TY  - JOUR
AU  - Anđelković, Ljubica
AU  - Šuljagić, Marija
AU  - Mirković, Miljana
AU  - Pavlović, Vera P.
AU  - Petronijević, Ivan
AU  - Stanković, Dalibor M.
AU  - Jeremić, Dejan
AU  - Uskoković, Vuk
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10935
AB  - The combination of an intense absorption of visible light and p-type semiconducting nature makes spinel cobalt oxide (Co3O4) a very attractive material for various optoelectronic applications. However, the traditional methods for its synthesis have been either time- and energy-consuming or relying on toxic chemicals. To solve this issue, a simple, facile, and eco-friendly method of synthesis was successfully developed to obtain spinel Co3O4 nanoparticles. The novel method for obtaining pure and monophasic Co3O4 reported here is based on the thermal decomposition of hexaaquacobalt(II) D-camphor10-sulfonate at 900 °C. This fast solid-state synthesis route overcomes the disadvantages of many combustion methods, most critically by avoiding the use of toxic organic solvents. The synthesized material was subjected to a detailed characterization to assess its potential for use as a nanocatalyst. The band gap measurements indicated the presence of two band gaps, one at 2.10 eV and another at 1.22 eV, confirming the purity and semiconducting properties of the sample. The electrochemical studies demonstrated a significant enhancement in the electron transfer kinetics with the addition of the synthesized Co3O4 to the carbon-paste electrode, leading to an enhanced electrocatalytic performance. These prominent functional properties, suitable for a wide range of technological applications, pave way for the implementation of the reported method for the synthesis of Co3O4 on a larger industrial scale. © 2023 Elsevier Ltd and Techna Group S.r.l.
T2  - Ceramics International
T1  - Semiconducting cobalt oxide nanocatalyst obtained through an eco-friendly thermal decomposition
VL  - 49
IS  - 14, Part A
SP  - 23491
EP  - 23498
DO  - 10.1016/j.ceramint.2023.04.182
ER  - 

@article{
author = "Anđelković, Ljubica and Šuljagić, Marija and Mirković, Miljana and Pavlović, Vera P. and Petronijević, Ivan and Stanković, Dalibor M. and Jeremić, Dejan and Uskoković, Vuk",
year = "2023",
abstract = "The combination of an intense absorption of visible light and p-type semiconducting nature makes spinel cobalt oxide (Co3O4) a very attractive material for various optoelectronic applications. However, the traditional methods for its synthesis have been either time- and energy-consuming or relying on toxic chemicals. To solve this issue, a simple, facile, and eco-friendly method of synthesis was successfully developed to obtain spinel Co3O4 nanoparticles. The novel method for obtaining pure and monophasic Co3O4 reported here is based on the thermal decomposition of hexaaquacobalt(II) D-camphor10-sulfonate at 900 °C. This fast solid-state synthesis route overcomes the disadvantages of many combustion methods, most critically by avoiding the use of toxic organic solvents. The synthesized material was subjected to a detailed characterization to assess its potential for use as a nanocatalyst. The band gap measurements indicated the presence of two band gaps, one at 2.10 eV and another at 1.22 eV, confirming the purity and semiconducting properties of the sample. The electrochemical studies demonstrated a significant enhancement in the electron transfer kinetics with the addition of the synthesized Co3O4 to the carbon-paste electrode, leading to an enhanced electrocatalytic performance. These prominent functional properties, suitable for a wide range of technological applications, pave way for the implementation of the reported method for the synthesis of Co3O4 on a larger industrial scale. © 2023 Elsevier Ltd and Techna Group S.r.l.",
journal = "Ceramics International",
title = "Semiconducting cobalt oxide nanocatalyst obtained through an eco-friendly thermal decomposition",
volume = "49",
number = "14, Part A",
pages = "23491-23498",
doi = "10.1016/j.ceramint.2023.04.182"
}

Anđelković, L., Šuljagić, M., Mirković, M., Pavlović, V. P., Petronijević, I., Stanković, D. M., Jeremić, D.,& Uskoković, V.. (2023). Semiconducting cobalt oxide nanocatalyst obtained through an eco-friendly thermal decomposition. in Ceramics International, 49(14, Part A), 23491-23498.
https://doi.org/10.1016/j.ceramint.2023.04.182

Anđelković L, Šuljagić M, Mirković M, Pavlović VP, Petronijević I, Stanković DM, Jeremić D, Uskoković V. Semiconducting cobalt oxide nanocatalyst obtained through an eco-friendly thermal decomposition. in Ceramics International. 2023;49(14, Part A):23491-23498.
doi:10.1016/j.ceramint.2023.04.182 .

Anđelković, Ljubica, Šuljagić, Marija, Mirković, Miljana, Pavlović, Vera P., Petronijević, Ivan, Stanković, Dalibor M., Jeremić, Dejan, Uskoković, Vuk, "Semiconducting cobalt oxide nanocatalyst obtained through an eco-friendly thermal decomposition" in Ceramics International, 49, no. 14, Part A (2023):23491-23498,
https://doi.org/10.1016/j.ceramint.2023.04.182 . .

TY  - JOUR
AU  - Petronijević, Ivan M.
AU  - Cerović, Dragana D.
AU  - Dudić, Duško
AU  - Dojčilović, Jablan R.
AU  - Dojčinović, Biljana P.
AU  - Pergal, Marija V.
PY  - 2018
UR  - http://doi.wiley.com/10.1002/pat.4289
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7708
AB  - In this paper, a new simple and environmentally friendly treatment technique for obtaining polymer nanocomposites with appropriate dielectric properties has been presented. Sheets of isotactic polypropylene and atactic polystyrene were immersed in 3 saturated water solutions of alkali metal salts (LiCl, NaCl, and KCl) at 2 fixed temperatures (23°C and 90°C), and 3 DC electrical potentials (+4 kV, −4 kV, and ground potential) were applied. A quantification of alkali metals in the polymer sheets was conducted by inductively coupled plasma optic emission spectrometry. The obtained concentration values were from 7.38·10−9 mol/cm3to 1.25·10−7 mol/cm3. The qualitative analysis of potassium distribution in the polymer matrix was conducted by time-of-flight secondary ion mass spectrometry cross-sectional record. The relative dielectric constant (ε′) of samples was investigated in the frequency range from 20 Hz to 9 MHz at the constant temperature of 22°C. Stable values of ε′ in fully measured frequency range were observed for both pure and treated samples. Next, the results of the dielectric spectroscopy measurements were compared and established the kind of treatment that provided the highest value of ε′. The relationship between the concentrations of alkali metals and the values of relative dielectric constant was determined for the samples obtained by a treatment at 90°C and +4 kV.
T2  - Polymers for Advanced Technologies
T1  - Dielectric spectroscopy of nanocomposites based on iPP and aPS treated in the water solutions of alkali metal salts
VL  - 29
IS  - 6
SP  - 1826
EP  - 1833
DO  - 10.1002/pat.4289
ER  - 

@article{
author = "Petronijević, Ivan M. and Cerović, Dragana D. and Dudić, Duško and Dojčilović, Jablan R. and Dojčinović, Biljana P. and Pergal, Marija V.",
year = "2018",
abstract = "In this paper, a new simple and environmentally friendly treatment technique for obtaining polymer nanocomposites with appropriate dielectric properties has been presented. Sheets of isotactic polypropylene and atactic polystyrene were immersed in 3 saturated water solutions of alkali metal salts (LiCl, NaCl, and KCl) at 2 fixed temperatures (23°C and 90°C), and 3 DC electrical potentials (+4 kV, −4 kV, and ground potential) were applied. A quantification of alkali metals in the polymer sheets was conducted by inductively coupled plasma optic emission spectrometry. The obtained concentration values were from 7.38·10−9 mol/cm3to 1.25·10−7 mol/cm3. The qualitative analysis of potassium distribution in the polymer matrix was conducted by time-of-flight secondary ion mass spectrometry cross-sectional record. The relative dielectric constant (ε′) of samples was investigated in the frequency range from 20 Hz to 9 MHz at the constant temperature of 22°C. Stable values of ε′ in fully measured frequency range were observed for both pure and treated samples. Next, the results of the dielectric spectroscopy measurements were compared and established the kind of treatment that provided the highest value of ε′. The relationship between the concentrations of alkali metals and the values of relative dielectric constant was determined for the samples obtained by a treatment at 90°C and +4 kV.",
journal = "Polymers for Advanced Technologies",
title = "Dielectric spectroscopy of nanocomposites based on iPP and aPS treated in the water solutions of alkali metal salts",
volume = "29",
number = "6",
pages = "1826-1833",
doi = "10.1002/pat.4289"
}

Petronijević, I. M., Cerović, D. D., Dudić, D., Dojčilović, J. R., Dojčinović, B. P.,& Pergal, M. V.. (2018). Dielectric spectroscopy of nanocomposites based on iPP and aPS treated in the water solutions of alkali metal salts. in Polymers for Advanced Technologies, 29(6), 1826-1833.
https://doi.org/10.1002/pat.4289

Petronijević IM, Cerović DD, Dudić D, Dojčilović JR, Dojčinović BP, Pergal MV. Dielectric spectroscopy of nanocomposites based on iPP and aPS treated in the water solutions of alkali metal salts. in Polymers for Advanced Technologies. 2018;29(6):1826-1833.
doi:10.1002/pat.4289 .

Petronijević, Ivan M., Cerović, Dragana D., Dudić, Duško, Dojčilović, Jablan R., Dojčinović, Biljana P., Pergal, Marija V., "Dielectric spectroscopy of nanocomposites based on iPP and aPS treated in the water solutions of alkali metal salts" in Polymers for Advanced Technologies, 29, no. 6 (2018):1826-1833,
https://doi.org/10.1002/pat.4289 . .

TY  - JOUR
AU  - Stojadinović, Bojan
AU  - Dohčević-Mitrović, Zorana 
AU  - Stepanenko, Dimitrije
AU  - Rosić, Milena
AU  - Petronijević, Ivan M.
AU  - Tasić, Nikola B.
AU  - Ilić, Nikola
AU  - Matović, Branko
AU  - Stojanovic, Biljana
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1804
AB  - We have studied Ho-doped BiFeO3 nanopowders (Bi1-xHoxFeO3, x = 0-0.15), prepared via sol-gel method, in order to analyse the effect of substitution-driven structural transition on dielectric and ferroelectric properties of bismuth ferrite. X-ray diffraction and Raman study demonstrated that an increased Ho concentration (x GT = 0.1) has induced gradual phase transition from rhombohedral to orthorhombic phase. The frequency dependent permittivity of Bi1-xHoxFeO3 nanopowders was analysed within a model which incorporates Debye-like dielectric response and dc and ac conductivity contributions based on universal dielectric response. It was shown that influence of leakage current and grain boundary/interface effects on dielectric and ferroelectric properties was substantially reduced in biphasic Bi1-xHoxFeO3 (x GT 0.1) samples. The electrical performance of Bi0.85Ho0.15FeO3 sample, for which orthorhombic phase prevailed, was significantly improved and Bi0.85Ho0.15FeO3 has sustained strong applied electric fields (up to 100 kV/cm) without breakdown. Under strong external fields, the polarization exhibited strong frequency dependence. The low-frequency remnant polarization and coercive field of Bi0.85Ho0.15FeO3 were significantly enhanced. It was proposed that defect dipolar polarization substantially contributed to the intrinsic polarization of Bi0.85Ho0.15FeO3 under strong electric fields at low frequencies.
T2  - Ceramics International
T1  - Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition
VL  - 43
IS  - 18
SP  - 16531
EP  - 16538
DO  - 10.1016/j.ceramint.2017.09.038
ER  - 

@article{
author = "Stojadinović, Bojan and Dohčević-Mitrović, Zorana  and Stepanenko, Dimitrije and Rosić, Milena and Petronijević, Ivan M. and Tasić, Nikola B. and Ilić, Nikola and Matović, Branko and Stojanovic, Biljana",
year = "2017",
abstract = "We have studied Ho-doped BiFeO3 nanopowders (Bi1-xHoxFeO3, x = 0-0.15), prepared via sol-gel method, in order to analyse the effect of substitution-driven structural transition on dielectric and ferroelectric properties of bismuth ferrite. X-ray diffraction and Raman study demonstrated that an increased Ho concentration (x GT = 0.1) has induced gradual phase transition from rhombohedral to orthorhombic phase. The frequency dependent permittivity of Bi1-xHoxFeO3 nanopowders was analysed within a model which incorporates Debye-like dielectric response and dc and ac conductivity contributions based on universal dielectric response. It was shown that influence of leakage current and grain boundary/interface effects on dielectric and ferroelectric properties was substantially reduced in biphasic Bi1-xHoxFeO3 (x GT 0.1) samples. The electrical performance of Bi0.85Ho0.15FeO3 sample, for which orthorhombic phase prevailed, was significantly improved and Bi0.85Ho0.15FeO3 has sustained strong applied electric fields (up to 100 kV/cm) without breakdown. Under strong external fields, the polarization exhibited strong frequency dependence. The low-frequency remnant polarization and coercive field of Bi0.85Ho0.15FeO3 were significantly enhanced. It was proposed that defect dipolar polarization substantially contributed to the intrinsic polarization of Bi0.85Ho0.15FeO3 under strong electric fields at low frequencies.",
journal = "Ceramics International",
title = "Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition",
volume = "43",
number = "18",
pages = "16531-16538",
doi = "10.1016/j.ceramint.2017.09.038"
}

Stojadinović, B., Dohčević-Mitrović, Z., Stepanenko, D., Rosić, M., Petronijević, I. M., Tasić, N. B., Ilić, N., Matović, B.,& Stojanovic, B.. (2017). Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition. in Ceramics International, 43(18), 16531-16538.
https://doi.org/10.1016/j.ceramint.2017.09.038

Stojadinović B, Dohčević-Mitrović Z, Stepanenko D, Rosić M, Petronijević IM, Tasić NB, Ilić N, Matović B, Stojanovic B. Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition. in Ceramics International. 2017;43(18):16531-16538.
doi:10.1016/j.ceramint.2017.09.038 .

Stojadinović, Bojan, Dohčević-Mitrović, Zorana , Stepanenko, Dimitrije, Rosić, Milena, Petronijević, Ivan M., Tasić, Nikola B., Ilić, Nikola, Matović, Branko, Stojanovic, Biljana, "Dielectric and ferroelectric properties of Ho-doped BiFeO3 nanopowders across the structural phase transition" in Ceramics International, 43, no. 18 (2017):16531-16538,
https://doi.org/10.1016/j.ceramint.2017.09.038 . .

TY  - JOUR
AU  - Dudić, Duško
AU  - Luyt, Adriaan S.
AU  - Marinković, Filip S.
AU  - Petronijević, Ivan M.
AU  - Dojčilović, Jablan R.
AU  - Kostoski, Dušan
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/341
AB  - Electrical AC conductivity of semiconducting low-density polyethylene (LDPE)-carbon black (CB) composites has been studied in the frequency range between 24 Hz and 75 kHz and the temperature range from 295 to 355 K. The composites were gamma irradiated at room temperature to different absorbed doses up to 300 kGy. The effects of gamma irradiation on the AC conductivity at room temperature and the conductive temperature coefficients (CTC) were observed. It was found that the effect of gamma irradiation on the stability of AC conductivity at elevated temperature (355 K) is dependent on the carbon black content and the gamma irradiation dose. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Radiation Physics and Chemistry
T1  - The effect of gamma irradiation on the thermal behavior of dielectric properties of linear low-density/carbon black semiconductive composites
VL  - 107
SP  - 89
EP  - 94
DO  - 10.1016/j.radphyschem.2014.10.003
ER  - 

@article{
author = "Dudić, Duško and Luyt, Adriaan S. and Marinković, Filip S. and Petronijević, Ivan M. and Dojčilović, Jablan R. and Kostoski, Dušan",
year = "2015",
abstract = "Electrical AC conductivity of semiconducting low-density polyethylene (LDPE)-carbon black (CB) composites has been studied in the frequency range between 24 Hz and 75 kHz and the temperature range from 295 to 355 K. The composites were gamma irradiated at room temperature to different absorbed doses up to 300 kGy. The effects of gamma irradiation on the AC conductivity at room temperature and the conductive temperature coefficients (CTC) were observed. It was found that the effect of gamma irradiation on the stability of AC conductivity at elevated temperature (355 K) is dependent on the carbon black content and the gamma irradiation dose. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Radiation Physics and Chemistry",
title = "The effect of gamma irradiation on the thermal behavior of dielectric properties of linear low-density/carbon black semiconductive composites",
volume = "107",
pages = "89-94",
doi = "10.1016/j.radphyschem.2014.10.003"
}

Dudić, D., Luyt, A. S., Marinković, F. S., Petronijević, I. M., Dojčilović, J. R.,& Kostoski, D.. (2015). The effect of gamma irradiation on the thermal behavior of dielectric properties of linear low-density/carbon black semiconductive composites. in Radiation Physics and Chemistry, 107, 89-94.
https://doi.org/10.1016/j.radphyschem.2014.10.003

Dudić D, Luyt AS, Marinković FS, Petronijević IM, Dojčilović JR, Kostoski D. The effect of gamma irradiation on the thermal behavior of dielectric properties of linear low-density/carbon black semiconductive composites. in Radiation Physics and Chemistry. 2015;107:89-94.
doi:10.1016/j.radphyschem.2014.10.003 .

Dudić, Duško, Luyt, Adriaan S., Marinković, Filip S., Petronijević, Ivan M., Dojčilović, Jablan R., Kostoski, Dušan, "The effect of gamma irradiation on the thermal behavior of dielectric properties of linear low-density/carbon black semiconductive composites" in Radiation Physics and Chemistry, 107 (2015):89-94,
https://doi.org/10.1016/j.radphyschem.2014.10.003 . .

TY  - JOUR
AU  - Csoka, Levente
AU  - Dudić, Duško
AU  - Petronijević, Ivan M.
AU  - Rozsa, C.
AU  - Halasz, K.
AU  - Đoković, Vladimir
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/439
AB  - Poly(ethyleneimine)-TiO2-anthocyanin modified cellulose fiber sheets were prepared as a support material for dye-sensitized solar cells. The study is focused on the effects of different anthocyanins on the photo-induced changes and contact relaxation of the surface AC-conductivity of the papers. The anthocyanins were extracted from purple cabbage, beet-root, plum peel, red vine and red currant juice. The results showed that there were pronounced contact relaxation effects at the interfaces between alumina electrode and the papers, which were further affected by the presence of anthocyanins. The electrode effects are mainly manifested by a decrease in conductance, which falls by about 30 % from its initial value about 400 min after the beginning of the experiment carried out in the dark. The illumination of the samples induces an increase in the magnitude of the observed changes in conductance but does not affect the nature of the relaxation processes. By estimating the temperature coefficients of conductivity of the papers and the changes in temperature during the illumination of the samples, we succeeded to separate the effects of heating from the total effects of illumination on the conductance and susceptance of the papers.
T2  - Cellulose
T1  - Photo-induced changes and contact relaxation of the surface AC-conductivity of the paper prepared from poly(ethyleneimine)-TiO2-anthocyanin modified cellulose fibers
VL  - 22
IS  - 1
SP  - 779
EP  - 788
DO  - 10.1007/s10570-014-0537-3
ER  - 

@article{
author = "Csoka, Levente and Dudić, Duško and Petronijević, Ivan M. and Rozsa, C. and Halasz, K. and Đoković, Vladimir",
year = "2015",
abstract = "Poly(ethyleneimine)-TiO2-anthocyanin modified cellulose fiber sheets were prepared as a support material for dye-sensitized solar cells. The study is focused on the effects of different anthocyanins on the photo-induced changes and contact relaxation of the surface AC-conductivity of the papers. The anthocyanins were extracted from purple cabbage, beet-root, plum peel, red vine and red currant juice. The results showed that there were pronounced contact relaxation effects at the interfaces between alumina electrode and the papers, which were further affected by the presence of anthocyanins. The electrode effects are mainly manifested by a decrease in conductance, which falls by about 30 % from its initial value about 400 min after the beginning of the experiment carried out in the dark. The illumination of the samples induces an increase in the magnitude of the observed changes in conductance but does not affect the nature of the relaxation processes. By estimating the temperature coefficients of conductivity of the papers and the changes in temperature during the illumination of the samples, we succeeded to separate the effects of heating from the total effects of illumination on the conductance and susceptance of the papers.",
journal = "Cellulose",
title = "Photo-induced changes and contact relaxation of the surface AC-conductivity of the paper prepared from poly(ethyleneimine)-TiO2-anthocyanin modified cellulose fibers",
volume = "22",
number = "1",
pages = "779-788",
doi = "10.1007/s10570-014-0537-3"
}

Csoka, L., Dudić, D., Petronijević, I. M., Rozsa, C., Halasz, K.,& Đoković, V.. (2015). Photo-induced changes and contact relaxation of the surface AC-conductivity of the paper prepared from poly(ethyleneimine)-TiO2-anthocyanin modified cellulose fibers. in Cellulose, 22(1), 779-788.
https://doi.org/10.1007/s10570-014-0537-3

Csoka L, Dudić D, Petronijević IM, Rozsa C, Halasz K, Đoković V. Photo-induced changes and contact relaxation of the surface AC-conductivity of the paper prepared from poly(ethyleneimine)-TiO2-anthocyanin modified cellulose fibers. in Cellulose. 2015;22(1):779-788.
doi:10.1007/s10570-014-0537-3 .

Csoka, Levente, Dudić, Duško, Petronijević, Ivan M., Rozsa, C., Halasz, K., Đoković, Vladimir, "Photo-induced changes and contact relaxation of the surface AC-conductivity of the paper prepared from poly(ethyleneimine)-TiO2-anthocyanin modified cellulose fibers" in Cellulose, 22, no. 1 (2015):779-788,
https://doi.org/10.1007/s10570-014-0537-3 . .

TY  - JOUR
AU  - Simonovic, Kosta
AU  - Petronijević, Ivan M.
AU  - Kostoski, Dušan
AU  - Dojčilović, Jablan R.
AU  - Luyt, Adriaan S.
AU  - Dudić, Duško
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/147
AB  - The surface dielectric properties of acid-etched low-density polyethylene (LDPE) were analysed in the frequency range from 20 Hz to 200 kHz. Samples were treated with various acids for a period of one hour, at temperatures ranging from 20 to 70 degrees C. After the treatment, the samples were analysed with Fourier transform infrared spectroscopy, revealing chemical and crystallinity changes on the surface, as a direct result of the treatment. The sample surfaces were analysed using atomic force microscopy. The micrographs show that the acid treatment increases the roughness of the samples. Compared to untreated LDPE, the etched samples may exhibit significantly different conductance values at low frequencies. It is also observed that an increase in the acid treatment temperature can result in lower values of conductance and susceptance compared to untreated samples. LDPE films with low value of surface AC conductivity after acid treatment are potentially useful substrates for high-speed electro-sensing applications. The presented results indicate that a suitable choice of acid treatment of LDPE can effect surface polarization while preserving low values of surface AC conductivity of the polymer. (c) 2014 Society of Chemical Industry
T2  - Polymer International
T1  - Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene
VL  - 63
IS  - 11
SP  - 1924
EP  - 1929
DO  - 10.1002/pi.4731
ER  - 

@article{
author = "Simonovic, Kosta and Petronijević, Ivan M. and Kostoski, Dušan and Dojčilović, Jablan R. and Luyt, Adriaan S. and Dudić, Duško",
year = "2014",
abstract = "The surface dielectric properties of acid-etched low-density polyethylene (LDPE) were analysed in the frequency range from 20 Hz to 200 kHz. Samples were treated with various acids for a period of one hour, at temperatures ranging from 20 to 70 degrees C. After the treatment, the samples were analysed with Fourier transform infrared spectroscopy, revealing chemical and crystallinity changes on the surface, as a direct result of the treatment. The sample surfaces were analysed using atomic force microscopy. The micrographs show that the acid treatment increases the roughness of the samples. Compared to untreated LDPE, the etched samples may exhibit significantly different conductance values at low frequencies. It is also observed that an increase in the acid treatment temperature can result in lower values of conductance and susceptance compared to untreated samples. LDPE films with low value of surface AC conductivity after acid treatment are potentially useful substrates for high-speed electro-sensing applications. The presented results indicate that a suitable choice of acid treatment of LDPE can effect surface polarization while preserving low values of surface AC conductivity of the polymer. (c) 2014 Society of Chemical Industry",
journal = "Polymer International",
title = "Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene",
volume = "63",
number = "11",
pages = "1924-1929",
doi = "10.1002/pi.4731"
}

Simonovic, K., Petronijević, I. M., Kostoski, D., Dojčilović, J. R., Luyt, A. S.,& Dudić, D.. (2014). Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene. in Polymer International, 63(11), 1924-1929.
https://doi.org/10.1002/pi.4731

Simonovic K, Petronijević IM, Kostoski D, Dojčilović JR, Luyt AS, Dudić D. Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene. in Polymer International. 2014;63(11):1924-1929.
doi:10.1002/pi.4731 .

Simonovic, Kosta, Petronijević, Ivan M., Kostoski, Dušan, Dojčilović, Jablan R., Luyt, Adriaan S., Dudić, Duško, "Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene" in Polymer International, 63, no. 11 (2014):1924-1929,
https://doi.org/10.1002/pi.4731 . .

TY  - JOUR
AU  - Petronijević, Ivan M.
AU  - Simonovic, K.
AU  - Marinković, Filip S.
AU  - Dojčilović, Jablan R.
AU  - Luyt, Adriaan S.
AU  - Dudić, Duško
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/120
AB  - This study describes the possibility of dielectric characterization of the initial stages of ageing in an low-density polyethylene (LDPE) + graphite composite, which is not possible using the standard method of dielectric spectroscopy. It is shown that the differences between the delay angles, Delta phi = phi(TRI)-phi(SIN), obtained using triangular and sinusoidal excitations on the composite samples, shows a maximum, and at the same time the position of this maximum shows more sensitivity to changes in the electrical properties of the material caused by ageing than other dielectric parameters. In order to clarify the applied methodology, a comparative analysis of the dielectric properties of other polymers poly(vinyl chloride) (PVC) and poly(vinyl alcohol) (PVA) and a conductive polymer composite (LDPE + carbon black) with respect to the application of sinusoidal and triangular electrical signals was carried out. Based on the presented results, we believe that the position of the peak in the frequency spectra of the difference between the delay angles obtained by using triangular and sinusoidal signals may be a suitable parameter for the dielectric characterization of polymeric materials.
T2  - Express Polymer Letters
T1  - The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals
VL  - 8
IS  - 10
SP  - 733
EP  - 744
DO  - 10.3144/expresspolymlett.2014.76
ER  - 

@article{
author = "Petronijević, Ivan M. and Simonovic, K. and Marinković, Filip S. and Dojčilović, Jablan R. and Luyt, Adriaan S. and Dudić, Duško",
year = "2014",
abstract = "This study describes the possibility of dielectric characterization of the initial stages of ageing in an low-density polyethylene (LDPE) + graphite composite, which is not possible using the standard method of dielectric spectroscopy. It is shown that the differences between the delay angles, Delta phi = phi(TRI)-phi(SIN), obtained using triangular and sinusoidal excitations on the composite samples, shows a maximum, and at the same time the position of this maximum shows more sensitivity to changes in the electrical properties of the material caused by ageing than other dielectric parameters. In order to clarify the applied methodology, a comparative analysis of the dielectric properties of other polymers poly(vinyl chloride) (PVC) and poly(vinyl alcohol) (PVA) and a conductive polymer composite (LDPE + carbon black) with respect to the application of sinusoidal and triangular electrical signals was carried out. Based on the presented results, we believe that the position of the peak in the frequency spectra of the difference between the delay angles obtained by using triangular and sinusoidal signals may be a suitable parameter for the dielectric characterization of polymeric materials.",
journal = "Express Polymer Letters",
title = "The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals",
volume = "8",
number = "10",
pages = "733-744",
doi = "10.3144/expresspolymlett.2014.76"
}

Petronijević, I. M., Simonovic, K., Marinković, F. S., Dojčilović, J. R., Luyt, A. S.,& Dudić, D.. (2014). The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals. in Express Polymer Letters, 8(10), 733-744.
https://doi.org/10.3144/expresspolymlett.2014.76

Petronijević IM, Simonovic K, Marinković FS, Dojčilović JR, Luyt AS, Dudić D. The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals. in Express Polymer Letters. 2014;8(10):733-744.
doi:10.3144/expresspolymlett.2014.76 .

Petronijević, Ivan M., Simonovic, K., Marinković, Filip S., Dojčilović, Jablan R., Luyt, Adriaan S., Dudić, Duško, "The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals" in Express Polymer Letters, 8, no. 10 (2014):733-744,
https://doi.org/10.3144/expresspolymlett.2014.76 . .