@article{
author = "Tomić, Nataša Z. and Saleh, Mohamed Nasr and Teixeira de Freitas, Sofia and Živković, Andreja and Vuksanović, Marija M. and Poulis, Johannes A. and Marinković, Aleksandar",
year = "2020",
abstract = "This paper presents a new process for obtaining eco-epoxide adhesives synthesized from bio-renewable raw material (tannic acid—TA) and used for bonding lightweight materials (aluminum (Al) and carbon fiber reinforced polymer (CFRP)). Two synthesized bio-epoxy components based on TA, (A) glycidyl ether and (B) glycidyl phosphate ester of TA, were used as a replacement for the toxic epoxy component based on Bisphenol A. The effect of eco-epoxy components on the interface adhesion was measured by the determination of adhesion parameter b, which was compared to the reference epoxy (REF). The increase of adhesion parameter b was 77.5% for A and 151.5% for B. The adhesion of both eco-adhesives was tested using the bell peel test (BPT) with the Al and CFRP adherends. When compared to REF, the average peel load for B was 17.6% (39.3%) and 58.3% (176.9%) higher for the Al and CFRP adherends, respectively. Complete adhesion failure of REF reflected the weak adhesion to both Al and CFRP, which was improved by the addition of eco-epoxy components A and B showing the presence of cohesive failure. The microhardness testing method of interface adhesion was proven to be a fast and reliable testing method, providing a qualitative indication in adhesive selection.",
journal = "Polymers",
title = "Enhanced Interface Adhesion by Novel Eco-Epoxy Adhesives Based on the Modified Tannic Acid on Al and CFRP Adherends",
volume = "12",
number = "7",
pages = "1541",
doi = "10.3390/polym12071541"
}