TY  - JOUR
AU  - Stefanovic, Ivan S.
AU  - Ekmescic, Bojana M.
AU  - Maksin, Danijela D.
AU  - Nastasović, Aleksandra B.
AU  - Miladinovic, Zoran P.
AU  - Vuković, Zorica M.
AU  - Micić, Darko M.
AU  - Pergal, Marija V.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/667
AB  - Novel macroporous functionalized copolymers with different cross-linker concentrations and porosity parameters were synthesized by reaction of the pendant epoxy groups of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (poly(GMA-co-EGDMA)) with hexamethylene diamine 1,3-bis(3-aminopropyl)tetramethyldisiloxane, and alpha,omega-diaminopropyl poly(dimethylsiloxane). The copolymers were prepared in forms, of spherical beads and characterized by Fourier transform infrared (FTIR); C-13 and Si-29 solid-state NMR, mercury porosimetry, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Copolymers prepared with the higher cross-linker concentrations have better thermal stability, higher glass transition temperatures; higher specific surface areas, and smaller pore diameters that correspond to half Of the pore volumes. Out results show that functionalization significantly changed porosity parameters, mechanism of thermal degradation; and increased thermal, stability in comparison with the initial copolymers. These macroporous copolymers could potentially have many applications, i.e. for sorption of heavy and precious metals or as Material for gas chromatography columns.
T2  - Industrial and Engineering Chemistry Research
T1  - Structure, Thermal, and Morphological Properties of Novel Macroporous Amino-Functionalized Glycidyl Methacrylate Based Copolymers
VL  - 54
IS  - 27
SP  - 6902
EP  - 6911
DO  - 10.1021/acs.iecr.5b01285
ER  - 

@article{
author = "Stefanovic, Ivan S. and Ekmescic, Bojana M. and Maksin, Danijela D. and Nastasović, Aleksandra B. and Miladinovic, Zoran P. and Vuković, Zorica M. and Micić, Darko M. and Pergal, Marija V.",
year = "2015",
abstract = "Novel macroporous functionalized copolymers with different cross-linker concentrations and porosity parameters were synthesized by reaction of the pendant epoxy groups of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (poly(GMA-co-EGDMA)) with hexamethylene diamine 1,3-bis(3-aminopropyl)tetramethyldisiloxane, and alpha,omega-diaminopropyl poly(dimethylsiloxane). The copolymers were prepared in forms, of spherical beads and characterized by Fourier transform infrared (FTIR); C-13 and Si-29 solid-state NMR, mercury porosimetry, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Copolymers prepared with the higher cross-linker concentrations have better thermal stability, higher glass transition temperatures; higher specific surface areas, and smaller pore diameters that correspond to half Of the pore volumes. Out results show that functionalization significantly changed porosity parameters, mechanism of thermal degradation; and increased thermal, stability in comparison with the initial copolymers. These macroporous copolymers could potentially have many applications, i.e. for sorption of heavy and precious metals or as Material for gas chromatography columns.",
journal = "Industrial and Engineering Chemistry Research",
title = "Structure, Thermal, and Morphological Properties of Novel Macroporous Amino-Functionalized Glycidyl Methacrylate Based Copolymers",
volume = "54",
number = "27",
pages = "6902-6911",
doi = "10.1021/acs.iecr.5b01285"
}

Stefanovic, I. S., Ekmescic, B. M., Maksin, D. D., Nastasović, A. B., Miladinovic, Z. P., Vuković, Z. M., Micić, D. M.,& Pergal, M. V.. (2015). Structure, Thermal, and Morphological Properties of Novel Macroporous Amino-Functionalized Glycidyl Methacrylate Based Copolymers. in Industrial and Engineering Chemistry Research, 54(27), 6902-6911.
https://doi.org/10.1021/acs.iecr.5b01285

Stefanovic IS, Ekmescic BM, Maksin DD, Nastasović AB, Miladinovic ZP, Vuković ZM, Micić DM, Pergal MV. Structure, Thermal, and Morphological Properties of Novel Macroporous Amino-Functionalized Glycidyl Methacrylate Based Copolymers. in Industrial and Engineering Chemistry Research. 2015;54(27):6902-6911.
doi:10.1021/acs.iecr.5b01285 .

Stefanovic, Ivan S., Ekmescic, Bojana M., Maksin, Danijela D., Nastasović, Aleksandra B., Miladinovic, Zoran P., Vuković, Zorica M., Micić, Darko M., Pergal, Marija V., "Structure, Thermal, and Morphological Properties of Novel Macroporous Amino-Functionalized Glycidyl Methacrylate Based Copolymers" in Industrial and Engineering Chemistry Research, 54, no. 27 (2015):6902-6911,
https://doi.org/10.1021/acs.iecr.5b01285 . .