
AU  - Jokić, Bojan M.
AU  - Panić, Vladimir
AU  - Mišković-Stanković, Vesna B.
AU  - Milonjić, Slobodan K.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/894
AB  - Ceria coating is formed on Al from the ceria sol prepared exclusively by forced hydrolysis of Ce(NO3)(4), in order to test their ability to protect Al from corrosion. The characterization of sol-gel-processed ceria coating and coating/Al assembly brings new issues on Al corrosion and protection caused by unique properties of the sol-gel coating. The corrosion behaviour of bare Al and Al/CeO2 is investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to NaCl aqueous solution. The morphology and composition of the samples are examined by scanning electron microscopy and energy dispersive spectroscopy. EIS data showed greater corrosion resistance of CeO2-coated aluminium in comparison to bare Al at long exposure times. CeO2 coating does not hinder completely the corrosion processes on Al. The Al beneath CeO2 coating is subjected to intrinsic formation of a uniform protective coating/Al interphase, cross-linked by AlO(OH) fibre-like structures. They appear created by corrosive medium from the coating reversely gelled by NaCl solution. As the fibre network is created during exposure, Al becomes better protected than by spontaneous formation of porous passive layer of Al(OH)(3) on bare aluminium. Sol-gel ceria coatings thus improve corrosion resistance of aluminium during prolonged exposure to corrosive medium.
PB  - Springer
T2  - Journal of Solid State Electrochemistry
T1  - Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium
VL  - 20
IS  - 1
SP  - 293
EP  - 303
DO  - 10.1007/s10008-015-3040-3
ER  - 
@article{
author = "Gulicovski, Jelena J. and Bajat, Jelena B. and Jokić, Bojan M. and Panić, Vladimir and Mišković-Stanković, Vesna B. and Milonjić, Slobodan K.",
year = "2016",
abstract = "Ceria coating is formed on Al from the ceria sol prepared exclusively by forced hydrolysis of Ce(NO3)(4), in order to test their ability to protect Al from corrosion. The characterization of sol-gel-processed ceria coating and coating/Al assembly brings new issues on Al corrosion and protection caused by unique properties of the sol-gel coating. The corrosion behaviour of bare Al and Al/CeO2 is investigated by the electrochemical impedance spectroscopy (EIS) during the exposure to NaCl aqueous solution. The morphology and composition of the samples are examined by scanning electron microscopy and energy dispersive spectroscopy. EIS data showed greater corrosion resistance of CeO2-coated aluminium in comparison to bare Al at long exposure times. CeO2 coating does not hinder completely the corrosion processes on Al. The Al beneath CeO2 coating is subjected to intrinsic formation of a uniform protective coating/Al interphase, cross-linked by AlO(OH) fibre-like structures. They appear created by corrosive medium from the coating reversely gelled by NaCl solution. As the fibre network is created during exposure, Al becomes better protected than by spontaneous formation of porous passive layer of Al(OH)(3) on bare aluminium. Sol-gel ceria coatings thus improve corrosion resistance of aluminium during prolonged exposure to corrosive medium.",
publisher = "Springer",
journal = "Journal of Solid State Electrochemistry",
title = "Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium",
volume = "20",
number = "1",
pages = "293-303",
doi = "10.1007/s10008-015-3040-3"
}
Gulicovski, J. J., Bajat, J. B., Jokić, B. M., Panić, V., Mišković-Stanković, V. B.,& Milonjić, S. K.. (2016). Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium. in Journal of Solid State Electrochemistry
Springer., 20(1), 293-303.
https://doi.org/10.1007/s10008-015-3040-3
Gulicovski JJ, Bajat JB, Jokić BM, Panić V, Mišković-Stanković VB, Milonjić SK. Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium. in Journal of Solid State Electrochemistry. 2016;20(1):293-303.
doi:10.1007/s10008-015-3040-3 .
Gulicovski, Jelena J., Bajat, Jelena B., Jokić, Bojan M., Panić, Vladimir, Mišković-Stanković, Vesna B., Milonjić, Slobodan K., "Protective ability and impedance response of sol-gel reversely transformed ceria conversion coating on aluminium" in Journal of Solid State Electrochemistry, 20, no. 1 (2016):293-303,
https://doi.org/10.1007/s10008-015-3040-3 . .
6
6
6

Characterization of nanoporous carbon fibrous materials obtained by chemical activation of plane tree seed under ultrasonic irradiation

Kaluđerović, Branka V.; Jovanovic, Vladislava M.; Stevanović, Sanja I.; Bogdanov, Žarko

(2014)

TY  - JOUR
AU  - Kaluđerović, Branka V.
AU  - Jovanovic, Vladislava M.
AU  - Stevanović, Sanja I.
AU  - Bogdanov, Žarko
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5837
AB  - An ultrasonic irradiation was applied for the impregnation by chemical agents in the chemical activation process of new type of active carbon precursor. Plane tree seed, due to the unique fibrous structure and low cost is a promising eco-friendly raw material for the preparation of activated carbon materials. Ultrasonic irradiation was used for the impregnation step allowing the chemical activation by different agents: potassium or sodium hydroxide, hydrogen peroxide and pyrogallol. The porous structures were examined by nitrogen adsorption/desorption isotherms at 77 K and electrochemically by cyclic voltammetry. The textures of these materials were observed by scanning electron microscopy. The application of ultrasonic irradiation in the impregnation step increased surface area of the final material more than two times in comparison to the material which impregnation in the activation process was by conventional stirring. Ultrasonic irradiation enhances the chemical activation process and the activated carbon fibrous materials with nanoporous structure were obtained by impregnation of seeds with alkaline hydroxides. Total surface areas of these samples were 976 m(2) g(-1), and 1130 m(2) g(-1). These fibers have total specific capacitance as high as 125 F g(-1) and 53 F g(-1) which major fraction in both cases originate from internal micropores structure. (C) 2013 Elsevier B.V. All rights reserved.
T2  - Ultrasonics Sonochemistry
T1  - Characterization of nanoporous carbon fibrous materials obtained by chemical activation of plane tree seed under ultrasonic irradiation
VL  - 21
IS  - 2
SP  - 782
EP  - 789
DO  - 10.1016/j.ultsonch.2013.09.004
ER  - 
@article{
author = "Kaluđerović, Branka V. and Jovanovic, Vladislava M. and Stevanović, Sanja I. and Bogdanov, Žarko",
year = "2014",
abstract = "An ultrasonic irradiation was applied for the impregnation by chemical agents in the chemical activation process of new type of active carbon precursor. Plane tree seed, due to the unique fibrous structure and low cost is a promising eco-friendly raw material for the preparation of activated carbon materials. Ultrasonic irradiation was used for the impregnation step allowing the chemical activation by different agents: potassium or sodium hydroxide, hydrogen peroxide and pyrogallol. The porous structures were examined by nitrogen adsorption/desorption isotherms at 77 K and electrochemically by cyclic voltammetry. The textures of these materials were observed by scanning electron microscopy. The application of ultrasonic irradiation in the impregnation step increased surface area of the final material more than two times in comparison to the material which impregnation in the activation process was by conventional stirring. Ultrasonic irradiation enhances the chemical activation process and the activated carbon fibrous materials with nanoporous structure were obtained by impregnation of seeds with alkaline hydroxides. Total surface areas of these samples were 976 m(2) g(-1), and 1130 m(2) g(-1). These fibers have total specific capacitance as high as 125 F g(-1) and 53 F g(-1) which major fraction in both cases originate from internal micropores structure. (C) 2013 Elsevier B.V. All rights reserved.",
journal = "Ultrasonics Sonochemistry",
title = "Characterization of nanoporous carbon fibrous materials obtained by chemical activation of plane tree seed under ultrasonic irradiation",
volume = "21",
number = "2",
pages = "782-789",
doi = "10.1016/j.ultsonch.2013.09.004"
}
Kaluđerović, B. V., Jovanovic, V. M., Stevanović, S. I.,& Bogdanov, Ž.. (2014). Characterization of nanoporous carbon fibrous materials obtained by chemical activation of plane tree seed under ultrasonic irradiation. in Ultrasonics Sonochemistry, 21(2), 782-789.
https://doi.org/10.1016/j.ultsonch.2013.09.004
Kaluđerović BV, Jovanovic VM, Stevanović SI, Bogdanov Ž. Characterization of nanoporous carbon fibrous materials obtained by chemical activation of plane tree seed under ultrasonic irradiation. in Ultrasonics Sonochemistry. 2014;21(2):782-789.
doi:10.1016/j.ultsonch.2013.09.004 .
Kaluđerović, Branka V., Jovanovic, Vladislava M., Stevanović, Sanja I., Bogdanov, Žarko, "Characterization of nanoporous carbon fibrous materials obtained by chemical activation of plane tree seed under ultrasonic irradiation" in Ultrasonics Sonochemistry, 21, no. 2 (2014):782-789,
https://doi.org/10.1016/j.ultsonch.2013.09.004 . .
21
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21