Estonian Research Council [PUT PRG111]

Link to this page

Estonian Research Council [PUT PRG111]

Authors

Publications

Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission

Ristić, Zoran; Đorđević, Vesna R.; Medić, Mina M.; Kuzman, Sanja; Brik, Mikhail G.; Antić, Željka; Dramićanin, Miroslav

(2021)

TY  - JOUR
AU  - Ristić, Zoran
AU  - Đorđević, Vesna R.
AU  - Medić, Mina M.
AU  - Kuzman, Sanja
AU  - Brik, Mikhail G.
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9910
AB  - This paper presents the Cr3+-activated Mg2TiO4 phosphor temperature dependance of its near infrared luminescence and its potential in the optical thermometry applications. In this respect, temperature dependences of three emission features were tested over the broad temperature range (10–500 K): (i) the luminescence intensity ratio (LIR) between emissions from 4T2→4A2 and 2E→4A2 transitions, (ii) the emission lifetime, and (iii) the shift of the 2E→4A2 emission band. We observed that LIR follows the Boltzmann equation for T > 300 K with the maximal value of relative sensitivity of 1.73 %K−1. The lifetime value of the 2E→4A2 transition strongly decreases with temperature with a maximal relative sensitivity of about 0.75 %K−1 at around 430K. Finally, the shift of the emission band is about 65 cm−1 over the complete temperature range.
T2  - Optical Materials
T1  - Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission
VL  - 120
SP  - 111468
DO  - 10.1016/j.optmat.2021.111468
ER  - 
@article{
author = "Ristić, Zoran and Đorđević, Vesna R. and Medić, Mina M. and Kuzman, Sanja and Brik, Mikhail G. and Antić, Željka and Dramićanin, Miroslav",
year = "2021",
abstract = "This paper presents the Cr3+-activated Mg2TiO4 phosphor temperature dependance of its near infrared luminescence and its potential in the optical thermometry applications. In this respect, temperature dependences of three emission features were tested over the broad temperature range (10–500 K): (i) the luminescence intensity ratio (LIR) between emissions from 4T2→4A2 and 2E→4A2 transitions, (ii) the emission lifetime, and (iii) the shift of the 2E→4A2 emission band. We observed that LIR follows the Boltzmann equation for T > 300 K with the maximal value of relative sensitivity of 1.73 %K−1. The lifetime value of the 2E→4A2 transition strongly decreases with temperature with a maximal relative sensitivity of about 0.75 %K−1 at around 430K. Finally, the shift of the emission band is about 65 cm−1 over the complete temperature range.",
journal = "Optical Materials",
title = "Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission",
volume = "120",
pages = "111468",
doi = "10.1016/j.optmat.2021.111468"
}
Ristić, Z., Đorđević, V. R., Medić, M. M., Kuzman, S., Brik, M. G., Antić, Ž.,& Dramićanin, M.. (2021). Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission. in Optical Materials, 120, 111468.
https://doi.org/10.1016/j.optmat.2021.111468
Ristić Z, Đorđević VR, Medić MM, Kuzman S, Brik MG, Antić Ž, Dramićanin M. Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission. in Optical Materials. 2021;120:111468.
doi:10.1016/j.optmat.2021.111468 .
Ristić, Zoran, Đorđević, Vesna R., Medić, Mina M., Kuzman, Sanja, Brik, Mikhail G., Antić, Željka, Dramićanin, Miroslav, "Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission" in Optical Materials, 120 (2021):111468,
https://doi.org/10.1016/j.optmat.2021.111468 . .
17
2
16

Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level

Ćirić, Aleksandar; Stojadinović, Stevan; Brik, Mikhail G.; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
AU  - Brik, Mikhail G.
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8496
AB  - Traditional applications of the Judd-Ofelt (JO) theory to the analysis of the Eu3+ optical spectra make use of the emission transitions originating from the 5D0 manifold. In the present paper, we report an alternative method of evaluating the JO intensity parameters from the Eu3+ emission spectra based on the 5D1 → 7F0,1 transitions. The reduced matrix elements of the unit tensor operators are re-calculated for the 5D0,1,2 → 7F0,1,…,6 Eu3+ transitions in the intermediate coupling approximation using the average electrostatic and spin-orbit coupling parameters. The suggested method was tested by analyzing the emission spectra of the Eu3+ doped GdAlO3, LaF3, NaYF4, Y2O3, ZrO2, YNbO4, ZBLA and PIGLZ hosts. It is shown that the developed method is more accurate for the hosts with relatively high 5D1 level population, which emphasizes its high potential and applicability. In addition to the JO analysis, the CIE chromaticity coordinates are calculated for the investigated spectra. © 2019 Elsevier B.V.
T2  - Chemical Physics
T1  - Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level
VL  - 528
SP  - 110513
DO  - 10.1016/j.chemphys.2019.110513
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan and Brik, Mikhail G. and Dramićanin, Miroslav",
year = "2020",
abstract = "Traditional applications of the Judd-Ofelt (JO) theory to the analysis of the Eu3+ optical spectra make use of the emission transitions originating from the 5D0 manifold. In the present paper, we report an alternative method of evaluating the JO intensity parameters from the Eu3+ emission spectra based on the 5D1 → 7F0,1 transitions. The reduced matrix elements of the unit tensor operators are re-calculated for the 5D0,1,2 → 7F0,1,…,6 Eu3+ transitions in the intermediate coupling approximation using the average electrostatic and spin-orbit coupling parameters. The suggested method was tested by analyzing the emission spectra of the Eu3+ doped GdAlO3, LaF3, NaYF4, Y2O3, ZrO2, YNbO4, ZBLA and PIGLZ hosts. It is shown that the developed method is more accurate for the hosts with relatively high 5D1 level population, which emphasizes its high potential and applicability. In addition to the JO analysis, the CIE chromaticity coordinates are calculated for the investigated spectra. © 2019 Elsevier B.V.",
journal = "Chemical Physics",
title = "Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level",
volume = "528",
pages = "110513",
doi = "10.1016/j.chemphys.2019.110513"
}
Ćirić, A., Stojadinović, S., Brik, M. G.,& Dramićanin, M.. (2020). Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level. in Chemical Physics, 528, 110513.
https://doi.org/10.1016/j.chemphys.2019.110513
Ćirić A, Stojadinović S, Brik MG, Dramićanin M. Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level. in Chemical Physics. 2020;528:110513.
doi:10.1016/j.chemphys.2019.110513 .
Ćirić, Aleksandar, Stojadinović, Stevan, Brik, Mikhail G., Dramićanin, Miroslav, "Judd-Ofelt parametrization from emission spectra: The case study of the Eu3+ 5D1 emitting level" in Chemical Physics, 528 (2020):110513,
https://doi.org/10.1016/j.chemphys.2019.110513 . .
40
18
35

High-throughput first-principles calculations as a powerful guiding tool for materials engineering: Case study of the AB2X4 (A = Be, Mg, Ca, Sr, ba; B = Al, Ga, in; X = O, S) spinel compounds

Wang, Y.; Chen, Wenbo; Liu, Feilong; Yang, D. W.; Tian, Ya; Ma, Chong-Geng; Dramićanin, Miroslav; Brik, Mikhail G.

(2019)

TY  - JOUR
AU  - Wang, Y.
AU  - Chen, Wenbo
AU  - Liu, Feilong
AU  - Yang, D. W.
AU  - Tian, Ya
AU  - Ma, Chong-Geng
AU  - Dramićanin, Miroslav
AU  - Brik, Mikhail G.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S2211379719305327
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8091
AB  - Modern methods of theoretical and experimental materials engineering can be greatly facilitated by reliably established guiding trends that set directions for a smart search for new materials with enhanced performance. Those trends can be derived from a thorough analysis of large arrays of the experimental data, obtained both experimentally and theoretically. In the present paper, the structural, elastic, and electronic properties of 30 spinel compounds AB 2 X 4 (A = Be, Mg, Ca, Sr, Ba; B = Al, Ga, In; X = O, S) were investigated using the CRYSTAL14 program. For the first time the lattice constants, bulk moduli, band gaps and density of states for these 30 spinels were systematically calculated and analyzed. Influence of the cation and anion variation on the above-mentioned properties was highlighted. Several relations between lattice constants, bulk modulus and ionic radii, electronegativities of constituting ions were found. Several linear equations are proposed, which provide a convenient way to predict the lattice constants and bulk moduli of isostructural spinels. © 2019
T2  - Results in Physics
T1  - High-throughput first-principles calculations as a powerful guiding tool for materials engineering: Case study of the AB2X4 (A = Be, Mg, Ca, Sr, ba; B = Al, Ga, in; X = O, S) spinel compounds
VL  - 13
SP  - 102180
DO  - 10.1016/j.rinp.2019.102180
ER  - 
@article{
author = "Wang, Y. and Chen, Wenbo and Liu, Feilong and Yang, D. W. and Tian, Ya and Ma, Chong-Geng and Dramićanin, Miroslav and Brik, Mikhail G.",
year = "2019",
abstract = "Modern methods of theoretical and experimental materials engineering can be greatly facilitated by reliably established guiding trends that set directions for a smart search for new materials with enhanced performance. Those trends can be derived from a thorough analysis of large arrays of the experimental data, obtained both experimentally and theoretically. In the present paper, the structural, elastic, and electronic properties of 30 spinel compounds AB 2 X 4 (A = Be, Mg, Ca, Sr, Ba; B = Al, Ga, In; X = O, S) were investigated using the CRYSTAL14 program. For the first time the lattice constants, bulk moduli, band gaps and density of states for these 30 spinels were systematically calculated and analyzed. Influence of the cation and anion variation on the above-mentioned properties was highlighted. Several relations between lattice constants, bulk modulus and ionic radii, electronegativities of constituting ions were found. Several linear equations are proposed, which provide a convenient way to predict the lattice constants and bulk moduli of isostructural spinels. © 2019",
journal = "Results in Physics",
title = "High-throughput first-principles calculations as a powerful guiding tool for materials engineering: Case study of the AB2X4 (A = Be, Mg, Ca, Sr, ba; B = Al, Ga, in; X = O, S) spinel compounds",
volume = "13",
pages = "102180",
doi = "10.1016/j.rinp.2019.102180"
}
Wang, Y., Chen, W., Liu, F., Yang, D. W., Tian, Y., Ma, C., Dramićanin, M.,& Brik, M. G.. (2019). High-throughput first-principles calculations as a powerful guiding tool for materials engineering: Case study of the AB2X4 (A = Be, Mg, Ca, Sr, ba; B = Al, Ga, in; X = O, S) spinel compounds. in Results in Physics, 13, 102180.
https://doi.org/10.1016/j.rinp.2019.102180
Wang Y, Chen W, Liu F, Yang DW, Tian Y, Ma C, Dramićanin M, Brik MG. High-throughput first-principles calculations as a powerful guiding tool for materials engineering: Case study of the AB2X4 (A = Be, Mg, Ca, Sr, ba; B = Al, Ga, in; X = O, S) spinel compounds. in Results in Physics. 2019;13:102180.
doi:10.1016/j.rinp.2019.102180 .
Wang, Y., Chen, Wenbo, Liu, Feilong, Yang, D. W., Tian, Ya, Ma, Chong-Geng, Dramićanin, Miroslav, Brik, Mikhail G., "High-throughput first-principles calculations as a powerful guiding tool for materials engineering: Case study of the AB2X4 (A = Be, Mg, Ca, Sr, ba; B = Al, Ga, in; X = O, S) spinel compounds" in Results in Physics, 13 (2019):102180,
https://doi.org/10.1016/j.rinp.2019.102180 . .
1
20
8
22