Physics of amorphous and nanostructural materials

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Physics of amorphous and nanostructural materials (en)
Физика аморфних и наноструктурних материјала (sr)
Fizika amorfnih i nanostrukturnih materijala (sr_RS)
Authors

Publications

Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review

Zhou, Qiang; Dolgov, Leonid; Srivastava, Alok M; Zhou, Lei; Wang, Zhengliang; Shi, Jianxin; Dramićanin, Miroslav; Brik, Mikhail G.; Wu, Mingmei

(2018)

TY  - JOUR
AU  - Zhou, Qiang
AU  - Dolgov, Leonid
AU  - Srivastava, Alok M
AU  - Zhou, Lei
AU  - Wang, Zhengliang
AU  - Shi, Jianxin
AU  - Dramićanin, Miroslav
AU  - Brik, Mikhail G.
AU  - Wu, Mingmei
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7638
AB  - Transition-metal activated phosphors are an important family of luminescent materials that can produce white light with an outstanding color rendering index and correlated color temperature for use in light-emitting diodes.  In recent years, work in this quite “hot” research field has focused on the development of Mn2+ and Mn4+ activated red phosphors. In this review article, we provide an overview of recent studies on Mn2+ and Mn4+ doped phosphors, including detailed synthesis routes (solid-state reaction and wet-chemical synthesis) and description of luminescence mechanisms and phosphors’ behaviors; discuss their promising applications in white light-emitting diodes; and present an extensive list of references to representative works in this field.
T2  - Journal of Materials Chemistry C
T1  - Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review
VL  - 6
IS  - 11
SP  - 2652
EP  - 2671
DO  - 10.1039/C8TC00251G
ER  - 
@article{
author = "Zhou, Qiang and Dolgov, Leonid and Srivastava, Alok M and Zhou, Lei and Wang, Zhengliang and Shi, Jianxin and Dramićanin, Miroslav and Brik, Mikhail G. and Wu, Mingmei",
year = "2018",
abstract = "Transition-metal activated phosphors are an important family of luminescent materials that can produce white light with an outstanding color rendering index and correlated color temperature for use in light-emitting diodes.  In recent years, work in this quite “hot” research field has focused on the development of Mn2+ and Mn4+ activated red phosphors. In this review article, we provide an overview of recent studies on Mn2+ and Mn4+ doped phosphors, including detailed synthesis routes (solid-state reaction and wet-chemical synthesis) and description of luminescence mechanisms and phosphors’ behaviors; discuss their promising applications in white light-emitting diodes; and present an extensive list of references to representative works in this field.",
journal = "Journal of Materials Chemistry C",
title = "Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review",
volume = "6",
number = "11",
pages = "2652-2671",
doi = "10.1039/C8TC00251G"
}
Zhou, Q., Dolgov, L., Srivastava, A. M., Zhou, L., Wang, Z., Shi, J., Dramićanin, M., Brik, M. G.,& Wu, M.. (2018). Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review. in Journal of Materials Chemistry C, 6(11), 2652-2671.
https://doi.org/10.1039/C8TC00251G
Zhou Q, Dolgov L, Srivastava AM, Zhou L, Wang Z, Shi J, Dramićanin M, Brik MG, Wu M. Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review. in Journal of Materials Chemistry C. 2018;6(11):2652-2671.
doi:10.1039/C8TC00251G .
Zhou, Qiang, Dolgov, Leonid, Srivastava, Alok M, Zhou, Lei, Wang, Zhengliang, Shi, Jianxin, Dramićanin, Miroslav, Brik, Mikhail G., Wu, Mingmei, "Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review" in Journal of Materials Chemistry C, 6, no. 11 (2018):2652-2671,
https://doi.org/10.1039/C8TC00251G . .
1
513
317
505

Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate

Dolić, Slobodan D; Jovanović, Dragana J.; Štrbac, Dragana; Đačanin Far, Ljubica; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Dolić, Slobodan D
AU  - Jovanović, Dragana J.
AU  - Štrbac, Dragana
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0272884218325227
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7960
AB  - Herein, fine powders of yellow pigments based on BiVO4 were successfully prepared in two crystalline forms, tetragonal zircon-structured and monoclinic scheelite-structured, through a ethylene glycol-assisted method subjected to a thermal treatment at two different temperatures. The obtained materials were brightly colored with different hues of yellow, exhibited high reflection in the near-infrared region and showed visible luminescence under excitation by UV light. The new preparation method had a considerable effect on chromatic properties of the prepared scheelite-structured BiVO4 pigments. The sample with the most vivid and bright shade of yellow was found to have the L*a*b* and L*C* ab h* ab color coordinates of (87.28, 0.37, 91.53) and (87.28, 91.53, 89.79), which are indicative of exceptionally good chromatic properties superior and/or comparable to those of other inorganic yellow pigments, both commercially available and recently described. In addition, the NIR reflectance of this powder was very high (≥ 80%). © 2018 Elsevier Ltd and Techna Group S.r.l.
T2  - Ceramics International
T1  - Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate
VL  - 44
IS  - 18
SP  - 22731
EP  - 22737
DO  - 10.1016/j.ceramint.2018.09.057
ER  - 
@article{
author = "Dolić, Slobodan D and Jovanović, Dragana J. and Štrbac, Dragana and Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2018",
abstract = "Herein, fine powders of yellow pigments based on BiVO4 were successfully prepared in two crystalline forms, tetragonal zircon-structured and monoclinic scheelite-structured, through a ethylene glycol-assisted method subjected to a thermal treatment at two different temperatures. The obtained materials were brightly colored with different hues of yellow, exhibited high reflection in the near-infrared region and showed visible luminescence under excitation by UV light. The new preparation method had a considerable effect on chromatic properties of the prepared scheelite-structured BiVO4 pigments. The sample with the most vivid and bright shade of yellow was found to have the L*a*b* and L*C* ab h* ab color coordinates of (87.28, 0.37, 91.53) and (87.28, 91.53, 89.79), which are indicative of exceptionally good chromatic properties superior and/or comparable to those of other inorganic yellow pigments, both commercially available and recently described. In addition, the NIR reflectance of this powder was very high (≥ 80%). © 2018 Elsevier Ltd and Techna Group S.r.l.",
journal = "Ceramics International",
title = "Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate",
volume = "44",
number = "18",
pages = "22731-22737",
doi = "10.1016/j.ceramint.2018.09.057"
}
Dolić, S. D., Jovanović, D. J., Štrbac, D., Đačanin Far, L.,& Dramićanin, M.. (2018). Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate. in Ceramics International, 44(18), 22731-22737.
https://doi.org/10.1016/j.ceramint.2018.09.057
Dolić SD, Jovanović DJ, Štrbac D, Đačanin Far L, Dramićanin M. Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate. in Ceramics International. 2018;44(18):22731-22737.
doi:10.1016/j.ceramint.2018.09.057 .
Dolić, Slobodan D, Jovanović, Dragana J., Štrbac, Dragana, Đačanin Far, Ljubica, Dramićanin, Miroslav, "Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate" in Ceramics International, 44, no. 18 (2018):22731-22737,
https://doi.org/10.1016/j.ceramint.2018.09.057 . .
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Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4

(2018)

TY  - JOUR
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7587
AB  - Dy3+-and Nd3+-doped YNbO4 powders were prepared using a mechanochemical method followed by annealing, and their photoluminescent properties were examined to assess the possibility of their use in phosphor thermometry. Luminescence intensity ratio technique was used as a temperature readout scheme for both YNba(4):Dy3+ and YNbO4:Nd3+ samples. The crystalline structure of the samples is confirmed by XRD measurements, while SEM was used for the microstructural and compositional characterization. Sample doped with Dy3+ ions emitting in the blue region has been investigated in the 293-773 K temperature range and exhibits maximal relative sensitivity of 1.97% K-1 at 300 K. YNbO4:Nd3+ sample showed intense NIR emission which fall into the first biological window. When heated from 303 up to 473 K relative temperature sensitivity of 0.28%K-1 at 300 K was achieved. Values of temperature sensitivities show that YNbO4 has a large potential for the development of thermographic phosphors in the blue and NIR spectral ranges when doped with trivalent Dy and Nd, respectively. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Sensors and Actuators A: Physical
T1  - Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4
VL  - 270
SP  - 89
EP  - 96
DO  - 10.1016/j.sna.2017.12.044
ER  - 
@article{
year = "2018",
abstract = "Dy3+-and Nd3+-doped YNbO4 powders were prepared using a mechanochemical method followed by annealing, and their photoluminescent properties were examined to assess the possibility of their use in phosphor thermometry. Luminescence intensity ratio technique was used as a temperature readout scheme for both YNba(4):Dy3+ and YNbO4:Nd3+ samples. The crystalline structure of the samples is confirmed by XRD measurements, while SEM was used for the microstructural and compositional characterization. Sample doped with Dy3+ ions emitting in the blue region has been investigated in the 293-773 K temperature range and exhibits maximal relative sensitivity of 1.97% K-1 at 300 K. YNbO4:Nd3+ sample showed intense NIR emission which fall into the first biological window. When heated from 303 up to 473 K relative temperature sensitivity of 0.28%K-1 at 300 K was achieved. Values of temperature sensitivities show that YNbO4 has a large potential for the development of thermographic phosphors in the blue and NIR spectral ranges when doped with trivalent Dy and Nd, respectively. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Sensors and Actuators A: Physical",
title = "Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4",
volume = "270",
pages = "89-96",
doi = "10.1016/j.sna.2017.12.044"
}
(2018). Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4. in Sensors and Actuators A: Physical, 270, 89-96.
https://doi.org/10.1016/j.sna.2017.12.044
Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4. in Sensors and Actuators A: Physical. 2018;270:89-96.
doi:10.1016/j.sna.2017.12.044 .
"Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4" in Sensors and Actuators A: Physical, 270 (2018):89-96,
https://doi.org/10.1016/j.sna.2017.12.044 . .
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54

MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe

Glais, Estelle; Đorđević, Vesna R.; Papan, Jelena; Viana, Bruno; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Glais, Estelle
AU  - Đorđević, Vesna R.
AU  - Papan, Jelena
AU  - Viana, Bruno
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - http://xlink.rsc.org/?DOI=C8RA02482K
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7693
AB  - MgTiO3 nanoparticles doped with Mn4+, with homogeneous size ranging about 63.1 ± 9.8 nm, were synthesized by a molten salt assisted sol gel method. These nanoparticles have been investigated as optical thermal sensors. The luminescence of tetravalent manganese ion in octahedral environment within the perovskite host presents drastic variations with temperature. Three different thermometry approaches have been proposed and characterized. Two luminescence intensity ratios are studied. Firstly between the two R-lines of Mn4+ emission at low temperature (-250 °C and -90 °C) with a maximal sensitivity of 0.9% °C-1, but also secondly between 2E → 4A2 (R-line) and the 4T2 → 4A2 transitions. This allows studying the temperature variation within a larger temperature range (-200 °C to 50 °C) with a sensitivity between 0.6% °C-1 and 1.2% °C-1 over this range. The last proposed method is the study of the lifetime variation versus temperature. The effective lifetime value corresponds to a combination of transitions from two excited energy levels of the tetravalent manganese (2E and 4T2) in thermal equilibrium toward the fundamental 4A2 state. Since the more energetic transition (4T2 → 4A2) is spin-allowed, contrary to the 2E → 4A2 one, the lifetime drastically decreases with the increase in temperature leading to an impressive high sensitivity value of 4.1% °C-1 at 4 °C and an exceptional temperature resolution of 0.025 °C. According to their optical features, MgTiO3:Mn4+ nanoparticles are indeed suitable candidates for the luminescence temperature probes at the nanoscale over several temperature ranges.
T2  - RSC Advances
T1  - MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe
VL  - 8
IS  - 33
SP  - 18341
EP  - 18346
DO  - 10.1039/C8RA02482K
ER  - 
@article{
author = "Glais, Estelle and Đorđević, Vesna R. and Papan, Jelena and Viana, Bruno and Dramićanin, Miroslav",
year = "2018",
abstract = "MgTiO3 nanoparticles doped with Mn4+, with homogeneous size ranging about 63.1 ± 9.8 nm, were synthesized by a molten salt assisted sol gel method. These nanoparticles have been investigated as optical thermal sensors. The luminescence of tetravalent manganese ion in octahedral environment within the perovskite host presents drastic variations with temperature. Three different thermometry approaches have been proposed and characterized. Two luminescence intensity ratios are studied. Firstly between the two R-lines of Mn4+ emission at low temperature (-250 °C and -90 °C) with a maximal sensitivity of 0.9% °C-1, but also secondly between 2E → 4A2 (R-line) and the 4T2 → 4A2 transitions. This allows studying the temperature variation within a larger temperature range (-200 °C to 50 °C) with a sensitivity between 0.6% °C-1 and 1.2% °C-1 over this range. The last proposed method is the study of the lifetime variation versus temperature. The effective lifetime value corresponds to a combination of transitions from two excited energy levels of the tetravalent manganese (2E and 4T2) in thermal equilibrium toward the fundamental 4A2 state. Since the more energetic transition (4T2 → 4A2) is spin-allowed, contrary to the 2E → 4A2 one, the lifetime drastically decreases with the increase in temperature leading to an impressive high sensitivity value of 4.1% °C-1 at 4 °C and an exceptional temperature resolution of 0.025 °C. According to their optical features, MgTiO3:Mn4+ nanoparticles are indeed suitable candidates for the luminescence temperature probes at the nanoscale over several temperature ranges.",
journal = "RSC Advances",
title = "MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe",
volume = "8",
number = "33",
pages = "18341-18346",
doi = "10.1039/C8RA02482K"
}
Glais, E., Đorđević, V. R., Papan, J., Viana, B.,& Dramićanin, M.. (2018). MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe. in RSC Advances, 8(33), 18341-18346.
https://doi.org/10.1039/C8RA02482K
Glais E, Đorđević VR, Papan J, Viana B, Dramićanin M. MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe. in RSC Advances. 2018;8(33):18341-18346.
doi:10.1039/C8RA02482K .
Glais, Estelle, Đorđević, Vesna R., Papan, Jelena, Viana, Bruno, Dramićanin, Miroslav, "MgTiO 3:Mn 4+ a multi-reading temperature nanoprobe" in RSC Advances, 8, no. 33 (2018):18341-18346,
https://doi.org/10.1039/C8RA02482K . .
55
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53

Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization

Ivetić, Tamara B.; Sekulić, Dalibor L.; Papan, Jelena; Guth, Imre O.; Petrović, Dragoslav M.; Lukić-Petrović, Svetlana R.

(2018)

TY  - JOUR
AU  - Ivetić, Tamara B.
AU  - Sekulić, Dalibor L.
AU  - Papan, Jelena
AU  - Guth, Imre O.
AU  - Petrović, Dragoslav M.
AU  - Lukić-Petrović, Svetlana R.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0272884218318674
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7813
AB  - This paper describes the processing, microstructure, optical and electrical properties of the nanocrystalline (NC) niobium and zinc doped titanium-tin-oxide (TTO:NZ) based ceramics. Variety of techniques was employed (X-ray diffraction, scanning electron microscopy, energy dispersive, Raman and impedance spectroscopy) in the characterization of the obtained TTO:NZ, which confirmed the formation of NC solid-solution matrix with Ti0.8Sn0.2O2 composition. A specific highly dense (approximately 97% of the theoretical density was reached) varistor like microstructure (matrix metal-oxide grains surrounded by the grain-boundary regions) and accordingly resembling electrical properties (breakdown electric field of approximately 130 V/mm and nonlinearity coefficient of α ≈ 6.5) were achieved through double cation doping and elected condition of the mechanochemical solid-state synthesis. Impedance response analysis of TTO:NZ ceramics by means of an equivalent electrical circuit based on the brick-layer model for polycrystalline materials revealed the presence of two temperature dependent electrical relaxation phenomena of the non-Debye type as well as the negative temperature coefficient of resistance behavior.
T2  - Ceramics International
T1  - Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization
VL  - 44
IS  - 15
SP  - 18987
EP  - 18995
DO  - 10.1016/j.ceramint.2018.07.139
ER  - 
@article{
author = "Ivetić, Tamara B. and Sekulić, Dalibor L. and Papan, Jelena and Guth, Imre O. and Petrović, Dragoslav M. and Lukić-Petrović, Svetlana R.",
year = "2018",
abstract = "This paper describes the processing, microstructure, optical and electrical properties of the nanocrystalline (NC) niobium and zinc doped titanium-tin-oxide (TTO:NZ) based ceramics. Variety of techniques was employed (X-ray diffraction, scanning electron microscopy, energy dispersive, Raman and impedance spectroscopy) in the characterization of the obtained TTO:NZ, which confirmed the formation of NC solid-solution matrix with Ti0.8Sn0.2O2 composition. A specific highly dense (approximately 97% of the theoretical density was reached) varistor like microstructure (matrix metal-oxide grains surrounded by the grain-boundary regions) and accordingly resembling electrical properties (breakdown electric field of approximately 130 V/mm and nonlinearity coefficient of α ≈ 6.5) were achieved through double cation doping and elected condition of the mechanochemical solid-state synthesis. Impedance response analysis of TTO:NZ ceramics by means of an equivalent electrical circuit based on the brick-layer model for polycrystalline materials revealed the presence of two temperature dependent electrical relaxation phenomena of the non-Debye type as well as the negative temperature coefficient of resistance behavior.",
journal = "Ceramics International",
title = "Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization",
volume = "44",
number = "15",
pages = "18987-18995",
doi = "10.1016/j.ceramint.2018.07.139"
}
Ivetić, T. B., Sekulić, D. L., Papan, J., Guth, I. O., Petrović, D. M.,& Lukić-Petrović, S. R.. (2018). Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization. in Ceramics International, 44(15), 18987-18995.
https://doi.org/10.1016/j.ceramint.2018.07.139
Ivetić TB, Sekulić DL, Papan J, Guth IO, Petrović DM, Lukić-Petrović SR. Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization. in Ceramics International. 2018;44(15):18987-18995.
doi:10.1016/j.ceramint.2018.07.139 .
Ivetić, Tamara B., Sekulić, Dalibor L., Papan, Jelena, Guth, Imre O., Petrović, Dragoslav M., Lukić-Petrović, Svetlana R., "Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization" in Ceramics International, 44, no. 15 (2018):18987-18995,
https://doi.org/10.1016/j.ceramint.2018.07.139 . .
6
1
7

Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations

Đorđević, Vesna R.; Brik, Mikhail G.; Srivastava, Alok M.; Medić, Mina M.; Vulić, Predrag J.; Glais, Estelle; Viana, Bruno; Dramićanin, Miroslav

(2017)

TY  - JOUR
AU  - Đorđević, Vesna R.
AU  - Brik, Mikhail G.
AU  - Srivastava, Alok M.
AU  - Medić, Mina M.
AU  - Vulić, Predrag J.
AU  - Glais, Estelle
AU  - Viana, Bruno
AU  - Dramićanin, Miroslav
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7197
AB  - Herein, the synthesis, structural and crystal field analysis and optical spectroscopy of Mn4+ doped metal titanates ATiO(3) (A = Ca, Mg) are presented. Materials of desired phase were prepared by molten salt assisted sol-gel method in the powder form. Crystallographic data of samples were obtained by refinement of X-ray diffraction measurements. From experimental excitation and emission spectra and structural data, crystal field parameters and energy levels of Mn4+ in CaTiO3 and MgTiO3 were calculated by the exchange charge model of crystal-field theory. It is found that crystalline field strength is lower (Dq = 1831 cm(-1)) in the rhombohedral Ilmenite MgTiO3 structure due to the relatively longer average Mn4+-O2- bond distance (2.059 angstrom), and higher (Dq = 2017 cm(-1)) in orthorhombic CaTiO3 which possess shorter average Mn4+-O2- bond distance (1.956 angstrom). Spectral positions of the Mn(4+2)Eg - GT (4)A(2g) transition maxima is 709 nm in MgTiO3 and 717 nm in CaTiO3 respectively in good agreement with calculated values. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations
VL  - 74
SP  - 46
EP  - 51
DO  - 10.1016/j.optmat.2017.03.021
ER  - 
@article{
author = "Đorđević, Vesna R. and Brik, Mikhail G. and Srivastava, Alok M. and Medić, Mina M. and Vulić, Predrag J. and Glais, Estelle and Viana, Bruno and Dramićanin, Miroslav",
year = "2017",
abstract = "Herein, the synthesis, structural and crystal field analysis and optical spectroscopy of Mn4+ doped metal titanates ATiO(3) (A = Ca, Mg) are presented. Materials of desired phase were prepared by molten salt assisted sol-gel method in the powder form. Crystallographic data of samples were obtained by refinement of X-ray diffraction measurements. From experimental excitation and emission spectra and structural data, crystal field parameters and energy levels of Mn4+ in CaTiO3 and MgTiO3 were calculated by the exchange charge model of crystal-field theory. It is found that crystalline field strength is lower (Dq = 1831 cm(-1)) in the rhombohedral Ilmenite MgTiO3 structure due to the relatively longer average Mn4+-O2- bond distance (2.059 angstrom), and higher (Dq = 2017 cm(-1)) in orthorhombic CaTiO3 which possess shorter average Mn4+-O2- bond distance (1.956 angstrom). Spectral positions of the Mn(4+2)Eg - GT (4)A(2g) transition maxima is 709 nm in MgTiO3 and 717 nm in CaTiO3 respectively in good agreement with calculated values. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations",
volume = "74",
pages = "46-51",
doi = "10.1016/j.optmat.2017.03.021"
}
Đorđević, V. R., Brik, M. G., Srivastava, A. M., Medić, M. M., Vulić, P. J., Glais, E., Viana, B.,& Dramićanin, M.. (2017). Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations. in Optical Materials, 74, 46-51.
https://doi.org/10.1016/j.optmat.2017.03.021
Đorđević VR, Brik MG, Srivastava AM, Medić MM, Vulić PJ, Glais E, Viana B, Dramićanin M. Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations. in Optical Materials. 2017;74:46-51.
doi:10.1016/j.optmat.2017.03.021 .
Đorđević, Vesna R., Brik, Mikhail G., Srivastava, Alok M., Medić, Mina M., Vulić, Predrag J., Glais, Estelle, Viana, Bruno, Dramićanin, Miroslav, "Luminescence of Mn4+ ions in CaTiO3 and MgTiO3 perovskites: Relationship of experimental spectroscopic data and crystal field calculations" in Optical Materials, 74 (2017):46-51,
https://doi.org/10.1016/j.optmat.2017.03.021 . .
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Sensing temperature via downshifting emissions of lanthanide-doped metal oxides and salts. A review

Dramićanin, Miroslav

(2016)

TY  - JOUR
AU  - Dramićanin, Miroslav
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1288
AB  - Temperature is important because it has an effect on even the tiniest elements of daily life and is involved in a broad spectrum of human activities. That is why it is the most commonly measured physical quantity. Traditional temperature measurements encounter difficulties when used in some emerging technologies and environments, such as nanotechnology and biomedicine. The problem may be alleviated using optical techniques, one of which is luminescence thermometry. This paper reviews the state of luminescence thermometry and presents different temperature read-out schemes with an emphasis on those utilizing the downshifting emission of lanthanide-doped metal oxides and salts. The read-out schemes for temperature include those based on measurements of spectral characteristics of luminescence (band positions and shapes, emission intensity and ratio of emission intensities), and those based on measurements of the temporal behavior of luminescence (lifetimes and rise times). This review (with 140 references) gives the basics of the fundamental principles and theory that underlie the methods presented, and describes the methodology for the estimation of their performance. The major part of the text is devoted to those lanthanide-doped metal oxides and salts that are used as temperature probes, and to the comparison of their performance and characteristics.
T2  - Methods and Applications in Fluorescence
T1  - Sensing temperature via downshifting emissions of lanthanide-doped metal oxides and salts. A review
VL  - 4
IS  - 4
DO  - 10.1088/2050-6120/4/4/042001
ER  - 
@article{
author = "Dramićanin, Miroslav",
year = "2016",
abstract = "Temperature is important because it has an effect on even the tiniest elements of daily life and is involved in a broad spectrum of human activities. That is why it is the most commonly measured physical quantity. Traditional temperature measurements encounter difficulties when used in some emerging technologies and environments, such as nanotechnology and biomedicine. The problem may be alleviated using optical techniques, one of which is luminescence thermometry. This paper reviews the state of luminescence thermometry and presents different temperature read-out schemes with an emphasis on those utilizing the downshifting emission of lanthanide-doped metal oxides and salts. The read-out schemes for temperature include those based on measurements of spectral characteristics of luminescence (band positions and shapes, emission intensity and ratio of emission intensities), and those based on measurements of the temporal behavior of luminescence (lifetimes and rise times). This review (with 140 references) gives the basics of the fundamental principles and theory that underlie the methods presented, and describes the methodology for the estimation of their performance. The major part of the text is devoted to those lanthanide-doped metal oxides and salts that are used as temperature probes, and to the comparison of their performance and characteristics.",
journal = "Methods and Applications in Fluorescence",
title = "Sensing temperature via downshifting emissions of lanthanide-doped metal oxides and salts. A review",
volume = "4",
number = "4",
doi = "10.1088/2050-6120/4/4/042001"
}
Dramićanin, M.. (2016). Sensing temperature via downshifting emissions of lanthanide-doped metal oxides and salts. A review. in Methods and Applications in Fluorescence, 4(4).
https://doi.org/10.1088/2050-6120/4/4/042001
Dramićanin M. Sensing temperature via downshifting emissions of lanthanide-doped metal oxides and salts. A review. in Methods and Applications in Fluorescence. 2016;4(4).
doi:10.1088/2050-6120/4/4/042001 .
Dramićanin, Miroslav, "Sensing temperature via downshifting emissions of lanthanide-doped metal oxides and salts. A review" in Methods and Applications in Fluorescence, 4, no. 4 (2016),
https://doi.org/10.1088/2050-6120/4/4/042001 . .
280
186

Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles

Medić, Mina M.; Antić, Željka; Đorđević, Vesna R.; Ahrenkiel, Scott Phillip; Marinović-Cincović, Milena; Dramićanin, Miroslav

(Elsevier, 2016)

TY  - JOUR
AU  - Medić, Mina M.
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Ahrenkiel, Scott Phillip
AU  - Marinović-Cincović, Milena
AU  - Dramićanin, Miroslav
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/879
AB  - This work explores the influence of annealing temperature on the structure and luminescence of 2 at% Eu3+ and 1 at Sm3+-doped Mg2TiO4 nanopowders produced via Pechini-type polymerized complex route. Mg2TiO4 samples were annealed at 7 different temperatures (400 degrees C, 450 degrees C, 500 degrees C, 550 degrees C, 600 degrees C, 650 degrees C and 700 degrees C) to determine the temperature range in which cubic inverse spinel structure is stable and to follow the changes of material luminescence properties. X-ray diffraction revealed that crystallization of both Eu3+ and Sm3+-doped Mg2TiO4 nanopowders starts at 400 degrees C, and that Sm3+ doped Mg2TiO4 starts to decompose at 650 degrees C, while Eu3+ doped Mg2TiO4 starts to decompose at 700 degrees C. Samples annealed at higher temperatures show higher crystallinity and larger crystallite size. Mg2TiO4 powder annealed at 600 degrees C is composed of similar to 5 nm size nanoparticles agglomerated in micron-size and dense chunks. The emission spectra of nanoparticles are composed of emissions from defects in Mg2TiO4 host and characteristic emissions of Eu3+ (D-5(0) - GT F-7(J)) and Sm3+ ((4)G(5/2) - GT H-6(J)) ions. The stronger emission and longer emission decays are observed with samples annealed at high temperatures. In the case of the Eu3+ ions emission intensity increased one order of magnitude between samples annealed at 400 degrees C and 650 degrees C. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Luminescence
T1  - Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles
VL  - 170
IS  - SI
SP  - 679
EP  - 685
DO  - 10.1016/j.jlumin.2015.06.007
ER  - 
@article{
author = "Medić, Mina M. and Antić, Željka and Đorđević, Vesna R. and Ahrenkiel, Scott Phillip and Marinović-Cincović, Milena and Dramićanin, Miroslav",
year = "2016",
abstract = "This work explores the influence of annealing temperature on the structure and luminescence of 2 at% Eu3+ and 1 at Sm3+-doped Mg2TiO4 nanopowders produced via Pechini-type polymerized complex route. Mg2TiO4 samples were annealed at 7 different temperatures (400 degrees C, 450 degrees C, 500 degrees C, 550 degrees C, 600 degrees C, 650 degrees C and 700 degrees C) to determine the temperature range in which cubic inverse spinel structure is stable and to follow the changes of material luminescence properties. X-ray diffraction revealed that crystallization of both Eu3+ and Sm3+-doped Mg2TiO4 nanopowders starts at 400 degrees C, and that Sm3+ doped Mg2TiO4 starts to decompose at 650 degrees C, while Eu3+ doped Mg2TiO4 starts to decompose at 700 degrees C. Samples annealed at higher temperatures show higher crystallinity and larger crystallite size. Mg2TiO4 powder annealed at 600 degrees C is composed of similar to 5 nm size nanoparticles agglomerated in micron-size and dense chunks. The emission spectra of nanoparticles are composed of emissions from defects in Mg2TiO4 host and characteristic emissions of Eu3+ (D-5(0) - GT F-7(J)) and Sm3+ ((4)G(5/2) - GT H-6(J)) ions. The stronger emission and longer emission decays are observed with samples annealed at high temperatures. In the case of the Eu3+ ions emission intensity increased one order of magnitude between samples annealed at 400 degrees C and 650 degrees C. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Luminescence",
title = "Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles",
volume = "170",
number = "SI",
pages = "679-685",
doi = "10.1016/j.jlumin.2015.06.007"
}
Medić, M. M., Antić, Ž., Đorđević, V. R., Ahrenkiel, S. P., Marinović-Cincović, M.,& Dramićanin, M.. (2016). Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles. in Journal of Luminescence
Elsevier., 170(SI), 679-685.
https://doi.org/10.1016/j.jlumin.2015.06.007
Medić MM, Antić Ž, Đorđević VR, Ahrenkiel SP, Marinović-Cincović M, Dramićanin M. Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles. in Journal of Luminescence. 2016;170(SI):679-685.
doi:10.1016/j.jlumin.2015.06.007 .
Medić, Mina M., Antić, Željka, Đorđević, Vesna R., Ahrenkiel, Scott Phillip, Marinović-Cincović, Milena, Dramićanin, Miroslav, "Effect of annealing on luminescence of Eu3+- and Sm3+-doped Mg2TiO4 nanoparticles" in Journal of Luminescence, 170, no. SI (2016):679-685,
https://doi.org/10.1016/j.jlumin.2015.06.007 . .
11
6
9

Structure and magnetic properties of Co3O4/SiO2 nanocomposite synthesized using combustion assisted sol-gel method

Ivetić, Tamara B.; Tadić, Marin; Jagodič, Marko; Gyergyek, Sašo; Štrbac, Goran R.; Lukić-Petrović, Svetlana R.

(2016)

TY  - JOUR
AU  - Ivetić, Tamara B.
AU  - Tadić, Marin
AU  - Jagodič, Marko
AU  - Gyergyek, Sašo
AU  - Štrbac, Goran R.
AU  - Lukić-Petrović, Svetlana R.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1316
AB  - This paper reports on novel cobalt oxide nanoparticles (NPs) embedded in an amorphous silica (SiO2) matrix, synthesized using a modified sol-gel method. SEM and TEM images show as-synthesized particles to aggregate in the shape of spheres and less than 5 nm in size, while XRD and SAED analysis both point to well crystallized cubic spinel cobalt oxide phase with an average crystallite size of about 4.6 nm. Raman analysis confirms the formation of cobalt (III) oxide (Co3O4) NPs. As-synthesized Co3O4 single-nanocrystallite has magnetic properties that correlate with finite size effects and uncompensated surface spins. Temperature dependence of ZFC-FC magnetization curves reveals a sharp peak around 10 K which corresponds to the blocking temperature. A Curie-Weiss behavior of magnetization above 25 K shows lower Neel temperature of the sample compared with its bulk counterpart T-N=40 K (possibly due to crystal defects and nano-dimensionality of the particles). The magnetic measurements exhibit high magnetization at low temperatures (M-s=54.3 emu/g) which can be associated with random canting of the particles surface spins and uncompensated spins in the core which tends to interact ferromagnetically at low temperatures. The initial magnetization curve falls out from the hysteresis loop at 5 K, which could be also the effect of surface spins. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Structure and magnetic properties of Co3O4/SiO2 nanocomposite synthesized using combustion assisted sol-gel method
VL  - 42
IS  - 16
SP  - 18312
EP  - 18317
DO  - 10.1016/j.ceramint.2016.08.159
ER  - 
@article{
author = "Ivetić, Tamara B. and Tadić, Marin and Jagodič, Marko and Gyergyek, Sašo and Štrbac, Goran R. and Lukić-Petrović, Svetlana R.",
year = "2016",
abstract = "This paper reports on novel cobalt oxide nanoparticles (NPs) embedded in an amorphous silica (SiO2) matrix, synthesized using a modified sol-gel method. SEM and TEM images show as-synthesized particles to aggregate in the shape of spheres and less than 5 nm in size, while XRD and SAED analysis both point to well crystallized cubic spinel cobalt oxide phase with an average crystallite size of about 4.6 nm. Raman analysis confirms the formation of cobalt (III) oxide (Co3O4) NPs. As-synthesized Co3O4 single-nanocrystallite has magnetic properties that correlate with finite size effects and uncompensated surface spins. Temperature dependence of ZFC-FC magnetization curves reveals a sharp peak around 10 K which corresponds to the blocking temperature. A Curie-Weiss behavior of magnetization above 25 K shows lower Neel temperature of the sample compared with its bulk counterpart T-N=40 K (possibly due to crystal defects and nano-dimensionality of the particles). The magnetic measurements exhibit high magnetization at low temperatures (M-s=54.3 emu/g) which can be associated with random canting of the particles surface spins and uncompensated spins in the core which tends to interact ferromagnetically at low temperatures. The initial magnetization curve falls out from the hysteresis loop at 5 K, which could be also the effect of surface spins. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Structure and magnetic properties of Co3O4/SiO2 nanocomposite synthesized using combustion assisted sol-gel method",
volume = "42",
number = "16",
pages = "18312-18317",
doi = "10.1016/j.ceramint.2016.08.159"
}
Ivetić, T. B., Tadić, M., Jagodič, M., Gyergyek, S., Štrbac, G. R.,& Lukić-Petrović, S. R.. (2016). Structure and magnetic properties of Co3O4/SiO2 nanocomposite synthesized using combustion assisted sol-gel method. in Ceramics International, 42(16), 18312-18317.
https://doi.org/10.1016/j.ceramint.2016.08.159
Ivetić TB, Tadić M, Jagodič M, Gyergyek S, Štrbac GR, Lukić-Petrović SR. Structure and magnetic properties of Co3O4/SiO2 nanocomposite synthesized using combustion assisted sol-gel method. in Ceramics International. 2016;42(16):18312-18317.
doi:10.1016/j.ceramint.2016.08.159 .
Ivetić, Tamara B., Tadić, Marin, Jagodič, Marko, Gyergyek, Sašo, Štrbac, Goran R., Lukić-Petrović, Svetlana R., "Structure and magnetic properties of Co3O4/SiO2 nanocomposite synthesized using combustion assisted sol-gel method" in Ceramics International, 42, no. 16 (2016):18312-18317,
https://doi.org/10.1016/j.ceramint.2016.08.159 . .
5
5
4

Y3Al5O12:Re3+ (Re=Ce, Eu, and Sm) Nanocrystalline Powders Prepared by Modified Glycine Combustion Method

Lojpur, Vesna; Egelja, Adela; Pantić, Jelena R.; Đorđević, Vesna R.; Matović, Branko; Dramićanin, Miroslav

(2014)

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Egelja, Adela
AU  - Pantić, Jelena R.
AU  - Đorđević, Vesna R.
AU  - Matović, Branko
AU  - Dramićanin, Miroslav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6082
AB  - Yttrium aluminum garnet doped with rare earth ions (Ce3+, Eu3+ and Sm3+) was prepared by modified glycine method. Ce3+ as a dopant was used in four different concentrations (Y3-xCexAl5O12; x(%) = 1, 2, 3, 5), while doping concentration of Eu3+ and Sm3+ was Y3-xEuxAl5O12; x(%) = 3 and Y3-xSmxAl5O12; x(%) = 1, respectively. Phase composition of powders was investigated using XRD technique and expected target phase was confirmed. Photoluminescent characterization included measurements of excitation and emission spectra, as well as determination of emission decays. Y3-xCexAl5O12 shows intense broad-band emission, with maximum in green spectral region, at about 524 nm under ultraviolet or blue excitation. The origin of the luminescence is the 5d(1)- GT 4f(1) transition which is both parity and spin allowed. Ultraviolet and blue excitations of Eu3+ and Sm3+ doped Y3Al5O12 produce intense orange and red emissions. These emissions are phosphorescent in character and come from spin forbidden f-f electron transitions in Eu3+ and Sm3+ ions. For the case of Eu3+ doping emission comes mainly from D-5(0)- GT F-7(1) transitions with Stark components peaking at 590 nm and 590.75 nm, and with emission decay of 4.15 ms. In the case of Sm3+ doping, the emission spectrum, shows (4)G(5/2)- GT H-6(5/2), (4)G(5/2)- GT H-6(7/2), and (4)G(5/2)- GT H-6(9/2) transitions, with the most intense stark components positioned at 567.5 nm, 617 nm, and 650 nm, respectively and for transition centered at 617 nm, emission decay is 3.12 ms.
T2  - Science of Sintering
T1  - Y3Al5O12:Re3+ (Re=Ce, Eu, and Sm) Nanocrystalline Powders Prepared by Modified Glycine Combustion Method
VL  - 46
IS  - 1
SP  - 75
EP  - 82
DO  - 10.2298/SOS1401075L
ER  - 
@article{
author = "Lojpur, Vesna and Egelja, Adela and Pantić, Jelena R. and Đorđević, Vesna R. and Matović, Branko and Dramićanin, Miroslav",
year = "2014",
abstract = "Yttrium aluminum garnet doped with rare earth ions (Ce3+, Eu3+ and Sm3+) was prepared by modified glycine method. Ce3+ as a dopant was used in four different concentrations (Y3-xCexAl5O12; x(%) = 1, 2, 3, 5), while doping concentration of Eu3+ and Sm3+ was Y3-xEuxAl5O12; x(%) = 3 and Y3-xSmxAl5O12; x(%) = 1, respectively. Phase composition of powders was investigated using XRD technique and expected target phase was confirmed. Photoluminescent characterization included measurements of excitation and emission spectra, as well as determination of emission decays. Y3-xCexAl5O12 shows intense broad-band emission, with maximum in green spectral region, at about 524 nm under ultraviolet or blue excitation. The origin of the luminescence is the 5d(1)- GT 4f(1) transition which is both parity and spin allowed. Ultraviolet and blue excitations of Eu3+ and Sm3+ doped Y3Al5O12 produce intense orange and red emissions. These emissions are phosphorescent in character and come from spin forbidden f-f electron transitions in Eu3+ and Sm3+ ions. For the case of Eu3+ doping emission comes mainly from D-5(0)- GT F-7(1) transitions with Stark components peaking at 590 nm and 590.75 nm, and with emission decay of 4.15 ms. In the case of Sm3+ doping, the emission spectrum, shows (4)G(5/2)- GT H-6(5/2), (4)G(5/2)- GT H-6(7/2), and (4)G(5/2)- GT H-6(9/2) transitions, with the most intense stark components positioned at 567.5 nm, 617 nm, and 650 nm, respectively and for transition centered at 617 nm, emission decay is 3.12 ms.",
journal = "Science of Sintering",
title = "Y3Al5O12:Re3+ (Re=Ce, Eu, and Sm) Nanocrystalline Powders Prepared by Modified Glycine Combustion Method",
volume = "46",
number = "1",
pages = "75-82",
doi = "10.2298/SOS1401075L"
}
Lojpur, V., Egelja, A., Pantić, J. R., Đorđević, V. R., Matović, B.,& Dramićanin, M.. (2014). Y3Al5O12:Re3+ (Re=Ce, Eu, and Sm) Nanocrystalline Powders Prepared by Modified Glycine Combustion Method. in Science of Sintering, 46(1), 75-82.
https://doi.org/10.2298/SOS1401075L
Lojpur V, Egelja A, Pantić JR, Đorđević VR, Matović B, Dramićanin M. Y3Al5O12:Re3+ (Re=Ce, Eu, and Sm) Nanocrystalline Powders Prepared by Modified Glycine Combustion Method. in Science of Sintering. 2014;46(1):75-82.
doi:10.2298/SOS1401075L .
Lojpur, Vesna, Egelja, Adela, Pantić, Jelena R., Đorđević, Vesna R., Matović, Branko, Dramićanin, Miroslav, "Y3Al5O12:Re3+ (Re=Ce, Eu, and Sm) Nanocrystalline Powders Prepared by Modified Glycine Combustion Method" in Science of Sintering, 46, no. 1 (2014):75-82,
https://doi.org/10.2298/SOS1401075L . .
13
12
14

Europium-doped nanocrystalline Y2O3 - La2O3 solid solutions with bixbyite structure

Đorđević, Vesna R.; Antić, Željka; Lojpur, Vesna; Dramićanin, Miroslav

(2014)

TY  - JOUR
AU  - Đorđević, Vesna R.
AU  - Antić, Željka
AU  - Lojpur, Vesna
AU  - Dramićanin, Miroslav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/129
AB  - Nanocrystals of Y2O3 and La2O3 solid solutions were synthesized with a cubic bixbyite structure containing La2O3 content of up to 50 mol%. This is comparatively higher than that in bulk materials of the same structure, where La2O3 content of only 20 mol% can be obtained. A set of europium-doped (Y1-xLax)(2)O-3 (x=0.1, 0.2, 0.3, 0.4) cubic bixbyite solid solutions with crystallites of approximately 10 nm in size was prepared using the polymer complex solution method. Structural analysis was performed using X-ray diffraction measurements, Rietveld full profile refinement, and from Eu3+ luminescence emission. The energy levels of the Eu3+ ion, second order crystal field parameters, and crystal field strength were obtained for all compositions of solid solutions. We show that the crystal field parameters linearly depend on unit cell parameter and that these dependencies may be considered as part of an overall dependence for the entire sesquioxide family. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Journal of Physics and Chemistry of Solids
T1  - Europium-doped nanocrystalline Y2O3 - La2O3 solid solutions with bixbyite structure
VL  - 75
IS  - 10
SP  - 1152
EP  - 1159
DO  - 10.1016/j.jpcs.2014.05.009
ER  - 
@article{
author = "Đorđević, Vesna R. and Antić, Željka and Lojpur, Vesna and Dramićanin, Miroslav",
year = "2014",
abstract = "Nanocrystals of Y2O3 and La2O3 solid solutions were synthesized with a cubic bixbyite structure containing La2O3 content of up to 50 mol%. This is comparatively higher than that in bulk materials of the same structure, where La2O3 content of only 20 mol% can be obtained. A set of europium-doped (Y1-xLax)(2)O-3 (x=0.1, 0.2, 0.3, 0.4) cubic bixbyite solid solutions with crystallites of approximately 10 nm in size was prepared using the polymer complex solution method. Structural analysis was performed using X-ray diffraction measurements, Rietveld full profile refinement, and from Eu3+ luminescence emission. The energy levels of the Eu3+ ion, second order crystal field parameters, and crystal field strength were obtained for all compositions of solid solutions. We show that the crystal field parameters linearly depend on unit cell parameter and that these dependencies may be considered as part of an overall dependence for the entire sesquioxide family. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Journal of Physics and Chemistry of Solids",
title = "Europium-doped nanocrystalline Y2O3 - La2O3 solid solutions with bixbyite structure",
volume = "75",
number = "10",
pages = "1152-1159",
doi = "10.1016/j.jpcs.2014.05.009"
}
Đorđević, V. R., Antić, Ž., Lojpur, V.,& Dramićanin, M.. (2014). Europium-doped nanocrystalline Y2O3 - La2O3 solid solutions with bixbyite structure. in Journal of Physics and Chemistry of Solids, 75(10), 1152-1159.
https://doi.org/10.1016/j.jpcs.2014.05.009
Đorđević VR, Antić Ž, Lojpur V, Dramićanin M. Europium-doped nanocrystalline Y2O3 - La2O3 solid solutions with bixbyite structure. in Journal of Physics and Chemistry of Solids. 2014;75(10):1152-1159.
doi:10.1016/j.jpcs.2014.05.009 .
Đorđević, Vesna R., Antić, Željka, Lojpur, Vesna, Dramićanin, Miroslav, "Europium-doped nanocrystalline Y2O3 - La2O3 solid solutions with bixbyite structure" in Journal of Physics and Chemistry of Solids, 75, no. 10 (2014):1152-1159,
https://doi.org/10.1016/j.jpcs.2014.05.009 . .
11
6
11

Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties

Đačanin, Ljubica; Dramićanin, Miroslav; Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, Marko G.; Ivetić, Tamara B.; Guth, Imre O.

(2014)

TY  - JOUR
AU  - Đačanin, Ljubica
AU  - Dramićanin, Miroslav
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, Marko G.
AU  - Ivetić, Tamara B.
AU  - Guth, Imre O.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5971
AB  - In this research we prepared nanocrystalline YNbO4:Eu3+ phosphor, i.e. nanophosphor, powder using an efficient mechanochemical method followed by annealing. X-ray diffraction analysis revealed that YNbO4:Eu3+ crystallizes in monoclinic structure C2/c where, from the point of view of A and B in ABO(4) compounds, cation coordination can be noted as [6+2, 4+2]. Crystallite size of about 40 nm, was estimated using Debye Scherrers equation. Raman spectroscopy with 785 and 532 rim excitation wavelengths is performed to record a majority of materials phonon modes and to provide more in depth understanding of the YNbO4 structure. Scanning electron microscopy observations indicate that the mechanical treatment during synthesis is causing non-uniformity of the powder microstructure. High resolution photoluminescent measurements upon UV excitation showed intense emission coming from f-f transitions of the europium ion with the lifetime of 0.68 ms, suggesting that the obtained YNbO4:Eu3+ is a good potential phosphor. A comparison of emissive properties with microcrystalline YNbO4:Eu3+ was made and it showed higher values of emission intensity and lifetime of the nanocrystalline sample.(C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties
VL  - 40
IS  - 6
SP  - 8281
EP  - 8286
DO  - 10.1016/j.ceramint.2014.01.028
ER  - 
@article{
author = "Đačanin, Ljubica and Dramićanin, Miroslav and Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, Marko G. and Ivetić, Tamara B. and Guth, Imre O.",
year = "2014",
abstract = "In this research we prepared nanocrystalline YNbO4:Eu3+ phosphor, i.e. nanophosphor, powder using an efficient mechanochemical method followed by annealing. X-ray diffraction analysis revealed that YNbO4:Eu3+ crystallizes in monoclinic structure C2/c where, from the point of view of A and B in ABO(4) compounds, cation coordination can be noted as [6+2, 4+2]. Crystallite size of about 40 nm, was estimated using Debye Scherrers equation. Raman spectroscopy with 785 and 532 rim excitation wavelengths is performed to record a majority of materials phonon modes and to provide more in depth understanding of the YNbO4 structure. Scanning electron microscopy observations indicate that the mechanical treatment during synthesis is causing non-uniformity of the powder microstructure. High resolution photoluminescent measurements upon UV excitation showed intense emission coming from f-f transitions of the europium ion with the lifetime of 0.68 ms, suggesting that the obtained YNbO4:Eu3+ is a good potential phosphor. A comparison of emissive properties with microcrystalline YNbO4:Eu3+ was made and it showed higher values of emission intensity and lifetime of the nanocrystalline sample.(C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties",
volume = "40",
number = "6",
pages = "8281-8286",
doi = "10.1016/j.ceramint.2014.01.028"
}
Đačanin, L., Dramićanin, M., Lukić-Petrović, S. R., Petrović, D. M., Nikolić, M. G., Ivetić, T. B.,& Guth, I. O.. (2014). Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties. in Ceramics International, 40(6), 8281-8286.
https://doi.org/10.1016/j.ceramint.2014.01.028
Đačanin L, Dramićanin M, Lukić-Petrović SR, Petrović DM, Nikolić MG, Ivetić TB, Guth IO. Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties. in Ceramics International. 2014;40(6):8281-8286.
doi:10.1016/j.ceramint.2014.01.028 .
Đačanin, Ljubica, Dramićanin, Miroslav, Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, Marko G., Ivetić, Tamara B., Guth, Imre O., "Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties" in Ceramics International, 40, no. 6 (2014):8281-8286,
https://doi.org/10.1016/j.ceramint.2014.01.028 . .
14
9
14

Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders

Đačanin, Ljubica; Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, Marko G.; Dramićanin, Miroslav

(2014)

TY  - JOUR
AU  - Đačanin, Ljubica
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, Marko G.
AU  - Dramićanin, Miroslav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6006
AB  - We prepared Eu3+- and Sm3+-doped YNbO4 phosphor powders using a simple solid-state reaction method and examined their photoluminescence properties in order to investigate the possibility for their usage in phosphor thermometry. Photoluminescence measurements were performed in the temperature range 303-773 K, and the fluorescence intensity ratio of the paired emissions lines was studied as a function of temperature. The results have shown that YNbO4:Eu3+ possesses the absolute sensitivity of approximately 3 Chi 10(-3) K-1 at about 700 K, while relative sensitivity changes within the range of 0.5-2.7% K-1. YNbO4:Sm3+ has the maximum sensitivity of around 7 Chi 10(-4) K-1 at about 700 K with the relative sensitivity of 0.43% K-1 around 500 K. Calculated temperature sensitivities of samples show that these materials have a good potential for the development of therrnographic phosphors. Experimental lifetime measurements recorded at 303-773 K were fitted using a temperature dependent charge transfer model, TDCT. This model yields good agreement between experimental and fitted lifetime data. The sample crystalline structure is confirmed by XRD measurements. (C) 2014 Elsevier B.V. All rights reserved.
T2  - Journal of Luminescence
T1  - Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders
VL  - 151
SP  - 82
EP  - 87
DO  - 10.1016/j.jlumin.2014.02.008
ER  - 
@article{
author = "Đačanin, Ljubica and Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, Marko G. and Dramićanin, Miroslav",
year = "2014",
abstract = "We prepared Eu3+- and Sm3+-doped YNbO4 phosphor powders using a simple solid-state reaction method and examined their photoluminescence properties in order to investigate the possibility for their usage in phosphor thermometry. Photoluminescence measurements were performed in the temperature range 303-773 K, and the fluorescence intensity ratio of the paired emissions lines was studied as a function of temperature. The results have shown that YNbO4:Eu3+ possesses the absolute sensitivity of approximately 3 Chi 10(-3) K-1 at about 700 K, while relative sensitivity changes within the range of 0.5-2.7% K-1. YNbO4:Sm3+ has the maximum sensitivity of around 7 Chi 10(-4) K-1 at about 700 K with the relative sensitivity of 0.43% K-1 around 500 K. Calculated temperature sensitivities of samples show that these materials have a good potential for the development of therrnographic phosphors. Experimental lifetime measurements recorded at 303-773 K were fitted using a temperature dependent charge transfer model, TDCT. This model yields good agreement between experimental and fitted lifetime data. The sample crystalline structure is confirmed by XRD measurements. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "Journal of Luminescence",
title = "Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders",
volume = "151",
pages = "82-87",
doi = "10.1016/j.jlumin.2014.02.008"
}
Đačanin, L., Lukić-Petrović, S. R., Petrović, D. M., Nikolić, M. G.,& Dramićanin, M.. (2014). Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders. in Journal of Luminescence, 151, 82-87.
https://doi.org/10.1016/j.jlumin.2014.02.008
Đačanin L, Lukić-Petrović SR, Petrović DM, Nikolić MG, Dramićanin M. Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders. in Journal of Luminescence. 2014;151:82-87.
doi:10.1016/j.jlumin.2014.02.008 .
Đačanin, Ljubica, Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, Marko G., Dramićanin, Miroslav, "Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders" in Journal of Luminescence, 151 (2014):82-87,
https://doi.org/10.1016/j.jlumin.2014.02.008 . .
58
36
60

Comparative structural and photoluminescent study of Eu3+-doped La2O3 and La(OH)(3) nanocrystalline powders

Đorđević, Vesna R.; Antić, Željka; Nikolić, Marko G.; Dramićanin, Miroslav

(2014)

TY  - JOUR
AU  - Đorđević, Vesna R.
AU  - Antić, Željka
AU  - Nikolić, Marko G.
AU  - Dramićanin, Miroslav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5831
AB  - Eu3+-doped La2O3 nanocrystalline powder was prepared by polymer complex solution method and further used for preparation of Eu3+-doped La(OH)(3). Structural and optical characterization was carried out by powder X-ray diffraction and photoluminescent spectroscopy. XRD measurements confirmed the formation of hexagonal La2O3 and its recrystallization into La(OH)3 in a humid atmosphere. Excitation spectra show redshift of host lattice and charge transfer emission bands in La(OH)3 while bands that correspond to Eu3+- f-f transitions are placed at same wavelengths in both samples. Photoluminescence spectra recorded over the temperature range from 10 K to 300 K show that intensities of emission lines in Eu3+-doped La2O3 do not depend on temperature as much as in La(OH)3 sample. Observed dominant D-5(0) - GT :F-7(2) and markedly visible D-5(0)- GT F-7(0) emissions in doped La2O3 indicate that Eu3+ ion is located in a structural site without an inversion center. On the other hand, in Eu3+-doped La(OH)3 D-5(0)- GT F-7(0) transition is barely visible while D-5(0)- GT F-7(2) is not prominent, and with temperature drop three D-5(0)- GT F-7(j) (J=1, 2, 4) transitions become almost of the same intensity. In both La2O3 and La(OH)3 structures Eu3 ion replaces La3+ in non-centrosymmetric C-3v and C-3h crystallographic sites, respectively, and difference in symmetry of the crystal field around europium ion is explained by comparing shape and volume of these sites. Decay times of the 5D0- level recorded over the temperature range 10-300 K revealed that emission lifetime values in La2O3 (-0.7 ms) are almost two times higher than in La(OH)3 (-0.4 ms), and unlike in La2O3, lifetime in La(OH)(3) is temperature dependent. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Journal of Physics and Chemistry of Solids
T1  - Comparative structural and photoluminescent study of Eu3+-doped La2O3 and La(OH)(3) nanocrystalline powders
VL  - 75
IS  - 2
SP  - 276
EP  - 282
DO  - 10.1016/j.jpcs.2013.10.004
ER  - 
@article{
author = "Đorđević, Vesna R. and Antić, Željka and Nikolić, Marko G. and Dramićanin, Miroslav",
year = "2014",
abstract = "Eu3+-doped La2O3 nanocrystalline powder was prepared by polymer complex solution method and further used for preparation of Eu3+-doped La(OH)(3). Structural and optical characterization was carried out by powder X-ray diffraction and photoluminescent spectroscopy. XRD measurements confirmed the formation of hexagonal La2O3 and its recrystallization into La(OH)3 in a humid atmosphere. Excitation spectra show redshift of host lattice and charge transfer emission bands in La(OH)3 while bands that correspond to Eu3+- f-f transitions are placed at same wavelengths in both samples. Photoluminescence spectra recorded over the temperature range from 10 K to 300 K show that intensities of emission lines in Eu3+-doped La2O3 do not depend on temperature as much as in La(OH)3 sample. Observed dominant D-5(0) - GT :F-7(2) and markedly visible D-5(0)- GT F-7(0) emissions in doped La2O3 indicate that Eu3+ ion is located in a structural site without an inversion center. On the other hand, in Eu3+-doped La(OH)3 D-5(0)- GT F-7(0) transition is barely visible while D-5(0)- GT F-7(2) is not prominent, and with temperature drop three D-5(0)- GT F-7(j) (J=1, 2, 4) transitions become almost of the same intensity. In both La2O3 and La(OH)3 structures Eu3 ion replaces La3+ in non-centrosymmetric C-3v and C-3h crystallographic sites, respectively, and difference in symmetry of the crystal field around europium ion is explained by comparing shape and volume of these sites. Decay times of the 5D0- level recorded over the temperature range 10-300 K revealed that emission lifetime values in La2O3 (-0.7 ms) are almost two times higher than in La(OH)3 (-0.4 ms), and unlike in La2O3, lifetime in La(OH)(3) is temperature dependent. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Journal of Physics and Chemistry of Solids",
title = "Comparative structural and photoluminescent study of Eu3+-doped La2O3 and La(OH)(3) nanocrystalline powders",
volume = "75",
number = "2",
pages = "276-282",
doi = "10.1016/j.jpcs.2013.10.004"
}
Đorđević, V. R., Antić, Ž., Nikolić, M. G.,& Dramićanin, M.. (2014). Comparative structural and photoluminescent study of Eu3+-doped La2O3 and La(OH)(3) nanocrystalline powders. in Journal of Physics and Chemistry of Solids, 75(2), 276-282.
https://doi.org/10.1016/j.jpcs.2013.10.004
Đorđević VR, Antić Ž, Nikolić MG, Dramićanin M. Comparative structural and photoluminescent study of Eu3+-doped La2O3 and La(OH)(3) nanocrystalline powders. in Journal of Physics and Chemistry of Solids. 2014;75(2):276-282.
doi:10.1016/j.jpcs.2013.10.004 .
Đorđević, Vesna R., Antić, Željka, Nikolić, Marko G., Dramićanin, Miroslav, "Comparative structural and photoluminescent study of Eu3+-doped La2O3 and La(OH)(3) nanocrystalline powders" in Journal of Physics and Chemistry of Solids, 75, no. 2 (2014):276-282,
https://doi.org/10.1016/j.jpcs.2013.10.004 . .
21
18
21

Strong emission via up-conversion of Gd2O3:Yb3+, Ho3+ nanopowders co-doped with alkali metals ions

Antić, Željka; Lojpur, Vesna; Nikoic, Marko G.; Đorđević, Vesna R.; Ahrenkiel, Scott Phillip; Dramićanin, Miroslav

(2014)

TY  - JOUR
AU  - Antić, Željka
AU  - Lojpur, Vesna
AU  - Nikoic, Marko G.
AU  - Đorđević, Vesna R.
AU  - Ahrenkiel, Scott Phillip
AU  - Dramićanin, Miroslav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5867
AB  - Gadolinium-oxide nanopowders doped with Yb3+ and Ho3+ ions and co-doped with alkali metal ions (Li+ and Na+) were synthesized via the polymer complex solution method and their up-conversion emission properties are analyzed. Prepared powders were well crystallized in cubic bixbyite structure, without any impurity phases and with an average crystallite size of about 25 nm, as shown by X-ray powder diffraction analysis. No adsorbed species on the surface of nanoparticles were detected by infrared measurements. The particle morphology was analyzed by transmission electron microscopy, which revealed agglomerated crystalline nanoparticles with irregular, polygonal-like shapes, having a size in the range from 30 to 50 nm. Up-conversion emission properties of Gd2O3:Ho3+,Yb3+ nanopowders were evaluated from photoluminescence emission and decay measurements using 980 nm excitation. Two-photon up-conversion processes produced emissions in visible - near infrared spectral range, with the strongest green emission from F-5(4),S-5(2)- GT I-5(8) Ho3+ electronic transition, and weak red and near infrared from F-5(5)- GT I-5(8) and F-5(4), S-5(2) - GT I-5(7) transitions, respectively. In addition, three-photon up-conversion emission was detected in ultra-violet-blue spectral region ((5)G(4)- GT I-5(8), D-3(3)- GT I-5(6) and (5)G(5)- GT I-5(8) transitions). Luminescence measurements were performed on samples with different Ho3+ (0.5 and 1 at%) and Yb3+ (2, 4 and 6 at%) concentrations to find that 0.5 at% of Ho3+ and 2 at% of Yb3+ provides the most intense up-conversion emission. The influence of alkali metal (Li+ and Na+) ion co-doping is studied on the sample that showed the most intense up-conversion emission. Increase in the intensity of up-conversion emission is observed for both Li+ and Na+ co-doping. The effect is more pronounced with Li, where addition of 5 at% of Li+ led to more than one order of magnitude emission enhancement. Alkali metal ion co-doping also significantly improved up-conversion color purity through considerably larger increase of green emission compared to red and near infrared. (C) 2013 Elsevier B.V. All rights reserved.
T2  - Journal of Luminescence
T1  - Strong emission via up-conversion of Gd2O3:Yb3+, Ho3+ nanopowders co-doped with alkali metals ions
VL  - 145
SP  - 466
EP  - 472
DO  - 10.1016/j.jlumin.2013.08.007
ER  - 
@article{
author = "Antić, Željka and Lojpur, Vesna and Nikoic, Marko G. and Đorđević, Vesna R. and Ahrenkiel, Scott Phillip and Dramićanin, Miroslav",
year = "2014",
abstract = "Gadolinium-oxide nanopowders doped with Yb3+ and Ho3+ ions and co-doped with alkali metal ions (Li+ and Na+) were synthesized via the polymer complex solution method and their up-conversion emission properties are analyzed. Prepared powders were well crystallized in cubic bixbyite structure, without any impurity phases and with an average crystallite size of about 25 nm, as shown by X-ray powder diffraction analysis. No adsorbed species on the surface of nanoparticles were detected by infrared measurements. The particle morphology was analyzed by transmission electron microscopy, which revealed agglomerated crystalline nanoparticles with irregular, polygonal-like shapes, having a size in the range from 30 to 50 nm. Up-conversion emission properties of Gd2O3:Ho3+,Yb3+ nanopowders were evaluated from photoluminescence emission and decay measurements using 980 nm excitation. Two-photon up-conversion processes produced emissions in visible - near infrared spectral range, with the strongest green emission from F-5(4),S-5(2)- GT I-5(8) Ho3+ electronic transition, and weak red and near infrared from F-5(5)- GT I-5(8) and F-5(4), S-5(2) - GT I-5(7) transitions, respectively. In addition, three-photon up-conversion emission was detected in ultra-violet-blue spectral region ((5)G(4)- GT I-5(8), D-3(3)- GT I-5(6) and (5)G(5)- GT I-5(8) transitions). Luminescence measurements were performed on samples with different Ho3+ (0.5 and 1 at%) and Yb3+ (2, 4 and 6 at%) concentrations to find that 0.5 at% of Ho3+ and 2 at% of Yb3+ provides the most intense up-conversion emission. The influence of alkali metal (Li+ and Na+) ion co-doping is studied on the sample that showed the most intense up-conversion emission. Increase in the intensity of up-conversion emission is observed for both Li+ and Na+ co-doping. The effect is more pronounced with Li, where addition of 5 at% of Li+ led to more than one order of magnitude emission enhancement. Alkali metal ion co-doping also significantly improved up-conversion color purity through considerably larger increase of green emission compared to red and near infrared. (C) 2013 Elsevier B.V. All rights reserved.",
journal = "Journal of Luminescence",
title = "Strong emission via up-conversion of Gd2O3:Yb3+, Ho3+ nanopowders co-doped with alkali metals ions",
volume = "145",
pages = "466-472",
doi = "10.1016/j.jlumin.2013.08.007"
}
Antić, Ž., Lojpur, V., Nikoic, M. G., Đorđević, V. R., Ahrenkiel, S. P.,& Dramićanin, M.. (2014). Strong emission via up-conversion of Gd2O3:Yb3+, Ho3+ nanopowders co-doped with alkali metals ions. in Journal of Luminescence, 145, 466-472.
https://doi.org/10.1016/j.jlumin.2013.08.007
Antić Ž, Lojpur V, Nikoic MG, Đorđević VR, Ahrenkiel SP, Dramićanin M. Strong emission via up-conversion of Gd2O3:Yb3+, Ho3+ nanopowders co-doped with alkali metals ions. in Journal of Luminescence. 2014;145:466-472.
doi:10.1016/j.jlumin.2013.08.007 .
Antić, Željka, Lojpur, Vesna, Nikoic, Marko G., Đorđević, Vesna R., Ahrenkiel, Scott Phillip, Dramićanin, Miroslav, "Strong emission via up-conversion of Gd2O3:Yb3+, Ho3+ nanopowders co-doped with alkali metals ions" in Journal of Luminescence, 145 (2014):466-472,
https://doi.org/10.1016/j.jlumin.2013.08.007 . .
39
29
40

Influence of copper on hardness of amorphous As-Se-I thin films

Strbac, D. D.; Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Videnovic, I. R.; Dramićanin, Miroslav

(2014)

TY  - JOUR
AU  - Strbac, D. D.
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Videnovic, I. R.
AU  - Dramićanin, Miroslav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6021
AB  - The paper reports on hardness of thin amorphous films of the Cux(As38.5Se54I7.5)(100-x) type for x=10, 15, 20 and 25 at-% evaluated by microindentation measurements and instrumented nanoindentation testing. Values of determined microhardness are in the interval of 748-1137 MPa, while nanohardness are in the interval of 930-1591 MPa and can be regarded as moderate in the category of chalcogenide glasses. Isotropic mechanical properties on thin films surface are determined. Influence of copper on mechanical properties of As-Se-I films is discussed in terms of possible structural units in glass matrix.
T2  - Materials Science and Technology
T1  - Influence of copper on hardness of amorphous As-Se-I thin films
VL  - 30
IS  - 2
SP  - 236
EP  - 240
DO  - 10.1179/1743284713Y.0000000346
ER  - 
@article{
author = "Strbac, D. D. and Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Videnovic, I. R. and Dramićanin, Miroslav",
year = "2014",
abstract = "The paper reports on hardness of thin amorphous films of the Cux(As38.5Se54I7.5)(100-x) type for x=10, 15, 20 and 25 at-% evaluated by microindentation measurements and instrumented nanoindentation testing. Values of determined microhardness are in the interval of 748-1137 MPa, while nanohardness are in the interval of 930-1591 MPa and can be regarded as moderate in the category of chalcogenide glasses. Isotropic mechanical properties on thin films surface are determined. Influence of copper on mechanical properties of As-Se-I films is discussed in terms of possible structural units in glass matrix.",
journal = "Materials Science and Technology",
title = "Influence of copper on hardness of amorphous As-Se-I thin films",
volume = "30",
number = "2",
pages = "236-240",
doi = "10.1179/1743284713Y.0000000346"
}
Strbac, D. D., Lukić-Petrović, S. R., Petrović, D. M., Videnovic, I. R.,& Dramićanin, M.. (2014). Influence of copper on hardness of amorphous As-Se-I thin films. in Materials Science and Technology, 30(2), 236-240.
https://doi.org/10.1179/1743284713Y.0000000346
Strbac DD, Lukić-Petrović SR, Petrović DM, Videnovic IR, Dramićanin M. Influence of copper on hardness of amorphous As-Se-I thin films. in Materials Science and Technology. 2014;30(2):236-240.
doi:10.1179/1743284713Y.0000000346 .
Strbac, D. D., Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Videnovic, I. R., Dramićanin, Miroslav, "Influence of copper on hardness of amorphous As-Se-I thin films" in Materials Science and Technology, 30, no. 2 (2014):236-240,
https://doi.org/10.1179/1743284713Y.0000000346 . .
1

Yb3+, Er3+ doped Y2O3 nanoparticles of different shapes prepared by self-propagating room temperature reaction method

Lojpur, Vesna; Ahrenkiel, Scott Phillip; Dramićanin, Miroslav

(2014)

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Ahrenkiel, Scott Phillip
AU  - Dramićanin, Miroslav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/197
AB  - In this report, a cost- and time-effective method for synthesis of Y2O3:Yb3+, Er3+ nanoparticles that exhibit up-conversion emission under infrared excitation is presented. The synthesis method is based on the self-propagating, room-temperature reaction between metal nitrates and sodium hydroxide, and a subsequent calcination process. Series of samples were prepared with calcinations at various temperatures (600 degrees C, 800 degrees C and 1100 degrees C) for 1 h, and also with different Yb3+-Er3+ ratios (10:1, 5:1 and 2:1). All calcined samples crystallized in a cubic bixbyite crystal phase with crystallite size from 12 to 44 nm in diameter, for samples calcined at 600 degrees C and 1100 degrees C, respectively. Different nanoparticle morphologies were obtained after calcinations on different temperatures; at temperatures under 1100 degrees C rod-like particles were obtained, while at 1100 degrees C spherical particles were formed. In all samples up-conversion emissions and corresponding lifetimes were measured after excitation in room temperature at 978 nm. The most intense emission originates from the characteristic intra-shell f-f electronic transitions of Er3+ ions: [2H(9/2)- GT I-4(15/2)] in blue (407-420 nm); [(H-2(11/2), S-4(3/2))- GT I-4(15/2)] green: 510-590 nm; and [F-4(9/2)- GT I-4(15/2)] in red (640-720 nm) spectral regions. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Yb3+, Er3+ doped Y2O3 nanoparticles of different shapes prepared by self-propagating room temperature reaction method
VL  - 40
IS  - 10
SP  - 16033
EP  - 16039
DO  - 10.1016/j.ceramint.2014.07.139
ER  - 
@article{
author = "Lojpur, Vesna and Ahrenkiel, Scott Phillip and Dramićanin, Miroslav",
year = "2014",
abstract = "In this report, a cost- and time-effective method for synthesis of Y2O3:Yb3+, Er3+ nanoparticles that exhibit up-conversion emission under infrared excitation is presented. The synthesis method is based on the self-propagating, room-temperature reaction between metal nitrates and sodium hydroxide, and a subsequent calcination process. Series of samples were prepared with calcinations at various temperatures (600 degrees C, 800 degrees C and 1100 degrees C) for 1 h, and also with different Yb3+-Er3+ ratios (10:1, 5:1 and 2:1). All calcined samples crystallized in a cubic bixbyite crystal phase with crystallite size from 12 to 44 nm in diameter, for samples calcined at 600 degrees C and 1100 degrees C, respectively. Different nanoparticle morphologies were obtained after calcinations on different temperatures; at temperatures under 1100 degrees C rod-like particles were obtained, while at 1100 degrees C spherical particles were formed. In all samples up-conversion emissions and corresponding lifetimes were measured after excitation in room temperature at 978 nm. The most intense emission originates from the characteristic intra-shell f-f electronic transitions of Er3+ ions: [2H(9/2)- GT I-4(15/2)] in blue (407-420 nm); [(H-2(11/2), S-4(3/2))- GT I-4(15/2)] green: 510-590 nm; and [F-4(9/2)- GT I-4(15/2)] in red (640-720 nm) spectral regions. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Yb3+, Er3+ doped Y2O3 nanoparticles of different shapes prepared by self-propagating room temperature reaction method",
volume = "40",
number = "10",
pages = "16033-16039",
doi = "10.1016/j.ceramint.2014.07.139"
}
Lojpur, V., Ahrenkiel, S. P.,& Dramićanin, M.. (2014). Yb3+, Er3+ doped Y2O3 nanoparticles of different shapes prepared by self-propagating room temperature reaction method. in Ceramics International, 40(10), 16033-16039.
https://doi.org/10.1016/j.ceramint.2014.07.139
Lojpur V, Ahrenkiel SP, Dramićanin M. Yb3+, Er3+ doped Y2O3 nanoparticles of different shapes prepared by self-propagating room temperature reaction method. in Ceramics International. 2014;40(10):16033-16039.
doi:10.1016/j.ceramint.2014.07.139 .
Lojpur, Vesna, Ahrenkiel, Scott Phillip, Dramićanin, Miroslav, "Yb3+, Er3+ doped Y2O3 nanoparticles of different shapes prepared by self-propagating room temperature reaction method" in Ceramics International, 40, no. 10 (2014):16033-16039,
https://doi.org/10.1016/j.ceramint.2014.07.139 . .
16
11
15

Annealing and Doping Concentration Effects on Y2O3: Sm3+ Nanopowder Obtained by Self-Propagation Room Temperature Reaction

Ćulubrk, Sanja; Lojpur, Vesna; Đorđević, Vesna R.; Dramićanin, Miroslav

(2013)

TY  - JOUR
AU  - Ćulubrk, Sanja
AU  - Lojpur, Vesna
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6080
AB  - In this report, structure, morphology and luminescence of Y2O3:Sm3+ nanoparticles prepared by self-propagating room temperature reaction are presented. This new, simple and cost effective synthesis allows obtaining desired phase composition by mixing appropriate amounts of yttrium and samarium nitrates together with sodium hydroxide. A set of samples is prepared with different Sm3+ concentrations (0.1, 0.2, 0.5, 1 and 2 at %) in order to observe changes of luminescence properties. Also, effects of post synthesis annealing at several temperatures (600 degrees C, 800 degrees C and 1100 degrees C) are analyzed. For all samples X-ray diffraction showed that powders have cubic bixbyite structure (I alpha-3), and TEM analysis showed particles of less than 100 nm. Luminescence emission spectra clearly show peaks characteristic for electronic spin-forbidden transition of Sm3+ ions (4)G(5/2)- GT H-6(5/2), H-6(7/2) and H-6(9/2) centered at 578, 607 and 654 nm, respectively. Emission lifetime values decrease with Sm3+ ion concentration increment, from 1.94 ms for 0.1 at% to 0.97 ms for 2 at%. In addition, enlargement of lifetime value is observed when thermal treatment is done at the highest temperature due to the elimination of luminescence quenching species from the surface of particles.
T2  - Science of Sintering
T1  - Annealing and Doping Concentration Effects on Y2O3: Sm3+ Nanopowder Obtained by Self-Propagation Room Temperature Reaction
VL  - 45
IS  - 3
SP  - 323
EP  - 329
DO  - 10.2298/SOS1303323C
ER  - 
@article{
author = "Ćulubrk, Sanja and Lojpur, Vesna and Đorđević, Vesna R. and Dramićanin, Miroslav",
year = "2013",
abstract = "In this report, structure, morphology and luminescence of Y2O3:Sm3+ nanoparticles prepared by self-propagating room temperature reaction are presented. This new, simple and cost effective synthesis allows obtaining desired phase composition by mixing appropriate amounts of yttrium and samarium nitrates together with sodium hydroxide. A set of samples is prepared with different Sm3+ concentrations (0.1, 0.2, 0.5, 1 and 2 at %) in order to observe changes of luminescence properties. Also, effects of post synthesis annealing at several temperatures (600 degrees C, 800 degrees C and 1100 degrees C) are analyzed. For all samples X-ray diffraction showed that powders have cubic bixbyite structure (I alpha-3), and TEM analysis showed particles of less than 100 nm. Luminescence emission spectra clearly show peaks characteristic for electronic spin-forbidden transition of Sm3+ ions (4)G(5/2)- GT H-6(5/2), H-6(7/2) and H-6(9/2) centered at 578, 607 and 654 nm, respectively. Emission lifetime values decrease with Sm3+ ion concentration increment, from 1.94 ms for 0.1 at% to 0.97 ms for 2 at%. In addition, enlargement of lifetime value is observed when thermal treatment is done at the highest temperature due to the elimination of luminescence quenching species from the surface of particles.",
journal = "Science of Sintering",
title = "Annealing and Doping Concentration Effects on Y2O3: Sm3+ Nanopowder Obtained by Self-Propagation Room Temperature Reaction",
volume = "45",
number = "3",
pages = "323-329",
doi = "10.2298/SOS1303323C"
}
Ćulubrk, S., Lojpur, V., Đorđević, V. R.,& Dramićanin, M.. (2013). Annealing and Doping Concentration Effects on Y2O3: Sm3+ Nanopowder Obtained by Self-Propagation Room Temperature Reaction. in Science of Sintering, 45(3), 323-329.
https://doi.org/10.2298/SOS1303323C
Ćulubrk S, Lojpur V, Đorđević VR, Dramićanin M. Annealing and Doping Concentration Effects on Y2O3: Sm3+ Nanopowder Obtained by Self-Propagation Room Temperature Reaction. in Science of Sintering. 2013;45(3):323-329.
doi:10.2298/SOS1303323C .
Ćulubrk, Sanja, Lojpur, Vesna, Đorđević, Vesna R., Dramićanin, Miroslav, "Annealing and Doping Concentration Effects on Y2O3: Sm3+ Nanopowder Obtained by Self-Propagation Room Temperature Reaction" in Science of Sintering, 45, no. 3 (2013):323-329,
https://doi.org/10.2298/SOS1303323C . .
5
3
5

Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder

Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, M.; Đačanin, Ljubica; Dramićanin, Miroslav

(2013)

TY  - JOUR
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, M.
AU  - Đačanin, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5530
AB  - Phosphor materials are of special interest due to their important applications ranging from solid state lightning and displays to biomedicine. Understanding the spectroscopic properties of these materials is important for optimizing their emission for technological applications. Zinc silicate (Zn2SiO4) has been identified as a very suitable host matrix for many rare-earth and transition metal dopant ions with excellent luminescent properties in the blue, green and red spectral zones. Here, we present high resolution measurements of low-temperature photoluminescence of trivalent europium doped zinc silicate particles prepared by combination of so-gel and combustion synthesis route. We observed and analyzed 5D(0) - GT F-7(J) spin forbidden f-f electronic transitions at low temperatures, as well as emission kinetics from D-5(0) level and lifetime-temperature dependence.
T2  - Optoelectronics and Advanced Materials - Rapid Communications
T1  - Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder
VL  - 7
IS  - 3-4
SP  - 290
EP  - 292
UR  - https://hdl.handle.net/21.15107/rcub_vinar_5530
ER  - 
@article{
author = "Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, M. and Đačanin, Ljubica and Dramićanin, Miroslav",
year = "2013",
abstract = "Phosphor materials are of special interest due to their important applications ranging from solid state lightning and displays to biomedicine. Understanding the spectroscopic properties of these materials is important for optimizing their emission for technological applications. Zinc silicate (Zn2SiO4) has been identified as a very suitable host matrix for many rare-earth and transition metal dopant ions with excellent luminescent properties in the blue, green and red spectral zones. Here, we present high resolution measurements of low-temperature photoluminescence of trivalent europium doped zinc silicate particles prepared by combination of so-gel and combustion synthesis route. We observed and analyzed 5D(0) - GT F-7(J) spin forbidden f-f electronic transitions at low temperatures, as well as emission kinetics from D-5(0) level and lifetime-temperature dependence.",
journal = "Optoelectronics and Advanced Materials - Rapid Communications",
title = "Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder",
volume = "7",
number = "3-4",
pages = "290-292",
url = "https://hdl.handle.net/21.15107/rcub_vinar_5530"
}
Lukić-Petrović, S. R., Petrović, D. M., Nikolić, M., Đačanin, L.,& Dramićanin, M.. (2013). Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder. in Optoelectronics and Advanced Materials - Rapid Communications, 7(3-4), 290-292.
https://hdl.handle.net/21.15107/rcub_vinar_5530
Lukić-Petrović SR, Petrović DM, Nikolić M, Đačanin L, Dramićanin M. Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder. in Optoelectronics and Advanced Materials - Rapid Communications. 2013;7(3-4):290-292.
https://hdl.handle.net/21.15107/rcub_vinar_5530 .
Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, M., Đačanin, Ljubica, Dramićanin, Miroslav, "Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder" in Optoelectronics and Advanced Materials - Rapid Communications, 7, no. 3-4 (2013):290-292,
https://hdl.handle.net/21.15107/rcub_vinar_5530 .

Y2O3:Yb,Tm and Y2O3:Yb,Ho powders for low-temperature thermometry based on up-conversion fluorescence

Lojpur, Vesna; Nikolić, M.; Mančić, Lidija; Milošević, Olivera; Dramićanin, Miroslav

(2013)

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Nikolić, M.
AU  - Mančić, Lidija
AU  - Milošević, Olivera
AU  - Dramićanin, Miroslav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5257
AB  - Recently, trivalent rare earth doped materials have received significant attention due to the strong temperature dependence of the fluorescence emission of these materials, which can be useful in temperature sensing. Here, we investigated Y2O3 ceramic powders doped with Yb3+ and co-doped with either Tm3+ or Ho3+. The powders were obtained via spray pyrolysis at 900 degrees C and additionally thermally treated at 1100 degrees C for 24 h. Structural characterization using X-ray powder diffraction confirmed the cubic bixbyte structure. Scanning electron microscopy (SEM) revealed that the particles exhibit a uniform spherical morphology. The up-conversion emissions were measured using laser excitation at 978 nm, resulting in the following transitions: blue emission in the range of 450-500 nm, weak red emission in the range of 650-680 nm and near infrared emission in the range of 765-840 nm for Tm3+, as well as green emission centered at 550 nm and weak near infrared emission at 755 nm for the Ho3+ ions. In addition, the temperature dependence of the fluorescence intensity ratios of different Stark components was analyzed in the range of 10-300 K. Significant temperature sensitivity was detected for several components, with the largest value of 0.097 K-1 related to the intensity ratio of I-536 and I-772 emissions observed for the Y2O3:Yb,Ho powder. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Y2O3:Yb,Tm and Y2O3:Yb,Ho powders for low-temperature thermometry based on up-conversion fluorescence
VL  - 39
IS  - 2
SP  - 1129
EP  - 1134
DO  - 10.1016/j.ceramint.2012.07.036
ER  - 
@article{
author = "Lojpur, Vesna and Nikolić, M. and Mančić, Lidija and Milošević, Olivera and Dramićanin, Miroslav",
year = "2013",
abstract = "Recently, trivalent rare earth doped materials have received significant attention due to the strong temperature dependence of the fluorescence emission of these materials, which can be useful in temperature sensing. Here, we investigated Y2O3 ceramic powders doped with Yb3+ and co-doped with either Tm3+ or Ho3+. The powders were obtained via spray pyrolysis at 900 degrees C and additionally thermally treated at 1100 degrees C for 24 h. Structural characterization using X-ray powder diffraction confirmed the cubic bixbyte structure. Scanning electron microscopy (SEM) revealed that the particles exhibit a uniform spherical morphology. The up-conversion emissions were measured using laser excitation at 978 nm, resulting in the following transitions: blue emission in the range of 450-500 nm, weak red emission in the range of 650-680 nm and near infrared emission in the range of 765-840 nm for Tm3+, as well as green emission centered at 550 nm and weak near infrared emission at 755 nm for the Ho3+ ions. In addition, the temperature dependence of the fluorescence intensity ratios of different Stark components was analyzed in the range of 10-300 K. Significant temperature sensitivity was detected for several components, with the largest value of 0.097 K-1 related to the intensity ratio of I-536 and I-772 emissions observed for the Y2O3:Yb,Ho powder. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Y2O3:Yb,Tm and Y2O3:Yb,Ho powders for low-temperature thermometry based on up-conversion fluorescence",
volume = "39",
number = "2",
pages = "1129-1134",
doi = "10.1016/j.ceramint.2012.07.036"
}
Lojpur, V., Nikolić, M., Mančić, L., Milošević, O.,& Dramićanin, M.. (2013). Y2O3:Yb,Tm and Y2O3:Yb,Ho powders for low-temperature thermometry based on up-conversion fluorescence. in Ceramics International, 39(2), 1129-1134.
https://doi.org/10.1016/j.ceramint.2012.07.036
Lojpur V, Nikolić M, Mančić L, Milošević O, Dramićanin M. Y2O3:Yb,Tm and Y2O3:Yb,Ho powders for low-temperature thermometry based on up-conversion fluorescence. in Ceramics International. 2013;39(2):1129-1134.
doi:10.1016/j.ceramint.2012.07.036 .
Lojpur, Vesna, Nikolić, M., Mančić, Lidija, Milošević, Olivera, Dramićanin, Miroslav, "Y2O3:Yb,Tm and Y2O3:Yb,Ho powders for low-temperature thermometry based on up-conversion fluorescence" in Ceramics International, 39, no. 2 (2013):1129-1134,
https://doi.org/10.1016/j.ceramint.2012.07.036 . .
135
100
132

Eu3+-doped (Y0.5La0.5)(2)O-3: new nanophosphor with the bixbyite cubic structure

Đorđević, Vesna R.; Nikolić, Marko G.; Bartova, Barbora; Krsmanović, Radenka; Antić, Željka; Dramićanin, Miroslav

(2013)

TY  - JOUR
AU  - Đorđević, Vesna R.
AU  - Nikolić, Marko G.
AU  - Bartova, Barbora
AU  - Krsmanović, Radenka
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5494
AB  - New red sesquioxide phosphor, Eu(3+)doped (Y0.5La0.5)(2)O-3, was synthesized in the form of nanocrystalline powder with excellent structural ordering in cubic bixbyite-type, and with nanoparticle sizes ranging between 10 and 20 nm. Photoluminescence measurements show strong, Eu3+ characteristic, red emission (x = 0.66 and y = 0.34 CIE color coordinates) with an average D-5(0) emission lifetime of about 1.3 ms. Maximum splitting of the F-7(1) manifold of the Eu3+ ion emission behaves in a way directly proportional to the crystal field strength parameter, and experimental results show perfect agreement with theoretical values for pure cubic sesquioxides. This could be used as an indicator of complete dissolution of Y2O3 and La2O3, showing that (Y0.5La0.5)(2)O-3:Eu3+ behaves as a new bixbyite structure oxide, M2O3, where M acts as an ion having average ionic radius of constituting Y3+ and La3+. Emission properties of this new phosphor were documented with detailed assignments of Eu3+ energy levels at 10 K and at room temperature. Second order crystal field parameters were found to be B-20 = -66 cm(-1) and B-22 = -665 cm(-1) at 10 K and B-20 = -78 cm(-1) and B-22 = -602 cm(-1) at room temperature, while for the crystal field strength the value of 1495 cm(-1) was calculated at 10 K and 1355 cm(-1) at room temperature.
T2  - Journal of Nanoparticle Research
T1  - Eu3+-doped (Y0.5La0.5)(2)O-3: new nanophosphor with the bixbyite cubic structure
VL  - 15
IS  - 1
DO  - 10.1007/s11051-012-1322-6
ER  - 
@article{
author = "Đorđević, Vesna R. and Nikolić, Marko G. and Bartova, Barbora and Krsmanović, Radenka and Antić, Željka and Dramićanin, Miroslav",
year = "2013",
abstract = "New red sesquioxide phosphor, Eu(3+)doped (Y0.5La0.5)(2)O-3, was synthesized in the form of nanocrystalline powder with excellent structural ordering in cubic bixbyite-type, and with nanoparticle sizes ranging between 10 and 20 nm. Photoluminescence measurements show strong, Eu3+ characteristic, red emission (x = 0.66 and y = 0.34 CIE color coordinates) with an average D-5(0) emission lifetime of about 1.3 ms. Maximum splitting of the F-7(1) manifold of the Eu3+ ion emission behaves in a way directly proportional to the crystal field strength parameter, and experimental results show perfect agreement with theoretical values for pure cubic sesquioxides. This could be used as an indicator of complete dissolution of Y2O3 and La2O3, showing that (Y0.5La0.5)(2)O-3:Eu3+ behaves as a new bixbyite structure oxide, M2O3, where M acts as an ion having average ionic radius of constituting Y3+ and La3+. Emission properties of this new phosphor were documented with detailed assignments of Eu3+ energy levels at 10 K and at room temperature. Second order crystal field parameters were found to be B-20 = -66 cm(-1) and B-22 = -665 cm(-1) at 10 K and B-20 = -78 cm(-1) and B-22 = -602 cm(-1) at room temperature, while for the crystal field strength the value of 1495 cm(-1) was calculated at 10 K and 1355 cm(-1) at room temperature.",
journal = "Journal of Nanoparticle Research",
title = "Eu3+-doped (Y0.5La0.5)(2)O-3: new nanophosphor with the bixbyite cubic structure",
volume = "15",
number = "1",
doi = "10.1007/s11051-012-1322-6"
}
Đorđević, V. R., Nikolić, M. G., Bartova, B., Krsmanović, R., Antić, Ž.,& Dramićanin, M.. (2013). Eu3+-doped (Y0.5La0.5)(2)O-3: new nanophosphor with the bixbyite cubic structure. in Journal of Nanoparticle Research, 15(1).
https://doi.org/10.1007/s11051-012-1322-6
Đorđević VR, Nikolić MG, Bartova B, Krsmanović R, Antić Ž, Dramićanin M. Eu3+-doped (Y0.5La0.5)(2)O-3: new nanophosphor with the bixbyite cubic structure. in Journal of Nanoparticle Research. 2013;15(1).
doi:10.1007/s11051-012-1322-6 .
Đorđević, Vesna R., Nikolić, Marko G., Bartova, Barbora, Krsmanović, Radenka, Antić, Željka, Dramićanin, Miroslav, "Eu3+-doped (Y0.5La0.5)(2)O-3: new nanophosphor with the bixbyite cubic structure" in Journal of Nanoparticle Research, 15, no. 1 (2013),
https://doi.org/10.1007/s11051-012-1322-6 . .
6
6
6

Temperature luminescence properties of Eu3+-doped Gd2O3 phosphors

Nikolić, Marko G.; Al-Juboori, A. Z.; Đorđević, Vesna R.; Dramićanin, Miroslav

(2013)

TY  - JOUR
AU  - Nikolić, Marko G.
AU  - Al-Juboori, A. Z.
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7025
AB  - Rare earth (RE) oxides are important hosts for the luminescence of RE activators with numerous practical applications in light-emitting devices. In this work, we investigated the possibility for Gd2O3: Eu3+ usage in phosphor thermometry by observing the temperature changes of trivalent europium ion transitions from the D-5(0) and D-5(1) energy levels to the ground-state levels. A set of three samples of Eu3+-doped Gd2O3 (1, 5 and 10 at.% Eu3+) was produced via combustion synthesis. The sample crystalline structure is confirmed by XRD measurements. The intensity ratio of the two emission lines was studied as a function of temperature in the temperature range 300-800 K, and lifetime was measured in the interval 10-800 K. All three Gd2O3: Eu3+ samples proved to have good potential for the development of thermographic phosphors.
T2  - Physica Scripta
T1  - Temperature luminescence properties of Eu3+-doped Gd2O3 phosphors
VL  - T157
DO  - 10.1088/0031-8949/2013/T157/014056
ER  - 
@article{
author = "Nikolić, Marko G. and Al-Juboori, A. Z. and Đorđević, Vesna R. and Dramićanin, Miroslav",
year = "2013",
abstract = "Rare earth (RE) oxides are important hosts for the luminescence of RE activators with numerous practical applications in light-emitting devices. In this work, we investigated the possibility for Gd2O3: Eu3+ usage in phosphor thermometry by observing the temperature changes of trivalent europium ion transitions from the D-5(0) and D-5(1) energy levels to the ground-state levels. A set of three samples of Eu3+-doped Gd2O3 (1, 5 and 10 at.% Eu3+) was produced via combustion synthesis. The sample crystalline structure is confirmed by XRD measurements. The intensity ratio of the two emission lines was studied as a function of temperature in the temperature range 300-800 K, and lifetime was measured in the interval 10-800 K. All three Gd2O3: Eu3+ samples proved to have good potential for the development of thermographic phosphors.",
journal = "Physica Scripta",
title = "Temperature luminescence properties of Eu3+-doped Gd2O3 phosphors",
volume = "T157",
doi = "10.1088/0031-8949/2013/T157/014056"
}
Nikolić, M. G., Al-Juboori, A. Z., Đorđević, V. R.,& Dramićanin, M.. (2013). Temperature luminescence properties of Eu3+-doped Gd2O3 phosphors. in Physica Scripta, T157.
https://doi.org/10.1088/0031-8949/2013/T157/014056
Nikolić MG, Al-Juboori AZ, Đorđević VR, Dramićanin M. Temperature luminescence properties of Eu3+-doped Gd2O3 phosphors. in Physica Scripta. 2013;T157.
doi:10.1088/0031-8949/2013/T157/014056 .
Nikolić, Marko G., Al-Juboori, A. Z., Đorđević, Vesna R., Dramićanin, Miroslav, "Temperature luminescence properties of Eu3+-doped Gd2O3 phosphors" in Physica Scripta, T157 (2013),
https://doi.org/10.1088/0031-8949/2013/T157/014056 . .
21
19
23

Thermographic properties of Sm3+-doped GdVO4 phosphor

Nikolić, Marko G.; Jovanović, Dragana J.; Đorđević, Vesna R.; Antić, Željka; Krsmanović, Radenka; Dramićanin, Miroslav

(2012)

TY  - JOUR
AU  - Nikolić, Marko G.
AU  - Jovanović, Dragana J.
AU  - Đorđević, Vesna R.
AU  - Antić, Željka
AU  - Krsmanović, Radenka
AU  - Dramićanin, Miroslav
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6952
AB  - Rare-earth orthovanadates are important hosts for the luminescence of rare earth activators with considerable practical applications in the artificial production of light. In this paper we investigated the possibility for GdVO4:Sm3+ usage in phosphor thermometry by observing the temperature changes of trivalent samarium transitions from F-4(3/2) and (4)G(5/2) energy levels to the ground state. A set of three samples of Sm3+-doped GdVO4 (0.5, 1 and 2 mol.% Sm3+ with respect to Gd3+ ions) was produced via solid state synthesis. The sample crystalline structure is confirmed from x-ray diffraction (XRD) measurements. Photoluminescence measurements were recorded in the temperature range 293-823 K and the fluorescence intensity ratio of the paired emissions bands was studied as a function of temperature. All three GdVO4:Sm3+ samples proved to have good potential for the development of thermographic phosphors, whereas the maximum sensitivity of approximately 4.5x10(-4) K-1 was found for the sample with 2 mol.% Sm3+ in the temperature region around 750 K.
T2  - Physica Scripta
T1  - Thermographic properties of Sm3+-doped GdVO4 phosphor
VL  - T149
DO  - 10.1088/0031-8949/2012/T149/014063
ER  - 
@article{
author = "Nikolić, Marko G. and Jovanović, Dragana J. and Đorđević, Vesna R. and Antić, Željka and Krsmanović, Radenka and Dramićanin, Miroslav",
year = "2012",
abstract = "Rare-earth orthovanadates are important hosts for the luminescence of rare earth activators with considerable practical applications in the artificial production of light. In this paper we investigated the possibility for GdVO4:Sm3+ usage in phosphor thermometry by observing the temperature changes of trivalent samarium transitions from F-4(3/2) and (4)G(5/2) energy levels to the ground state. A set of three samples of Sm3+-doped GdVO4 (0.5, 1 and 2 mol.% Sm3+ with respect to Gd3+ ions) was produced via solid state synthesis. The sample crystalline structure is confirmed from x-ray diffraction (XRD) measurements. Photoluminescence measurements were recorded in the temperature range 293-823 K and the fluorescence intensity ratio of the paired emissions bands was studied as a function of temperature. All three GdVO4:Sm3+ samples proved to have good potential for the development of thermographic phosphors, whereas the maximum sensitivity of approximately 4.5x10(-4) K-1 was found for the sample with 2 mol.% Sm3+ in the temperature region around 750 K.",
journal = "Physica Scripta",
title = "Thermographic properties of Sm3+-doped GdVO4 phosphor",
volume = "T149",
doi = "10.1088/0031-8949/2012/T149/014063"
}
Nikolić, M. G., Jovanović, D. J., Đorđević, V. R., Antić, Ž., Krsmanović, R.,& Dramićanin, M.. (2012). Thermographic properties of Sm3+-doped GdVO4 phosphor. in Physica Scripta, T149.
https://doi.org/10.1088/0031-8949/2012/T149/014063
Nikolić MG, Jovanović DJ, Đorđević VR, Antić Ž, Krsmanović R, Dramićanin M. Thermographic properties of Sm3+-doped GdVO4 phosphor. in Physica Scripta. 2012;T149.
doi:10.1088/0031-8949/2012/T149/014063 .
Nikolić, Marko G., Jovanović, Dragana J., Đorđević, Vesna R., Antić, Željka, Krsmanović, Radenka, Dramićanin, Miroslav, "Thermographic properties of Sm3+-doped GdVO4 phosphor" in Physica Scripta, T149 (2012),
https://doi.org/10.1088/0031-8949/2012/T149/014063 . .
30
18
32

Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2

Đačanin, Ljubica; Dramićanin, Miroslav; Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, Marko G.

(2012)

TY  - JOUR
AU  - Đačanin, Ljubica
AU  - Dramićanin, Miroslav
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, Marko G.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4356
AB  - Lithium-indium oxide is a high-density (5.9 g center dot cm(-3)), wide band-gap semiconductor with promising applications for scintillating detection of solar neutrinos as well as for efficient phosphorescence when doped with Er3+ or Sm3+ ions. In this report, we demonstrate visible upconversion emission of Er3+-doped LiInO2 synthesized by a simple solid-state chemistry procedure and discuss mechanisms responsible for pumping the Er3+ ions to upper levels. Intense upconversion emission is observed in the green and red spectral regions under near-infrared excitation, and it is greatly enhanced by co-doping with Yb3+ ions. We also examined the upconversion intensity change as a function of temperature, and, consequently, possible applications of this material as a low-temperature sensor.
T2  - Central European Journal of Physics
T1  - Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2
VL  - 10
IS  - 2
SP  - 519
EP  - 523
DO  - 10.2478/s11534-012-0009-z
ER  - 
@article{
author = "Đačanin, Ljubica and Dramićanin, Miroslav and Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, Marko G.",
year = "2012",
abstract = "Lithium-indium oxide is a high-density (5.9 g center dot cm(-3)), wide band-gap semiconductor with promising applications for scintillating detection of solar neutrinos as well as for efficient phosphorescence when doped with Er3+ or Sm3+ ions. In this report, we demonstrate visible upconversion emission of Er3+-doped LiInO2 synthesized by a simple solid-state chemistry procedure and discuss mechanisms responsible for pumping the Er3+ ions to upper levels. Intense upconversion emission is observed in the green and red spectral regions under near-infrared excitation, and it is greatly enhanced by co-doping with Yb3+ ions. We also examined the upconversion intensity change as a function of temperature, and, consequently, possible applications of this material as a low-temperature sensor.",
journal = "Central European Journal of Physics",
title = "Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2",
volume = "10",
number = "2",
pages = "519-523",
doi = "10.2478/s11534-012-0009-z"
}
Đačanin, L., Dramićanin, M., Lukić-Petrović, S. R., Petrović, D. M.,& Nikolić, M. G.. (2012). Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2. in Central European Journal of Physics, 10(2), 519-523.
https://doi.org/10.2478/s11534-012-0009-z
Đačanin L, Dramićanin M, Lukić-Petrović SR, Petrović DM, Nikolić MG. Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2. in Central European Journal of Physics. 2012;10(2):519-523.
doi:10.2478/s11534-012-0009-z .
Đačanin, Ljubica, Dramićanin, Miroslav, Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, Marko G., "Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2" in Central European Journal of Physics, 10, no. 2 (2012):519-523,
https://doi.org/10.2478/s11534-012-0009-z . .
1
1
3
4

Thermographic properties of Eu3+- and Sm3+-doped Lu2O3 nanophosphor

Lojpur, Vesna; Antić, Željka; Krsmanović, Radenka; Medić, Mina M.; Nikolić, Marko G.; Dramićanin, Miroslav

(2012)

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Antić, Željka
AU  - Krsmanović, Radenka
AU  - Medić, Mina M.
AU  - Nikolić, Marko G.
AU  - Dramićanin, Miroslav
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5280
AB  - Samples of Lu2O3:Eu3+ (3 at. % Eu) and Lu2O3:Sm3+ (1 at. % Sm), were prepared via the polymer complex solution method using poly(ethylene glycol) as the fuel and as nucleation agent for crystallization process. Knowing that lutetium oxide has high chemical stability and temperature resistance, in this study, the possibility for its application in high-temperature phosphor thermometry was investigated. This non-contact technique uses the thermal dependence of phosphor fluorescence to measure temperature remotely. The structural and morphological properties were investigated by X-ray powder diffraction (XRPD) analysis and transmission electron microscopy (TEM). The obtained results confirmed that this synthesis yields the desired crystalline structure with particle sizes in the range from 30 to 50 nm. Photoluminescence emission measurements were recorded in the temperature range from ambient up to 873 K. The obtained results demonstrated the performance of Eu3+- and Sm3+-doped Lu2O3 as high temperature thermographic phosphors of very good sensitivity.
T2  - Journal of the Serbian Chemical Society
T1  - Thermographic properties of Eu3+- and Sm3+-doped Lu2O3 nanophosphor
VL  - 77
IS  - 12
SP  - 1735
EP  - 1746
DO  - 10.2298/JSC121021140L
ER  - 
@article{
author = "Lojpur, Vesna and Antić, Željka and Krsmanović, Radenka and Medić, Mina M. and Nikolić, Marko G. and Dramićanin, Miroslav",
year = "2012",
abstract = "Samples of Lu2O3:Eu3+ (3 at. % Eu) and Lu2O3:Sm3+ (1 at. % Sm), were prepared via the polymer complex solution method using poly(ethylene glycol) as the fuel and as nucleation agent for crystallization process. Knowing that lutetium oxide has high chemical stability and temperature resistance, in this study, the possibility for its application in high-temperature phosphor thermometry was investigated. This non-contact technique uses the thermal dependence of phosphor fluorescence to measure temperature remotely. The structural and morphological properties were investigated by X-ray powder diffraction (XRPD) analysis and transmission electron microscopy (TEM). The obtained results confirmed that this synthesis yields the desired crystalline structure with particle sizes in the range from 30 to 50 nm. Photoluminescence emission measurements were recorded in the temperature range from ambient up to 873 K. The obtained results demonstrated the performance of Eu3+- and Sm3+-doped Lu2O3 as high temperature thermographic phosphors of very good sensitivity.",
journal = "Journal of the Serbian Chemical Society",
title = "Thermographic properties of Eu3+- and Sm3+-doped Lu2O3 nanophosphor",
volume = "77",
number = "12",
pages = "1735-1746",
doi = "10.2298/JSC121021140L"
}
Lojpur, V., Antić, Ž., Krsmanović, R., Medić, M. M., Nikolić, M. G.,& Dramićanin, M.. (2012). Thermographic properties of Eu3+- and Sm3+-doped Lu2O3 nanophosphor. in Journal of the Serbian Chemical Society, 77(12), 1735-1746.
https://doi.org/10.2298/JSC121021140L
Lojpur V, Antić Ž, Krsmanović R, Medić MM, Nikolić MG, Dramićanin M. Thermographic properties of Eu3+- and Sm3+-doped Lu2O3 nanophosphor. in Journal of the Serbian Chemical Society. 2012;77(12):1735-1746.
doi:10.2298/JSC121021140L .
Lojpur, Vesna, Antić, Željka, Krsmanović, Radenka, Medić, Mina M., Nikolić, Marko G., Dramićanin, Miroslav, "Thermographic properties of Eu3+- and Sm3+-doped Lu2O3 nanophosphor" in Journal of the Serbian Chemical Society, 77, no. 12 (2012):1735-1746,
https://doi.org/10.2298/JSC121021140L . .
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