Marković, Darka

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Authority KeyName Variants
251ca748-4eb2-4b49-b719-5761f2d87b62
  • Marković, Darka (25)
Projects
Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200287 (Innovation Center of the Faculty of Technology and Metallurgy)
COST Action [CA17107] Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden German Academic Exchange Service - DAAD (Project ID: 57140416)
German Federal Ministry of Education and Research - BMBF (FKZ 01PL11082B) STRENTEX - ERA Chair for emerging technologies and innovative research in Stretchable and Textile Electronics
Functionalization, characterization and application of cellulose and cellulose derivatives Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes
Functional physiologically active plant materials with additional values for application in pharmaceutical and food industry Research and verification of the multidisciplinary forensic methods in
info:eu-repo/grantAgreement/ScienceFundRS/Ideje/7673808/RS/ SORBTEX - Sustainable implementation of textile waste in treatment of polluted water
NATO Science for Peace and Security Programme [G5905 - MULProTex] NATO Science for Peace and Security (SPS) program [G5905 (MULProTex)]
NATO Science for Peace and Security (SPS) program [Project G5905 (MULProTex)]

Author's Bibliography

Čišćenje naftnih mrlja pomoću netkanog sorbenta proizvedenog od post-industrijskog tekstilnog otpada

Kovačević, Aleksandar; Marković, Darka; Radoičić, Marija; Radetić, Maja

(Belgrade : Serbian Chemical Society, 2023)

TY  - CONF
AU  - Kovačević, Aleksandar
AU  - Marković, Darka
AU  - Radoičić, Marija
AU  - Radetić, Maja
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13038
AB  - Efikasno i jeftino čišćenje naftnih mrlja sa vode i tla kao i generisanje ogromnih količina tekstilnog otpada su goreći ekološki problemi koji zahtevaju hitno rešavanje. U pokušaju da se odgovori na oba izazova, proizveden je iglovani netkani sorbent od recikliranih vlakana jute iz industrije tepiha. Ispitan je uticaj površinske mase i debljine sorbenata na sorpcioni kapacitet za naftu u vodi i u nafti bez vode, sposobnost plutanja, sposobnost zadržavanja nafte i mogućnost ponovne upotrebe. Svi sorbenti su položili test plutanja. Površinska masa sorbenata i viskozitet testirane nafte i naftnih derivata (sirova nafta, dizel gorivo i dva motorna ulja) imaju snažan uticaj na sorpcioni kapacitet i sposobnost zadržavanja nafte. Sorbenti uglavnom zadržavaju do 50% svojih početnih sorpcionih kapaciteta nakon 5 ponovljenih ciklusa sorpcije što ukazuje da se mogu višekratno koristiti.
AB  - Efficient and inexpensive cleanup of oil spills on water or land and huge generation of textile waste are burning environmental issues that are seeking urgent solutions. In an attempt to address both challenges, needle-punched non-woven sorbents (NWSs) based on recycled jute fibers from the carpet industry were manufactured. The influence of NWS area density and thickness on oil sorption capacity in water and oil without water, buoyancy, oil retention and reusability were studied. All NWSs passed the buoyancy test. The area density of NWSs and viscosity of tested oils (crude oil, diesel oil and two motor oils) strongly affect the oil sorption capacity and oil retention. NWSs mainly retain 50% of their initial oil sorption capacities after 5 repeated sorption cycles indicating that NWSs could be used several times.
PB  - Belgrade : Serbian Chemical Society
C3  - 59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings
T1  - Čišćenje naftnih mrlja pomoću netkanog sorbenta proizvedenog od post-industrijskog tekstilnog otpada
T1  - Oil spills cleanup with non-woven sorbent produced from postindustrial textile waste
SP  - 143
EP  - 143
UR  - https://hdl.handle.net/21.15107/rcub_vinar_13038
ER  - 
@conference{
author = "Kovačević, Aleksandar and Marković, Darka and Radoičić, Marija and Radetić, Maja",
year = "2023",
abstract = "Efikasno i jeftino čišćenje naftnih mrlja sa vode i tla kao i generisanje ogromnih količina tekstilnog otpada su goreći ekološki problemi koji zahtevaju hitno rešavanje. U pokušaju da se odgovori na oba izazova, proizveden je iglovani netkani sorbent od recikliranih vlakana jute iz industrije tepiha. Ispitan je uticaj površinske mase i debljine sorbenata na sorpcioni kapacitet za naftu u vodi i u nafti bez vode, sposobnost plutanja, sposobnost zadržavanja nafte i mogućnost ponovne upotrebe. Svi sorbenti su položili test plutanja. Površinska masa sorbenata i viskozitet testirane nafte i naftnih derivata (sirova nafta, dizel gorivo i dva motorna ulja) imaju snažan uticaj na sorpcioni kapacitet i sposobnost zadržavanja nafte. Sorbenti uglavnom zadržavaju do 50% svojih početnih sorpcionih kapaciteta nakon 5 ponovljenih ciklusa sorpcije što ukazuje da se mogu višekratno koristiti., Efficient and inexpensive cleanup of oil spills on water or land and huge generation of textile waste are burning environmental issues that are seeking urgent solutions. In an attempt to address both challenges, needle-punched non-woven sorbents (NWSs) based on recycled jute fibers from the carpet industry were manufactured. The influence of NWS area density and thickness on oil sorption capacity in water and oil without water, buoyancy, oil retention and reusability were studied. All NWSs passed the buoyancy test. The area density of NWSs and viscosity of tested oils (crude oil, diesel oil and two motor oils) strongly affect the oil sorption capacity and oil retention. NWSs mainly retain 50% of their initial oil sorption capacities after 5 repeated sorption cycles indicating that NWSs could be used several times.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings",
title = "Čišćenje naftnih mrlja pomoću netkanog sorbenta proizvedenog od post-industrijskog tekstilnog otpada, Oil spills cleanup with non-woven sorbent produced from postindustrial textile waste",
pages = "143-143",
url = "https://hdl.handle.net/21.15107/rcub_vinar_13038"
}
Kovačević, A., Marković, D., Radoičić, M.,& Radetić, M.. (2023). Čišćenje naftnih mrlja pomoću netkanog sorbenta proizvedenog od post-industrijskog tekstilnog otpada. in 59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings
Belgrade : Serbian Chemical Society., 143-143.
https://hdl.handle.net/21.15107/rcub_vinar_13038
Kovačević A, Marković D, Radoičić M, Radetić M. Čišćenje naftnih mrlja pomoću netkanog sorbenta proizvedenog od post-industrijskog tekstilnog otpada. in 59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings. 2023;:143-143.
https://hdl.handle.net/21.15107/rcub_vinar_13038 .
Kovačević, Aleksandar, Marković, Darka, Radoičić, Marija, Radetić, Maja, "Čišćenje naftnih mrlja pomoću netkanog sorbenta proizvedenog od post-industrijskog tekstilnog otpada" in 59th Meeting of the Serbian Chemical Society : Book of Abstracts, Proceedings (2023):143-143,
https://hdl.handle.net/21.15107/rcub_vinar_13038 .

Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles

Marković, Darka; Petkovska, Jovana; Mladenović, Nina; Radoičić, Marija B.; Rodriguez-Melendez, Danixa; Ilić-Tomić, Tatjana; Radetić, Maja M.; Grunlan, Jaime; Jordanov, Igor

(2023)

TY  - JOUR
AU  - Marković, Darka
AU  - Petkovska, Jovana
AU  - Mladenović, Nina
AU  - Radoičić, Marija B.
AU  - Rodriguez-Melendez, Danixa
AU  - Ilić-Tomić, Tatjana
AU  - Radetić, Maja M.
AU  - Grunlan, Jaime
AU  - Jordanov, Igor
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10753
AB  - Poor antimicrobial activity and lack of protection against UV irradiation are weaknesses of cottontextiles. In an attempt to impart superior antimicrobial and UV-protective properties to cotton, layer-by-layer deposition of chitosan and magnesium lignosulfonate, and in situ synthesis of silver (Ag)nanoparticles (NPs), was performed. Lignin, in a chitosan/lignin multilayer, simultaneously acts as a UVprotective macromolecule and natural reducing and stabilizing agent, allowing formation of Ag NPs. Fourbilayers of this coating is sufficient for fabrication of a chitosan/lignin/Ag-NP textile nanocompositetreatment with 50+ UV protection. 100% reduction of Gram-negative bacteria Escherichia coli, gram-positive bacteria Staphylococcus aureus, and yeast Candida albicans can be achieved with a 12-bilayercoating, when 20 mM silver nitrate solution and sodium borohydride are applied. On the other hand,four bilayers impregnated with Ag NPs, using 10 mM silver nitrate solution, provides sufficientantimicrobial activity independent of an added reducing agent. This treatment exhibits no inhibition ofhuman keratinocyte cells growth on the skin, indicating low cytotoxicity.
T2  - Journal of Applied Polymer Science
T1  - Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles
VL  - 140
IS  - 19
SP  - e53823
DO  - 10.1002/app.53823
ER  - 
@article{
author = "Marković, Darka and Petkovska, Jovana and Mladenović, Nina and Radoičić, Marija B. and Rodriguez-Melendez, Danixa and Ilić-Tomić, Tatjana and Radetić, Maja M. and Grunlan, Jaime and Jordanov, Igor",
year = "2023",
abstract = "Poor antimicrobial activity and lack of protection against UV irradiation are weaknesses of cottontextiles. In an attempt to impart superior antimicrobial and UV-protective properties to cotton, layer-by-layer deposition of chitosan and magnesium lignosulfonate, and in situ synthesis of silver (Ag)nanoparticles (NPs), was performed. Lignin, in a chitosan/lignin multilayer, simultaneously acts as a UVprotective macromolecule and natural reducing and stabilizing agent, allowing formation of Ag NPs. Fourbilayers of this coating is sufficient for fabrication of a chitosan/lignin/Ag-NP textile nanocompositetreatment with 50+ UV protection. 100% reduction of Gram-negative bacteria Escherichia coli, gram-positive bacteria Staphylococcus aureus, and yeast Candida albicans can be achieved with a 12-bilayercoating, when 20 mM silver nitrate solution and sodium borohydride are applied. On the other hand,four bilayers impregnated with Ag NPs, using 10 mM silver nitrate solution, provides sufficientantimicrobial activity independent of an added reducing agent. This treatment exhibits no inhibition ofhuman keratinocyte cells growth on the skin, indicating low cytotoxicity.",
journal = "Journal of Applied Polymer Science",
title = "Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles",
volume = "140",
number = "19",
pages = "e53823",
doi = "10.1002/app.53823"
}
Marković, D., Petkovska, J., Mladenović, N., Radoičić, M. B., Rodriguez-Melendez, D., Ilić-Tomić, T., Radetić, M. M., Grunlan, J.,& Jordanov, I.. (2023). Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles. in Journal of Applied Polymer Science, 140(19), e53823.
https://doi.org/10.1002/app.53823
Marković D, Petkovska J, Mladenović N, Radoičić MB, Rodriguez-Melendez D, Ilić-Tomić T, Radetić MM, Grunlan J, Jordanov I. Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles. in Journal of Applied Polymer Science. 2023;140(19):e53823.
doi:10.1002/app.53823 .
Marković, Darka, Petkovska, Jovana, Mladenović, Nina, Radoičić, Marija B., Rodriguez-Melendez, Danixa, Ilić-Tomić, Tatjana, Radetić, Maja M., Grunlan, Jaime, Jordanov, Igor, "Antimicrobial and UV protective chitosan/lignin multilayer nanocoating with immobilized silver nanoparticles" in Journal of Applied Polymer Science, 140, no. 19 (2023):e53823,
https://doi.org/10.1002/app.53823 . .
3
3

Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation

Kovačević, Aleksandar; Radoičić, Marija B.; Marković, Darka; Ponjavić, Marijana; Nikodinović-Runić, Jasmina; Radetić, Maja M.

(2023)

TY  - JOUR
AU  - Kovačević, Aleksandar
AU  - Radoičić, Marija B.
AU  - Marković, Darka
AU  - Ponjavić, Marijana
AU  - Nikodinović-Runić, Jasmina
AU  - Radetić, Maja M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10920
AB  - Loose assemblies of cellulose fibers could be employed in the clean-up of oil spills, but the difficulty to separate them from the spill after use makes them impractical. In an effort to tackle this issue, a non-woven sorbent based on recycled jute fibers from the carpet industry was developed. To enhance the porosity and hydrophobicity/oleophilicity of the sorbent, carbonization in an inert atmosphere was carried out. A comparison in oil sorption performance between non-carbonized and carbonized sorbents was made by evaluating the oil capacity in a water medium, buoyancy, oil retention and reusability. Carbonization of sorbent resulted in more than doubled oil sorption capacity independent of oil viscosity. Oil viscosity did not affect the oil sorption capacity of non-carbonized sorbent. Carbonized sorbent showed superior buoyancy in water even after 24 hours, oil retention of approximately 60–80% after 3 hours and only 12–20% decline of oil sorption capacity after five repeated sorption/desorption trials. However, the ability of oiled non-carbonized sorbent to efficiently biodegrade in model compost (up to 45% weight loss after 10 weeks) makes it a sustainable candidate for oil spill clean-up.
T2  - Environmental Technology and Innovation
T1  - Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation
VL  - 31
SP  - 103170
DO  - 10.1016/j.eti.2023.103170
ER  - 
@article{
author = "Kovačević, Aleksandar and Radoičić, Marija B. and Marković, Darka and Ponjavić, Marijana and Nikodinović-Runić, Jasmina and Radetić, Maja M.",
year = "2023",
abstract = "Loose assemblies of cellulose fibers could be employed in the clean-up of oil spills, but the difficulty to separate them from the spill after use makes them impractical. In an effort to tackle this issue, a non-woven sorbent based on recycled jute fibers from the carpet industry was developed. To enhance the porosity and hydrophobicity/oleophilicity of the sorbent, carbonization in an inert atmosphere was carried out. A comparison in oil sorption performance between non-carbonized and carbonized sorbents was made by evaluating the oil capacity in a water medium, buoyancy, oil retention and reusability. Carbonization of sorbent resulted in more than doubled oil sorption capacity independent of oil viscosity. Oil viscosity did not affect the oil sorption capacity of non-carbonized sorbent. Carbonized sorbent showed superior buoyancy in water even after 24 hours, oil retention of approximately 60–80% after 3 hours and only 12–20% decline of oil sorption capacity after five repeated sorption/desorption trials. However, the ability of oiled non-carbonized sorbent to efficiently biodegrade in model compost (up to 45% weight loss after 10 weeks) makes it a sustainable candidate for oil spill clean-up.",
journal = "Environmental Technology and Innovation",
title = "Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation",
volume = "31",
pages = "103170",
doi = "10.1016/j.eti.2023.103170"
}
Kovačević, A., Radoičić, M. B., Marković, D., Ponjavić, M., Nikodinović-Runić, J.,& Radetić, M. M.. (2023). Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation. in Environmental Technology and Innovation, 31, 103170.
https://doi.org/10.1016/j.eti.2023.103170
Kovačević A, Radoičić MB, Marković D, Ponjavić M, Nikodinović-Runić J, Radetić MM. Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation. in Environmental Technology and Innovation. 2023;31:103170.
doi:10.1016/j.eti.2023.103170 .
Kovačević, Aleksandar, Radoičić, Marija B., Marković, Darka, Ponjavić, Marijana, Nikodinović-Runić, Jasmina, Radetić, Maja M., "Non-woven sorbent based on recycled jute fibers for efficient oil spill clean-up: From production to biodegradation" in Environmental Technology and Innovation, 31 (2023):103170,
https://doi.org/10.1016/j.eti.2023.103170 . .
2
2

Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric

Petkovska, Jovana; Mladenović, Nina; Marković, Darka; Radoičić, Marija B.; Chiang, Hsu-Cheng; Palen, Bethany; Mirakovski, Dejan; Dimova, Vesna; Radetić, Maja; Grunlan, Jaime C.; Jordanov, Igor

(2023)

TY  - JOUR
AU  - Petkovska, Jovana
AU  - Mladenović, Nina
AU  - Marković, Darka
AU  - Radoičić, Marija B.
AU  - Chiang, Hsu-Cheng
AU  - Palen, Bethany
AU  - Mirakovski, Dejan
AU  - Dimova, Vesna
AU  - Radetić, Maja
AU  - Grunlan, Jaime C.
AU  - Jordanov, Igor
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11020
AB  - The flammability of polyester textiles remains a significant challenge that must be overcome to allow their use in a variety of clothing and upholstery applications. In this work, water-based polyelectrolyte solutions composed of chitosan (CH) and pectin (P), as carbon-rich biomacromolecules, and mono ammonium phosphate (MAP) were deposited on enzyme/corona modified polyester via layer-by-layer (LbL) deposition. Four bilayers (BL) of 1% CH3/(1% P-30% MAP)4.2 renders the polyester fabric self-extinguishing in vertical flame testing. This recipe yields a 42.6% lower peak heat release rate and a nearly 40% reduction in the fire growth capacity, compared to uncoated polyester, as measured by micro cone calorimetry. The enzyme/corona modification, combined with the CH/(P-MAP) intumescent system, results in a very effective flame retardant treatment with few BL deposited.
T2  - Polymer Degradation and Stability
T1  - Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric
VL  - 214
SP  - 110406
DO  - 10.1016/j.polymdegradstab.2023.110406
ER  - 
@article{
author = "Petkovska, Jovana and Mladenović, Nina and Marković, Darka and Radoičić, Marija B. and Chiang, Hsu-Cheng and Palen, Bethany and Mirakovski, Dejan and Dimova, Vesna and Radetić, Maja and Grunlan, Jaime C. and Jordanov, Igor",
year = "2023",
abstract = "The flammability of polyester textiles remains a significant challenge that must be overcome to allow their use in a variety of clothing and upholstery applications. In this work, water-based polyelectrolyte solutions composed of chitosan (CH) and pectin (P), as carbon-rich biomacromolecules, and mono ammonium phosphate (MAP) were deposited on enzyme/corona modified polyester via layer-by-layer (LbL) deposition. Four bilayers (BL) of 1% CH3/(1% P-30% MAP)4.2 renders the polyester fabric self-extinguishing in vertical flame testing. This recipe yields a 42.6% lower peak heat release rate and a nearly 40% reduction in the fire growth capacity, compared to uncoated polyester, as measured by micro cone calorimetry. The enzyme/corona modification, combined with the CH/(P-MAP) intumescent system, results in a very effective flame retardant treatment with few BL deposited.",
journal = "Polymer Degradation and Stability",
title = "Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric",
volume = "214",
pages = "110406",
doi = "10.1016/j.polymdegradstab.2023.110406"
}
Petkovska, J., Mladenović, N., Marković, D., Radoičić, M. B., Chiang, H., Palen, B., Mirakovski, D., Dimova, V., Radetić, M., Grunlan, J. C.,& Jordanov, I.. (2023). Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric. in Polymer Degradation and Stability, 214, 110406.
https://doi.org/10.1016/j.polymdegradstab.2023.110406
Petkovska J, Mladenović N, Marković D, Radoičić MB, Chiang H, Palen B, Mirakovski D, Dimova V, Radetić M, Grunlan JC, Jordanov I. Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric. in Polymer Degradation and Stability. 2023;214:110406.
doi:10.1016/j.polymdegradstab.2023.110406 .
Petkovska, Jovana, Mladenović, Nina, Marković, Darka, Radoičić, Marija B., Chiang, Hsu-Cheng, Palen, Bethany, Mirakovski, Dejan, Dimova, Vesna, Radetić, Maja, Grunlan, Jaime C., Jordanov, Igor, "Environmentally benign few-bilayer intumescent nanocoating for flame retardant enzyme/plasma modified polyester fabric" in Polymer Degradation and Stability, 214 (2023):110406,
https://doi.org/10.1016/j.polymdegradstab.2023.110406 . .
5
2

Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract

Krkobabić, Ana; Marković, Darka; Kovačević, Aleksandar; Tadić, Vanja; Radoičić, Marija B.; Barudžija, Tanja; Ilić-Tomić, Tatjana; Radetić, Maja M.

(2022)

TY  - JOUR
AU  - Krkobabić, Ana
AU  - Marković, Darka
AU  - Kovačević, Aleksandar
AU  - Tadić, Vanja
AU  - Radoičić, Marija B.
AU  - Barudžija, Tanja
AU  - Ilić-Tomić, Tatjana
AU  - Radetić, Maja M.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10256
AB  - The aim of this study was to develop antimicrobial nanocomposite textile material comprising of Cu-based nanostructures synthesized on oxidized cotton fabric using Arctostaphylos uva-ursi (L.) Spreng., Ericaceae (bearberry leaves) as a green reducing agent for adsorbed Cu2+-ions. In order to provide sufficient number of carboxyl groups for complexation with Cu2+-ions a two-step oxidation process with NaIO4 and NaClO2 was carried out. The influence of NaIO4 concentration on content of carboxyl groups and Cu-based nanoparticles was studied by FTIR and AAS. HPLC analysis identified the gallic acid known as a reducing agent in bearberry leaves extract. FESEM and XRD analyses revealed that using bearberry leaves extract and gallic acid solution as reducing agents led to a formation of spherical Cu2O/CuO nanoparticles and CuO nanosheets, respectively. These nanoparticles and nanosheets provided excellent antibacterial activity against Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. Cytotoxicity on human keratinocyte cells was shown to depend on their copper content.
T2  - Fibers and Polymers
T1  - Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract
VL  - 23
IS  - 4
SP  - 954
EP  - 966
DO  - 10.1007/s12221-022-4639-5
ER  - 
@article{
author = "Krkobabić, Ana and Marković, Darka and Kovačević, Aleksandar and Tadić, Vanja and Radoičić, Marija B. and Barudžija, Tanja and Ilić-Tomić, Tatjana and Radetić, Maja M.",
year = "2022",
abstract = "The aim of this study was to develop antimicrobial nanocomposite textile material comprising of Cu-based nanostructures synthesized on oxidized cotton fabric using Arctostaphylos uva-ursi (L.) Spreng., Ericaceae (bearberry leaves) as a green reducing agent for adsorbed Cu2+-ions. In order to provide sufficient number of carboxyl groups for complexation with Cu2+-ions a two-step oxidation process with NaIO4 and NaClO2 was carried out. The influence of NaIO4 concentration on content of carboxyl groups and Cu-based nanoparticles was studied by FTIR and AAS. HPLC analysis identified the gallic acid known as a reducing agent in bearberry leaves extract. FESEM and XRD analyses revealed that using bearberry leaves extract and gallic acid solution as reducing agents led to a formation of spherical Cu2O/CuO nanoparticles and CuO nanosheets, respectively. These nanoparticles and nanosheets provided excellent antibacterial activity against Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. Cytotoxicity on human keratinocyte cells was shown to depend on their copper content.",
journal = "Fibers and Polymers",
title = "Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract",
volume = "23",
number = "4",
pages = "954-966",
doi = "10.1007/s12221-022-4639-5"
}
Krkobabić, A., Marković, D., Kovačević, A., Tadić, V., Radoičić, M. B., Barudžija, T., Ilić-Tomić, T.,& Radetić, M. M.. (2022). Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract. in Fibers and Polymers, 23(4), 954-966.
https://doi.org/10.1007/s12221-022-4639-5
Krkobabić A, Marković D, Kovačević A, Tadić V, Radoičić MB, Barudžija T, Ilić-Tomić T, Radetić MM. Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract. in Fibers and Polymers. 2022;23(4):954-966.
doi:10.1007/s12221-022-4639-5 .
Krkobabić, Ana, Marković, Darka, Kovačević, Aleksandar, Tadić, Vanja, Radoičić, Marija B., Barudžija, Tanja, Ilić-Tomić, Tatjana, Radetić, Maja M., "Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract" in Fibers and Polymers, 23, no. 4 (2022):954-966,
https://doi.org/10.1007/s12221-022-4639-5 . .
3
1
3

Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating

Petkovska, Jovana; Mladenović, Nina; Marković, Darka; Radoičić, Marija B.; Vest, Natalie A.; Palen, Bethany; Radetić, Maja M.; Grunlan, Jaime C.; Jordanov, Igor

(2022)

TY  - JOUR
AU  - Petkovska, Jovana
AU  - Mladenović, Nina
AU  - Marković, Darka
AU  - Radoičić, Marija B.
AU  - Vest, Natalie A.
AU  - Palen, Bethany
AU  - Radetić, Maja M.
AU  - Grunlan, Jaime C.
AU  - Jordanov, Igor
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10317
AB  - Creating multifunctional textiles using chemicals from renewable sources is challenging. In an effort to develop a sustainable and efficient multifunctional cotton treatment, a lignin-based multilayer nanocoating comprising magnesium lignosulfonate, chitosan, and monoammonium phosphate (MAP) was deposited using layer-by-layer assembly. A five bilayer coating adds 15.5 wt % to cotton and imparts fire extinguishing behavior and excellent UV and antimicrobial protection to the fabric. Just a two bilayer coating imparts sufficient self-extinguishing behavior to pass the standard vertical flame test. The combined influence of lignin as a char-forming and UV-protective macromolecule, chitosan as a char-forming biopolymer, and MAP acting as an antimicrobial agent (and a blowing agent and an acid source in an intumescent flame retardant system) results in a very powerful multifunctional textile treatment with very few layers of deposition.
T2  - ACS Applied Polymer Materials
T1  - Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating
VL  - 4
IS  - 6
SP  - 4528
EP  - 4537
DO  - 10.1021/acsapm.2c00520
ER  - 
@article{
author = "Petkovska, Jovana and Mladenović, Nina and Marković, Darka and Radoičić, Marija B. and Vest, Natalie A. and Palen, Bethany and Radetić, Maja M. and Grunlan, Jaime C. and Jordanov, Igor",
year = "2022",
abstract = "Creating multifunctional textiles using chemicals from renewable sources is challenging. In an effort to develop a sustainable and efficient multifunctional cotton treatment, a lignin-based multilayer nanocoating comprising magnesium lignosulfonate, chitosan, and monoammonium phosphate (MAP) was deposited using layer-by-layer assembly. A five bilayer coating adds 15.5 wt % to cotton and imparts fire extinguishing behavior and excellent UV and antimicrobial protection to the fabric. Just a two bilayer coating imparts sufficient self-extinguishing behavior to pass the standard vertical flame test. The combined influence of lignin as a char-forming and UV-protective macromolecule, chitosan as a char-forming biopolymer, and MAP acting as an antimicrobial agent (and a blowing agent and an acid source in an intumescent flame retardant system) results in a very powerful multifunctional textile treatment with very few layers of deposition.",
journal = "ACS Applied Polymer Materials",
title = "Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating",
volume = "4",
number = "6",
pages = "4528-4537",
doi = "10.1021/acsapm.2c00520"
}
Petkovska, J., Mladenović, N., Marković, D., Radoičić, M. B., Vest, N. A., Palen, B., Radetić, M. M., Grunlan, J. C.,& Jordanov, I.. (2022). Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating. in ACS Applied Polymer Materials, 4(6), 4528-4537.
https://doi.org/10.1021/acsapm.2c00520
Petkovska J, Mladenović N, Marković D, Radoičić MB, Vest NA, Palen B, Radetić MM, Grunlan JC, Jordanov I. Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating. in ACS Applied Polymer Materials. 2022;4(6):4528-4537.
doi:10.1021/acsapm.2c00520 .
Petkovska, Jovana, Mladenović, Nina, Marković, Darka, Radoičić, Marija B., Vest, Natalie A., Palen, Bethany, Radetić, Maja M., Grunlan, Jaime C., Jordanov, Igor, "Flame-Retardant, Antimicrobial, and UV-Protective Lignin-Based Multilayer Nanocoating" in ACS Applied Polymer Materials, 4, no. 6 (2022):4528-4537,
https://doi.org/10.1021/acsapm.2c00520 . .
13
9

Modification of PET and PA fabrics with alginate and copper oxides nanoparticles

Marković, Darka; Radoičić, Marija B.; Barudžija, Tanja; Radetić, Maja M.

(2021)

TY  - JOUR
AU  - Marković, Darka
AU  - Radoičić, Marija B.
AU  - Barudžija, Tanja
AU  - Radetić, Maja M.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9824
AB  - The aim of this study was to fabricate novel antimicrobial nanocomposite materials by in-situ syntheses of Cu-based nanoparticles on PET and PA fabrics. The synthesis comprised three steps: (i) modification of PET and PA fabrics with biopolymer alginate in order to improve uptake of Cu2+-ions, (ii) sorption of Cu2+-ions from the solution of precursor salt and (iii) reduction of adsorbed Cu2+-ions in an alkaline solution of sodium borohydride. The influence of concentration of alginate and copper(II) sulphate solutions on Cu2+-ions uptake and total copper content after reduction was evaluated. The presence of Cu-based nanoparticles was proved by FESEM and XRD analysis. XRD analysis revealed the presence of CuO and Cu2O on the PET and PA fibers, respectively. Larger amounts of mostly agglomerated nanoparticles were detected on PET fiber surface than on the PA fiber surface. This observation is in line with results of AAS measurements confirming that the total content of Cu on the PET fabric was nearly 30% higher compared to PA fabric. Nanocomposite containing PET fibers provided excellent antimicrobial activity against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. On the other hand, nanocomposite comprising PA fibers ensured maximum antibacterial and fungistatic activities.
T2  - Composite Interfaces
T1  - Modification of PET and PA fabrics with alginate and copper oxides nanoparticles
SP  - 1
EP  - 17
DO  - 10.1080/09276440.2020.1868267
ER  - 
@article{
author = "Marković, Darka and Radoičić, Marija B. and Barudžija, Tanja and Radetić, Maja M.",
year = "2021",
abstract = "The aim of this study was to fabricate novel antimicrobial nanocomposite materials by in-situ syntheses of Cu-based nanoparticles on PET and PA fabrics. The synthesis comprised three steps: (i) modification of PET and PA fabrics with biopolymer alginate in order to improve uptake of Cu2+-ions, (ii) sorption of Cu2+-ions from the solution of precursor salt and (iii) reduction of adsorbed Cu2+-ions in an alkaline solution of sodium borohydride. The influence of concentration of alginate and copper(II) sulphate solutions on Cu2+-ions uptake and total copper content after reduction was evaluated. The presence of Cu-based nanoparticles was proved by FESEM and XRD analysis. XRD analysis revealed the presence of CuO and Cu2O on the PET and PA fibers, respectively. Larger amounts of mostly agglomerated nanoparticles were detected on PET fiber surface than on the PA fiber surface. This observation is in line with results of AAS measurements confirming that the total content of Cu on the PET fabric was nearly 30% higher compared to PA fabric. Nanocomposite containing PET fibers provided excellent antimicrobial activity against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. On the other hand, nanocomposite comprising PA fibers ensured maximum antibacterial and fungistatic activities.",
journal = "Composite Interfaces",
title = "Modification of PET and PA fabrics with alginate and copper oxides nanoparticles",
pages = "1-17",
doi = "10.1080/09276440.2020.1868267"
}
Marković, D., Radoičić, M. B., Barudžija, T.,& Radetić, M. M.. (2021). Modification of PET and PA fabrics with alginate and copper oxides nanoparticles. in Composite Interfaces, 1-17.
https://doi.org/10.1080/09276440.2020.1868267
Marković D, Radoičić MB, Barudžija T, Radetić MM. Modification of PET and PA fabrics with alginate and copper oxides nanoparticles. in Composite Interfaces. 2021;:1-17.
doi:10.1080/09276440.2020.1868267 .
Marković, Darka, Radoičić, Marija B., Barudžija, Tanja, Radetić, Maja M., "Modification of PET and PA fabrics with alginate and copper oxides nanoparticles" in Composite Interfaces (2021):1-17,
https://doi.org/10.1080/09276440.2020.1868267 . .
8
1
8

Impedance analysis of milk quality using functionalized polyamide textile-based sensor

Stojanović, Goran M.; Sinha, Ankita; Ali, Adnan E.; Jeoti, Varun; Radoičić, Marija B.; Marković, Darka; Radetić, Maja M.

(2021)

TY  - JOUR
AU  - Stojanović, Goran M.
AU  - Sinha, Ankita
AU  - Ali, Adnan E.
AU  - Jeoti, Varun
AU  - Radoičić, Marija B.
AU  - Marković, Darka
AU  - Radetić, Maja M.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10035
AB  - Present paper demonstrates design and characterization of a textile based microfluidic chip sensor for the detection of milk adulteration through measuring the real part of the impedance and impedance phase angle. Polyamide (PA) based textile fabric was chemically functionalized with polyaniline and titanium dioxide nanoparticles (PANI/TiO2) nanocomposite and embedded in the microfluidic chip. Prototyping of microfluidic chip was performed by xurography and hot lamination using polyvinyl chloride foils. Morphological and chemical properties of fabricated textile-based PA-PANI/TiO2 chip sensor were evaluated by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). Quality of milk was accessed with fabricated textile sensor using cow and goat milk samples. The electrochemical impedance spectroscopy (EIS) was applied to detect the change in resistance and phase angle of pure and diluted milk. The developed PA-PANI/TiO2 chip sensor acted as a variable resistor that was able to identify adulterations and spoilage of the milk samples with sensitivity of 0.06 degrees of phase angle variation per % of water dilution. Our work promises that application of textile electronics could be efficiently exploited for food safety, point-of-care and environment monitoring applications.
T2  - Computers and Electronics in Agriculture
T1  - Impedance analysis of milk quality using functionalized polyamide textile-based sensor
VL  - 191
SP  - 106545
DO  - 10.1016/j.compag.2021.106545
ER  - 
@article{
author = "Stojanović, Goran M. and Sinha, Ankita and Ali, Adnan E. and Jeoti, Varun and Radoičić, Marija B. and Marković, Darka and Radetić, Maja M.",
year = "2021",
abstract = "Present paper demonstrates design and characterization of a textile based microfluidic chip sensor for the detection of milk adulteration through measuring the real part of the impedance and impedance phase angle. Polyamide (PA) based textile fabric was chemically functionalized with polyaniline and titanium dioxide nanoparticles (PANI/TiO2) nanocomposite and embedded in the microfluidic chip. Prototyping of microfluidic chip was performed by xurography and hot lamination using polyvinyl chloride foils. Morphological and chemical properties of fabricated textile-based PA-PANI/TiO2 chip sensor were evaluated by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). Quality of milk was accessed with fabricated textile sensor using cow and goat milk samples. The electrochemical impedance spectroscopy (EIS) was applied to detect the change in resistance and phase angle of pure and diluted milk. The developed PA-PANI/TiO2 chip sensor acted as a variable resistor that was able to identify adulterations and spoilage of the milk samples with sensitivity of 0.06 degrees of phase angle variation per % of water dilution. Our work promises that application of textile electronics could be efficiently exploited for food safety, point-of-care and environment monitoring applications.",
journal = "Computers and Electronics in Agriculture",
title = "Impedance analysis of milk quality using functionalized polyamide textile-based sensor",
volume = "191",
pages = "106545",
doi = "10.1016/j.compag.2021.106545"
}
Stojanović, G. M., Sinha, A., Ali, A. E., Jeoti, V., Radoičić, M. B., Marković, D.,& Radetić, M. M.. (2021). Impedance analysis of milk quality using functionalized polyamide textile-based sensor. in Computers and Electronics in Agriculture, 191, 106545.
https://doi.org/10.1016/j.compag.2021.106545
Stojanović GM, Sinha A, Ali AE, Jeoti V, Radoičić MB, Marković D, Radetić MM. Impedance analysis of milk quality using functionalized polyamide textile-based sensor. in Computers and Electronics in Agriculture. 2021;191:106545.
doi:10.1016/j.compag.2021.106545 .
Stojanović, Goran M., Sinha, Ankita, Ali, Adnan E., Jeoti, Varun, Radoičić, Marija B., Marković, Darka, Radetić, Maja M., "Impedance analysis of milk quality using functionalized polyamide textile-based sensor" in Computers and Electronics in Agriculture, 191 (2021):106545,
https://doi.org/10.1016/j.compag.2021.106545 . .
1
5
3

Tehnološki postupak za dobijanje antimikrobnog nanokompozitnog tekstilnog materijala od PET vlakana, alginata i nanočestica CuO

Marković, Darka; Radetić, Maja; Radoičić, Marija

(2021)


                                            

                                            
Marković, D., Radetić, M.,& Radoičić, M.. (2021). Tehnološki postupak za dobijanje antimikrobnog nanokompozitnog tekstilnog materijala od PET vlakana, alginata i nanočestica CuO. in Matični naučni odbor za materijale i hemijske tehnologije.
https://hdl.handle.net/21.15107/rcub_vinar_12274
Marković D, Radetić M, Radoičić M. Tehnološki postupak za dobijanje antimikrobnog nanokompozitnog tekstilnog materijala od PET vlakana, alginata i nanočestica CuO. in Matični naučni odbor za materijale i hemijske tehnologije. 2021;.
https://hdl.handle.net/21.15107/rcub_vinar_12274 .
Marković, Darka, Radetić, Maja, Radoičić, Marija, "Tehnološki postupak za dobijanje antimikrobnog nanokompozitnog tekstilnog materijala od PET vlakana, alginata i nanočestica CuO" in Matični naučni odbor za materijale i hemijske tehnologije (2021),
https://hdl.handle.net/21.15107/rcub_vinar_12274 .

The influence of coating with aminopropyl triethoxysilane and CuO/Cu2O nanoparticles on antimicrobial activity of cotton fabrics under dark conditions

Marković, Darka; Vasiljević, Jelena; Ašanin, Jelena; Ilić‐Tomić, Tatjana; Tomšič, Brigita; Jokić, Bojan M.; Mitrić, Miodrag; Simončič, Barbara; Mišić, Dušan; Radetić, Maja M.

(2020)

TY  - JOUR
AU  - Marković, Darka
AU  - Vasiljević, Jelena
AU  - Ašanin, Jelena
AU  - Ilić‐Tomić, Tatjana
AU  - Tomšič, Brigita
AU  - Jokić, Bojan M.
AU  - Mitrić, Miodrag
AU  - Simončič, Barbara
AU  - Mišić, Dušan
AU  - Radetić, Maja M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8844
AB  - A novel impregnation process for the fabrication of cotton nanocomposite with strong antimicrobial activity against antibiotics-resistant bacteria and yeast was developed. The impregnation process includes the sol–gel treatment of fabric with (3-aminopropyl)triethoxysilane in the first step, and synthesis of the CuO/Cu2O nanoparticles (NPs) on the fabric surface in the second step. The in situ synthesis of the CuO/Cu2O NPs was based on the adsorption of Cu2+-ions by the introduced amino groups of the sol–gel coating. The adsorbed Cu2+-ions are subsequently reduced in the alkaline solution of NaBH4. X-ray diffraction measurements confirmed the formation of CuO/Cu2O NPs. Scanning electron microscopy and atomic absorption spectrometry analyses indicate that the particle size, agglomeration, and amounts of synthesized NPs were highly affected by the initial concentration of CuSO4 solution. The toxicity of nanocomposites to human keratinocytes (HaCaT) and antimicrobial activity against Gram-negative Escherichia coli ATCC 25922, E. coli ATCC BAA 2469, and Klebsiella pneumoniae ATCC BAA 2146, and Gram-positive bacteria Staphylococcus aureus ATCC 25923, S. aureus ATCC 43300 and yeast Candida albicans ATCC 24433 strongly depended on the copper content. In addition to excellent antimicrobial activity, controlled release of Cu2+-ions from the fabrics into physiological saline solution was obtained. © 2020 Wiley Periodicals, Inc.
T2  - Journal of Applied Polymer Science
T1  - The influence of coating with aminopropyl triethoxysilane and CuO/Cu2O nanoparticles on antimicrobial activity of cotton fabrics under dark conditions
VL  - 137
IS  - 40
SP  - 49194
DO  - 10.1002/app.49194
ER  - 
@article{
author = "Marković, Darka and Vasiljević, Jelena and Ašanin, Jelena and Ilić‐Tomić, Tatjana and Tomšič, Brigita and Jokić, Bojan M. and Mitrić, Miodrag and Simončič, Barbara and Mišić, Dušan and Radetić, Maja M.",
year = "2020",
abstract = "A novel impregnation process for the fabrication of cotton nanocomposite with strong antimicrobial activity against antibiotics-resistant bacteria and yeast was developed. The impregnation process includes the sol–gel treatment of fabric with (3-aminopropyl)triethoxysilane in the first step, and synthesis of the CuO/Cu2O nanoparticles (NPs) on the fabric surface in the second step. The in situ synthesis of the CuO/Cu2O NPs was based on the adsorption of Cu2+-ions by the introduced amino groups of the sol–gel coating. The adsorbed Cu2+-ions are subsequently reduced in the alkaline solution of NaBH4. X-ray diffraction measurements confirmed the formation of CuO/Cu2O NPs. Scanning electron microscopy and atomic absorption spectrometry analyses indicate that the particle size, agglomeration, and amounts of synthesized NPs were highly affected by the initial concentration of CuSO4 solution. The toxicity of nanocomposites to human keratinocytes (HaCaT) and antimicrobial activity against Gram-negative Escherichia coli ATCC 25922, E. coli ATCC BAA 2469, and Klebsiella pneumoniae ATCC BAA 2146, and Gram-positive bacteria Staphylococcus aureus ATCC 25923, S. aureus ATCC 43300 and yeast Candida albicans ATCC 24433 strongly depended on the copper content. In addition to excellent antimicrobial activity, controlled release of Cu2+-ions from the fabrics into physiological saline solution was obtained. © 2020 Wiley Periodicals, Inc.",
journal = "Journal of Applied Polymer Science",
title = "The influence of coating with aminopropyl triethoxysilane and CuO/Cu2O nanoparticles on antimicrobial activity of cotton fabrics under dark conditions",
volume = "137",
number = "40",
pages = "49194",
doi = "10.1002/app.49194"
}
Marković, D., Vasiljević, J., Ašanin, J., Ilić‐Tomić, T., Tomšič, B., Jokić, B. M., Mitrić, M., Simončič, B., Mišić, D.,& Radetić, M. M.. (2020). The influence of coating with aminopropyl triethoxysilane and CuO/Cu2O nanoparticles on antimicrobial activity of cotton fabrics under dark conditions. in Journal of Applied Polymer Science, 137(40), 49194.
https://doi.org/10.1002/app.49194
Marković D, Vasiljević J, Ašanin J, Ilić‐Tomić T, Tomšič B, Jokić BM, Mitrić M, Simončič B, Mišić D, Radetić MM. The influence of coating with aminopropyl triethoxysilane and CuO/Cu2O nanoparticles on antimicrobial activity of cotton fabrics under dark conditions. in Journal of Applied Polymer Science. 2020;137(40):49194.
doi:10.1002/app.49194 .
Marković, Darka, Vasiljević, Jelena, Ašanin, Jelena, Ilić‐Tomić, Tatjana, Tomšič, Brigita, Jokić, Bojan M., Mitrić, Miodrag, Simončič, Barbara, Mišić, Dušan, Radetić, Maja M., "The influence of coating with aminopropyl triethoxysilane and CuO/Cu2O nanoparticles on antimicrobial activity of cotton fabrics under dark conditions" in Journal of Applied Polymer Science, 137, no. 40 (2020):49194,
https://doi.org/10.1002/app.49194 . .
3
19
4
18

Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles

Marković, Darka; Tseng, Hsiang-Han; Nunney, Tim; Radoičić, Marija B.; Ilić-Tomić, Tatjana; Radetić, Maja M.

(2020)

TY  - JOUR
AU  - Marković, Darka
AU  - Tseng, Hsiang-Han
AU  - Nunney, Tim
AU  - Radoičić, Marija B.
AU  - Ilić-Tomić, Tatjana
AU  - Radetić, Maja M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9029
AB  - The objective of this study was to develop novel antimicrobial nanocomposite material based on polypropylene (PP) non-woven fabric, biopolymer alginate and copper oxides nanoparticles. In order to introduce polar groups onto the surface of PP fibers necessary for binding of alginate, non-woven fabric was activated by corona discharge. Carboxylate groups of alginate were further utilized for binding of Cu2+-ions which were reduced with sodium borohydride as a conventional and ascorbic acid as a green reducing agent. Characteristic morphological and chemical changes induced by corona activation and alginate impregnation were confirmed by FTIR, XPS and FESEM analyses. AAS measurements showed that the amounts of generated nanoparticles depend on applied reducing agent and the concentration of precursor salt. XPS analysis suggested that nanoparticles were mixture of copper (I) and (II) oxides. XPS depth profiling gave an exceptional insight into chemical changes within the thin layer on the fiber surface and formation of certain interfaces induced by each treatment. All fabricated nanocomposites provided excellent antimicrobial activity against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. The cytotoxicity assay indicated that maximum amount of Cu2+-ions released from synthetized nanocomposite within 24 h was not cytotoxic to human keratinocyte (HaCaT) cells.
T2  - Applied Surface Science
T1  - Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles
VL  - 527
SP  - 146829
DO  - 10.1016/j.apsusc.2020.146829
ER  - 
@article{
author = "Marković, Darka and Tseng, Hsiang-Han and Nunney, Tim and Radoičić, Marija B. and Ilić-Tomić, Tatjana and Radetić, Maja M.",
year = "2020",
abstract = "The objective of this study was to develop novel antimicrobial nanocomposite material based on polypropylene (PP) non-woven fabric, biopolymer alginate and copper oxides nanoparticles. In order to introduce polar groups onto the surface of PP fibers necessary for binding of alginate, non-woven fabric was activated by corona discharge. Carboxylate groups of alginate were further utilized for binding of Cu2+-ions which were reduced with sodium borohydride as a conventional and ascorbic acid as a green reducing agent. Characteristic morphological and chemical changes induced by corona activation and alginate impregnation were confirmed by FTIR, XPS and FESEM analyses. AAS measurements showed that the amounts of generated nanoparticles depend on applied reducing agent and the concentration of precursor salt. XPS analysis suggested that nanoparticles were mixture of copper (I) and (II) oxides. XPS depth profiling gave an exceptional insight into chemical changes within the thin layer on the fiber surface and formation of certain interfaces induced by each treatment. All fabricated nanocomposites provided excellent antimicrobial activity against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. The cytotoxicity assay indicated that maximum amount of Cu2+-ions released from synthetized nanocomposite within 24 h was not cytotoxic to human keratinocyte (HaCaT) cells.",
journal = "Applied Surface Science",
title = "Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles",
volume = "527",
pages = "146829",
doi = "10.1016/j.apsusc.2020.146829"
}
Marković, D., Tseng, H., Nunney, T., Radoičić, M. B., Ilić-Tomić, T.,& Radetić, M. M.. (2020). Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles. in Applied Surface Science, 527, 146829.
https://doi.org/10.1016/j.apsusc.2020.146829
Marković D, Tseng H, Nunney T, Radoičić MB, Ilić-Tomić T, Radetić MM. Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles. in Applied Surface Science. 2020;527:146829.
doi:10.1016/j.apsusc.2020.146829 .
Marković, Darka, Tseng, Hsiang-Han, Nunney, Tim, Radoičić, Marija B., Ilić-Tomić, Tatjana, Radetić, Maja M., "Novel antimicrobial nanocomposite based on polypropylene non-woven fabric, biopolymer alginate and copper oxides nanoparticles" in Applied Surface Science, 527 (2020):146829,
https://doi.org/10.1016/j.apsusc.2020.146829 . .
1
56
16
48

Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics

Marković, Darka; Jokić, Bojan M.; Radovanović, Željko; Ašanin, Jelena; Radoičić, Marija B.; Mitrić, Miodrag; Mišić, Dušan; Radetić, Maja M.

(2019)

TY  - JOUR
AU  - Marković, Darka
AU  - Jokić, Bojan M.
AU  - Radovanović, Željko
AU  - Ašanin, Jelena
AU  - Radoičić, Marija B.
AU  - Mitrić, Miodrag
AU  - Mišić, Dušan
AU  - Radetić, Maja M.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8517
AB  - The antioxidant properties of cool-climate Regent wines from Podkarpacie region, Poland were investigated. Total polyphenols, total flavonoids, total monomeric anthocyanins, trans-resveratrol concentration, radical scavenging ability using 1,1-diphenyl-2-picryl-hydrazyl (DPPH) and total antioxidant capacity with TEAC and FRAP methods were measured. The average contents of the compounds determined for Regent wines were comparable to the respective data available in literature found for warm-climate wines. Correspondence Analysis of the data revealed the relation of total polyphenols content and antioxidant capacity and radical scavenging ability of studied wines, and in lesser extent correlation with total flavonoids content. The total monomeric anthocyanins content and resveratrol concentration were poorly related to the total polyphenols content and antioxidant capacity.
T2  - Cellulose Chemistry and Technology
T1  - Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics
VL  - 53
IS  - 7-8
SP  - 805
EP  - 813
DO  - 10.35812/CelluloseChemTechnol.2019.53.79
ER  - 
@article{
author = "Marković, Darka and Jokić, Bojan M. and Radovanović, Željko and Ašanin, Jelena and Radoičić, Marija B. and Mitrić, Miodrag and Mišić, Dušan and Radetić, Maja M.",
year = "2019",
abstract = "The antioxidant properties of cool-climate Regent wines from Podkarpacie region, Poland were investigated. Total polyphenols, total flavonoids, total monomeric anthocyanins, trans-resveratrol concentration, radical scavenging ability using 1,1-diphenyl-2-picryl-hydrazyl (DPPH) and total antioxidant capacity with TEAC and FRAP methods were measured. The average contents of the compounds determined for Regent wines were comparable to the respective data available in literature found for warm-climate wines. Correspondence Analysis of the data revealed the relation of total polyphenols content and antioxidant capacity and radical scavenging ability of studied wines, and in lesser extent correlation with total flavonoids content. The total monomeric anthocyanins content and resveratrol concentration were poorly related to the total polyphenols content and antioxidant capacity.",
journal = "Cellulose Chemistry and Technology",
title = "Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics",
volume = "53",
number = "7-8",
pages = "805-813",
doi = "10.35812/CelluloseChemTechnol.2019.53.79"
}
Marković, D., Jokić, B. M., Radovanović, Ž., Ašanin, J., Radoičić, M. B., Mitrić, M., Mišić, D.,& Radetić, M. M.. (2019). Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics. in Cellulose Chemistry and Technology, 53(7-8), 805-813.
https://doi.org/10.35812/CelluloseChemTechnol.2019.53.79
Marković D, Jokić BM, Radovanović Ž, Ašanin J, Radoičić MB, Mitrić M, Mišić D, Radetić MM. Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics. in Cellulose Chemistry and Technology. 2019;53(7-8):805-813.
doi:10.35812/CelluloseChemTechnol.2019.53.79 .
Marković, Darka, Jokić, Bojan M., Radovanović, Željko, Ašanin, Jelena, Radoičić, Marija B., Mitrić, Miodrag, Mišić, Dušan, Radetić, Maja M., "Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of CuO/Cu2O nanoparticles on cotton and viscose rayon fabrics" in Cellulose Chemistry and Technology, 53, no. 7-8 (2019):805-813,
https://doi.org/10.35812/CelluloseChemTechnol.2019.53.79 . .
1
1
1

Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles

Marković, Darka; Ašanin, Jelena; Nunney, Tim; Radovanović, Željko; Radoičić, Marija B.; Mitrić, Miodrag; Mišić, Dušan; Radetić, Maja M.

(2019)

TY  - JOUR
AU  - Marković, Darka
AU  - Ašanin, Jelena
AU  - Nunney, Tim
AU  - Radovanović, Željko
AU  - Radoičić, Marija B.
AU  - Mitrić, Miodrag
AU  - Mišić, Dušan
AU  - Radetić, Maja M.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8669
AB  - This study discusses the possibility of fabrication of textile nanocomposites with antimicrobial activity against antibiotics-resistant bacterial strains and yeast. Modification of cotton fabric with oxalic acid solutions of different concentrations provided free carboxyl groups for binding of Cu2+ -ions from copper (II) sulfate solution which were further reduced with sodium borohydride in alkaline solution. An increase in the concentration of applied oxalic acid resulted in larger amounts of free carboxyl groups on the cotton fibers, Cu2+ -ions uptake and total amounts of Cu-based nanoparticles after reduction. XPS and XRD analyses suggested that nanoparticles mainly consisted of CuO with fractions of Cu2O. Fabricated textile nanocomposites ensured maximum reduction of Gram-negative E. coli ATCC 25922, E. coli NCTC 13846, E. coli ATCC BAA-2469, K. pneumoniae ATCC-BAA 2146 and P. aeruginosa ATCC 27853, Gram-positive bacteria S. aureus ATCC 25923 and S. aureus ATCC 43300 and yeast C. albicans ATCC 24433. Additionally, controlled release of Cu2+ -ions from fabrics into the physiological saline solution was obtained within 24 hours. © 2019, The Korean Fiber Society.
T2  - Fibers and Polymers
T1  - Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles
VL  - 20
IS  - 11
SP  - 2317
EP  - 2325
DO  - 10.1007/s12221-019-9131-5
ER  - 
@article{
author = "Marković, Darka and Ašanin, Jelena and Nunney, Tim and Radovanović, Željko and Radoičić, Marija B. and Mitrić, Miodrag and Mišić, Dušan and Radetić, Maja M.",
year = "2019",
abstract = "This study discusses the possibility of fabrication of textile nanocomposites with antimicrobial activity against antibiotics-resistant bacterial strains and yeast. Modification of cotton fabric with oxalic acid solutions of different concentrations provided free carboxyl groups for binding of Cu2+ -ions from copper (II) sulfate solution which were further reduced with sodium borohydride in alkaline solution. An increase in the concentration of applied oxalic acid resulted in larger amounts of free carboxyl groups on the cotton fibers, Cu2+ -ions uptake and total amounts of Cu-based nanoparticles after reduction. XPS and XRD analyses suggested that nanoparticles mainly consisted of CuO with fractions of Cu2O. Fabricated textile nanocomposites ensured maximum reduction of Gram-negative E. coli ATCC 25922, E. coli NCTC 13846, E. coli ATCC BAA-2469, K. pneumoniae ATCC-BAA 2146 and P. aeruginosa ATCC 27853, Gram-positive bacteria S. aureus ATCC 25923 and S. aureus ATCC 43300 and yeast C. albicans ATCC 24433. Additionally, controlled release of Cu2+ -ions from fabrics into the physiological saline solution was obtained within 24 hours. © 2019, The Korean Fiber Society.",
journal = "Fibers and Polymers",
title = "Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles",
volume = "20",
number = "11",
pages = "2317-2325",
doi = "10.1007/s12221-019-9131-5"
}
Marković, D., Ašanin, J., Nunney, T., Radovanović, Ž., Radoičić, M. B., Mitrić, M., Mišić, D.,& Radetić, M. M.. (2019). Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles. in Fibers and Polymers, 20(11), 2317-2325.
https://doi.org/10.1007/s12221-019-9131-5
Marković D, Ašanin J, Nunney T, Radovanović Ž, Radoičić MB, Mitrić M, Mišić D, Radetić MM. Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles. in Fibers and Polymers. 2019;20(11):2317-2325.
doi:10.1007/s12221-019-9131-5 .
Marković, Darka, Ašanin, Jelena, Nunney, Tim, Radovanović, Željko, Radoičić, Marija B., Mitrić, Miodrag, Mišić, Dušan, Radetić, Maja M., "Broad Spectrum of Antimicrobial Activity of Cotton Fabric Modified with Oxalic Acid and CuO/Cu2O Nanoparticles" in Fibers and Polymers, 20, no. 11 (2019):2317-2325,
https://doi.org/10.1007/s12221-019-9131-5 . .
3
13
5
14

Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida

Radetić, Maja; Marković, Darka; Milovanović, Stoja; Žižović, Irena; Šaponjić, Zoran; Radoičić, Marija

(2019)

TY  - PAT
AU  - Radetić, Maja
AU  - Marković, Darka
AU  - Milovanović, Stoja
AU  - Žižović, Irena
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12273
T2  - Zavod za intelektualnu svojinu Republike Srbije
T1  - Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida
T1  - Floating photocatalyst based on polycaprolactone foam and titanium dioxide nanoparticles
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12273
ER  - 
@misc{
author = "Radetić, Maja and Marković, Darka and Milovanović, Stoja and Žižović, Irena and Šaponjić, Zoran and Radoičić, Marija",
year = "2019",
journal = "Zavod za intelektualnu svojinu Republike Srbije",
title = "Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida, Floating photocatalyst based on polycaprolactone foam and titanium dioxide nanoparticles",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12273"
}
Radetić, M., Marković, D., Milovanović, S., Žižović, I., Šaponjić, Z.,& Radoičić, M.. (2019). Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida. in Zavod za intelektualnu svojinu Republike Srbije.
https://hdl.handle.net/21.15107/rcub_vinar_12273
Radetić M, Marković D, Milovanović S, Žižović I, Šaponjić Z, Radoičić M. Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida. in Zavod za intelektualnu svojinu Republike Srbije. 2019;.
https://hdl.handle.net/21.15107/rcub_vinar_12273 .
Radetić, Maja, Marković, Darka, Milovanović, Stoja, Žižović, Irena, Šaponjić, Zoran, Radoičić, Marija, "Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida" in Zavod za intelektualnu svojinu Republike Srbije (2019),
https://hdl.handle.net/21.15107/rcub_vinar_12273 .

Supercritical CO2 - assisted production of PLA and PLGA foams for controlled thymol release

Milovanović, Stoja; Marković, Darka; Mraković, Ana Đ.; Kuska, Robert; Žižović, Irena T.; Frerich, Sulamith; Ivanović, Jasna

(2019)

TY  - JOUR
AU  - Milovanović, Stoja
AU  - Marković, Darka
AU  - Mraković, Ana Đ.
AU  - Kuska, Robert
AU  - Žižović, Irena T.
AU  - Frerich, Sulamith
AU  - Ivanović, Jasna
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0928493117342169
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8041
AB  - Amorphous, medical grade poly(D,L-lactic acid) (PLA) and poly(D,L-lactic-co-glycolic acid) (PLGA) were used to develop systems for controlled release of a natural bioactive substance - thymol. Supercritical carbon dioxide (scCO2) was successfully used both as an impregnation medium for thymol incorporation into the polymer matrix and a foaming agent in a single-step batch process. Impregnation of samples using low to moderate scCO2 densities (273 kg/m3 and 630 kg/m3) and short processing times (2 h and 4 h) enabled thymol loading of 0.92%–6.62% and formation of microcellular foams upon system depressurization. Thymol effect on structural and thermal properties on foamed samples was proven by FTIR and DSC. The effect of CO2 under elevated pressure on the neat polymers was analysed by high pressure DSC. Foaming of polymers with lower molecular weight by CO2 of higher density yielded foams with smaller pores. All tested foams released thymol in a controlled manner in phosphate buffered saline (PBS) at 37 °C within 3 to 6 weeks. Higher loading and lower cell density favoured thymol release rate, while its concentration in PBS for the tested period depended on foam interaction with the medium. Representative PLGA foam sample with the highest thymol loading (6.62%) showed controlled thymol release within 72 h in mediums having pH values from 1.1 to 7.4. © 2019 Elsevier B.V.
T2  - Materials Science and Engineering: C
T1  - Supercritical CO2 - assisted production of PLA and PLGA foams for controlled thymol release
VL  - 99
SP  - 394
EP  - 404
DO  - 10.1016/j.msec.2019.01.106
ER  - 
@article{
author = "Milovanović, Stoja and Marković, Darka and Mraković, Ana Đ. and Kuska, Robert and Žižović, Irena T. and Frerich, Sulamith and Ivanović, Jasna",
year = "2019",
abstract = "Amorphous, medical grade poly(D,L-lactic acid) (PLA) and poly(D,L-lactic-co-glycolic acid) (PLGA) were used to develop systems for controlled release of a natural bioactive substance - thymol. Supercritical carbon dioxide (scCO2) was successfully used both as an impregnation medium for thymol incorporation into the polymer matrix and a foaming agent in a single-step batch process. Impregnation of samples using low to moderate scCO2 densities (273 kg/m3 and 630 kg/m3) and short processing times (2 h and 4 h) enabled thymol loading of 0.92%–6.62% and formation of microcellular foams upon system depressurization. Thymol effect on structural and thermal properties on foamed samples was proven by FTIR and DSC. The effect of CO2 under elevated pressure on the neat polymers was analysed by high pressure DSC. Foaming of polymers with lower molecular weight by CO2 of higher density yielded foams with smaller pores. All tested foams released thymol in a controlled manner in phosphate buffered saline (PBS) at 37 °C within 3 to 6 weeks. Higher loading and lower cell density favoured thymol release rate, while its concentration in PBS for the tested period depended on foam interaction with the medium. Representative PLGA foam sample with the highest thymol loading (6.62%) showed controlled thymol release within 72 h in mediums having pH values from 1.1 to 7.4. © 2019 Elsevier B.V.",
journal = "Materials Science and Engineering: C",
title = "Supercritical CO2 - assisted production of PLA and PLGA foams for controlled thymol release",
volume = "99",
pages = "394-404",
doi = "10.1016/j.msec.2019.01.106"
}
Milovanović, S., Marković, D., Mraković, A. Đ., Kuska, R., Žižović, I. T., Frerich, S.,& Ivanović, J.. (2019). Supercritical CO2 - assisted production of PLA and PLGA foams for controlled thymol release. in Materials Science and Engineering: C, 99, 394-404.
https://doi.org/10.1016/j.msec.2019.01.106
Milovanović S, Marković D, Mraković AĐ, Kuska R, Žižović IT, Frerich S, Ivanović J. Supercritical CO2 - assisted production of PLA and PLGA foams for controlled thymol release. in Materials Science and Engineering: C. 2019;99:394-404.
doi:10.1016/j.msec.2019.01.106 .
Milovanović, Stoja, Marković, Darka, Mraković, Ana Đ., Kuska, Robert, Žižović, Irena T., Frerich, Sulamith, Ivanović, Jasna, "Supercritical CO2 - assisted production of PLA and PLGA foams for controlled thymol release" in Materials Science and Engineering: C, 99 (2019):394-404,
https://doi.org/10.1016/j.msec.2019.01.106 . .
74
37
73

Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes

Marković, Darka; Milovanović, Stoja; Radovanović, Željko; Žižović, Irena T.; Šaponjić, Zoran; Radetić, Maja M.

(2018)

TY  - JOUR
AU  - Marković, Darka
AU  - Milovanović, Stoja
AU  - Radovanović, Željko
AU  - Žižović, Irena T.
AU  - Šaponjić, Zoran
AU  - Radetić, Maja M.
PY  - 2018
UR  - http://link.springer.com/10.1007/s12221-018-8148-5
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7782
AB  - This study discusses a novel approach for fabrication of floating photocatalyst which can be efficiently exploited for photodegradation of dyes in aqueous solutions. A fabrication of the floating photocatalyst consisted of two steps: transformation of the poly(ε-caprolactone) beads (PCLb) into poly(ε-caprolactone) foam (PCLf) with porous structure in supercritical carbon-dioxide and subsequent loading of PCLf with TiO2 nanoparticles (NPs). Morphological characterization of the PCLf before and after TiO2 NPs loading was carried out by FESEM. The presence of titanium on the surface and inside the PCLf was detected by EDX. Photocatalytical activity of the floating photocatalyst was investigated in aqueous solution of textile dyes C.I. Acid Orange 7 (AO7) and C.I. Basic Yellow 28 (BY28) which were exposed to lamp that simulates the sun light. In addition to sustainable floatability for a long period of time, developed floating photocatalyst exhibited high rate of photodegradation since the complete discoloration of AO7 and BY28 solutions and photocatalysts alone occurred after 300 and 180 min of illumination, respectively. Its photocatalytic activity was preserved after three repeated photodegradation cycles with unchanged chemical structure that was confirmed by FTIR analysis.
T2  - Fibers and Polymers
T1  - Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes
VL  - 19
IS  - 6
SP  - 1219
EP  - 1227
DO  - 10.1007/s12221-018-8148-5
ER  - 
@article{
author = "Marković, Darka and Milovanović, Stoja and Radovanović, Željko and Žižović, Irena T. and Šaponjić, Zoran and Radetić, Maja M.",
year = "2018",
abstract = "This study discusses a novel approach for fabrication of floating photocatalyst which can be efficiently exploited for photodegradation of dyes in aqueous solutions. A fabrication of the floating photocatalyst consisted of two steps: transformation of the poly(ε-caprolactone) beads (PCLb) into poly(ε-caprolactone) foam (PCLf) with porous structure in supercritical carbon-dioxide and subsequent loading of PCLf with TiO2 nanoparticles (NPs). Morphological characterization of the PCLf before and after TiO2 NPs loading was carried out by FESEM. The presence of titanium on the surface and inside the PCLf was detected by EDX. Photocatalytical activity of the floating photocatalyst was investigated in aqueous solution of textile dyes C.I. Acid Orange 7 (AO7) and C.I. Basic Yellow 28 (BY28) which were exposed to lamp that simulates the sun light. In addition to sustainable floatability for a long period of time, developed floating photocatalyst exhibited high rate of photodegradation since the complete discoloration of AO7 and BY28 solutions and photocatalysts alone occurred after 300 and 180 min of illumination, respectively. Its photocatalytic activity was preserved after three repeated photodegradation cycles with unchanged chemical structure that was confirmed by FTIR analysis.",
journal = "Fibers and Polymers",
title = "Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes",
volume = "19",
number = "6",
pages = "1219-1227",
doi = "10.1007/s12221-018-8148-5"
}
Marković, D., Milovanović, S., Radovanović, Ž., Žižović, I. T., Šaponjić, Z.,& Radetić, M. M.. (2018). Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes. in Fibers and Polymers, 19(6), 1219-1227.
https://doi.org/10.1007/s12221-018-8148-5
Marković D, Milovanović S, Radovanović Ž, Žižović IT, Šaponjić Z, Radetić MM. Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes. in Fibers and Polymers. 2018;19(6):1219-1227.
doi:10.1007/s12221-018-8148-5 .
Marković, Darka, Milovanović, Stoja, Radovanović, Željko, Žižović, Irena T., Šaponjić, Zoran, Radetić, Maja M., "Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes" in Fibers and Polymers, 19, no. 6 (2018):1219-1227,
https://doi.org/10.1007/s12221-018-8148-5 . .
11
5
10

Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids

Marković, Darka; Deeks, Christopher; Nunney, Tim; Radovanović, Željko; Radoičić, Marija B.; Šaponjić, Zoran; Radetić, Maja M.

(2018)

TY  - JOUR
AU  - Marković, Darka
AU  - Deeks, Christopher
AU  - Nunney, Tim
AU  - Radovanović, Željko
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Radetić, Maja M.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0144861718308890
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7826
AB  - The fabrication of antimicrobial textile nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabrics modified with different polycarboxylic acids was discussed in this study. In order to evaluate the influence of carboxyl group content on Cu2+-ions adsorption, their subsequent reduction with sodium borohydride and formation of Cu-based nanoparticles, cotton fabrics were modified with succinic, citric and 1,2,3,4-butanetetracarboxylic acids. It was shown that the larger the number of carboxyl groups in applied acid, the larger the content of free carboxyl groups on the fibers and consequently, the larger the Cu2+-ions uptake and total amounts of Cu-based nanoparticles. On the basis of the XPS and XRD measurements, it was suggested that synthesized nanoparticles were mixture of Cu2O and CuO. Fabricated nanocomposites provided maximum reduction of Gram-negative bacterium E. coli and Gram-positive bacterium S. aureus and controlled release of Cu2+-ions in physiological saline solution which are necessary prerequisites for infection prevention.
T2  - Carbohydrate Polymers
T1  - Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids
VL  - 200
SP  - 173
EP  - 182
DO  - 10.1016/j.carbpol.2018.08.001
ER  - 
@article{
author = "Marković, Darka and Deeks, Christopher and Nunney, Tim and Radovanović, Željko and Radoičić, Marija B. and Šaponjić, Zoran and Radetić, Maja M.",
year = "2018",
abstract = "The fabrication of antimicrobial textile nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabrics modified with different polycarboxylic acids was discussed in this study. In order to evaluate the influence of carboxyl group content on Cu2+-ions adsorption, their subsequent reduction with sodium borohydride and formation of Cu-based nanoparticles, cotton fabrics were modified with succinic, citric and 1,2,3,4-butanetetracarboxylic acids. It was shown that the larger the number of carboxyl groups in applied acid, the larger the content of free carboxyl groups on the fibers and consequently, the larger the Cu2+-ions uptake and total amounts of Cu-based nanoparticles. On the basis of the XPS and XRD measurements, it was suggested that synthesized nanoparticles were mixture of Cu2O and CuO. Fabricated nanocomposites provided maximum reduction of Gram-negative bacterium E. coli and Gram-positive bacterium S. aureus and controlled release of Cu2+-ions in physiological saline solution which are necessary prerequisites for infection prevention.",
journal = "Carbohydrate Polymers",
title = "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids",
volume = "200",
pages = "173-182",
doi = "10.1016/j.carbpol.2018.08.001"
}
Marković, D., Deeks, C., Nunney, T., Radovanović, Ž., Radoičić, M. B., Šaponjić, Z.,& Radetić, M. M.. (2018). Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids. in Carbohydrate Polymers, 200, 173-182.
https://doi.org/10.1016/j.carbpol.2018.08.001
Marković D, Deeks C, Nunney T, Radovanović Ž, Radoičić MB, Šaponjić Z, Radetić MM. Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids. in Carbohydrate Polymers. 2018;200:173-182.
doi:10.1016/j.carbpol.2018.08.001 .
Marković, Darka, Deeks, Christopher, Nunney, Tim, Radovanović, Željko, Radoičić, Marija B., Šaponjić, Zoran, Radetić, Maja M., "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids" in Carbohydrate Polymers, 200 (2018):173-182,
https://doi.org/10.1016/j.carbpol.2018.08.001 . .
83
44
82

Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams

Marković, Darka; Milovanović, Stoja; Radoičić, Marija B.; Radovanović, Željko; Žižović, Irena T.; Šaponjić, Zoran; Radetić, Maja M.

(2018)

TY  - JOUR
AU  - Marković, Darka
AU  - Milovanović, Stoja
AU  - Radoičić, Marija B.
AU  - Radovanović, Željko
AU  - Žižović, Irena T.
AU  - Šaponjić, Zoran
AU  - Radetić, Maja M.
PY  - 2018
UR  - http://www.doiserbia.nb.rs/Article.aspx?ID=0352-51391800089M
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8018
AB  - This study discusses the possibility of immobilization of colloidal TiO2 nanoparticles (NPs) onto poly(ε-caprolactone) (PCL) beads and foams that could be utilized for the removal of textile dyes from water by photodegradation. PCL foams were fabricated by environmentally friendly treatment of PCL beads in supercritical carbon dioxide. PCL beads and foams loaded with colloidal TiO2 NPs were used as photocatalysts for the removal of the textile dyes C.I. Acid Orange 7 and C.I. Basic Yellow 28 from aqueous solutions (10 mg L-1) under illumination that simulated sunlight. Unlike the PCL beads, the PCL foams provided complete discoloration of the dye solution within 24 h of illumination. The PCL foams also exhibited excellent floatability that was maintained for more than four weeks. Additionally, their photocatalytic activity was preserved within three repeated photodegradation cycles, indicating that the floating photocatalyst provided superior photocatalytic activity compared to the non-floating PCL beads.
AB  - У овом раду је дискутована могућност имобилизације колоидних наночестица TiO2 на
перлама или пени од поли(ε-капролактона) (PCL) које би се искористиле за уклањање боја
за текстил из воде процесом фотодеградације. PCL пена је добијена еколошки прихватљивим третманом PCL перли у наткритичном CO2. PCL перле и пене су накнадно импрегниране колоидним наночестицама TiO2 и употребљене су као фотокатализатори за
уклањање боја за текстил C.I. Acid Orange 7 и C.I. Basic Yellow 28 из воденог раствора (10
mg L-1) при осветљењу које симулира сунчеву светлост. За разлику од PCL перли, PCL пене
су обезбедиле потпуно обезбојавање раствора боје током 24 h осветљавања. PCL пена је
такође показала одличну способност плутања која је очувана дуже од четири недеље.
Фотокаталитичка активност пена је задржана таком три поновљена циклуса испитивања
фотодеградације што указује да овај плутајући фотокатализатор показује супериорну
фотокаталитичку активност у поређењу са неплутајућим PCL перлама.
T2  - Journal of the Serbian Chemical Society
T1  - Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams
VL  - 83
IS  - 12
SP  - 1379
EP  - 1389
DO  - 10.2298/JSC180913089M
ER  - 
@article{
author = "Marković, Darka and Milovanović, Stoja and Radoičić, Marija B. and Radovanović, Željko and Žižović, Irena T. and Šaponjić, Zoran and Radetić, Maja M.",
year = "2018",
abstract = "This study discusses the possibility of immobilization of colloidal TiO2 nanoparticles (NPs) onto poly(ε-caprolactone) (PCL) beads and foams that could be utilized for the removal of textile dyes from water by photodegradation. PCL foams were fabricated by environmentally friendly treatment of PCL beads in supercritical carbon dioxide. PCL beads and foams loaded with colloidal TiO2 NPs were used as photocatalysts for the removal of the textile dyes C.I. Acid Orange 7 and C.I. Basic Yellow 28 from aqueous solutions (10 mg L-1) under illumination that simulated sunlight. Unlike the PCL beads, the PCL foams provided complete discoloration of the dye solution within 24 h of illumination. The PCL foams also exhibited excellent floatability that was maintained for more than four weeks. Additionally, their photocatalytic activity was preserved within three repeated photodegradation cycles, indicating that the floating photocatalyst provided superior photocatalytic activity compared to the non-floating PCL beads., У овом раду је дискутована могућност имобилизације колоидних наночестица TiO2 на
перлама или пени од поли(ε-капролактона) (PCL) које би се искористиле за уклањање боја
за текстил из воде процесом фотодеградације. PCL пена је добијена еколошки прихватљивим третманом PCL перли у наткритичном CO2. PCL перле и пене су накнадно импрегниране колоидним наночестицама TiO2 и употребљене су као фотокатализатори за
уклањање боја за текстил C.I. Acid Orange 7 и C.I. Basic Yellow 28 из воденог раствора (10
mg L-1) при осветљењу које симулира сунчеву светлост. За разлику од PCL перли, PCL пене
су обезбедиле потпуно обезбојавање раствора боје током 24 h осветљавања. PCL пена је
такође показала одличну способност плутања која је очувана дуже од четири недеље.
Фотокаталитичка активност пена је задржана таком три поновљена циклуса испитивања
фотодеградације што указује да овај плутајући фотокатализатор показује супериорну
фотокаталитичку активност у поређењу са неплутајућим PCL перлама.",
journal = "Journal of the Serbian Chemical Society",
title = "Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams",
volume = "83",
number = "12",
pages = "1379-1389",
doi = "10.2298/JSC180913089M"
}
Marković, D., Milovanović, S., Radoičić, M. B., Radovanović, Ž., Žižović, I. T., Šaponjić, Z.,& Radetić, M. M.. (2018). Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams. in Journal of the Serbian Chemical Society, 83(12), 1379-1389.
https://doi.org/10.2298/JSC180913089M
Marković D, Milovanović S, Radoičić MB, Radovanović Ž, Žižović IT, Šaponjić Z, Radetić MM. Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams. in Journal of the Serbian Chemical Society. 2018;83(12):1379-1389.
doi:10.2298/JSC180913089M .
Marković, Darka, Milovanović, Stoja, Radoičić, Marija B., Radovanović, Željko, Žižović, Irena T., Šaponjić, Zoran, Radetić, Maja M., "Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams" in Journal of the Serbian Chemical Society, 83, no. 12 (2018):1379-1389,
https://doi.org/10.2298/JSC180913089M . .
3
4

In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics

Marković, Darka; Korica, Matea; Kostić, Mirjana M.; Radovanović, Željko; Šaponjić, Zoran; Mitrić, Miodrag; Radetić, Maja M.

(2018)

TY  - JOUR
AU  - Marković, Darka
AU  - Korica, Matea
AU  - Kostić, Mirjana M.
AU  - Radovanović, Željko
AU  - Šaponjić, Zoran
AU  - Mitrić, Miodrag
AU  - Radetić, Maja M.
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1911
AB  - In situ synthesis of Cu/Cu2O nanoparticles on the cotton fabric discussed in this study relies on adsorption of Cu2+-ions by carboxylate groups generated through the TEMPO-mediated oxidation of cellulose and their subsequent reduction by sodium borohydride. In order to establish the influence of aldehyde and carboxylate groups on the nanoparticles formation, the duration of TEMPO-mediated oxidation was varied. Chemical changes induced by TEMPO-mediated oxidation were evaluated by titrimetric determination of the amounts of aldehyde and carboxylic groups in cotton and FTIR spectroscopy. The presence of Cu/Cu2O nanoparticles on the cotton fabric was confirmed by FE-SEM, AAS and XRD analyses. Antimicrobial activity of synthesized nanoparticles was tested against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and fungi C. albicans. The extension of TEMPO oxidation time led to an increase of carboxylate group content and consequently, formation of larger amounts of Cu/Cu2O nanoparticles. All fabricated textile nanocomposites provided excellent antibacterial and acceptable antifungal activity. They also ensured a controlled release of Cu2+-ions in physiological solution which is an imperative for infection prevention.
T2  - Cellulose
T1  - In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics
VL  - 25
IS  - 1
SP  - 829
EP  - 841
DO  - 10.1007/s10570-017-1566-5
ER  - 
@article{
author = "Marković, Darka and Korica, Matea and Kostić, Mirjana M. and Radovanović, Željko and Šaponjić, Zoran and Mitrić, Miodrag and Radetić, Maja M.",
year = "2018",
abstract = "In situ synthesis of Cu/Cu2O nanoparticles on the cotton fabric discussed in this study relies on adsorption of Cu2+-ions by carboxylate groups generated through the TEMPO-mediated oxidation of cellulose and their subsequent reduction by sodium borohydride. In order to establish the influence of aldehyde and carboxylate groups on the nanoparticles formation, the duration of TEMPO-mediated oxidation was varied. Chemical changes induced by TEMPO-mediated oxidation were evaluated by titrimetric determination of the amounts of aldehyde and carboxylic groups in cotton and FTIR spectroscopy. The presence of Cu/Cu2O nanoparticles on the cotton fabric was confirmed by FE-SEM, AAS and XRD analyses. Antimicrobial activity of synthesized nanoparticles was tested against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and fungi C. albicans. The extension of TEMPO oxidation time led to an increase of carboxylate group content and consequently, formation of larger amounts of Cu/Cu2O nanoparticles. All fabricated textile nanocomposites provided excellent antibacterial and acceptable antifungal activity. They also ensured a controlled release of Cu2+-ions in physiological solution which is an imperative for infection prevention.",
journal = "Cellulose",
title = "In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics",
volume = "25",
number = "1",
pages = "829-841",
doi = "10.1007/s10570-017-1566-5"
}
Marković, D., Korica, M., Kostić, M. M., Radovanović, Ž., Šaponjić, Z., Mitrić, M.,& Radetić, M. M.. (2018). In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics. in Cellulose, 25(1), 829-841.
https://doi.org/10.1007/s10570-017-1566-5
Marković D, Korica M, Kostić MM, Radovanović Ž, Šaponjić Z, Mitrić M, Radetić MM. In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics. in Cellulose. 2018;25(1):829-841.
doi:10.1007/s10570-017-1566-5 .
Marković, Darka, Korica, Matea, Kostić, Mirjana M., Radovanović, Željko, Šaponjić, Zoran, Mitrić, Miodrag, Radetić, Maja M., "In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics" in Cellulose, 25, no. 1 (2018):829-841,
https://doi.org/10.1007/s10570-017-1566-5 . .
45
29
42

Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric

Marković, Darka; Šaponjić, Zoran; Radoičić, Marija B.; Radetić, Tamara; Vodnik, Vesna; Potkonjak, Branislav; Radetić, Maja M.

(2015)

TY  - JOUR
AU  - Marković, Darka
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija B.
AU  - Radetić, Tamara
AU  - Vodnik, Vesna
AU  - Potkonjak, Branislav
AU  - Radetić, Maja M.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/411
AB  - This study discusses the possibility of using corona pre-treated polypropylene (PP) non-woven fabric as a support for immobilization of colloidal TiO2 and Ag nanoparticles in order to remove dye C.I. Acid Orange 7 from aqueous solution. Dye removal efficiency by sonocatalysis, photocatalysis and sonophotocatalysis was evaluated on corona pre-treated fabric loaded with TiO2 nanoparticles, corona pre-treated fabric double loaded with TiO2 nanoparticles and corona pre-treated fabrics loaded with TiO2 nanoparticles before and after deposition of Ag nanoparticles. In addition, the stability of PP non-woven fabric during these processes was investigated. The substrates were characterized by SEM, EDX and AAS analyses. The change of the dye concentration was evaluated by UV-VIS spectrophotometry. Unlike sonocatalysis and photocatalysis, complete dye removal from both solution and non-woven fabric was obtained already after 240-270 min of sonophotocatalysis. Corona pre-treated PP non-woven fabric loaded with Ag nanoparticles prior to deposition of TiO2 nanoparticles provided excellent degradation efficiency and superior reusability. Sonophotocatalytic degradation of dye in the presence of all investigated samples was the most prominent in acidic conditions. Although this nanocomposite system ensured fast discoloration of dye solution, TOC values of water measured after sonophotocatalysis were not satisfactory because of PP degradation. Therefore, it is suggested to include TOC evaluation in each case study where different supports for TiO2 nanoparticles are used since these nanoparticles may guarantee the dye removal from solution but the stability of support could be problematic causing even more serious environmental impact. (C) 2014 Elsevier B.V. All rights reserved.
T2  - Ultrasonics Sonochemistry
T1  - Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric
VL  - 24
SP  - 221
EP  - 229
DO  - 10.1016/j.ultsonch.2014.11.017
ER  - 
@article{
author = "Marković, Darka and Šaponjić, Zoran and Radoičić, Marija B. and Radetić, Tamara and Vodnik, Vesna and Potkonjak, Branislav and Radetić, Maja M.",
year = "2015",
abstract = "This study discusses the possibility of using corona pre-treated polypropylene (PP) non-woven fabric as a support for immobilization of colloidal TiO2 and Ag nanoparticles in order to remove dye C.I. Acid Orange 7 from aqueous solution. Dye removal efficiency by sonocatalysis, photocatalysis and sonophotocatalysis was evaluated on corona pre-treated fabric loaded with TiO2 nanoparticles, corona pre-treated fabric double loaded with TiO2 nanoparticles and corona pre-treated fabrics loaded with TiO2 nanoparticles before and after deposition of Ag nanoparticles. In addition, the stability of PP non-woven fabric during these processes was investigated. The substrates were characterized by SEM, EDX and AAS analyses. The change of the dye concentration was evaluated by UV-VIS spectrophotometry. Unlike sonocatalysis and photocatalysis, complete dye removal from both solution and non-woven fabric was obtained already after 240-270 min of sonophotocatalysis. Corona pre-treated PP non-woven fabric loaded with Ag nanoparticles prior to deposition of TiO2 nanoparticles provided excellent degradation efficiency and superior reusability. Sonophotocatalytic degradation of dye in the presence of all investigated samples was the most prominent in acidic conditions. Although this nanocomposite system ensured fast discoloration of dye solution, TOC values of water measured after sonophotocatalysis were not satisfactory because of PP degradation. Therefore, it is suggested to include TOC evaluation in each case study where different supports for TiO2 nanoparticles are used since these nanoparticles may guarantee the dye removal from solution but the stability of support could be problematic causing even more serious environmental impact. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "Ultrasonics Sonochemistry",
title = "Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric",
volume = "24",
pages = "221-229",
doi = "10.1016/j.ultsonch.2014.11.017"
}
Marković, D., Šaponjić, Z., Radoičić, M. B., Radetić, T., Vodnik, V., Potkonjak, B.,& Radetić, M. M.. (2015). Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric. in Ultrasonics Sonochemistry, 24, 221-229.
https://doi.org/10.1016/j.ultsonch.2014.11.017
Marković D, Šaponjić Z, Radoičić MB, Radetić T, Vodnik V, Potkonjak B, Radetić MM. Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric. in Ultrasonics Sonochemistry. 2015;24:221-229.
doi:10.1016/j.ultsonch.2014.11.017 .
Marković, Darka, Šaponjić, Zoran, Radoičić, Marija B., Radetić, Tamara, Vodnik, Vesna, Potkonjak, Branislav, Radetić, Maja M., "Sonophotocatalytic degradation of dye CI Acid Orange 7 by TiO2 and Ag nanoparticles immobilized on corona pretreated polypropylene non-woven fabric" in Ultrasonics Sonochemistry, 24 (2015):221-229,
https://doi.org/10.1016/j.ultsonch.2014.11.017 . .
41
29
40

Functionalization of Textile Materials with Colloidal Ag and TiO2 Nanoparticles

Radetić, Maja; Šaponjić, Zoran; Marković, Darka; Lazić, Vesna; Radoičić, Marija; Vodnik, Vesna

(2014)

TY  - CONF
AU  - Radetić, Maja
AU  - Šaponjić, Zoran
AU  - Marković, Darka
AU  - Lazić, Vesna
AU  - Radoičić, Marija
AU  - Vodnik, Vesna
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12540
AB  - The functionalization of textile materials with metal and metal oxide nanoparticles gained much scientific attention over the last decade [1-2]. Textile nano-finishing could be a promising alternative to conventional finishing as the small amount of nanoparticles can impart specific properties to textile materials in different forms (fibers, yarns, fabrics). Ag nanoparticles were the most extensively investigated since they provide extraordinary antimicrobial properties against hundreds of various microorganisms (bacteria, fungi, viruses). On the other hand, photocatalytic activity, non-toxicity, high availability, biocompatibility, and low price make TiO2 nanoparticles particularly attractive for manufacturing of different high value-added textile goods. Many efforts have been made to immobilize TiO2 nanoparticles onto textile materials with an aim to fabricate goods with multifunctional properties such as UV protective, self-cleaning and antibacterial. The impregnation of textile materials with colloidal Ag and TiO2 nanoparticles is relatively simple by exhaustion method, but insufficient binding efficiency between certain fibers and nanoparticles imposes a problem related to stability and durability of nanocomposite systems during their exploitation. Therefore, recent studies were more oriented towards chemical and physico-chemical modification of fiber surfaces prior to impregnation with Ag and TiO2 nanoparticles. Plasma treatment of textile surfaces at atmospheric pressure and low pressures ensures superficial chemical and morphological modification of fibers. Controlled plasma processing is limited to the thin surface layers of fibers, leaving the bulk properties unchanged. Hydrophilization of naturally hydrophobic fibers (PET, PA, PP) by plasma treatment is particularly important as fiber surfaces become more accessible for hydrophilic colloidal nanoparticles. In addition, desired functional groups on the fiber surface are introduced which improve binding efficiency of nanoparticles. Taking into account the importance of environmental impact of novel technologies, potential environmental risks emerging from Ag and TiO2 release during washing of textile materials became the focus of many recent studies [3].
C3  - Workshop on Synthesis of advanced nano-and bio-colloidal materials with highly active surfaces : Program and Abstracts
T1  - Functionalization of Textile Materials with Colloidal Ag and TiO2 Nanoparticles
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12540
ER  - 
@conference{
author = "Radetić, Maja and Šaponjić, Zoran and Marković, Darka and Lazić, Vesna and Radoičić, Marija and Vodnik, Vesna",
year = "2014",
abstract = "The functionalization of textile materials with metal and metal oxide nanoparticles gained much scientific attention over the last decade [1-2]. Textile nano-finishing could be a promising alternative to conventional finishing as the small amount of nanoparticles can impart specific properties to textile materials in different forms (fibers, yarns, fabrics). Ag nanoparticles were the most extensively investigated since they provide extraordinary antimicrobial properties against hundreds of various microorganisms (bacteria, fungi, viruses). On the other hand, photocatalytic activity, non-toxicity, high availability, biocompatibility, and low price make TiO2 nanoparticles particularly attractive for manufacturing of different high value-added textile goods. Many efforts have been made to immobilize TiO2 nanoparticles onto textile materials with an aim to fabricate goods with multifunctional properties such as UV protective, self-cleaning and antibacterial. The impregnation of textile materials with colloidal Ag and TiO2 nanoparticles is relatively simple by exhaustion method, but insufficient binding efficiency between certain fibers and nanoparticles imposes a problem related to stability and durability of nanocomposite systems during their exploitation. Therefore, recent studies were more oriented towards chemical and physico-chemical modification of fiber surfaces prior to impregnation with Ag and TiO2 nanoparticles. Plasma treatment of textile surfaces at atmospheric pressure and low pressures ensures superficial chemical and morphological modification of fibers. Controlled plasma processing is limited to the thin surface layers of fibers, leaving the bulk properties unchanged. Hydrophilization of naturally hydrophobic fibers (PET, PA, PP) by plasma treatment is particularly important as fiber surfaces become more accessible for hydrophilic colloidal nanoparticles. In addition, desired functional groups on the fiber surface are introduced which improve binding efficiency of nanoparticles. Taking into account the importance of environmental impact of novel technologies, potential environmental risks emerging from Ag and TiO2 release during washing of textile materials became the focus of many recent studies [3].",
journal = "Workshop on Synthesis of advanced nano-and bio-colloidal materials with highly active surfaces : Program and Abstracts",
title = "Functionalization of Textile Materials with Colloidal Ag and TiO2 Nanoparticles",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12540"
}
Radetić, M., Šaponjić, Z., Marković, D., Lazić, V., Radoičić, M.,& Vodnik, V.. (2014). Functionalization of Textile Materials with Colloidal Ag and TiO2 Nanoparticles. in Workshop on Synthesis of advanced nano-and bio-colloidal materials with highly active surfaces : Program and Abstracts.
https://hdl.handle.net/21.15107/rcub_vinar_12540
Radetić M, Šaponjić Z, Marković D, Lazić V, Radoičić M, Vodnik V. Functionalization of Textile Materials with Colloidal Ag and TiO2 Nanoparticles. in Workshop on Synthesis of advanced nano-and bio-colloidal materials with highly active surfaces : Program and Abstracts. 2014;.
https://hdl.handle.net/21.15107/rcub_vinar_12540 .
Radetić, Maja, Šaponjić, Zoran, Marković, Darka, Lazić, Vesna, Radoičić, Marija, Vodnik, Vesna, "Functionalization of Textile Materials with Colloidal Ag and TiO2 Nanoparticles" in Workshop on Synthesis of advanced nano-and bio-colloidal materials with highly active surfaces : Program and Abstracts (2014),
https://hdl.handle.net/21.15107/rcub_vinar_12540 .

Palladium sorption by aminofunctionalized macroporous copolymer from chloride–nitrate solutions

Sandić, Zvijezdana; Marković, Darka; Novaković, Tatjana; Miladinović, Zoran; Hercigonja, Radmila V.

(Society of Physical Chemists of Serbia, 2014)

TY  - CONF
AU  - Sandić, Zvijezdana
AU  - Marković, Darka
AU  - Novaković, Tatjana
AU  - Miladinović, Zoran
AU  - Hercigonja, Radmila V.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9245
AB  - Macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
with attached diethylene triamine [PGME-deta] with high amino-group
content was used for the investigation of the Pd(II) sorption kinetics from
mixed chloride/nitrate aqueous solutions in acidic medium (pH 2.0) at
T=298 K. Four kinetic models were employed in order to comprehend the
mechanism of Pd(II) sorption. The maximum experimental Pd(II) sorption
capacity at initial pH 2.0 and 298 K was 20 mg g-1.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
T1  - Palladium sorption by aminofunctionalized macroporous copolymer from chloride–nitrate solutions
VL  - J-17-P
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9245
ER  - 
@conference{
author = "Sandić, Zvijezdana and Marković, Darka and Novaković, Tatjana and Miladinović, Zoran and Hercigonja, Radmila V.",
year = "2014",
abstract = "Macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
with attached diethylene triamine [PGME-deta] with high amino-group
content was used for the investigation of the Pd(II) sorption kinetics from
mixed chloride/nitrate aqueous solutions in acidic medium (pH 2.0) at
T=298 K. Four kinetic models were employed in order to comprehend the
mechanism of Pd(II) sorption. The maximum experimental Pd(II) sorption
capacity at initial pH 2.0 and 298 K was 20 mg g-1.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry",
title = "Palladium sorption by aminofunctionalized macroporous copolymer from chloride–nitrate solutions",
volume = "J-17-P",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9245"
}
Sandić, Z., Marković, D., Novaković, T., Miladinović, Z.,& Hercigonja, R. V.. (2014). Palladium sorption by aminofunctionalized macroporous copolymer from chloride–nitrate solutions. in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry
Society of Physical Chemists of Serbia., J-17-P.
https://hdl.handle.net/21.15107/rcub_vinar_9245
Sandić Z, Marković D, Novaković T, Miladinović Z, Hercigonja RV. Palladium sorption by aminofunctionalized macroporous copolymer from chloride–nitrate solutions. in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry. 2014;J-17-P.
https://hdl.handle.net/21.15107/rcub_vinar_9245 .
Sandić, Zvijezdana, Marković, Darka, Novaković, Tatjana, Miladinović, Zoran, Hercigonja, Radmila V., "Palladium sorption by aminofunctionalized macroporous copolymer from chloride–nitrate solutions" in Physical chemistry 2014: 12th International Conference on Fundamental and Applied Aspects of Physical Chemistry, J-17-P (2014),
https://hdl.handle.net/21.15107/rcub_vinar_9245 .

In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles

Milošević, Milica V.; Radoičić, Marija B.; Šaponjić, Zoran; Nunney, Tim; Marković, Darka; Nedeljković, Jovan; Radetić, Maja M.

(2013)

TY  - JOUR
AU  - Milošević, Milica V.
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Nunney, Tim
AU  - Marković, Darka
AU  - Nedeljković, Jovan
AU  - Radetić, Maja M.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5522
AB  - This study discusses the possibility of in situ generation of Ag nanoparticles on polyester fabric by photoreduction of Ag+ ions with deposited TiO2 nanoparticles in the presence of amino acid alanine and methyl alcohol. The presence of TiO2/Ag nanoparticles on the polyester fiber surface was confirmed by XRD, XPS, and SEM analyses. Such nanocomposite textile material provides excellent antimicrobial activity against Gram-negative bacterium E. coli, Gram-positive bacterium S. aureus, and fungus C. albicans. Maximum microbial reduction was preserved even after ten washing cycles. In spite of satisfactory laundering durability, the release of silver occurred during washing. The leaching of silver was also present when the fabrics were exposed to artificial sweat at pH 5.5 and pH 8.0 for 24 h. In addition to excellent antimicrobial properties, TiO2/Ag nanoparticles imparted maximum UV protection to polyester fabrics.
T2  - Journal of Materials Science
T1  - In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles
VL  - 48
IS  - 16
SP  - 5447
EP  - 5455
DO  - 10.1007/s10853-013-7338-1
ER  - 
@article{
author = "Milošević, Milica V. and Radoičić, Marija B. and Šaponjić, Zoran and Nunney, Tim and Marković, Darka and Nedeljković, Jovan and Radetić, Maja M.",
year = "2013",
abstract = "This study discusses the possibility of in situ generation of Ag nanoparticles on polyester fabric by photoreduction of Ag+ ions with deposited TiO2 nanoparticles in the presence of amino acid alanine and methyl alcohol. The presence of TiO2/Ag nanoparticles on the polyester fiber surface was confirmed by XRD, XPS, and SEM analyses. Such nanocomposite textile material provides excellent antimicrobial activity against Gram-negative bacterium E. coli, Gram-positive bacterium S. aureus, and fungus C. albicans. Maximum microbial reduction was preserved even after ten washing cycles. In spite of satisfactory laundering durability, the release of silver occurred during washing. The leaching of silver was also present when the fabrics were exposed to artificial sweat at pH 5.5 and pH 8.0 for 24 h. In addition to excellent antimicrobial properties, TiO2/Ag nanoparticles imparted maximum UV protection to polyester fabrics.",
journal = "Journal of Materials Science",
title = "In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles",
volume = "48",
number = "16",
pages = "5447-5455",
doi = "10.1007/s10853-013-7338-1"
}
Milošević, M. V., Radoičić, M. B., Šaponjić, Z., Nunney, T., Marković, D., Nedeljković, J.,& Radetić, M. M.. (2013). In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles. in Journal of Materials Science, 48(16), 5447-5455.
https://doi.org/10.1007/s10853-013-7338-1
Milošević MV, Radoičić MB, Šaponjić Z, Nunney T, Marković D, Nedeljković J, Radetić MM. In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles. in Journal of Materials Science. 2013;48(16):5447-5455.
doi:10.1007/s10853-013-7338-1 .
Milošević, Milica V., Radoičić, Marija B., Šaponjić, Zoran, Nunney, Tim, Marković, Darka, Nedeljković, Jovan, Radetić, Maja M., "In situ generation of Ag nanoparticles on polyester fabrics by photoreduction using TiO2 nanoparticles" in Journal of Materials Science, 48, no. 16 (2013):5447-5455,
https://doi.org/10.1007/s10853-013-7338-1 . .
20
14
22

Photocatalytic Degradation of Dye CI Direct Blue 78 Using TiO2 Nanoparticles Immobilized on Recycled Wool-Based Nonwoven Material

Marković, Darka; Jokić, Bojan M.; Šaponjić, Zoran; Potkonjak, Branislav; Jovancic, Petar; Radetić, Maja M.

(2013)

TY  - JOUR
AU  - Marković, Darka
AU  - Jokić, Bojan M.
AU  - Šaponjić, Zoran
AU  - Potkonjak, Branislav
AU  - Jovancic, Petar
AU  - Radetić, Maja M.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5786
AB  - This paper discusses the possibility of immobilization of TiO2 nanoparticles onto recycled wool-based nonwoven material, which can be utilized for removal of dyes from wastewater. The photocatalytic activity of TiO2 nanoparticles deposited on the nonwoven material was evaluated in the aqueous solution of direct dye C.I. Direct Blue 78 under the UV illumination. Nonwoven material modified with TiO2 nanoparticles provides complete removal of dye from the solution already after 4-6h of UV illumination. However, photodegradation of the dye adsorbed on the nonwoven material was obtained within 24h of UV illumination. The rate of dye adsorption and photodegradation depends on the amount of deposited TiO2 nanoparticles. The increase of initial dye concentration induced decrease in photocatalytic efficiency of immobilized TiO2 nanoparticles. The highest photodegradation rate was achieved in acidic conditions. Elevated temperatures positively affected the removal of dye from solution. Photocatalytic activity of TiO2 nanoparticles deposited on nonwoven material was preserved after three photodegradation cycles.
T2  - CLEAN - Soil Air Water
T1  - Photocatalytic Degradation of Dye CI Direct Blue 78 Using TiO2 Nanoparticles Immobilized on Recycled Wool-Based Nonwoven Material
VL  - 41
IS  - 10
SP  - 1002
EP  - 1009
DO  - 10.1002/clen.201200413
ER  - 
@article{
author = "Marković, Darka and Jokić, Bojan M. and Šaponjić, Zoran and Potkonjak, Branislav and Jovancic, Petar and Radetić, Maja M.",
year = "2013",
abstract = "This paper discusses the possibility of immobilization of TiO2 nanoparticles onto recycled wool-based nonwoven material, which can be utilized for removal of dyes from wastewater. The photocatalytic activity of TiO2 nanoparticles deposited on the nonwoven material was evaluated in the aqueous solution of direct dye C.I. Direct Blue 78 under the UV illumination. Nonwoven material modified with TiO2 nanoparticles provides complete removal of dye from the solution already after 4-6h of UV illumination. However, photodegradation of the dye adsorbed on the nonwoven material was obtained within 24h of UV illumination. The rate of dye adsorption and photodegradation depends on the amount of deposited TiO2 nanoparticles. The increase of initial dye concentration induced decrease in photocatalytic efficiency of immobilized TiO2 nanoparticles. The highest photodegradation rate was achieved in acidic conditions. Elevated temperatures positively affected the removal of dye from solution. Photocatalytic activity of TiO2 nanoparticles deposited on nonwoven material was preserved after three photodegradation cycles.",
journal = "CLEAN - Soil Air Water",
title = "Photocatalytic Degradation of Dye CI Direct Blue 78 Using TiO2 Nanoparticles Immobilized on Recycled Wool-Based Nonwoven Material",
volume = "41",
number = "10",
pages = "1002-1009",
doi = "10.1002/clen.201200413"
}
Marković, D., Jokić, B. M., Šaponjić, Z., Potkonjak, B., Jovancic, P.,& Radetić, M. M.. (2013). Photocatalytic Degradation of Dye CI Direct Blue 78 Using TiO2 Nanoparticles Immobilized on Recycled Wool-Based Nonwoven Material. in CLEAN - Soil Air Water, 41(10), 1002-1009.
https://doi.org/10.1002/clen.201200413
Marković D, Jokić BM, Šaponjić Z, Potkonjak B, Jovancic P, Radetić MM. Photocatalytic Degradation of Dye CI Direct Blue 78 Using TiO2 Nanoparticles Immobilized on Recycled Wool-Based Nonwoven Material. in CLEAN - Soil Air Water. 2013;41(10):1002-1009.
doi:10.1002/clen.201200413 .
Marković, Darka, Jokić, Bojan M., Šaponjić, Zoran, Potkonjak, Branislav, Jovancic, Petar, Radetić, Maja M., "Photocatalytic Degradation of Dye CI Direct Blue 78 Using TiO2 Nanoparticles Immobilized on Recycled Wool-Based Nonwoven Material" in CLEAN - Soil Air Water, 41, no. 10 (2013):1002-1009,
https://doi.org/10.1002/clen.201200413 . .
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Thermodynamcis of molybdenum adsorption onto porous copolymer

Ekmeščić, Bojana; Maksin, Danijela D.; Suručić, Ljiljana T.; Marković, Jelena P.; Marković, Darka; Vuković, Zorica M.; Onjia, Antonije E.

(Society of Physical Chemists of Serbia, 2012)

TY  - CONF
AU  - Ekmeščić, Bojana
AU  - Maksin, Danijela D.
AU  - Suručić, Ljiljana T.
AU  - Marković, Jelena P.
AU  - Marković, Darka
AU  - Vuković, Zorica M.
AU  - Onjia, Antonije E.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9271
AB  - Macroporous glycidyl methacrylate and ethylene glycol dimethacrylate copolymer
functionalized with diethylene triamine, PGME-deta, was tested as molybdate ion
adsorbent from aqueous solutions. Kinetics of Mo(VI) sorption was investigated in
batch static experiments, in the temperature range 298-343 K. The temperature rise
promotes Mo(VI) removal, with the maximum experimental adsorption capacity of
585 mg g-1 at 343 K. Thermodynamic parameters revealed spontaneous and
endothermic nature of Mo(VI) adsorption onto PGME-deta.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry
T1  - Thermodynamcis of molybdenum adsorption onto porous copolymer
VL  - 1
SP  - 206
EP  - 208
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9271
ER  - 
@conference{
author = "Ekmeščić, Bojana and Maksin, Danijela D. and Suručić, Ljiljana T. and Marković, Jelena P. and Marković, Darka and Vuković, Zorica M. and Onjia, Antonije E.",
year = "2012",
abstract = "Macroporous glycidyl methacrylate and ethylene glycol dimethacrylate copolymer
functionalized with diethylene triamine, PGME-deta, was tested as molybdate ion
adsorbent from aqueous solutions. Kinetics of Mo(VI) sorption was investigated in
batch static experiments, in the temperature range 298-343 K. The temperature rise
promotes Mo(VI) removal, with the maximum experimental adsorption capacity of
585 mg g-1 at 343 K. Thermodynamic parameters revealed spontaneous and
endothermic nature of Mo(VI) adsorption onto PGME-deta.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry",
title = "Thermodynamcis of molybdenum adsorption onto porous copolymer",
volume = "1",
pages = "206-208",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9271"
}
Ekmeščić, B., Maksin, D. D., Suručić, L. T., Marković, J. P., Marković, D., Vuković, Z. M.,& Onjia, A. E.. (2012). Thermodynamcis of molybdenum adsorption onto porous copolymer. in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry
Society of Physical Chemists of Serbia., 1, 206-208.
https://hdl.handle.net/21.15107/rcub_vinar_9271
Ekmeščić B, Maksin DD, Suručić LT, Marković JP, Marković D, Vuković ZM, Onjia AE. Thermodynamcis of molybdenum adsorption onto porous copolymer. in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry. 2012;1:206-208.
https://hdl.handle.net/21.15107/rcub_vinar_9271 .
Ekmeščić, Bojana, Maksin, Danijela D., Suručić, Ljiljana T., Marković, Jelena P., Marković, Darka, Vuković, Zorica M., Onjia, Antonije E., "Thermodynamcis of molybdenum adsorption onto porous copolymer" in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry, 1 (2012):206-208,
https://hdl.handle.net/21.15107/rcub_vinar_9271 .