AP Vojvodina Provincial Secretariat for Higher Education and Scientific Research (“Properties and electrical characteristics of doped amorphous chalcogenide materials and nanostructured ceramics”, project no. 142-451-2362/2018-04)

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AP Vojvodina Provincial Secretariat for Higher Education and Scientific Research (“Properties and electrical characteristics of doped amorphous chalcogenide materials and nanostructured ceramics”, project no. 142-451-2362/2018-04)

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Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization

Ivetić, Tamara B.; Sekulić, Dalibor L.; Papan, Jelena; Guth, Imre O.; Petrović, Dragoslav M.; Lukić-Petrović, Svetlana R.

(2018)

TY  - JOUR
AU  - Ivetić, Tamara B.
AU  - Sekulić, Dalibor L.
AU  - Papan, Jelena
AU  - Guth, Imre O.
AU  - Petrović, Dragoslav M.
AU  - Lukić-Petrović, Svetlana R.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0272884218318674
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7813
AB  - This paper describes the processing, microstructure, optical and electrical properties of the nanocrystalline (NC) niobium and zinc doped titanium-tin-oxide (TTO:NZ) based ceramics. Variety of techniques was employed (X-ray diffraction, scanning electron microscopy, energy dispersive, Raman and impedance spectroscopy) in the characterization of the obtained TTO:NZ, which confirmed the formation of NC solid-solution matrix with Ti0.8Sn0.2O2 composition. A specific highly dense (approximately 97% of the theoretical density was reached) varistor like microstructure (matrix metal-oxide grains surrounded by the grain-boundary regions) and accordingly resembling electrical properties (breakdown electric field of approximately 130 V/mm and nonlinearity coefficient of α ≈ 6.5) were achieved through double cation doping and elected condition of the mechanochemical solid-state synthesis. Impedance response analysis of TTO:NZ ceramics by means of an equivalent electrical circuit based on the brick-layer model for polycrystalline materials revealed the presence of two temperature dependent electrical relaxation phenomena of the non-Debye type as well as the negative temperature coefficient of resistance behavior.
T2  - Ceramics International
T1  - Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization
VL  - 44
IS  - 15
SP  - 18987
EP  - 18995
DO  - 10.1016/j.ceramint.2018.07.139
ER  - 
@article{
author = "Ivetić, Tamara B. and Sekulić, Dalibor L. and Papan, Jelena and Guth, Imre O. and Petrović, Dragoslav M. and Lukić-Petrović, Svetlana R.",
year = "2018",
abstract = "This paper describes the processing, microstructure, optical and electrical properties of the nanocrystalline (NC) niobium and zinc doped titanium-tin-oxide (TTO:NZ) based ceramics. Variety of techniques was employed (X-ray diffraction, scanning electron microscopy, energy dispersive, Raman and impedance spectroscopy) in the characterization of the obtained TTO:NZ, which confirmed the formation of NC solid-solution matrix with Ti0.8Sn0.2O2 composition. A specific highly dense (approximately 97% of the theoretical density was reached) varistor like microstructure (matrix metal-oxide grains surrounded by the grain-boundary regions) and accordingly resembling electrical properties (breakdown electric field of approximately 130 V/mm and nonlinearity coefficient of α ≈ 6.5) were achieved through double cation doping and elected condition of the mechanochemical solid-state synthesis. Impedance response analysis of TTO:NZ ceramics by means of an equivalent electrical circuit based on the brick-layer model for polycrystalline materials revealed the presence of two temperature dependent electrical relaxation phenomena of the non-Debye type as well as the negative temperature coefficient of resistance behavior.",
journal = "Ceramics International",
title = "Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization",
volume = "44",
number = "15",
pages = "18987-18995",
doi = "10.1016/j.ceramint.2018.07.139"
}
Ivetić, T. B., Sekulić, D. L., Papan, J., Guth, I. O., Petrović, D. M.,& Lukić-Petrović, S. R.. (2018). Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization. in Ceramics International, 44(15), 18987-18995.
https://doi.org/10.1016/j.ceramint.2018.07.139
Ivetić TB, Sekulić DL, Papan J, Guth IO, Petrović DM, Lukić-Petrović SR. Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization. in Ceramics International. 2018;44(15):18987-18995.
doi:10.1016/j.ceramint.2018.07.139 .
Ivetić, Tamara B., Sekulić, Dalibor L., Papan, Jelena, Guth, Imre O., Petrović, Dragoslav M., Lukić-Petrović, Svetlana R., "Niobium and zinc doped titanium-tin-oxide solid-solution ceramics: Synthesis, structure and electrical characterization" in Ceramics International, 44, no. 15 (2018):18987-18995,
https://doi.org/10.1016/j.ceramint.2018.07.139 . .
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