TY  - JOUR
AU  - Simonovic, Kosta
AU  - Petronijević, Ivan M.
AU  - Kostoski, Dušan
AU  - Dojčilović, Jablan R.
AU  - Luyt, Adriaan S.
AU  - Dudić, Duško
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/147
AB  - The surface dielectric properties of acid-etched low-density polyethylene (LDPE) were analysed in the frequency range from 20 Hz to 200 kHz. Samples were treated with various acids for a period of one hour, at temperatures ranging from 20 to 70 degrees C. After the treatment, the samples were analysed with Fourier transform infrared spectroscopy, revealing chemical and crystallinity changes on the surface, as a direct result of the treatment. The sample surfaces were analysed using atomic force microscopy. The micrographs show that the acid treatment increases the roughness of the samples. Compared to untreated LDPE, the etched samples may exhibit significantly different conductance values at low frequencies. It is also observed that an increase in the acid treatment temperature can result in lower values of conductance and susceptance compared to untreated samples. LDPE films with low value of surface AC conductivity after acid treatment are potentially useful substrates for high-speed electro-sensing applications. The presented results indicate that a suitable choice of acid treatment of LDPE can effect surface polarization while preserving low values of surface AC conductivity of the polymer. (c) 2014 Society of Chemical Industry
T2  - Polymer International
T1  - Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene
VL  - 63
IS  - 11
SP  - 1924
EP  - 1929
DO  - 10.1002/pi.4731
ER  - 

@article{
author = "Simonovic, Kosta and Petronijević, Ivan M. and Kostoski, Dušan and Dojčilović, Jablan R. and Luyt, Adriaan S. and Dudić, Duško",
year = "2014",
abstract = "The surface dielectric properties of acid-etched low-density polyethylene (LDPE) were analysed in the frequency range from 20 Hz to 200 kHz. Samples were treated with various acids for a period of one hour, at temperatures ranging from 20 to 70 degrees C. After the treatment, the samples were analysed with Fourier transform infrared spectroscopy, revealing chemical and crystallinity changes on the surface, as a direct result of the treatment. The sample surfaces were analysed using atomic force microscopy. The micrographs show that the acid treatment increases the roughness of the samples. Compared to untreated LDPE, the etched samples may exhibit significantly different conductance values at low frequencies. It is also observed that an increase in the acid treatment temperature can result in lower values of conductance and susceptance compared to untreated samples. LDPE films with low value of surface AC conductivity after acid treatment are potentially useful substrates for high-speed electro-sensing applications. The presented results indicate that a suitable choice of acid treatment of LDPE can effect surface polarization while preserving low values of surface AC conductivity of the polymer. (c) 2014 Society of Chemical Industry",
journal = "Polymer International",
title = "Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene",
volume = "63",
number = "11",
pages = "1924-1929",
doi = "10.1002/pi.4731"
}

Simonovic, K., Petronijević, I. M., Kostoski, D., Dojčilović, J. R., Luyt, A. S.,& Dudić, D.. (2014). Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene. in Polymer International, 63(11), 1924-1929.
https://doi.org/10.1002/pi.4731

Simonovic K, Petronijević IM, Kostoski D, Dojčilović JR, Luyt AS, Dudić D. Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene. in Polymer International. 2014;63(11):1924-1929.
doi:10.1002/pi.4731 .

Simonovic, Kosta, Petronijević, Ivan M., Kostoski, Dušan, Dojčilović, Jablan R., Luyt, Adriaan S., Dudić, Duško, "Effects of acid treatment at different temperatures on the surface dielectric properties of low-density polyethylene" in Polymer International, 63, no. 11 (2014):1924-1929,
https://doi.org/10.1002/pi.4731 . .

TY  - JOUR
AU  - Petronijević, Ivan M.
AU  - Simonovic, K.
AU  - Marinković, Filip S.
AU  - Dojčilović, Jablan R.
AU  - Luyt, Adriaan S.
AU  - Dudić, Duško
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/120
AB  - This study describes the possibility of dielectric characterization of the initial stages of ageing in an low-density polyethylene (LDPE) + graphite composite, which is not possible using the standard method of dielectric spectroscopy. It is shown that the differences between the delay angles, Delta phi = phi(TRI)-phi(SIN), obtained using triangular and sinusoidal excitations on the composite samples, shows a maximum, and at the same time the position of this maximum shows more sensitivity to changes in the electrical properties of the material caused by ageing than other dielectric parameters. In order to clarify the applied methodology, a comparative analysis of the dielectric properties of other polymers poly(vinyl chloride) (PVC) and poly(vinyl alcohol) (PVA) and a conductive polymer composite (LDPE + carbon black) with respect to the application of sinusoidal and triangular electrical signals was carried out. Based on the presented results, we believe that the position of the peak in the frequency spectra of the difference between the delay angles obtained by using triangular and sinusoidal signals may be a suitable parameter for the dielectric characterization of polymeric materials.
T2  - Express Polymer Letters
T1  - The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals
VL  - 8
IS  - 10
SP  - 733
EP  - 744
DO  - 10.3144/expresspolymlett.2014.76
ER  - 

@article{
author = "Petronijević, Ivan M. and Simonovic, K. and Marinković, Filip S. and Dojčilović, Jablan R. and Luyt, Adriaan S. and Dudić, Duško",
year = "2014",
abstract = "This study describes the possibility of dielectric characterization of the initial stages of ageing in an low-density polyethylene (LDPE) + graphite composite, which is not possible using the standard method of dielectric spectroscopy. It is shown that the differences between the delay angles, Delta phi = phi(TRI)-phi(SIN), obtained using triangular and sinusoidal excitations on the composite samples, shows a maximum, and at the same time the position of this maximum shows more sensitivity to changes in the electrical properties of the material caused by ageing than other dielectric parameters. In order to clarify the applied methodology, a comparative analysis of the dielectric properties of other polymers poly(vinyl chloride) (PVC) and poly(vinyl alcohol) (PVA) and a conductive polymer composite (LDPE + carbon black) with respect to the application of sinusoidal and triangular electrical signals was carried out. Based on the presented results, we believe that the position of the peak in the frequency spectra of the difference between the delay angles obtained by using triangular and sinusoidal signals may be a suitable parameter for the dielectric characterization of polymeric materials.",
journal = "Express Polymer Letters",
title = "The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals",
volume = "8",
number = "10",
pages = "733-744",
doi = "10.3144/expresspolymlett.2014.76"
}

Petronijević, I. M., Simonovic, K., Marinković, F. S., Dojčilović, J. R., Luyt, A. S.,& Dudić, D.. (2014). The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals. in Express Polymer Letters, 8(10), 733-744.
https://doi.org/10.3144/expresspolymlett.2014.76

Petronijević IM, Simonovic K, Marinković FS, Dojčilović JR, Luyt AS, Dudić D. The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals. in Express Polymer Letters. 2014;8(10):733-744.
doi:10.3144/expresspolymlett.2014.76 .

Petronijević, Ivan M., Simonovic, K., Marinković, Filip S., Dojčilović, Jablan R., Luyt, Adriaan S., Dudić, Duško, "The detection of the early stages of ageing in an LDPE plus graphite composite by comparison of dielectric responses induced by sinusoidal and triangular signals" in Express Polymer Letters, 8, no. 10 (2014):733-744,
https://doi.org/10.3144/expresspolymlett.2014.76 . .