Magmatism and geodynamics of the Balkan Peninsula from Mesozoic to present day: significance for the formation of metallic and non-metallic mineral deposits

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Magmatism and geodynamics of the Balkan Peninsula from Mesozoic to present day: significance for the formation of metallic and non-metallic mineral deposits (en)
Магматизам и геодинамика Балканског полуострва од мезозоика до данас: значај за образовање металичних и неметаличних рудних лежишта (sr)
Magmatizam i geodinamika Balkanskog poluostrva od mezozoika do danas: značaj za obrazovanje metaličnih i nemetaličnih rudnih ležišta (sr_RS)
Authors

Publications

Accumulation of trace elements in Tussilago farfara colonizing post-flotation tailing sites in Serbia

Jakovljević, Ksenija; Mišljenović, Tomica; Savović, Jelena; Ranković, Dragan; Ranđelović, Dragana; Mihailović, Nevena; Jovanović, Slobodan

(2020)

TY  - JOUR
AU  - Jakovljević, Ksenija
AU  - Mišljenović, Tomica
AU  - Savović, Jelena
AU  - Ranković, Dragan
AU  - Ranđelović, Dragana
AU  - Mihailović, Nevena
AU  - Jovanović, Slobodan
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8746
AB  - The purpose of this study was to examine the accumulation potential of spontaneously developed Tussilago farfara populations colonizing sites with different levels of anthropogenic pollution. Physical characteristics of the soil are presented, together with the concentrations of macroelements and microelements (Ca, Mg, Fe, S, Al, Pb, Zn, Cu, Cd, Mn, As, Sb, Ag, Ti, and Sr) in both soil and plants. The biological concentration, accumulation, and translocation factors were used to assess the potential for heavy metal accumulation. Considerable differences were found among assessions from unevenly contaminated habitats, particularly in comparison with an unpolluted site. In line with the ore’s characteristics, substrate samples from polluted sites were heavily contaminated with Pb, Zn, As, and Sb. Increased levels of microelements were also detected in plant samples from flotation tailings. Despite active absorption of Zn, Cu, Cd, Mn, and Sr by the plants from mining sites, the detected quantities of these elements in all samples were below the hyperaccumulation threshold. However, the obtained results indicate that the use of T. farfara from such sites in traditional medicine could pose a risk to human health due to accumulation of several toxic elements in the plant’s aboveground tissues. Additionally, as a successful primary colonizer and stabilizer of technogenic substrates, T. farfara has an important role in the initial phases of revegetation of highly contaminated sites. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - Environmental Science and Pollution Research
T1  - Accumulation of trace elements in Tussilago farfara colonizing post-flotation tailing sites in Serbia
VL  - 27
IS  - 4
SP  - 4089
EP  - 4103
DO  - 10.1007/s11356-019-07010-z
ER  - 
@article{
author = "Jakovljević, Ksenija and Mišljenović, Tomica and Savović, Jelena and Ranković, Dragan and Ranđelović, Dragana and Mihailović, Nevena and Jovanović, Slobodan",
year = "2020",
abstract = "The purpose of this study was to examine the accumulation potential of spontaneously developed Tussilago farfara populations colonizing sites with different levels of anthropogenic pollution. Physical characteristics of the soil are presented, together with the concentrations of macroelements and microelements (Ca, Mg, Fe, S, Al, Pb, Zn, Cu, Cd, Mn, As, Sb, Ag, Ti, and Sr) in both soil and plants. The biological concentration, accumulation, and translocation factors were used to assess the potential for heavy metal accumulation. Considerable differences were found among assessions from unevenly contaminated habitats, particularly in comparison with an unpolluted site. In line with the ore’s characteristics, substrate samples from polluted sites were heavily contaminated with Pb, Zn, As, and Sb. Increased levels of microelements were also detected in plant samples from flotation tailings. Despite active absorption of Zn, Cu, Cd, Mn, and Sr by the plants from mining sites, the detected quantities of these elements in all samples were below the hyperaccumulation threshold. However, the obtained results indicate that the use of T. farfara from such sites in traditional medicine could pose a risk to human health due to accumulation of several toxic elements in the plant’s aboveground tissues. Additionally, as a successful primary colonizer and stabilizer of technogenic substrates, T. farfara has an important role in the initial phases of revegetation of highly contaminated sites. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "Environmental Science and Pollution Research",
title = "Accumulation of trace elements in Tussilago farfara colonizing post-flotation tailing sites in Serbia",
volume = "27",
number = "4",
pages = "4089-4103",
doi = "10.1007/s11356-019-07010-z"
}
Jakovljević, K., Mišljenović, T., Savović, J., Ranković, D., Ranđelović, D., Mihailović, N.,& Jovanović, S.. (2020). Accumulation of trace elements in Tussilago farfara colonizing post-flotation tailing sites in Serbia. in Environmental Science and Pollution Research, 27(4), 4089-4103.
https://doi.org/10.1007/s11356-019-07010-z
Jakovljević K, Mišljenović T, Savović J, Ranković D, Ranđelović D, Mihailović N, Jovanović S. Accumulation of trace elements in Tussilago farfara colonizing post-flotation tailing sites in Serbia. in Environmental Science and Pollution Research. 2020;27(4):4089-4103.
doi:10.1007/s11356-019-07010-z .
Jakovljević, Ksenija, Mišljenović, Tomica, Savović, Jelena, Ranković, Dragan, Ranđelović, Dragana, Mihailović, Nevena, Jovanović, Slobodan, "Accumulation of trace elements in Tussilago farfara colonizing post-flotation tailing sites in Serbia" in Environmental Science and Pollution Research, 27, no. 4 (2020):4089-4103,
https://doi.org/10.1007/s11356-019-07010-z . .
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Basalt-polyester hybrid composite materials for demanding wear applications

Abusahmin, Faisal; Algellai, Ahmed; Tomić, Nataša; Vuksanović, Marija M.; Majstorović, Jelena; Volkov-Husović, Tatjana; Simić, Vladimir; Jančić-Heinemann, Radmila; Toljić, Marinko; Kovačević, Jovan

(2020)

TY  - JOUR
AU  - Abusahmin, Faisal
AU  - Algellai, Ahmed
AU  - Tomić, Nataša
AU  - Vuksanović, Marija M.
AU  - Majstorović, Jelena
AU  - Volkov-Husović, Tatjana
AU  - Simić, Vladimir
AU  - Jančić-Heinemann, Radmila
AU  - Toljić, Marinko
AU  - Kovačević, Jovan
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8979
AB  - Basalt as a filler in a polymer-based composite material fulfils the demand of being natural, environment-friendly material for the production of various composite materials. The material could be used as protective layer and the abrasion should be tested in order to evaluate the properties of the material. The cavitation test enables the evaluation of the possible service in conditions that simulate the extensive erosion. The presence of basalt in the matrix improves the resistance to cavitation. The possibility to further improve the material could be obtained using the reinforcement of the matrix itself by incorporation of submicron ceramic particles into the composite. The obtained hybrid composite material with the addition of reinforcement in the matrix further improves the cavitation resistance.
T2  - Science of Sintering
T1  - Basalt-polyester hybrid composite materials for demanding wear applications
VL  - 52
IS  - 1
SP  - 67
EP  - 76
DO  - 10.2298/SOS2001067A
ER  - 
@article{
author = "Abusahmin, Faisal and Algellai, Ahmed and Tomić, Nataša and Vuksanović, Marija M. and Majstorović, Jelena and Volkov-Husović, Tatjana and Simić, Vladimir and Jančić-Heinemann, Radmila and Toljić, Marinko and Kovačević, Jovan",
year = "2020",
abstract = "Basalt as a filler in a polymer-based composite material fulfils the demand of being natural, environment-friendly material for the production of various composite materials. The material could be used as protective layer and the abrasion should be tested in order to evaluate the properties of the material. The cavitation test enables the evaluation of the possible service in conditions that simulate the extensive erosion. The presence of basalt in the matrix improves the resistance to cavitation. The possibility to further improve the material could be obtained using the reinforcement of the matrix itself by incorporation of submicron ceramic particles into the composite. The obtained hybrid composite material with the addition of reinforcement in the matrix further improves the cavitation resistance.",
journal = "Science of Sintering",
title = "Basalt-polyester hybrid composite materials for demanding wear applications",
volume = "52",
number = "1",
pages = "67-76",
doi = "10.2298/SOS2001067A"
}
Abusahmin, F., Algellai, A., Tomić, N., Vuksanović, M. M., Majstorović, J., Volkov-Husović, T., Simić, V., Jančić-Heinemann, R., Toljić, M.,& Kovačević, J.. (2020). Basalt-polyester hybrid composite materials for demanding wear applications. in Science of Sintering, 52(1), 67-76.
https://doi.org/10.2298/SOS2001067A
Abusahmin F, Algellai A, Tomić N, Vuksanović MM, Majstorović J, Volkov-Husović T, Simić V, Jančić-Heinemann R, Toljić M, Kovačević J. Basalt-polyester hybrid composite materials for demanding wear applications. in Science of Sintering. 2020;52(1):67-76.
doi:10.2298/SOS2001067A .
Abusahmin, Faisal, Algellai, Ahmed, Tomić, Nataša, Vuksanović, Marija M., Majstorović, Jelena, Volkov-Husović, Tatjana, Simić, Vladimir, Jančić-Heinemann, Radmila, Toljić, Marinko, Kovačević, Jovan, "Basalt-polyester hybrid composite materials for demanding wear applications" in Science of Sintering, 52, no. 1 (2020):67-76,
https://doi.org/10.2298/SOS2001067A . .
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Phase and microstructural study of urinary stones

Mirković, Miljana M.; Došen, Anja M.; Erić, Suzana; Vulić, Predrag; Matović, Branko; Rosić, Aleksandra

(2020)

TY  - JOUR
AU  - Mirković, Miljana M.
AU  - Došen, Anja M.
AU  - Erić, Suzana
AU  - Vulić, Predrag
AU  - Matović, Branko
AU  - Rosić, Aleksandra
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8663
AB  - In this paper we present the phase and morphological characteristics of urinary stones from Serbian patients. The study included for the first time the determination of the phase composition and a statistical analysis of the presence of different types of urinary stones in both men and women in Serbia. The main goal of study was representation of collected data for the first time. For past three years, more than 600 samples were collected from Serbian patients. The phase composition of all samples of urinary stones was investigated using XRD analysis. Morphology and chemical composition of phases in some characteristic samples was determinate by the SEM-EDS analysis. Results indicate that there are several different types of urinary stones that vary in mineral composition, chemistry and morphology. It was found that 312 (52%) of the 600 stones were composed of calcium oxalate minerals (CaOx): 17.3% of which were pure calcium oxalate monohydrate COM, 4% were pure calcium oxalate dihydrate COD; 200 (33.3%) were a mixture of CaOx and Hydroxyapatite HA, 19 (3.1%) were uric acid (uricite) UA and uric acid dihydrate UAD, 17 (2.8%) were a combination of UA and CaOx minerals, 41 (6.8%) were combination of CaP minerals and CaOx, 11 (1.9%) were cystine (Cy) stones. The obtained data shows the diversity of types of urinary stones. Morphological, chemical and XRPD analysis give us statistical data which shows that the most common urinary stones from Serbian patients are from CaOx group and in most of cases are associated with CaP. © 2019 Elsevier B.V.
T2  - Microchemical Journal
T1  - Phase and microstructural study of urinary stones
VL  - 152
SP  - 104429
DO  - 10.1016/j.microc.2019.104429
ER  - 
@article{
author = "Mirković, Miljana M. and Došen, Anja M. and Erić, Suzana and Vulić, Predrag and Matović, Branko and Rosić, Aleksandra",
year = "2020",
abstract = "In this paper we present the phase and morphological characteristics of urinary stones from Serbian patients. The study included for the first time the determination of the phase composition and a statistical analysis of the presence of different types of urinary stones in both men and women in Serbia. The main goal of study was representation of collected data for the first time. For past three years, more than 600 samples were collected from Serbian patients. The phase composition of all samples of urinary stones was investigated using XRD analysis. Morphology and chemical composition of phases in some characteristic samples was determinate by the SEM-EDS analysis. Results indicate that there are several different types of urinary stones that vary in mineral composition, chemistry and morphology. It was found that 312 (52%) of the 600 stones were composed of calcium oxalate minerals (CaOx): 17.3% of which were pure calcium oxalate monohydrate COM, 4% were pure calcium oxalate dihydrate COD; 200 (33.3%) were a mixture of CaOx and Hydroxyapatite HA, 19 (3.1%) were uric acid (uricite) UA and uric acid dihydrate UAD, 17 (2.8%) were a combination of UA and CaOx minerals, 41 (6.8%) were combination of CaP minerals and CaOx, 11 (1.9%) were cystine (Cy) stones. The obtained data shows the diversity of types of urinary stones. Morphological, chemical and XRPD analysis give us statistical data which shows that the most common urinary stones from Serbian patients are from CaOx group and in most of cases are associated with CaP. © 2019 Elsevier B.V.",
journal = "Microchemical Journal",
title = "Phase and microstructural study of urinary stones",
volume = "152",
pages = "104429",
doi = "10.1016/j.microc.2019.104429"
}
Mirković, M. M., Došen, A. M., Erić, S., Vulić, P., Matović, B.,& Rosić, A.. (2020). Phase and microstructural study of urinary stones. in Microchemical Journal, 152, 104429.
https://doi.org/10.1016/j.microc.2019.104429
Mirković MM, Došen AM, Erić S, Vulić P, Matović B, Rosić A. Phase and microstructural study of urinary stones. in Microchemical Journal. 2020;152:104429.
doi:10.1016/j.microc.2019.104429 .
Mirković, Miljana M., Došen, Anja M., Erić, Suzana, Vulić, Predrag, Matović, Branko, Rosić, Aleksandra, "Phase and microstructural study of urinary stones" in Microchemical Journal, 152 (2020):104429,
https://doi.org/10.1016/j.microc.2019.104429 . .
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Structural, morphological and electrical properties of multi-doped calcium phosphate materials as solid electrolytes for intermediate temperature solid oxide fuel cells

Mirković, Miljana M.; Došen, Anja M.; Erić, Suzana; Stojmenović, Marija; Matović, Branko; Rosić, Aleksandra

(2018)

TY  - JOUR
AU  - Mirković, Miljana M.
AU  - Došen, Anja M.
AU  - Erić, Suzana
AU  - Stojmenović, Marija
AU  - Matović, Branko
AU  - Rosić, Aleksandra
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7647
AB  - Modified solution precipitation method was used to prepare pure and doped Mg, Sr and Na hydroxyapatite type materials (CaP, CaMgP and CaSrNaP). Modification consisted of partial substitution of nitrates by acetate solution in order to achieve a more soluble and cost effective synthesis. The obtained samples were calcined at 400 degrees C (CaP400, CaMgP400 and CaSrNaP400). All powders were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). Calcined samples were densified at 1000 degrees C in an air for 3 h (CaP1000, CaMgP1000 and CaSrNaP1000). Sintered samples were characterized by XRPD, FTIR, SEM, EDS and complex impedance methods. The highest conductivity was found for the multi-doped phosphate sample (CaSrNaP1000) at 700 degrees C (1.90x10(-3)Omega(-1)cm(-1)). The corresponding activation energies of conductivity amounted to 0.31 eV in the temperature range 500-700 degrees C.
AB  - Метода таложне титрације коришћена је за добијање чистог и допираног хидроксиапатита јонима Sr, Mg и Na (CaP, CaMgP and CaSrNaP). За синтезу супституисаних хидроксиапатитских материјала коришћена је модификована таложна метода у односу на досада познате методе. Због боље растворљивости и знатно веће исплативости коришћени су раствори ацетата уместо нитрата. Синтетисани материјали су калцинисани на 400 °C, а затим окарактерисани
рендгенском дифракцијом, инфра црвеном спектроскопијом са Фуријеовом трансформацијом и скенирајућом електронском микроскопијом. Калцинисани узорци су синтеровани на 1000 °C са задржавањем од 3 сата у атмосфери ваздуха (CaP1000, CaMgP1000 and CaSrNaP1000). Синтеровани материјали окарактерисани су: рендгенском дифракцијом на поликристалном узорку, инфрацрвеном спекторскопијом са Фуријеовом трансформацијом и скенирајућом електронском микроскопијом са енергетско дисперзивном анализом као и методе комплексне импендансе. Највећа проводљивост добијена је на температури од 700 °C и износи 1.90×10-3 Ω-1cm-1 за мешовито допирани фосфатни материјал (CaSrNaP1000). Добијене активационе енергије проводљивости износе 0.31 eV у температурном опсегу од 500-700 ºC.
T2  - Science of Sintering
T1  - Structural, morphological and electrical properties of multi-doped calcium phosphate materials as solid electrolytes for intermediate temperature solid oxide fuel cells
VL  - 50
IS  - 1
SP  - 95
EP  - 109
DO  - 10.2298/SOS1801095M
ER  - 
@article{
author = "Mirković, Miljana M. and Došen, Anja M. and Erić, Suzana and Stojmenović, Marija and Matović, Branko and Rosić, Aleksandra",
year = "2018",
abstract = "Modified solution precipitation method was used to prepare pure and doped Mg, Sr and Na hydroxyapatite type materials (CaP, CaMgP and CaSrNaP). Modification consisted of partial substitution of nitrates by acetate solution in order to achieve a more soluble and cost effective synthesis. The obtained samples were calcined at 400 degrees C (CaP400, CaMgP400 and CaSrNaP400). All powders were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). Calcined samples were densified at 1000 degrees C in an air for 3 h (CaP1000, CaMgP1000 and CaSrNaP1000). Sintered samples were characterized by XRPD, FTIR, SEM, EDS and complex impedance methods. The highest conductivity was found for the multi-doped phosphate sample (CaSrNaP1000) at 700 degrees C (1.90x10(-3)Omega(-1)cm(-1)). The corresponding activation energies of conductivity amounted to 0.31 eV in the temperature range 500-700 degrees C., Метода таложне титрације коришћена је за добијање чистог и допираног хидроксиапатита јонима Sr, Mg и Na (CaP, CaMgP and CaSrNaP). За синтезу супституисаних хидроксиапатитских материјала коришћена је модификована таложна метода у односу на досада познате методе. Због боље растворљивости и знатно веће исплативости коришћени су раствори ацетата уместо нитрата. Синтетисани материјали су калцинисани на 400 °C, а затим окарактерисани
рендгенском дифракцијом, инфра црвеном спектроскопијом са Фуријеовом трансформацијом и скенирајућом електронском микроскопијом. Калцинисани узорци су синтеровани на 1000 °C са задржавањем од 3 сата у атмосфери ваздуха (CaP1000, CaMgP1000 and CaSrNaP1000). Синтеровани материјали окарактерисани су: рендгенском дифракцијом на поликристалном узорку, инфрацрвеном спекторскопијом са Фуријеовом трансформацијом и скенирајућом електронском микроскопијом са енергетско дисперзивном анализом као и методе комплексне импендансе. Највећа проводљивост добијена је на температури од 700 °C и износи 1.90×10-3 Ω-1cm-1 за мешовито допирани фосфатни материјал (CaSrNaP1000). Добијене активационе енергије проводљивости износе 0.31 eV у температурном опсегу од 500-700 ºC.",
journal = "Science of Sintering",
title = "Structural, morphological and electrical properties of multi-doped calcium phosphate materials as solid electrolytes for intermediate temperature solid oxide fuel cells",
volume = "50",
number = "1",
pages = "95-109",
doi = "10.2298/SOS1801095M"
}
Mirković, M. M., Došen, A. M., Erić, S., Stojmenović, M., Matović, B.,& Rosić, A.. (2018). Structural, morphological and electrical properties of multi-doped calcium phosphate materials as solid electrolytes for intermediate temperature solid oxide fuel cells. in Science of Sintering, 50(1), 95-109.
https://doi.org/10.2298/SOS1801095M
Mirković MM, Došen AM, Erić S, Stojmenović M, Matović B, Rosić A. Structural, morphological and electrical properties of multi-doped calcium phosphate materials as solid electrolytes for intermediate temperature solid oxide fuel cells. in Science of Sintering. 2018;50(1):95-109.
doi:10.2298/SOS1801095M .
Mirković, Miljana M., Došen, Anja M., Erić, Suzana, Stojmenović, Marija, Matović, Branko, Rosić, Aleksandra, "Structural, morphological and electrical properties of multi-doped calcium phosphate materials as solid electrolytes for intermediate temperature solid oxide fuel cells" in Science of Sintering, 50, no. 1 (2018):95-109,
https://doi.org/10.2298/SOS1801095M . .
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Refractive indices of unfilled resin mixtures and cured composites related to color and translucency of conventional and low-shrinkage composites

Miletić, Vesna; Jakovljević, Nikola; Manojlović, Dragica; Marjanović, Jovana; Rosić, Aleksandra; Dramićanin, Miroslav

(2017)

TY  - JOUR
AU  - Miletić, Vesna
AU  - Jakovljević, Nikola
AU  - Manojlović, Dragica
AU  - Marjanović, Jovana
AU  - Rosić, Aleksandra
AU  - Dramićanin, Miroslav
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1357
AB  - This study correlated the refractive indices (RIs) of unfilled resin mixtures and resin-based composites (RBCs) with color and translucency of conventional and low-shrinkage RBCs. Unfilled resin mixtures based on different ratios of conventional monomers Bisphenol A-glycidyl-methacrylate (BisGMA)/triethyleneglycol-dimethacrylate (TEGDMA) and urethane-dimethacrylate (UDMA)/TEGDMA and a low-shrinkage monomer FIT-852 (FIT, Esstech Inc.)/TEGDMA were used to prepare model RBCs, containing 30 wt % of the organic matrix and 70 wt % of silanated barium-glass fillers (n=1.553, Esstech Inc.). The RIs of resins were measured on an ABBE refractometer, those of cured RBCs using the Becke-line method in immersion oils. Color and translucency were determined using an AvaSpec-2048 (Avantes BV) spectrometer. The RIs of unfilled resin mixtures decreased with increasing amounts of TEGDMA. Cured RBCs had higher RIs than their respective resin mixtures. BisGMA-based composites were more translucent with significantly lower L* values than FIT- and UDMA-based RBCs. The RIs of unfilled resins positively correlated with cured RBCs (p=0.001), as did the RIs with translucency (p=0.001) and color (p=0.008). Resin mixtures and corresponding RBCs based on UDMA and its modified low-shrinkage version, FIT, showed similar optical properties. The RIs of unfilled resins appeared to be good predictors of the RIs of cured RBCs. (c) 2015 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 105B: 7-13, 2017.
T2  - Journal of Biomedical Materials Research. Part B: Applied Biomaterials
T1  - Refractive indices of unfilled resin mixtures and cured composites related to color and translucency of conventional and low-shrinkage composites
VL  - 105
IS  - 1
SP  - 7
EP  - 13
DO  - 10.1002/jbm.b.33523
ER  - 
@article{
author = "Miletić, Vesna and Jakovljević, Nikola and Manojlović, Dragica and Marjanović, Jovana and Rosić, Aleksandra and Dramićanin, Miroslav",
year = "2017",
abstract = "This study correlated the refractive indices (RIs) of unfilled resin mixtures and resin-based composites (RBCs) with color and translucency of conventional and low-shrinkage RBCs. Unfilled resin mixtures based on different ratios of conventional monomers Bisphenol A-glycidyl-methacrylate (BisGMA)/triethyleneglycol-dimethacrylate (TEGDMA) and urethane-dimethacrylate (UDMA)/TEGDMA and a low-shrinkage monomer FIT-852 (FIT, Esstech Inc.)/TEGDMA were used to prepare model RBCs, containing 30 wt % of the organic matrix and 70 wt % of silanated barium-glass fillers (n=1.553, Esstech Inc.). The RIs of resins were measured on an ABBE refractometer, those of cured RBCs using the Becke-line method in immersion oils. Color and translucency were determined using an AvaSpec-2048 (Avantes BV) spectrometer. The RIs of unfilled resin mixtures decreased with increasing amounts of TEGDMA. Cured RBCs had higher RIs than their respective resin mixtures. BisGMA-based composites were more translucent with significantly lower L* values than FIT- and UDMA-based RBCs. The RIs of unfilled resins positively correlated with cured RBCs (p=0.001), as did the RIs with translucency (p=0.001) and color (p=0.008). Resin mixtures and corresponding RBCs based on UDMA and its modified low-shrinkage version, FIT, showed similar optical properties. The RIs of unfilled resins appeared to be good predictors of the RIs of cured RBCs. (c) 2015 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 105B: 7-13, 2017.",
journal = "Journal of Biomedical Materials Research. Part B: Applied Biomaterials",
title = "Refractive indices of unfilled resin mixtures and cured composites related to color and translucency of conventional and low-shrinkage composites",
volume = "105",
number = "1",
pages = "7-13",
doi = "10.1002/jbm.b.33523"
}
Miletić, V., Jakovljević, N., Manojlović, D., Marjanović, J., Rosić, A.,& Dramićanin, M.. (2017). Refractive indices of unfilled resin mixtures and cured composites related to color and translucency of conventional and low-shrinkage composites. in Journal of Biomedical Materials Research. Part B: Applied Biomaterials, 105(1), 7-13.
https://doi.org/10.1002/jbm.b.33523
Miletić V, Jakovljević N, Manojlović D, Marjanović J, Rosić A, Dramićanin M. Refractive indices of unfilled resin mixtures and cured composites related to color and translucency of conventional and low-shrinkage composites. in Journal of Biomedical Materials Research. Part B: Applied Biomaterials. 2017;105(1):7-13.
doi:10.1002/jbm.b.33523 .
Miletić, Vesna, Jakovljević, Nikola, Manojlović, Dragica, Marjanović, Jovana, Rosić, Aleksandra, Dramićanin, Miroslav, "Refractive indices of unfilled resin mixtures and cured composites related to color and translucency of conventional and low-shrinkage composites" in Journal of Biomedical Materials Research. Part B: Applied Biomaterials, 105, no. 1 (2017):7-13,
https://doi.org/10.1002/jbm.b.33523 . .
18
10
17

Ouzo effect-New simple nanoemulsion method for synthesis of strontium hydroxyapatite nanospheres

Prekajski, Marija D.; Mirković, Miljana M.; Todorović, Bratislav Ž.; Matković, Aleksandar; Marinović-Cincović, Milena; Luković, Jelena M.; Matović, Branko

(Elsevier, 2016)

TY  - JOUR
AU  - Prekajski, Marija D.
AU  - Mirković, Miljana M.
AU  - Todorović, Bratislav Ž.
AU  - Matković, Aleksandar
AU  - Marinović-Cincović, Milena
AU  - Luković, Jelena M.
AU  - Matović, Branko
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/924
AB  - Nanoemulsion technique was applied for synthesis of carbonated strontium hydroxyapatite (CSrHAp) at room temperature. X-ray powder diffraction analysis accompanied with Rietveld refinement reviled that synthesized powder were single-phase hydroxyapatite. Fourier transform infrared (FTIR) spectroscopy showed that the CSrHAp was A-type substitution. The carbonate amount substituting the hydroxide group in the synthesized apatite was estimated, from the corresponding CO2 weight loss in the range 600-1100 degrees C. According to this empirical formula of as synthesized CHAp is S-10(PO4)(6)(OH)(0.60)(CO3)(0.70). These results were confirmed by the Rietveld refinement analysis. Using scanning electron microscopy analysis it was found that the synthesized CSrHAp particles were spherical in shape and that their sizes were in the nanometer range. Nanoemulsion strategy procedure provides a simple pathway to obtain single-phase CSrHAp. (C) 2015 Elsevier Ltd. All rights reserved.
PB  - Elsevier
T2  - Journal of the European Ceramic Society
T1  - Ouzo effect-New simple nanoemulsion method for synthesis of strontium hydroxyapatite nanospheres
VL  - 36
IS  - 5
SP  - 1293
EP  - 1298
DO  - 10.1016/j.jeurceramsoc.2015.11.045
ER  - 
@article{
author = "Prekajski, Marija D. and Mirković, Miljana M. and Todorović, Bratislav Ž. and Matković, Aleksandar and Marinović-Cincović, Milena and Luković, Jelena M. and Matović, Branko",
year = "2016",
abstract = "Nanoemulsion technique was applied for synthesis of carbonated strontium hydroxyapatite (CSrHAp) at room temperature. X-ray powder diffraction analysis accompanied with Rietveld refinement reviled that synthesized powder were single-phase hydroxyapatite. Fourier transform infrared (FTIR) spectroscopy showed that the CSrHAp was A-type substitution. The carbonate amount substituting the hydroxide group in the synthesized apatite was estimated, from the corresponding CO2 weight loss in the range 600-1100 degrees C. According to this empirical formula of as synthesized CHAp is S-10(PO4)(6)(OH)(0.60)(CO3)(0.70). These results were confirmed by the Rietveld refinement analysis. Using scanning electron microscopy analysis it was found that the synthesized CSrHAp particles were spherical in shape and that their sizes were in the nanometer range. Nanoemulsion strategy procedure provides a simple pathway to obtain single-phase CSrHAp. (C) 2015 Elsevier Ltd. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of the European Ceramic Society",
title = "Ouzo effect-New simple nanoemulsion method for synthesis of strontium hydroxyapatite nanospheres",
volume = "36",
number = "5",
pages = "1293-1298",
doi = "10.1016/j.jeurceramsoc.2015.11.045"
}
Prekajski, M. D., Mirković, M. M., Todorović, B. Ž., Matković, A., Marinović-Cincović, M., Luković, J. M.,& Matović, B.. (2016). Ouzo effect-New simple nanoemulsion method for synthesis of strontium hydroxyapatite nanospheres. in Journal of the European Ceramic Society
Elsevier., 36(5), 1293-1298.
https://doi.org/10.1016/j.jeurceramsoc.2015.11.045
Prekajski MD, Mirković MM, Todorović BŽ, Matković A, Marinović-Cincović M, Luković JM, Matović B. Ouzo effect-New simple nanoemulsion method for synthesis of strontium hydroxyapatite nanospheres. in Journal of the European Ceramic Society. 2016;36(5):1293-1298.
doi:10.1016/j.jeurceramsoc.2015.11.045 .
Prekajski, Marija D., Mirković, Miljana M., Todorović, Bratislav Ž., Matković, Aleksandar, Marinović-Cincović, Milena, Luković, Jelena M., Matović, Branko, "Ouzo effect-New simple nanoemulsion method for synthesis of strontium hydroxyapatite nanospheres" in Journal of the European Ceramic Society, 36, no. 5 (2016):1293-1298,
https://doi.org/10.1016/j.jeurceramsoc.2015.11.045 . .
46
22
47

Thermally induced phase transformation of Pb-exchanged LTA and FAU-framework zeolite to feldspar phases

Radosavljević-Mihajlović, Ana S.; Kremenović, Aleksandar S.; Došen, Anja M.; Andrejic, J. Z.; Dondur, Vera

(2015)

TY  - JOUR
AU  - Radosavljević-Mihajlović, Ana S.
AU  - Kremenović, Aleksandar S.
AU  - Došen, Anja M.
AU  - Andrejic, J. Z.
AU  - Dondur, Vera
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/218
AB  - Thermally induced phase transformations of Pb-exchange LTA and FAU zeolites were from ambient temperature to 1300 degrees C. Both frameworks collapse into amorphous intermediate products after heating between 600 and 650 degrees C. Prolonged heating of the intermediate product over 1100 degrees C results in the formation of disordered Pb-feldspar(LTA) [a = 8.414 (4) angstrom, b = 13.048 (4) angstrom, c = 7.169 (4) angstrom, beta = 115.35 degrees (3)] and Pb-feldspar(FAU) [a = 8.422 (4) angstrom, b = 13.054 (4) angstrom, c = 7.173 (4) angstrom, beta = 115.37 degrees (3)] phases. The phase conversions within the investigated temperature range were followed by thermal (DTA, TGA, and DSC), XRPD, and Raman methods. (C) 2014 Elsevier Inc. All rights reserved.
T2  - Microporous and Mesoporous Materials
T1  - Thermally induced phase transformation of Pb-exchanged LTA and FAU-framework zeolite to feldspar phases
VL  - 201
SP  - 210
EP  - 218
DO  - 10.1016/j.micromeso.2014.08.059
ER  - 
@article{
author = "Radosavljević-Mihajlović, Ana S. and Kremenović, Aleksandar S. and Došen, Anja M. and Andrejic, J. Z. and Dondur, Vera",
year = "2015",
abstract = "Thermally induced phase transformations of Pb-exchange LTA and FAU zeolites were from ambient temperature to 1300 degrees C. Both frameworks collapse into amorphous intermediate products after heating between 600 and 650 degrees C. Prolonged heating of the intermediate product over 1100 degrees C results in the formation of disordered Pb-feldspar(LTA) [a = 8.414 (4) angstrom, b = 13.048 (4) angstrom, c = 7.169 (4) angstrom, beta = 115.35 degrees (3)] and Pb-feldspar(FAU) [a = 8.422 (4) angstrom, b = 13.054 (4) angstrom, c = 7.173 (4) angstrom, beta = 115.37 degrees (3)] phases. The phase conversions within the investigated temperature range were followed by thermal (DTA, TGA, and DSC), XRPD, and Raman methods. (C) 2014 Elsevier Inc. All rights reserved.",
journal = "Microporous and Mesoporous Materials",
title = "Thermally induced phase transformation of Pb-exchanged LTA and FAU-framework zeolite to feldspar phases",
volume = "201",
pages = "210-218",
doi = "10.1016/j.micromeso.2014.08.059"
}
Radosavljević-Mihajlović, A. S., Kremenović, A. S., Došen, A. M., Andrejic, J. Z.,& Dondur, V.. (2015). Thermally induced phase transformation of Pb-exchanged LTA and FAU-framework zeolite to feldspar phases. in Microporous and Mesoporous Materials, 201, 210-218.
https://doi.org/10.1016/j.micromeso.2014.08.059
Radosavljević-Mihajlović AS, Kremenović AS, Došen AM, Andrejic JZ, Dondur V. Thermally induced phase transformation of Pb-exchanged LTA and FAU-framework zeolite to feldspar phases. in Microporous and Mesoporous Materials. 2015;201:210-218.
doi:10.1016/j.micromeso.2014.08.059 .
Radosavljević-Mihajlović, Ana S., Kremenović, Aleksandar S., Došen, Anja M., Andrejic, J. Z., Dondur, Vera, "Thermally induced phase transformation of Pb-exchanged LTA and FAU-framework zeolite to feldspar phases" in Microporous and Mesoporous Materials, 201 (2015):210-218,
https://doi.org/10.1016/j.micromeso.2014.08.059 . .
8
8
9

Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships

Radosavljevic, Slobodan A.; Stojanovic, Jovica N.; Vuković, Nikola S.; Radosavljević-Mihajlović, Ana S.; Kasic, Vladan D.

(2015)

TY  - JOUR
AU  - Radosavljevic, Slobodan A.
AU  - Stojanovic, Jovica N.
AU  - Vuković, Nikola S.
AU  - Radosavljević-Mihajlović, Ana S.
AU  - Kasic, Vladan D.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/363
AB  - The Rogozna ore field (ROF) belongs to the Serbo-Macedonian Metallogenic Province (SMMP), and covers a part of the western Dinarides rim and the Vardar ophiolite zone, situated within the Neogene volcanogenic-intrusive complex of calc-alkaline and shoshonitic rocks within the territories of Serbia and Kosovo. It is well-known for its Cu(Au, Pb, Zn) skarn mineralization and Pb(Ag)-Zn hydrothermal deposits and occurences. Mineral associations, deposition order and genesis of the ROF were discussed in detail. Complex ore parageneses were determined in the Crnac, Plalcaonica, and Kaludjer Pb(Ag)-Zn deposits and are composed of the following minerals: sulfides (pyrrhotite, chalcopyrrhotite, chalcopyrite, sphalerite, galena, pyrite, marcasite, millerite, bravoite), sulfosalts (arsenopolybasite, tetrahedrite, Ag-bearing tetrahedrite, Zn-bearing tetrahedrite, semseyite, heteromorphite, jamesonite, ferrokesterite), arsenides (nickeline), sulfarsenides and sulfantimonides (gersdorffite, Sb-bearing gersdorffite, Fe-bearing gersdorffite, As-bearing ullmannite, arsenopyrite), native metals (native Au, native Ag), oxides (Cr-spinel, rutile, anatase, leucoxene, magnetite, hematite) and gangue minerals (quartz, silicates, chalcedony, carbonates, monazite(Ce), barite, gypsum, anglesite, cerussite, smithsonite, zaratite, limonite). The high-, medium-, and low-temperature hydrothermal mineral assemblage occur throughout the Pb(Ag)-Zn deposits at Kaludjer-Crnac-Plakaonica ore system, in which the whole ore field as high- to medium-temperature hydrothermal formed at shallow to moderate depth. The following stages of ore mineral formation are recognized in the Pb-Zn mineral assemblage at the ROF: i) pre-ore; ii) high-temperature hydrothermal; iii) hypogene; iv) medium-temperature hydrothermal; v) low-temperature hydrothermal; and vi) supergene. Generally, there are two types of mineralization, brecciated ore veins with ribbon-like textures deposited in amphibolites or in contact with quarz latites, and impregnations within columnar ore bodies hosted in silicified and carbonated serpentinites (listwaenites). Ni-mineralization is represented by significant sulphide, arsenide, sulfarsenide, and sulfantimonide occurrences, but the most significant consists of gersdorffite-ullmannite series (GUS) minerals. It is the most developed in the Kaludjer deposit, much lesser at Plakaonica, whereas in the Crnac deposit it was not noted. The importance of the Ni mineralization is of scientific interest for now, as the attention has been directed only to the exploration of lead and zinc. However, it is believed that plans for the future will be focused on a detailed study of nickel. (C) 2014 Elsevier B.V. All rights reserved.
T2  - ORE Geology Reviews
T1  - Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships
VL  - 65
SP  - 213
EP  - 227
DO  - 10.1016/j.oregeorev.2014.09.029
ER  - 
@article{
author = "Radosavljevic, Slobodan A. and Stojanovic, Jovica N. and Vuković, Nikola S. and Radosavljević-Mihajlović, Ana S. and Kasic, Vladan D.",
year = "2015",
abstract = "The Rogozna ore field (ROF) belongs to the Serbo-Macedonian Metallogenic Province (SMMP), and covers a part of the western Dinarides rim and the Vardar ophiolite zone, situated within the Neogene volcanogenic-intrusive complex of calc-alkaline and shoshonitic rocks within the territories of Serbia and Kosovo. It is well-known for its Cu(Au, Pb, Zn) skarn mineralization and Pb(Ag)-Zn hydrothermal deposits and occurences. Mineral associations, deposition order and genesis of the ROF were discussed in detail. Complex ore parageneses were determined in the Crnac, Plalcaonica, and Kaludjer Pb(Ag)-Zn deposits and are composed of the following minerals: sulfides (pyrrhotite, chalcopyrrhotite, chalcopyrite, sphalerite, galena, pyrite, marcasite, millerite, bravoite), sulfosalts (arsenopolybasite, tetrahedrite, Ag-bearing tetrahedrite, Zn-bearing tetrahedrite, semseyite, heteromorphite, jamesonite, ferrokesterite), arsenides (nickeline), sulfarsenides and sulfantimonides (gersdorffite, Sb-bearing gersdorffite, Fe-bearing gersdorffite, As-bearing ullmannite, arsenopyrite), native metals (native Au, native Ag), oxides (Cr-spinel, rutile, anatase, leucoxene, magnetite, hematite) and gangue minerals (quartz, silicates, chalcedony, carbonates, monazite(Ce), barite, gypsum, anglesite, cerussite, smithsonite, zaratite, limonite). The high-, medium-, and low-temperature hydrothermal mineral assemblage occur throughout the Pb(Ag)-Zn deposits at Kaludjer-Crnac-Plakaonica ore system, in which the whole ore field as high- to medium-temperature hydrothermal formed at shallow to moderate depth. The following stages of ore mineral formation are recognized in the Pb-Zn mineral assemblage at the ROF: i) pre-ore; ii) high-temperature hydrothermal; iii) hypogene; iv) medium-temperature hydrothermal; v) low-temperature hydrothermal; and vi) supergene. Generally, there are two types of mineralization, brecciated ore veins with ribbon-like textures deposited in amphibolites or in contact with quarz latites, and impregnations within columnar ore bodies hosted in silicified and carbonated serpentinites (listwaenites). Ni-mineralization is represented by significant sulphide, arsenide, sulfarsenide, and sulfantimonide occurrences, but the most significant consists of gersdorffite-ullmannite series (GUS) minerals. It is the most developed in the Kaludjer deposit, much lesser at Plakaonica, whereas in the Crnac deposit it was not noted. The importance of the Ni mineralization is of scientific interest for now, as the attention has been directed only to the exploration of lead and zinc. However, it is believed that plans for the future will be focused on a detailed study of nickel. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "ORE Geology Reviews",
title = "Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships",
volume = "65",
pages = "213-227",
doi = "10.1016/j.oregeorev.2014.09.029"
}
Radosavljevic, S. A., Stojanovic, J. N., Vuković, N. S., Radosavljević-Mihajlović, A. S.,& Kasic, V. D.. (2015). Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships. in ORE Geology Reviews, 65, 213-227.
https://doi.org/10.1016/j.oregeorev.2014.09.029
Radosavljevic SA, Stojanovic JN, Vuković NS, Radosavljević-Mihajlović AS, Kasic VD. Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships. in ORE Geology Reviews. 2015;65:213-227.
doi:10.1016/j.oregeorev.2014.09.029 .
Radosavljevic, Slobodan A., Stojanovic, Jovica N., Vuković, Nikola S., Radosavljević-Mihajlović, Ana S., Kasic, Vladan D., "Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships" in ORE Geology Reviews, 65 (2015):213-227,
https://doi.org/10.1016/j.oregeorev.2014.09.029 . .
18
18
19

Sintering and electrical properties of Ce1-xBixO2-delta solid solution

Prekajski, Marija D.; Stojmenović, Marija; Radojkovic, A.; Branković, Goran O.; Oraon, H.; Subasri, R.; Matović, Branko

(2014)

TY  - JOUR
AU  - Prekajski, Marija D.
AU  - Stojmenović, Marija
AU  - Radojkovic, A.
AU  - Branković, Goran O.
AU  - Oraon, H.
AU  - Subasri, R.
AU  - Matović, Branko
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/187
AB  - Solid solution Ce1-xBixO2-delta nanopowders with the composition of x = 0.1-0.5 were synthesized by using Self Propagating Room Temperature procedure (SPRT). The results obtained by XRPD show that synthesized samples were single-phase solid solution at room temperature. Powders were densified by using Conventional (CS) and Microwave (MS) Sintering techniques at different temperatures, in an air atmosphere for 1 h. Scanning electron microscopy (SEM) and complex impedance method measurements were carried out on sintered samples. Maximum achieved density was for sample with Ce0.80Bi0.20O2-delta composition for both applied sintering techniques. The highest conductivity was obtained for the ceramic composition Ce0.80Bi0.20O2-delta sintered by microwave technique at 700 degrees C. (C) 2014 Elsevier B.V. All rights reserved.
T2  - Journal of Alloys and Compounds
T1  - Sintering and electrical properties of Ce1-xBixO2-delta solid solution
VL  - 617
SP  - 563
EP  - 568
DO  - 10.1016/j.jallcom.2014.08.090
ER  - 
@article{
author = "Prekajski, Marija D. and Stojmenović, Marija and Radojkovic, A. and Branković, Goran O. and Oraon, H. and Subasri, R. and Matović, Branko",
year = "2014",
abstract = "Solid solution Ce1-xBixO2-delta nanopowders with the composition of x = 0.1-0.5 were synthesized by using Self Propagating Room Temperature procedure (SPRT). The results obtained by XRPD show that synthesized samples were single-phase solid solution at room temperature. Powders were densified by using Conventional (CS) and Microwave (MS) Sintering techniques at different temperatures, in an air atmosphere for 1 h. Scanning electron microscopy (SEM) and complex impedance method measurements were carried out on sintered samples. Maximum achieved density was for sample with Ce0.80Bi0.20O2-delta composition for both applied sintering techniques. The highest conductivity was obtained for the ceramic composition Ce0.80Bi0.20O2-delta sintered by microwave technique at 700 degrees C. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "Journal of Alloys and Compounds",
title = "Sintering and electrical properties of Ce1-xBixO2-delta solid solution",
volume = "617",
pages = "563-568",
doi = "10.1016/j.jallcom.2014.08.090"
}
Prekajski, M. D., Stojmenović, M., Radojkovic, A., Branković, G. O., Oraon, H., Subasri, R.,& Matović, B.. (2014). Sintering and electrical properties of Ce1-xBixO2-delta solid solution. in Journal of Alloys and Compounds, 617, 563-568.
https://doi.org/10.1016/j.jallcom.2014.08.090
Prekajski MD, Stojmenović M, Radojkovic A, Branković GO, Oraon H, Subasri R, Matović B. Sintering and electrical properties of Ce1-xBixO2-delta solid solution. in Journal of Alloys and Compounds. 2014;617:563-568.
doi:10.1016/j.jallcom.2014.08.090 .
Prekajski, Marija D., Stojmenović, Marija, Radojkovic, A., Branković, Goran O., Oraon, H., Subasri, R., Matović, Branko, "Sintering and electrical properties of Ce1-xBixO2-delta solid solution" in Journal of Alloys and Compounds, 617 (2014):563-568,
https://doi.org/10.1016/j.jallcom.2014.08.090 . .
17
14
18

Rujevac Sb-Pb-Zn-As polymetallic deposit, Boranja orefield, Western Serbia: native arsenic and arsenic mineralization

Radosavljevic, Slobodan A.; Stojanovic, Jovica N.; Radosavljević-Mihajlović, Ana S.; Vuković, Nikola S.

(2014)

TY  - JOUR
AU  - Radosavljevic, Slobodan A.
AU  - Stojanovic, Jovica N.
AU  - Radosavljević-Mihajlović, Ana S.
AU  - Vuković, Nikola S.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5864
AB  - Rujevac is a low-temperature hydrothermal polymetallic Sb-Pb-Zn-As vein-type ore deposit, hosted within a volcanogenic-sedimentary zone situated in the Rujevac-Crvene Stene-Brezovica Diabase-Chert Formation (DCF) of the Podrinje Metallogenic District (PMD), Serbia. It is located several kilometers SE from the Boranja contact aureole, which is an integral part of the PMD in Western Serbia. Genetically related to the Tertiary granodioritic magma, the mineral assemblages are characterized by specific features. The mineral association of this deposit consists of sulfides, Pb-Sb(As) sulfosalts, native metals, oxides, hydroxides and gangue minerals. Chemical composition of the ore is very complex, where contents of valuable metals range as follows: Sb (0.17-24.31 wt.%), Zn (0.21-6.29 wt.%), Pb (0.15-6.33 wt.%), As (0.06-1.28 wt.%), Cd (25-747 ppm), Ag (7-408 ppm), Hg (13-473 ppm), and Tl ( LT 1-29 ppm). Electron Probe Microanalyses (EPMA) of native arsenic from both the Rujevac and Stragari deposits showed contents of As up to 98.8 and 97.1 wt.%, with impurity contents of Sb up to 1.3 and 6.6 wt.%, and Tl up to 2 and 1.3 wt.%, respectively. Rhombohedral unit-cell parameters for native arsenic from Rujevac and Stragari deposits amount to: a=3.760(2), c=10.555(3) angstrom, V=129.23(7) angstrom(3) and a=3.763(1), c=10.560(5) angstrom, V=129.48(8) angstrom(3), respectively. Mineral assemblages, deposition order and genesis of the Rujevac polymetallic deposit were also discussed in detail. Native arsenic mineralization here has been additionally compared with similar well-known global deposits.
T2  - Mineralogy and Petrology
T1  - Rujevac Sb-Pb-Zn-As polymetallic deposit, Boranja orefield, Western Serbia: native arsenic and arsenic mineralization
VL  - 108
IS  - 1
SP  - 111
EP  - 122
DO  - 10.1007/s00710-013-0291-5
ER  - 
@article{
author = "Radosavljevic, Slobodan A. and Stojanovic, Jovica N. and Radosavljević-Mihajlović, Ana S. and Vuković, Nikola S.",
year = "2014",
abstract = "Rujevac is a low-temperature hydrothermal polymetallic Sb-Pb-Zn-As vein-type ore deposit, hosted within a volcanogenic-sedimentary zone situated in the Rujevac-Crvene Stene-Brezovica Diabase-Chert Formation (DCF) of the Podrinje Metallogenic District (PMD), Serbia. It is located several kilometers SE from the Boranja contact aureole, which is an integral part of the PMD in Western Serbia. Genetically related to the Tertiary granodioritic magma, the mineral assemblages are characterized by specific features. The mineral association of this deposit consists of sulfides, Pb-Sb(As) sulfosalts, native metals, oxides, hydroxides and gangue minerals. Chemical composition of the ore is very complex, where contents of valuable metals range as follows: Sb (0.17-24.31 wt.%), Zn (0.21-6.29 wt.%), Pb (0.15-6.33 wt.%), As (0.06-1.28 wt.%), Cd (25-747 ppm), Ag (7-408 ppm), Hg (13-473 ppm), and Tl ( LT 1-29 ppm). Electron Probe Microanalyses (EPMA) of native arsenic from both the Rujevac and Stragari deposits showed contents of As up to 98.8 and 97.1 wt.%, with impurity contents of Sb up to 1.3 and 6.6 wt.%, and Tl up to 2 and 1.3 wt.%, respectively. Rhombohedral unit-cell parameters for native arsenic from Rujevac and Stragari deposits amount to: a=3.760(2), c=10.555(3) angstrom, V=129.23(7) angstrom(3) and a=3.763(1), c=10.560(5) angstrom, V=129.48(8) angstrom(3), respectively. Mineral assemblages, deposition order and genesis of the Rujevac polymetallic deposit were also discussed in detail. Native arsenic mineralization here has been additionally compared with similar well-known global deposits.",
journal = "Mineralogy and Petrology",
title = "Rujevac Sb-Pb-Zn-As polymetallic deposit, Boranja orefield, Western Serbia: native arsenic and arsenic mineralization",
volume = "108",
number = "1",
pages = "111-122",
doi = "10.1007/s00710-013-0291-5"
}
Radosavljevic, S. A., Stojanovic, J. N., Radosavljević-Mihajlović, A. S.,& Vuković, N. S.. (2014). Rujevac Sb-Pb-Zn-As polymetallic deposit, Boranja orefield, Western Serbia: native arsenic and arsenic mineralization. in Mineralogy and Petrology, 108(1), 111-122.
https://doi.org/10.1007/s00710-013-0291-5
Radosavljevic SA, Stojanovic JN, Radosavljević-Mihajlović AS, Vuković NS. Rujevac Sb-Pb-Zn-As polymetallic deposit, Boranja orefield, Western Serbia: native arsenic and arsenic mineralization. in Mineralogy and Petrology. 2014;108(1):111-122.
doi:10.1007/s00710-013-0291-5 .
Radosavljevic, Slobodan A., Stojanovic, Jovica N., Radosavljević-Mihajlović, Ana S., Vuković, Nikola S., "Rujevac Sb-Pb-Zn-As polymetallic deposit, Boranja orefield, Western Serbia: native arsenic and arsenic mineralization" in Mineralogy and Petrology, 108, no. 1 (2014):111-122,
https://doi.org/10.1007/s00710-013-0291-5 . .
8
5
8

Preparation and characterization of chrome doped sphene pigments prepared via precursor mechanochemical activation

Pantić, Jelena R.; Prekajski, Marija D.; Dramićanin, Miroslav; Abazović, Nadica; Vuković, Nikola; Kremenović, Aleksandar S.; Matović, Branko

(2013)

TY  - JOUR
AU  - Pantić, Jelena R.
AU  - Prekajski, Marija D.
AU  - Dramićanin, Miroslav
AU  - Abazović, Nadica
AU  - Vuković, Nikola
AU  - Kremenović, Aleksandar S.
AU  - Matović, Branko
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5684
AB  - Mechanical activation of precursors has been used for the preparation of Cr-doped sphene ceramic pigments (CaTi1-yCrySiO5). Ceramic material has been prepared from a powder mixture of CaCO3, TiO2, SiO2 and Cr(NO3)center dot 9H(2)O using vibro-milling for homogenization and activation of precursors. The mechanochemical process initially yielded amorphous powders, which on further calcination, crystallized to yield Cr-doped sphene ceramic pigment. Phase evolution in CaTi1-yCrySiO5 composition with thermal treatment was investigated by X-ray powder diffraction (XRPD). Texture properties and particle size distribution were analyzed by scanning electron microscopy (SEM) and laser diffraction, respectively. UV/Vis reflectance spectra are used to determinate the behavior of the chromium ion. The color efficiency of pigments was evaluated by colorimetric analysis (CIE L * a * b system). Photoluminescence measurements were also performed. (c) 2013 Elsevier B.V. All rights reserved.
T2  - Journal of Alloys and Compounds
T1  - Preparation and characterization of chrome doped sphene pigments prepared via precursor mechanochemical activation
VL  - 579
SP  - 290
EP  - 294
DO  - 10.1016/j.jallcom.2013.06.046
ER  - 
@article{
author = "Pantić, Jelena R. and Prekajski, Marija D. and Dramićanin, Miroslav and Abazović, Nadica and Vuković, Nikola and Kremenović, Aleksandar S. and Matović, Branko",
year = "2013",
abstract = "Mechanical activation of precursors has been used for the preparation of Cr-doped sphene ceramic pigments (CaTi1-yCrySiO5). Ceramic material has been prepared from a powder mixture of CaCO3, TiO2, SiO2 and Cr(NO3)center dot 9H(2)O using vibro-milling for homogenization and activation of precursors. The mechanochemical process initially yielded amorphous powders, which on further calcination, crystallized to yield Cr-doped sphene ceramic pigment. Phase evolution in CaTi1-yCrySiO5 composition with thermal treatment was investigated by X-ray powder diffraction (XRPD). Texture properties and particle size distribution were analyzed by scanning electron microscopy (SEM) and laser diffraction, respectively. UV/Vis reflectance spectra are used to determinate the behavior of the chromium ion. The color efficiency of pigments was evaluated by colorimetric analysis (CIE L * a * b system). Photoluminescence measurements were also performed. (c) 2013 Elsevier B.V. All rights reserved.",
journal = "Journal of Alloys and Compounds",
title = "Preparation and characterization of chrome doped sphene pigments prepared via precursor mechanochemical activation",
volume = "579",
pages = "290-294",
doi = "10.1016/j.jallcom.2013.06.046"
}
Pantić, J. R., Prekajski, M. D., Dramićanin, M., Abazović, N., Vuković, N., Kremenović, A. S.,& Matović, B.. (2013). Preparation and characterization of chrome doped sphene pigments prepared via precursor mechanochemical activation. in Journal of Alloys and Compounds, 579, 290-294.
https://doi.org/10.1016/j.jallcom.2013.06.046
Pantić JR, Prekajski MD, Dramićanin M, Abazović N, Vuković N, Kremenović AS, Matović B. Preparation and characterization of chrome doped sphene pigments prepared via precursor mechanochemical activation. in Journal of Alloys and Compounds. 2013;579:290-294.
doi:10.1016/j.jallcom.2013.06.046 .
Pantić, Jelena R., Prekajski, Marija D., Dramićanin, Miroslav, Abazović, Nadica, Vuković, Nikola, Kremenović, Aleksandar S., Matović, Branko, "Preparation and characterization of chrome doped sphene pigments prepared via precursor mechanochemical activation" in Journal of Alloys and Compounds, 579 (2013):290-294,
https://doi.org/10.1016/j.jallcom.2013.06.046 . .
5
5
7

Influence of mechanical activation on sphene based ceramic material synthesis

Pantić, Jelena R.; Kremenović, Aleksandar S.; Došen, Anja M.; Prekajski, Marija D.; Stanković, Nadežda; Baščarević, Zvezdana D.; Matović, Branko

(2013)

TY  - JOUR
AU  - Pantić, Jelena R.
AU  - Kremenović, Aleksandar S.
AU  - Došen, Anja M.
AU  - Prekajski, Marija D.
AU  - Stanković, Nadežda
AU  - Baščarević, Zvezdana D.
AU  - Matović, Branko
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5325
AB  - Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibromilling for homogenization and activation of precursors. The mechanochemical process initially yielded amorphous powders, which on further calcination, crystallized to yield sphene ceramic. The evolution of the phase composition with thermal treatment was investigated by X-ray powder diffraction (XRPD). Powder morphology and particle size distribution were analyzed by scanning electron microscopy (SEM) and laser diffraction, respectively. Rietveld refinement was employed to get the structural information of the synthesized powder. Densification and microstructure evolution was determined by means of density and scanning electron microscopy (SEM). The most favorable conditions for mechanical activation and synthesis of sphene based ceramic material are reported. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Influence of mechanical activation on sphene based ceramic material synthesis
VL  - 39
IS  - 1
SP  - 483
EP  - 488
DO  - 10.1016/j.ceramint.2012.06.052
ER  - 
@article{
author = "Pantić, Jelena R. and Kremenović, Aleksandar S. and Došen, Anja M. and Prekajski, Marija D. and Stanković, Nadežda and Baščarević, Zvezdana D. and Matović, Branko",
year = "2013",
abstract = "Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibromilling for homogenization and activation of precursors. The mechanochemical process initially yielded amorphous powders, which on further calcination, crystallized to yield sphene ceramic. The evolution of the phase composition with thermal treatment was investigated by X-ray powder diffraction (XRPD). Powder morphology and particle size distribution were analyzed by scanning electron microscopy (SEM) and laser diffraction, respectively. Rietveld refinement was employed to get the structural information of the synthesized powder. Densification and microstructure evolution was determined by means of density and scanning electron microscopy (SEM). The most favorable conditions for mechanical activation and synthesis of sphene based ceramic material are reported. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Influence of mechanical activation on sphene based ceramic material synthesis",
volume = "39",
number = "1",
pages = "483-488",
doi = "10.1016/j.ceramint.2012.06.052"
}
Pantić, J. R., Kremenović, A. S., Došen, A. M., Prekajski, M. D., Stanković, N., Baščarević, Z. D.,& Matović, B.. (2013). Influence of mechanical activation on sphene based ceramic material synthesis. in Ceramics International, 39(1), 483-488.
https://doi.org/10.1016/j.ceramint.2012.06.052
Pantić JR, Kremenović AS, Došen AM, Prekajski MD, Stanković N, Baščarević ZD, Matović B. Influence of mechanical activation on sphene based ceramic material synthesis. in Ceramics International. 2013;39(1):483-488.
doi:10.1016/j.ceramint.2012.06.052 .
Pantić, Jelena R., Kremenović, Aleksandar S., Došen, Anja M., Prekajski, Marija D., Stanković, Nadežda, Baščarević, Zvezdana D., Matović, Branko, "Influence of mechanical activation on sphene based ceramic material synthesis" in Ceramics International, 39, no. 1 (2013):483-488,
https://doi.org/10.1016/j.ceramint.2012.06.052 . .
10
11
12

Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features

Radosavljevic, Slobodan A.; Stojanovic, Jovica N.; Radosavljević-Mihajlović, Ana S.; Kasic, Vladan D.

(2013)

TY  - JOUR
AU  - Radosavljevic, Slobodan A.
AU  - Stojanovic, Jovica N.
AU  - Radosavljević-Mihajlović, Ana S.
AU  - Kasic, Vladan D.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5500
AB  - The Serbo-Macedonian Metallogenetic Province, part of the Alpine metallogenic belt, hosts several ore deposits in mainly three geotectonic units: the Vardar Zone, the Serbo-Macedonian massif, and to a lesser extend the Dinarides. This metallogenic province includes the most significant Pb-Zn and Sb deposits in Serbia, as well as smaller Bi, Mo, Cu, Fe, Sn, Au and minor U, Wand Hg deposits, which are genetically related to emplacement of granitoids. The Podrinje Metallogenic District belongs to the Serbo-Macedonian Metallogenetic Province and incorporates several smaller orefields: Cer (Northwest Serbia), Boranja (West Serbia), and Srebrenica (East Bosnia and Herzegovina). Polymetallic deposits in the Boranja orefield are genetically related to the emplacement of the Tertiary Boranja granodiorite complex. The orefield contains a large number of sulfide deposits with Pb-Zn, and Sb with subordinate Cu, As, Bi and Ag. Small magnetite deposits connected to pyrometasomatic (skarn) stage are also significant. Skarns are of calcic type, and were formed along contacts of Triassic limestones and quartz diorites. Ore minerals are similar among the various types of orebodies in the Boranja orefield and consist of sulfides, sulfosalts [Pb-Bi-(Ag)-Te-Cu, Pb-Sb-(As), Sb-Cu-(Ag, Fe, Zn)], tellurides, native metals and alloys, oxides and complex-oxides, and gangue minerals. Minerals of the Boranja orefield were formed in several successive stages, which together correspond to a single regional-scale mineralization event that is genetically related to the subvulcanic-plutonic intrusion of the Neogene-aged magmatic Boranja complex. This can be best demonstrated by the zonal arrangement of several metallic mineral associations [Fe-Cu(Bi) - GT Pb(Ag)-Zn - GT Sb(As) - GT CaF2(Pb-Zn)], with increasing distance from the Boranja granodiorite. Silver occurs as a minor metal principally as Ag-tetrahedrite, with subordinate native silver, Ag-bearing gold and pyrargyrite. Significant quantities of Ag can also be accommodated in galena as it is found to contain varied amounts of Ag, Bi and Sb (0.001-0.936, 0-3.345, and 0.012-0.510 wt%, respectively). The presence of both Ag and Bi in significant amounts in a Pb-rich sulfide system is essential for development of galena [solid solution alpha-(Pb-2, AgSb, AgBi)S-2]. This study demonstrates that silver, the most economic metal in Boranja orefield, is mainly accommodated in the galena structure, with lesser amounts present in the form of visible and/or invisible Pb-Bi-(Ag) sulfosalts.
T2  - Periodico di Mineralogia
T1  - Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features
VL  - 82
IS  - 1
SP  - 61
EP  - 87
DO  - 10.2451/2013PM0004
ER  - 
@article{
author = "Radosavljevic, Slobodan A. and Stojanovic, Jovica N. and Radosavljević-Mihajlović, Ana S. and Kasic, Vladan D.",
year = "2013",
abstract = "The Serbo-Macedonian Metallogenetic Province, part of the Alpine metallogenic belt, hosts several ore deposits in mainly three geotectonic units: the Vardar Zone, the Serbo-Macedonian massif, and to a lesser extend the Dinarides. This metallogenic province includes the most significant Pb-Zn and Sb deposits in Serbia, as well as smaller Bi, Mo, Cu, Fe, Sn, Au and minor U, Wand Hg deposits, which are genetically related to emplacement of granitoids. The Podrinje Metallogenic District belongs to the Serbo-Macedonian Metallogenetic Province and incorporates several smaller orefields: Cer (Northwest Serbia), Boranja (West Serbia), and Srebrenica (East Bosnia and Herzegovina). Polymetallic deposits in the Boranja orefield are genetically related to the emplacement of the Tertiary Boranja granodiorite complex. The orefield contains a large number of sulfide deposits with Pb-Zn, and Sb with subordinate Cu, As, Bi and Ag. Small magnetite deposits connected to pyrometasomatic (skarn) stage are also significant. Skarns are of calcic type, and were formed along contacts of Triassic limestones and quartz diorites. Ore minerals are similar among the various types of orebodies in the Boranja orefield and consist of sulfides, sulfosalts [Pb-Bi-(Ag)-Te-Cu, Pb-Sb-(As), Sb-Cu-(Ag, Fe, Zn)], tellurides, native metals and alloys, oxides and complex-oxides, and gangue minerals. Minerals of the Boranja orefield were formed in several successive stages, which together correspond to a single regional-scale mineralization event that is genetically related to the subvulcanic-plutonic intrusion of the Neogene-aged magmatic Boranja complex. This can be best demonstrated by the zonal arrangement of several metallic mineral associations [Fe-Cu(Bi) - GT Pb(Ag)-Zn - GT Sb(As) - GT CaF2(Pb-Zn)], with increasing distance from the Boranja granodiorite. Silver occurs as a minor metal principally as Ag-tetrahedrite, with subordinate native silver, Ag-bearing gold and pyrargyrite. Significant quantities of Ag can also be accommodated in galena as it is found to contain varied amounts of Ag, Bi and Sb (0.001-0.936, 0-3.345, and 0.012-0.510 wt%, respectively). The presence of both Ag and Bi in significant amounts in a Pb-rich sulfide system is essential for development of galena [solid solution alpha-(Pb-2, AgSb, AgBi)S-2]. This study demonstrates that silver, the most economic metal in Boranja orefield, is mainly accommodated in the galena structure, with lesser amounts present in the form of visible and/or invisible Pb-Bi-(Ag) sulfosalts.",
journal = "Periodico di Mineralogia",
title = "Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features",
volume = "82",
number = "1",
pages = "61-87",
doi = "10.2451/2013PM0004"
}
Radosavljevic, S. A., Stojanovic, J. N., Radosavljević-Mihajlović, A. S.,& Kasic, V. D.. (2013). Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features. in Periodico di Mineralogia, 82(1), 61-87.
https://doi.org/10.2451/2013PM0004
Radosavljevic SA, Stojanovic JN, Radosavljević-Mihajlović AS, Kasic VD. Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features. in Periodico di Mineralogia. 2013;82(1):61-87.
doi:10.2451/2013PM0004 .
Radosavljevic, Slobodan A., Stojanovic, Jovica N., Radosavljević-Mihajlović, Ana S., Kasic, Vladan D., "Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features" in Periodico di Mineralogia, 82, no. 1 (2013):61-87,
https://doi.org/10.2451/2013PM0004 . .
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9

Exchange-Bias and Grain-Surface Relaxations in Nanostructured NiO/Ni Induced by a Particle Size Reduction

Kremenović, Aleksandar S.; Jančar, Boštjan; Ristić, Mira; Vučinić-Vasić, Milica; Rogan, Jelena R.; Pacevski, Aleksandar; Antić, Bratislav

(2012)

TY  - JOUR
AU  - Kremenović, Aleksandar S.
AU  - Jančar, Boštjan
AU  - Ristić, Mira
AU  - Vučinić-Vasić, Milica
AU  - Rogan, Jelena R.
AU  - Pacevski, Aleksandar
AU  - Antić, Bratislav
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4726
AB  - Transition-metal-oxide/transition-metal nanocomposites, such as NiO/Ni, FeO/Fe, and CoO/Co, have been the subject of much recent investigation (i) because of their potential applications and (ii) because they are good model systems for studies of some effects on the nanoscale. They are used, for example, as catalysts, fuel-cell electrodes, magnetic memories, etc. When a nanocomposite is composed of both ferromagnetic (FM) and antiferromagnetic (AFM) nanoparticles, interesting physical properties can occur, such as the phenomenon of exchange bias (EB). A Ni/NiO nanocomposite obtained by the thermal decomposition of nickel(II) acetate tetrahydrate, Ni(CH3COO)(2)center dot 4H(2)O, at 300 degrees C, is composed of NiO (62%) and Ni (38%) with crystallite sizes of 11 and 278 nm, respectively. We observed an increase in the crystallite size for NiO and decrease of crystallite size for Ni, a decrease in the microstrain for both and an increase in the NiO phase content with thermal annealing in air, while high-energy ball milling leads to a decrease of the crystallite size, an increase in the size of the agglomerates, and microstrain as well as reduction, NiO - GT Ni. The lattice parameters of the nanosized NiO and Ni show a deviation from the value for the bulk counterparts as a consequence of crystallite size reduction and the grain-surface relaxation effect. The exchange bias found in a milled sample with particles of 10 nm (NiO) and 11 nm (Ni) disappears for larger particles as a consequence of a coupling-area decrease between the antiferromagnetic and ferromagnetic particles. Due to reduction/oxidation (NiO LT - GT Ni) and size as well as surface-relaxation effects the saturation magnetization value increases/decreases with milling/annealing, respectively. Having in mind the effect of size on the exchange bias, coercivity, and magnetization values, it is possible, by annealing/milling, to tailor the composition and particle size and then control the exchange bias and improve the other magnetic properties of the Ni/NiO.
T2  - Journal of Physical Chemistry. C
T1  - Exchange-Bias and Grain-Surface Relaxations in Nanostructured NiO/Ni Induced by a Particle Size Reduction
VL  - 116
IS  - 7
SP  - 4356
EP  - 4364
DO  - 10.1021/jp206658v
ER  - 
@article{
author = "Kremenović, Aleksandar S. and Jančar, Boštjan and Ristić, Mira and Vučinić-Vasić, Milica and Rogan, Jelena R. and Pacevski, Aleksandar and Antić, Bratislav",
year = "2012",
abstract = "Transition-metal-oxide/transition-metal nanocomposites, such as NiO/Ni, FeO/Fe, and CoO/Co, have been the subject of much recent investigation (i) because of their potential applications and (ii) because they are good model systems for studies of some effects on the nanoscale. They are used, for example, as catalysts, fuel-cell electrodes, magnetic memories, etc. When a nanocomposite is composed of both ferromagnetic (FM) and antiferromagnetic (AFM) nanoparticles, interesting physical properties can occur, such as the phenomenon of exchange bias (EB). A Ni/NiO nanocomposite obtained by the thermal decomposition of nickel(II) acetate tetrahydrate, Ni(CH3COO)(2)center dot 4H(2)O, at 300 degrees C, is composed of NiO (62%) and Ni (38%) with crystallite sizes of 11 and 278 nm, respectively. We observed an increase in the crystallite size for NiO and decrease of crystallite size for Ni, a decrease in the microstrain for both and an increase in the NiO phase content with thermal annealing in air, while high-energy ball milling leads to a decrease of the crystallite size, an increase in the size of the agglomerates, and microstrain as well as reduction, NiO - GT Ni. The lattice parameters of the nanosized NiO and Ni show a deviation from the value for the bulk counterparts as a consequence of crystallite size reduction and the grain-surface relaxation effect. The exchange bias found in a milled sample with particles of 10 nm (NiO) and 11 nm (Ni) disappears for larger particles as a consequence of a coupling-area decrease between the antiferromagnetic and ferromagnetic particles. Due to reduction/oxidation (NiO LT - GT Ni) and size as well as surface-relaxation effects the saturation magnetization value increases/decreases with milling/annealing, respectively. Having in mind the effect of size on the exchange bias, coercivity, and magnetization values, it is possible, by annealing/milling, to tailor the composition and particle size and then control the exchange bias and improve the other magnetic properties of the Ni/NiO.",
journal = "Journal of Physical Chemistry. C",
title = "Exchange-Bias and Grain-Surface Relaxations in Nanostructured NiO/Ni Induced by a Particle Size Reduction",
volume = "116",
number = "7",
pages = "4356-4364",
doi = "10.1021/jp206658v"
}
Kremenović, A. S., Jančar, B., Ristić, M., Vučinić-Vasić, M., Rogan, J. R., Pacevski, A.,& Antić, B.. (2012). Exchange-Bias and Grain-Surface Relaxations in Nanostructured NiO/Ni Induced by a Particle Size Reduction. in Journal of Physical Chemistry. C, 116(7), 4356-4364.
https://doi.org/10.1021/jp206658v
Kremenović AS, Jančar B, Ristić M, Vučinić-Vasić M, Rogan JR, Pacevski A, Antić B. Exchange-Bias and Grain-Surface Relaxations in Nanostructured NiO/Ni Induced by a Particle Size Reduction. in Journal of Physical Chemistry. C. 2012;116(7):4356-4364.
doi:10.1021/jp206658v .
Kremenović, Aleksandar S., Jančar, Boštjan, Ristić, Mira, Vučinić-Vasić, Milica, Rogan, Jelena R., Pacevski, Aleksandar, Antić, Bratislav, "Exchange-Bias and Grain-Surface Relaxations in Nanostructured NiO/Ni Induced by a Particle Size Reduction" in Journal of Physical Chemistry. C, 116, no. 7 (2012):4356-4364,
https://doi.org/10.1021/jp206658v . .
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