Functional, Functionalized and Advanced Nanomaterials

Link to this page

info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45005/RS//

Functional, Functionalized and Advanced Nanomaterials (en)
Функционални, функционализовани и усавршени нано материјали (sr)
Funkcionalni, funkcionalizovani i usavršeni nano materijali (sr_RS)
Authors

Publications

Detailed phisyco-chemical characterization of the multilayered thin films based on titanium oxynitride and copper doped titanium nitride obtained by different PVD techniques

Jokanović, Vukoman R.; Bundaleski, Nenad; Petrović, Božana; Ferarra, Manuela; Jokanović, Bojan; Živković, Slavoljub; Nasov, Ilija

(2022)

TY  - JOUR
AU  - Jokanović, Vukoman R.
AU  - Bundaleski, Nenad
AU  - Petrović, Božana
AU  - Ferarra, Manuela
AU  - Jokanović, Bojan
AU  - Živković, Slavoljub
AU  - Nasov, Ilija
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10029
AB  - Thin films on the base of titanium oxynitrides and copper doped titanium nitride were obtained by a combination of different PVD techniques on the surface of glass substrate and their physicochemical properties were analyzed in details. Phase composition of the samples was analyzed by XRD and FTIR methods, while microstructure of the samples was analyzed by SEM. XPS was used for depth profiling of the samples, which enabled determination of the oxidative state of titanium and corresponding phases through various film layers from the surface to the substrate. The depth of the various layers and their extinction coefficients and refractory indexes were estimated by spectroscopic ellipsometry.
T2  - Vacuum
T1  - Detailed phisyco-chemical characterization of the multilayered thin films based on titanium oxynitride and copper doped titanium nitride obtained by different PVD techniques
VL  - 195
SP  - 110708
DO  - 10.1016/j.vacuum.2021.110708
ER  - 
@article{
author = "Jokanović, Vukoman R. and Bundaleski, Nenad and Petrović, Božana and Ferarra, Manuela and Jokanović, Bojan and Živković, Slavoljub and Nasov, Ilija",
year = "2022",
abstract = "Thin films on the base of titanium oxynitrides and copper doped titanium nitride were obtained by a combination of different PVD techniques on the surface of glass substrate and their physicochemical properties were analyzed in details. Phase composition of the samples was analyzed by XRD and FTIR methods, while microstructure of the samples was analyzed by SEM. XPS was used for depth profiling of the samples, which enabled determination of the oxidative state of titanium and corresponding phases through various film layers from the surface to the substrate. The depth of the various layers and their extinction coefficients and refractory indexes were estimated by spectroscopic ellipsometry.",
journal = "Vacuum",
title = "Detailed phisyco-chemical characterization of the multilayered thin films based on titanium oxynitride and copper doped titanium nitride obtained by different PVD techniques",
volume = "195",
pages = "110708",
doi = "10.1016/j.vacuum.2021.110708"
}
Jokanović, V. R., Bundaleski, N., Petrović, B., Ferarra, M., Jokanović, B., Živković, S.,& Nasov, I.. (2022). Detailed phisyco-chemical characterization of the multilayered thin films based on titanium oxynitride and copper doped titanium nitride obtained by different PVD techniques. in Vacuum, 195, 110708.
https://doi.org/10.1016/j.vacuum.2021.110708
Jokanović VR, Bundaleski N, Petrović B, Ferarra M, Jokanović B, Živković S, Nasov I. Detailed phisyco-chemical characterization of the multilayered thin films based on titanium oxynitride and copper doped titanium nitride obtained by different PVD techniques. in Vacuum. 2022;195:110708.
doi:10.1016/j.vacuum.2021.110708 .
Jokanović, Vukoman R., Bundaleski, Nenad, Petrović, Božana, Ferarra, Manuela, Jokanović, Bojan, Živković, Slavoljub, Nasov, Ilija, "Detailed phisyco-chemical characterization of the multilayered thin films based on titanium oxynitride and copper doped titanium nitride obtained by different PVD techniques" in Vacuum, 195 (2022):110708,
https://doi.org/10.1016/j.vacuum.2021.110708 . .
5
4

The influence of various coatings of hydroxyapatite bone carrier on the success of bone regeneration in rabbit calvarial defects: Histomorphometric and histological analysis

Milutinović-Smiljanić, Sanja; Antonijević, Đorđe; Mićić, Milutin; Biočanin, Vladimir; Sjerobabin, Nikola; Petrović, Božana; Danilović, Vesna; Jokanović, Vukoman R.

(2022)

TY  - JOUR
AU  - Milutinović-Smiljanić, Sanja
AU  - Antonijević, Đorđe
AU  - Mićić, Milutin
AU  - Biočanin, Vladimir
AU  - Sjerobabin, Nikola
AU  - Petrović, Božana
AU  - Danilović, Vesna
AU  - Jokanović, Vukoman R.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11221
AB  - Background/Aim. The materials used nowadays for bone replacement do not fully meet the requirements for complete regeneration, which is why new ones are being tested. Despite numerous attempts to improve bone tissue regeneration, no fulfilling material has been found yet. This study investigated the influence of poly-lactide-co-glycolide (PLGA) and polyethyleneimine (PEI) as coatings for hydroxyapatite (HAP) bone carriers on bone tissue regenerative potential in rabbits? calvarial defect. Methods. Calvarial defects measuring 6 mm in diameter were made in 19 skeletally mature rabbits. Defects were filled with one of the following materials: PLGA coated HAP (HAP + PLGA), PEI coated HAP (HAP + PEI), and bovine HAP ? Bio-Oss? (positive control). Unfilled defects represented negative control. Histological analysis was performed in order to determine the inflammatory response of the host tissue. The formation of the new bone was evaluated using histomorphometric analysis. All analyses have been conducted in samples obtained 3, 6, and 9 weeks after implantation. Results. Three weeks post-implantation, a trend toward increased healing in the HAP + PLGA group compared to other investigated materials was noticed, with no statistically significant difference between the study groups (p > 0.05). However, after 6 and 9 weeks, significant healing was observed in favor of the HAP coated with PLGA compared to other groups (p
AB  - Uvod/Cilj. Materijali koji se u današnje vreme koriste za nadoknadu koštanog tkiva ne dovode do kompletne regeneracije, zbog čega se ispituju novi. Uprkos mnogobrojnim pokušajima da se poboljša regeneracija koštanog tkiva, još uvek nije pronađen materijal koji ispunjava sve kriterijume. Cilj rada bio je da se utvrdi uticaj poli(laktid-ko-glikolida) (PLGA) i polietilenimina (PEI), kao premaza za oblaganje hidroksiapatita (HAP), na regenerativni potencijal koštanog tkiva u defektu kalvarije zeca. Metode. Kod 19 zečeva „zrelog” skeleta načinjeni su defekti kalvarije dijametra 6 mm. Defekti su potom ispunjeni jednim od sledećih materijala: HAP obložen PLGA (HAP + PLGA), HAP obložen PEI (HAP + PEI) i goveđi HAP – Bio-Oss® (pozitivna kontrola). Prazni defekti su predstavljali negativnu kontrolu. Inflamacijska reakcija tkiva domaćina je ispitana histološkom analizom. Formiranje nove kosti je procenjivano histomorfometrijskom analizom. Analizirani su uzorci dobijeni 3, 6 i 9 nedelja nakon implantacije. Rezultati. Tri nedelje nakon implantacije, uočena je tendencija boljeg zarastanja u HAP + PLGA grupi, bez statistički značajne razlike između ispitivanih grupa (p > 0.05). Međutim, 6 i 9 nedelja nakon implantacije, primećeno je značajno formiranje koštanog tkiva u korist HAP + PLGA grupe (p < 0,05). Oblaganje HAP sa PLGA dovelo je do boljeg koštanog zarastanja u poređenju sa HAP+PEI i Bio-Oss®. Zaključak. U pogledu stimulisanja osteogeneze u rekonstruktivnoj hirurgiji kostiju, PLGA je pokazao veći potencijal prekrivanja defekta od PEI.
T2  - Vojnosanitetski pregled
T1  - The influence of various coatings of hydroxyapatite bone carrier on the success of bone regeneration in rabbit calvarial defects: Histomorphometric and histological analysis
T1  - Uticaj različitih materijala koji oblažu hidroksiapatit koštanog nosača na uspeh regeneracije koštanih defekta kalvarije zeca: histomorfometrijska i histološka analiza
VL  - 79
IS  - 10
SP  - 1025
EP  - 1034
DO  - 10.2298/VSP210513072M
ER  - 
@article{
author = "Milutinović-Smiljanić, Sanja and Antonijević, Đorđe and Mićić, Milutin and Biočanin, Vladimir and Sjerobabin, Nikola and Petrović, Božana and Danilović, Vesna and Jokanović, Vukoman R.",
year = "2022",
abstract = "Background/Aim. The materials used nowadays for bone replacement do not fully meet the requirements for complete regeneration, which is why new ones are being tested. Despite numerous attempts to improve bone tissue regeneration, no fulfilling material has been found yet. This study investigated the influence of poly-lactide-co-glycolide (PLGA) and polyethyleneimine (PEI) as coatings for hydroxyapatite (HAP) bone carriers on bone tissue regenerative potential in rabbits? calvarial defect. Methods. Calvarial defects measuring 6 mm in diameter were made in 19 skeletally mature rabbits. Defects were filled with one of the following materials: PLGA coated HAP (HAP + PLGA), PEI coated HAP (HAP + PEI), and bovine HAP ? Bio-Oss? (positive control). Unfilled defects represented negative control. Histological analysis was performed in order to determine the inflammatory response of the host tissue. The formation of the new bone was evaluated using histomorphometric analysis. All analyses have been conducted in samples obtained 3, 6, and 9 weeks after implantation. Results. Three weeks post-implantation, a trend toward increased healing in the HAP + PLGA group compared to other investigated materials was noticed, with no statistically significant difference between the study groups (p > 0.05). However, after 6 and 9 weeks, significant healing was observed in favor of the HAP coated with PLGA compared to other groups (p, Uvod/Cilj. Materijali koji se u današnje vreme koriste za nadoknadu koštanog tkiva ne dovode do kompletne regeneracije, zbog čega se ispituju novi. Uprkos mnogobrojnim pokušajima da se poboljša regeneracija koštanog tkiva, još uvek nije pronađen materijal koji ispunjava sve kriterijume. Cilj rada bio je da se utvrdi uticaj poli(laktid-ko-glikolida) (PLGA) i polietilenimina (PEI), kao premaza za oblaganje hidroksiapatita (HAP), na regenerativni potencijal koštanog tkiva u defektu kalvarije zeca. Metode. Kod 19 zečeva „zrelog” skeleta načinjeni su defekti kalvarije dijametra 6 mm. Defekti su potom ispunjeni jednim od sledećih materijala: HAP obložen PLGA (HAP + PLGA), HAP obložen PEI (HAP + PEI) i goveđi HAP – Bio-Oss® (pozitivna kontrola). Prazni defekti su predstavljali negativnu kontrolu. Inflamacijska reakcija tkiva domaćina je ispitana histološkom analizom. Formiranje nove kosti je procenjivano histomorfometrijskom analizom. Analizirani su uzorci dobijeni 3, 6 i 9 nedelja nakon implantacije. Rezultati. Tri nedelje nakon implantacije, uočena je tendencija boljeg zarastanja u HAP + PLGA grupi, bez statistički značajne razlike između ispitivanih grupa (p > 0.05). Međutim, 6 i 9 nedelja nakon implantacije, primećeno je značajno formiranje koštanog tkiva u korist HAP + PLGA grupe (p < 0,05). Oblaganje HAP sa PLGA dovelo je do boljeg koštanog zarastanja u poređenju sa HAP+PEI i Bio-Oss®. Zaključak. U pogledu stimulisanja osteogeneze u rekonstruktivnoj hirurgiji kostiju, PLGA je pokazao veći potencijal prekrivanja defekta od PEI.",
journal = "Vojnosanitetski pregled",
title = "The influence of various coatings of hydroxyapatite bone carrier on the success of bone regeneration in rabbit calvarial defects: Histomorphometric and histological analysis, Uticaj različitih materijala koji oblažu hidroksiapatit koštanog nosača na uspeh regeneracije koštanih defekta kalvarije zeca: histomorfometrijska i histološka analiza",
volume = "79",
number = "10",
pages = "1025-1034",
doi = "10.2298/VSP210513072M"
}
Milutinović-Smiljanić, S., Antonijević, Đ., Mićić, M., Biočanin, V., Sjerobabin, N., Petrović, B., Danilović, V.,& Jokanović, V. R.. (2022). The influence of various coatings of hydroxyapatite bone carrier on the success of bone regeneration in rabbit calvarial defects: Histomorphometric and histological analysis. in Vojnosanitetski pregled, 79(10), 1025-1034.
https://doi.org/10.2298/VSP210513072M
Milutinović-Smiljanić S, Antonijević Đ, Mićić M, Biočanin V, Sjerobabin N, Petrović B, Danilović V, Jokanović VR. The influence of various coatings of hydroxyapatite bone carrier on the success of bone regeneration in rabbit calvarial defects: Histomorphometric and histological analysis. in Vojnosanitetski pregled. 2022;79(10):1025-1034.
doi:10.2298/VSP210513072M .
Milutinović-Smiljanić, Sanja, Antonijević, Đorđe, Mićić, Milutin, Biočanin, Vladimir, Sjerobabin, Nikola, Petrović, Božana, Danilović, Vesna, Jokanović, Vukoman R., "The influence of various coatings of hydroxyapatite bone carrier on the success of bone regeneration in rabbit calvarial defects: Histomorphometric and histological analysis" in Vojnosanitetski pregled, 79, no. 10 (2022):1025-1034,
https://doi.org/10.2298/VSP210513072M . .
1

Detailed characterization of the Ti-O based thin films obtained by cathodic arc evaporation

Jokanović, Vukoman R.; Bundaleski, Nenad; Čolović, Božana M.; Ferarra, Manuela; Jokanović, Bojan; Nasov, Ilija

(2021)

TY  - JOUR
AU  - Jokanović, Vukoman R.
AU  - Bundaleski, Nenad
AU  - Čolović, Božana M.
AU  - Ferarra, Manuela
AU  - Jokanović, Bojan
AU  - Nasov, Ilija
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9891
AB  - Physicochemical properties of thin films on the base of titanium oxides, obtained by a cathodic arc evaporation on the surface of glass substrate are analysed in details. The analysis of these films was made by using XRD, FTIR, SEM, XPS analysis and ellipsometry. On the basis of these analyses, particularly analysis obtained by XPS, the oxidative state Ti and corresponding phases are determined through various film layers from the surface to the substrate. The depth of the various levels and their extinction coefficients and refractory indexes are estimated by ellipsometry.
T2  - Zaštita materijala
T1  - Detailed characterization of the Ti-O based thin films obtained by cathodic arc evaporation
VL  - 62
IS  - 1
SP  - 41
EP  - 50
DO  - 10.5937/zasmat2101041J
ER  - 
@article{
author = "Jokanović, Vukoman R. and Bundaleski, Nenad and Čolović, Božana M. and Ferarra, Manuela and Jokanović, Bojan and Nasov, Ilija",
year = "2021",
abstract = "Physicochemical properties of thin films on the base of titanium oxides, obtained by a cathodic arc evaporation on the surface of glass substrate are analysed in details. The analysis of these films was made by using XRD, FTIR, SEM, XPS analysis and ellipsometry. On the basis of these analyses, particularly analysis obtained by XPS, the oxidative state Ti and corresponding phases are determined through various film layers from the surface to the substrate. The depth of the various levels and their extinction coefficients and refractory indexes are estimated by ellipsometry.",
journal = "Zaštita materijala",
title = "Detailed characterization of the Ti-O based thin films obtained by cathodic arc evaporation",
volume = "62",
number = "1",
pages = "41-50",
doi = "10.5937/zasmat2101041J"
}
Jokanović, V. R., Bundaleski, N., Čolović, B. M., Ferarra, M., Jokanović, B.,& Nasov, I.. (2021). Detailed characterization of the Ti-O based thin films obtained by cathodic arc evaporation. in Zaštita materijala, 62(1), 41-50.
https://doi.org/10.5937/zasmat2101041J
Jokanović VR, Bundaleski N, Čolović BM, Ferarra M, Jokanović B, Nasov I. Detailed characterization of the Ti-O based thin films obtained by cathodic arc evaporation. in Zaštita materijala. 2021;62(1):41-50.
doi:10.5937/zasmat2101041J .
Jokanović, Vukoman R., Bundaleski, Nenad, Čolović, Božana M., Ferarra, Manuela, Jokanović, Bojan, Nasov, Ilija, "Detailed characterization of the Ti-O based thin films obtained by cathodic arc evaporation" in Zaštita materijala, 62, no. 1 (2021):41-50,
https://doi.org/10.5937/zasmat2101041J . .
1

Biocompatibility study of a new dental cement based on hydroxyapatite and calcium silicates: Focus on liver, kidney, and spleen tissue effects

Paraš, Smiljana; Trišić, Dijana; Mitrović-Ajtić, Olivera; Antonijević, Đorđe; Čolović, Božana M.; Drobne, Damjana; Jokanović, Vukoman R.

(2021)

TY  - JOUR
AU  - Paraš, Smiljana
AU  - Trišić, Dijana
AU  - Mitrović-Ajtić, Olivera
AU  - Antonijević, Đorđe
AU  - Čolović, Božana M.
AU  - Drobne, Damjana
AU  - Jokanović, Vukoman R.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9821
AB  - The effects of a new material based on hydroxyapatite and calcium silicates, named ALBO-MPCA, were investigated on the liver, kidney and spleen. The material was administrated orally for 120 days in an in vivo model in Wistar rats, and untreated animals served as a control. Hematological and biochemical blood parameters were analyzed. Qualitative histological analysis of tissues, change in mitotic activity of cells, and histological characteristics was conducted, as well as quantitative stereological analysis of parenchymal cells, blood sinusoids, and connective tissues. Additionally, the protein expressions of Ki67 and CD68 markers were evaluated. Histological analysis revealed no pathological changes after the tested period. It showed the preservation of the architecture of blood sinusoids and epithelial cells and the presence of mitosis. Additionally, the significantly increased number of the Ki67 in the presence of ALBO-MPCA confirmed the proliferative effect of the material noticed by stereological analysis, while immunoreactive CD68 positive cells did not differ between groups. The study showed non-toxicity of the tested material based on the effects on the hematological, biochemical, and observed histological parameters; in addition, it showed evidence of its biocompatibility. These results could be the basis for further steps toward the application of tested materials in endodontics.
T2  - International Journal of Molecular Science
T1  - Biocompatibility study of a new dental cement based on hydroxyapatite and calcium silicates: Focus on liver, kidney, and spleen tissue effects
VL  - 22
IS  - 11
SP  - 5468
DO  - 10.3390/ijms22115468
ER  - 
@article{
author = "Paraš, Smiljana and Trišić, Dijana and Mitrović-Ajtić, Olivera and Antonijević, Đorđe and Čolović, Božana M. and Drobne, Damjana and Jokanović, Vukoman R.",
year = "2021",
abstract = "The effects of a new material based on hydroxyapatite and calcium silicates, named ALBO-MPCA, were investigated on the liver, kidney and spleen. The material was administrated orally for 120 days in an in vivo model in Wistar rats, and untreated animals served as a control. Hematological and biochemical blood parameters were analyzed. Qualitative histological analysis of tissues, change in mitotic activity of cells, and histological characteristics was conducted, as well as quantitative stereological analysis of parenchymal cells, blood sinusoids, and connective tissues. Additionally, the protein expressions of Ki67 and CD68 markers were evaluated. Histological analysis revealed no pathological changes after the tested period. It showed the preservation of the architecture of blood sinusoids and epithelial cells and the presence of mitosis. Additionally, the significantly increased number of the Ki67 in the presence of ALBO-MPCA confirmed the proliferative effect of the material noticed by stereological analysis, while immunoreactive CD68 positive cells did not differ between groups. The study showed non-toxicity of the tested material based on the effects on the hematological, biochemical, and observed histological parameters; in addition, it showed evidence of its biocompatibility. These results could be the basis for further steps toward the application of tested materials in endodontics.",
journal = "International Journal of Molecular Science",
title = "Biocompatibility study of a new dental cement based on hydroxyapatite and calcium silicates: Focus on liver, kidney, and spleen tissue effects",
volume = "22",
number = "11",
pages = "5468",
doi = "10.3390/ijms22115468"
}
Paraš, S., Trišić, D., Mitrović-Ajtić, O., Antonijević, Đ., Čolović, B. M., Drobne, D.,& Jokanović, V. R.. (2021). Biocompatibility study of a new dental cement based on hydroxyapatite and calcium silicates: Focus on liver, kidney, and spleen tissue effects. in International Journal of Molecular Science, 22(11), 5468.
https://doi.org/10.3390/ijms22115468
Paraš S, Trišić D, Mitrović-Ajtić O, Antonijević Đ, Čolović BM, Drobne D, Jokanović VR. Biocompatibility study of a new dental cement based on hydroxyapatite and calcium silicates: Focus on liver, kidney, and spleen tissue effects. in International Journal of Molecular Science. 2021;22(11):5468.
doi:10.3390/ijms22115468 .
Paraš, Smiljana, Trišić, Dijana, Mitrović-Ajtić, Olivera, Antonijević, Đorđe, Čolović, Božana M., Drobne, Damjana, Jokanović, Vukoman R., "Biocompatibility study of a new dental cement based on hydroxyapatite and calcium silicates: Focus on liver, kidney, and spleen tissue effects" in International Journal of Molecular Science, 22, no. 11 (2021):5468,
https://doi.org/10.3390/ijms22115468 . .
1

Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature

Suljovrujić, Edin H.; Rogić Miladinović, Zorana; Krstić, Maja

(2021)

TY  - JOUR
AU  - Suljovrujić, Edin H.
AU  - Rogić Miladinović, Zorana
AU  - Krstić, Maja
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11469
AB  - Oligo (ethylene glycol) oligo (propylene glycol) methacrylates (OEGOPGMA) with diferent numbers of ethylene glycol (EG) and propylene glycol (PG) units in backbone were used for the preparation of new thermoresponsive POEGOPGMA hydrogels; EG6PG3MA and EG3PG6MA monomers were used; and three diferent POEGOPGMA hydrogels (PEG6PG3MA, PEG3PG6MA and P(EG6PG3/EG3PG6) MA copolymer with equal mol% of previous two) were fabricated from mono‑ mer–solvent (OEGOPGMA–water/ethanol) mixture by gamma radiation. Charac‑ terisation of the hydrogels was conducted by swelling, UV–Vis, scanning electron microscope, diferential scanning calorimetry and in  vitro biocompatibility (cyto‑ compatibility and haemolytic activity) investigations. The modelling of drug release and difusion characteristics was tested using cephalexin drug. For the frst time, it was shown how to efectively tune the volume phase transition temperature (VPTT) values of the hydrogels by changing the ratio of more hydrophilic (EG) and more hydrophobic (PG) units in (EGPG) “block” pendant chains. The obtained hydrogels revealed the great potential for diferent biomedical applications not only due to the possibility to tune VPTT in the desired way but also due to the good biocompatibil‑ ity and controlled drug delivery within the target temperature range.
T2  - Polymer Bulletin
T1  - Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature
VL  - 78
SP  - 2405
EP  - 2425
DO  - 10.1007/s00289-020-03217-0
ER  - 
@article{
author = "Suljovrujić, Edin H. and Rogić Miladinović, Zorana and Krstić, Maja",
year = "2021",
abstract = "Oligo (ethylene glycol) oligo (propylene glycol) methacrylates (OEGOPGMA) with diferent numbers of ethylene glycol (EG) and propylene glycol (PG) units in backbone were used for the preparation of new thermoresponsive POEGOPGMA hydrogels; EG6PG3MA and EG3PG6MA monomers were used; and three diferent POEGOPGMA hydrogels (PEG6PG3MA, PEG3PG6MA and P(EG6PG3/EG3PG6) MA copolymer with equal mol% of previous two) were fabricated from mono‑ mer–solvent (OEGOPGMA–water/ethanol) mixture by gamma radiation. Charac‑ terisation of the hydrogels was conducted by swelling, UV–Vis, scanning electron microscope, diferential scanning calorimetry and in  vitro biocompatibility (cyto‑ compatibility and haemolytic activity) investigations. The modelling of drug release and difusion characteristics was tested using cephalexin drug. For the frst time, it was shown how to efectively tune the volume phase transition temperature (VPTT) values of the hydrogels by changing the ratio of more hydrophilic (EG) and more hydrophobic (PG) units in (EGPG) “block” pendant chains. The obtained hydrogels revealed the great potential for diferent biomedical applications not only due to the possibility to tune VPTT in the desired way but also due to the good biocompatibil‑ ity and controlled drug delivery within the target temperature range.",
journal = "Polymer Bulletin",
title = "Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature",
volume = "78",
pages = "2405-2425",
doi = "10.1007/s00289-020-03217-0"
}
Suljovrujić, E. H., Rogić Miladinović, Z.,& Krstić, M.. (2021). Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature. in Polymer Bulletin, 78, 2405-2425.
https://doi.org/10.1007/s00289-020-03217-0
Suljovrujić EH, Rogić Miladinović Z, Krstić M. Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature. in Polymer Bulletin. 2021;78:2405-2425.
doi:10.1007/s00289-020-03217-0 .
Suljovrujić, Edin H., Rogić Miladinović, Zorana, Krstić, Maja, "Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature" in Polymer Bulletin, 78 (2021):2405-2425,
https://doi.org/10.1007/s00289-020-03217-0 . .
7
2
6

Improvement of Neural Networks Applied to Photoacoustic Signals of Semiconductors with Added Noise

Đorđević, Кatarina Lj.; Galović, Slobodanka; Jordović-Pavlović, Miroslava I.; Ćojbašić, Žarko М.; Markushev, Dragan D.

(2021)

TY  - JOUR
AU  - Đorđević, Кatarina Lj.
AU  - Galović, Slobodanka
AU  - Jordović-Pavlović, Miroslava I.
AU  - Ćojbašić, Žarko М.
AU  - Markushev, Dragan D.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9581
AB  - This paper provides an overview of the characteristics of different neural networks trained on the same theoretical database of n-type silicon photoacoustic signals. By adding different levels of random Gaussian noise to the training input signals, two important goals were achieved. First, the optimal level of noise was found which significantly shortens the training networks with minimal loss of accuracy of its predictions. Second, the termination criteria of networks training were activated to avoid overtraining, i.e., networks generalization was performed. A networks efficiency analysis was performed on both theoretical and experimental photoacoustic signals, resulting in a selection of one neural network that is optimal to the performance requirements of the real experiment. It is indicated that the application of such trained networks is more reliable on thicker semiconductors, whose thickness is greater than the value of the carrier diffusion length in the investigated sample. © 2020, Springer Nature B.V.
T2  - Silicon
T1  - Improvement of Neural Networks Applied to Photoacoustic Signals of Semiconductors with Added Noise
VL  - 13
IS  - 9
SP  - 2959
EP  - 2969
DO  - 10.1007/s12633-020-00606-y
ER  - 
@article{
author = "Đorđević, Кatarina Lj. and Galović, Slobodanka and Jordović-Pavlović, Miroslava I. and Ćojbašić, Žarko М. and Markushev, Dragan D.",
year = "2021",
abstract = "This paper provides an overview of the characteristics of different neural networks trained on the same theoretical database of n-type silicon photoacoustic signals. By adding different levels of random Gaussian noise to the training input signals, two important goals were achieved. First, the optimal level of noise was found which significantly shortens the training networks with minimal loss of accuracy of its predictions. Second, the termination criteria of networks training were activated to avoid overtraining, i.e., networks generalization was performed. A networks efficiency analysis was performed on both theoretical and experimental photoacoustic signals, resulting in a selection of one neural network that is optimal to the performance requirements of the real experiment. It is indicated that the application of such trained networks is more reliable on thicker semiconductors, whose thickness is greater than the value of the carrier diffusion length in the investigated sample. © 2020, Springer Nature B.V.",
journal = "Silicon",
title = "Improvement of Neural Networks Applied to Photoacoustic Signals of Semiconductors with Added Noise",
volume = "13",
number = "9",
pages = "2959-2969",
doi = "10.1007/s12633-020-00606-y"
}
Đorđević, К. Lj., Galović, S., Jordović-Pavlović, M. I., Ćojbašić, Ž. М.,& Markushev, D. D.. (2021). Improvement of Neural Networks Applied to Photoacoustic Signals of Semiconductors with Added Noise. in Silicon, 13(9), 2959-2969.
https://doi.org/10.1007/s12633-020-00606-y
Đorđević КL, Galović S, Jordović-Pavlović MI, Ćojbašić ŽМ, Markushev DD. Improvement of Neural Networks Applied to Photoacoustic Signals of Semiconductors with Added Noise. in Silicon. 2021;13(9):2959-2969.
doi:10.1007/s12633-020-00606-y .
Đorđević, Кatarina Lj., Galović, Slobodanka, Jordović-Pavlović, Miroslava I., Ćojbašić, Žarko М., Markushev, Dragan D., "Improvement of Neural Networks Applied to Photoacoustic Signals of Semiconductors with Added Noise" in Silicon, 13, no. 9 (2021):2959-2969,
https://doi.org/10.1007/s12633-020-00606-y . .
2
1

The advantages and disadvantages of biodentine: satisfactory mechanical properties and radiopacity not meeting ISO standard

Milutinović-Smiljanić, Sanja; Ilić, Dragan; Danilović, Vesna; Antonijević, Đorđe

(2021)

TY  - JOUR
AU  - Milutinović-Smiljanić, Sanja
AU  - Ilić, Dragan
AU  - Danilović, Vesna
AU  - Antonijević, Đorđe
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10030
AB  - Background/Aim. In dentistry, the concept of using inert materials for tissue repair has been replaced by the strategy to find bioactive materials which positively interact with human tissues. The aim of this study was to characterize the physicochemical properties of the commercially available calcium silicate and calcium carbonate-based dental cement, biodentine (Septodont, France). Methods. Material elucidation included the measurements of radiopacity, scanning electron microscopy and x-ray dispersive analyses, wettability, Fourier transform infrared spectroscopy, microindentation, micro- to nanoporosity, setting time, pH and calcium ion release. The cells (mouse bone marrow mesenchymal stem cells – BMSCs) were grown on biodentine surface in order to evaluate its behaviour under biological conditions. Results. The radiopacity of the cement (2.8 mmAl) was below ISO requirement for a root canal filling material. The cement was composed of fine powder with particles similar in size and shape, changing from oval to cubic after having been soaked in a simulated body fluid. Biodentine demonstrated good micromechanical properties and low porosity attributed to microporosity with the average pore size of 92 μm. Wettability (contact angle = 41°), calcium ion release (0.098 μg/cm2) and pH of storage solution (9.07) showed satisfactory characteristics. The BMSCa in intimate contact with cement particles remained viable, indicating biodentine good biocompatibility. Conclusion. Biodentine exhibits good mechanical and physicochemical characteristics, but possesses insufficient radiopacity. © 2021 Inst. Sci. inf., Univ. Defence in Belgrade. All rights reserved.
T2  - Vojnosanitetski pregled
T1  - The advantages and disadvantages of biodentine: satisfactory mechanical properties and radiopacity not meeting ISO standard
VL  - 78
IS  - 9
SP  - 973
EP  - 980
DO  - 10.2298/VSP191212014M
ER  - 
@article{
author = "Milutinović-Smiljanić, Sanja and Ilić, Dragan and Danilović, Vesna and Antonijević, Đorđe",
year = "2021",
abstract = "Background/Aim. In dentistry, the concept of using inert materials for tissue repair has been replaced by the strategy to find bioactive materials which positively interact with human tissues. The aim of this study was to characterize the physicochemical properties of the commercially available calcium silicate and calcium carbonate-based dental cement, biodentine (Septodont, France). Methods. Material elucidation included the measurements of radiopacity, scanning electron microscopy and x-ray dispersive analyses, wettability, Fourier transform infrared spectroscopy, microindentation, micro- to nanoporosity, setting time, pH and calcium ion release. The cells (mouse bone marrow mesenchymal stem cells – BMSCs) were grown on biodentine surface in order to evaluate its behaviour under biological conditions. Results. The radiopacity of the cement (2.8 mmAl) was below ISO requirement for a root canal filling material. The cement was composed of fine powder with particles similar in size and shape, changing from oval to cubic after having been soaked in a simulated body fluid. Biodentine demonstrated good micromechanical properties and low porosity attributed to microporosity with the average pore size of 92 μm. Wettability (contact angle = 41°), calcium ion release (0.098 μg/cm2) and pH of storage solution (9.07) showed satisfactory characteristics. The BMSCa in intimate contact with cement particles remained viable, indicating biodentine good biocompatibility. Conclusion. Biodentine exhibits good mechanical and physicochemical characteristics, but possesses insufficient radiopacity. © 2021 Inst. Sci. inf., Univ. Defence in Belgrade. All rights reserved.",
journal = "Vojnosanitetski pregled",
title = "The advantages and disadvantages of biodentine: satisfactory mechanical properties and radiopacity not meeting ISO standard",
volume = "78",
number = "9",
pages = "973-980",
doi = "10.2298/VSP191212014M"
}
Milutinović-Smiljanić, S., Ilić, D., Danilović, V.,& Antonijević, Đ.. (2021). The advantages and disadvantages of biodentine: satisfactory mechanical properties and radiopacity not meeting ISO standard. in Vojnosanitetski pregled, 78(9), 973-980.
https://doi.org/10.2298/VSP191212014M
Milutinović-Smiljanić S, Ilić D, Danilović V, Antonijević Đ. The advantages and disadvantages of biodentine: satisfactory mechanical properties and radiopacity not meeting ISO standard. in Vojnosanitetski pregled. 2021;78(9):973-980.
doi:10.2298/VSP191212014M .
Milutinović-Smiljanić, Sanja, Ilić, Dragan, Danilović, Vesna, Antonijević, Đorđe, "The advantages and disadvantages of biodentine: satisfactory mechanical properties and radiopacity not meeting ISO standard" in Vojnosanitetski pregled, 78, no. 9 (2021):973-980,
https://doi.org/10.2298/VSP191212014M . .
1
1

Another two families of integer-valued polynomials associated with finite trigonometric sums

Cvijović, Đurđe

(2021)

TY  - JOUR
AU  - Cvijović, Đurđe
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10525
AB  - As a sequel to our recent paper, its general approach was here extended to finite alternating trigonometric sums giving rise to polynomials which were systematically examined in full detail as well as in a unified manner using simple arguments. Two new general families of integer-valued polynomials (along with four other families derived from them, also integer-valued, including two already known) were deduced. Also, these polynomials enable closed-form summation of a great deal of general families of finite sums.
T2  - Applicable Analysis and Discrete Mathematics
T1  - Another two families of integer-valued polynomials associated with finite trigonometric sums
VL  - 15
IS  - 1
SP  - 69
EP  - 81
DO  - 10.2298/AADM200915004C
ER  - 
@article{
author = "Cvijović, Đurđe",
year = "2021",
abstract = "As a sequel to our recent paper, its general approach was here extended to finite alternating trigonometric sums giving rise to polynomials which were systematically examined in full detail as well as in a unified manner using simple arguments. Two new general families of integer-valued polynomials (along with four other families derived from them, also integer-valued, including two already known) were deduced. Also, these polynomials enable closed-form summation of a great deal of general families of finite sums.",
journal = "Applicable Analysis and Discrete Mathematics",
title = "Another two families of integer-valued polynomials associated with finite trigonometric sums",
volume = "15",
number = "1",
pages = "69-81",
doi = "10.2298/AADM200915004C"
}
Cvijović, Đ.. (2021). Another two families of integer-valued polynomials associated with finite trigonometric sums. in Applicable Analysis and Discrete Mathematics, 15(1), 69-81.
https://doi.org/10.2298/AADM200915004C
Cvijović Đ. Another two families of integer-valued polynomials associated with finite trigonometric sums. in Applicable Analysis and Discrete Mathematics. 2021;15(1):69-81.
doi:10.2298/AADM200915004C .
Cvijović, Đurđe, "Another two families of integer-valued polynomials associated with finite trigonometric sums" in Applicable Analysis and Discrete Mathematics, 15, no. 1 (2021):69-81,
https://doi.org/10.2298/AADM200915004C . .

Inverse problem solving in semiconductor photoacoustics by neural networks

Đorđević, Katarina Lj.; Markushev, Dragan D.; Ćojbašić, Žarko М.; Galović, Slobodanka

(2021)

TY  - JOUR
AU  - Đorđević, Katarina Lj.
AU  - Markushev, Dragan D.
AU  - Ćojbašić, Žarko М.
AU  - Galović, Slobodanka
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9075
AB  - We developed a method of inverse problem solving in semiconductor photoacoustics based on neural networks application. Simple structured neural networks, trained on a large set of data obtained by the well–known theoretical models in the 20 Hz–20 kHz modulation frequency range, are applied to determine thermal diffusivity, coefficient of linear expansion and thickness of n–type silicon samples, using undistorted experimental photoacoustic signals. The efficiency of the neural networks was tested depending on the type of input data, showing the best performances in the case when signal amplitudes and phases are simultaneously presented to the network. Real–time parameter prediction is achieved together with high accuracy and reliability allowing one to perform the full characterization of a sample in the frequency domain.
T2  - Inverse Problems in Science and Engineering
T1  - Inverse problem solving in semiconductor photoacoustics by neural networks
VL  - 29
IS  - 2
SP  - 248
EP  - 262
DO  - 10.1080/17415977.2020.1787405
ER  - 
@article{
author = "Đorđević, Katarina Lj. and Markushev, Dragan D. and Ćojbašić, Žarko М. and Galović, Slobodanka",
year = "2021",
abstract = "We developed a method of inverse problem solving in semiconductor photoacoustics based on neural networks application. Simple structured neural networks, trained on a large set of data obtained by the well–known theoretical models in the 20 Hz–20 kHz modulation frequency range, are applied to determine thermal diffusivity, coefficient of linear expansion and thickness of n–type silicon samples, using undistorted experimental photoacoustic signals. The efficiency of the neural networks was tested depending on the type of input data, showing the best performances in the case when signal amplitudes and phases are simultaneously presented to the network. Real–time parameter prediction is achieved together with high accuracy and reliability allowing one to perform the full characterization of a sample in the frequency domain.",
journal = "Inverse Problems in Science and Engineering",
title = "Inverse problem solving in semiconductor photoacoustics by neural networks",
volume = "29",
number = "2",
pages = "248-262",
doi = "10.1080/17415977.2020.1787405"
}
Đorđević, K. Lj., Markushev, D. D., Ćojbašić, Ž. М.,& Galović, S.. (2021). Inverse problem solving in semiconductor photoacoustics by neural networks. in Inverse Problems in Science and Engineering, 29(2), 248-262.
https://doi.org/10.1080/17415977.2020.1787405
Đorđević KL, Markushev DD, Ćojbašić ŽМ, Galović S. Inverse problem solving in semiconductor photoacoustics by neural networks. in Inverse Problems in Science and Engineering. 2021;29(2):248-262.
doi:10.1080/17415977.2020.1787405 .
Đorđević, Katarina Lj., Markushev, Dragan D., Ćojbašić, Žarko М., Galović, Slobodanka, "Inverse problem solving in semiconductor photoacoustics by neural networks" in Inverse Problems in Science and Engineering, 29, no. 2 (2021):248-262,
https://doi.org/10.1080/17415977.2020.1787405 . .
1
10
1
7

Multicomponent Modelling Kinetics and Simultaneous Thermal Analysis of Apricot Kernel Shell Pyrolysis

Manić, Nebojša; Janković, Bojan; Dodevski, Vladimir; Stojiljković, Dragoslava; Jovanović, Vladimir

(2020)

TY  - JOUR
AU  - Manić, Nebojša
AU  - Janković, Bojan
AU  - Dodevski, Vladimir
AU  - Stojiljković, Dragoslava
AU  - Jovanović, Vladimir
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12629
AB  - Apricot kernel shells are naturally available source of biomass with potential for conversion to clean energy through a thermo-chemical process such as pyrolysis. To facilitate further process development, an advanced mathematical model which represents the process kinetics is developed and validated on the thermal decomposition studies using simultaneous thermal analysis, over a temperature range of 30-900 °C, at four heating rates of 5, 10, 15 and 20 °C min−1, under argon atmosphere. Model-free analysis and numerically developed methods were utilized for determination of effective activation energies, pre-exponential factors and the fractional contribution. A novel approach is introduced in order to determine actual pseudo-components of studied biomass that are included in its composition. The comparative study of the obtained kinetic results was also presented. The results obtained strongly indicated that the pseudo-component reaction modelling method could be employed to predict the experimental devolatilization rate and biomass composition with a high likelihood of success.
T2  - Journal of Sustainable Development of Energy, Water and Environment Systems
T1  - Multicomponent Modelling Kinetics and Simultaneous Thermal Analysis of Apricot Kernel Shell Pyrolysis
VL  - 8
IS  - 4
SP  - 766
EP  - 787
DO  - 10.13044/j.sdewes.d7.0307
ER  - 
@article{
author = "Manić, Nebojša and Janković, Bojan and Dodevski, Vladimir and Stojiljković, Dragoslava and Jovanović, Vladimir",
year = "2020",
abstract = "Apricot kernel shells are naturally available source of biomass with potential for conversion to clean energy through a thermo-chemical process such as pyrolysis. To facilitate further process development, an advanced mathematical model which represents the process kinetics is developed and validated on the thermal decomposition studies using simultaneous thermal analysis, over a temperature range of 30-900 °C, at four heating rates of 5, 10, 15 and 20 °C min−1, under argon atmosphere. Model-free analysis and numerically developed methods were utilized for determination of effective activation energies, pre-exponential factors and the fractional contribution. A novel approach is introduced in order to determine actual pseudo-components of studied biomass that are included in its composition. The comparative study of the obtained kinetic results was also presented. The results obtained strongly indicated that the pseudo-component reaction modelling method could be employed to predict the experimental devolatilization rate and biomass composition with a high likelihood of success.",
journal = "Journal of Sustainable Development of Energy, Water and Environment Systems",
title = "Multicomponent Modelling Kinetics and Simultaneous Thermal Analysis of Apricot Kernel Shell Pyrolysis",
volume = "8",
number = "4",
pages = "766-787",
doi = "10.13044/j.sdewes.d7.0307"
}
Manić, N., Janković, B., Dodevski, V., Stojiljković, D.,& Jovanović, V.. (2020). Multicomponent Modelling Kinetics and Simultaneous Thermal Analysis of Apricot Kernel Shell Pyrolysis. in Journal of Sustainable Development of Energy, Water and Environment Systems, 8(4), 766-787.
https://doi.org/10.13044/j.sdewes.d7.0307
Manić N, Janković B, Dodevski V, Stojiljković D, Jovanović V. Multicomponent Modelling Kinetics and Simultaneous Thermal Analysis of Apricot Kernel Shell Pyrolysis. in Journal of Sustainable Development of Energy, Water and Environment Systems. 2020;8(4):766-787.
doi:10.13044/j.sdewes.d7.0307 .
Manić, Nebojša, Janković, Bojan, Dodevski, Vladimir, Stojiljković, Dragoslava, Jovanović, Vladimir, "Multicomponent Modelling Kinetics and Simultaneous Thermal Analysis of Apricot Kernel Shell Pyrolysis" in Journal of Sustainable Development of Energy, Water and Environment Systems, 8, no. 4 (2020):766-787,
https://doi.org/10.13044/j.sdewes.d7.0307 . .
10
10

Formation of Au-Ag alloy nanoparticles in amorphous silicon using sequential ion implantation

Novaković, Mirjana M.; Popović, Maja; Noga, Pavol; Vaňa, Dušan; Rakočević, Zlatko Lj.

(2020)

TY  - JOUR
AU  - Novaković, Mirjana M.
AU  - Popović, Maja
AU  - Noga, Pavol
AU  - Vaňa, Dušan
AU  - Rakočević, Zlatko Lj.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8929
AB  - Au-Ag alloy nanoparticles were formed into amorphous silicon by sequential ion implantation of Au and Ag. Monocrystalline Si was amorphized at the initial moment of implantation with 1 × 1016 ions/cm2 gold ions, and then different silver fluences were applied in the range of 1 × 1016–1 × 1017 ions/cm2. After implantations the samples were investigated by means of Rutherford backscattering spectrometry and transmission electron microscopy. The nanoparticles were found to be formed at surface and sub-surface regions of the Si substrate, at depths corresponding to the maximum distribution of Au and Ag ions. The particles are crystalline in nature with sizes from 2 nm to 30 nm in diameter, increasing with silver ion fluence. Although the lattice constants of gold and silver are too close to be distinguished by measuring the characteristic interplanar spacings, imaging in scanning transmission mode confirms the formation of Au-Ag bimetallic nanoparticles, presenting a solid-solution alloy of gold and silver.
T2  - Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
T1  - Formation of Au-Ag alloy nanoparticles in amorphous silicon using sequential ion implantation
VL  - 471
SP  - 33
EP  - 41
DO  - 10.1016/j.nimb.2020.03.021
ER  - 
@article{
author = "Novaković, Mirjana M. and Popović, Maja and Noga, Pavol and Vaňa, Dušan and Rakočević, Zlatko Lj.",
year = "2020",
abstract = "Au-Ag alloy nanoparticles were formed into amorphous silicon by sequential ion implantation of Au and Ag. Monocrystalline Si was amorphized at the initial moment of implantation with 1 × 1016 ions/cm2 gold ions, and then different silver fluences were applied in the range of 1 × 1016–1 × 1017 ions/cm2. After implantations the samples were investigated by means of Rutherford backscattering spectrometry and transmission electron microscopy. The nanoparticles were found to be formed at surface and sub-surface regions of the Si substrate, at depths corresponding to the maximum distribution of Au and Ag ions. The particles are crystalline in nature with sizes from 2 nm to 30 nm in diameter, increasing with silver ion fluence. Although the lattice constants of gold and silver are too close to be distinguished by measuring the characteristic interplanar spacings, imaging in scanning transmission mode confirms the formation of Au-Ag bimetallic nanoparticles, presenting a solid-solution alloy of gold and silver.",
journal = "Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms",
title = "Formation of Au-Ag alloy nanoparticles in amorphous silicon using sequential ion implantation",
volume = "471",
pages = "33-41",
doi = "10.1016/j.nimb.2020.03.021"
}
Novaković, M. M., Popović, M., Noga, P., Vaňa, D.,& Rakočević, Z. Lj.. (2020). Formation of Au-Ag alloy nanoparticles in amorphous silicon using sequential ion implantation. in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 471, 33-41.
https://doi.org/10.1016/j.nimb.2020.03.021
Novaković MM, Popović M, Noga P, Vaňa D, Rakočević ZL. Formation of Au-Ag alloy nanoparticles in amorphous silicon using sequential ion implantation. in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 2020;471:33-41.
doi:10.1016/j.nimb.2020.03.021 .
Novaković, Mirjana M., Popović, Maja, Noga, Pavol, Vaňa, Dušan, Rakočević, Zlatko Lj., "Formation of Au-Ag alloy nanoparticles in amorphous silicon using sequential ion implantation" in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 471 (2020):33-41,
https://doi.org/10.1016/j.nimb.2020.03.021 . .
6
2
6

Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight

Šojić Merkulov, Daniela V.; Lazarević, Marina J.; Đorđević, Aleksandar N.; Náfrádi, Máté; Alapi, Tünde; Putnik, Predrag; Rakočević, Zlatko Lj.; Novaković, Mirjana M.; Miljević, Bojan; Bognár, Szabolcs; Abramović, Biljana F.

(2020)

TY  - JOUR
AU  - Šojić Merkulov, Daniela V.
AU  - Lazarević, Marina J.
AU  - Đorđević, Aleksandar N.
AU  - Náfrádi, Máté
AU  - Alapi, Tünde
AU  - Putnik, Predrag
AU  - Rakočević, Zlatko Lj.
AU  - Novaković, Mirjana M.
AU  - Miljević, Bojan
AU  - Bognár, Szabolcs
AU  - Abramović, Biljana F.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9588
AB  - Nowadays, great focus is given to the contamination of surface and groundwater because of the extensive usage of pesticides in agriculture. The improvements of commercial catalyst TiO2 activity using different Au nanoparticles were investigated for mesotrione photocatalytic degradation under simulated sunlight. The selected system was 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) that was studied by transmission electron microscopy and ultraviolet-visible (UV-Vis) spectroscopy. It was found that TiO2 particles size was ~20 nm and ~50 nm, respectively. The Au nanoparticles were below 10 nm and were well distributed within the framework of TiO2 . For 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L), band gap energy was 2.45 eV. In comparison to the pure TiO2, addition of Au nanoparticles generally enhanced photocatalytic removal of mesotrione. By examining the degree of mineralization, it was found that 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) system was the most efficient for the removal of the mesotrione and intermediates. The effect of tert-butanol, NaF and ethylenediaminetetraacetic acid disodium salt on the transformation rate suggested that the relative contribution of various reactive species changed in following order: h+ &gt;•OHads &gt;•OHbulk. Finally, several intermediates that were formed during the photocatalytic treatment of mesotrione were identified. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
T2  - Nanomaterials
T1  - Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight
VL  - 10
IS  - 8
SP  - 1
EP  - 15
DO  - 10.3390/nano10081591
ER  - 
@article{
author = "Šojić Merkulov, Daniela V. and Lazarević, Marina J. and Đorđević, Aleksandar N. and Náfrádi, Máté and Alapi, Tünde and Putnik, Predrag and Rakočević, Zlatko Lj. and Novaković, Mirjana M. and Miljević, Bojan and Bognár, Szabolcs and Abramović, Biljana F.",
year = "2020",
abstract = "Nowadays, great focus is given to the contamination of surface and groundwater because of the extensive usage of pesticides in agriculture. The improvements of commercial catalyst TiO2 activity using different Au nanoparticles were investigated for mesotrione photocatalytic degradation under simulated sunlight. The selected system was 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) that was studied by transmission electron microscopy and ultraviolet-visible (UV-Vis) spectroscopy. It was found that TiO2 particles size was ~20 nm and ~50 nm, respectively. The Au nanoparticles were below 10 nm and were well distributed within the framework of TiO2 . For 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L), band gap energy was 2.45 eV. In comparison to the pure TiO2, addition of Au nanoparticles generally enhanced photocatalytic removal of mesotrione. By examining the degree of mineralization, it was found that 2.43 × 10−3% Au–S–CH2–CH2–OH/TiO2 (0.5 g/L) system was the most efficient for the removal of the mesotrione and intermediates. The effect of tert-butanol, NaF and ethylenediaminetetraacetic acid disodium salt on the transformation rate suggested that the relative contribution of various reactive species changed in following order: h+ &gt;•OHads &gt;•OHbulk. Finally, several intermediates that were formed during the photocatalytic treatment of mesotrione were identified. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.",
journal = "Nanomaterials",
title = "Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight",
volume = "10",
number = "8",
pages = "1-15",
doi = "10.3390/nano10081591"
}
Šojić Merkulov, D. V., Lazarević, M. J., Đorđević, A. N., Náfrádi, M., Alapi, T., Putnik, P., Rakočević, Z. Lj., Novaković, M. M., Miljević, B., Bognár, S.,& Abramović, B. F.. (2020). Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight. in Nanomaterials, 10(8), 1-15.
https://doi.org/10.3390/nano10081591
Šojić Merkulov DV, Lazarević MJ, Đorđević AN, Náfrádi M, Alapi T, Putnik P, Rakočević ZL, Novaković MM, Miljević B, Bognár S, Abramović BF. Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight. in Nanomaterials. 2020;10(8):1-15.
doi:10.3390/nano10081591 .
Šojić Merkulov, Daniela V., Lazarević, Marina J., Đorđević, Aleksandar N., Náfrádi, Máté, Alapi, Tünde, Putnik, Predrag, Rakočević, Zlatko Lj., Novaković, Mirjana M., Miljević, Bojan, Bognár, Szabolcs, Abramović, Biljana F., "Potential of TiO2 with various au nanoparticles for catalyzing mesotrione removal from wastewaters under sunlight" in Nanomaterials, 10, no. 8 (2020):1-15,
https://doi.org/10.3390/nano10081591 . .
6
3
5

Passive and active shielding against electromagnetic radiation

Đekić, Saša B.; Nikezić, Dušan P.; Brajović, Dragan; Kartalović, Nenad M.; Ramadani, Uzahir

(2020)

TY  - JOUR
AU  - Đekić, Saša B.
AU  - Nikezić, Dušan P.
AU  - Brajović, Dragan
AU  - Kartalović, Nenad M.
AU  - Ramadani, Uzahir
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9165
AB  - In nuclear physics experiments, it is very important to isolate the measured quantities from electromagnetic noise. Without this possibility, it is impossible to obtain usable experimental results since natural electromagnetic noise can be several orders of magnitude larger than the measured magnitude. In order to enable such measurements, it is necessary to eliminate electromagnetic noise from the experimental procedure. This is achieved by shielding against electromagnetic radiation. In this paper, experiments were performed to protect a room from electromagnetic noise. By applying all known methods of shielding against electromagnetic radiation, it was concluded that the room can be protected from the electrical component, but it is impossible to protect it from the magnetic component of electromagnetic radiation.
T2  - Nuclear Technology and Radiation Protection
T1  - Passive and active shielding against electromagnetic radiation
VL  - 35
IS  - 4
SP  - 331
EP  - 338
DO  - 10.2298/NTRP2004331D
ER  - 
@article{
author = "Đekić, Saša B. and Nikezić, Dušan P. and Brajović, Dragan and Kartalović, Nenad M. and Ramadani, Uzahir",
year = "2020",
abstract = "In nuclear physics experiments, it is very important to isolate the measured quantities from electromagnetic noise. Without this possibility, it is impossible to obtain usable experimental results since natural electromagnetic noise can be several orders of magnitude larger than the measured magnitude. In order to enable such measurements, it is necessary to eliminate electromagnetic noise from the experimental procedure. This is achieved by shielding against electromagnetic radiation. In this paper, experiments were performed to protect a room from electromagnetic noise. By applying all known methods of shielding against electromagnetic radiation, it was concluded that the room can be protected from the electrical component, but it is impossible to protect it from the magnetic component of electromagnetic radiation.",
journal = "Nuclear Technology and Radiation Protection",
title = "Passive and active shielding against electromagnetic radiation",
volume = "35",
number = "4",
pages = "331-338",
doi = "10.2298/NTRP2004331D"
}
Đekić, S. B., Nikezić, D. P., Brajović, D., Kartalović, N. M.,& Ramadani, U.. (2020). Passive and active shielding against electromagnetic radiation. in Nuclear Technology and Radiation Protection, 35(4), 331-338.
https://doi.org/10.2298/NTRP2004331D
Đekić SB, Nikezić DP, Brajović D, Kartalović NM, Ramadani U. Passive and active shielding against electromagnetic radiation. in Nuclear Technology and Radiation Protection. 2020;35(4):331-338.
doi:10.2298/NTRP2004331D .
Đekić, Saša B., Nikezić, Dušan P., Brajović, Dragan, Kartalović, Nenad M., Ramadani, Uzahir, "Passive and active shielding against electromagnetic radiation" in Nuclear Technology and Radiation Protection, 35, no. 4 (2020):331-338,
https://doi.org/10.2298/NTRP2004331D . .
8
1
6

Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior

Kisić, Danilo; Nenadović, Miloš; Potočnik, Jelena; Novaković, Mirjana M.; Noga, Pavol; Vaňa, Dušan; Závacká, Anna; Rakočević, Zlatko Lj.

(2020)

TY  - JOUR
AU  - Kisić, Danilo
AU  - Nenadović, Miloš
AU  - Potočnik, Jelena
AU  - Novaković, Mirjana M.
AU  - Noga, Pavol
AU  - Vaňa, Dušan
AU  - Závacká, Anna
AU  - Rakočević, Zlatko Lj.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8587
AB  - Fe/Polyethylene nanocomposite was synthesized by ion beam implantation of 56Fe+ into bulk high-density polyethylene. Nanoscale surface morphology along with magnetic and optical behavior was investigated. The aim of the research was to investigate changes of polyethylene's surface layer morphology with the change of Fe implantation fluence in the high fluence range and to find correlations with the magnetic and optical behavior. Four implantation fluences were applied: 5 × 1016, 1 × 1017, 2 × 1017 and 5 × 1017 cm−2, while the implantation energy was 95 keV. Concentration profiles of implanted Fe were analyzed by Rutherford backscattering spectrometry, showing Fe concentration profile maxima closer to the surface with increasing implantation fluence. Cross-sectional transmission electron microscopy showed the formation of metallic nanoparticles with sizes in a range from below 1 nm up to few tens of nanometers, depending on the fluence, and for the highest implantation fluence, a continuous layer was formed. Magneto-optic Kerr effect magnetometry demonstrates weak ferromagnetic behavior for the 2 higher fluences, and superparamagnetic for the 2 lower fluences. The UV-VIS remission function spectra show the peak in the UV region, which we attribute to iron nanoparticles.
T2  - Vacuum
T1  - Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior
VL  - 171
SP  - 109016
DO  - 10.1016/j.vacuum.2019.109016
ER  - 
@article{
author = "Kisić, Danilo and Nenadović, Miloš and Potočnik, Jelena and Novaković, Mirjana M. and Noga, Pavol and Vaňa, Dušan and Závacká, Anna and Rakočević, Zlatko Lj.",
year = "2020",
abstract = "Fe/Polyethylene nanocomposite was synthesized by ion beam implantation of 56Fe+ into bulk high-density polyethylene. Nanoscale surface morphology along with magnetic and optical behavior was investigated. The aim of the research was to investigate changes of polyethylene's surface layer morphology with the change of Fe implantation fluence in the high fluence range and to find correlations with the magnetic and optical behavior. Four implantation fluences were applied: 5 × 1016, 1 × 1017, 2 × 1017 and 5 × 1017 cm−2, while the implantation energy was 95 keV. Concentration profiles of implanted Fe were analyzed by Rutherford backscattering spectrometry, showing Fe concentration profile maxima closer to the surface with increasing implantation fluence. Cross-sectional transmission electron microscopy showed the formation of metallic nanoparticles with sizes in a range from below 1 nm up to few tens of nanometers, depending on the fluence, and for the highest implantation fluence, a continuous layer was formed. Magneto-optic Kerr effect magnetometry demonstrates weak ferromagnetic behavior for the 2 higher fluences, and superparamagnetic for the 2 lower fluences. The UV-VIS remission function spectra show the peak in the UV region, which we attribute to iron nanoparticles.",
journal = "Vacuum",
title = "Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior",
volume = "171",
pages = "109016",
doi = "10.1016/j.vacuum.2019.109016"
}
Kisić, D., Nenadović, M., Potočnik, J., Novaković, M. M., Noga, P., Vaňa, D., Závacká, A.,& Rakočević, Z. Lj.. (2020). Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior. in Vacuum, 171, 109016.
https://doi.org/10.1016/j.vacuum.2019.109016
Kisić D, Nenadović M, Potočnik J, Novaković MM, Noga P, Vaňa D, Závacká A, Rakočević ZL. Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior. in Vacuum. 2020;171:109016.
doi:10.1016/j.vacuum.2019.109016 .
Kisić, Danilo, Nenadović, Miloš, Potočnik, Jelena, Novaković, Mirjana M., Noga, Pavol, Vaňa, Dušan, Závacká, Anna, Rakočević, Zlatko Lj., "Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior" in Vacuum, 171 (2020):109016,
https://doi.org/10.1016/j.vacuum.2019.109016 . .
3
3
4

Low total electron yield graphene coatings produced by electrophoretic deposition

Aguincha, R.; Bundaleski, Nenad; Bundaleska, N; Novaković, Mirjana M.; Henriques, Julio A. P.; Rakočević, Zlatko Lj.; Tatarova, Elena; Teodoro, Orlando M. N. D.

(2020)

TY  - JOUR
AU  - Aguincha, R.
AU  - Bundaleski, Nenad
AU  - Bundaleska, N
AU  - Novaković, Mirjana M.
AU  - Henriques, Julio A. P.
AU  - Rakočević, Zlatko Lj.
AU  - Tatarova, Elena
AU  - Teodoro, Orlando M. N. D.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8616
AB  - Stainless steel and copper technical substrates have been coated by free standing graphene using electrophoretic deposition technique, with the final goal to obtain chemically inert low secondary electron emission surfaces. This class of materials is of utmost interest in future accelerators in order to increase further the flux of accelerated charged particles in the beam. The measured maximum total electron yield of pristine graphene, which has been previously characterized by electron microscopies and X-ray photoelectron spectroscopy, appears to be about 1.0. The deposition parameters have been optimized in order to obtain surfaces with lowest total electron yield, but also composition and morphology close to that of pristine graphene. When applying these optimized deposition parameters graphene coatings on two substrates, i.e. stainless steel and copper, the maximum total electron yield of about 1.04 was obtained. The composition of coatings and the relative amounts of sp2 bonds are slightly worse than those of the pristine graphene, while the surface morphology appears to be the same. Annealing at 150 °C for 64 h in high vacuum, showed that vacuum baking did not affect considerably the electron emission properties of the coatings. © 2019 Elsevier B.V.
T2  - Applied Surface Science
T1  - Low total electron yield graphene coatings produced by electrophoretic deposition
VL  - 504
SP  - 143870
DO  - 10.1016/j.apsusc.2019.143870
ER  - 
@article{
author = "Aguincha, R. and Bundaleski, Nenad and Bundaleska, N and Novaković, Mirjana M. and Henriques, Julio A. P. and Rakočević, Zlatko Lj. and Tatarova, Elena and Teodoro, Orlando M. N. D.",
year = "2020",
abstract = "Stainless steel and copper technical substrates have been coated by free standing graphene using electrophoretic deposition technique, with the final goal to obtain chemically inert low secondary electron emission surfaces. This class of materials is of utmost interest in future accelerators in order to increase further the flux of accelerated charged particles in the beam. The measured maximum total electron yield of pristine graphene, which has been previously characterized by electron microscopies and X-ray photoelectron spectroscopy, appears to be about 1.0. The deposition parameters have been optimized in order to obtain surfaces with lowest total electron yield, but also composition and morphology close to that of pristine graphene. When applying these optimized deposition parameters graphene coatings on two substrates, i.e. stainless steel and copper, the maximum total electron yield of about 1.04 was obtained. The composition of coatings and the relative amounts of sp2 bonds are slightly worse than those of the pristine graphene, while the surface morphology appears to be the same. Annealing at 150 °C for 64 h in high vacuum, showed that vacuum baking did not affect considerably the electron emission properties of the coatings. © 2019 Elsevier B.V.",
journal = "Applied Surface Science",
title = "Low total electron yield graphene coatings produced by electrophoretic deposition",
volume = "504",
pages = "143870",
doi = "10.1016/j.apsusc.2019.143870"
}
Aguincha, R., Bundaleski, N., Bundaleska, N., Novaković, M. M., Henriques, J. A. P., Rakočević, Z. Lj., Tatarova, E.,& Teodoro, O. M. N. D.. (2020). Low total electron yield graphene coatings produced by electrophoretic deposition. in Applied Surface Science, 504, 143870.
https://doi.org/10.1016/j.apsusc.2019.143870
Aguincha R, Bundaleski N, Bundaleska N, Novaković MM, Henriques JAP, Rakočević ZL, Tatarova E, Teodoro OMND. Low total electron yield graphene coatings produced by electrophoretic deposition. in Applied Surface Science. 2020;504:143870.
doi:10.1016/j.apsusc.2019.143870 .
Aguincha, R., Bundaleski, Nenad, Bundaleska, N, Novaković, Mirjana M., Henriques, Julio A. P., Rakočević, Zlatko Lj., Tatarova, Elena, Teodoro, Orlando M. N. D., "Low total electron yield graphene coatings produced by electrophoretic deposition" in Applied Surface Science, 504 (2020):143870,
https://doi.org/10.1016/j.apsusc.2019.143870 . .
13
3
12

Performances of ionic liquid matrices with butyl ammonium counterion for matrix-assisted laser desorption/ionization mass spectrometric detection and analysis of sucralfate

Petković, Marijana; Leopold, Jenny; Popović, Iva A.; Dimić, Dušan; Ilić, Jelica; Nenadović, Miloš; Rakočević, Zlatko Lj.; Schiller, Jürgen

(2020)

TY  - JOUR
AU  - Petković, Marijana
AU  - Leopold, Jenny
AU  - Popović, Iva A.
AU  - Dimić, Dušan
AU  - Ilić, Jelica
AU  - Nenadović, Miloš
AU  - Rakočević, Zlatko Lj.
AU  - Schiller, Jürgen
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8623
AB  - In this work, the performances of two ionic liquid matrices (ILMs) with the same ammonium counterpart for mass spectrometric analysis of the insoluble and soluble sucralfate were compared. Matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) was performed assisted by the butylammonium salts of α-cyano-hydroxycinnamic acid (CHCAB) and 2,5-dihydroxybenzoic acid (DHBB). CHCAB has a higher IE than DHBB, but better optical properties. CHCAB is more suitable for the analysis of sucralfate, although molecular ions of both compounds were detectable only with low intensities. Thus, optical properties of ILMs are crucial to enhance the sensitivity of MALDI MS detection of polysulfated oligosaccharides. © 2019, © 2019 Taylor & Francis Group, LLC.
T2  - Journal of Carbohydrate Chemistry
T1  - Performances of ionic liquid matrices with butyl ammonium counterion for matrix-assisted laser desorption/ionization mass spectrometric detection and analysis of sucralfate
VL  - 39
IS  - 1
SP  - 1
EP  - 23
DO  - 10.1080/07328303.2019.1669633
ER  - 
@article{
author = "Petković, Marijana and Leopold, Jenny and Popović, Iva A. and Dimić, Dušan and Ilić, Jelica and Nenadović, Miloš and Rakočević, Zlatko Lj. and Schiller, Jürgen",
year = "2020",
abstract = "In this work, the performances of two ionic liquid matrices (ILMs) with the same ammonium counterpart for mass spectrometric analysis of the insoluble and soluble sucralfate were compared. Matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) was performed assisted by the butylammonium salts of α-cyano-hydroxycinnamic acid (CHCAB) and 2,5-dihydroxybenzoic acid (DHBB). CHCAB has a higher IE than DHBB, but better optical properties. CHCAB is more suitable for the analysis of sucralfate, although molecular ions of both compounds were detectable only with low intensities. Thus, optical properties of ILMs are crucial to enhance the sensitivity of MALDI MS detection of polysulfated oligosaccharides. © 2019, © 2019 Taylor & Francis Group, LLC.",
journal = "Journal of Carbohydrate Chemistry",
title = "Performances of ionic liquid matrices with butyl ammonium counterion for matrix-assisted laser desorption/ionization mass spectrometric detection and analysis of sucralfate",
volume = "39",
number = "1",
pages = "1-23",
doi = "10.1080/07328303.2019.1669633"
}
Petković, M., Leopold, J., Popović, I. A., Dimić, D., Ilić, J., Nenadović, M., Rakočević, Z. Lj.,& Schiller, J.. (2020). Performances of ionic liquid matrices with butyl ammonium counterion for matrix-assisted laser desorption/ionization mass spectrometric detection and analysis of sucralfate. in Journal of Carbohydrate Chemistry, 39(1), 1-23.
https://doi.org/10.1080/07328303.2019.1669633
Petković M, Leopold J, Popović IA, Dimić D, Ilić J, Nenadović M, Rakočević ZL, Schiller J. Performances of ionic liquid matrices with butyl ammonium counterion for matrix-assisted laser desorption/ionization mass spectrometric detection and analysis of sucralfate. in Journal of Carbohydrate Chemistry. 2020;39(1):1-23.
doi:10.1080/07328303.2019.1669633 .
Petković, Marijana, Leopold, Jenny, Popović, Iva A., Dimić, Dušan, Ilić, Jelica, Nenadović, Miloš, Rakočević, Zlatko Lj., Schiller, Jürgen, "Performances of ionic liquid matrices with butyl ammonium counterion for matrix-assisted laser desorption/ionization mass spectrometric detection and analysis of sucralfate" in Journal of Carbohydrate Chemistry, 39, no. 1 (2020):1-23,
https://doi.org/10.1080/07328303.2019.1669633 . .
8
7

Modification of polyethylene’s surface properties by high fluence Fe implantation

Kisić, Danilo; Nenadović, Miloš; Barudžija, Tanja; Noga, Pavol; Vaňa, Dušan; Muška, Martin; Rakočević, Zlatko Lj.

(2020)

TY  - JOUR
AU  - Kisić, Danilo
AU  - Nenadović, Miloš
AU  - Barudžija, Tanja
AU  - Noga, Pavol
AU  - Vaňa, Dušan
AU  - Muška, Martin
AU  - Rakočević, Zlatko Lj.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8646
AB  - In the presented paper, changes of high-density polyethylene's (HDPE) surface properties along with the changes of chemical composition, as a consequence of Fe ion implantation with different fluences, were investigated. Applied implantation fluences were as follows: 5 × 1016, 1 × 1017, 2 × 1017 and 5 × 1017 ions cm−2, while the implantation energy was 95 keV. The samples were analyzed by X-ray photoelectron spectroscopy (XPS), Atomic Force Microscopy (AFM), Four point contact probe, Fourier transform infrared spectroscopy (FTIR) and contact angle measurements. Significant changes in the chemical composition were found by XPS and FTIR, which were followed by changes in surface morphology, increase of roughness, and decrease of sheet resistance that has a percolation threshold that starts for the fluence of 1 × 1017 ions cm−2. Surface free energy increases as a consequence of implantation, up to the fluence of 1 × 1017 ions cm−2, and then decreases for the 2 higher fluences. © 2019 Elsevier B.V.
T2  - Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
T1  - Modification of polyethylene’s surface properties by high fluence Fe implantation
VL  - 462
SP  - 143
EP  - 153
DO  - 10.1016/j.nimb.2019.11.022
ER  - 
@article{
author = "Kisić, Danilo and Nenadović, Miloš and Barudžija, Tanja and Noga, Pavol and Vaňa, Dušan and Muška, Martin and Rakočević, Zlatko Lj.",
year = "2020",
abstract = "In the presented paper, changes of high-density polyethylene's (HDPE) surface properties along with the changes of chemical composition, as a consequence of Fe ion implantation with different fluences, were investigated. Applied implantation fluences were as follows: 5 × 1016, 1 × 1017, 2 × 1017 and 5 × 1017 ions cm−2, while the implantation energy was 95 keV. The samples were analyzed by X-ray photoelectron spectroscopy (XPS), Atomic Force Microscopy (AFM), Four point contact probe, Fourier transform infrared spectroscopy (FTIR) and contact angle measurements. Significant changes in the chemical composition were found by XPS and FTIR, which were followed by changes in surface morphology, increase of roughness, and decrease of sheet resistance that has a percolation threshold that starts for the fluence of 1 × 1017 ions cm−2. Surface free energy increases as a consequence of implantation, up to the fluence of 1 × 1017 ions cm−2, and then decreases for the 2 higher fluences. © 2019 Elsevier B.V.",
journal = "Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms",
title = "Modification of polyethylene’s surface properties by high fluence Fe implantation",
volume = "462",
pages = "143-153",
doi = "10.1016/j.nimb.2019.11.022"
}
Kisić, D., Nenadović, M., Barudžija, T., Noga, P., Vaňa, D., Muška, M.,& Rakočević, Z. Lj.. (2020). Modification of polyethylene’s surface properties by high fluence Fe implantation. in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 462, 143-153.
https://doi.org/10.1016/j.nimb.2019.11.022
Kisić D, Nenadović M, Barudžija T, Noga P, Vaňa D, Muška M, Rakočević ZL. Modification of polyethylene’s surface properties by high fluence Fe implantation. in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 2020;462:143-153.
doi:10.1016/j.nimb.2019.11.022 .
Kisić, Danilo, Nenadović, Miloš, Barudžija, Tanja, Noga, Pavol, Vaňa, Dušan, Muška, Martin, Rakočević, Zlatko Lj., "Modification of polyethylene’s surface properties by high fluence Fe implantation" in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 462 (2020):143-153,
https://doi.org/10.1016/j.nimb.2019.11.022 . .
4
2
3

XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited

Medić-Ilić, Mirjana; Bundaleski, Nenad; Ivanović, Nenad; Teodoro, Orlando M. N. D.; Rakočević, Zlatko Lj.; Minić, Dragica M.; Romčević, Nebojša Ž.; Radisavljević, Ivana

(2020)

TY  - JOUR
AU  - Medić-Ilić, Mirjana
AU  - Bundaleski, Nenad
AU  - Ivanović, Nenad
AU  - Teodoro, Orlando M. N. D.
AU  - Rakočević, Zlatko Lj.
AU  - Minić, Dragica M.
AU  - Romčević, Nebojša Ž.
AU  - Radisavljević, Ivana
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8910
AB  - Recently introduced model for quantitative analysis of in-depth non-uniform surfaces is applied to reexamine the X-ray Photoelectron Spectroscopy (XPS) data of Cd0.99Fe0.01Te0.97Se0.03 and Zn0.98Fe0.02Te0.91Se0.09 crystalline samples. Special attention is paid to the precise identification of phases which form the bulk-like near-surface region and the surface overlayers (the oxide layer and the layer of organic impurities), as well as the influence of surface morphology on the measurements. The obtained results fully support earlier qualitative estimations, but also provide new quantitative insight into the composition of the three investigated regions. The near-surface region of Cd0.99Fe0.01Te0.97Se0.03 and Zn0.98Fe0.02Te0.91Se0.09 samples is slightly electropositive, with cation/anion ratio 52:48 and 53:47, respectively. Model surface structures, which are fully compatible with the experimental results, comprise 0.76 nm thick CdTeO3 layer at the surface of Cd0.99Fe0.01Te0.97Se0.03 and 0.33 nm thick mixed ZnO/TeO2 oxide layer on Zn0.98Fe0.02Te0.91Se0.09. In both samples the oxide layer is only a few atomic layers thick, implying that it suppresses further rapid migration of oxygen into the bulk.
T2  - Vacuum
T1  - XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited
VL  - 176
SP  - 109340
DO  - 10.1016/j.vacuum.2020.109340
ER  - 
@article{
author = "Medić-Ilić, Mirjana and Bundaleski, Nenad and Ivanović, Nenad and Teodoro, Orlando M. N. D. and Rakočević, Zlatko Lj. and Minić, Dragica M. and Romčević, Nebojša Ž. and Radisavljević, Ivana",
year = "2020",
abstract = "Recently introduced model for quantitative analysis of in-depth non-uniform surfaces is applied to reexamine the X-ray Photoelectron Spectroscopy (XPS) data of Cd0.99Fe0.01Te0.97Se0.03 and Zn0.98Fe0.02Te0.91Se0.09 crystalline samples. Special attention is paid to the precise identification of phases which form the bulk-like near-surface region and the surface overlayers (the oxide layer and the layer of organic impurities), as well as the influence of surface morphology on the measurements. The obtained results fully support earlier qualitative estimations, but also provide new quantitative insight into the composition of the three investigated regions. The near-surface region of Cd0.99Fe0.01Te0.97Se0.03 and Zn0.98Fe0.02Te0.91Se0.09 samples is slightly electropositive, with cation/anion ratio 52:48 and 53:47, respectively. Model surface structures, which are fully compatible with the experimental results, comprise 0.76 nm thick CdTeO3 layer at the surface of Cd0.99Fe0.01Te0.97Se0.03 and 0.33 nm thick mixed ZnO/TeO2 oxide layer on Zn0.98Fe0.02Te0.91Se0.09. In both samples the oxide layer is only a few atomic layers thick, implying that it suppresses further rapid migration of oxygen into the bulk.",
journal = "Vacuum",
title = "XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited",
volume = "176",
pages = "109340",
doi = "10.1016/j.vacuum.2020.109340"
}
Medić-Ilić, M., Bundaleski, N., Ivanović, N., Teodoro, O. M. N. D., Rakočević, Z. Lj., Minić, D. M., Romčević, N. Ž.,& Radisavljević, I.. (2020). XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited. in Vacuum, 176, 109340.
https://doi.org/10.1016/j.vacuum.2020.109340
Medić-Ilić M, Bundaleski N, Ivanović N, Teodoro OMND, Rakočević ZL, Minić DM, Romčević NŽ, Radisavljević I. XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited. in Vacuum. 2020;176:109340.
doi:10.1016/j.vacuum.2020.109340 .
Medić-Ilić, Mirjana, Bundaleski, Nenad, Ivanović, Nenad, Teodoro, Orlando M. N. D., Rakočević, Zlatko Lj., Minić, Dragica M., Romčević, Nebojša Ž., Radisavljević, Ivana, "XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited" in Vacuum, 176 (2020):109340,
https://doi.org/10.1016/j.vacuum.2020.109340 . .
7
7

Origin of photocatalytic activity enhancement in Pd/Pt-deposited anatase N-TiO2-experimental insights and DFT study of the (001) surface

Batalović, Katarina; Radaković, Jana; Bundaleski, Nenad; Rakočević, Zlatko Lj.; Pašti, Igor A.; Skorodumova, Natalia V.; Rangel, Carmen Mireya

(2020)

TY  - JOUR
AU  - Batalović, Katarina
AU  - Radaković, Jana
AU  - Bundaleski, Nenad
AU  - Rakočević, Zlatko Lj.
AU  - Pašti, Igor A.
AU  - Skorodumova, Natalia V.
AU  - Rangel, Carmen Mireya
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9620
AB  - In pursuit of the ideal photocatalyst, cheap and stable semiconductor TiO2 is considered to be a good choice if one is able to reduce its band gap and decrease the recombination rate of charge carriers. The approach that offers such improvements for energy conversion applications is the modification of TiO2 with nitrogen and noble metals. However, the origin of these improvements and possibilities for further design of single-atom catalysts are not always straightforward. To shed light on the atomic-scale picture, we modeled the nitrogen-doped (001) anatase TiO2 surface as a support for palladium and platinum single-atom deposition. The thermodynamics of various synthesis routes for Pd/Pt deposition and nitrogen doping is considered based on density functional theory (DFT)-calculated energies, highlighting the effect of nitrogen doping on metal dimer formation and metal-support interaction. XPS analysis of the valence band of the modified TiO2 nanocrystals, and the calculated charge transfer and electronic structure of single-atom catalysts supported on the (001) anatase TiO2 surface provide an insight into modifications occurring in the valence zone of TiO2 due to nitrogen doping and Pd/Pt deposition at the surface. DFT results also show that substitutional nitrogen doping significantly increases metal-support interaction, while interstitial nitrogen doping promotes only Pt-support interaction. © the Owner Societies.
T2  - Physical Chemistry Chemical Physics
T1  - Origin of photocatalytic activity enhancement in Pd/Pt-deposited anatase N-TiO2-experimental insights and DFT study of the (001) surface
VL  - 22
IS  - 33
SP  - 18536
EP  - 18547
DO  - 10.1039/d0cp03186k
ER  - 
@article{
author = "Batalović, Katarina and Radaković, Jana and Bundaleski, Nenad and Rakočević, Zlatko Lj. and Pašti, Igor A. and Skorodumova, Natalia V. and Rangel, Carmen Mireya",
year = "2020",
abstract = "In pursuit of the ideal photocatalyst, cheap and stable semiconductor TiO2 is considered to be a good choice if one is able to reduce its band gap and decrease the recombination rate of charge carriers. The approach that offers such improvements for energy conversion applications is the modification of TiO2 with nitrogen and noble metals. However, the origin of these improvements and possibilities for further design of single-atom catalysts are not always straightforward. To shed light on the atomic-scale picture, we modeled the nitrogen-doped (001) anatase TiO2 surface as a support for palladium and platinum single-atom deposition. The thermodynamics of various synthesis routes for Pd/Pt deposition and nitrogen doping is considered based on density functional theory (DFT)-calculated energies, highlighting the effect of nitrogen doping on metal dimer formation and metal-support interaction. XPS analysis of the valence band of the modified TiO2 nanocrystals, and the calculated charge transfer and electronic structure of single-atom catalysts supported on the (001) anatase TiO2 surface provide an insight into modifications occurring in the valence zone of TiO2 due to nitrogen doping and Pd/Pt deposition at the surface. DFT results also show that substitutional nitrogen doping significantly increases metal-support interaction, while interstitial nitrogen doping promotes only Pt-support interaction. © the Owner Societies.",
journal = "Physical Chemistry Chemical Physics",
title = "Origin of photocatalytic activity enhancement in Pd/Pt-deposited anatase N-TiO2-experimental insights and DFT study of the (001) surface",
volume = "22",
number = "33",
pages = "18536-18547",
doi = "10.1039/d0cp03186k"
}
Batalović, K., Radaković, J., Bundaleski, N., Rakočević, Z. Lj., Pašti, I. A., Skorodumova, N. V.,& Rangel, C. M.. (2020). Origin of photocatalytic activity enhancement in Pd/Pt-deposited anatase N-TiO2-experimental insights and DFT study of the (001) surface. in Physical Chemistry Chemical Physics, 22(33), 18536-18547.
https://doi.org/10.1039/d0cp03186k
Batalović K, Radaković J, Bundaleski N, Rakočević ZL, Pašti IA, Skorodumova NV, Rangel CM. Origin of photocatalytic activity enhancement in Pd/Pt-deposited anatase N-TiO2-experimental insights and DFT study of the (001) surface. in Physical Chemistry Chemical Physics. 2020;22(33):18536-18547.
doi:10.1039/d0cp03186k .
Batalović, Katarina, Radaković, Jana, Bundaleski, Nenad, Rakočević, Zlatko Lj., Pašti, Igor A., Skorodumova, Natalia V., Rangel, Carmen Mireya, "Origin of photocatalytic activity enhancement in Pd/Pt-deposited anatase N-TiO2-experimental insights and DFT study of the (001) surface" in Physical Chemistry Chemical Physics, 22, no. 33 (2020):18536-18547,
https://doi.org/10.1039/d0cp03186k . .
1
5
1
5

Interactions of moving charge with supported graphene in the presence of strain-induced pseudomagnetic field

He, Xian-Long; Zhang, Ying-Ying; Mišković, Zoran L.; Radović, Ivan; Li, Chun-Zhi; Song, Yuan-Hong

(2020)

TY  - JOUR
AU  - He, Xian-Long
AU  - Zhang, Ying-Ying
AU  - Mišković, Zoran L.
AU  - Radović, Ivan
AU  - Li, Chun-Zhi
AU  - Song, Yuan-Hong
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8477
AB  - Abstract: A two-component hydrodynamic model is used to investigate low-energy plasmon excitations within the K and K′ valleys of the π electron bands in doped graphene on a dielectric substrate by a slow charged particle moving parallel to the graphene in the presence of a strain-induced pseudomagnetic field in graphene. Calculations of the stopping and the image forces on the moving charge, as well as of the total electrostatic potential in the plane of graphene are performed. The simulation results indicate that the valley polarization of electrons in graphene resulting from the pseudomagnetic field and the electrostatic coupling between graphene and the supporting substrate both have important impact on the stopping and the image forces, affecting the maximum values and the peak positions of those forces, as well as the velocity threshold for the plasmon excitation. In addition, we also study the dependence of the amplitude and period of the wake potential oscillations on the pseudomagnetic field strength, the gap size between graphene and substrate, as well as the incident particle speed. In particular, our results show that the pseudomagnetic field exerts quite strong influence on the period of the wake potential oscillations at the above-threshold particle speeds, especially for small graphene-substrate gap sizes. Graphical abstract: [Figure not available: see fulltext.] © 2020, EDP Sciences / Società Italiana di Fisica / Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - European Physical Journal D. Atoms, Molecules, Clusters and Optical Physics
T1  - Interactions of moving charge with supported graphene in the presence of strain-induced pseudomagnetic field
VL  - 74
IS  - 1
SP  - 18
DO  - 10.1140/epjd/e2019-100450-1
ER  - 
@article{
author = "He, Xian-Long and Zhang, Ying-Ying and Mišković, Zoran L. and Radović, Ivan and Li, Chun-Zhi and Song, Yuan-Hong",
year = "2020",
abstract = "Abstract: A two-component hydrodynamic model is used to investigate low-energy plasmon excitations within the K and K′ valleys of the π electron bands in doped graphene on a dielectric substrate by a slow charged particle moving parallel to the graphene in the presence of a strain-induced pseudomagnetic field in graphene. Calculations of the stopping and the image forces on the moving charge, as well as of the total electrostatic potential in the plane of graphene are performed. The simulation results indicate that the valley polarization of electrons in graphene resulting from the pseudomagnetic field and the electrostatic coupling between graphene and the supporting substrate both have important impact on the stopping and the image forces, affecting the maximum values and the peak positions of those forces, as well as the velocity threshold for the plasmon excitation. In addition, we also study the dependence of the amplitude and period of the wake potential oscillations on the pseudomagnetic field strength, the gap size between graphene and substrate, as well as the incident particle speed. In particular, our results show that the pseudomagnetic field exerts quite strong influence on the period of the wake potential oscillations at the above-threshold particle speeds, especially for small graphene-substrate gap sizes. Graphical abstract: [Figure not available: see fulltext.] © 2020, EDP Sciences / Società Italiana di Fisica / Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "European Physical Journal D. Atoms, Molecules, Clusters and Optical Physics",
title = "Interactions of moving charge with supported graphene in the presence of strain-induced pseudomagnetic field",
volume = "74",
number = "1",
pages = "18",
doi = "10.1140/epjd/e2019-100450-1"
}
He, X., Zhang, Y., Mišković, Z. L., Radović, I., Li, C.,& Song, Y.. (2020). Interactions of moving charge with supported graphene in the presence of strain-induced pseudomagnetic field. in European Physical Journal D. Atoms, Molecules, Clusters and Optical Physics, 74(1), 18.
https://doi.org/10.1140/epjd/e2019-100450-1
He X, Zhang Y, Mišković ZL, Radović I, Li C, Song Y. Interactions of moving charge with supported graphene in the presence of strain-induced pseudomagnetic field. in European Physical Journal D. Atoms, Molecules, Clusters and Optical Physics. 2020;74(1):18.
doi:10.1140/epjd/e2019-100450-1 .
He, Xian-Long, Zhang, Ying-Ying, Mišković, Zoran L., Radović, Ivan, Li, Chun-Zhi, Song, Yuan-Hong, "Interactions of moving charge with supported graphene in the presence of strain-induced pseudomagnetic field" in European Physical Journal D. Atoms, Molecules, Clusters and Optical Physics, 74, no. 1 (2020):18,
https://doi.org/10.1140/epjd/e2019-100450-1 . .
3
2
3

Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization

Dodevski, Vladimir; Pagnacco, Maja C.; Radović, Ivana M.; Rosić, Milena; Janković, Bojan Ž.; Stojmenović, Marija; Mitić, Vojislav V.

(2020)

TY  - JOUR
AU  - Dodevski, Vladimir
AU  - Pagnacco, Maja C.
AU  - Radović, Ivana M.
AU  - Rosić, Milena
AU  - Janković, Bojan Ž.
AU  - Stojmenović, Marija
AU  - Mitić, Vojislav V.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8817
AB  - The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.
T2  - Materials Chemistry and Physics
T1  - Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization
VL  - 245
SP  - 122768
DO  - 10.1016/j.matchemphys.2020.122768
ER  - 
@article{
author = "Dodevski, Vladimir and Pagnacco, Maja C. and Radović, Ivana M. and Rosić, Milena and Janković, Bojan Ž. and Stojmenović, Marija and Mitić, Vojislav V.",
year = "2020",
abstract = "The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.",
journal = "Materials Chemistry and Physics",
title = "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization",
volume = "245",
pages = "122768",
doi = "10.1016/j.matchemphys.2020.122768"
}
Dodevski, V., Pagnacco, M. C., Radović, I. M., Rosić, M., Janković, B. Ž., Stojmenović, M.,& Mitić, V. V.. (2020). Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics, 245, 122768.
https://doi.org/10.1016/j.matchemphys.2020.122768
Dodevski V, Pagnacco MC, Radović IM, Rosić M, Janković BŽ, Stojmenović M, Mitić VV. Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics. 2020;245:122768.
doi:10.1016/j.matchemphys.2020.122768 .
Dodevski, Vladimir, Pagnacco, Maja C., Radović, Ivana M., Rosić, Milena, Janković, Bojan Ž., Stojmenović, Marija, Mitić, Vojislav V., "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization" in Materials Chemistry and Physics, 245 (2020):122768,
https://doi.org/10.1016/j.matchemphys.2020.122768 . .
1
10
4
9

Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds

Dodevski, Vladimir; Janković, Bojan Ž.; Radović, Ivana M.; Stojmenović, Marija; Čebela, Maria; Nikolić, Željka; Pagnacco, Maja C.; Panić, Ivan; Stanković, Miroslav

(2020)

TY  - JOUR
AU  - Dodevski, Vladimir
AU  - Janković, Bojan Ž.
AU  - Radović, Ivana M.
AU  - Stojmenović, Marija
AU  - Čebela, Maria
AU  - Nikolić, Željka
AU  - Pagnacco, Maja C.
AU  - Panić, Ivan
AU  - Stanković, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8900
AB  - In this work, plane tree seed-based activated carbons were characterized in detail for a variety of applications. The particularly important area of application would be in the artificial photosynthesis. After carbonization process of biomass precursor at 650°C, the resulting preliminary activated carbons were activated at various temperatures. The activated carbons were characterized by oxygen functionalities (a particularly important role has ester oxygen groups) which provide a unique microstructure. The chemical compositions of as-prepared activated carbons were analyzed through Fourier transform infrared and Raman spectra as well as gas chromatography–mass spectroscopy analysis, while morphology was observed by scanning electron microscopy analysis. Applied analysis showed that detected graphite mainly becomes uniformly nanocrystalline system. The current study also explored the applicability of carbon material obtained from plane tree seed as a potential gaseous adsorbent. The characterization showed that the tested material contains both mesopores and micropores, and this should be advantageous for the gas sorption process, since mesopores may provide low-resistant pathways for the diffusion of CO 2 molecules, while the micropores are the most suitable for trapping of CO 2 . The sorption process analysis (including adsorption/desorption isotherms behavior) shows indication that the rate-limiting step of CO 2 adsorption onto activated carbon is probably governed by diffusion-controlled process, especially at temperatures below 850°C.
T2  - Energy and Environment
T1  - Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds
VL  - 31
IS  - 4
SP  - 583
EP  - 612
DO  - 10.1177/0958305X19880878
ER  - 
@article{
author = "Dodevski, Vladimir and Janković, Bojan Ž. and Radović, Ivana M. and Stojmenović, Marija and Čebela, Maria and Nikolić, Željka and Pagnacco, Maja C. and Panić, Ivan and Stanković, Miroslav",
year = "2020",
abstract = "In this work, plane tree seed-based activated carbons were characterized in detail for a variety of applications. The particularly important area of application would be in the artificial photosynthesis. After carbonization process of biomass precursor at 650°C, the resulting preliminary activated carbons were activated at various temperatures. The activated carbons were characterized by oxygen functionalities (a particularly important role has ester oxygen groups) which provide a unique microstructure. The chemical compositions of as-prepared activated carbons were analyzed through Fourier transform infrared and Raman spectra as well as gas chromatography–mass spectroscopy analysis, while morphology was observed by scanning electron microscopy analysis. Applied analysis showed that detected graphite mainly becomes uniformly nanocrystalline system. The current study also explored the applicability of carbon material obtained from plane tree seed as a potential gaseous adsorbent. The characterization showed that the tested material contains both mesopores and micropores, and this should be advantageous for the gas sorption process, since mesopores may provide low-resistant pathways for the diffusion of CO 2 molecules, while the micropores are the most suitable for trapping of CO 2 . The sorption process analysis (including adsorption/desorption isotherms behavior) shows indication that the rate-limiting step of CO 2 adsorption onto activated carbon is probably governed by diffusion-controlled process, especially at temperatures below 850°C.",
journal = "Energy and Environment",
title = "Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds",
volume = "31",
number = "4",
pages = "583-612",
doi = "10.1177/0958305X19880878"
}
Dodevski, V., Janković, B. Ž., Radović, I. M., Stojmenović, M., Čebela, M., Nikolić, Ž., Pagnacco, M. C., Panić, I.,& Stanković, M.. (2020). Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds. in Energy and Environment, 31(4), 583-612.
https://doi.org/10.1177/0958305X19880878
Dodevski V, Janković BŽ, Radović IM, Stojmenović M, Čebela M, Nikolić Ž, Pagnacco MC, Panić I, Stanković M. Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds. in Energy and Environment. 2020;31(4):583-612.
doi:10.1177/0958305X19880878 .
Dodevski, Vladimir, Janković, Bojan Ž., Radović, Ivana M., Stojmenović, Marija, Čebela, Maria, Nikolić, Željka, Pagnacco, Maja C., Panić, Ivan, Stanković, Miroslav, "Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds" in Energy and Environment, 31, no. 4 (2020):583-612,
https://doi.org/10.1177/0958305X19880878 . .
8
2
8

Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application

Dodevski, Vladimir; Janković, Bojan Ž.; Mirković, Miljana M.; Kragović, Milan M.; Radović, Ivana M.; Veljković, Filip M.; Stojmenović, Marija

(2020)

TY  - JOUR
AU  - Dodevski, Vladimir
AU  - Janković, Bojan Ž.
AU  - Mirković, Miljana M.
AU  - Kragović, Milan M.
AU  - Radović, Ivana M.
AU  - Veljković, Filip M.
AU  - Stojmenović, Marija
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8922
AB  - Goal of this work is to establish technical feasibility and fundamentals of producing activated carbon from plane tree seeds biomass for porous materials derivation. Bio-chars produced via carbonization from plane tree seeds precursor were activated in CO2 at 750 and 850?C, during various residence times. Their surface area and porosity were characterized by N2 adsorption at 77 K. Surface areas of activated carbons can be correlated with kinetics mechanism and activation energy magnitudes of oxidation reaction by CO2, which are closely related to applied activation temperature. Result showed that high temperature activated carbon had higher gas adsorption as compared to activated carbon obtained from lower temperature during two-hour residence time. Breakthrough behavior was detected at 850?C where surface reactions dominate, and it is characterized by autocatalytic kinetic model under designed conditions. Both, temperature and CO2 concentration in vicinity of solid surface effect on breakthrough time of adsorbent. Derived bio-chars are converted into high quality activated carbons, with surface area of 776.55 m2/g, where micro-pores with pore diameters less than 2 nm prevail. Produced activated carbons have properties comparable with commercially available activated carbons, which can be successfully used for removal of harmful gaseous pollutants toward air purification.
T2  - Thermal Science
T1  - Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application
VL  - 24
IS  - 6 (Part A)
SP  - 3807
EP  - 3821
DO  - 10.2298/TSCI190913064D
ER  - 
@article{
author = "Dodevski, Vladimir and Janković, Bojan Ž. and Mirković, Miljana M. and Kragović, Milan M. and Radović, Ivana M. and Veljković, Filip M. and Stojmenović, Marija",
year = "2020",
abstract = "Goal of this work is to establish technical feasibility and fundamentals of producing activated carbon from plane tree seeds biomass for porous materials derivation. Bio-chars produced via carbonization from plane tree seeds precursor were activated in CO2 at 750 and 850?C, during various residence times. Their surface area and porosity were characterized by N2 adsorption at 77 K. Surface areas of activated carbons can be correlated with kinetics mechanism and activation energy magnitudes of oxidation reaction by CO2, which are closely related to applied activation temperature. Result showed that high temperature activated carbon had higher gas adsorption as compared to activated carbon obtained from lower temperature during two-hour residence time. Breakthrough behavior was detected at 850?C where surface reactions dominate, and it is characterized by autocatalytic kinetic model under designed conditions. Both, temperature and CO2 concentration in vicinity of solid surface effect on breakthrough time of adsorbent. Derived bio-chars are converted into high quality activated carbons, with surface area of 776.55 m2/g, where micro-pores with pore diameters less than 2 nm prevail. Produced activated carbons have properties comparable with commercially available activated carbons, which can be successfully used for removal of harmful gaseous pollutants toward air purification.",
journal = "Thermal Science",
title = "Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application",
volume = "24",
number = "6 (Part A)",
pages = "3807-3821",
doi = "10.2298/TSCI190913064D"
}
Dodevski, V., Janković, B. Ž., Mirković, M. M., Kragović, M. M., Radović, I. M., Veljković, F. M.,& Stojmenović, M.. (2020). Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application. in Thermal Science, 24(6 (Part A)), 3807-3821.
https://doi.org/10.2298/TSCI190913064D
Dodevski V, Janković BŽ, Mirković MM, Kragović MM, Radović IM, Veljković FM, Stojmenović M. Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application. in Thermal Science. 2020;24(6 (Part A)):3807-3821.
doi:10.2298/TSCI190913064D .
Dodevski, Vladimir, Janković, Bojan Ž., Mirković, Miljana M., Kragović, Milan M., Radović, Ivana M., Veljković, Filip M., Stojmenović, Marija, "Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application" in Thermal Science, 24, no. 6 (Part A) (2020):3807-3821,
https://doi.org/10.2298/TSCI190913064D . .
1
1

Developing a novel resorptive hydroxyapatite-based bone substitute for over-critical size defect reconstruction: Physicochemical and biological characterization and proof of concept in segmental rabbit's ulna reconstruction

Micić, Milutin; Antonijević, Đorđe; Milutinović-Smiljanić, Sanja; Trišić, Dijana; Čolović, Božana M.; Kosanović, Dejana; Prokić, Bogomir Bolka; Vasić, Jugoslav; Živković, Slavoljub; Milašin, Jelena; Danilović, Vesna; Đurić, Marija P.; Jokanović, Vukoman R.

(2020)

TY  - JOUR
AU  - Micić, Milutin
AU  - Antonijević, Đorđe
AU  - Milutinović-Smiljanić, Sanja
AU  - Trišić, Dijana
AU  - Čolović, Božana M.
AU  - Kosanović, Dejana
AU  - Prokić, Bogomir Bolka
AU  - Vasić, Jugoslav
AU  - Živković, Slavoljub
AU  - Milašin, Jelena
AU  - Danilović, Vesna
AU  - Đurić, Marija P.
AU  - Jokanović, Vukoman R.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8993
AB  - The aim of this study was to develop novel hydroxyapatite (HAP)-based bioactive bone replacement materials for segmental osteotomy reconstruction. Customized three-dimensional (3D) bone construct was manufactured from nanohydroxyapatite (nHAP) with poly(lactide-co-glycolide) (PLGA) coating using 3D models derived from the computed tomography (CT) scanning of the rabbit's ulna and gradient 3D printing of the bone substitute mimicking the anatomical shape of the natural bone defect. Engineered construct revealed adequate micro-architectural design for successful bone regeneration having a total porosity of 64% and an average pore size of 256 μm. Radiography and micro-CT analysis depicted new bone apposition through the whole length of the reconstructed ulna with a small area of non-resorbed construct in the central area of defect. Histological analysis revealed new bone formation with both endochondral and endesmal type of ossification. Immunohistochemistry analysis depicted the presence of bone formation indicators-bone morphogenetic protein (BMP), osteocalcin (OCN) and osteopontin (OPN) within newly formed bone. Manufactured personalized construct acts as a "smart" responsive biomaterial capable of modulating the functionality and potential for the personalized bone reconstruction on a clinically relevant length scale.
T2  - Biomedizinische Technik
T1  - Developing a novel resorptive hydroxyapatite-based bone substitute for over-critical size defect reconstruction: Physicochemical and biological characterization and proof of concept in segmental rabbit's ulna reconstruction
VL  - 65
IS  - 4
SP  - 491
EP  - 505
DO  - 10.1515/bmt-2019-0218
ER  - 
@article{
author = "Micić, Milutin and Antonijević, Đorđe and Milutinović-Smiljanić, Sanja and Trišić, Dijana and Čolović, Božana M. and Kosanović, Dejana and Prokić, Bogomir Bolka and Vasić, Jugoslav and Živković, Slavoljub and Milašin, Jelena and Danilović, Vesna and Đurić, Marija P. and Jokanović, Vukoman R.",
year = "2020",
abstract = "The aim of this study was to develop novel hydroxyapatite (HAP)-based bioactive bone replacement materials for segmental osteotomy reconstruction. Customized three-dimensional (3D) bone construct was manufactured from nanohydroxyapatite (nHAP) with poly(lactide-co-glycolide) (PLGA) coating using 3D models derived from the computed tomography (CT) scanning of the rabbit's ulna and gradient 3D printing of the bone substitute mimicking the anatomical shape of the natural bone defect. Engineered construct revealed adequate micro-architectural design for successful bone regeneration having a total porosity of 64% and an average pore size of 256 μm. Radiography and micro-CT analysis depicted new bone apposition through the whole length of the reconstructed ulna with a small area of non-resorbed construct in the central area of defect. Histological analysis revealed new bone formation with both endochondral and endesmal type of ossification. Immunohistochemistry analysis depicted the presence of bone formation indicators-bone morphogenetic protein (BMP), osteocalcin (OCN) and osteopontin (OPN) within newly formed bone. Manufactured personalized construct acts as a "smart" responsive biomaterial capable of modulating the functionality and potential for the personalized bone reconstruction on a clinically relevant length scale.",
journal = "Biomedizinische Technik",
title = "Developing a novel resorptive hydroxyapatite-based bone substitute for over-critical size defect reconstruction: Physicochemical and biological characterization and proof of concept in segmental rabbit's ulna reconstruction",
volume = "65",
number = "4",
pages = "491-505",
doi = "10.1515/bmt-2019-0218"
}
Micić, M., Antonijević, Đ., Milutinović-Smiljanić, S., Trišić, D., Čolović, B. M., Kosanović, D., Prokić, B. B., Vasić, J., Živković, S., Milašin, J., Danilović, V., Đurić, M. P.,& Jokanović, V. R.. (2020). Developing a novel resorptive hydroxyapatite-based bone substitute for over-critical size defect reconstruction: Physicochemical and biological characterization and proof of concept in segmental rabbit's ulna reconstruction. in Biomedizinische Technik, 65(4), 491-505.
https://doi.org/10.1515/bmt-2019-0218
Micić M, Antonijević Đ, Milutinović-Smiljanić S, Trišić D, Čolović BM, Kosanović D, Prokić BB, Vasić J, Živković S, Milašin J, Danilović V, Đurić MP, Jokanović VR. Developing a novel resorptive hydroxyapatite-based bone substitute for over-critical size defect reconstruction: Physicochemical and biological characterization and proof of concept in segmental rabbit's ulna reconstruction. in Biomedizinische Technik. 2020;65(4):491-505.
doi:10.1515/bmt-2019-0218 .
Micić, Milutin, Antonijević, Đorđe, Milutinović-Smiljanić, Sanja, Trišić, Dijana, Čolović, Božana M., Kosanović, Dejana, Prokić, Bogomir Bolka, Vasić, Jugoslav, Živković, Slavoljub, Milašin, Jelena, Danilović, Vesna, Đurić, Marija P., Jokanović, Vukoman R., "Developing a novel resorptive hydroxyapatite-based bone substitute for over-critical size defect reconstruction: Physicochemical and biological characterization and proof of concept in segmental rabbit's ulna reconstruction" in Biomedizinische Technik, 65, no. 4 (2020):491-505,
https://doi.org/10.1515/bmt-2019-0218 . .
11
1
8

Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)

Manić, Nebojša G.; Janković, Bojan Ž.; Pijović, Milena; Waisi, Hadi; Dodevski, Vladimir; Stojiljković, Dragoslava; Jovanović, Vladimir V.

(2020)

TY  - JOUR
AU  - Manić, Nebojša G.
AU  - Janković, Bojan Ž.
AU  - Pijović, Milena
AU  - Waisi, Hadi
AU  - Dodevski, Vladimir
AU  - Stojiljković, Dragoslava
AU  - Jovanović, Vladimir V.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8904
AB  - In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin fragments) by four-parameter Fraser–Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO2 gases) and charification of the solid residue (increased the bio-char yield). © 2020, Akadémiai Kiadó, Budapest, Hungary.
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)
VL  - 142
IS  - 2
SP  - 565
EP  - 579
DO  - 10.1007/s10973-020-09307-5
ER  - 
@article{
author = "Manić, Nebojša G. and Janković, Bojan Ž. and Pijović, Milena and Waisi, Hadi and Dodevski, Vladimir and Stojiljković, Dragoslava and Jovanović, Vladimir V.",
year = "2020",
abstract = "In order to clarify relationship between apricot kernel shell biomass slow pyrolysis mechanism and its main constituents (viz. hemicelluloses, cellulose and lignin), the reactivity effects of main constituents on pyrolysis characteristics were determined by the non-isothermal simultaneous thermal analysis. It was found that four-step (parallel) reaction model is suitable for studying the slow pyrolysis process, within the semi-global model which excludes the strong interaction between biomass constituents (pseudo-components). The application of the proposed model was allowed by the results obtained from KAS iterative isoconversional (model-free) approach. The valorization of the model was confirmed by the process optimization. The complex (cumulative) apricot kernel shell pyrolysis rate curves at different heating rates are successfully resolved into the individual decomposition rate curves (arising from thermal conversion of hemicelluloses, cellulose, and primary/secondary lignin fragments) by four-parameter Fraser–Suzuki function. Besides hemicelluloses and cellulose pyrolyses, the proposed model distinguishes primary and secondary lignin reactions, which enhance the gaseous products releasing (primarily CO and CO2 gases) and charification of the solid residue (increased the bio-char yield). © 2020, Akadémiai Kiadó, Budapest, Hungary.",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)",
volume = "142",
number = "2",
pages = "565-579",
doi = "10.1007/s10973-020-09307-5"
}
Manić, N. G., Janković, B. Ž., Pijović, M., Waisi, H., Dodevski, V., Stojiljković, D.,& Jovanović, V. V.. (2020). Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA). in Journal of Thermal Analysis and Calorimetry, 142(2), 565-579.
https://doi.org/10.1007/s10973-020-09307-5
Manić NG, Janković BŽ, Pijović M, Waisi H, Dodevski V, Stojiljković D, Jovanović VV. Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA). in Journal of Thermal Analysis and Calorimetry. 2020;142(2):565-579.
doi:10.1007/s10973-020-09307-5 .
Manić, Nebojša G., Janković, Bojan Ž., Pijović, Milena, Waisi, Hadi, Dodevski, Vladimir, Stojiljković, Dragoslava, Jovanović, Vladimir V., "Apricot kernel shells pyrolysis controlled by non-isothermal simultaneous thermal analysis (STA)" in Journal of Thermal Analysis and Calorimetry, 142, no. 2 (2020):565-579,
https://doi.org/10.1007/s10973-020-09307-5 . .
18
7
18