@article{
author = "Miletić, Miodrag B. and Nešković, Olivera M. and Veljković, Miomir V. and Zmbov, Kiro F.",
year = "1996",
abstract = "The dissociative ionization of sulphuryl fluoride (SO2F2) under electron impact has been examined by using a trochoidal electron velocity selector and a magnetic sector mass spectrometer. The ionization efficiency curves of SO2F2+, SOF2+, SO2F+ and SOF+ have been recorded and the appearance energies of different electronic states of these ions were determined. The results were used to evaluate the dissociation energy D(OSF2-O)=5.32 eV, enthalpies of formation Delta H-f(SO2F)=-427.5 kJ/mol (-4.43eV), Delta H-f(SO2F+)=616 kJ/mol (6.39 eV), Delta H-f(SOF)=-207.5 kJ/mol (-2.15 eV), Delta H-f(SOF+)=710 kJ/mol (7.36 eV) and the ionization energies IE(SO2F)=10.82 eV and IE(SOF)=9.51 eV.",
journal = "Rapid Communications in Mass Spectrometry",
title = "Mass spectrometric study of the dissociative ionization of sulphuryl fluoride by monoenergetic electron impact .1. Heteronuclear fragment ions",
volume = "10",
number = "15",
pages = "1961-1965",
doi = "10.1002/(SICI)1097-0231(199612)10:15<1961::AID-RCM782>3.0.CO;2-Lopen_in_newISSN09"
}