TY  - JOUR
AU  - Smiljanić, Milutin Lj.
AU  - Srejić, Irina
AU  - Marinovic, Vedrana M.
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5134
AB  - The oxygen reduction reaction (ORR) was studied on a polycrystalline Pt electrode in 0.1 M NaCl electrolyte containing various amounts of acetonitrile (AcN). The state of the electrode surface was characterized by cyclic voltammetry in oxygen free electrolytes, while ORR studies were performed on a polycrystalline Pt rotating disc electrode by linear sweep voltammetry in oxygen saturated electrolytes. The acetonitrile is chemisorbed on Pt over a wide potential range, inhibiting both hydrogen adsorption and oxide formation. The extent of AcN chemisorption depends on its concentration in the solution. The initial potential of oxygen reduction is shifted negatively, while the ORR current is increasingly reduced with the increase of AcN concentration. Complete inhibition of ORR in the potential range of AcN and Cl anion coadsorption is achieved for a 0.1 M NaCl + 1 M AcN solution.
T2  - Hemijska industrija
T1  - Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline Pt electrode in sodium chloride solution
VL  - 66
IS  - 3
SP  - 327
EP  - 333
DO  - 10.2298/HEMIND111010097S
ER  - 

@article{
author = "Smiljanić, Milutin Lj. and Srejić, Irina and Marinovic, Vedrana M. and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2012",
abstract = "The oxygen reduction reaction (ORR) was studied on a polycrystalline Pt electrode in 0.1 M NaCl electrolyte containing various amounts of acetonitrile (AcN). The state of the electrode surface was characterized by cyclic voltammetry in oxygen free electrolytes, while ORR studies were performed on a polycrystalline Pt rotating disc electrode by linear sweep voltammetry in oxygen saturated electrolytes. The acetonitrile is chemisorbed on Pt over a wide potential range, inhibiting both hydrogen adsorption and oxide formation. The extent of AcN chemisorption depends on its concentration in the solution. The initial potential of oxygen reduction is shifted negatively, while the ORR current is increasingly reduced with the increase of AcN concentration. Complete inhibition of ORR in the potential range of AcN and Cl anion coadsorption is achieved for a 0.1 M NaCl + 1 M AcN solution.",
journal = "Hemijska industrija",
title = "Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline Pt electrode in sodium chloride solution",
volume = "66",
number = "3",
pages = "327-333",
doi = "10.2298/HEMIND111010097S"
}

Smiljanić, M. Lj., Srejić, I., Marinovic, V. M., Rakočević, Z. Lj.,& Štrbac, S.. (2012). Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline Pt electrode in sodium chloride solution. in Hemijska industrija, 66(3), 327-333.
https://doi.org/10.2298/HEMIND111010097S

Smiljanić ML, Srejić I, Marinovic VM, Rakočević ZL, Štrbac S. Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline Pt electrode in sodium chloride solution. in Hemijska industrija. 2012;66(3):327-333.
doi:10.2298/HEMIND111010097S .

Smiljanić, Milutin Lj., Srejić, Irina, Marinovic, Vedrana M., Rakočević, Zlatko Lj., Štrbac, Svetlana, "Inhibiting effect of acetonitrile on oxygen reduction on polycrystalline Pt electrode in sodium chloride solution" in Hemijska industrija, 66, no. 3 (2012):327-333,
https://doi.org/10.2298/HEMIND111010097S . .