TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Jović, Vladimir D.
AU  - Nikolić, Nebojša D.
AU  - Barudžija, Tanja
AU  - Dimitrijević, Silvana
AU  - Jovićević, Jovan N.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12936
AB  - Electrodeposition of copper from deep eutectic solvents (DES) based on a mixture of choline chloride and ethylene glycol containing CuCl2·2H2O at 50 °C and 80 °C was studied. Electrochemical reduction/oxidation of Cu(II)/Cu(0) on glassy carbon (GC) and palladium (Pd) electrodes was investigated by cyclic voltammetry (CV) and square wave voltammetry (SWV) emphasizing that this process takes place through two steps, Cu(II) ↔ Cu(I) and Cu(I) ↔ Cu(0). The CV results showed that in chloride-rich DES electrolytes, the increased presence of chloro ligands raises the overpotential required for Cu electrodeposition. The electrochemical impedance spectroscopy (EIS) results indicate simultaneous electrodeposition of Cu and electrosorption of large cations on electrodeposited Cu on both GC and Pd substrates. Scanning electron microscopy (SEM) results showed that Cu grains of approximately 1 μm were obtained by electrodeposition of Cu on both Pd and GC, whereby better coverage by electrodeposited Cu was obtained on Pd than on GC. Cu electrodeposited on Pd was relatively uniform and smooth, but porous, while Cu electrodeposited on GC was dispersed in small agglomerates. Energy-dispersive X-ray spectroscopy (EDS) of Cu electrodeposited on Pd detected the dominant presence of Cu with the possibility of the formation of CuPd alloy. The presence of CuPd alloy face-centred cubic structures is confirmed by X-ray diffraction (XRD) along with metallic Cu.
T2  - Journal of Electroanalytical Chemistry
T1  - Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent
VL  - 958
SP  - 118161
DO  - 10.1016/j.jelechem.2024.118161
ER  - 

@article{
author = "Cvetković, Vesna S. and Jović, Vladimir D. and Nikolić, Nebojša D. and Barudžija, Tanja and Dimitrijević, Silvana and Jovićević, Jovan N.",
year = "2024",
abstract = "Electrodeposition of copper from deep eutectic solvents (DES) based on a mixture of choline chloride and ethylene glycol containing CuCl2·2H2O at 50 °C and 80 °C was studied. Electrochemical reduction/oxidation of Cu(II)/Cu(0) on glassy carbon (GC) and palladium (Pd) electrodes was investigated by cyclic voltammetry (CV) and square wave voltammetry (SWV) emphasizing that this process takes place through two steps, Cu(II) ↔ Cu(I) and Cu(I) ↔ Cu(0). The CV results showed that in chloride-rich DES electrolytes, the increased presence of chloro ligands raises the overpotential required for Cu electrodeposition. The electrochemical impedance spectroscopy (EIS) results indicate simultaneous electrodeposition of Cu and electrosorption of large cations on electrodeposited Cu on both GC and Pd substrates. Scanning electron microscopy (SEM) results showed that Cu grains of approximately 1 μm were obtained by electrodeposition of Cu on both Pd and GC, whereby better coverage by electrodeposited Cu was obtained on Pd than on GC. Cu electrodeposited on Pd was relatively uniform and smooth, but porous, while Cu electrodeposited on GC was dispersed in small agglomerates. Energy-dispersive X-ray spectroscopy (EDS) of Cu electrodeposited on Pd detected the dominant presence of Cu with the possibility of the formation of CuPd alloy. The presence of CuPd alloy face-centred cubic structures is confirmed by X-ray diffraction (XRD) along with metallic Cu.",
journal = "Journal of Electroanalytical Chemistry",
title = "Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent",
volume = "958",
pages = "118161",
doi = "10.1016/j.jelechem.2024.118161"
}

Cvetković, V. S., Jović, V. D., Nikolić, N. D., Barudžija, T., Dimitrijević, S.,& Jovićević, J. N.. (2024). Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent. in Journal of Electroanalytical Chemistry, 958, 118161.
https://doi.org/10.1016/j.jelechem.2024.118161

Cvetković VS, Jović VD, Nikolić ND, Barudžija T, Dimitrijević S, Jovićević JN. Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent. in Journal of Electroanalytical Chemistry. 2024;958:118161.
doi:10.1016/j.jelechem.2024.118161 .

Cvetković, Vesna S., Jović, Vladimir D., Nikolić, Nebojša D., Barudžija, Tanja, Dimitrijević, Silvana, Jovićević, Jovan N., "Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent" in Journal of Electroanalytical Chemistry, 958 (2024):118161,
https://doi.org/10.1016/j.jelechem.2024.118161 . .

TY  - JOUR
AU  - Maksimović, Vesna
AU  - Lacnjevac, U. C.
AU  - Stoiljković, Milovan
AU  - Pavlović, Miomir G.
AU  - Jović, Vladimir D.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4645
AB  - The morphology, phase and chemical composition of Ni-Co alloy powders electrodeposited from an ammonium sulfate-boric acid containing electrolyte with different ratio of Ni/Co ions were investigated. The ratios of NVCo ions were 1/1, 1/2 and 1/3. The morphology, chemical composition and phase composition of the electrodeposited alloy powders were investigated using AES, SEM, EDS and XRD analysis. Composition of the electrolyte, i.e. the ratio of Ni/Co concentrations was found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni/Co = 1/1 concentrations typical 2D fern-like dendritic particles were obtained. With a decrease of NVCo ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates were obtained. X-ray diffraction studies showed that the alloy powders mainly consisted of the face-centered cubic alpha-nickel phase and hexagonal close-packed alpha-cobalt phase and minor proportions of face-centered cubic alpha-cobalt phase. The occurrence of the latter phase was observed only in the alloy powder with the higher cobalt concentration in electrolyte. The electrodeposition of Ni-Co powders occurred in an anomalous manner. (C) 2011 Elsevier Inc. All rights reserved.
T2  - Materials Characterization
T1  - Morphology and composition of Ni-Co electrodeposited powders
VL  - 62
IS  - 12
SP  - 1173
EP  - 1179
DO  - 10.1016/j.matchar.2011.09.001
ER  - 

@article{
author = "Maksimović, Vesna and Lacnjevac, U. C. and Stoiljković, Milovan and Pavlović, Miomir G. and Jović, Vladimir D.",
year = "2011",
abstract = "The morphology, phase and chemical composition of Ni-Co alloy powders electrodeposited from an ammonium sulfate-boric acid containing electrolyte with different ratio of Ni/Co ions were investigated. The ratios of NVCo ions were 1/1, 1/2 and 1/3. The morphology, chemical composition and phase composition of the electrodeposited alloy powders were investigated using AES, SEM, EDS and XRD analysis. Composition of the electrolyte, i.e. the ratio of Ni/Co concentrations was found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni/Co = 1/1 concentrations typical 2D fern-like dendritic particles were obtained. With a decrease of NVCo ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates were obtained. X-ray diffraction studies showed that the alloy powders mainly consisted of the face-centered cubic alpha-nickel phase and hexagonal close-packed alpha-cobalt phase and minor proportions of face-centered cubic alpha-cobalt phase. The occurrence of the latter phase was observed only in the alloy powder with the higher cobalt concentration in electrolyte. The electrodeposition of Ni-Co powders occurred in an anomalous manner. (C) 2011 Elsevier Inc. All rights reserved.",
journal = "Materials Characterization",
title = "Morphology and composition of Ni-Co electrodeposited powders",
volume = "62",
number = "12",
pages = "1173-1179",
doi = "10.1016/j.matchar.2011.09.001"
}

Maksimović, V., Lacnjevac, U. C., Stoiljković, M., Pavlović, M. G.,& Jović, V. D.. (2011). Morphology and composition of Ni-Co electrodeposited powders. in Materials Characterization, 62(12), 1173-1179.
https://doi.org/10.1016/j.matchar.2011.09.001

Maksimović V, Lacnjevac UC, Stoiljković M, Pavlović MG, Jović VD. Morphology and composition of Ni-Co electrodeposited powders. in Materials Characterization. 2011;62(12):1173-1179.
doi:10.1016/j.matchar.2011.09.001 .

Maksimović, Vesna, Lacnjevac, U. C., Stoiljković, Milovan, Pavlović, Miomir G., Jović, Vladimir D., "Morphology and composition of Ni-Co electrodeposited powders" in Materials Characterization, 62, no. 12 (2011):1173-1179,
https://doi.org/10.1016/j.matchar.2011.09.001 . .

TY  - JOUR
AU  - Lacnjevac, U.
AU  - Jovic, B. M.
AU  - Maksimović, Vesna
AU  - Jović, Vladimir D.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3896
AB  - The electrodeposition of the Fe-Ni powders from citrate-ammonium chloride containing electrolytes for different Ni/Fe ions concentration ratios at pH 4.0 was investigated by the polarization measurements. The morphology, chemical composition, and phase composition of the obtained powders were investigated using SEM, EDS, and XRD analysis. EDS analysis of as-deposited alloy powders confirmed anomalous co-deposition of Fe and Ni. A common characteristic for all as-deposited powder samples was the presence of cone-shaped cavities and nodules on the big agglomerates of the order of 200-400 mu m. After annealing in air at 400, 600, and 700 A degrees C for 3 h, all alloy powders oxidized forming NiO, NiFe2O4, and Fe2O3 phases in different proportions depending on the original powder composition. The NiFe2O4 phase was found to be dominant in the sample with the highest percentage of Fe after annealing at 600 A degrees C.
T2  - Journal of Applied Electrochemistry
T1  - An attempt to produce NiFe2O4 powder from electrodeposited Fe-Ni alloy powders by subsequent recrystallization in air
VL  - 40
IS  - 3
SP  - 701
EP  - 708
DO  - 10.1007/s10800-009-0047-4
ER  - 

@article{
author = "Lacnjevac, U. and Jovic, B. M. and Maksimović, Vesna and Jović, Vladimir D.",
year = "2010",
abstract = "The electrodeposition of the Fe-Ni powders from citrate-ammonium chloride containing electrolytes for different Ni/Fe ions concentration ratios at pH 4.0 was investigated by the polarization measurements. The morphology, chemical composition, and phase composition of the obtained powders were investigated using SEM, EDS, and XRD analysis. EDS analysis of as-deposited alloy powders confirmed anomalous co-deposition of Fe and Ni. A common characteristic for all as-deposited powder samples was the presence of cone-shaped cavities and nodules on the big agglomerates of the order of 200-400 mu m. After annealing in air at 400, 600, and 700 A degrees C for 3 h, all alloy powders oxidized forming NiO, NiFe2O4, and Fe2O3 phases in different proportions depending on the original powder composition. The NiFe2O4 phase was found to be dominant in the sample with the highest percentage of Fe after annealing at 600 A degrees C.",
journal = "Journal of Applied Electrochemistry",
title = "An attempt to produce NiFe2O4 powder from electrodeposited Fe-Ni alloy powders by subsequent recrystallization in air",
volume = "40",
number = "3",
pages = "701-708",
doi = "10.1007/s10800-009-0047-4"
}

Lacnjevac, U., Jovic, B. M., Maksimović, V.,& Jović, V. D.. (2010). An attempt to produce NiFe2O4 powder from electrodeposited Fe-Ni alloy powders by subsequent recrystallization in air. in Journal of Applied Electrochemistry, 40(3), 701-708.
https://doi.org/10.1007/s10800-009-0047-4

Lacnjevac U, Jovic BM, Maksimović V, Jović VD. An attempt to produce NiFe2O4 powder from electrodeposited Fe-Ni alloy powders by subsequent recrystallization in air. in Journal of Applied Electrochemistry. 2010;40(3):701-708.
doi:10.1007/s10800-009-0047-4 .

Lacnjevac, U., Jovic, B. M., Maksimović, Vesna, Jović, Vladimir D., "An attempt to produce NiFe2O4 powder from electrodeposited Fe-Ni alloy powders by subsequent recrystallization in air" in Journal of Applied Electrochemistry, 40, no. 3 (2010):701-708,
https://doi.org/10.1007/s10800-009-0047-4 . .

TY  - JOUR
AU  - Lacnjevac, U.
AU  - Jovic, B. M.
AU  - Baščarević, Zvezdana D.
AU  - Maksimović, Vesna
AU  - Jović, Vladimir D.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3681
AB  - The Ni-Mo-O alloy powders were electrodeposited from ammonium sulfate containing electrolytes for different Ni/Mo ions concentration ratios. Electrodeposition was investigated by the polarization measurements. The morphology, chemical composition and phase composition of these powders were investigated using SEM, EDS, AAS and XRD analysis. The EDS and AAS analysis showed that the powder composition depends on the Ni/Mo ions concentration ratio, with the Ni/Mo metals ratio in the powders being the same as the one in the solution. The as-deposited alloy powders were nanocrystalline, while after stepwise annealing at 300, 400, 500 and 600 degrees C for 2 h in N(2) atmosphere their crystallinity became more and more pronounced, with the dimension of crystallites increasing with the increase of the annealing temperature. Already after the annealing at 300 degrees C the presence of two phases, MoO(3) and NiMoO(4), was identified by XRD, while SEM analysis showed that the surfaces of powder particles were partially recrystallized. With the increase of the annealing temperature the amount of the NiMoO(4) was found to increase in all powders. For the powder electrodeposited from the solution with the highest Ni/Mo ratio (1/0.3) NiMoO(4) phase was detected together with a small amount of Ni(4)Mo phase, indicating phase transition of MoO(3) into NiMoO(4) (and probably Ni(4)Mo) at the temperature of 600 degrees C. (c) 2008 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Morphology and phase composition of as-deposited and recrystallized Ni-Mo-O powders
VL  - 54
IS  - 11
SP  - 3115
EP  - 3123
DO  - 10.1016/j.electacta.2008.11.068
ER  - 

@article{
author = "Lacnjevac, U. and Jovic, B. M. and Baščarević, Zvezdana D. and Maksimović, Vesna and Jović, Vladimir D.",
year = "2009",
abstract = "The Ni-Mo-O alloy powders were electrodeposited from ammonium sulfate containing electrolytes for different Ni/Mo ions concentration ratios. Electrodeposition was investigated by the polarization measurements. The morphology, chemical composition and phase composition of these powders were investigated using SEM, EDS, AAS and XRD analysis. The EDS and AAS analysis showed that the powder composition depends on the Ni/Mo ions concentration ratio, with the Ni/Mo metals ratio in the powders being the same as the one in the solution. The as-deposited alloy powders were nanocrystalline, while after stepwise annealing at 300, 400, 500 and 600 degrees C for 2 h in N(2) atmosphere their crystallinity became more and more pronounced, with the dimension of crystallites increasing with the increase of the annealing temperature. Already after the annealing at 300 degrees C the presence of two phases, MoO(3) and NiMoO(4), was identified by XRD, while SEM analysis showed that the surfaces of powder particles were partially recrystallized. With the increase of the annealing temperature the amount of the NiMoO(4) was found to increase in all powders. For the powder electrodeposited from the solution with the highest Ni/Mo ratio (1/0.3) NiMoO(4) phase was detected together with a small amount of Ni(4)Mo phase, indicating phase transition of MoO(3) into NiMoO(4) (and probably Ni(4)Mo) at the temperature of 600 degrees C. (c) 2008 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Morphology and phase composition of as-deposited and recrystallized Ni-Mo-O powders",
volume = "54",
number = "11",
pages = "3115-3123",
doi = "10.1016/j.electacta.2008.11.068"
}

Lacnjevac, U., Jovic, B. M., Baščarević, Z. D., Maksimović, V.,& Jović, V. D.. (2009). Morphology and phase composition of as-deposited and recrystallized Ni-Mo-O powders. in Electrochimica Acta, 54(11), 3115-3123.
https://doi.org/10.1016/j.electacta.2008.11.068

Lacnjevac U, Jovic BM, Baščarević ZD, Maksimović V, Jović VD. Morphology and phase composition of as-deposited and recrystallized Ni-Mo-O powders. in Electrochimica Acta. 2009;54(11):3115-3123.
doi:10.1016/j.electacta.2008.11.068 .

Lacnjevac, U., Jovic, B. M., Baščarević, Zvezdana D., Maksimović, Vesna, Jović, Vladimir D., "Morphology and phase composition of as-deposited and recrystallized Ni-Mo-O powders" in Electrochimica Acta, 54, no. 11 (2009):3115-3123,
https://doi.org/10.1016/j.electacta.2008.11.068 . .

TY  - JOUR
AU  - Jovic, B. M.
AU  - Jović, Vladimir D.
AU  - Maksimović, Vesna
AU  - Pavlović, Miomir G.
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3440
AB  - The electrodeposition of the Ni-Mo-O alloy powders from ammonium chloride containing electrolytes for different Ni/Mo ions concentration ratios was investigated by the polarization measurements. The morphology, chemical composition and phase composition of the electrodeposited Ni-Mo-O alloy powders were investigated using DSC, TGA, SEM, EDS and XRD analysis. According to the EDS results, the powder composition depends on the Ni/Mo ions concentration ratio. However, some deviations in the composition of the as-deposited powders, as the result of the position of the EDS analysis, revealed that the composition of such powders is not homogeneous. The as-deposited alloy powders were nanocrystalline showing only one broad XRD peak around 44 degrees. Their morphology was found to depend on the Ni/Mo ions concentration ratio. After annealing of the Ni-Mo-O powders for 2 h in N-2 atmosphere at 600 degrees C, well-defined crystals for all powders were detected by SEM. The presence of the NiMoO4 phase only or NiMoO4 and MoO3 phases in these powders (XRD), depending on the Ni/Mo ions concentration ratio, was identified. The additional EDS analysis on different recrystallized grains revealed the influence of the annealing on a composition of the alloy powders. (c) 2008 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Characterization of electrodeposited powders of the system Ni-Mo-O
VL  - 53
IS  - 14
SP  - 4796
EP  - 4804
DO  - 10.1016/j.electacta.2008.02.004
ER  - 

@article{
author = "Jovic, B. M. and Jović, Vladimir D. and Maksimović, Vesna and Pavlović, Miomir G.",
year = "2008",
abstract = "The electrodeposition of the Ni-Mo-O alloy powders from ammonium chloride containing electrolytes for different Ni/Mo ions concentration ratios was investigated by the polarization measurements. The morphology, chemical composition and phase composition of the electrodeposited Ni-Mo-O alloy powders were investigated using DSC, TGA, SEM, EDS and XRD analysis. According to the EDS results, the powder composition depends on the Ni/Mo ions concentration ratio. However, some deviations in the composition of the as-deposited powders, as the result of the position of the EDS analysis, revealed that the composition of such powders is not homogeneous. The as-deposited alloy powders were nanocrystalline showing only one broad XRD peak around 44 degrees. Their morphology was found to depend on the Ni/Mo ions concentration ratio. After annealing of the Ni-Mo-O powders for 2 h in N-2 atmosphere at 600 degrees C, well-defined crystals for all powders were detected by SEM. The presence of the NiMoO4 phase only or NiMoO4 and MoO3 phases in these powders (XRD), depending on the Ni/Mo ions concentration ratio, was identified. The additional EDS analysis on different recrystallized grains revealed the influence of the annealing on a composition of the alloy powders. (c) 2008 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Characterization of electrodeposited powders of the system Ni-Mo-O",
volume = "53",
number = "14",
pages = "4796-4804",
doi = "10.1016/j.electacta.2008.02.004"
}

Jovic, B. M., Jović, V. D., Maksimović, V.,& Pavlović, M. G.. (2008). Characterization of electrodeposited powders of the system Ni-Mo-O. in Electrochimica Acta, 53(14), 4796-4804.
https://doi.org/10.1016/j.electacta.2008.02.004

Jovic BM, Jović VD, Maksimović V, Pavlović MG. Characterization of electrodeposited powders of the system Ni-Mo-O. in Electrochimica Acta. 2008;53(14):4796-4804.
doi:10.1016/j.electacta.2008.02.004 .

Jovic, B. M., Jović, Vladimir D., Maksimović, Vesna, Pavlović, Miomir G., "Characterization of electrodeposited powders of the system Ni-Mo-O" in Electrochimica Acta, 53, no. 14 (2008):4796-4804,
https://doi.org/10.1016/j.electacta.2008.02.004 . .

TY  - JOUR
AU  - Maksimović, Vesna
AU  - Pavlović, Miomir G.
AU  - Pavlović, Ljubica J.
AU  - Tomić, Milorad V.
AU  - Jović, Vladimir D.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2571
AB  - The effect of overpotential pulsing and periodic current reversal on the morphology of silver powders was investigated using a scanning electron microscope (SEM). It is shown that the profile of pulses or current reversal determines the micromorphology of the electrodeposited silver particles. Generally, three forms of silver were detected: (1) dendrites, (2) equiaxial crystals (independent and/or agglomerates) and (3) rods. The shape of particle seems to be the result of an interplay between the surface energy and growth kinetics.
T2  - Hydrometallurgy
T1  - Morphology and growth of electrodeposited silver powder particles
VL  - 86
IS  - 1-2
SP  - 22
EP  - 26
DO  - 10.1016/j.hydromet.2006.10.004
ER  - 

@article{
author = "Maksimović, Vesna and Pavlović, Miomir G. and Pavlović, Ljubica J. and Tomić, Milorad V. and Jović, Vladimir D.",
year = "2007",
abstract = "The effect of overpotential pulsing and periodic current reversal on the morphology of silver powders was investigated using a scanning electron microscope (SEM). It is shown that the profile of pulses or current reversal determines the micromorphology of the electrodeposited silver particles. Generally, three forms of silver were detected: (1) dendrites, (2) equiaxial crystals (independent and/or agglomerates) and (3) rods. The shape of particle seems to be the result of an interplay between the surface energy and growth kinetics.",
journal = "Hydrometallurgy",
title = "Morphology and growth of electrodeposited silver powder particles",
volume = "86",
number = "1-2",
pages = "22-26",
doi = "10.1016/j.hydromet.2006.10.004"
}

Maksimović, V., Pavlović, M. G., Pavlović, L. J., Tomić, M. V.,& Jović, V. D.. (2007). Morphology and growth of electrodeposited silver powder particles. in Hydrometallurgy, 86(1-2), 22-26.
https://doi.org/10.1016/j.hydromet.2006.10.004

Maksimović V, Pavlović MG, Pavlović LJ, Tomić MV, Jović VD. Morphology and growth of electrodeposited silver powder particles. in Hydrometallurgy. 2007;86(1-2):22-26.
doi:10.1016/j.hydromet.2006.10.004 .

Maksimović, Vesna, Pavlović, Miomir G., Pavlović, Ljubica J., Tomić, Milorad V., Jović, Vladimir D., "Morphology and growth of electrodeposited silver powder particles" in Hydrometallurgy, 86, no. 1-2 (2007):22-26,
https://doi.org/10.1016/j.hydromet.2006.10.004 . .

TY  - JOUR
AU  - Jović, Vladimir D.
AU  - Jovic, B. M.
AU  - Maksimović, Vesna
AU  - Pavlović, Miomir G.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3179
AB  - Polarization characteristics of the processes of Ni and Co powders and Ni-Co alloy powders electrodeposition from ammonium chloride containing supporting electrolyte and their morphologies are investigated as a function of Ni2+ and Co2+ ions concentrations. It is found that the shape of the polarization curves in all cases is practically defined by the shape of the polarization curve for hydrogen evolution. It is shown that correct polarization curves, as well as the morphology of electrodeposited powders are sensitive to the ratio of Ni2+/CO2+ ions concentration. Characteristic feature of powder particles obtained from chloride containing electrolytes is the presence of cone-shaped cavities. In the case of Ni powder cauliflower and spongy type particles are detected, while Co powder contains only spongy type particles. In all cases of alloy powder formation anomalous type of co-deposition is detected. (c) 2006 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Electrodeposition and morphology of Ni, Co and Ni-Co alloy powders - Part II. Ammonium chloride supporting electrolyte
VL  - 52
IS  - 12
SP  - 4254
EP  - 4263
DO  - 10.1016/j.electacta.2006.12.003
ER  - 

@article{
author = "Jović, Vladimir D. and Jovic, B. M. and Maksimović, Vesna and Pavlović, Miomir G.",
year = "2007",
abstract = "Polarization characteristics of the processes of Ni and Co powders and Ni-Co alloy powders electrodeposition from ammonium chloride containing supporting electrolyte and their morphologies are investigated as a function of Ni2+ and Co2+ ions concentrations. It is found that the shape of the polarization curves in all cases is practically defined by the shape of the polarization curve for hydrogen evolution. It is shown that correct polarization curves, as well as the morphology of electrodeposited powders are sensitive to the ratio of Ni2+/CO2+ ions concentration. Characteristic feature of powder particles obtained from chloride containing electrolytes is the presence of cone-shaped cavities. In the case of Ni powder cauliflower and spongy type particles are detected, while Co powder contains only spongy type particles. In all cases of alloy powder formation anomalous type of co-deposition is detected. (c) 2006 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Electrodeposition and morphology of Ni, Co and Ni-Co alloy powders - Part II. Ammonium chloride supporting electrolyte",
volume = "52",
number = "12",
pages = "4254-4263",
doi = "10.1016/j.electacta.2006.12.003"
}

Jović, V. D., Jovic, B. M., Maksimović, V.,& Pavlović, M. G.. (2007). Electrodeposition and morphology of Ni, Co and Ni-Co alloy powders - Part II. Ammonium chloride supporting electrolyte. in Electrochimica Acta, 52(12), 4254-4263.
https://doi.org/10.1016/j.electacta.2006.12.003

Jović VD, Jovic BM, Maksimović V, Pavlović MG. Electrodeposition and morphology of Ni, Co and Ni-Co alloy powders - Part II. Ammonium chloride supporting electrolyte. in Electrochimica Acta. 2007;52(12):4254-4263.
doi:10.1016/j.electacta.2006.12.003 .

Jović, Vladimir D., Jovic, B. M., Maksimović, Vesna, Pavlović, Miomir G., "Electrodeposition and morphology of Ni, Co and Ni-Co alloy powders - Part II. Ammonium chloride supporting electrolyte" in Electrochimica Acta, 52, no. 12 (2007):4254-4263,
https://doi.org/10.1016/j.electacta.2006.12.003 . .

TY  - JOUR
AU  - Jović, Vladimir D.
AU  - Maksimović, Vesna
AU  - Pavlović, Miomir G.
AU  - Jovic, B. M.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6608
AB  - In this paper the morphology of Ni-Co powders electrodeposited from ammonium sulfate-boric acid containing electrolyte is investigated as a function of alloy powder composition. Composition of the electrolyte, i.e. the ratio of Ni2+/CO2+ concentration is found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni2+/Co2+ ions concentration, typical 2D fern-like dendritic particles were obtained. With decrease of Ni2+/Co2+ ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates of a size of about 100 mu m, being either compact (typical for pure Co powder) or composed of a large number of small 3D dendrites on their surface were obtained. According to the X-ray analysis, with decreasing Ni2+/Co2+ concentration ratio the amount of f.c.c. beta-Ni phase was found to decrease, while the amount of h.c.p. alpha-Co phase was found to increase being accompanied by the appearance of the f.c.c. Co phase at Ni2+/Co2+ = 0.33.
T2  - Materials Science Forum
T1  - Morphology and phase composition of Ni-Co alloy powders electrodeposited from ammonium sulfate-boric acid electrolyte
VL  - 518
SP  - 307
EP  - 312
DO  - 10.4028/www.scientific.net/MSF.518.307
ER  - 

@article{
author = "Jović, Vladimir D. and Maksimović, Vesna and Pavlović, Miomir G. and Jovic, B. M.",
year = "2006",
abstract = "In this paper the morphology of Ni-Co powders electrodeposited from ammonium sulfate-boric acid containing electrolyte is investigated as a function of alloy powder composition. Composition of the electrolyte, i.e. the ratio of Ni2+/CO2+ concentration is found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni2+/Co2+ ions concentration, typical 2D fern-like dendritic particles were obtained. With decrease of Ni2+/Co2+ ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates of a size of about 100 mu m, being either compact (typical for pure Co powder) or composed of a large number of small 3D dendrites on their surface were obtained. According to the X-ray analysis, with decreasing Ni2+/Co2+ concentration ratio the amount of f.c.c. beta-Ni phase was found to decrease, while the amount of h.c.p. alpha-Co phase was found to increase being accompanied by the appearance of the f.c.c. Co phase at Ni2+/Co2+ = 0.33.",
journal = "Materials Science Forum",
title = "Morphology and phase composition of Ni-Co alloy powders electrodeposited from ammonium sulfate-boric acid electrolyte",
volume = "518",
pages = "307-312",
doi = "10.4028/www.scientific.net/MSF.518.307"
}

Jović, V. D., Maksimović, V., Pavlović, M. G.,& Jovic, B. M.. (2006). Morphology and phase composition of Ni-Co alloy powders electrodeposited from ammonium sulfate-boric acid electrolyte. in Materials Science Forum, 518, 307-312.
https://doi.org/10.4028/www.scientific.net/MSF.518.307

Jović VD, Maksimović V, Pavlović MG, Jovic BM. Morphology and phase composition of Ni-Co alloy powders electrodeposited from ammonium sulfate-boric acid electrolyte. in Materials Science Forum. 2006;518:307-312.
doi:10.4028/www.scientific.net/MSF.518.307 .

Jović, Vladimir D., Maksimović, Vesna, Pavlović, Miomir G., Jovic, B. M., "Morphology and phase composition of Ni-Co alloy powders electrodeposited from ammonium sulfate-boric acid electrolyte" in Materials Science Forum, 518 (2006):307-312,
https://doi.org/10.4028/www.scientific.net/MSF.518.307 . .

TY  - JOUR
AU  - Jović, Vladimir D.
AU  - Jovic, B. M.
AU  - Pavlović, Miomir G.
AU  - Maksimović, Vesna
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3074
AB  - In this paper, the morphology and phase structure of Ni-Co powders electrodeposited from ammoniacal electrolyte are investigated as a function of alloy powder composition. Composition of the electrolyte, i.e. the ratio of Ni(2+)/Co(2+) concentration is found to influence both, the phase structure and the morphology of Ni-Co alloy powders. It is shown that the current density practically does not influence the morphology of Ni-Co alloy powders as well as alloy powder composition. At the highest ratio of the Ni(2+)/Co(2+) ions typical spongy particles were obtained. With the decrease of the Ni(2+)/Co(2+) ions ratio agglomerates of the size of about 100 mu m, composed of a large number of fern-like dendrites on their surface were obtained. At the lowest Ni(2+)/Co(2+) concentration ratio, among more dendritic particles, agglomerates typical for pure Co powder deposition were detected. It is also shown that depending on the Ni(2+)/Co(2+) ratio different types of Ni and Co codeposition could be detected: anomalous and irregular. At the Ni(2+)/Co(2+) ions ratio higher than 1 only beta-Ni phase was detected, while at concentration ratios Ni(2+)/Co(2+) LT 1 h.c.p. alpha-Co phase together with beta-Ni phase was detected in the alloy powder deposit.
T2  - Journal of Solid State Electrochemistry
T1  - Morphology and composition of Ni-Co alloy powders electrodeposited from ammoniacal electrolyte
VL  - 10
IS  - 12
SP  - 959
EP  - 966
DO  - 10.1007/s10008-005-0047-1
ER  - 

@article{
author = "Jović, Vladimir D. and Jovic, B. M. and Pavlović, Miomir G. and Maksimović, Vesna",
year = "2006",
abstract = "In this paper, the morphology and phase structure of Ni-Co powders electrodeposited from ammoniacal electrolyte are investigated as a function of alloy powder composition. Composition of the electrolyte, i.e. the ratio of Ni(2+)/Co(2+) concentration is found to influence both, the phase structure and the morphology of Ni-Co alloy powders. It is shown that the current density practically does not influence the morphology of Ni-Co alloy powders as well as alloy powder composition. At the highest ratio of the Ni(2+)/Co(2+) ions typical spongy particles were obtained. With the decrease of the Ni(2+)/Co(2+) ions ratio agglomerates of the size of about 100 mu m, composed of a large number of fern-like dendrites on their surface were obtained. At the lowest Ni(2+)/Co(2+) concentration ratio, among more dendritic particles, agglomerates typical for pure Co powder deposition were detected. It is also shown that depending on the Ni(2+)/Co(2+) ratio different types of Ni and Co codeposition could be detected: anomalous and irregular. At the Ni(2+)/Co(2+) ions ratio higher than 1 only beta-Ni phase was detected, while at concentration ratios Ni(2+)/Co(2+) LT 1 h.c.p. alpha-Co phase together with beta-Ni phase was detected in the alloy powder deposit.",
journal = "Journal of Solid State Electrochemistry",
title = "Morphology and composition of Ni-Co alloy powders electrodeposited from ammoniacal electrolyte",
volume = "10",
number = "12",
pages = "959-966",
doi = "10.1007/s10008-005-0047-1"
}

Jović, V. D., Jovic, B. M., Pavlović, M. G.,& Maksimović, V.. (2006). Morphology and composition of Ni-Co alloy powders electrodeposited from ammoniacal electrolyte. in Journal of Solid State Electrochemistry, 10(12), 959-966.
https://doi.org/10.1007/s10008-005-0047-1

Jović VD, Jovic BM, Pavlović MG, Maksimović V. Morphology and composition of Ni-Co alloy powders electrodeposited from ammoniacal electrolyte. in Journal of Solid State Electrochemistry. 2006;10(12):959-966.
doi:10.1007/s10008-005-0047-1 .

Jović, Vladimir D., Jovic, B. M., Pavlović, Miomir G., Maksimović, Vesna, "Morphology and composition of Ni-Co alloy powders electrodeposited from ammoniacal electrolyte" in Journal of Solid State Electrochemistry, 10, no. 12 (2006):959-966,
https://doi.org/10.1007/s10008-005-0047-1 . .