Serbian Ministry of Science and Technological Development [142066], NCEM, Office of Science, Office of Basic Energy Sciences of the US Department of Energy [DE:-AC02-05CH11231], Spanish MEC f

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Serbian Ministry of Science and Technological Development [142066], NCEM, Office of Science, Office of Basic Energy Sciences of the US Department of Energy [DE:-AC02-05CH11231], Spanish MEC f

Authors

Publications

Presence of Room Temperature Ferromagnetism in CO2+ Doped TiO2 Nanoparticles Synthesized through Shape Transformation

Kuljanin-Jakovljević, Jadranka Ž.; Radoičić, Marija B.; Radetić, Tamara; Konstantinović, Zorica; Šaponjić, Zoran; Nedeljković, Jovan

(2009)

TY  - JOUR
AU  - Kuljanin-Jakovljević, Jadranka Ž.
AU  - Radoičić, Marija B.
AU  - Radetić, Tamara
AU  - Konstantinović, Zorica
AU  - Šaponjić, Zoran
AU  - Nedeljković, Jovan
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3847
AB  - New approach for synthesis of Co2+ doped TiO2 nanoparticles showing room temperature ferromagnetic behavior, through shape transformation of hydrothermally treated scrolled titania nanotubes in the presence of Co2+ ions is described. The XRD and ICP measurements demonstrated successful incorporation of 0.46 at % Co2+ ions in preserved anatase crystal structure of TiO2 nanoparticles, without presence of Co-oxide Clustering, metallic Co, or Various Co-Ti oxide species. HRTEM measurements revealed that majority of the nanoparticles have polygonal shapes with average dimension of similar to 6-10 nm. Obtained Value of 3.06 eV for band gap energy of Co2+ doped TiO2 nanoparticles explained altered optical properties of TiO2 matrix and indicates narrowing of the electronic properties in respect to the undoped anatase TiO2 nanomaterials. The Co2+ doped TiO2 nanocrystals enabled synthesis of optically transparent film that shows room temperature ferromagnetic ordering with a saturation magnetic moment of 0 25 mu B per Co atom The proposed explanation for room temperature ferromagnetic behavior is based oil the presence of critical amount of oxygen vacancies that mediate interaction between Co2+ spins trapped in the lattice Structure of titania nanoparticles with undercoordinated surface defect sites.
T2  - Journal of Physical Chemistry. C
T1  - Presence of Room Temperature Ferromagnetism in CO2+ Doped TiO2 Nanoparticles Synthesized through Shape Transformation
VL  - 113
IS  - 50
SP  - 21029
EP  - 21033
DO  - 10.1021/jp905042k
ER  - 
@article{
author = "Kuljanin-Jakovljević, Jadranka Ž. and Radoičić, Marija B. and Radetić, Tamara and Konstantinović, Zorica and Šaponjić, Zoran and Nedeljković, Jovan",
year = "2009",
abstract = "New approach for synthesis of Co2+ doped TiO2 nanoparticles showing room temperature ferromagnetic behavior, through shape transformation of hydrothermally treated scrolled titania nanotubes in the presence of Co2+ ions is described. The XRD and ICP measurements demonstrated successful incorporation of 0.46 at % Co2+ ions in preserved anatase crystal structure of TiO2 nanoparticles, without presence of Co-oxide Clustering, metallic Co, or Various Co-Ti oxide species. HRTEM measurements revealed that majority of the nanoparticles have polygonal shapes with average dimension of similar to 6-10 nm. Obtained Value of 3.06 eV for band gap energy of Co2+ doped TiO2 nanoparticles explained altered optical properties of TiO2 matrix and indicates narrowing of the electronic properties in respect to the undoped anatase TiO2 nanomaterials. The Co2+ doped TiO2 nanocrystals enabled synthesis of optically transparent film that shows room temperature ferromagnetic ordering with a saturation magnetic moment of 0 25 mu B per Co atom The proposed explanation for room temperature ferromagnetic behavior is based oil the presence of critical amount of oxygen vacancies that mediate interaction between Co2+ spins trapped in the lattice Structure of titania nanoparticles with undercoordinated surface defect sites.",
journal = "Journal of Physical Chemistry. C",
title = "Presence of Room Temperature Ferromagnetism in CO2+ Doped TiO2 Nanoparticles Synthesized through Shape Transformation",
volume = "113",
number = "50",
pages = "21029-21033",
doi = "10.1021/jp905042k"
}
Kuljanin-Jakovljević, J. Ž., Radoičić, M. B., Radetić, T., Konstantinović, Z., Šaponjić, Z.,& Nedeljković, J.. (2009). Presence of Room Temperature Ferromagnetism in CO2+ Doped TiO2 Nanoparticles Synthesized through Shape Transformation. in Journal of Physical Chemistry. C, 113(50), 21029-21033.
https://doi.org/10.1021/jp905042k
Kuljanin-Jakovljević JŽ, Radoičić MB, Radetić T, Konstantinović Z, Šaponjić Z, Nedeljković J. Presence of Room Temperature Ferromagnetism in CO2+ Doped TiO2 Nanoparticles Synthesized through Shape Transformation. in Journal of Physical Chemistry. C. 2009;113(50):21029-21033.
doi:10.1021/jp905042k .
Kuljanin-Jakovljević, Jadranka Ž., Radoičić, Marija B., Radetić, Tamara, Konstantinović, Zorica, Šaponjić, Zoran, Nedeljković, Jovan, "Presence of Room Temperature Ferromagnetism in CO2+ Doped TiO2 Nanoparticles Synthesized through Shape Transformation" in Journal of Physical Chemistry. C, 113, no. 50 (2009):21029-21033,
https://doi.org/10.1021/jp905042k . .
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