TY  - JOUR
AU  - Živković, Nikola V.
AU  - Zivkovic, Emila M.
AU  - Šerbanović, Slobodan P.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1443
AB  - Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations. (C) 2017 Elsevier Ltd.
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes
VL  - 108
SP  - 162
EP  - 180
DO  - 10.1016/j.jct.2017.01.018
ER  - 

@article{
author = "Živković, Nikola V. and Zivkovic, Emila M. and Šerbanović, Slobodan P. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj.",
year = "2017",
abstract = "Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations. (C) 2017 Elsevier Ltd.",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes",
volume = "108",
pages = "162-180",
doi = "10.1016/j.jct.2017.01.018"
}

Živković, N. V., Zivkovic, E. M., Šerbanović, S. P., Majstorović, D. M.,& Kijevčanin, M. Lj.. (2017). Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. in Journal of Chemical Thermodynamics, 108, 162-180.
https://doi.org/10.1016/j.jct.2017.01.018

Živković NV, Zivkovic EM, Šerbanović SP, Majstorović DM, Kijevčanin ML. Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2017;108:162-180.
doi:10.1016/j.jct.2017.01.018 .

Živković, Nikola V., Zivkovic, Emila M., Šerbanović, Slobodan P., Majstorović, Divna M., Kijevčanin, Mirjana Lj., "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 108 (2017):162-180,
https://doi.org/10.1016/j.jct.2017.01.018 . .

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Šerbanović, Slobodan P.
AU  - Stefanović, Predrag Lj.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5980
AB  - In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.
T2  - Hemijska industrija
T1  - Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases
VL  - 68
IS  - 1
SP  - 123
EP  - 134
DO  - 10.2298/HEMIND130312039S
ER  - 

@article{
author = "Spasojević, Vuk D. and Šerbanović, Slobodan P. and Stefanović, Predrag Lj. and Kijevčanin, Mirjana Lj.",
year = "2014",
abstract = "In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.",
journal = "Hemijska industrija",
title = "Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases",
volume = "68",
number = "1",
pages = "123-134",
doi = "10.2298/HEMIND130312039S"
}

Spasojević, V. D., Šerbanović, S. P., Stefanović, P. Lj.,& Kijevčanin, M. Lj.. (2014). Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. in Hemijska industrija, 68(1), 123-134.
https://doi.org/10.2298/HEMIND130312039S

Spasojević VD, Šerbanović SP, Stefanović PL, Kijevčanin ML. Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. in Hemijska industrija. 2014;68(1):123-134.
doi:10.2298/HEMIND130312039S .

Spasojević, Vuk D., Šerbanović, Slobodan P., Stefanović, Predrag Lj., Kijevčanin, Mirjana Lj., "Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases" in Hemijska industrija, 68, no. 1 (2014):123-134,
https://doi.org/10.2298/HEMIND130312039S . .

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Šerbanović, Slobodan P.
AU  - Zivkovic, Emila M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Stefanović, Predrag Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/162
AB  - In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.
T2  - Hemijska industrija
T1  - Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination
VL  - 68
IS  - 4
SP  - 491
EP  - 500
DO  - 10.2298/HEMIND130610074Z
ER  - 

@article{
author = "Živković, Nikola V. and Šerbanović, Slobodan P. and Zivkovic, Emila M. and Kijevčanin, Mirjana Lj. and Stefanović, Predrag Lj.",
year = "2014",
abstract = "In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.",
journal = "Hemijska industrija",
title = "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination",
volume = "68",
number = "4",
pages = "491-500",
doi = "10.2298/HEMIND130610074Z"
}

Živković, N. V., Šerbanović, S. P., Zivkovic, E. M., Kijevčanin, M. Lj.,& Stefanović, P. Lj.. (2014). Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. in Hemijska industrija, 68(4), 491-500.
https://doi.org/10.2298/HEMIND130610074Z

Živković NV, Šerbanović SP, Zivkovic EM, Kijevčanin ML, Stefanović PL. Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. in Hemijska industrija. 2014;68(4):491-500.
doi:10.2298/HEMIND130610074Z .

Živković, Nikola V., Šerbanović, Slobodan P., Zivkovic, Emila M., Kijevčanin, Mirjana Lj., Stefanović, Predrag Lj., "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination" in Hemijska industrija, 68, no. 4 (2014):491-500,
https://doi.org/10.2298/HEMIND130610074Z . .

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Djordjevic, Bojan D.
AU  - Šerbanović, Slobodan P.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6039
AB  - Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.
T2  - Journal of Chemical and Engineering Data
T1  - Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K
VL  - 59
IS  - 6
SP  - 1817
EP  - 1829
DO  - 10.1021/je401036f
ER  - 

@article{
author = "Spasojević, Vuk D. and Djordjevic, Bojan D. and Šerbanović, Slobodan P. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2014",
abstract = "Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.",
journal = "Journal of Chemical and Engineering Data",
title = "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K",
volume = "59",
number = "6",
pages = "1817-1829",
doi = "10.1021/je401036f"
}

Spasojević, V. D., Djordjevic, B. D., Šerbanović, S. P., Radović, I. R.,& Kijevčanin, M. Lj.. (2014). Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data, 59(6), 1817-1829.
https://doi.org/10.1021/je401036f

Spasojević VD, Djordjevic BD, Šerbanović SP, Radović IR, Kijevčanin ML. Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data. 2014;59(6):1817-1829.
doi:10.1021/je401036f .

Spasojević, Vuk D., Djordjevic, Bojan D., Šerbanović, Slobodan P., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K" in Journal of Chemical and Engineering Data, 59, no. 6 (2014):1817-1829,
https://doi.org/10.1021/je401036f . .