Ministry of Science and Technological Development of the Republic of Serbia [142028]

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Ministry of Science and Technological Development of the Republic of Serbia [142028]

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Publications

Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)

Novaković, Slađana B.; Bogdanović, Goran A.; Brceski, Ilija D.; Leovac, Vukadin M.

(2009)

TY  - JOUR
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Brceski, Ilija D.
AU  - Leovac, Vukadin M.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3754
AB  - The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)
VL  - 65
SP  - M263
EP  - M265
DO  - 10.1107/S0108270109021970
ER  - 
@article{
author = "Novaković, Slađana B. and Bogdanović, Goran A. and Brceski, Ilija D. and Leovac, Vukadin M.",
year = "2009",
abstract = "The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)",
volume = "65",
pages = "M263-M265",
doi = "10.1107/S0108270109021970"
}
Novaković, S. B., Bogdanović, G. A., Brceski, I. D.,& Leovac, V. M.. (2009). Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications, 65, M263-M265.
https://doi.org/10.1107/S0108270109021970
Novaković SB, Bogdanović GA, Brceski ID, Leovac VM. Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications. 2009;65:M263-M265.
doi:10.1107/S0108270109021970 .
Novaković, Slađana B., Bogdanović, Goran A., Brceski, Ilija D., Leovac, Vukadin M., "Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)" in Acta Crystallographica. Section C: Crystal Structure Communications, 65 (2009):M263-M265,
https://doi.org/10.1107/S0108270109021970 . .
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{4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate

Leovac, Vukadin M.; Vojinović-Ješić, Ljiljana S.; Češljević, Valerija I.; Novaković, Slađana B.; Bogdanović, Goran A.

(2009)

TY  - JOUR
AU  - Leovac, Vukadin M.
AU  - Vojinović-Ješić, Ljiljana S.
AU  - Češljević, Valerija I.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3780
AB  - The title compound, [Cu(C9H13N5O2)(CH4O)](NO3)(2), consists of square-planar cationic complex units where the Cu-II centre is coordinated by an N, N, O-tridentate pyridoxal aminoguanidine Schiff base adduct and a methanol molecule. The tridentate ligand is a zwitterion exhibiting an almost planar conformation. The dihedral angles between the mean planes of the pyridoxal ring and the six-and five-membered chelate rings are all less than 2.0 degrees. The charge on the complex cation is neutralized by two nitrate counter-ions. Extensive N -H center dot center dot center dot O and C -H center dot center dot center dot O hydrogen bonding connects these ionic species and leads to the formation of layers. The pyridoxal hydroxy groups are the only fragments that deviate significantly from the flat layer structure; these groups are involved in O-H center dot center dot center dot O hydrogen bonding, connecting the layers into a three-dimensional crystal structure.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - {4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate
VL  - 65
SP  - M337
EP  - M339
DO  - 10.1107/S0108270109029023
ER  - 
@article{
author = "Leovac, Vukadin M. and Vojinović-Ješić, Ljiljana S. and Češljević, Valerija I. and Novaković, Slađana B. and Bogdanović, Goran A.",
year = "2009",
abstract = "The title compound, [Cu(C9H13N5O2)(CH4O)](NO3)(2), consists of square-planar cationic complex units where the Cu-II centre is coordinated by an N, N, O-tridentate pyridoxal aminoguanidine Schiff base adduct and a methanol molecule. The tridentate ligand is a zwitterion exhibiting an almost planar conformation. The dihedral angles between the mean planes of the pyridoxal ring and the six-and five-membered chelate rings are all less than 2.0 degrees. The charge on the complex cation is neutralized by two nitrate counter-ions. Extensive N -H center dot center dot center dot O and C -H center dot center dot center dot O hydrogen bonding connects these ionic species and leads to the formation of layers. The pyridoxal hydroxy groups are the only fragments that deviate significantly from the flat layer structure; these groups are involved in O-H center dot center dot center dot O hydrogen bonding, connecting the layers into a three-dimensional crystal structure.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "{4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate",
volume = "65",
pages = "M337-M339",
doi = "10.1107/S0108270109029023"
}
Leovac, V. M., Vojinović-Ješić, L. S., Češljević, V. I., Novaković, S. B.,& Bogdanović, G. A.. (2009). {4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate. in Acta Crystallographica. Section C: Crystal Structure Communications, 65, M337-M339.
https://doi.org/10.1107/S0108270109029023
Leovac VM, Vojinović-Ješić LS, Češljević VI, Novaković SB, Bogdanović GA. {4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate. in Acta Crystallographica. Section C: Crystal Structure Communications. 2009;65:M337-M339.
doi:10.1107/S0108270109029023 .
Leovac, Vukadin M., Vojinović-Ješić, Ljiljana S., Češljević, Valerija I., Novaković, Slađana B., Bogdanović, Goran A., "{4-[(Carbamimidoylhydrazono)methyl-kappa N-2(1),N-4]-5-hydroxymethyl-2-methylpyridinium-3-olate-kappa O}(methanol-kappa O)copper(II) dinitrate" in Acta Crystallographica. Section C: Crystal Structure Communications, 65 (2009):M337-M339,
https://doi.org/10.1107/S0108270109029023 . .
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