TY  - JOUR
AU  - Danilović, Danijela
AU  - Božanić, Dušan K.
AU  - Dojčilović, Radovan
AU  - Vukmirović, Nenad
AU  - Sapkota, Pitambar
AU  - Vukašinović, Ivana
AU  - Đoković, Vladimir
AU  - Bozek, John
AU  - Nicolas, Christophe
AU  - Ptasinska, Sylwia
AU  - Milosavljević, Aleksandar R.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9732
AB  - We report on the aerosol generation of ligand-free silver iodobismuthate (Ag-Bi-I) nanoparticles (NPs) and on in situ investigation of their electronic structure using synchrotron radiation soft X-ray aerosol photoelectron spectroscopy (XAPS). The structural and morphological characterizations revealed the aerosol to be composed of spherical rudorffite Ag3BiI6 particles, approximately 100 nm in size. The XAPS showed well-resolved signals from all expected elements (Ag, Bi, and I) and allowed estimation of the NP work function to be about 4.5 eV. The ionization energy of Ag3BiI6 NPs was determined to be 6.1 eV that is in good agreement with our calculations based on a hybrid functional approach. The presented method of production of Ag3BiI6 aerosol can prove beneficial for the future development of Ag-Bi-I-based photovoltaic materials, since it allows the deposition of Ag-Bi-I particles on large surface areas of arbitrary shape and roughness.
T2  - The Journal of Physical Chemistry C
T1  - Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems
VL  - 124
IS  - 43
SP  - 23930
EP  - 23937
DO  - 10.1021/acs.jpcc.0c06819
ER  - 

@article{
author = "Danilović, Danijela and Božanić, Dušan K. and Dojčilović, Radovan and Vukmirović, Nenad and Sapkota, Pitambar and Vukašinović, Ivana and Đoković, Vladimir and Bozek, John and Nicolas, Christophe and Ptasinska, Sylwia and Milosavljević, Aleksandar R.",
year = "2020",
abstract = "We report on the aerosol generation of ligand-free silver iodobismuthate (Ag-Bi-I) nanoparticles (NPs) and on in situ investigation of their electronic structure using synchrotron radiation soft X-ray aerosol photoelectron spectroscopy (XAPS). The structural and morphological characterizations revealed the aerosol to be composed of spherical rudorffite Ag3BiI6 particles, approximately 100 nm in size. The XAPS showed well-resolved signals from all expected elements (Ag, Bi, and I) and allowed estimation of the NP work function to be about 4.5 eV. The ionization energy of Ag3BiI6 NPs was determined to be 6.1 eV that is in good agreement with our calculations based on a hybrid functional approach. The presented method of production of Ag3BiI6 aerosol can prove beneficial for the future development of Ag-Bi-I-based photovoltaic materials, since it allows the deposition of Ag-Bi-I particles on large surface areas of arbitrary shape and roughness.",
journal = "The Journal of Physical Chemistry C",
title = "Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems",
volume = "124",
number = "43",
pages = "23930-23937",
doi = "10.1021/acs.jpcc.0c06819"
}

Danilović, D., Božanić, D. K., Dojčilović, R., Vukmirović, N., Sapkota, P., Vukašinović, I., Đoković, V., Bozek, J., Nicolas, C., Ptasinska, S.,& Milosavljević, A. R.. (2020). Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems. in The Journal of Physical Chemistry C, 124(43), 23930-23937.
https://doi.org/10.1021/acs.jpcc.0c06819

Danilović D, Božanić DK, Dojčilović R, Vukmirović N, Sapkota P, Vukašinović I, Đoković V, Bozek J, Nicolas C, Ptasinska S, Milosavljević AR. Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems. in The Journal of Physical Chemistry C. 2020;124(43):23930-23937.
doi:10.1021/acs.jpcc.0c06819 .

Danilović, Danijela, Božanić, Dušan K., Dojčilović, Radovan, Vukmirović, Nenad, Sapkota, Pitambar, Vukašinović, Ivana, Đoković, Vladimir, Bozek, John, Nicolas, Christophe, Ptasinska, Sylwia, Milosavljević, Aleksandar R., "Aerosol Synthesis and Gas-Phase Photoelectron Spectroscopy of Ag-Bi-I Nanosystems" in The Journal of Physical Chemistry C, 124, no. 43 (2020):23930-23937,
https://doi.org/10.1021/acs.jpcc.0c06819 . .