Marinkovic, K.

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  • Marinkovic, K. (3)
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Author's Bibliography

Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics

Mančić, Lidija; Marinković, Bojan A.; Marinkovic, K.; Dramićanin, Miroslav; Milošević, Olivera

(2011)

TY  - JOUR
AU  - Mančić, Lidija
AU  - Marinković, Bojan A.
AU  - Marinkovic, K.
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6933
AB  - Phosphors of (Y0.75Gd0.25)(2)O-3:Eu3+ (5 at.%) have been prepared through soft chemistry routes. Conversion of the starting nitrates mixture into oxide is performed through two approaches: (a) hydrothermal treatment (HT) at 200 degrees C/3 h of an ammonium hydrogen carbonate precipitated mixture and (b) by thermally decomposition of pure nitrate precursor solution at 900 degrees C in dispersed phase (aerosol) within a tubular flow reactor by spray pyrolysis process (SP). The powders are additionally thermally treated at different temperatures: 600, 1000, and 1100 degrees C for either 3 or 12 h. HT-derived particles present exclusively one-dimensional morphology (nanorods) up to the temperatures of 600 degrees C, while the leaf-like particles start to grow afterward. SP-derived particles maintain their spherical shape up to the temperatures of 1100 degrees C. These submicron sized spheres were actually composed of randomly aggregated nanoparticles. All powders exhibits cubic Ia-3 structure (Y0.75Gd0.25)(2)O-3:Eu and have improved optical characteristics due to their nanocrystalline nature. The detailed study of the influence of structural and morphological powder characteristics on their emission properties is performed based on the results of X-ray powder diffractometry, scanning electron microscopy, X-ray energy dispersive spectroscopy, transmission electron microscopy, and photoluminescence measurements.
T2  - Journal of Nanoparticle Research
T1  - Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics
VL  - 13
IS  - 11
SP  - 5887
EP  - 5897
DO  - 10.1007/s11051-010-0215-9
ER  - 
@article{
author = "Mančić, Lidija and Marinković, Bojan A. and Marinkovic, K. and Dramićanin, Miroslav and Milošević, Olivera",
year = "2011",
abstract = "Phosphors of (Y0.75Gd0.25)(2)O-3:Eu3+ (5 at.%) have been prepared through soft chemistry routes. Conversion of the starting nitrates mixture into oxide is performed through two approaches: (a) hydrothermal treatment (HT) at 200 degrees C/3 h of an ammonium hydrogen carbonate precipitated mixture and (b) by thermally decomposition of pure nitrate precursor solution at 900 degrees C in dispersed phase (aerosol) within a tubular flow reactor by spray pyrolysis process (SP). The powders are additionally thermally treated at different temperatures: 600, 1000, and 1100 degrees C for either 3 or 12 h. HT-derived particles present exclusively one-dimensional morphology (nanorods) up to the temperatures of 600 degrees C, while the leaf-like particles start to grow afterward. SP-derived particles maintain their spherical shape up to the temperatures of 1100 degrees C. These submicron sized spheres were actually composed of randomly aggregated nanoparticles. All powders exhibits cubic Ia-3 structure (Y0.75Gd0.25)(2)O-3:Eu and have improved optical characteristics due to their nanocrystalline nature. The detailed study of the influence of structural and morphological powder characteristics on their emission properties is performed based on the results of X-ray powder diffractometry, scanning electron microscopy, X-ray energy dispersive spectroscopy, transmission electron microscopy, and photoluminescence measurements.",
journal = "Journal of Nanoparticle Research",
title = "Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics",
volume = "13",
number = "11",
pages = "5887-5897",
doi = "10.1007/s11051-010-0215-9"
}
Mančić, L., Marinković, B. A., Marinkovic, K., Dramićanin, M.,& Milošević, O.. (2011). Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics. in Journal of Nanoparticle Research, 13(11), 5887-5897.
https://doi.org/10.1007/s11051-010-0215-9
Mančić L, Marinković BA, Marinkovic K, Dramićanin M, Milošević O. Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics. in Journal of Nanoparticle Research. 2011;13(11):5887-5897.
doi:10.1007/s11051-010-0215-9 .
Mančić, Lidija, Marinković, Bojan A., Marinkovic, K., Dramićanin, Miroslav, Milošević, Olivera, "Soft chemistry routes for synthesis of rare earth oxide nanoparticles with well defined morphological and structural characteristics" in Journal of Nanoparticle Research, 13, no. 11 (2011):5887-5897,
https://doi.org/10.1007/s11051-010-0215-9 . .
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Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis

Marinkovic, K.; Mančić, Lidija; Gomez, Luz S.; Rabanal, Maria Eugenia; Dramićanin, Miroslav; Milošević, Olivera

(2010)

TY  - JOUR
AU  - Marinkovic, K.
AU  - Mančić, Lidija
AU  - Gomez, Luz S.
AU  - Rabanal, Maria Eugenia
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6891
AB  - Red emitting Y2O3:Eu3+ (5 and 10 at.%) submicronic particles were synthesized through ultrasonic spray pyrolysis method from the pure nitrate solutions at 900 degrees C. The employed synthesis conditions (gradual increase of temperature within triple zone reactor and extended residence time) assured formation of spherical, dense, non-agglomerated particles that are nanostructured (crystallite size similar to 20 nm). The as-prepared powders were additionally thermally treated at temperatures up to 1200 degrees C. A bcc la-3 cubic phase presence and exceptional powder morphological features were maintained with heating and are followed with particle structural changes (crystallite growth up to 130 nm). Emission spectra were studied after excitation with 393 nm wavelength and together with the decay lifetimes for Eu3+ ion D-5(0) and D-5(1) levels revealed the effect of powder nanocrystalline nature on its luminescent properties. The emission spectra showed typical Eu3+ D-5(0)- GT F-7(i) (i = 0, 1, 2, 3, 4) transitions with dominant red emission at 611 nm, while the lifetime measurements revealed the quenching effect with the rise of dopant concentration and its more consistent distribution into host lattice due to the thermal treatment. (C) 2010 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis
VL  - 32
IS  - 12
SP  - 1606
EP  - 1611
DO  - 10.1016/j.optmat.2010.05.023
ER  - 
@article{
author = "Marinkovic, K. and Mančić, Lidija and Gomez, Luz S. and Rabanal, Maria Eugenia and Dramićanin, Miroslav and Milošević, Olivera",
year = "2010",
abstract = "Red emitting Y2O3:Eu3+ (5 and 10 at.%) submicronic particles were synthesized through ultrasonic spray pyrolysis method from the pure nitrate solutions at 900 degrees C. The employed synthesis conditions (gradual increase of temperature within triple zone reactor and extended residence time) assured formation of spherical, dense, non-agglomerated particles that are nanostructured (crystallite size similar to 20 nm). The as-prepared powders were additionally thermally treated at temperatures up to 1200 degrees C. A bcc la-3 cubic phase presence and exceptional powder morphological features were maintained with heating and are followed with particle structural changes (crystallite growth up to 130 nm). Emission spectra were studied after excitation with 393 nm wavelength and together with the decay lifetimes for Eu3+ ion D-5(0) and D-5(1) levels revealed the effect of powder nanocrystalline nature on its luminescent properties. The emission spectra showed typical Eu3+ D-5(0)- GT F-7(i) (i = 0, 1, 2, 3, 4) transitions with dominant red emission at 611 nm, while the lifetime measurements revealed the quenching effect with the rise of dopant concentration and its more consistent distribution into host lattice due to the thermal treatment. (C) 2010 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis",
volume = "32",
number = "12",
pages = "1606-1611",
doi = "10.1016/j.optmat.2010.05.023"
}
Marinkovic, K., Mančić, L., Gomez, L. S., Rabanal, M. E., Dramićanin, M.,& Milošević, O.. (2010). Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis. in Optical Materials, 32(12), 1606-1611.
https://doi.org/10.1016/j.optmat.2010.05.023
Marinkovic K, Mančić L, Gomez LS, Rabanal ME, Dramićanin M, Milošević O. Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis. in Optical Materials. 2010;32(12):1606-1611.
doi:10.1016/j.optmat.2010.05.023 .
Marinkovic, K., Mančić, Lidija, Gomez, Luz S., Rabanal, Maria Eugenia, Dramićanin, Miroslav, Milošević, Olivera, "Photoluminescent properties of nanostructured Y2O3:Eu3+ powders obtained through aerosol synthesis" in Optical Materials, 32, no. 12 (2010):1606-1611,
https://doi.org/10.1016/j.optmat.2010.05.023 . .
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YAG:Ce3+ nanostructured particles obtained via spray pyrolysis of polymeric precursor solution

Mančić, Lidija; Marinkovic, K.; Marinković, Bojan A.; Dramićanin, Miroslav; Milošević, Olivera

(2010)

TY  - JOUR
AU  - Mančić, Lidija
AU  - Marinkovic, K.
AU  - Marinković, Bojan A.
AU  - Dramićanin, Miroslav
AU  - Milošević, Olivera
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6855
AB  - Cerium-doped yttrium aluminum garnet (YAG:Ce3+) powder phosphor is synthesized via spray pyrolysis of polymeric precursor solution obtained by dissolving the corresponding nitrates in ethylenediaminetetraacetic acid (EDTA). Ultrasonically generated aerosol droplets are decomposed at 600 degrees C in argon atmosphere. Following the initial attempt in providing pure YAG:Ce3+, phase generation the particles were additionally thermally treated for 3 h in air at 1000 and 1100 degrees C. The powder morphology is followed with scanning electron microscopy (SEM), while inner particle structure is analysed by analytical and high-resolution transmission electron microscopy (TEM). Phase identification is performed by X-ray powder diffraction (XRPD) based on which a structural refinement through Rietveld method was done. The spherical submicronic particles have grained sub-structure comprising clustered garnet monocrystals sized below 100 nm. The YAG:Ce3+ emission shows wide peak in the range 470-600 nm with the maximum near 520 nm. (C) 2009 Elsevier Ltd. All rights reserved.
T2  - Journal of the European Ceramic Society
T1  - YAG:Ce3+ nanostructured particles obtained via spray pyrolysis of polymeric precursor solution
VL  - 30
IS  - 2
SP  - 577
EP  - 582
DO  - 10.1016/j.jeurceramsoc.2009.05.037
ER  - 
@article{
author = "Mančić, Lidija and Marinkovic, K. and Marinković, Bojan A. and Dramićanin, Miroslav and Milošević, Olivera",
year = "2010",
abstract = "Cerium-doped yttrium aluminum garnet (YAG:Ce3+) powder phosphor is synthesized via spray pyrolysis of polymeric precursor solution obtained by dissolving the corresponding nitrates in ethylenediaminetetraacetic acid (EDTA). Ultrasonically generated aerosol droplets are decomposed at 600 degrees C in argon atmosphere. Following the initial attempt in providing pure YAG:Ce3+, phase generation the particles were additionally thermally treated for 3 h in air at 1000 and 1100 degrees C. The powder morphology is followed with scanning electron microscopy (SEM), while inner particle structure is analysed by analytical and high-resolution transmission electron microscopy (TEM). Phase identification is performed by X-ray powder diffraction (XRPD) based on which a structural refinement through Rietveld method was done. The spherical submicronic particles have grained sub-structure comprising clustered garnet monocrystals sized below 100 nm. The YAG:Ce3+ emission shows wide peak in the range 470-600 nm with the maximum near 520 nm. (C) 2009 Elsevier Ltd. All rights reserved.",
journal = "Journal of the European Ceramic Society",
title = "YAG:Ce3+ nanostructured particles obtained via spray pyrolysis of polymeric precursor solution",
volume = "30",
number = "2",
pages = "577-582",
doi = "10.1016/j.jeurceramsoc.2009.05.037"
}
Mančić, L., Marinkovic, K., Marinković, B. A., Dramićanin, M.,& Milošević, O.. (2010). YAG:Ce3+ nanostructured particles obtained via spray pyrolysis of polymeric precursor solution. in Journal of the European Ceramic Society, 30(2), 577-582.
https://doi.org/10.1016/j.jeurceramsoc.2009.05.037
Mančić L, Marinkovic K, Marinković BA, Dramićanin M, Milošević O. YAG:Ce3+ nanostructured particles obtained via spray pyrolysis of polymeric precursor solution. in Journal of the European Ceramic Society. 2010;30(2):577-582.
doi:10.1016/j.jeurceramsoc.2009.05.037 .
Mančić, Lidija, Marinkovic, K., Marinković, Bojan A., Dramićanin, Miroslav, Milošević, Olivera, "YAG:Ce3+ nanostructured particles obtained via spray pyrolysis of polymeric precursor solution" in Journal of the European Ceramic Society, 30, no. 2 (2010):577-582,
https://doi.org/10.1016/j.jeurceramsoc.2009.05.037 . .
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