Ministry of Science and Technology of the Republic of Serbia [Contract No. 0206]

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Ministry of Science and Technology of the Republic of Serbia [Contract No. 0206]

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Publications

Mass spectrometric study of the dissociative ionization of sulphuryl fluoride by monoenergetic electron impact .1. Heteronuclear fragment ions

Miletić, Miodrag B.; Nešković, Olivera M.; Veljković, Miomir V.; Zmbov, Kiro F.

(1996)

TY  - JOUR
AU  - Miletić, Miodrag B.
AU  - Nešković, Olivera M.
AU  - Veljković, Miomir V.
AU  - Zmbov, Kiro F.
PY  - 1996
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2039
AB  - The dissociative ionization of sulphuryl fluoride (SO2F2) under electron impact has been examined by using a trochoidal electron velocity selector and a magnetic sector mass spectrometer. The ionization efficiency curves of SO2F2+, SOF2+, SO2F+ and SOF+ have been recorded and the appearance energies of different electronic states of these ions were determined. The results were used to evaluate the dissociation energy D(OSF2-O)=5.32 eV, enthalpies of formation Delta H-f(SO2F)=-427.5 kJ/mol (-4.43eV), Delta H-f(SO2F+)=616 kJ/mol (6.39 eV), Delta H-f(SOF)=-207.5 kJ/mol (-2.15 eV), Delta H-f(SOF+)=710 kJ/mol (7.36 eV) and the ionization energies IE(SO2F)=10.82 eV and IE(SOF)=9.51 eV.
T2  - Rapid Communications in Mass Spectrometry
T1  - Mass spectrometric study of the dissociative ionization of sulphuryl fluoride by monoenergetic electron impact .1. Heteronuclear fragment ions
VL  - 10
IS  - 15
SP  - 1961
EP  - 1965
DO  - 10.1002/(SICI)1097-0231(199612)10:15<1961::AID-RCM782>3.0.CO;2-Lopen_in_newISSN09
ER  - 
@article{
author = "Miletić, Miodrag B. and Nešković, Olivera M. and Veljković, Miomir V. and Zmbov, Kiro F.",
year = "1996",
abstract = "The dissociative ionization of sulphuryl fluoride (SO2F2) under electron impact has been examined by using a trochoidal electron velocity selector and a magnetic sector mass spectrometer. The ionization efficiency curves of SO2F2+, SOF2+, SO2F+ and SOF+ have been recorded and the appearance energies of different electronic states of these ions were determined. The results were used to evaluate the dissociation energy D(OSF2-O)=5.32 eV, enthalpies of formation Delta H-f(SO2F)=-427.5 kJ/mol (-4.43eV), Delta H-f(SO2F+)=616 kJ/mol (6.39 eV), Delta H-f(SOF)=-207.5 kJ/mol (-2.15 eV), Delta H-f(SOF+)=710 kJ/mol (7.36 eV) and the ionization energies IE(SO2F)=10.82 eV and IE(SOF)=9.51 eV.",
journal = "Rapid Communications in Mass Spectrometry",
title = "Mass spectrometric study of the dissociative ionization of sulphuryl fluoride by monoenergetic electron impact .1. Heteronuclear fragment ions",
volume = "10",
number = "15",
pages = "1961-1965",
doi = "10.1002/(SICI)1097-0231(199612)10:15<1961::AID-RCM782>3.0.CO;2-Lopen_in_newISSN09"
}
Miletić, M. B., Nešković, O. M., Veljković, M. V.,& Zmbov, K. F.. (1996). Mass spectrometric study of the dissociative ionization of sulphuryl fluoride by monoenergetic electron impact .1. Heteronuclear fragment ions. in Rapid Communications in Mass Spectrometry, 10(15), 1961-1965.
https://doi.org/10.1002/(SICI)1097-0231(199612)10:15<1961::AID-RCM782>3.0.CO;2-Lopen_in_newISSN09
Miletić MB, Nešković OM, Veljković MV, Zmbov KF. Mass spectrometric study of the dissociative ionization of sulphuryl fluoride by monoenergetic electron impact .1. Heteronuclear fragment ions. in Rapid Communications in Mass Spectrometry. 1996;10(15):1961-1965.
doi:10.1002/(SICI)1097-0231(199612)10:15<1961::AID-RCM782>3.0.CO;2-Lopen_in_newISSN09 .
Miletić, Miodrag B., Nešković, Olivera M., Veljković, Miomir V., Zmbov, Kiro F., "Mass spectrometric study of the dissociative ionization of sulphuryl fluoride by monoenergetic electron impact .1. Heteronuclear fragment ions" in Rapid Communications in Mass Spectrometry, 10, no. 15 (1996):1961-1965,
https://doi.org/10.1002/(SICI)1097-0231(199612)10:15<1961::AID-RCM782>3.0.CO;2-Lopen_in_newISSN09 . .
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