TY  - JOUR
AU  - Radenković, Marina
AU  - Petrović, Jelena
AU  - Pap, Sabolc
AU  - Kalijadis, Ana
AU  - Momčilović, Miloš
AU  - Krstulović, Nikša
AU  - Živković, Sanja
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12206
AB  - Toxic elements, lead, and copper are often found in wastewater discharged from industries such as mining. The discharge of untreated effluent poses severe environmental challenges and sorption methods using agricultural waste materials are proposed as an efficient and cost-effective solution. For this research, activated sunflower material (ASM) was prepared from abundantly available agricultural sunflower waste residues and utilised to remove Pb2+ and Cu2+ ions from an aqueous medium. To begin, we examine variables that may have an impact on the adsorption process, such as pH, contact time, adsorbent dose, and initial concentration using Box-Behnken Design (BBD) to find optimal conditions. Maximum removal efficiency was found at a pH of 5, contact time of 180 min, and initial concentration of 50 mg/L for Pb2+ and 150 mg/L for Cu2+. Additionally, adsorbent dose differed by element, for Cu2+ it was 200 mg, whilst for Pb2+ it was 124 mg. Features of activated carbon such as morphology, elemental composition, textural properties, and surface functionalities were characterised using SEM-EDS, BET, FTIR, and XPS. The adsorption equilibrium data were analysed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. It was found that the obtained results for Pb2+ adsorption were better described with the Freundlich isotherm model. Maximum adsorption capacities for Pb2+ and Cu2+ were 91.8 mg/g and 20.5 mg/g, respectively. Furthermore, kinetic studies confirmed that the adsorption process followed a pseudo-first-order kinetic model for Pb2+, but for Cu2+ all applied kinetic models fitted experimental data with the same values of the correlation coefficient (R2 = 0.99). After comprehensive analysis using the methods mentioned above, ASM was tested for the removal of Cu2+ from mining wastewater sample, and the obtained removal efficiency was 98.6% ± 2.0%. The results of desorption experiments conducted, confirm that ASM has good potential to be reused for the purpose of removing Cu2+ from wastewater.
T2  - Chemosphere
T1  - Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications
VL  - 347
SP  - 140684
DO  - 10.1016/j.chemosphere.2023.140684
ER  - 

@article{
author = "Radenković, Marina and Petrović, Jelena and Pap, Sabolc and Kalijadis, Ana and Momčilović, Miloš and Krstulović, Nikša and Živković, Sanja",
year = "2024",
abstract = "Toxic elements, lead, and copper are often found in wastewater discharged from industries such as mining. The discharge of untreated effluent poses severe environmental challenges and sorption methods using agricultural waste materials are proposed as an efficient and cost-effective solution. For this research, activated sunflower material (ASM) was prepared from abundantly available agricultural sunflower waste residues and utilised to remove Pb2+ and Cu2+ ions from an aqueous medium. To begin, we examine variables that may have an impact on the adsorption process, such as pH, contact time, adsorbent dose, and initial concentration using Box-Behnken Design (BBD) to find optimal conditions. Maximum removal efficiency was found at a pH of 5, contact time of 180 min, and initial concentration of 50 mg/L for Pb2+ and 150 mg/L for Cu2+. Additionally, adsorbent dose differed by element, for Cu2+ it was 200 mg, whilst for Pb2+ it was 124 mg. Features of activated carbon such as morphology, elemental composition, textural properties, and surface functionalities were characterised using SEM-EDS, BET, FTIR, and XPS. The adsorption equilibrium data were analysed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. It was found that the obtained results for Pb2+ adsorption were better described with the Freundlich isotherm model. Maximum adsorption capacities for Pb2+ and Cu2+ were 91.8 mg/g and 20.5 mg/g, respectively. Furthermore, kinetic studies confirmed that the adsorption process followed a pseudo-first-order kinetic model for Pb2+, but for Cu2+ all applied kinetic models fitted experimental data with the same values of the correlation coefficient (R2 = 0.99). After comprehensive analysis using the methods mentioned above, ASM was tested for the removal of Cu2+ from mining wastewater sample, and the obtained removal efficiency was 98.6% ± 2.0%. The results of desorption experiments conducted, confirm that ASM has good potential to be reused for the purpose of removing Cu2+ from wastewater.",
journal = "Chemosphere",
title = "Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications",
volume = "347",
pages = "140684",
doi = "10.1016/j.chemosphere.2023.140684"
}

Radenković, M., Petrović, J., Pap, S., Kalijadis, A., Momčilović, M., Krstulović, N.,& Živković, S.. (2024). Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications. in Chemosphere, 347, 140684.
https://doi.org/10.1016/j.chemosphere.2023.140684

Radenković M, Petrović J, Pap S, Kalijadis A, Momčilović M, Krstulović N, Živković S. Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications. in Chemosphere. 2024;347:140684.
doi:10.1016/j.chemosphere.2023.140684 .

Radenković, Marina, Petrović, Jelena, Pap, Sabolc, Kalijadis, Ana, Momčilović, Miloš, Krstulović, Nikša, Živković, Sanja, "Waste biomass derived highly-porous carbon material for toxic metal removal: Optimisation, mechanisms and environmental implications" in Chemosphere, 347 (2024):140684,
https://doi.org/10.1016/j.chemosphere.2023.140684 . .

TY  - CONF
AU  - Radenković, Marina
AU  - Petrović, Jelena D.
AU  - Pap, Sabolc
AU  - Kalijadis, Ana
AU  - Momčilović, Miloš
AU  - Živković, Sanja
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12436
AB  - U ovom radu za procenu efikasnosti uklanjanja bakra iz vodenih rastvora korišćen je aktivni ugalj dobijen od agroindustrijskog otpada suncokreta. Boks-Benkenov dizajn i metoda odzivne površine korišćeni su za optimizaciju procesnih parametara adsorpcije kao i međusobni uticaj varijabli na efikasnost uklanjanja. Sintetizovani aktivni ugalj primenjen je za uklanjanje bakra iz realnog uzorka otpadne vode, a dobijeni rezultati ukazuju na veliki afinitet za separaciju bakra (98,6% ± 2,0%).
AB  - In this work, activated carbon obtained from sunflower agro-industrial waste was used to evaluate the removal efficiency of copper from aqueous solutions. The Box-Behnken design combined with the response surface method was employed to optimize the adsorption process parameters as well as the mutual influence of the variables on removal efficiency. The synthesized activated carbon was applied to remove copper from a real wastewater sample, and the obtained results indicate a high affinity for copper separation (98,6% ± 2,0%).
PB  - Belgrade : Serbian Chemical Society
C3  - 59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings
T1  - Statistička optimizacija adsorpcije bakra iz vodenih rastvora korišćenjem aktiviranog ugljeničnog materijala agroindustrijskog otpada suncokreta
T1  - Statistical optimization of copper adsorption from aqueous solutions by sunflower waste derived activated carbon
SP  - 129
EP  - 129
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12079
ER  - 

@conference{
author = "Radenković, Marina and Petrović, Jelena D. and Pap, Sabolc and Kalijadis, Ana and Momčilović, Miloš and Živković, Sanja",
year = "2023",
abstract = "U ovom radu za procenu efikasnosti uklanjanja bakra iz vodenih rastvora korišćen je aktivni ugalj dobijen od agroindustrijskog otpada suncokreta. Boks-Benkenov dizajn i metoda odzivne površine korišćeni su za optimizaciju procesnih parametara adsorpcije kao i međusobni uticaj varijabli na efikasnost uklanjanja. Sintetizovani aktivni ugalj primenjen je za uklanjanje bakra iz realnog uzorka otpadne vode, a dobijeni rezultati ukazuju na veliki afinitet za separaciju bakra (98,6% ± 2,0%)., In this work, activated carbon obtained from sunflower agro-industrial waste was used to evaluate the removal efficiency of copper from aqueous solutions. The Box-Behnken design combined with the response surface method was employed to optimize the adsorption process parameters as well as the mutual influence of the variables on removal efficiency. The synthesized activated carbon was applied to remove copper from a real wastewater sample, and the obtained results indicate a high affinity for copper separation (98,6% ± 2,0%).",
publisher = "Belgrade : Serbian Chemical Society",
journal = "59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings",
title = "Statistička optimizacija adsorpcije bakra iz vodenih rastvora korišćenjem aktiviranog ugljeničnog materijala agroindustrijskog otpada suncokreta, Statistical optimization of copper adsorption from aqueous solutions by sunflower waste derived activated carbon",
pages = "129-129",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12079"
}

Radenković, M., Petrović, J. D., Pap, S., Kalijadis, A., Momčilović, M.,& Živković, S.. (2023). Statistička optimizacija adsorpcije bakra iz vodenih rastvora korišćenjem aktiviranog ugljeničnog materijala agroindustrijskog otpada suncokreta. in 59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings
Belgrade : Serbian Chemical Society., 129-129.
https://hdl.handle.net/21.15107/rcub_vinar_12079

Radenković M, Petrović JD, Pap S, Kalijadis A, Momčilović M, Živković S. Statistička optimizacija adsorpcije bakra iz vodenih rastvora korišćenjem aktiviranog ugljeničnog materijala agroindustrijskog otpada suncokreta. in 59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings. 2023;:129-129.
https://hdl.handle.net/21.15107/rcub_vinar_12079 .

Radenković, Marina, Petrović, Jelena D., Pap, Sabolc, Kalijadis, Ana, Momčilović, Miloš, Živković, Sanja, "Statistička optimizacija adsorpcije bakra iz vodenih rastvora korišćenjem aktiviranog ugljeničnog materijala agroindustrijskog otpada suncokreta" in 59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings (2023):129-129,
https://hdl.handle.net/21.15107/rcub_vinar_12079 .

TY  - CONF
AU  - Radenković, Marina
AU  - Petrović, Jelena D.
AU  - Pap, Sabolc
AU  - Živković, Sanja
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12437
AB  - Different industrial processes can potentially discharge heavy metals into surface and underground waters. These heavy metals can subsequently accumulate in organisms, posing a significant risk to both the environment and human health. Carbon-based materials such as biochar, carbon nanotubes-based materials, and activated carbon have been extensively researched for their effectiveness in adsorbing heavy metals from aqueous solutions [1]. Today, there is an increased interest in the usage of different low-cost, abundantly available lignocellulosic waste as a precursor for the production of activated carbon material. Activated carbon materials produced from different types of agricultural waste are widely used as adsorbent material for the removal of organic and inorganic pollutants from wastewater. High adsorption capacity is associated with characteristics of the adsorbent such as a large specific surface area, pore structure development, and the presence of different types of functional groups [2]. In this work, activated carbon is produced by the carbonization of sunflower agricultural waste followed by an activation process with potassium hydroxide. Activated carbon samples were characterized by SEM-EDS, BET, FTIR, and XPS. The obtained material has a porous structure with micropores and a large specific surface area, exhibiting a high affinity for the adsorption of lead and copper. Additionally, the main mechanism of lead and copper adsorption by sunflower-derived activated carbon has been successfully predicted.
PB  - Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club
C3  - 9th Conference of Young Chemists of Serbia : Book of abstracts
T1  - Highly microporous sunflower-derived activated carbon for lead and copper removal: Synthesis, characterization, and adsorption mechanism
SP  - 84
EP  - 84
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12437
ER  - 

@conference{
author = "Radenković, Marina and Petrović, Jelena D. and Pap, Sabolc and Živković, Sanja",
year = "2023",
abstract = "Different industrial processes can potentially discharge heavy metals into surface and underground waters. These heavy metals can subsequently accumulate in organisms, posing a significant risk to both the environment and human health. Carbon-based materials such as biochar, carbon nanotubes-based materials, and activated carbon have been extensively researched for their effectiveness in adsorbing heavy metals from aqueous solutions [1]. Today, there is an increased interest in the usage of different low-cost, abundantly available lignocellulosic waste as a precursor for the production of activated carbon material. Activated carbon materials produced from different types of agricultural waste are widely used as adsorbent material for the removal of organic and inorganic pollutants from wastewater. High adsorption capacity is associated with characteristics of the adsorbent such as a large specific surface area, pore structure development, and the presence of different types of functional groups [2]. In this work, activated carbon is produced by the carbonization of sunflower agricultural waste followed by an activation process with potassium hydroxide. Activated carbon samples were characterized by SEM-EDS, BET, FTIR, and XPS. The obtained material has a porous structure with micropores and a large specific surface area, exhibiting a high affinity for the adsorption of lead and copper. Additionally, the main mechanism of lead and copper adsorption by sunflower-derived activated carbon has been successfully predicted.",
publisher = "Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club",
journal = "9th Conference of Young Chemists of Serbia : Book of abstracts",
title = "Highly microporous sunflower-derived activated carbon for lead and copper removal: Synthesis, characterization, and adsorption mechanism",
pages = "84-84",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12437"
}

Radenković, M., Petrović, J. D., Pap, S.,& Živković, S.. (2023). Highly microporous sunflower-derived activated carbon for lead and copper removal: Synthesis, characterization, and adsorption mechanism. in 9th Conference of Young Chemists of Serbia : Book of abstracts
Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club., 84-84.
https://hdl.handle.net/21.15107/rcub_vinar_12437

Radenković M, Petrović JD, Pap S, Živković S. Highly microporous sunflower-derived activated carbon for lead and copper removal: Synthesis, characterization, and adsorption mechanism. in 9th Conference of Young Chemists of Serbia : Book of abstracts. 2023;:84-84.
https://hdl.handle.net/21.15107/rcub_vinar_12437 .

Radenković, Marina, Petrović, Jelena D., Pap, Sabolc, Živković, Sanja, "Highly microporous sunflower-derived activated carbon for lead and copper removal: Synthesis, characterization, and adsorption mechanism" in 9th Conference of Young Chemists of Serbia : Book of abstracts (2023):84-84,
https://hdl.handle.net/21.15107/rcub_vinar_12437 .