Cvjetićanin, Nikola

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Authority KeyName Variants
orcid::0000-0001-9350-4010
  • Cvjetićanin, Nikola (56)
Projects
Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them Magnetic and radionuclide labeled nanostructured materials for medical applications
Lithium-ion batteries and fuel cells - research and development Struktura, termodinamičke i elektrohemijske osobine materijala za konverziju energije i nove tehnologije
Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine Serbian Academy of Science and Arts
Bilateral Serbia-Slovenia [06-00-118/2018-09/32/02] Bilateral Serbia-Slovenia [BI-RS/18-19-031]
CENN Nanocenter for the use of Transmission Electron Microscope Jeol [JEM-2100] Electronic, transport and optical properties of nanostructured materials
Chemical and structural designing of nanomaterials for application in medicine and tissue engineering Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200053 (University of Belgrade, Institute for Multidisciplinary Research) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200146 (University of Belgrade, Faculty of Physical Chemistry)
Sinteza funkcionalnih materijala sa kontrolisanom strukturom na molekularnom i nano nivou MESTD, DGA (Gobierno de Aragon) [E26], Spanish Ministerio de Economia y Competitividad (MINECO) [MAT2013-42551]
Ministry of Science, Technologies and Development of Republic of Serbia [Project no. 1431] Serbian Ministry of Science [141027]
The Serbian Ministry of Science [141027], National Science Foundation (NSF) [DMR-0304391, DMR-0703940], DOE [DE-AC02-06CH11357], Spanish MICINN

Author's Bibliography

Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers

Ahmetović, Sanita; Vasiljević, Zorka Ž.; Rajić, Vladimir; Bartolić, Dragana; Novaković, Mirjana M.; Tadić, Nenad B.; Cvjetićanin, Nikola; Nikolić, Maria Vesna

(2023)

TY  - JOUR
AU  - Ahmetović, Sanita
AU  - Vasiljević, Zorka Ž.
AU  - Rajić, Vladimir
AU  - Bartolić, Dragana
AU  - Novaković, Mirjana M.
AU  - Tadić, Nenad B.
AU  - Cvjetićanin, Nikola
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10448
AB  - Pure and samarium (Sm3+) - or zirconium (Zr4+)-doped TiO2 nanofibers were synthesized by electrospinning method followed by calcination at 500 °C for 1 h. As-spun fibers were smooth, straight and continuous, whilst EDS analysis confirmed the fiber composition and incorporation of dopants in the fibers. Doping with Sm3+ and Zr4+ greatly inhibited the phase transformation of anatase to rutile, by surrounding of Sm3+ ions through formation of Ti-O-Sm bonds and by replacement of Ti4+ ions with larger Zr4+ ions. This was confirmed by HRTEM and SAED analysis. The size of nanofibers was determined to be 133 nm, 175 nm and 155 nm for pure, (0.5%)Sm3+:TiO2 and (1%)Zr4+:TiO2, respectively. After calcination, TiO2 crystal lattice with interplanar spacing of 0.353 nm of (101) crystal plane was not significantly disturbed by Sm doping whilst crystal lattice spacing of 0.357 nm of (101) planes of anatase phase in case TiO2:1.0%Zr4+, significantly differs from the value of pure TiO2 (0.352 nm), thus implying that Zr was doped into substitutional sites of the TiO2 lattice. The indirect band gaps were calculated to be in the range 3.07–3.24 eV. TiO2:0.5%Sm3+ and TiO2:1.0%Zr4+ exhibited higher specific surface area, of 47.1 and 59.4 m2/g, respectively, than pure TiO2 fibers (19.7 m2/g). Effects of Sm3+ and Zr4+ dopant content on the photodegradation efficiency of methylene blue (MB) were studied. TiO2:0.5%Sm3+ and TiO2:1.0%Zr4+ nanofibers have shown the highest photocatalytic activity of 97% and 98% with constant rates 0.01768 min−1 and 0.01939 min−1, respectively, within180 min irradiation under visible light.
T2  - Journal of Alloys and Compounds
T1  - Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers
VL  - 930
SP  - 167423
DO  - 10.1016/j.jallcom.2022.167423
ER  - 
@article{
author = "Ahmetović, Sanita and Vasiljević, Zorka Ž. and Rajić, Vladimir and Bartolić, Dragana and Novaković, Mirjana M. and Tadić, Nenad B. and Cvjetićanin, Nikola and Nikolić, Maria Vesna",
year = "2023",
abstract = "Pure and samarium (Sm3+) - or zirconium (Zr4+)-doped TiO2 nanofibers were synthesized by electrospinning method followed by calcination at 500 °C for 1 h. As-spun fibers were smooth, straight and continuous, whilst EDS analysis confirmed the fiber composition and incorporation of dopants in the fibers. Doping with Sm3+ and Zr4+ greatly inhibited the phase transformation of anatase to rutile, by surrounding of Sm3+ ions through formation of Ti-O-Sm bonds and by replacement of Ti4+ ions with larger Zr4+ ions. This was confirmed by HRTEM and SAED analysis. The size of nanofibers was determined to be 133 nm, 175 nm and 155 nm for pure, (0.5%)Sm3+:TiO2 and (1%)Zr4+:TiO2, respectively. After calcination, TiO2 crystal lattice with interplanar spacing of 0.353 nm of (101) crystal plane was not significantly disturbed by Sm doping whilst crystal lattice spacing of 0.357 nm of (101) planes of anatase phase in case TiO2:1.0%Zr4+, significantly differs from the value of pure TiO2 (0.352 nm), thus implying that Zr was doped into substitutional sites of the TiO2 lattice. The indirect band gaps were calculated to be in the range 3.07–3.24 eV. TiO2:0.5%Sm3+ and TiO2:1.0%Zr4+ exhibited higher specific surface area, of 47.1 and 59.4 m2/g, respectively, than pure TiO2 fibers (19.7 m2/g). Effects of Sm3+ and Zr4+ dopant content on the photodegradation efficiency of methylene blue (MB) were studied. TiO2:0.5%Sm3+ and TiO2:1.0%Zr4+ nanofibers have shown the highest photocatalytic activity of 97% and 98% with constant rates 0.01768 min−1 and 0.01939 min−1, respectively, within180 min irradiation under visible light.",
journal = "Journal of Alloys and Compounds",
title = "Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers",
volume = "930",
pages = "167423",
doi = "10.1016/j.jallcom.2022.167423"
}
Ahmetović, S., Vasiljević, Z. Ž., Rajić, V., Bartolić, D., Novaković, M. M., Tadić, N. B., Cvjetićanin, N.,& Nikolić, M. V.. (2023). Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers. in Journal of Alloys and Compounds, 930, 167423.
https://doi.org/10.1016/j.jallcom.2022.167423
Ahmetović S, Vasiljević ZŽ, Rajić V, Bartolić D, Novaković MM, Tadić NB, Cvjetićanin N, Nikolić MV. Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers. in Journal of Alloys and Compounds. 2023;930:167423.
doi:10.1016/j.jallcom.2022.167423 .
Ahmetović, Sanita, Vasiljević, Zorka Ž., Rajić, Vladimir, Bartolić, Dragana, Novaković, Mirjana M., Tadić, Nenad B., Cvjetićanin, Nikola, Nikolić, Maria Vesna, "Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers" in Journal of Alloys and Compounds, 930 (2023):167423,
https://doi.org/10.1016/j.jallcom.2022.167423 . .
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Magnetic memory effect in hollandite-type α-K MnO2 monocrystalline nanorods

Barudžija, Tanja; Perović, Marija M.; Bošković, Marko; Cvjetićanin, Nikola; Gyergyek, Sašo; Mitrić, Miodrag

(2020)

TY  - JOUR
AU  - Barudžija, Tanja
AU  - Perović, Marija M.
AU  - Bošković, Marko
AU  - Cvjetićanin, Nikola
AU  - Gyergyek, Sašo
AU  - Mitrić, Miodrag
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8743
AB  - Memory effect due to spin-glass state below about 20 K has been illustrated in the hollandite-type α-KxMnO2 monocrystalline nanorods by systematic magnetization measurements including temperature- and time-dependent magnetization curves in low fields. In this work, we succeeded in writing, reading, and deleting 8-bits digital information in the investigated system. These results show that α-KxMnO2 is a good candidate material for a thermal memory cell. The phenomenological droplet model was used in the description of the observed memory effect, whose origin in α-KxMnO2 is associated with bulk properties, doping and frustration. © 2019 Elsevier B.V.
T2  - Journal of Alloys and Compounds
T1  - Magnetic memory effect in hollandite-type α-K MnO2 monocrystalline nanorods
VL  - 820
SP  - 153406
DO  - 10.1016/j.jallcom.2019.153406
ER  - 
@article{
author = "Barudžija, Tanja and Perović, Marija M. and Bošković, Marko and Cvjetićanin, Nikola and Gyergyek, Sašo and Mitrić, Miodrag",
year = "2020",
abstract = "Memory effect due to spin-glass state below about 20 K has been illustrated in the hollandite-type α-KxMnO2 monocrystalline nanorods by systematic magnetization measurements including temperature- and time-dependent magnetization curves in low fields. In this work, we succeeded in writing, reading, and deleting 8-bits digital information in the investigated system. These results show that α-KxMnO2 is a good candidate material for a thermal memory cell. The phenomenological droplet model was used in the description of the observed memory effect, whose origin in α-KxMnO2 is associated with bulk properties, doping and frustration. © 2019 Elsevier B.V.",
journal = "Journal of Alloys and Compounds",
title = "Magnetic memory effect in hollandite-type α-K MnO2 monocrystalline nanorods",
volume = "820",
pages = "153406",
doi = "10.1016/j.jallcom.2019.153406"
}
Barudžija, T., Perović, M. M., Bošković, M., Cvjetićanin, N., Gyergyek, S.,& Mitrić, M.. (2020). Magnetic memory effect in hollandite-type α-K MnO2 monocrystalline nanorods. in Journal of Alloys and Compounds, 820, 153406.
https://doi.org/10.1016/j.jallcom.2019.153406
Barudžija T, Perović MM, Bošković M, Cvjetićanin N, Gyergyek S, Mitrić M. Magnetic memory effect in hollandite-type α-K MnO2 monocrystalline nanorods. in Journal of Alloys and Compounds. 2020;820:153406.
doi:10.1016/j.jallcom.2019.153406 .
Barudžija, Tanja, Perović, Marija M., Bošković, Marko, Cvjetićanin, Nikola, Gyergyek, Sašo, Mitrić, Miodrag, "Magnetic memory effect in hollandite-type α-K MnO2 monocrystalline nanorods" in Journal of Alloys and Compounds, 820 (2020):153406,
https://doi.org/10.1016/j.jallcom.2019.153406 . .
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2
3

Magnetic and power absorption measurements on iron oxide nanoparticles synthesized by thermal decomposition of Fe(acac)(3)

Jović Orsini, Nataša; Babić-Stojić, Branka S.; Spasojević, Vojislav; Calatayud, Maria Pilar; Cvjetićanin, Nikola; Goya, Gerardo F.

(2018)

TY  - JOUR
AU  - Jović Orsini, Nataša
AU  - Babić-Stojić, Branka S.
AU  - Spasojević, Vojislav
AU  - Calatayud, Maria Pilar
AU  - Cvjetićanin, Nikola
AU  - Goya, Gerardo F.
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1835
AB  - Iron oxide magnetic nanoparticles with diameters d, 7 nm LT = d LT = 12 nm, were synthesized by thermal decomposition of Fe(acac)(3). Different experimental conditions, keeping constant concetration of Fe ions in solvent, showed that the heating rates is the most important parameter determining the final particle size. Use of two different solvents, 1-eicosene and 1-octadecene, yielded similar nanoparticle sizes (7.1 nm LT = d LT = 7.5 nm), but different magnetic anisotropies. All samples were superparamagnetic at room temperature. Spin disordering was inferred in samples coated with trioctylphosphine oxide (TOPO) co-ligand in addition to oleic acid and oleyamine. The heating ability of similar to 12 nm-sized nanoparticles dispersed in hexane under alternating magnetic fields (3.98 kA/m LT = H-0 LT = 23.87 kA/m; 229.3 kHz LT = f LT = 828 kHz) has been studied, finding a nearly quadratic dependence upon H-0, as expected from the linear response theory. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Journal of Magnetism and Magnetic Materials
T1  - Magnetic and power absorption measurements on iron oxide nanoparticles synthesized by thermal decomposition of Fe(acac)(3)
VL  - 449
SP  - 286
EP  - 296
DO  - 10.1016/j.jmmm.2017.10.053
ER  - 
@article{
author = "Jović Orsini, Nataša and Babić-Stojić, Branka S. and Spasojević, Vojislav and Calatayud, Maria Pilar and Cvjetićanin, Nikola and Goya, Gerardo F.",
year = "2018",
abstract = "Iron oxide magnetic nanoparticles with diameters d, 7 nm LT = d LT = 12 nm, were synthesized by thermal decomposition of Fe(acac)(3). Different experimental conditions, keeping constant concetration of Fe ions in solvent, showed that the heating rates is the most important parameter determining the final particle size. Use of two different solvents, 1-eicosene and 1-octadecene, yielded similar nanoparticle sizes (7.1 nm LT = d LT = 7.5 nm), but different magnetic anisotropies. All samples were superparamagnetic at room temperature. Spin disordering was inferred in samples coated with trioctylphosphine oxide (TOPO) co-ligand in addition to oleic acid and oleyamine. The heating ability of similar to 12 nm-sized nanoparticles dispersed in hexane under alternating magnetic fields (3.98 kA/m LT = H-0 LT = 23.87 kA/m; 229.3 kHz LT = f LT = 828 kHz) has been studied, finding a nearly quadratic dependence upon H-0, as expected from the linear response theory. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Journal of Magnetism and Magnetic Materials",
title = "Magnetic and power absorption measurements on iron oxide nanoparticles synthesized by thermal decomposition of Fe(acac)(3)",
volume = "449",
pages = "286-296",
doi = "10.1016/j.jmmm.2017.10.053"
}
Jović Orsini, N., Babić-Stojić, B. S., Spasojević, V., Calatayud, M. P., Cvjetićanin, N.,& Goya, G. F.. (2018). Magnetic and power absorption measurements on iron oxide nanoparticles synthesized by thermal decomposition of Fe(acac)(3). in Journal of Magnetism and Magnetic Materials, 449, 286-296.
https://doi.org/10.1016/j.jmmm.2017.10.053
Jović Orsini N, Babić-Stojić BS, Spasojević V, Calatayud MP, Cvjetićanin N, Goya GF. Magnetic and power absorption measurements on iron oxide nanoparticles synthesized by thermal decomposition of Fe(acac)(3). in Journal of Magnetism and Magnetic Materials. 2018;449:286-296.
doi:10.1016/j.jmmm.2017.10.053 .
Jović Orsini, Nataša, Babić-Stojić, Branka S., Spasojević, Vojislav, Calatayud, Maria Pilar, Cvjetićanin, Nikola, Goya, Gerardo F., "Magnetic and power absorption measurements on iron oxide nanoparticles synthesized by thermal decomposition of Fe(acac)(3)" in Journal of Magnetism and Magnetic Materials, 449 (2018):286-296,
https://doi.org/10.1016/j.jmmm.2017.10.053 . .
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54
35
51

Synthesis and characterization of Li2FeP2O7 cathode material

Uskoković, Dragan; Radmilović, Velimir R.; Jugović, Dragana; Milović, Miloš; Mitrić, Miodrag; Cvjetićanin, Nikola; Škapin, Srečo Davor; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2017)

TY  - CONF
AU  - Jugović, Dragana
AU  - Milović, Miloš
AU  - Mitrić, Miodrag
AU  - Cvjetićanin, Nikola
AU  - Škapin, Srečo Davor
AU  - Uskoković, Dragan
PY  - 2017
UR  - http://dais.sanu.ac.rs/123456789/15439
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7560
AB  - The search for alternative cathode materials for Li-ion batteries has recently emerged Li2FeP2O7 pyrophosphate as a new potential competitor for LiFePO4 material. It has a possibility to offer good rate capability, lithium ion diffusivity and volumetric energy density, and is a material of high safety and low raw materials cost. In addition, there is the probability of releasing the second Li-atom at a higher redox potential of 5.2 V, where the theoretical capacity would reach 220 mAhg−1. Optimized solid state reaction is used for the synthesis of pure Li2FeP2O7 powder and a composite Li2FeP2O7/C. The synthesized powders are characterized by X-ray powder diffraction, field emission scanning electron microscopy, FTIR spectroscopy, and galvanostatic charge/discharge cycling.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
T1  - Synthesis and characterization of Li2FeP2O7 cathode material
SP  - 46
EP  - 46
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7560
ER  - 
@conference{
editor = "Uskoković, Dragan, Radmilović, Velimir R.",
author = "Jugović, Dragana and Milović, Miloš and Mitrić, Miodrag and Cvjetićanin, Nikola and Škapin, Srečo Davor and Uskoković, Dragan",
year = "2017",
abstract = "The search for alternative cathode materials for Li-ion batteries has recently emerged Li2FeP2O7 pyrophosphate as a new potential competitor for LiFePO4 material. It has a possibility to offer good rate capability, lithium ion diffusivity and volumetric energy density, and is a material of high safety and low raw materials cost. In addition, there is the probability of releasing the second Li-atom at a higher redox potential of 5.2 V, where the theoretical capacity would reach 220 mAhg−1. Optimized solid state reaction is used for the synthesis of pure Li2FeP2O7 powder and a composite Li2FeP2O7/C. The synthesized powders are characterized by X-ray powder diffraction, field emission scanning electron microscopy, FTIR spectroscopy, and galvanostatic charge/discharge cycling.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017",
title = "Synthesis and characterization of Li2FeP2O7 cathode material",
pages = "46-46",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7560"
}
Uskoković, D., Radmilović, V. R., Jugović, D., Milović, M., Mitrić, M., Cvjetićanin, N., Škapin, S. D.,& Uskoković, D.. (2017). Synthesis and characterization of Li2FeP2O7 cathode material. in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017
Belgrade : Materials Research Society of Serbia., 46-46.
https://hdl.handle.net/21.15107/rcub_vinar_7560
Uskoković D, Radmilović VR, Jugović D, Milović M, Mitrić M, Cvjetićanin N, Škapin SD, Uskoković D. Synthesis and characterization of Li2FeP2O7 cathode material. in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017. 2017;:46-46.
https://hdl.handle.net/21.15107/rcub_vinar_7560 .
Uskoković, Dragan, Radmilović, Velimir R., Jugović, Dragana, Milović, Miloš, Mitrić, Miodrag, Cvjetićanin, Nikola, Škapin, Srečo Davor, Uskoković, Dragan, "Synthesis and characterization of Li2FeP2O7 cathode material" in Programme and The Book of Abstracts / Nineteenth Annual Conference YUCOMAT 2017, Herceg Novi, September 4-8, 2017 (2017):46-46,
https://hdl.handle.net/21.15107/rcub_vinar_7560 .

Vibrational and electron paramagnetic resonance spectroscopic studies of beta-MnO2 and alpha-KxMnO(2) nanorods

Barudžija, Tanja; Cvjetićanin, Nikola; Bajuk-Bogdanović, Danica V.; Mojovic, Milos; Mitrić, Miodrag

(2017)

TY  - JOUR
AU  - Barudžija, Tanja
AU  - Cvjetićanin, Nikola
AU  - Bajuk-Bogdanović, Danica V.
AU  - Mojovic, Milos
AU  - Mitrić, Miodrag
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1777
AB  - Raman scattering (RS), Fourier transform infrared (FTIR) and electron paramagnetic resonance (EPR) spectroscopic measurements on beta-MnO2 and alpha-KxMnO2 nanorods were performed. The infrared spectrum of beta-MnO2 is sensitive towards the particle sizes, while the Raman spectrum is sensitive towards the presence of nonstoichiometric and disordered MnO2-delta on the surface of nanorods. EPR measurements show the appearance of two types of Mn4+ ions having different local environment: (i) Mn4+ ions in Mn4+-rich environment and (ii) Mn4+ ions in mixed-valence Mn4+/Mn3+ environment that match up with region of nonstoichiometric MnO2-delta. Observed bands in vibrational spectra of tetragonal hollanditetype alpha-KxMnO(2) are considered to be mainly due to the vibration modes of Mn-O frameworks. The EPR spectra of alpha-KxMnO(2) nanorods contain two signals that can be attributed to Mn4+ ions in Mn4+-rich environment and Mn4+ ions in mixed-valence Mn4+/Mn3+ environment close to K+ ions. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Journal of Alloys and Compounds
T1  - Vibrational and electron paramagnetic resonance spectroscopic studies of beta-MnO2 and alpha-KxMnO(2) nanorods
VL  - 728
SP  - 259
EP  - 270
DO  - 10.1016/j.jallcom.2017.09.015
ER  - 
@article{
author = "Barudžija, Tanja and Cvjetićanin, Nikola and Bajuk-Bogdanović, Danica V. and Mojovic, Milos and Mitrić, Miodrag",
year = "2017",
abstract = "Raman scattering (RS), Fourier transform infrared (FTIR) and electron paramagnetic resonance (EPR) spectroscopic measurements on beta-MnO2 and alpha-KxMnO2 nanorods were performed. The infrared spectrum of beta-MnO2 is sensitive towards the particle sizes, while the Raman spectrum is sensitive towards the presence of nonstoichiometric and disordered MnO2-delta on the surface of nanorods. EPR measurements show the appearance of two types of Mn4+ ions having different local environment: (i) Mn4+ ions in Mn4+-rich environment and (ii) Mn4+ ions in mixed-valence Mn4+/Mn3+ environment that match up with region of nonstoichiometric MnO2-delta. Observed bands in vibrational spectra of tetragonal hollanditetype alpha-KxMnO(2) are considered to be mainly due to the vibration modes of Mn-O frameworks. The EPR spectra of alpha-KxMnO(2) nanorods contain two signals that can be attributed to Mn4+ ions in Mn4+-rich environment and Mn4+ ions in mixed-valence Mn4+/Mn3+ environment close to K+ ions. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Journal of Alloys and Compounds",
title = "Vibrational and electron paramagnetic resonance spectroscopic studies of beta-MnO2 and alpha-KxMnO(2) nanorods",
volume = "728",
pages = "259-270",
doi = "10.1016/j.jallcom.2017.09.015"
}
Barudžija, T., Cvjetićanin, N., Bajuk-Bogdanović, D. V., Mojovic, M.,& Mitrić, M.. (2017). Vibrational and electron paramagnetic resonance spectroscopic studies of beta-MnO2 and alpha-KxMnO(2) nanorods. in Journal of Alloys and Compounds, 728, 259-270.
https://doi.org/10.1016/j.jallcom.2017.09.015
Barudžija T, Cvjetićanin N, Bajuk-Bogdanović DV, Mojovic M, Mitrić M. Vibrational and electron paramagnetic resonance spectroscopic studies of beta-MnO2 and alpha-KxMnO(2) nanorods. in Journal of Alloys and Compounds. 2017;728:259-270.
doi:10.1016/j.jallcom.2017.09.015 .
Barudžija, Tanja, Cvjetićanin, Nikola, Bajuk-Bogdanović, Danica V., Mojovic, Milos, Mitrić, Miodrag, "Vibrational and electron paramagnetic resonance spectroscopic studies of beta-MnO2 and alpha-KxMnO(2) nanorods" in Journal of Alloys and Compounds, 728 (2017):259-270,
https://doi.org/10.1016/j.jallcom.2017.09.015 . .
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16

The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Cvjetićanin, Nikola; Jokić, Bojan M.; Umićević, Ana; Uskoković, Dragan

(2017)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Cvjetićanin, Nikola
AU  - Jokić, Bojan M.
AU  - Umićević, Ana
AU  - Uskoković, Dragan
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1401
AB  - Low intrinsic electronic conductivity is the main disadvantage of LiFePO4 when used as a cathode material in lithium ion batteries. The paper offers experimental proofs of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. The LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon free powders are synthesized and examined. The crystal structure refinements in the Pnma space group reveal that doping with fluorine ions preserves the olivine structure, while reducing both the lattice parameters and the antisite defect, and increasing the crystallite size. A small amount of incorporated fluorine enhances the electrical conductivity from 4.6x10(-7) S cm(-1) to 2.3x10(-6) S cm(-1) and has a positive impact on the electrochemical performance. Several spectroscopy techniques (Mossbauer, FTIR, and Raman) reveal differences between the two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.
T2  - Ceramics International
T1  - The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder
VL  - 43
IS  - 3
SP  - 3224
EP  - 3230
DO  - 10.1016/j.ceramint.2016.11.149
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Cvjetićanin, Nikola and Jokić, Bojan M. and Umićević, Ana and Uskoković, Dragan",
year = "2017",
abstract = "Low intrinsic electronic conductivity is the main disadvantage of LiFePO4 when used as a cathode material in lithium ion batteries. The paper offers experimental proofs of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. The LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon free powders are synthesized and examined. The crystal structure refinements in the Pnma space group reveal that doping with fluorine ions preserves the olivine structure, while reducing both the lattice parameters and the antisite defect, and increasing the crystallite size. A small amount of incorporated fluorine enhances the electrical conductivity from 4.6x10(-7) S cm(-1) to 2.3x10(-6) S cm(-1) and has a positive impact on the electrochemical performance. Several spectroscopy techniques (Mossbauer, FTIR, and Raman) reveal differences between the two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.",
journal = "Ceramics International",
title = "The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder",
volume = "43",
number = "3",
pages = "3224-3230",
doi = "10.1016/j.ceramint.2016.11.149"
}
Jugović, D., Mitrić, M., Milović, M., Cvjetićanin, N., Jokić, B. M., Umićević, A.,& Uskoković, D.. (2017). The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder. in Ceramics International, 43(3), 3224-3230.
https://doi.org/10.1016/j.ceramint.2016.11.149
Jugović D, Mitrić M, Milović M, Cvjetićanin N, Jokić BM, Umićević A, Uskoković D. The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder. in Ceramics International. 2017;43(3):3224-3230.
doi:10.1016/j.ceramint.2016.11.149 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Cvjetićanin, Nikola, Jokić, Bojan M., Umićević, Ana, Uskoković, Dragan, "The influence of fluorine doping on the structural and electrical properties of the LiFePO4 powder" in Ceramics International, 43, no. 3 (2017):3224-3230,
https://doi.org/10.1016/j.ceramint.2016.11.149 . .
18
12
20

Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology

Bratić, Milan; Jugović, Dragana; Mitrić, Miodrag; Cvjetićanin, Nikola

(2017)

TY  - JOUR
AU  - Bratić, Milan
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Cvjetićanin, Nikola
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1585
AB  - Anatase TiO2 nanotube arrays of different morphology were prepared by a two-step process: anodic oxidation at voltages 20-60 V and subsequent annealing at 400 degrees C. By amplifying anodization voltage the inner diameter of nanotubes increased. At 60 V nanotubes changed the shape from cylindrical tube to truncated cone with elliptical opening. Electrochemical insertion of Li-ion in nanotubes was studied by cyclic voltammetry and galvanostatic charge-discharge experiments. The cyclovoltammetric response was fast for all nanotube arrays. The galvanostatic areal charge/discharge capacity of nanotube arrays increased with increasing anodizaton voltage. Although the mass of nanotubes prepared at 45 V was larger, the gravimetrical capacity was much higher for nanotubes prepared at 60 V because of the larger surface area exposed to the electrolyte. Gravimetrical capacity values exceed theoretical bulk capacity of anatase due to the surface storage of Li-ion. Diffusion coefficient of Li-ion was calculated to be between 5.9.10(-16) and 5.9.10(-15) cm(2) s(-1). (C) 2017 Elsevier B.V. All rights reserved.
T2  - Journal of Alloys and Compounds
T1  - Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology
VL  - 712
SP  - 90
EP  - 96
DO  - 10.1016/j.jallcom.2017.04.065
ER  - 
@article{
author = "Bratić, Milan and Jugović, Dragana and Mitrić, Miodrag and Cvjetićanin, Nikola",
year = "2017",
abstract = "Anatase TiO2 nanotube arrays of different morphology were prepared by a two-step process: anodic oxidation at voltages 20-60 V and subsequent annealing at 400 degrees C. By amplifying anodization voltage the inner diameter of nanotubes increased. At 60 V nanotubes changed the shape from cylindrical tube to truncated cone with elliptical opening. Electrochemical insertion of Li-ion in nanotubes was studied by cyclic voltammetry and galvanostatic charge-discharge experiments. The cyclovoltammetric response was fast for all nanotube arrays. The galvanostatic areal charge/discharge capacity of nanotube arrays increased with increasing anodizaton voltage. Although the mass of nanotubes prepared at 45 V was larger, the gravimetrical capacity was much higher for nanotubes prepared at 60 V because of the larger surface area exposed to the electrolyte. Gravimetrical capacity values exceed theoretical bulk capacity of anatase due to the surface storage of Li-ion. Diffusion coefficient of Li-ion was calculated to be between 5.9.10(-16) and 5.9.10(-15) cm(2) s(-1). (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Journal of Alloys and Compounds",
title = "Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology",
volume = "712",
pages = "90-96",
doi = "10.1016/j.jallcom.2017.04.065"
}
Bratić, M., Jugović, D., Mitrić, M.,& Cvjetićanin, N.. (2017). Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology. in Journal of Alloys and Compounds, 712, 90-96.
https://doi.org/10.1016/j.jallcom.2017.04.065
Bratić M, Jugović D, Mitrić M, Cvjetićanin N. Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology. in Journal of Alloys and Compounds. 2017;712:90-96.
doi:10.1016/j.jallcom.2017.04.065 .
Bratić, Milan, Jugović, Dragana, Mitrić, Miodrag, Cvjetićanin, Nikola, "Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology" in Journal of Alloys and Compounds, 712 (2017):90-96,
https://doi.org/10.1016/j.jallcom.2017.04.065 . .
10
7
10

Influence of annealing treatment on magnetic properties of Fe2O3/SiO2 and formation of epsilon-Fe2O3 phase

Nikolić, Violeta N.; Tadić, Marin; Panjan, Matjaž; Kopanja, Lazar; Cvjetićanin, Nikola; Spasojević, Vojislav

(2017)

TY  - JOUR
AU  - Nikolić, Violeta N.
AU  - Tadić, Marin
AU  - Panjan, Matjaž
AU  - Kopanja, Lazar
AU  - Cvjetićanin, Nikola
AU  - Spasojević, Vojislav
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1400
AB  - Magnetic properties of Fe2O3/SiO2 samples were studied after being produced by sol-gel synthesis and formation of epsilon-Fe2O3 polymorph. Samples were thermally treated, using different annealing temperatures and annealing times. The size and morphological characteristics of the iron oxide nanoparticles were examined using a TEM microscope. We used the ellipticity of shapes, which is a measure of how much the shape of a nanoparticle differs from a perfect ellipse, in order to quantitatively describe morphological properties of nanoparticles. Coercivity measurements were used to identify and monitor the formation of the epsilon-iron oxide phase during the thermal treatments (annealing). Coercivity values were in the range from 1.2 to 15.4 kOe, which is in accordance with previous experience regarding the existence of epsilon-Fe2O3. We have determined the optimal formation conditions for the epsilon-Fe2O3 polymorph (t=1050 degrees C for 7 h, H-c=15.4 kOe), as well as the narrow temperature interval (1050-1060 C) in which the polymorph abruptly vanished (H-c=2300 Oe), on the basis of results of the magnetic properties. The threshold temperature for the epsilon-Fe2O3 phase transformation was measured as 1060 degrees C. We found that different annealing temperatures and annealing times significantly affected magnetic properties of the examined samples.
T2  - Ceramics International
T1  - Influence of annealing treatment on magnetic properties of Fe2O3/SiO2 and formation of epsilon-Fe2O3 phase
VL  - 43
IS  - 3
SP  - 3147
EP  - 3155
DO  - 10.1016/j.ceramint.2016.11.132
ER  - 
@article{
author = "Nikolić, Violeta N. and Tadić, Marin and Panjan, Matjaž and Kopanja, Lazar and Cvjetićanin, Nikola and Spasojević, Vojislav",
year = "2017",
abstract = "Magnetic properties of Fe2O3/SiO2 samples were studied after being produced by sol-gel synthesis and formation of epsilon-Fe2O3 polymorph. Samples were thermally treated, using different annealing temperatures and annealing times. The size and morphological characteristics of the iron oxide nanoparticles were examined using a TEM microscope. We used the ellipticity of shapes, which is a measure of how much the shape of a nanoparticle differs from a perfect ellipse, in order to quantitatively describe morphological properties of nanoparticles. Coercivity measurements were used to identify and monitor the formation of the epsilon-iron oxide phase during the thermal treatments (annealing). Coercivity values were in the range from 1.2 to 15.4 kOe, which is in accordance with previous experience regarding the existence of epsilon-Fe2O3. We have determined the optimal formation conditions for the epsilon-Fe2O3 polymorph (t=1050 degrees C for 7 h, H-c=15.4 kOe), as well as the narrow temperature interval (1050-1060 C) in which the polymorph abruptly vanished (H-c=2300 Oe), on the basis of results of the magnetic properties. The threshold temperature for the epsilon-Fe2O3 phase transformation was measured as 1060 degrees C. We found that different annealing temperatures and annealing times significantly affected magnetic properties of the examined samples.",
journal = "Ceramics International",
title = "Influence of annealing treatment on magnetic properties of Fe2O3/SiO2 and formation of epsilon-Fe2O3 phase",
volume = "43",
number = "3",
pages = "3147-3155",
doi = "10.1016/j.ceramint.2016.11.132"
}
Nikolić, V. N., Tadić, M., Panjan, M., Kopanja, L., Cvjetićanin, N.,& Spasojević, V.. (2017). Influence of annealing treatment on magnetic properties of Fe2O3/SiO2 and formation of epsilon-Fe2O3 phase. in Ceramics International, 43(3), 3147-3155.
https://doi.org/10.1016/j.ceramint.2016.11.132
Nikolić VN, Tadić M, Panjan M, Kopanja L, Cvjetićanin N, Spasojević V. Influence of annealing treatment on magnetic properties of Fe2O3/SiO2 and formation of epsilon-Fe2O3 phase. in Ceramics International. 2017;43(3):3147-3155.
doi:10.1016/j.ceramint.2016.11.132 .
Nikolić, Violeta N., Tadić, Marin, Panjan, Matjaž, Kopanja, Lazar, Cvjetićanin, Nikola, Spasojević, Vojislav, "Influence of annealing treatment on magnetic properties of Fe2O3/SiO2 and formation of epsilon-Fe2O3 phase" in Ceramics International, 43, no. 3 (2017):3147-3155,
https://doi.org/10.1016/j.ceramint.2016.11.132 . .
39
28
39

The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Cvjetićanin, Nikola; Jokić, Bojan M.; Umićević, Ana; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2016)

TY  - CONF
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Cvjetićanin, Nikola
AU  - Jokić, Bojan M.
AU  - Umićević, Ana
AU  - Uskoković, Dragan
PY  - 2016
UR  - http://dais.sanu.ac.rs/123456789/898
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7555
AB  - Low intrinsic electronic conductivity is the main weakness of LiFePO4 for the use as cathode material in lithium ion batteries. Here is presented an experimental proof of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. Crystal structure refinements in the space group Pnma reveal that doping with fluorine ions preserves olivine structure with the reduction of both the lattice parameters and the antisite defect, and an increase of a crystallite size. A small amount of incorporated fluorine enhances electrical conductivity from 4.6 × 10-7 Scm-1 to 2.3 × 10-6 Scm-1 and has positive impact on the electrochemical performances. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) disclose differences between two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.
PB  - Belgrade : Materials Research Society of Serbia
C3  - YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : programme and the book of abstracts; September 5-10, Herceg Novi
T1  - The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder
SP  - 35
EP  - 35
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7555
ER  - 
@conference{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Cvjetićanin, Nikola and Jokić, Bojan M. and Umićević, Ana and Uskoković, Dragan",
year = "2016",
abstract = "Low intrinsic electronic conductivity is the main weakness of LiFePO4 for the use as cathode material in lithium ion batteries. Here is presented an experimental proof of the theoretical prediction that fluorine doping of LiFePO4 can enhance its electrical conductivity. LiFePO4 and fluorine-doped LiFePO4 olivine type, carbon-free powders are synthesized and examined. Crystal structure refinements in the space group Pnma reveal that doping with fluorine ions preserves olivine structure with the reduction of both the lattice parameters and the antisite defect, and an increase of a crystallite size. A small amount of incorporated fluorine enhances electrical conductivity from 4.6 × 10-7 Scm-1 to 2.3 × 10-6 Scm-1 and has positive impact on the electrochemical performances. Several spectroscopy techniques (Mössbauer, FTIR, and Raman) disclose differences between two powders and additionally support the findings of both the Rietveld refinement and the conductivity measurements.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : programme and the book of abstracts; September 5-10, Herceg Novi",
title = "The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder",
pages = "35-35",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7555"
}
Jugović, D., Mitrić, M., Milović, M., Cvjetićanin, N., Jokić, B. M., Umićević, A.,& Uskoković, D.. (2016). The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder. in YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : programme and the book of abstracts; September 5-10, Herceg Novi
Belgrade : Materials Research Society of Serbia., 35-35.
https://hdl.handle.net/21.15107/rcub_vinar_7555
Jugović D, Mitrić M, Milović M, Cvjetićanin N, Jokić BM, Umićević A, Uskoković D. The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder. in YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : programme and the book of abstracts; September 5-10, Herceg Novi. 2016;:35-35.
https://hdl.handle.net/21.15107/rcub_vinar_7555 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Cvjetićanin, Nikola, Jokić, Bojan M., Umićević, Ana, Uskoković, Dragan, "The influence of fluorine doping on the structural and the electrical properties of LiFePO4 powder" in YUCOMAT 2016 : 18th Annual Conference YUCOMAT 2016 : programme and the book of abstracts; September 5-10, Herceg Novi (2016):35-35,
https://hdl.handle.net/21.15107/rcub_vinar_7555 .

Structural and magnetic properties of hydrothermally synthesized beta-MnO2 and alpha-KxMnO2 nanorods

Barudžija, Tanja; Kusigerski, Vladan; Cvjetićanin, Nikola; Šorgić, Saša; Perović, Marija M.; Mitrić, Miodrag

(Elsevier, 2016)

TY  - JOUR
AU  - Barudžija, Tanja
AU  - Kusigerski, Vladan
AU  - Cvjetićanin, Nikola
AU  - Šorgić, Saša
AU  - Perović, Marija M.
AU  - Mitrić, Miodrag
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/920
AB  - Hydrothermal synthesis was applied for obtaining different manganese dioxide polymorphs whose morphology, structure and magnetic properties were thoroughly investigated. Variations in the synthesis pathways lead to the formation of tetragonal rutile-type beta-MnO2 and two tetragonal hollandite-type alpha-KxMnO2 samples with different concentration of potassium cations (x = 0.15 and 0.18). SEM images showed nanorod shape of all specimens, while microstructure characterization done by XRD measurements revealed that crystallites have an elongated rod-like shape and, hence, it confirmed the anisotropic morphology. Magnetic ordering of beta-MnO2 is antiferromagnetic below 93 K, while both alpha-KxMnO2 samples possess more complicated low-temperature behaviour of the reentrant spin-glass type: the onset of the spin-glass like state occurs at temperatures below the weak ferromagnetic ordering. (C) 2016 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural and magnetic properties of hydrothermally synthesized beta-MnO2 and alpha-KxMnO2 nanorods
VL  - 665
SP  - 261
EP  - 270
DO  - 10.1016/j.jallcom.2016.01.024
ER  - 
@article{
author = "Barudžija, Tanja and Kusigerski, Vladan and Cvjetićanin, Nikola and Šorgić, Saša and Perović, Marija M. and Mitrić, Miodrag",
year = "2016",
abstract = "Hydrothermal synthesis was applied for obtaining different manganese dioxide polymorphs whose morphology, structure and magnetic properties were thoroughly investigated. Variations in the synthesis pathways lead to the formation of tetragonal rutile-type beta-MnO2 and two tetragonal hollandite-type alpha-KxMnO2 samples with different concentration of potassium cations (x = 0.15 and 0.18). SEM images showed nanorod shape of all specimens, while microstructure characterization done by XRD measurements revealed that crystallites have an elongated rod-like shape and, hence, it confirmed the anisotropic morphology. Magnetic ordering of beta-MnO2 is antiferromagnetic below 93 K, while both alpha-KxMnO2 samples possess more complicated low-temperature behaviour of the reentrant spin-glass type: the onset of the spin-glass like state occurs at temperatures below the weak ferromagnetic ordering. (C) 2016 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural and magnetic properties of hydrothermally synthesized beta-MnO2 and alpha-KxMnO2 nanorods",
volume = "665",
pages = "261-270",
doi = "10.1016/j.jallcom.2016.01.024"
}
Barudžija, T., Kusigerski, V., Cvjetićanin, N., Šorgić, S., Perović, M. M.,& Mitrić, M.. (2016). Structural and magnetic properties of hydrothermally synthesized beta-MnO2 and alpha-KxMnO2 nanorods. in Journal of Alloys and Compounds
Elsevier., 665, 261-270.
https://doi.org/10.1016/j.jallcom.2016.01.024
Barudžija T, Kusigerski V, Cvjetićanin N, Šorgić S, Perović MM, Mitrić M. Structural and magnetic properties of hydrothermally synthesized beta-MnO2 and alpha-KxMnO2 nanorods. in Journal of Alloys and Compounds. 2016;665:261-270.
doi:10.1016/j.jallcom.2016.01.024 .
Barudžija, Tanja, Kusigerski, Vladan, Cvjetićanin, Nikola, Šorgić, Saša, Perović, Marija M., Mitrić, Miodrag, "Structural and magnetic properties of hydrothermally synthesized beta-MnO2 and alpha-KxMnO2 nanorods" in Journal of Alloys and Compounds, 665 (2016):261-270,
https://doi.org/10.1016/j.jallcom.2016.01.024 . .
22
18
24

Fluorine Doping of Layered NaxCoO2 Structure

Jugović, Dragana; Milović, Miloš; Mitrić, Miodrag; Cvjetićanin, Nikola; Avdeev, Max; Jokić, Bojan M.; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2015)

TY  - CONF
AU  - Jugović, Dragana
AU  - Milović, Miloš
AU  - Mitrić, Miodrag
AU  - Cvjetićanin, Nikola
AU  - Avdeev, Max
AU  - Jokić, Bojan M.
AU  - Uskoković, Dragan
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7543
AB  - The room temperature Na-ion secondary battery has been under focus lately due to its feasibility to compete against the already well-established Li-ion secondary battery. Transition metal oxides of general formula NaxMO2 have been investigated as potential cathode materials for sodium batteries. Layered NaxCoO2 is synthesized via solid-state method at 900 ºC in air atmosphere. Fluorine doping of the as-prepared powder is established by the use of ammonium hydrogen difluoride (NH4HF2) as a fluorinating agent. The fluorination takes place only at low temperature (200 ºC), while the treatment at higher temperatures (≥ 400 ºC) facilitates the formation of NaF. It is shown that various and controllable amounts of fluorine can be successfully incorporated into the structure. Finally, the effects of fluorine doping on both structural and electrochemical properties are examined.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts
T1  - Fluorine Doping of Layered NaxCoO2 Structure
SP  - 12
EP  - 12
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7543
ER  - 
@conference{
author = "Jugović, Dragana and Milović, Miloš and Mitrić, Miodrag and Cvjetićanin, Nikola and Avdeev, Max and Jokić, Bojan M. and Uskoković, Dragan",
year = "2015",
abstract = "The room temperature Na-ion secondary battery has been under focus lately due to its feasibility to compete against the already well-established Li-ion secondary battery. Transition metal oxides of general formula NaxMO2 have been investigated as potential cathode materials for sodium batteries. Layered NaxCoO2 is synthesized via solid-state method at 900 ºC in air atmosphere. Fluorine doping of the as-prepared powder is established by the use of ammonium hydrogen difluoride (NH4HF2) as a fluorinating agent. The fluorination takes place only at low temperature (200 ºC), while the treatment at higher temperatures (≥ 400 ºC) facilitates the formation of NaF. It is shown that various and controllable amounts of fluorine can be successfully incorporated into the structure. Finally, the effects of fluorine doping on both structural and electrochemical properties are examined.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts",
title = "Fluorine Doping of Layered NaxCoO2 Structure",
pages = "12-12",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7543"
}
Jugović, D., Milović, M., Mitrić, M., Cvjetićanin, N., Avdeev, M., Jokić, B. M.,& Uskoković, D.. (2015). Fluorine Doping of Layered NaxCoO2 Structure. in Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts
Belgrade : Materials Research Society of Serbia., 12-12.
https://hdl.handle.net/21.15107/rcub_vinar_7543
Jugović D, Milović M, Mitrić M, Cvjetićanin N, Avdeev M, Jokić BM, Uskoković D. Fluorine Doping of Layered NaxCoO2 Structure. in Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts. 2015;:12-12.
https://hdl.handle.net/21.15107/rcub_vinar_7543 .
Jugović, Dragana, Milović, Miloš, Mitrić, Miodrag, Cvjetićanin, Nikola, Avdeev, Max, Jokić, Bojan M., Uskoković, Dragan, "Fluorine Doping of Layered NaxCoO2 Structure" in Seventeenth Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts (2015):12-12,
https://hdl.handle.net/21.15107/rcub_vinar_7543 .

High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries

Milošević, Sanja S.; Stojković, Ivana; Mitrić, Miodrag; Cvjetićanin, Nikola

(2015)

TY  - JOUR
AU  - Milošević, Sanja S.
AU  - Stojković, Ivana
AU  - Mitrić, Miodrag
AU  - Cvjetićanin, Nikola
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/708
AB  - The VO2(B) was synthesized via a simple solvothermal route at 160 degrees C in ethanol. The initial discharge capacity of the VO2(B) anode, in saturated aqueous solution of LiNO3, was 177 mAh g(-1) at a current rate of 50 mA g(-1). After 50 cycles, the capacity fade was 4 %, but from 20th-50th cycle, no capacity drop was observed. The VO2(B) showed very good cyclability at a current rate of even 1000 mA g(-1) with initial discharge capacity of 92 mAh g(-1). The excellent electrochemical performance of VO2(B) was attributed to the stability of micro-nano structures to a repeated intercalation/deintercalation process, very good electronic conductivity as well as the very low charge transfer resistance in an aqueous electrolyte.
T2  - Journal of the Serbian Chemical Society
T1  - High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries
VL  - 80
IS  - 5
SP  - 685
EP  - 694
DO  - 10.2298/JSC140922128M
ER  - 
@article{
author = "Milošević, Sanja S. and Stojković, Ivana and Mitrić, Miodrag and Cvjetićanin, Nikola",
year = "2015",
abstract = "The VO2(B) was synthesized via a simple solvothermal route at 160 degrees C in ethanol. The initial discharge capacity of the VO2(B) anode, in saturated aqueous solution of LiNO3, was 177 mAh g(-1) at a current rate of 50 mA g(-1). After 50 cycles, the capacity fade was 4 %, but from 20th-50th cycle, no capacity drop was observed. The VO2(B) showed very good cyclability at a current rate of even 1000 mA g(-1) with initial discharge capacity of 92 mAh g(-1). The excellent electrochemical performance of VO2(B) was attributed to the stability of micro-nano structures to a repeated intercalation/deintercalation process, very good electronic conductivity as well as the very low charge transfer resistance in an aqueous electrolyte.",
journal = "Journal of the Serbian Chemical Society",
title = "High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries",
volume = "80",
number = "5",
pages = "685-694",
doi = "10.2298/JSC140922128M"
}
Milošević, S. S., Stojković, I., Mitrić, M.,& Cvjetićanin, N.. (2015). High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries. in Journal of the Serbian Chemical Society, 80(5), 685-694.
https://doi.org/10.2298/JSC140922128M
Milošević SS, Stojković I, Mitrić M, Cvjetićanin N. High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries. in Journal of the Serbian Chemical Society. 2015;80(5):685-694.
doi:10.2298/JSC140922128M .
Milošević, Sanja S., Stojković, Ivana, Mitrić, Miodrag, Cvjetićanin, Nikola, "High performance of solvothermally prepared VO2(B) as an anode for aqueous rechargeable lithium batteries" in Journal of the Serbian Chemical Society, 80, no. 5 (2015):685-694,
https://doi.org/10.2298/JSC140922128M . .
1
8
6
8

The use of various dicarboxylic acids as a carbon source for the preparation of LiFePO4/C composite

Kuzmanović, Maja D.; Jugović, Dragana; Mitrić, Miodrag; Jokić, Bojan M.; Cvjetićanin, Nikola; Uskoković, Dragan

(2015)

TY  - JOUR
AU  - Kuzmanović, Maja D.
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Jokić, Bojan M.
AU  - Cvjetićanin, Nikola
AU  - Uskoković, Dragan
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/255
AB  - Olivine-type LiFePO4 composite powders with carbon were synthesized by freeze drying and subsequent thermal annealing. The main purpose of the research is to explore how various dicarboxylic acids as carbon sources influence the electrochemical properties of the resulting composites. Three dicarboxylic acids (oxalic, malonic, and adipic) were used as a carbon source. The synthesis was followed by X-ray powder diffraction, scanning electron microscopy, particle-size analysis, and electrochemical experiments. It is shown that the amount of the in situ formed carbon depends on the thermal behaviour of the acids in inert atmosphere rather than on their carbon content. Cyclic voltammetry experiments and galvanostatic cycling illustrate the behaviour of different powders: the powder obtained with oxalic acid yields the highest discharge capacity at small currents, while the one obtained with adipic acid shows better high-current response. Malonic acid has turned out to be a poor carbon source and it consequently yields powder with poor electrochemical performance. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - The use of various dicarboxylic acids as a carbon source for the preparation of LiFePO4/C composite
VL  - 41
IS  - 5
SP  - 6753
EP  - 6758
DO  - 10.1016/j.ceramint.2015.01.121
ER  - 
@article{
author = "Kuzmanović, Maja D. and Jugović, Dragana and Mitrić, Miodrag and Jokić, Bojan M. and Cvjetićanin, Nikola and Uskoković, Dragan",
year = "2015",
abstract = "Olivine-type LiFePO4 composite powders with carbon were synthesized by freeze drying and subsequent thermal annealing. The main purpose of the research is to explore how various dicarboxylic acids as carbon sources influence the electrochemical properties of the resulting composites. Three dicarboxylic acids (oxalic, malonic, and adipic) were used as a carbon source. The synthesis was followed by X-ray powder diffraction, scanning electron microscopy, particle-size analysis, and electrochemical experiments. It is shown that the amount of the in situ formed carbon depends on the thermal behaviour of the acids in inert atmosphere rather than on their carbon content. Cyclic voltammetry experiments and galvanostatic cycling illustrate the behaviour of different powders: the powder obtained with oxalic acid yields the highest discharge capacity at small currents, while the one obtained with adipic acid shows better high-current response. Malonic acid has turned out to be a poor carbon source and it consequently yields powder with poor electrochemical performance. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "The use of various dicarboxylic acids as a carbon source for the preparation of LiFePO4/C composite",
volume = "41",
number = "5",
pages = "6753-6758",
doi = "10.1016/j.ceramint.2015.01.121"
}
Kuzmanović, M. D., Jugović, D., Mitrić, M., Jokić, B. M., Cvjetićanin, N.,& Uskoković, D.. (2015). The use of various dicarboxylic acids as a carbon source for the preparation of LiFePO4/C composite. in Ceramics International, 41(5), 6753-6758.
https://doi.org/10.1016/j.ceramint.2015.01.121
Kuzmanović MD, Jugović D, Mitrić M, Jokić BM, Cvjetićanin N, Uskoković D. The use of various dicarboxylic acids as a carbon source for the preparation of LiFePO4/C composite. in Ceramics International. 2015;41(5):6753-6758.
doi:10.1016/j.ceramint.2015.01.121 .
Kuzmanović, Maja D., Jugović, Dragana, Mitrić, Miodrag, Jokić, Bojan M., Cvjetićanin, Nikola, Uskoković, Dragan, "The use of various dicarboxylic acids as a carbon source for the preparation of LiFePO4/C composite" in Ceramics International, 41, no. 5 (2015):6753-6758,
https://doi.org/10.1016/j.ceramint.2015.01.121 . .
14
15
15

Synthesis of LiFePO4 by mechanical stressing and thermal annealing

Milović, Miloš; Jugović, Dragana; Mitrić, Miodrag; Cvjetićanin, Nikola; Mraković, Ana Đ.; Senna, Mamoru; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2014)

TY  - CONF
AU  - Milović, Miloš
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Cvjetićanin, Nikola
AU  - Mraković, Ana Đ.
AU  - Senna, Mamoru
AU  - Uskoković, Dragan
PY  - 2014
UR  - http://dais.sanu.ac.rs/123456789/582
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7485
AB  - Mechanical activation can be regarded as a multi-step process with changes in the energetic parameters and the amount of accumulated energy of solids in each step. Here we report the influence of mechanochemical processing on the synthesis of LiFePO4 powders. The different precursor powders were milled in a planetary mill by using WC vials and 5 mm balls made of the same material. A slightly reductive atmosphere (Ar + 5%H2) was used in both mechanical stressing and thermal annealing so as to prevent the oxidation of iron. All synthesis steps were followed by an X-ray diffractometry and FT-IR spectroscopy. The results were compared with previous findings of precipitated and annealed powder, without mechanochemical treatment.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts
T1  - Synthesis of LiFePO4 by mechanical stressing and thermal annealing
SP  - 62
EP  - 62
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7485
ER  - 
@conference{
author = "Milović, Miloš and Jugović, Dragana and Mitrić, Miodrag and Cvjetićanin, Nikola and Mraković, Ana Đ. and Senna, Mamoru and Uskoković, Dragan",
year = "2014",
abstract = "Mechanical activation can be regarded as a multi-step process with changes in the energetic parameters and the amount of accumulated energy of solids in each step. Here we report the influence of mechanochemical processing on the synthesis of LiFePO4 powders. The different precursor powders were milled in a planetary mill by using WC vials and 5 mm balls made of the same material. A slightly reductive atmosphere (Ar + 5%H2) was used in both mechanical stressing and thermal annealing so as to prevent the oxidation of iron. All synthesis steps were followed by an X-ray diffractometry and FT-IR spectroscopy. The results were compared with previous findings of precipitated and annealed powder, without mechanochemical treatment.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts",
title = "Synthesis of LiFePO4 by mechanical stressing and thermal annealing",
pages = "62-62",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7485"
}
Milović, M., Jugović, D., Mitrić, M., Cvjetićanin, N., Mraković, A. Đ., Senna, M.,& Uskoković, D.. (2014). Synthesis of LiFePO4 by mechanical stressing and thermal annealing. in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 62-62.
https://hdl.handle.net/21.15107/rcub_vinar_7485
Milović M, Jugović D, Mitrić M, Cvjetićanin N, Mraković AĐ, Senna M, Uskoković D. Synthesis of LiFePO4 by mechanical stressing and thermal annealing. in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts. 2014;:62-62.
https://hdl.handle.net/21.15107/rcub_vinar_7485 .
Milović, Miloš, Jugović, Dragana, Mitrić, Miodrag, Cvjetićanin, Nikola, Mraković, Ana Đ., Senna, Mamoru, Uskoković, Dragan, "Synthesis of LiFePO4 by mechanical stressing and thermal annealing" in The Sixteenth Annual Conference YUCOMAT 2014: Programme and the Book of Abstracts (2014):62-62,
https://hdl.handle.net/21.15107/rcub_vinar_7485 .

Crystal structure analysis and first principle investigation of F doping in LiFePO4

Milović, Miloš; Jugović, Dragana; Cvjetićanin, Nikola; Uskoković, Dragan; Milošević, Aleksandar S.; Popović, Zoran S.; Vukajlović, Filip R.

(2013)

TY  - JOUR
AU  - Milović, Miloš
AU  - Jugović, Dragana
AU  - Cvjetićanin, Nikola
AU  - Uskoković, Dragan
AU  - Milošević, Aleksandar S.
AU  - Popović, Zoran S.
AU  - Vukajlović, Filip R.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5624
AB  - This work presents the synthesis of F-doped LiFePO4/C composite by the specific modification of the recently suggested synthesis procedure based on an aqueous precipitation of precursor material in molten stearic acid, followed by a high temperature treatment. Besides the lattice parameters and the primitive cell volume reductions, compared to the undoped sample synthesized under the same conditions, the Rietveld refinement also shows that fluorine ions preferably occupy specific oxygen sites. Particularly, the best refinement is accomplished when fluorine ions occupy O(2) sites exclusively. By means of up-to-date electronic structure and total energy calculations this experimental finding is theoretically confirmed. Such fluorine doping also produces closing of the gap in the electronic structure and consequently better conductivity properties of the doped compound. In addition, the morphological and electrochemical performances of the synthesized powder are fully characterized. (C) 2013 Elsevier B.V. All rights reserved.
T2  - Journal of Power Sources
T1  - Crystal structure analysis and first principle investigation of F doping in LiFePO4
VL  - 241
SP  - 70
EP  - 79
DO  - 10.1016/j.jpowsour.2013.04.109
ER  - 
@article{
author = "Milović, Miloš and Jugović, Dragana and Cvjetićanin, Nikola and Uskoković, Dragan and Milošević, Aleksandar S. and Popović, Zoran S. and Vukajlović, Filip R.",
year = "2013",
abstract = "This work presents the synthesis of F-doped LiFePO4/C composite by the specific modification of the recently suggested synthesis procedure based on an aqueous precipitation of precursor material in molten stearic acid, followed by a high temperature treatment. Besides the lattice parameters and the primitive cell volume reductions, compared to the undoped sample synthesized under the same conditions, the Rietveld refinement also shows that fluorine ions preferably occupy specific oxygen sites. Particularly, the best refinement is accomplished when fluorine ions occupy O(2) sites exclusively. By means of up-to-date electronic structure and total energy calculations this experimental finding is theoretically confirmed. Such fluorine doping also produces closing of the gap in the electronic structure and consequently better conductivity properties of the doped compound. In addition, the morphological and electrochemical performances of the synthesized powder are fully characterized. (C) 2013 Elsevier B.V. All rights reserved.",
journal = "Journal of Power Sources",
title = "Crystal structure analysis and first principle investigation of F doping in LiFePO4",
volume = "241",
pages = "70-79",
doi = "10.1016/j.jpowsour.2013.04.109"
}
Milović, M., Jugović, D., Cvjetićanin, N., Uskoković, D., Milošević, A. S., Popović, Z. S.,& Vukajlović, F. R.. (2013). Crystal structure analysis and first principle investigation of F doping in LiFePO4. in Journal of Power Sources, 241, 70-79.
https://doi.org/10.1016/j.jpowsour.2013.04.109
Milović M, Jugović D, Cvjetićanin N, Uskoković D, Milošević AS, Popović ZS, Vukajlović FR. Crystal structure analysis and first principle investigation of F doping in LiFePO4. in Journal of Power Sources. 2013;241:70-79.
doi:10.1016/j.jpowsour.2013.04.109 .
Milović, Miloš, Jugović, Dragana, Cvjetićanin, Nikola, Uskoković, Dragan, Milošević, Aleksandar S., Popović, Zoran S., Vukajlović, Filip R., "Crystal structure analysis and first principle investigation of F doping in LiFePO4" in Journal of Power Sources, 241 (2013):70-79,
https://doi.org/10.1016/j.jpowsour.2013.04.109 . .
41
33
42

Synthesis of f-doped LiFePO4 via precipitation method

Milović, Miloš; Vukajlović, Filip R.; Jugović, Dragana; Mitrić, Miodrag; Jokić, Bojan M.; Cvjetićanin, Nikola; Milošević, Aleksandar S.; Popović, Zoran S.; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2013)

TY  - CONF
AU  - Milović, Miloš
AU  - Vukajlović, Filip R.
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Jokić, Bojan M.
AU  - Cvjetićanin, Nikola
AU  - Milošević, Aleksandar S.
AU  - Popović, Zoran S.
AU  - Uskoković, Dragan
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/399
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7418
AB  - Fluorine-doped, olivine-structured LiFePO4 suitable for cathode material in rechargeable lithium batteries was prepared by aqueous precipitation followed by high temperature treatment at 700°C under slightly reductive atmosphere (Ar+5%H2). The starting materials were equimolar quantities of (NH4)2HPO4, FeSO4·7H2O and LiF. LiF served as both lithium and fluorine source. Besides the lattice parameters and the primitive cell volume reductions, compared to the undoped sample synthesized under the same conditions using LiNO3 as lithium source, the Rietveld refinement also shows that fluorine ions preferably occupy specific oxygen sites. Particularly, the best refinement is accomplished when fluorine ions occupy O(2) sites exclusively. By means of up-to-date electronic structure and total energy calculations this experimental finding is theoretically confirmed. Such fluorine doping also produces closing of the gap in the electronic structure and consequently better conductivity properties of the doped compound. In addition, the morphological and electrochemical performances of the synthesized powders are fully characterized.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
T1  - Synthesis of f-doped LiFePO4 via precipitation method
SP  - 75
EP  - 75
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7418
ER  - 
@conference{
author = "Milović, Miloš and Vukajlović, Filip R. and Jugović, Dragana and Mitrić, Miodrag and Jokić, Bojan M. and Cvjetićanin, Nikola and Milošević, Aleksandar S. and Popović, Zoran S. and Uskoković, Dragan",
year = "2013",
abstract = "Fluorine-doped, olivine-structured LiFePO4 suitable for cathode material in rechargeable lithium batteries was prepared by aqueous precipitation followed by high temperature treatment at 700°C under slightly reductive atmosphere (Ar+5%H2). The starting materials were equimolar quantities of (NH4)2HPO4, FeSO4·7H2O and LiF. LiF served as both lithium and fluorine source. Besides the lattice parameters and the primitive cell volume reductions, compared to the undoped sample synthesized under the same conditions using LiNO3 as lithium source, the Rietveld refinement also shows that fluorine ions preferably occupy specific oxygen sites. Particularly, the best refinement is accomplished when fluorine ions occupy O(2) sites exclusively. By means of up-to-date electronic structure and total energy calculations this experimental finding is theoretically confirmed. Such fluorine doping also produces closing of the gap in the electronic structure and consequently better conductivity properties of the doped compound. In addition, the morphological and electrochemical performances of the synthesized powders are fully characterized.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts",
title = "Synthesis of f-doped LiFePO4 via precipitation method",
pages = "75-75",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7418"
}
Milović, M., Vukajlović, F. R., Jugović, D., Mitrić, M., Jokić, B. M., Cvjetićanin, N., Milošević, A. S., Popović, Z. S.,& Uskoković, D.. (2013). Synthesis of f-doped LiFePO4 via precipitation method. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 75-75.
https://hdl.handle.net/21.15107/rcub_vinar_7418
Milović M, Vukajlović FR, Jugović D, Mitrić M, Jokić BM, Cvjetićanin N, Milošević AS, Popović ZS, Uskoković D. Synthesis of f-doped LiFePO4 via precipitation method. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts. 2013;:75-75.
https://hdl.handle.net/21.15107/rcub_vinar_7418 .
Milović, Miloš, Vukajlović, Filip R., Jugović, Dragana, Mitrić, Miodrag, Jokić, Bojan M., Cvjetićanin, Nikola, Milošević, Aleksandar S., Popović, Zoran S., Uskoković, Dragan, "Synthesis of f-doped LiFePO4 via precipitation method" in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts (2013):75-75,
https://hdl.handle.net/21.15107/rcub_vinar_7418 .

Freeze-drying method for LiFePO4/C composite processing

Kuzmanović, Maja D.; Jugović, Dragana; Mitrić, Miodrag; Jokić, Bojan M.; Cvjetićanin, Nikola; Uskoković, Dragan

(Belgrade : Institute of Technical Sciences of SASA, 2013)

TY  - CONF
AU  - Kuzmanović, Maja D.
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Jokić, Bojan M.
AU  - Cvjetićanin, Nikola
AU  - Uskoković, Dragan
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/445
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7441
AB  - Based on its high capacity, stability, low toxicity and low cost of raw materials, phosphoolivine LiFePO4 became a material of great interest for Li-ion battery application. Synthesis of LiFePO4/C cathode material was performed by freeze-drying method using different organic acids as carbon source. Freeze-drying process consists of freezing of a precursor solution, elimination of solvent by sublimation (vacuum drying) and final calcinations of as-dried powder under slightly reductive atmosphere. The main advantage of this synthesis method is possibility of introducing a carbon source and mixing of reactants at atomic level which provides homogeneity of precursor solution. Synthesized materials were characterized by X-ray powder diffraction, scanning electron microscopy, particle size analyzer and galvanostatic charging/discharging.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia
T1  - Freeze-drying method for LiFePO4/C composite processing
SP  - 33
EP  - 33
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7441
ER  - 
@conference{
author = "Kuzmanović, Maja D. and Jugović, Dragana and Mitrić, Miodrag and Jokić, Bojan M. and Cvjetićanin, Nikola and Uskoković, Dragan",
year = "2013",
abstract = "Based on its high capacity, stability, low toxicity and low cost of raw materials, phosphoolivine LiFePO4 became a material of great interest for Li-ion battery application. Synthesis of LiFePO4/C cathode material was performed by freeze-drying method using different organic acids as carbon source. Freeze-drying process consists of freezing of a precursor solution, elimination of solvent by sublimation (vacuum drying) and final calcinations of as-dried powder under slightly reductive atmosphere. The main advantage of this synthesis method is possibility of introducing a carbon source and mixing of reactants at atomic level which provides homogeneity of precursor solution. Synthesized materials were characterized by X-ray powder diffraction, scanning electron microscopy, particle size analyzer and galvanostatic charging/discharging.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia",
title = "Freeze-drying method for LiFePO4/C composite processing",
pages = "33-33",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7441"
}
Kuzmanović, M. D., Jugović, D., Mitrić, M., Jokić, B. M., Cvjetićanin, N.,& Uskoković, D.. (2013). Freeze-drying method for LiFePO4/C composite processing. in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 33-33.
https://hdl.handle.net/21.15107/rcub_vinar_7441
Kuzmanović MD, Jugović D, Mitrić M, Jokić BM, Cvjetićanin N, Uskoković D. Freeze-drying method for LiFePO4/C composite processing. in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia. 2013;:33-33.
https://hdl.handle.net/21.15107/rcub_vinar_7441 .
Kuzmanović, Maja D., Jugović, Dragana, Mitrić, Miodrag, Jokić, Bojan M., Cvjetićanin, Nikola, Uskoković, Dragan, "Freeze-drying method for LiFePO4/C composite processing" in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia (2013):33-33,
https://hdl.handle.net/21.15107/rcub_vinar_7441 .

Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride

Milošević, Sanja S.; Rašković-Lovre, Željka; Kurko, Sandra V.; Vujasin, Radojka; Cvjetićanin, Nikola; Matović, Ljiljana; Grbović-Novaković, Jasmina

(2013)

TY  - JOUR
AU  - Milošević, Sanja S.
AU  - Rašković-Lovre, Željka
AU  - Kurko, Sandra V.
AU  - Vujasin, Radojka
AU  - Cvjetićanin, Nikola
AU  - Matović, Ljiljana
AU  - Grbović-Novaković, Jasmina
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5324
AB  - The hydrogen desorption properties and kinetics of MgH2-VO2 composite prepared by mechanical milling of MgH2 and VO2 have been investigated. Structural characterization of produced nanocomposite was done by X-ray powder diffraction (XRD), particle size analysis and scanning electron microscopy (SEM). The structure and morphology of the composite have been correlated with hydrogen desorption properties investigated by differential thermal analysis (DTA). It has been shown that short mechanical milling of nanostructured VO2 and MgH2 leads to decrease of hydrogen desorption temperature of MgH2 by 80 K. The mechanism of desorption has been changed from phase boundary reaction, spherical symmetry for untreated MgH2 to phase boundary reaction, cylindrical symmetry for the composite material. The activation energy for desorption has been reduced by adding VO2 ceramics as a catalyst. (C) 2012 Elsevier Ltd and, Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride
VL  - 39
IS  - 1
SP  - 51
EP  - 56
DO  - 10.1016/j.ceramint.2012.05.091
ER  - 
@article{
author = "Milošević, Sanja S. and Rašković-Lovre, Željka and Kurko, Sandra V. and Vujasin, Radojka and Cvjetićanin, Nikola and Matović, Ljiljana and Grbović-Novaković, Jasmina",
year = "2013",
abstract = "The hydrogen desorption properties and kinetics of MgH2-VO2 composite prepared by mechanical milling of MgH2 and VO2 have been investigated. Structural characterization of produced nanocomposite was done by X-ray powder diffraction (XRD), particle size analysis and scanning electron microscopy (SEM). The structure and morphology of the composite have been correlated with hydrogen desorption properties investigated by differential thermal analysis (DTA). It has been shown that short mechanical milling of nanostructured VO2 and MgH2 leads to decrease of hydrogen desorption temperature of MgH2 by 80 K. The mechanism of desorption has been changed from phase boundary reaction, spherical symmetry for untreated MgH2 to phase boundary reaction, cylindrical symmetry for the composite material. The activation energy for desorption has been reduced by adding VO2 ceramics as a catalyst. (C) 2012 Elsevier Ltd and, Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride",
volume = "39",
number = "1",
pages = "51-56",
doi = "10.1016/j.ceramint.2012.05.091"
}
Milošević, S. S., Rašković-Lovre, Ž., Kurko, S. V., Vujasin, R., Cvjetićanin, N., Matović, L.,& Grbović-Novaković, J.. (2013). Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride. in Ceramics International, 39(1), 51-56.
https://doi.org/10.1016/j.ceramint.2012.05.091
Milošević SS, Rašković-Lovre Ž, Kurko SV, Vujasin R, Cvjetićanin N, Matović L, Grbović-Novaković J. Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride. in Ceramics International. 2013;39(1):51-56.
doi:10.1016/j.ceramint.2012.05.091 .
Milošević, Sanja S., Rašković-Lovre, Željka, Kurko, Sandra V., Vujasin, Radojka, Cvjetićanin, Nikola, Matović, Ljiljana, Grbović-Novaković, Jasmina, "Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride" in Ceramics International, 39, no. 1 (2013):51-56,
https://doi.org/10.1016/j.ceramint.2012.05.091 . .
26
22
24

Carbon coated LiFePO4 cathode material obtained by freeze-drying method

Kuzmanović, Maja D.; Jugović, Dragana; Mitrić, Miodrag; Jokić, Bojan M.; Cvjetićanin, Nikola; Uskoković, Dragan

(Belgrade : Materials Research Society of Serbia, 2013)

TY  - CONF
AU  - Kuzmanović, Maja D.
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Jokić, Bojan M.
AU  - Cvjetićanin, Nikola
AU  - Uskoković, Dragan
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/395
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7417
AB  - One of the most perspective cathode materials for the application in the Li-ion batteries is LiFePO4. It has high theoretical specific capacity, good cycle life and technically suitable flat voltage of 3.45 V versus Li. However, its main disadvantages are low electronic and ionic conductivities which can be overcome by particle size minimization and/or carbon coating. Here is presented the freeze-drying method for the preparation of carbon coated LiFePO4 particles. It involves freezing of a precursor solution, vacuum drying and final calcination of as-dried powder under slightly reductive atmosphere. The main advantage of this preparation process is mixing at the atomic level which provides more homogeneous precursor. Water solutions containing Li+,PO4 3- and Fe2+ ions with the addition of various organic compounds as a carbon source were used as the precursor solutions. The as-prepared powders were fully characterized by means of X-ray powder diffraction, scanning electron microscopy, particle size analyzer and galvanostatic cycling.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
T1  - Carbon coated LiFePO4 cathode material obtained by freeze-drying method
SP  - 76
EP  - 76
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7417
ER  - 
@conference{
author = "Kuzmanović, Maja D. and Jugović, Dragana and Mitrić, Miodrag and Jokić, Bojan M. and Cvjetićanin, Nikola and Uskoković, Dragan",
year = "2013",
abstract = "One of the most perspective cathode materials for the application in the Li-ion batteries is LiFePO4. It has high theoretical specific capacity, good cycle life and technically suitable flat voltage of 3.45 V versus Li. However, its main disadvantages are low electronic and ionic conductivities which can be overcome by particle size minimization and/or carbon coating. Here is presented the freeze-drying method for the preparation of carbon coated LiFePO4 particles. It involves freezing of a precursor solution, vacuum drying and final calcination of as-dried powder under slightly reductive atmosphere. The main advantage of this preparation process is mixing at the atomic level which provides more homogeneous precursor. Water solutions containing Li+,PO4 3- and Fe2+ ions with the addition of various organic compounds as a carbon source were used as the precursor solutions. The as-prepared powders were fully characterized by means of X-ray powder diffraction, scanning electron microscopy, particle size analyzer and galvanostatic cycling.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts",
title = "Carbon coated LiFePO4 cathode material obtained by freeze-drying method",
pages = "76-76",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7417"
}
Kuzmanović, M. D., Jugović, D., Mitrić, M., Jokić, B. M., Cvjetićanin, N.,& Uskoković, D.. (2013). Carbon coated LiFePO4 cathode material obtained by freeze-drying method. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 76-76.
https://hdl.handle.net/21.15107/rcub_vinar_7417
Kuzmanović MD, Jugović D, Mitrić M, Jokić BM, Cvjetićanin N, Uskoković D. Carbon coated LiFePO4 cathode material obtained by freeze-drying method. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts. 2013;:76-76.
https://hdl.handle.net/21.15107/rcub_vinar_7417 .
Kuzmanović, Maja D., Jugović, Dragana, Mitrić, Miodrag, Jokić, Bojan M., Cvjetićanin, Nikola, Uskoković, Dragan, "Carbon coated LiFePO4 cathode material obtained by freeze-drying method" in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts (2013):76-76,
https://hdl.handle.net/21.15107/rcub_vinar_7417 .

The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte

Vujković, Milica; Jugović, Dragana; Mitrić, Miodrag; Stojković-Simatović, Ivana; Cvjetićanin, Nikola; Mentus, Slavko V.

(Belgrade : Materials Research Society of Serbia, 2013)

TY  - CONF
AU  - Vujković, Milica
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Stojković-Simatović, Ivana
AU  - Cvjetićanin, Nikola
AU  - Mentus, Slavko V.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/407
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7423
AB  - The simple and fast (malonic acid+glycine)-assisted gel-combustion process, followed by a heat treatment at 750oC under reductive atmosphere, is found to be a very effective way for the synthesis of (V-doped LiFePO4)/C composites. The Rietveld refinement confirms that vanadium incorporation into olivine structure was accompanied by the formation of iron phosphide conducting phase. The coulombic capacity and rate capability of (V-doped LiFePO4)/C composite, in both organic and aqueous electrolyte solutions, were significantly improved relative to an undoped sample, as revealed by both galvanostatic cycling and cyclic voltammetry. The average discharging capacities of ~5mol.%V-doped LiFePO4/C composite in an aqueous LiNO3 solution were 91, 73 and 35 mAh g-1 at 1, 10 and 100 C, respectively, with no perceivable capacity fade upon 100 charging/discharging cycles.
PB  - Belgrade : Materials Research Society of Serbia
C3  - The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
T1  - The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte
SP  - 101
EP  - 101
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7423
ER  - 
@conference{
author = "Vujković, Milica and Jugović, Dragana and Mitrić, Miodrag and Stojković-Simatović, Ivana and Cvjetićanin, Nikola and Mentus, Slavko V.",
year = "2013",
abstract = "The simple and fast (malonic acid+glycine)-assisted gel-combustion process, followed by a heat treatment at 750oC under reductive atmosphere, is found to be a very effective way for the synthesis of (V-doped LiFePO4)/C composites. The Rietveld refinement confirms that vanadium incorporation into olivine structure was accompanied by the formation of iron phosphide conducting phase. The coulombic capacity and rate capability of (V-doped LiFePO4)/C composite, in both organic and aqueous electrolyte solutions, were significantly improved relative to an undoped sample, as revealed by both galvanostatic cycling and cyclic voltammetry. The average discharging capacities of ~5mol.%V-doped LiFePO4/C composite in an aqueous LiNO3 solution were 91, 73 and 35 mAh g-1 at 1, 10 and 100 C, respectively, with no perceivable capacity fade upon 100 charging/discharging cycles.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts",
title = "The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte",
pages = "101-101",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7423"
}
Vujković, M., Jugović, D., Mitrić, M., Stojković-Simatović, I., Cvjetićanin, N.,& Mentus, S. V.. (2013). The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts
Belgrade : Materials Research Society of Serbia., 101-101.
https://hdl.handle.net/21.15107/rcub_vinar_7423
Vujković M, Jugović D, Mitrić M, Stojković-Simatović I, Cvjetićanin N, Mentus SV. The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte. in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts. 2013;:101-101.
https://hdl.handle.net/21.15107/rcub_vinar_7423 .
Vujković, Milica, Jugović, Dragana, Mitrić, Miodrag, Stojković-Simatović, Ivana, Cvjetićanin, Nikola, Mentus, Slavko V., "The incorporation of vanadium into olivine LiFePO4/C: improvement of lithium intercalation from both organic and aqueous electrolyte" in The Fifteenth Annual Conference YUCOMAT 2013: Programme and the Book of Abstracts (2013):101-101,
https://hdl.handle.net/21.15107/rcub_vinar_7423 .

Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance

Vujković, Milica; Stojković, Ivana; Mitrić, Miodrag; Mentus, Slavko V.; Cvjetićanin, Nikola

(2013)

TY  - JOUR
AU  - Vujković, Milica
AU  - Stojković, Ivana
AU  - Mitrić, Miodrag
AU  - Mentus, Slavko V.
AU  - Cvjetićanin, Nikola
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5356
AB  - Li4Ti5O12/C composites with low (3 wt.%) and high (33 wt.%) carbon black content as well as carbon-free Li4Ti5O12 were prepared in two steps under identical conditions: hydrothermal reaction at 130 degrees C and post-calcination at 400 degrees C. The X-ray diffraction experiments confirmed the spinet structure of Li4Ti5O12 in all samples. The carbon content altered significantly the morphology of obtained micro/nanoparticles. The Li4Ti5O12/C composite with the high carbon content showed the highest electrical conductivity (2.0 S cm(-1)), and displayed also extraordinary electrochemical performance: the cyclovoltammograms consisted of well defined reversible redox peaks at a scan rate as high as 10 mV s(-1), while, by galvanostatic cycling, the coulombic capacity of 150 mAh g(-1) was evidenced at a discharging rate of 10 C. (c) 2012 Elsevier Ltd. All rights reserved.
T2  - Materials Research Bulletin
T1  - Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance
VL  - 48
IS  - 2
SP  - 218
EP  - 223
DO  - 10.1016/j.materresbull.2012.09.071
ER  - 
@article{
author = "Vujković, Milica and Stojković, Ivana and Mitrić, Miodrag and Mentus, Slavko V. and Cvjetićanin, Nikola",
year = "2013",
abstract = "Li4Ti5O12/C composites with low (3 wt.%) and high (33 wt.%) carbon black content as well as carbon-free Li4Ti5O12 were prepared in two steps under identical conditions: hydrothermal reaction at 130 degrees C and post-calcination at 400 degrees C. The X-ray diffraction experiments confirmed the spinet structure of Li4Ti5O12 in all samples. The carbon content altered significantly the morphology of obtained micro/nanoparticles. The Li4Ti5O12/C composite with the high carbon content showed the highest electrical conductivity (2.0 S cm(-1)), and displayed also extraordinary electrochemical performance: the cyclovoltammograms consisted of well defined reversible redox peaks at a scan rate as high as 10 mV s(-1), while, by galvanostatic cycling, the coulombic capacity of 150 mAh g(-1) was evidenced at a discharging rate of 10 C. (c) 2012 Elsevier Ltd. All rights reserved.",
journal = "Materials Research Bulletin",
title = "Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance",
volume = "48",
number = "2",
pages = "218-223",
doi = "10.1016/j.materresbull.2012.09.071"
}
Vujković, M., Stojković, I., Mitrić, M., Mentus, S. V.,& Cvjetićanin, N.. (2013). Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance. in Materials Research Bulletin, 48(2), 218-223.
https://doi.org/10.1016/j.materresbull.2012.09.071
Vujković M, Stojković I, Mitrić M, Mentus SV, Cvjetićanin N. Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance. in Materials Research Bulletin. 2013;48(2):218-223.
doi:10.1016/j.materresbull.2012.09.071 .
Vujković, Milica, Stojković, Ivana, Mitrić, Miodrag, Mentus, Slavko V., Cvjetićanin, Nikola, "Hydrothermal synthesis of Li4Ti5O12/C nanostructured composites: Morphology and electrochemical performance" in Materials Research Bulletin, 48, no. 2 (2013):218-223,
https://doi.org/10.1016/j.materresbull.2012.09.071 . .
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The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions

Vujković, Milica; Jugović, Dragana; Mitrić, Miodrag; Stojković, Ivana; Cvjetićanin, Nikola; Mentus, Slavko V.

(2013)

TY  - JOUR
AU  - Vujković, Milica
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Stojković, Ivana
AU  - Cvjetićanin, Nikola
AU  - Mentus, Slavko V.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5784
AB  - The nitrate-(glycine + malonic acid)-assisted gel-combustion process, followed by a heat treatment at 750 degrees C under reductive atmosphere, was used as a fast and effective way to synthesize vanadium doped olivine incorporated in carbon matrix, of general formula LiFe(1-x)VxPO4/C. The two-phased Rietveld refinement confirmed that vanadium incorporation into olivine structure was complete. The heating under reduction atmosphere caused the formation of iron phosphide to some extent, the concentration was determined by Rietveld analysis. The capacity and rate capability of these composites were tested by both cyclic voltammetry and galvanostatic cycling. Specifically, the average discharging capacities of the composite with x=0.055, determined in an saturated aqueous LiNO3 solution equilibrated with air, at the rates of 1, 10 and 100 C, amounted to 91, 73 and 35 mAh g(-1), respectively, with no perceivable capacity fade. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions
VL  - 109
SP  - 835
EP  - 842
DO  - 10.1016/j.electacta.2013.07.219
ER  - 
@article{
author = "Vujković, Milica and Jugović, Dragana and Mitrić, Miodrag and Stojković, Ivana and Cvjetićanin, Nikola and Mentus, Slavko V.",
year = "2013",
abstract = "The nitrate-(glycine + malonic acid)-assisted gel-combustion process, followed by a heat treatment at 750 degrees C under reductive atmosphere, was used as a fast and effective way to synthesize vanadium doped olivine incorporated in carbon matrix, of general formula LiFe(1-x)VxPO4/C. The two-phased Rietveld refinement confirmed that vanadium incorporation into olivine structure was complete. The heating under reduction atmosphere caused the formation of iron phosphide to some extent, the concentration was determined by Rietveld analysis. The capacity and rate capability of these composites were tested by both cyclic voltammetry and galvanostatic cycling. Specifically, the average discharging capacities of the composite with x=0.055, determined in an saturated aqueous LiNO3 solution equilibrated with air, at the rates of 1, 10 and 100 C, amounted to 91, 73 and 35 mAh g(-1), respectively, with no perceivable capacity fade. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions",
volume = "109",
pages = "835-842",
doi = "10.1016/j.electacta.2013.07.219"
}
Vujković, M., Jugović, D., Mitrić, M., Stojković, I., Cvjetićanin, N.,& Mentus, S. V.. (2013). The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions. in Electrochimica Acta, 109, 835-842.
https://doi.org/10.1016/j.electacta.2013.07.219
Vujković M, Jugović D, Mitrić M, Stojković I, Cvjetićanin N, Mentus SV. The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions. in Electrochimica Acta. 2013;109:835-842.
doi:10.1016/j.electacta.2013.07.219 .
Vujković, Milica, Jugović, Dragana, Mitrić, Miodrag, Stojković, Ivana, Cvjetićanin, Nikola, Mentus, Slavko V., "The LiFe(1-x)VxPO4/C composite synthesized by gel-combustion method, with improved rate capability and cycle life in aerated aqueous solutions" in Electrochimica Acta, 109 (2013):835-842,
https://doi.org/10.1016/j.electacta.2013.07.219 . .
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Synthesis of hematite and iron oxyhydroxide nanocrystals by precipitation of Fe3+ ions inside oleic acid micelles

Jović, Nataša G.; Cvjetićanin, Nikola; Babić-Stojić, Branka S.; Makovec, Darko; Jokanović, Vukoman R.

(2013)

TY  - JOUR
AU  - Jović, Nataša G.
AU  - Cvjetićanin, Nikola
AU  - Babić-Stojić, Branka S.
AU  - Makovec, Darko
AU  - Jokanović, Vukoman R.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5499
AB  - alpha-Fe2O3 nanospheres with diameters of 20-40 nm and FeOOH nanorods with diameters of 150-200 nm and lengths of 0.5-1.0 mu m were synthesized via hydrolysis of Fe(NO3)(3) and FeCl3 solutions, respectively, in the presence of urea and oleic acid, under reflux at temperature similar to 90 degrees C for 8 h. The molar ratio of Fe3+ ions and urea were changed until pure phases have been obtained. The key parameter of the synthesis which provides pure hematite and beta-FeOOH phases was the pH. The samples were characterized by X-ray powder diffraction, transmission electron microscopy and Mossbauer spectroscopy. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Synthesis of hematite and iron oxyhydroxide nanocrystals by precipitation of Fe3+ ions inside oleic acid micelles
VL  - 39
IS  - 5
SP  - 5659
EP  - 5665
DO  - 10.1016/j.ceramint.2012.12.082
ER  - 
@article{
author = "Jović, Nataša G. and Cvjetićanin, Nikola and Babić-Stojić, Branka S. and Makovec, Darko and Jokanović, Vukoman R.",
year = "2013",
abstract = "alpha-Fe2O3 nanospheres with diameters of 20-40 nm and FeOOH nanorods with diameters of 150-200 nm and lengths of 0.5-1.0 mu m were synthesized via hydrolysis of Fe(NO3)(3) and FeCl3 solutions, respectively, in the presence of urea and oleic acid, under reflux at temperature similar to 90 degrees C for 8 h. The molar ratio of Fe3+ ions and urea were changed until pure phases have been obtained. The key parameter of the synthesis which provides pure hematite and beta-FeOOH phases was the pH. The samples were characterized by X-ray powder diffraction, transmission electron microscopy and Mossbauer spectroscopy. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Synthesis of hematite and iron oxyhydroxide nanocrystals by precipitation of Fe3+ ions inside oleic acid micelles",
volume = "39",
number = "5",
pages = "5659-5665",
doi = "10.1016/j.ceramint.2012.12.082"
}
Jović, N. G., Cvjetićanin, N., Babić-Stojić, B. S., Makovec, D.,& Jokanović, V. R.. (2013). Synthesis of hematite and iron oxyhydroxide nanocrystals by precipitation of Fe3+ ions inside oleic acid micelles. in Ceramics International, 39(5), 5659-5665.
https://doi.org/10.1016/j.ceramint.2012.12.082
Jović NG, Cvjetićanin N, Babić-Stojić BS, Makovec D, Jokanović VR. Synthesis of hematite and iron oxyhydroxide nanocrystals by precipitation of Fe3+ ions inside oleic acid micelles. in Ceramics International. 2013;39(5):5659-5665.
doi:10.1016/j.ceramint.2012.12.082 .
Jović, Nataša G., Cvjetićanin, Nikola, Babić-Stojić, Branka S., Makovec, Darko, Jokanović, Vukoman R., "Synthesis of hematite and iron oxyhydroxide nanocrystals by precipitation of Fe3+ ions inside oleic acid micelles" in Ceramics International, 39, no. 5 (2013):5659-5665,
https://doi.org/10.1016/j.ceramint.2012.12.082 . .
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The simple one-step solvothermal synthesis of nanostructurated VO2(B)

Milošević, Sanja S.; Stojković, Ivana; Kurko, Sandra V.; Grbović-Novaković, Jasmina; Cvjetićanin, Nikola

(2012)

TY  - JOUR
AU  - Milošević, Sanja S.
AU  - Stojković, Ivana
AU  - Kurko, Sandra V.
AU  - Grbović-Novaković, Jasmina
AU  - Cvjetićanin, Nikola
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4747
AB  - VO2(B) has been successfully synthesized by simple, facile and environmental friendly one-step solvothermal method using V2O5 and ethanol as a starting agent. Obtained micrometer-sized powder was composed from mutually welded nanosized rod-like, flat and snowflake structures. VO2(B) powder was tested for possible application as anode material for aqueous lithium ion batteries. Lithium intercalation/deintercalation reaction has been carried out by cyclic voltammetry in a saturated aqueous solution of LiNO3. At scan rate of 10 mV s(-1) very stable cyclic performance of such obtained VO2 was established with discharge capacity around 184 mAh g(-1). (C) 2011 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - The simple one-step solvothermal synthesis of nanostructurated VO2(B)
VL  - 38
IS  - 3
SP  - 2313
EP  - 2317
DO  - 10.1016/j.ceramint.2011.11.001
ER  - 
@article{
author = "Milošević, Sanja S. and Stojković, Ivana and Kurko, Sandra V. and Grbović-Novaković, Jasmina and Cvjetićanin, Nikola",
year = "2012",
abstract = "VO2(B) has been successfully synthesized by simple, facile and environmental friendly one-step solvothermal method using V2O5 and ethanol as a starting agent. Obtained micrometer-sized powder was composed from mutually welded nanosized rod-like, flat and snowflake structures. VO2(B) powder was tested for possible application as anode material for aqueous lithium ion batteries. Lithium intercalation/deintercalation reaction has been carried out by cyclic voltammetry in a saturated aqueous solution of LiNO3. At scan rate of 10 mV s(-1) very stable cyclic performance of such obtained VO2 was established with discharge capacity around 184 mAh g(-1). (C) 2011 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "The simple one-step solvothermal synthesis of nanostructurated VO2(B)",
volume = "38",
number = "3",
pages = "2313-2317",
doi = "10.1016/j.ceramint.2011.11.001"
}
Milošević, S. S., Stojković, I., Kurko, S. V., Grbović-Novaković, J.,& Cvjetićanin, N.. (2012). The simple one-step solvothermal synthesis of nanostructurated VO2(B). in Ceramics International, 38(3), 2313-2317.
https://doi.org/10.1016/j.ceramint.2011.11.001
Milošević SS, Stojković I, Kurko SV, Grbović-Novaković J, Cvjetićanin N. The simple one-step solvothermal synthesis of nanostructurated VO2(B). in Ceramics International. 2012;38(3):2313-2317.
doi:10.1016/j.ceramint.2011.11.001 .
Milošević, Sanja S., Stojković, Ivana, Kurko, Sandra V., Grbović-Novaković, Jasmina, Cvjetićanin, Nikola, "The simple one-step solvothermal synthesis of nanostructurated VO2(B)" in Ceramics International, 38, no. 3 (2012):2313-2317,
https://doi.org/10.1016/j.ceramint.2011.11.001 . .
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Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis

Jugović, Dragana; Mitrić, Miodrag; Kuzmanović, Maja D.; Cvjetićanin, Nikola; Marković, Smilja; Škapin, Srečo Davor; Uskoković, Dragan

(2012)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Kuzmanović, Maja D.
AU  - Cvjetićanin, Nikola
AU  - Marković, Smilja
AU  - Škapin, Srečo Davor
AU  - Uskoković, Dragan
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4733
AB  - Lithium iron phosphate powders were obtained by solvothermal treatments of quaternary emulsions Triton X-100/cyclohexane/n-hexanol/water at low temperature (180 degrees C), with or without stirring. Such synthesis conditions allowed for fast crystallization of pure olivine-type LiFePO4 powder, evidenced by the X-ray powder diffraction measurements and energy dispersive spectroscopy. It has been found that stirring drastically changes the morphology of LiFePO4 particles, causing a preferential crystal orientation. Also, a great difference in the morphology was demonstrated by field emission scanning electron microscopy. The powder obtained after only half an hour of the dynamic solvothermal treatment, without additional post annealing, and without carbon coating, was electrochemically active, showing the discharge capacity of 115 mAh g(-1). (C) 2011 Elsevier B.V. All rights reserved.
T2  - Powder Technology
T1  - Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis
VL  - 219
SP  - 128
EP  - 134
DO  - 10.1016/j.powtec.2011.12.028
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Kuzmanović, Maja D. and Cvjetićanin, Nikola and Marković, Smilja and Škapin, Srečo Davor and Uskoković, Dragan",
year = "2012",
abstract = "Lithium iron phosphate powders were obtained by solvothermal treatments of quaternary emulsions Triton X-100/cyclohexane/n-hexanol/water at low temperature (180 degrees C), with or without stirring. Such synthesis conditions allowed for fast crystallization of pure olivine-type LiFePO4 powder, evidenced by the X-ray powder diffraction measurements and energy dispersive spectroscopy. It has been found that stirring drastically changes the morphology of LiFePO4 particles, causing a preferential crystal orientation. Also, a great difference in the morphology was demonstrated by field emission scanning electron microscopy. The powder obtained after only half an hour of the dynamic solvothermal treatment, without additional post annealing, and without carbon coating, was electrochemically active, showing the discharge capacity of 115 mAh g(-1). (C) 2011 Elsevier B.V. All rights reserved.",
journal = "Powder Technology",
title = "Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis",
volume = "219",
pages = "128-134",
doi = "10.1016/j.powtec.2011.12.028"
}
Jugović, D., Mitrić, M., Kuzmanović, M. D., Cvjetićanin, N., Marković, S., Škapin, S. D.,& Uskoković, D.. (2012). Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis. in Powder Technology, 219, 128-134.
https://doi.org/10.1016/j.powtec.2011.12.028
Jugović D, Mitrić M, Kuzmanović MD, Cvjetićanin N, Marković S, Škapin SD, Uskoković D. Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis. in Powder Technology. 2012;219:128-134.
doi:10.1016/j.powtec.2011.12.028 .
Jugović, Dragana, Mitrić, Miodrag, Kuzmanović, Maja D., Cvjetićanin, Nikola, Marković, Smilja, Škapin, Srečo Davor, Uskoković, Dragan, "Rapid crystallization of LiFePO4 particles by facile emulsion-mediated solvothermal synthesis" in Powder Technology, 219 (2012):128-134,
https://doi.org/10.1016/j.powtec.2011.12.028 . .
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13