Babić, Biljana M.

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Authority KeyName Variants
4c393981-6192-4ab1-bb9f-c3aa9f6be3f3
  • Babić, Biljana M. (114)
Projects
Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine Development, characterization and application nanostructured and composite electrocatalysts and interactive supports for fuel cells and water electrolysis
Physics of nanostructured oxide materials and strongly correlated systems Nanostructured multifunctional materials and nanocomposites
Nanostrukturni neoksidni keramički i karbonski materijali i njihovi kompoziti Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden
Lithium-ion batteries and fuel cells - research and development Development of Methods of Monitoring and Removal of Biologically Actives Substances Aimed at Improving the Quality of the Environment
Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231] Reinforcing of Nanotechnology and Functional Materials Centre
Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals Physics and Chemistry with Ion Beams
Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing SASA [F-134], Swiss National Science Foundation [IZ73Z0-128169]
H2FC - Integrating European Infrastructure to support science and development of Hydrogen- and Fuel Cell Technologies towards European Strategy for Sustainable, Competitive and Secure Energy Optoelectronics nanodimension systems - the rout towards applications
Implementation of new technical, technological and environmental solutions in the mining and metallurgical operations RBB and RBM Ministry of Education, Science and Technological Development of the Republic of Serbia
Ministry of Science and Technological Development, Republic of Serbia [142038], US Department of Energy [DE-AC02-05CH11231] Nanotechnology and Functional Materials Center, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
A. von Humboldt Foundation Bilateral cooperation with Slovenia [451-033095/2014-09/32]
Grant Agency of the Czech Republic [P206/12/G151] Efficient use of resources in energy converting applications
Thin films of single wall carbon nanotubes and graphene for electronic application Oxide-based environmentally-friendly porous materials for genotoxic substances removal
Studies of enzyme interactions with toxic and pharmacologically active molecules Hydrogen Energy - Research and Development of New Materials: Electrolytic Hydrogen Production, Hydrogen Fuel Cells, Isotope Effects
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200287 (Innovation Center of the Faculty of Technology and Metallurgy)

Author's Bibliography

Ekstrakcija estrogenih hormona iz vode korišćenjem ugljeničnog kriogela kao sorbenta

Prokić, Danijela; Vukčević, Marija; Maletić, Marina; Kalijadis, Ana; Babić, Biljana M.; Janković-Častvan, Ivona; Đurkić, Tatjana

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS) : Društvo za procesnu tehniku, 2021)

TY  - CONF
AU  - Prokić, Danijela
AU  - Vukčević, Marija
AU  - Maletić, Marina
AU  - Kalijadis, Ana
AU  - Babić, Biljana M.
AU  - Janković-Častvan, Ivona
AU  - Đurkić, Tatjana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11598
AB  - Za ekstrakciju estrogenih hormona (estrona, 17β-estradiola i 17α-etinilestradiola) iz vodenih rastvora metodom ekstrakcije na čvrstoj fazi, u ovom radu korišćen je ugljenični kriogel kao sorbent. Metoda ekstrakcije na čvrstoj fazi optimizovana je izborom odgovarajuće mase sorbenta, zapremine i početne pH vrednosti vodenog rastvora hormona, kao i odabirom organskog rastvarača za eluira-nje. Koncentracija ispitivanih hormona u rastvoru nakon ekstrakcije određivana je metodom tečne hromatografije visoke performance u sprezi sa tandem masenom spektrometrijom. Na osnovu prinosa ispitivanih hormona, dobijeni su optimalni parametri metode ekstrakcije na čvrstoj fazi za predkon-centrisanje hormona iz vodenog rastvora: ekstrakcija hormona iz 100 cm3 vodenog rastvora, početne pH vrednosti podešene na 7, vrši se na 20 mg sorpcionog materijala, a smeša dihlormetan/methanol koristi se kao organski rastvarač za eluiranje. Vrednosti prinosa, dobijenih pri optimalnim uslovima, iznosile su od 77 % za estron, do 86 % za 17β-estradiol, uz relativnu standardnu devijaciju od 7,4 do 18 %.
AB  - In this study, carbon cryogel was used as solid-phase extraction sorbent for the extraction of estrogenic hormones (estrone, 17β-estradiol, and 17α-ethinylestradiol) from water solution.
The solid-phase extraction (SPE) method was optimized by choosing an appropriate mass of the sorbent, volume, and initial pH of estrogenic hormone water solution, as well as by choosing an appropriate organic solvent. The concentration of tested hormones after extraction was measured by liquid
chromatography coupled with tandem mass spectrometry. Based on the obtained hormone recoveries, the following optimal conditions of the SPE procedure were chosen: 100 cm3
of hormone water
solution at initial pH adjusted to 7, 20 mg of the sorbent, the methanol-dichloromethane mixture was
used for hormone elution. Recoveries obtained under the optimal conditions ranged from 77 % for
estrone, to 86 % for 17β-estradiol, with relative standard deviation from 7,4 to 18 %.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS) : Društvo za procesnu tehniku
C3  - 34. Međunarodni kongres o procesnoj industriji - PROCESING ′21 : zbornik radova
T1  - Ekstrakcija estrogenih hormona iz vode korišćenjem ugljeničnog kriogela kao sorbenta
T1  - Extraction of estrogen hormones from water using
carbon cryogel as sorbent
SP  - 123
EP  - 127
DO  - 10.24094/ptk.021.34.1.123
ER  - 
@conference{
author = "Prokić, Danijela and Vukčević, Marija and Maletić, Marina and Kalijadis, Ana and Babić, Biljana M. and Janković-Častvan, Ivona and Đurkić, Tatjana",
year = "2021",
abstract = "Za ekstrakciju estrogenih hormona (estrona, 17β-estradiola i 17α-etinilestradiola) iz vodenih rastvora metodom ekstrakcije na čvrstoj fazi, u ovom radu korišćen je ugljenični kriogel kao sorbent. Metoda ekstrakcije na čvrstoj fazi optimizovana je izborom odgovarajuće mase sorbenta, zapremine i početne pH vrednosti vodenog rastvora hormona, kao i odabirom organskog rastvarača za eluira-nje. Koncentracija ispitivanih hormona u rastvoru nakon ekstrakcije određivana je metodom tečne hromatografije visoke performance u sprezi sa tandem masenom spektrometrijom. Na osnovu prinosa ispitivanih hormona, dobijeni su optimalni parametri metode ekstrakcije na čvrstoj fazi za predkon-centrisanje hormona iz vodenog rastvora: ekstrakcija hormona iz 100 cm3 vodenog rastvora, početne pH vrednosti podešene na 7, vrši se na 20 mg sorpcionog materijala, a smeša dihlormetan/methanol koristi se kao organski rastvarač za eluiranje. Vrednosti prinosa, dobijenih pri optimalnim uslovima, iznosile su od 77 % za estron, do 86 % za 17β-estradiol, uz relativnu standardnu devijaciju od 7,4 do 18 %., In this study, carbon cryogel was used as solid-phase extraction sorbent for the extraction of estrogenic hormones (estrone, 17β-estradiol, and 17α-ethinylestradiol) from water solution.
The solid-phase extraction (SPE) method was optimized by choosing an appropriate mass of the sorbent, volume, and initial pH of estrogenic hormone water solution, as well as by choosing an appropriate organic solvent. The concentration of tested hormones after extraction was measured by liquid
chromatography coupled with tandem mass spectrometry. Based on the obtained hormone recoveries, the following optimal conditions of the SPE procedure were chosen: 100 cm3
of hormone water
solution at initial pH adjusted to 7, 20 mg of the sorbent, the methanol-dichloromethane mixture was
used for hormone elution. Recoveries obtained under the optimal conditions ranged from 77 % for
estrone, to 86 % for 17β-estradiol, with relative standard deviation from 7,4 to 18 %.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS) : Društvo za procesnu tehniku",
journal = "34. Međunarodni kongres o procesnoj industriji - PROCESING ′21 : zbornik radova",
title = "Ekstrakcija estrogenih hormona iz vode korišćenjem ugljeničnog kriogela kao sorbenta, Extraction of estrogen hormones from water using
carbon cryogel as sorbent",
pages = "123-127",
doi = "10.24094/ptk.021.34.1.123"
}
Prokić, D., Vukčević, M., Maletić, M., Kalijadis, A., Babić, B. M., Janković-Častvan, I.,& Đurkić, T.. (2021). Ekstrakcija estrogenih hormona iz vode korišćenjem ugljeničnog kriogela kao sorbenta. in 34. Međunarodni kongres o procesnoj industriji - PROCESING ′21 : zbornik radova
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS) : Društvo za procesnu tehniku., 123-127.
https://doi.org/10.24094/ptk.021.34.1.123
Prokić D, Vukčević M, Maletić M, Kalijadis A, Babić BM, Janković-Častvan I, Đurkić T. Ekstrakcija estrogenih hormona iz vode korišćenjem ugljeničnog kriogela kao sorbenta. in 34. Međunarodni kongres o procesnoj industriji - PROCESING ′21 : zbornik radova. 2021;:123-127.
doi:10.24094/ptk.021.34.1.123 .
Prokić, Danijela, Vukčević, Marija, Maletić, Marina, Kalijadis, Ana, Babić, Biljana M., Janković-Častvan, Ivona, Đurkić, Tatjana, "Ekstrakcija estrogenih hormona iz vode korišćenjem ugljeničnog kriogela kao sorbenta" in 34. Međunarodni kongres o procesnoj industriji - PROCESING ′21 : zbornik radova (2021):123-127,
https://doi.org/10.24094/ptk.021.34.1.123 . .

In-situ immobilization of Sr radioactive isotope using nanocrystalline hydroxyapatite

Prekajski-Đorđević, Marija D.; Maletaškić, Jelena; Stanković, Nadežda; Babić, Biljana M.; Yoshida, Katsumi; Yano, Toyohiko; Matović, Branko

(2018)

TY  - JOUR
AU  - Prekajski-Đorđević, Marija D.
AU  - Maletaškić, Jelena
AU  - Stanković, Nadežda
AU  - Babić, Biljana M.
AU  - Yoshida, Katsumi
AU  - Yano, Toyohiko
AU  - Matović, Branko
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1874
AB  - Hydroxyapatite was used as the inert matrix for in-situ immobilization of strontium (Sr) radioactive isotopes at room temperature. A nano-emulsification method was applied to synthesize Sr-substituted calcium hydroxyapatite (Ca1-xSrx)PO4)(6)(OH)(2). The concentration of incorporated Sr was in the range of 0 LT = x LT = 1. Immobilization of Sr was evaluated using a stable isotope instead of radioactive isotope. The effect of strontium concentration on the crystal structure was studied and the results have showed that in the whole concentration range, Sr forms solid solutions with the host hydroxyapatite crystal structure. Powders comprised of nanometre sized particles were obtained and their properties, such as crystallite and particle size, changes in lattice parameters as function of dopant content and thermal stability, were further examined. It was found that the crystal structure of obtained powders is thermally stable at high temperatures. No secondary phases were formed in as-prepared powders or during calcination. The results in this study showed that nano-emulsion strategy provides a simple pathway for synthesis of a single-phase Sr-substituted hydroxyapatite, which can be used for immobilization of Sr radioactive isotopes.
T2  - Ceramics International
T1  - In-situ immobilization of Sr radioactive isotope using nanocrystalline hydroxyapatite
VL  - 44
IS  - 2
SP  - 1771
EP  - 1777
DO  - 10.1016/j.ceramint.2017.10.110
ER  - 
@article{
author = "Prekajski-Đorđević, Marija D. and Maletaškić, Jelena and Stanković, Nadežda and Babić, Biljana M. and Yoshida, Katsumi and Yano, Toyohiko and Matović, Branko",
year = "2018",
abstract = "Hydroxyapatite was used as the inert matrix for in-situ immobilization of strontium (Sr) radioactive isotopes at room temperature. A nano-emulsification method was applied to synthesize Sr-substituted calcium hydroxyapatite (Ca1-xSrx)PO4)(6)(OH)(2). The concentration of incorporated Sr was in the range of 0 LT = x LT = 1. Immobilization of Sr was evaluated using a stable isotope instead of radioactive isotope. The effect of strontium concentration on the crystal structure was studied and the results have showed that in the whole concentration range, Sr forms solid solutions with the host hydroxyapatite crystal structure. Powders comprised of nanometre sized particles were obtained and their properties, such as crystallite and particle size, changes in lattice parameters as function of dopant content and thermal stability, were further examined. It was found that the crystal structure of obtained powders is thermally stable at high temperatures. No secondary phases were formed in as-prepared powders or during calcination. The results in this study showed that nano-emulsion strategy provides a simple pathway for synthesis of a single-phase Sr-substituted hydroxyapatite, which can be used for immobilization of Sr radioactive isotopes.",
journal = "Ceramics International",
title = "In-situ immobilization of Sr radioactive isotope using nanocrystalline hydroxyapatite",
volume = "44",
number = "2",
pages = "1771-1777",
doi = "10.1016/j.ceramint.2017.10.110"
}
Prekajski-Đorđević, M. D., Maletaškić, J., Stanković, N., Babić, B. M., Yoshida, K., Yano, T.,& Matović, B.. (2018). In-situ immobilization of Sr radioactive isotope using nanocrystalline hydroxyapatite. in Ceramics International, 44(2), 1771-1777.
https://doi.org/10.1016/j.ceramint.2017.10.110
Prekajski-Đorđević MD, Maletaškić J, Stanković N, Babić BM, Yoshida K, Yano T, Matović B. In-situ immobilization of Sr radioactive isotope using nanocrystalline hydroxyapatite. in Ceramics International. 2018;44(2):1771-1777.
doi:10.1016/j.ceramint.2017.10.110 .
Prekajski-Đorđević, Marija D., Maletaškić, Jelena, Stanković, Nadežda, Babić, Biljana M., Yoshida, Katsumi, Yano, Toyohiko, Matović, Branko, "In-situ immobilization of Sr radioactive isotope using nanocrystalline hydroxyapatite" in Ceramics International, 44, no. 2 (2018):1771-1777,
https://doi.org/10.1016/j.ceramint.2017.10.110 . .
14
8
14

Structural and photocatalytic examination of CoMoO4 nanopowders synthesized by GNP method

Rosić, Milena; Zarubica, Aleksandra R.; Šaponjić, Aleksandra; Babić, Biljana M.; Zagorac, Jelena B.; Jordanov, Dragana; Matović, Branko

(2018)

TY  - JOUR
AU  - Rosić, Milena
AU  - Zarubica, Aleksandra R.
AU  - Šaponjić, Aleksandra
AU  - Babić, Biljana M.
AU  - Zagorac, Jelena B.
AU  - Jordanov, Dragana
AU  - Matović, Branko
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1876
AB  - The synthesis route by solution combustion, a glycine nitrate procedure (GNP) of CoMoO4 nanopowders by a glycine as a fuel and as a complexant was examined concerning the photocatalytic aspects and powder characteristics. The synthesized samples were investigated by differential thermal analysis (DTA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Ultraviolet-Visible (UV/Vis) spectroscopy and nitrogen adsorption method. In this work, we presented a simple and effective method for controlling the composition and morphology of CoMoO4. A single-phase a and 13 crystalline form of CoMoO4 compound was confirmed by X-ray diffraction (XRD). The photocatalytic activity of CoMoO4 nanopowders was estimated by the photocatalytic degradation of crystal violet in aqueous solution. In addition, the obtained specific CoMoO4 nanopowder demonstrated acceptable specific surface area, which can be of particular importance for the photocatalytic processes.
T2  - Materials Research Bulletin
T1  - Structural and photocatalytic examination of CoMoO4 nanopowders synthesized by GNP method
VL  - 98
SP  - 111
EP  - 120
DO  - 10.1016/j.materresbull.2017.10.015
ER  - 
@article{
author = "Rosić, Milena and Zarubica, Aleksandra R. and Šaponjić, Aleksandra and Babić, Biljana M. and Zagorac, Jelena B. and Jordanov, Dragana and Matović, Branko",
year = "2018",
abstract = "The synthesis route by solution combustion, a glycine nitrate procedure (GNP) of CoMoO4 nanopowders by a glycine as a fuel and as a complexant was examined concerning the photocatalytic aspects and powder characteristics. The synthesized samples were investigated by differential thermal analysis (DTA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Ultraviolet-Visible (UV/Vis) spectroscopy and nitrogen adsorption method. In this work, we presented a simple and effective method for controlling the composition and morphology of CoMoO4. A single-phase a and 13 crystalline form of CoMoO4 compound was confirmed by X-ray diffraction (XRD). The photocatalytic activity of CoMoO4 nanopowders was estimated by the photocatalytic degradation of crystal violet in aqueous solution. In addition, the obtained specific CoMoO4 nanopowder demonstrated acceptable specific surface area, which can be of particular importance for the photocatalytic processes.",
journal = "Materials Research Bulletin",
title = "Structural and photocatalytic examination of CoMoO4 nanopowders synthesized by GNP method",
volume = "98",
pages = "111-120",
doi = "10.1016/j.materresbull.2017.10.015"
}
Rosić, M., Zarubica, A. R., Šaponjić, A., Babić, B. M., Zagorac, J. B., Jordanov, D.,& Matović, B.. (2018). Structural and photocatalytic examination of CoMoO4 nanopowders synthesized by GNP method. in Materials Research Bulletin, 98, 111-120.
https://doi.org/10.1016/j.materresbull.2017.10.015
Rosić M, Zarubica AR, Šaponjić A, Babić BM, Zagorac JB, Jordanov D, Matović B. Structural and photocatalytic examination of CoMoO4 nanopowders synthesized by GNP method. in Materials Research Bulletin. 2018;98:111-120.
doi:10.1016/j.materresbull.2017.10.015 .
Rosić, Milena, Zarubica, Aleksandra R., Šaponjić, Aleksandra, Babić, Biljana M., Zagorac, Jelena B., Jordanov, Dragana, Matović, Branko, "Structural and photocatalytic examination of CoMoO4 nanopowders synthesized by GNP method" in Materials Research Bulletin, 98 (2018):111-120,
https://doi.org/10.1016/j.materresbull.2017.10.015 . .
20
13
21

Sol-gel Synthesis of Anatase Nanopowders for Efficient Photocatalytic Degradation of Herbicide Clomazone in Aqueous Media

Golubović, Aleksandar V.; Simović, Bojana; Gašić, Slavica M.; Mijin, Dušan Ž.; Matković, Aleksandar; Babić, Biljana M.; Šćepanović, Maja

(2017)

TY  - JOUR
AU  - Golubović, Aleksandar V.
AU  - Simović, Bojana
AU  - Gašić, Slavica M.
AU  - Mijin, Dušan Ž.
AU  - Matković, Aleksandar
AU  - Babić, Biljana M.
AU  - Šćepanović, Maja
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1779
AB  - TiO2 nanopowders were produced by sol-gel technique using TiCl4 as a starting material. For the preparation of crystalline anatase with developed surface area, this aqueous solution has been mixed with 0.05 M or 0.07 M (NH4)(2)SO4 solution in a temperature-controlled bath. The pH values of the suspension were 7, 8 or 9. According to the x-ray diffraction (XRD) analysis the anatase crystallite sizes were about 12 nm, which coincided with the average particle size revealed by scanning electron microscopy (SEM). The Raman scattering measurements have shown the presence of a small amount of highly disordered brookite phase in addition to dominant anatase phase with similar nanostructure in all synthesized powders. BET measurements revealed that all synthesized catalysts were fully mesoporous, except the sample synthesized with 0.07 M (NH4)(2)SO4 at pH=9, which had small amount of micropores. The photocatalytic degradation of herbicide Clomazone was carried out for both the pure active substance and as the commercial product (GAMIT 4-EC) under UV irradiation. The best photocatalytic efficiency was obtained for the catalyst with the largest specific surface area, confirming this parameter as crucial for enhanced photocatalytic degradation of the pure active substance and commercial product of herbicide Clomazone.
T2  - Science of Sintering
T1  - Sol-gel Synthesis of Anatase Nanopowders for Efficient Photocatalytic Degradation of Herbicide Clomazone in Aqueous Media
VL  - 49
IS  - 3
SP  - 319
EP  - 330
DO  - 10.2298/SOS1703319G
ER  - 
@article{
author = "Golubović, Aleksandar V. and Simović, Bojana and Gašić, Slavica M. and Mijin, Dušan Ž. and Matković, Aleksandar and Babić, Biljana M. and Šćepanović, Maja",
year = "2017",
abstract = "TiO2 nanopowders were produced by sol-gel technique using TiCl4 as a starting material. For the preparation of crystalline anatase with developed surface area, this aqueous solution has been mixed with 0.05 M or 0.07 M (NH4)(2)SO4 solution in a temperature-controlled bath. The pH values of the suspension were 7, 8 or 9. According to the x-ray diffraction (XRD) analysis the anatase crystallite sizes were about 12 nm, which coincided with the average particle size revealed by scanning electron microscopy (SEM). The Raman scattering measurements have shown the presence of a small amount of highly disordered brookite phase in addition to dominant anatase phase with similar nanostructure in all synthesized powders. BET measurements revealed that all synthesized catalysts were fully mesoporous, except the sample synthesized with 0.07 M (NH4)(2)SO4 at pH=9, which had small amount of micropores. The photocatalytic degradation of herbicide Clomazone was carried out for both the pure active substance and as the commercial product (GAMIT 4-EC) under UV irradiation. The best photocatalytic efficiency was obtained for the catalyst with the largest specific surface area, confirming this parameter as crucial for enhanced photocatalytic degradation of the pure active substance and commercial product of herbicide Clomazone.",
journal = "Science of Sintering",
title = "Sol-gel Synthesis of Anatase Nanopowders for Efficient Photocatalytic Degradation of Herbicide Clomazone in Aqueous Media",
volume = "49",
number = "3",
pages = "319-330",
doi = "10.2298/SOS1703319G"
}
Golubović, A. V., Simović, B., Gašić, S. M., Mijin, D. Ž., Matković, A., Babić, B. M.,& Šćepanović, M.. (2017). Sol-gel Synthesis of Anatase Nanopowders for Efficient Photocatalytic Degradation of Herbicide Clomazone in Aqueous Media. in Science of Sintering, 49(3), 319-330.
https://doi.org/10.2298/SOS1703319G
Golubović AV, Simović B, Gašić SM, Mijin DŽ, Matković A, Babić BM, Šćepanović M. Sol-gel Synthesis of Anatase Nanopowders for Efficient Photocatalytic Degradation of Herbicide Clomazone in Aqueous Media. in Science of Sintering. 2017;49(3):319-330.
doi:10.2298/SOS1703319G .
Golubović, Aleksandar V., Simović, Bojana, Gašić, Slavica M., Mijin, Dušan Ž., Matković, Aleksandar, Babić, Biljana M., Šćepanović, Maja, "Sol-gel Synthesis of Anatase Nanopowders for Efficient Photocatalytic Degradation of Herbicide Clomazone in Aqueous Media" in Science of Sintering, 49, no. 3 (2017):319-330,
https://doi.org/10.2298/SOS1703319G . .
2
2

A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim

Kalijadis, Ana; Đorđević, Jelena S.; Papp, Zsigmond; Jokić, Bojan M.; Spasojević, Vuk D.; Babić, Biljana M.; Trtić-Petrović, Tatjana M.

(2017)

TY  - JOUR
AU  - Kalijadis, Ana
AU  - Đorđević, Jelena S.
AU  - Papp, Zsigmond
AU  - Jokić, Bojan M.
AU  - Spasojević, Vuk D.
AU  - Babić, Biljana M.
AU  - Trtić-Petrović, Tatjana M.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1867
AB  - In this work, a new carbon paste electrode, prepared from nitrogen-doped hydrothermal carbon (CHTCN) was applied for the electrochemical detection and determination of carbendazim fungicide. CHTCN samples with the nominal nitrogen content 0.05-0.5 wt. % in glucose precursor were prepared by simple, low-cost synthesis with the accompanying carbonization to 1273 K. The presence of nitrogen in CHTCN samples was confirmed by elemental analysis. Characterization of CHTCN as material for carbon paste electrode was achieved by cyclic voltammetry measurement of the Fe(CN)(6)(3-/4-) redox couple. The results showed that best electrochemical response was obtained from the sample with a nominal nitrogen concentration of 0.1 wt. % and with tricresyl phosphate as a binder. During the development of a differential pulse stripping voltammetric method for carbendazim determination applying new electrode, the following experimental parameters were studied: the sort and amount of binding liquid, the effect of pH, accumulation potential and accumulation time. Under optimal conditions, the electrode offered linearity in the wide concentration range from 25 to 490 ng cm(-3) and an estimated detection limit of 1.21 ng cm(-3). Moreover, the electrode showed good stability, high selectivity and satisfactory anti-interference ability. Finally, the developed method was successfully applied for the determination of carbendazim traces in spiked tap and river water samples.
T2  - Journal of the Serbian Chemical Society
T1  - A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim
VL  - 82
IS  - 11
SP  - 1259
EP  - 1272
DO  - 10.2298/JSC161228053K
ER  - 
@article{
author = "Kalijadis, Ana and Đorđević, Jelena S. and Papp, Zsigmond and Jokić, Bojan M. and Spasojević, Vuk D. and Babić, Biljana M. and Trtić-Petrović, Tatjana M.",
year = "2017",
abstract = "In this work, a new carbon paste electrode, prepared from nitrogen-doped hydrothermal carbon (CHTCN) was applied for the electrochemical detection and determination of carbendazim fungicide. CHTCN samples with the nominal nitrogen content 0.05-0.5 wt. % in glucose precursor were prepared by simple, low-cost synthesis with the accompanying carbonization to 1273 K. The presence of nitrogen in CHTCN samples was confirmed by elemental analysis. Characterization of CHTCN as material for carbon paste electrode was achieved by cyclic voltammetry measurement of the Fe(CN)(6)(3-/4-) redox couple. The results showed that best electrochemical response was obtained from the sample with a nominal nitrogen concentration of 0.1 wt. % and with tricresyl phosphate as a binder. During the development of a differential pulse stripping voltammetric method for carbendazim determination applying new electrode, the following experimental parameters were studied: the sort and amount of binding liquid, the effect of pH, accumulation potential and accumulation time. Under optimal conditions, the electrode offered linearity in the wide concentration range from 25 to 490 ng cm(-3) and an estimated detection limit of 1.21 ng cm(-3). Moreover, the electrode showed good stability, high selectivity and satisfactory anti-interference ability. Finally, the developed method was successfully applied for the determination of carbendazim traces in spiked tap and river water samples.",
journal = "Journal of the Serbian Chemical Society",
title = "A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim",
volume = "82",
number = "11",
pages = "1259-1272",
doi = "10.2298/JSC161228053K"
}
Kalijadis, A., Đorđević, J. S., Papp, Z., Jokić, B. M., Spasojević, V. D., Babić, B. M.,& Trtić-Petrović, T. M.. (2017). A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim. in Journal of the Serbian Chemical Society, 82(11), 1259-1272.
https://doi.org/10.2298/JSC161228053K
Kalijadis A, Đorđević JS, Papp Z, Jokić BM, Spasojević VD, Babić BM, Trtić-Petrović TM. A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim. in Journal of the Serbian Chemical Society. 2017;82(11):1259-1272.
doi:10.2298/JSC161228053K .
Kalijadis, Ana, Đorđević, Jelena S., Papp, Zsigmond, Jokić, Bojan M., Spasojević, Vuk D., Babić, Biljana M., Trtić-Petrović, Tatjana M., "A novel carbon paste electrode based on nitrogen-doped hydrothermal carbon for electrochemical determination of carbendazim" in Journal of the Serbian Chemical Society, 82, no. 11 (2017):1259-1272,
https://doi.org/10.2298/JSC161228053K . .
7
4
7

Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders

Matović, Branko; Luković, Jelena M.; Stojadinović, Bojan; Aškrabić, Sonja; Zarubica, Aleksandra R.; Babić, Biljana M.; Dohčević-Mitrović, Zorana

(2017)

TY  - JOUR
AU  - Matović, Branko
AU  - Luković, Jelena M.
AU  - Stojadinović, Bojan
AU  - Aškrabić, Sonja
AU  - Zarubica, Aleksandra R.
AU  - Babić, Biljana M.
AU  - Dohčević-Mitrović, Zorana 
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1905
AB  - Nanosized Mg-doped ceria powders were obtained by self-propagating room temperature reaction without using surfactants or templates. X-ray diffraction analysis and field emission scanning microscopy results showed that the doped samples are solid solutions with fluorite-type structure and spherical morphology. Raman spectra revealed an increase in the amount of oxygen vacancies with the increase of Mg concentration. This increasing results in a narrowing of the bandgap of CeO2. The photocatalytic performances of the Mg-doped ceria solid solutions were evaluated by decomposing an organic dye, crystal violet under UV irradiation. The Mg-doped ceria solid solutions exhibit significantly better photocatalytic activity than the pure CeO2 and commercial TiO2. The higher first rate constant of the Mg-doped samples demonstrated that they are much more efficient than TiO2 and CeO2 under UV light. Mg2+ dopant ions and oxygen vacancies play a significant role in the enhancement of photocatalytic performances of the Mg-doped ceria.
T2  - Processing and Application of Ceramics
T1  - Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders
VL  - 11
IS  - 4
SP  - 304
EP  - 310
DO  - 10.2298/PAC1704304M
ER  - 
@article{
author = "Matović, Branko and Luković, Jelena M. and Stojadinović, Bojan and Aškrabić, Sonja and Zarubica, Aleksandra R. and Babić, Biljana M. and Dohčević-Mitrović, Zorana ",
year = "2017",
abstract = "Nanosized Mg-doped ceria powders were obtained by self-propagating room temperature reaction without using surfactants or templates. X-ray diffraction analysis and field emission scanning microscopy results showed that the doped samples are solid solutions with fluorite-type structure and spherical morphology. Raman spectra revealed an increase in the amount of oxygen vacancies with the increase of Mg concentration. This increasing results in a narrowing of the bandgap of CeO2. The photocatalytic performances of the Mg-doped ceria solid solutions were evaluated by decomposing an organic dye, crystal violet under UV irradiation. The Mg-doped ceria solid solutions exhibit significantly better photocatalytic activity than the pure CeO2 and commercial TiO2. The higher first rate constant of the Mg-doped samples demonstrated that they are much more efficient than TiO2 and CeO2 under UV light. Mg2+ dopant ions and oxygen vacancies play a significant role in the enhancement of photocatalytic performances of the Mg-doped ceria.",
journal = "Processing and Application of Ceramics",
title = "Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders",
volume = "11",
number = "4",
pages = "304-310",
doi = "10.2298/PAC1704304M"
}
Matović, B., Luković, J. M., Stojadinović, B., Aškrabić, S., Zarubica, A. R., Babić, B. M.,& Dohčević-Mitrović, Z.. (2017). Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders. in Processing and Application of Ceramics, 11(4), 304-310.
https://doi.org/10.2298/PAC1704304M
Matović B, Luković JM, Stojadinović B, Aškrabić S, Zarubica AR, Babić BM, Dohčević-Mitrović Z. Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders. in Processing and Application of Ceramics. 2017;11(4):304-310.
doi:10.2298/PAC1704304M .
Matović, Branko, Luković, Jelena M., Stojadinović, Bojan, Aškrabić, Sonja, Zarubica, Aleksandra R., Babić, Biljana M., Dohčević-Mitrović, Zorana , "Influence of Mg doping on structural, optical and photocatalytic performances of ceria nanopowders" in Processing and Application of Ceramics, 11, no. 4 (2017):304-310,
https://doi.org/10.2298/PAC1704304M . .
5
2
7

Enhanced photocatalytic degradation of RO16 dye using Ag modified ZnO nanopowders prepared by the solvothermal method

Simović, Bojana; Poleti, Dejan; Golubović, Aleksandar V.; Matković, Aleksandar; Šćepanović, Maja; Babić, Biljana M.; Branković, Goran O.

(2017)

TY  - JOUR
AU  - Simović, Bojana
AU  - Poleti, Dejan
AU  - Golubović, Aleksandar V.
AU  - Matković, Aleksandar
AU  - Šćepanović, Maja
AU  - Babić, Biljana M.
AU  - Branković, Goran O.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1523
AB  - In this work, Zn(CH3 COO)(2) 2 H-2 O with AgNO3 content from 0 to 6 mol% was solvothermally treated at 120 C for 18 h in the presence of poly(vinyl pyrrolidone), ethylene glycol and sodium hydroxide. The structural , microstructural and photocatalytic properties of the unmodified and Ag modified ZnO powders have been investigated by the XRPD, FESEM, TEM, UV-vis, Raman and BET techniques. The Ag modified samples consist of ZnO nanocrystals and metallic Ag on the surface. The average crystallite size of all samples was about 20 nm. The FESEM revealed the uniformity in size and approximately spherical shape of ZnO nanopar-ticles. The BET data suggest that all prepared samples are mesoporous. All prepared samples showed higher photocatalytic efficiency in the degradation of the Reactive Orange 16 (RO16) azo dye than the commercial ZnO. In addition, Ag modified ZnO powders, especially those with 1.5 and 0.75 mol% of Ag, were more efficient than the unmodified one.
T2  - Processing and Application of Ceramics
T1  - Enhanced photocatalytic degradation of RO16 dye using Ag modified ZnO nanopowders prepared by the solvothermal method
VL  - 11
IS  - 1
SP  - 27
EP  - 38
DO  - 10.2298/PAC1701027S
ER  - 
@article{
author = "Simović, Bojana and Poleti, Dejan and Golubović, Aleksandar V. and Matković, Aleksandar and Šćepanović, Maja and Babić, Biljana M. and Branković, Goran O.",
year = "2017",
abstract = "In this work, Zn(CH3 COO)(2) 2 H-2 O with AgNO3 content from 0 to 6 mol% was solvothermally treated at 120 C for 18 h in the presence of poly(vinyl pyrrolidone), ethylene glycol and sodium hydroxide. The structural , microstructural and photocatalytic properties of the unmodified and Ag modified ZnO powders have been investigated by the XRPD, FESEM, TEM, UV-vis, Raman and BET techniques. The Ag modified samples consist of ZnO nanocrystals and metallic Ag on the surface. The average crystallite size of all samples was about 20 nm. The FESEM revealed the uniformity in size and approximately spherical shape of ZnO nanopar-ticles. The BET data suggest that all prepared samples are mesoporous. All prepared samples showed higher photocatalytic efficiency in the degradation of the Reactive Orange 16 (RO16) azo dye than the commercial ZnO. In addition, Ag modified ZnO powders, especially those with 1.5 and 0.75 mol% of Ag, were more efficient than the unmodified one.",
journal = "Processing and Application of Ceramics",
title = "Enhanced photocatalytic degradation of RO16 dye using Ag modified ZnO nanopowders prepared by the solvothermal method",
volume = "11",
number = "1",
pages = "27-38",
doi = "10.2298/PAC1701027S"
}
Simović, B., Poleti, D., Golubović, A. V., Matković, A., Šćepanović, M., Babić, B. M.,& Branković, G. O.. (2017). Enhanced photocatalytic degradation of RO16 dye using Ag modified ZnO nanopowders prepared by the solvothermal method. in Processing and Application of Ceramics, 11(1), 27-38.
https://doi.org/10.2298/PAC1701027S
Simović B, Poleti D, Golubović AV, Matković A, Šćepanović M, Babić BM, Branković GO. Enhanced photocatalytic degradation of RO16 dye using Ag modified ZnO nanopowders prepared by the solvothermal method. in Processing and Application of Ceramics. 2017;11(1):27-38.
doi:10.2298/PAC1701027S .
Simović, Bojana, Poleti, Dejan, Golubović, Aleksandar V., Matković, Aleksandar, Šćepanović, Maja, Babić, Biljana M., Branković, Goran O., "Enhanced photocatalytic degradation of RO16 dye using Ag modified ZnO nanopowders prepared by the solvothermal method" in Processing and Application of Ceramics, 11, no. 1 (2017):27-38,
https://doi.org/10.2298/PAC1701027S . .
13
9
12

Nanoporous activated carbon cloth as a versatile material for hydrogen adsorption, selective gas separation and electrochemical energy storage

Kostoglou, Nikolaos; Koczwara, Christian; Prehal, Christian; Terziyska, Velislava; Babić, Biljana M.; Matović, Branko; Constantinides, Georgios; Tampaxis, Christos; Charalambopoulou, Georgia; Steriotis, Theodore; Hinder, Steve; Baker, Mark; Polychronopoulou, Kyriaki; Doumanidis, Charalabos; Paris, Oskar; Mitterer, Christian; Rebholz, Claus

(2017)

TY  - JOUR
AU  - Kostoglou, Nikolaos
AU  - Koczwara, Christian
AU  - Prehal, Christian
AU  - Terziyska, Velislava
AU  - Babić, Biljana M.
AU  - Matović, Branko
AU  - Constantinides, Georgios
AU  - Tampaxis, Christos
AU  - Charalambopoulou, Georgia
AU  - Steriotis, Theodore
AU  - Hinder, Steve
AU  - Baker, Mark
AU  - Polychronopoulou, Kyriaki
AU  - Doumanidis, Charalabos
AU  - Paris, Oskar
AU  - Mitterer, Christian
AU  - Rebholz, Claus
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1749
AB  - The efficient storage of energy combined with a minimum carbon footprint is still considered one of the major challenges towards the transition to a progressive, sustainable and environmental friendly society on a global scale. The energy storage in pure chemical form using gas carriers with high heating values, including H-2 and CH4, as well as via electrochemical means using state-of-the-art devices, such as batteries or supercapacitors, are two of the most attractive alternatives for the combustion of finite, carbon-rich and environmentally harmful fossil fuels, such as diesel and gasoline. A few-step, reproducible and scalable method is presented in this study for the preparation of an ultra-microporous (average pore size around 0.6 nm) activated carbon cloth (ACC) with large specific area ( GT 1200 m(2)/g) and pore volume (similar to 0.5 cm(3)/g) upon combining chemical impregnation, carbonization and CO2 activation of a low-cost cellulose-based polymeric fabric. The ACC material shows a versatile character towards three different applications, including H2 storage via cryo-adsorption, separation of energy-dense CO2/CH4 mixtures via selective adsorption and electrochemical energy storage using super-capacitor technology. Fully reversible H-2 uptake capacities in excess of 3.1 wt% at 77 K and similar to 72 bar along with a significant heat of adsorption value of up to 8.4 kJ/mol for low surface coverage have been found. Upon incorporation of low-pressure sorption data in the ideal adsorbed solution theory model, the ACC is predicted to selectively adsorb about 4.5 times more CO2 than CH4 in ambient conditions and thus represents an appealing adsorbent for the purification of such gaseous mixtures. Finally, an electric double-layer capacitor device was assembled and tested for its electrochemical performance, constructed of binder-free and flexible ACC electrodes and aqueous CsCl electrolyte. The full-cell exhibits a gravimetric capacitance of similar to 121 F/g for a specific current of 0.02 A/g, which relative to the ACCs specific area, is superior to commercially available activated carbons. A capacitance retention of more than 97% was observed after 10,000 charging/discharging cycles, thus indicating the ACCs suitability for demanding and high-performance energy storage on a commercial scale. The enhanced performance in all tested applications seems to be attributed to the mean ultra-micropore size of the ACC material instead of the available specific area and/or pore volume.
T2  - Nano Energy
T1  - Nanoporous activated carbon cloth as a versatile material for hydrogen adsorption, selective gas separation and electrochemical energy storage
VL  - 40
SP  - 49
EP  - 64
DO  - 10.1016/j.nanoen.2017.07.056
ER  - 
@article{
author = "Kostoglou, Nikolaos and Koczwara, Christian and Prehal, Christian and Terziyska, Velislava and Babić, Biljana M. and Matović, Branko and Constantinides, Georgios and Tampaxis, Christos and Charalambopoulou, Georgia and Steriotis, Theodore and Hinder, Steve and Baker, Mark and Polychronopoulou, Kyriaki and Doumanidis, Charalabos and Paris, Oskar and Mitterer, Christian and Rebholz, Claus",
year = "2017",
abstract = "The efficient storage of energy combined with a minimum carbon footprint is still considered one of the major challenges towards the transition to a progressive, sustainable and environmental friendly society on a global scale. The energy storage in pure chemical form using gas carriers with high heating values, including H-2 and CH4, as well as via electrochemical means using state-of-the-art devices, such as batteries or supercapacitors, are two of the most attractive alternatives for the combustion of finite, carbon-rich and environmentally harmful fossil fuels, such as diesel and gasoline. A few-step, reproducible and scalable method is presented in this study for the preparation of an ultra-microporous (average pore size around 0.6 nm) activated carbon cloth (ACC) with large specific area ( GT 1200 m(2)/g) and pore volume (similar to 0.5 cm(3)/g) upon combining chemical impregnation, carbonization and CO2 activation of a low-cost cellulose-based polymeric fabric. The ACC material shows a versatile character towards three different applications, including H2 storage via cryo-adsorption, separation of energy-dense CO2/CH4 mixtures via selective adsorption and electrochemical energy storage using super-capacitor technology. Fully reversible H-2 uptake capacities in excess of 3.1 wt% at 77 K and similar to 72 bar along with a significant heat of adsorption value of up to 8.4 kJ/mol for low surface coverage have been found. Upon incorporation of low-pressure sorption data in the ideal adsorbed solution theory model, the ACC is predicted to selectively adsorb about 4.5 times more CO2 than CH4 in ambient conditions and thus represents an appealing adsorbent for the purification of such gaseous mixtures. Finally, an electric double-layer capacitor device was assembled and tested for its electrochemical performance, constructed of binder-free and flexible ACC electrodes and aqueous CsCl electrolyte. The full-cell exhibits a gravimetric capacitance of similar to 121 F/g for a specific current of 0.02 A/g, which relative to the ACCs specific area, is superior to commercially available activated carbons. A capacitance retention of more than 97% was observed after 10,000 charging/discharging cycles, thus indicating the ACCs suitability for demanding and high-performance energy storage on a commercial scale. The enhanced performance in all tested applications seems to be attributed to the mean ultra-micropore size of the ACC material instead of the available specific area and/or pore volume.",
journal = "Nano Energy",
title = "Nanoporous activated carbon cloth as a versatile material for hydrogen adsorption, selective gas separation and electrochemical energy storage",
volume = "40",
pages = "49-64",
doi = "10.1016/j.nanoen.2017.07.056"
}
Kostoglou, N., Koczwara, C., Prehal, C., Terziyska, V., Babić, B. M., Matović, B., Constantinides, G., Tampaxis, C., Charalambopoulou, G., Steriotis, T., Hinder, S., Baker, M., Polychronopoulou, K., Doumanidis, C., Paris, O., Mitterer, C.,& Rebholz, C.. (2017). Nanoporous activated carbon cloth as a versatile material for hydrogen adsorption, selective gas separation and electrochemical energy storage. in Nano Energy, 40, 49-64.
https://doi.org/10.1016/j.nanoen.2017.07.056
Kostoglou N, Koczwara C, Prehal C, Terziyska V, Babić BM, Matović B, Constantinides G, Tampaxis C, Charalambopoulou G, Steriotis T, Hinder S, Baker M, Polychronopoulou K, Doumanidis C, Paris O, Mitterer C, Rebholz C. Nanoporous activated carbon cloth as a versatile material for hydrogen adsorption, selective gas separation and electrochemical energy storage. in Nano Energy. 2017;40:49-64.
doi:10.1016/j.nanoen.2017.07.056 .
Kostoglou, Nikolaos, Koczwara, Christian, Prehal, Christian, Terziyska, Velislava, Babić, Biljana M., Matović, Branko, Constantinides, Georgios, Tampaxis, Christos, Charalambopoulou, Georgia, Steriotis, Theodore, Hinder, Steve, Baker, Mark, Polychronopoulou, Kyriaki, Doumanidis, Charalabos, Paris, Oskar, Mitterer, Christian, Rebholz, Claus, "Nanoporous activated carbon cloth as a versatile material for hydrogen adsorption, selective gas separation and electrochemical energy storage" in Nano Energy, 40 (2017):49-64,
https://doi.org/10.1016/j.nanoen.2017.07.056 . .
11
102
61
90

Mechanically activated carbonized rayon fibers as an electrochemical supercapacitor in aqueous solutions

Vujković, Milica; Matović, Ljiljana; Krstić, Jugoslav B.; Stojmenović, Marija; Đukić, Anđelka B.; Babić, Biljana M.; Mentus, Slavko V.

(2017)

TY  - JOUR
AU  - Vujković, Milica
AU  - Matović, Ljiljana
AU  - Krstić, Jugoslav B.
AU  - Stojmenović, Marija
AU  - Đukić, Anđelka B.
AU  - Babić, Biljana M.
AU  - Mentus, Slavko V.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1661
AB  - The activated carbon cloth (ACC), obtained by chemical/physical activation of carbonized rayon fibers, was grinded in a ball mill and studied from the aspect of double layer capacitance. The changes in pore structure, morphology and acid/basic properties caused by ball milling were studied by means of N-2 adsorption/desorption, Fourier-transformed infrared spectrometry, Boehms titration and Scanning Electron Microscopy. Both potentiodynamic and galvanostatic cycling were used to evaluate the double layer capacitance in three alkaline, acidic and neutral aqueous solutions (KOH, H2SO4 and Na2SO4). While double layer capacitance of original ACC was found to be negligible, ball milled material (ACCm) displayed capacitance in the range of supercapacitors. In order to explain this huge capacitance improvement, we found that ball milling substantially increased the concentration of lactone, phenolic and quinone groups on the surface. We suggest that these groups, through improved hydrophilicity, enable faster ion diffusion into carbon micropores. The energy density stored by double layer was highest in neutral sodium sulphate solution. Namely, operational voltage of similar to 2 V and double layer capacitance of 220 F g(-1) at 1A g(-1), enable the energy density of ACCm/Na2SO4/ACCm capacitor of 31.7 Wh kg(-1) at 2000 W kg(-1), much higher than that of commercial EDLC carbon capacitors. According to the here presented literature survey in a tabular form, the energy density of the studied sample is also higher from that of numerous thus far published aqueous carbon capacitors. (C) 2017 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Mechanically activated carbonized rayon fibers as an electrochemical supercapacitor in aqueous solutions
VL  - 245
SP  - 796
EP  - 806
DO  - 10.1016/j.electacta.2017.06.018
ER  - 
@article{
author = "Vujković, Milica and Matović, Ljiljana and Krstić, Jugoslav B. and Stojmenović, Marija and Đukić, Anđelka B. and Babić, Biljana M. and Mentus, Slavko V.",
year = "2017",
abstract = "The activated carbon cloth (ACC), obtained by chemical/physical activation of carbonized rayon fibers, was grinded in a ball mill and studied from the aspect of double layer capacitance. The changes in pore structure, morphology and acid/basic properties caused by ball milling were studied by means of N-2 adsorption/desorption, Fourier-transformed infrared spectrometry, Boehms titration and Scanning Electron Microscopy. Both potentiodynamic and galvanostatic cycling were used to evaluate the double layer capacitance in three alkaline, acidic and neutral aqueous solutions (KOH, H2SO4 and Na2SO4). While double layer capacitance of original ACC was found to be negligible, ball milled material (ACCm) displayed capacitance in the range of supercapacitors. In order to explain this huge capacitance improvement, we found that ball milling substantially increased the concentration of lactone, phenolic and quinone groups on the surface. We suggest that these groups, through improved hydrophilicity, enable faster ion diffusion into carbon micropores. The energy density stored by double layer was highest in neutral sodium sulphate solution. Namely, operational voltage of similar to 2 V and double layer capacitance of 220 F g(-1) at 1A g(-1), enable the energy density of ACCm/Na2SO4/ACCm capacitor of 31.7 Wh kg(-1) at 2000 W kg(-1), much higher than that of commercial EDLC carbon capacitors. According to the here presented literature survey in a tabular form, the energy density of the studied sample is also higher from that of numerous thus far published aqueous carbon capacitors. (C) 2017 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Mechanically activated carbonized rayon fibers as an electrochemical supercapacitor in aqueous solutions",
volume = "245",
pages = "796-806",
doi = "10.1016/j.electacta.2017.06.018"
}
Vujković, M., Matović, L., Krstić, J. B., Stojmenović, M., Đukić, A. B., Babić, B. M.,& Mentus, S. V.. (2017). Mechanically activated carbonized rayon fibers as an electrochemical supercapacitor in aqueous solutions. in Electrochimica Acta, 245, 796-806.
https://doi.org/10.1016/j.electacta.2017.06.018
Vujković M, Matović L, Krstić JB, Stojmenović M, Đukić AB, Babić BM, Mentus SV. Mechanically activated carbonized rayon fibers as an electrochemical supercapacitor in aqueous solutions. in Electrochimica Acta. 2017;245:796-806.
doi:10.1016/j.electacta.2017.06.018 .
Vujković, Milica, Matović, Ljiljana, Krstić, Jugoslav B., Stojmenović, Marija, Đukić, Anđelka B., Babić, Biljana M., Mentus, Slavko V., "Mechanically activated carbonized rayon fibers as an electrochemical supercapacitor in aqueous solutions" in Electrochimica Acta, 245 (2017):796-806,
https://doi.org/10.1016/j.electacta.2017.06.018 . .
27
19
27

Influence of Some Sol-Gel Synthesis Parameters of Mesoporous Tio2 on Photocatalytic Degradation of Pollutants

Golubović, Aleksandar V.; Veljkovic, Ivana; Šćepanović, Maja; Grujić-Brojčin, Mirjana; Tomić, Nataša; Mijin, Dušan Ž.; Babić, Biljana M.

(2016)

TY  - JOUR
AU  - Golubović, Aleksandar V.
AU  - Veljkovic, Ivana
AU  - Šćepanović, Maja
AU  - Grujić-Brojčin, Mirjana
AU  - Tomić, Nataša
AU  - Mijin, Dušan Ž.
AU  - Babić, Biljana M.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1020
AB  - Titanium dioxide (TiO2) nanopowders were produced by sol-gel technique from tetrabutyl titanate as a precursor by varying some parameters of the sol-gel synthesis, such as temperature (500 and 550 degrees C) and the duration of calcination (1.5, 2 and 2.5 h). X-ray powder diffraction (XRPD) results have shown that all synthesized nanopowders were dominantly in the anatase phase, with the presence of a small amount of rutile in samples calcined at 550 degrees C. According to the results obtained by the Williamson-Hall method, the anatase crystallite size was increased with the duration of the calcination (from 24 to 29 nm in samples calcined at lower temperature, and from 30 to 35 nm in samples calcined at higher temperature). The analysis of the shift and line-width of the most intensive anatase Eg Raman mode confirmed the XRPD results. The analysis of pore structure from nitrogen sorption experimental data described all samples as mesoporous, with mean pore diameters in the range of 5-8 nm. Nanopowder properties have been related to the photocatalytic activity, tested in degradation of the textile dye (C.I. Reactive Orange 16), car-bofuran ray scattering.
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Influence of Some Sol-Gel Synthesis Parameters of Mesoporous Tio2 on Photocatalytic Degradation of Pollutants
VL  - 22
IS  - 1
SP  - 65
EP  - 73
DO  - 10.2298/CICEQ150110020G
ER  - 
@article{
author = "Golubović, Aleksandar V. and Veljkovic, Ivana and Šćepanović, Maja and Grujić-Brojčin, Mirjana and Tomić, Nataša and Mijin, Dušan Ž. and Babić, Biljana M.",
year = "2016",
abstract = "Titanium dioxide (TiO2) nanopowders were produced by sol-gel technique from tetrabutyl titanate as a precursor by varying some parameters of the sol-gel synthesis, such as temperature (500 and 550 degrees C) and the duration of calcination (1.5, 2 and 2.5 h). X-ray powder diffraction (XRPD) results have shown that all synthesized nanopowders were dominantly in the anatase phase, with the presence of a small amount of rutile in samples calcined at 550 degrees C. According to the results obtained by the Williamson-Hall method, the anatase crystallite size was increased with the duration of the calcination (from 24 to 29 nm in samples calcined at lower temperature, and from 30 to 35 nm in samples calcined at higher temperature). The analysis of the shift and line-width of the most intensive anatase Eg Raman mode confirmed the XRPD results. The analysis of pore structure from nitrogen sorption experimental data described all samples as mesoporous, with mean pore diameters in the range of 5-8 nm. Nanopowder properties have been related to the photocatalytic activity, tested in degradation of the textile dye (C.I. Reactive Orange 16), car-bofuran ray scattering.",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Influence of Some Sol-Gel Synthesis Parameters of Mesoporous Tio2 on Photocatalytic Degradation of Pollutants",
volume = "22",
number = "1",
pages = "65-73",
doi = "10.2298/CICEQ150110020G"
}
Golubović, A. V., Veljkovic, I., Šćepanović, M., Grujić-Brojčin, M., Tomić, N., Mijin, D. Ž.,& Babić, B. M.. (2016). Influence of Some Sol-Gel Synthesis Parameters of Mesoporous Tio2 on Photocatalytic Degradation of Pollutants. in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 22(1), 65-73.
https://doi.org/10.2298/CICEQ150110020G
Golubović AV, Veljkovic I, Šćepanović M, Grujić-Brojčin M, Tomić N, Mijin DŽ, Babić BM. Influence of Some Sol-Gel Synthesis Parameters of Mesoporous Tio2 on Photocatalytic Degradation of Pollutants. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2016;22(1):65-73.
doi:10.2298/CICEQ150110020G .
Golubović, Aleksandar V., Veljkovic, Ivana, Šćepanović, Maja, Grujić-Brojčin, Mirjana, Tomić, Nataša, Mijin, Dušan Ž., Babić, Biljana M., "Influence of Some Sol-Gel Synthesis Parameters of Mesoporous Tio2 on Photocatalytic Degradation of Pollutants" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 22, no. 1 (2016):65-73,
https://doi.org/10.2298/CICEQ150110020G . .
2
3
3

Synthesis and characterization of Cr3+ doped TiO2 nanometric powders

Prekajski-Đorđević, Marija D.; Zarubica, Aleksandra R.; Babić, Biljana M.; Jokić, Bojan M.; Pantić, Jelena R.; Luković, Jelena M.; Matović, Branko

(Elsevier, 2016)

TY  - JOUR
AU  - Prekajski-Đorđević, Marija D.
AU  - Zarubica, Aleksandra R.
AU  - Babić, Biljana M.
AU  - Jokić, Bojan M.
AU  - Pantić, Jelena R.
AU  - Luković, Jelena M.
AU  - Matović, Branko
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/824
AB  - Simple route was used for synthesis of nanostructured titania samples doped with 3 and 6 mol% of Cr3+ Titanium(IV)-isopropoxide and water were used as starting materials and as an agents for controlling hydrolysis and condensation reactions. The phase evolution of titania (TiO2) was followed by calcination at 400, 600 and 800 degrees C. The synthesized powders were examined by field emission scanning electron microscopy (FESEM), and X-ray diffraction (XRD). Single-phase anatase was obtained at low temperature (400 degrees C) in all cases. The photocatalytic activity of TiO2 doped nanopowders was evaluated by the photocatalytic degradation of crystal violet in aqueous solution. The present study indicates that this simple synthesis method can be an effective route to produce efficient photoactive doped anatase nanopowders. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
PB  - Elsevier
T2  - Ceramics International
T1  - Synthesis and characterization of Cr3+ doped TiO2 nanometric powders
VL  - 42
IS  - 1
SP  - 1862
EP  - 1869
DO  - 10.1016/j.ceramint.2015.09.151
ER  - 
@article{
author = "Prekajski-Đorđević, Marija D. and Zarubica, Aleksandra R. and Babić, Biljana M. and Jokić, Bojan M. and Pantić, Jelena R. and Luković, Jelena M. and Matović, Branko",
year = "2016",
abstract = "Simple route was used for synthesis of nanostructured titania samples doped with 3 and 6 mol% of Cr3+ Titanium(IV)-isopropoxide and water were used as starting materials and as an agents for controlling hydrolysis and condensation reactions. The phase evolution of titania (TiO2) was followed by calcination at 400, 600 and 800 degrees C. The synthesized powders were examined by field emission scanning electron microscopy (FESEM), and X-ray diffraction (XRD). Single-phase anatase was obtained at low temperature (400 degrees C) in all cases. The photocatalytic activity of TiO2 doped nanopowders was evaluated by the photocatalytic degradation of crystal violet in aqueous solution. The present study indicates that this simple synthesis method can be an effective route to produce efficient photoactive doped anatase nanopowders. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Synthesis and characterization of Cr3+ doped TiO2 nanometric powders",
volume = "42",
number = "1",
pages = "1862-1869",
doi = "10.1016/j.ceramint.2015.09.151"
}
Prekajski-Đorđević, M. D., Zarubica, A. R., Babić, B. M., Jokić, B. M., Pantić, J. R., Luković, J. M.,& Matović, B.. (2016). Synthesis and characterization of Cr3+ doped TiO2 nanometric powders. in Ceramics International
Elsevier., 42(1), 1862-1869.
https://doi.org/10.1016/j.ceramint.2015.09.151
Prekajski-Đorđević MD, Zarubica AR, Babić BM, Jokić BM, Pantić JR, Luković JM, Matović B. Synthesis and characterization of Cr3+ doped TiO2 nanometric powders. in Ceramics International. 2016;42(1):1862-1869.
doi:10.1016/j.ceramint.2015.09.151 .
Prekajski-Đorđević, Marija D., Zarubica, Aleksandra R., Babić, Biljana M., Jokić, Bojan M., Pantić, Jelena R., Luković, Jelena M., Matović, Branko, "Synthesis and characterization of Cr3+ doped TiO2 nanometric powders" in Ceramics International, 42, no. 1 (2016):1862-1869,
https://doi.org/10.1016/j.ceramint.2015.09.151 . .
1
7
5
8

Iron doped anatase for application in photocatalysis

Babić, Biljana M.; Zarubica, Aleksandra R.; Minović-Arsić, Tamara; Pantić, Jelena R.; Jokić, Bojan M.; Abazović, Nadica; Matović, Branko

(2016)

TY  - JOUR
AU  - Babić, Biljana M.
AU  - Zarubica, Aleksandra R.
AU  - Minović-Arsić, Tamara
AU  - Pantić, Jelena R.
AU  - Jokić, Bojan M.
AU  - Abazović, Nadica
AU  - Matović, Branko
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1133
AB  - Titanium dioxide nanopowders, doped with different amount of Fe3+ ions (0.3-5.0 mass%), were synthesized by acid-catalyzed sol-gel method in a non-aqueous medium. The obtained powders were characterized by field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectrometry (EDX) and UV/vis spectroscopy. Degradation reaction of crystal violet (CV) azo dye is used to test the photocatalytic activity of iron doped titanium dioxide nanopowders. The results are correlated with previous investigations about the structure and physico-chemical characteristics of obtained nanopowders. (C) 2015 Elsevier Ltd. All rights reserved.
T2  - Journal of the European Ceramic Society
T1  - Iron doped anatase for application in photocatalysis
VL  - 36
IS  - 12
SP  - 2991
EP  - 2996
DO  - 10.1016/j.jeurceramsoc.2015.11.031
ER  - 
@article{
author = "Babić, Biljana M. and Zarubica, Aleksandra R. and Minović-Arsić, Tamara and Pantić, Jelena R. and Jokić, Bojan M. and Abazović, Nadica and Matović, Branko",
year = "2016",
abstract = "Titanium dioxide nanopowders, doped with different amount of Fe3+ ions (0.3-5.0 mass%), were synthesized by acid-catalyzed sol-gel method in a non-aqueous medium. The obtained powders were characterized by field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectrometry (EDX) and UV/vis spectroscopy. Degradation reaction of crystal violet (CV) azo dye is used to test the photocatalytic activity of iron doped titanium dioxide nanopowders. The results are correlated with previous investigations about the structure and physico-chemical characteristics of obtained nanopowders. (C) 2015 Elsevier Ltd. All rights reserved.",
journal = "Journal of the European Ceramic Society",
title = "Iron doped anatase for application in photocatalysis",
volume = "36",
number = "12",
pages = "2991-2996",
doi = "10.1016/j.jeurceramsoc.2015.11.031"
}
Babić, B. M., Zarubica, A. R., Minović-Arsić, T., Pantić, J. R., Jokić, B. M., Abazović, N.,& Matović, B.. (2016). Iron doped anatase for application in photocatalysis. in Journal of the European Ceramic Society, 36(12), 2991-2996.
https://doi.org/10.1016/j.jeurceramsoc.2015.11.031
Babić BM, Zarubica AR, Minović-Arsić T, Pantić JR, Jokić BM, Abazović N, Matović B. Iron doped anatase for application in photocatalysis. in Journal of the European Ceramic Society. 2016;36(12):2991-2996.
doi:10.1016/j.jeurceramsoc.2015.11.031 .
Babić, Biljana M., Zarubica, Aleksandra R., Minović-Arsić, Tamara, Pantić, Jelena R., Jokić, Bojan M., Abazović, Nadica, Matović, Branko, "Iron doped anatase for application in photocatalysis" in Journal of the European Ceramic Society, 36, no. 12 (2016):2991-2996,
https://doi.org/10.1016/j.jeurceramsoc.2015.11.031 . .
12
11
12

Arsenic(III) adsorption from aqueous solutions on novel carbon cryogel/ceria nanocomposite

Minović-Arsić, Tamara; Kalijadis, Ana; Matović, Branko; Stoiljković, Milovan; Pantić, Jelena R.; Jovanović, Jovan; Petrović, Rada; Jokić, Bojan M.; Babić, Biljana M.

(2016)

TY  - JOUR
AU  - Minović-Arsić, Tamara
AU  - Kalijadis, Ana
AU  - Matović, Branko
AU  - Stoiljković, Milovan
AU  - Pantić, Jelena R.
AU  - Jovanović, Jovan
AU  - Petrović, Rada
AU  - Jokić, Bojan M.
AU  - Babić, Biljana M.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1171
AB  - Carbon cryogel/ceria composite, with 10 wt.% of ceria, was synthesized by mixing of ceria and carbon cryogel (CC). The sample was characterized by field emission scanning electron microscopy, nitrogen adsorption and X-ray diffraction. The adsorption of arsenic(III) ions from aqueous solutions on carbon cryogel/ceria nanocomposite was studied as a function of time, solution pH and As(III) ion concentration. The results are correlated with previous investigations of adsorption mechanism of arsenic(III) on carbon cryogel. Adsorption dose experiments showed that the mass of the adsorbent was reduced for 20 times, in comparison with pure CC, for the same amount of adsorbed arsenic(III) ions. BET isotherm was used to interpret the experimental data for modelling liquid phase adsorption.
T2  - Processing and Application of Ceramics
T1  - Arsenic(III) adsorption from aqueous solutions on novel carbon cryogel/ceria nanocomposite
VL  - 10
IS  - 1
SP  - 17
EP  - 23
DO  - 10.2298/PAC1601017M
ER  - 
@article{
author = "Minović-Arsić, Tamara and Kalijadis, Ana and Matović, Branko and Stoiljković, Milovan and Pantić, Jelena R. and Jovanović, Jovan and Petrović, Rada and Jokić, Bojan M. and Babić, Biljana M.",
year = "2016",
abstract = "Carbon cryogel/ceria composite, with 10 wt.% of ceria, was synthesized by mixing of ceria and carbon cryogel (CC). The sample was characterized by field emission scanning electron microscopy, nitrogen adsorption and X-ray diffraction. The adsorption of arsenic(III) ions from aqueous solutions on carbon cryogel/ceria nanocomposite was studied as a function of time, solution pH and As(III) ion concentration. The results are correlated with previous investigations of adsorption mechanism of arsenic(III) on carbon cryogel. Adsorption dose experiments showed that the mass of the adsorbent was reduced for 20 times, in comparison with pure CC, for the same amount of adsorbed arsenic(III) ions. BET isotherm was used to interpret the experimental data for modelling liquid phase adsorption.",
journal = "Processing and Application of Ceramics",
title = "Arsenic(III) adsorption from aqueous solutions on novel carbon cryogel/ceria nanocomposite",
volume = "10",
number = "1",
pages = "17-23",
doi = "10.2298/PAC1601017M"
}
Minović-Arsić, T., Kalijadis, A., Matović, B., Stoiljković, M., Pantić, J. R., Jovanović, J., Petrović, R., Jokić, B. M.,& Babić, B. M.. (2016). Arsenic(III) adsorption from aqueous solutions on novel carbon cryogel/ceria nanocomposite. in Processing and Application of Ceramics, 10(1), 17-23.
https://doi.org/10.2298/PAC1601017M
Minović-Arsić T, Kalijadis A, Matović B, Stoiljković M, Pantić JR, Jovanović J, Petrović R, Jokić BM, Babić BM. Arsenic(III) adsorption from aqueous solutions on novel carbon cryogel/ceria nanocomposite. in Processing and Application of Ceramics. 2016;10(1):17-23.
doi:10.2298/PAC1601017M .
Minović-Arsić, Tamara, Kalijadis, Ana, Matović, Branko, Stoiljković, Milovan, Pantić, Jelena R., Jovanović, Jovan, Petrović, Rada, Jokić, Bojan M., Babić, Biljana M., "Arsenic(III) adsorption from aqueous solutions on novel carbon cryogel/ceria nanocomposite" in Processing and Application of Ceramics, 10, no. 1 (2016):17-23,
https://doi.org/10.2298/PAC1601017M . .
9
5
9

Synthesis and characterization of nanocrystaline hexagonal boron nitride powders: XRD and luminescence properties

Matović, Branko; Luković, Jelena M.; Nikolić, Marko; Babić, Biljana M.; Stanković, Nadežda; Jokić, Bojan M.; Jelenković, Branislav

(2016)

TY  - JOUR
AU  - Matović, Branko
AU  - Luković, Jelena M.
AU  - Nikolić, Marko
AU  - Babić, Biljana M.
AU  - Stanković, Nadežda
AU  - Jokić, Bojan M.
AU  - Jelenković, Branislav
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1260
AB  - Nanocrystalline hexagonal boron nitride powders (h-BN) were synthesized from urea and boric acid followed by pirolysis and subsequent heat treatment in nitrogen atmosphere. Materials have been analyzed by means of X-ray diffraction, Photoluminescence and Field emission electron microscopy methods. Obtained results show that starting h-BN powder, synthesized at 750 degrees C, is composed of similar to 11 layer crystallites with average crystallite thickness and crystallite lateral size of 3.94 and 10.4 nm, respectively. A broad emission and intense luminescence intensity were observed due to the large atomic disorder. Higher annealing temperature increases crystallite size and turbostratic h-BN transforms to well crystallized h-BN at 1500 degrees C. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Synthesis and characterization of nanocrystaline hexagonal boron nitride powders: XRD and luminescence properties
VL  - 42
IS  - 15
SP  - 16655
EP  - 16658
DO  - 10.1016/j.ceramint.2016.07.096
ER  - 
@article{
author = "Matović, Branko and Luković, Jelena M. and Nikolić, Marko and Babić, Biljana M. and Stanković, Nadežda and Jokić, Bojan M. and Jelenković, Branislav",
year = "2016",
abstract = "Nanocrystalline hexagonal boron nitride powders (h-BN) were synthesized from urea and boric acid followed by pirolysis and subsequent heat treatment in nitrogen atmosphere. Materials have been analyzed by means of X-ray diffraction, Photoluminescence and Field emission electron microscopy methods. Obtained results show that starting h-BN powder, synthesized at 750 degrees C, is composed of similar to 11 layer crystallites with average crystallite thickness and crystallite lateral size of 3.94 and 10.4 nm, respectively. A broad emission and intense luminescence intensity were observed due to the large atomic disorder. Higher annealing temperature increases crystallite size and turbostratic h-BN transforms to well crystallized h-BN at 1500 degrees C. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Synthesis and characterization of nanocrystaline hexagonal boron nitride powders: XRD and luminescence properties",
volume = "42",
number = "15",
pages = "16655-16658",
doi = "10.1016/j.ceramint.2016.07.096"
}
Matović, B., Luković, J. M., Nikolić, M., Babić, B. M., Stanković, N., Jokić, B. M.,& Jelenković, B.. (2016). Synthesis and characterization of nanocrystaline hexagonal boron nitride powders: XRD and luminescence properties. in Ceramics International, 42(15), 16655-16658.
https://doi.org/10.1016/j.ceramint.2016.07.096
Matović B, Luković JM, Nikolić M, Babić BM, Stanković N, Jokić BM, Jelenković B. Synthesis and characterization of nanocrystaline hexagonal boron nitride powders: XRD and luminescence properties. in Ceramics International. 2016;42(15):16655-16658.
doi:10.1016/j.ceramint.2016.07.096 .
Matović, Branko, Luković, Jelena M., Nikolić, Marko, Babić, Biljana M., Stanković, Nadežda, Jokić, Bojan M., Jelenković, Branislav, "Synthesis and characterization of nanocrystaline hexagonal boron nitride powders: XRD and luminescence properties" in Ceramics International, 42, no. 15 (2016):16655-16658,
https://doi.org/10.1016/j.ceramint.2016.07.096 . .
76
43
78

Few-step synthesis, thermal purification and structural characterization of porous boron nitride nanoplatelets

Kostoglou, Nikolaos; Luković, Jelena M.; Babić, Biljana M.; Matović, Branko; Photiou, Demetris; Constantinides, Georgios; Polychronopoulou, Kyriaki; Ryzhkov, Vladislav; Grossmann, Birgit; Mitterer, Christian; Rebholz, Claus

(2016)

TY  - JOUR
AU  - Kostoglou, Nikolaos
AU  - Luković, Jelena M.
AU  - Babić, Biljana M.
AU  - Matović, Branko
AU  - Photiou, Demetris
AU  - Constantinides, Georgios
AU  - Polychronopoulou, Kyriaki
AU  - Ryzhkov, Vladislav
AU  - Grossmann, Birgit
AU  - Mitterer, Christian
AU  - Rebholz, Claus
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1276
AB  - Hexagonal boron nitride (h-BN) nanoplatelets with similar to 99 wt.% purity, 900 to 2000 nm particle width, 30 to 90 nm particle thickness, similar to 213 m(2)/g specific surface area (SSA), similar to 66% micropore SSA and similar to 0.85 nm average pore size were synthesized in a powder form using H3BO3 and CO(NH2)(2) as precursors followed by consecutive thermal treatments under inert and oxidized atmospheres. Thermal gravimetric analysis (TGA) combined with differential scanning calorimetry (DSC), under synthetic air-flow and up to similar to 1300 degrees C, were employed to evaluate both purity and oxidation resistance of the product directly upon its synthesis. The h-BN powder was collected at the stage of its highest purity which, based on TGA-DSC data, corresponded to an additional heat treatment up to similar to 700 degrees C. The active oxidation seems to occur in the temperature range between similar to 860 and similar to 1000 degrees C, followed by formation of B2O3 in the final residue. Subsequently, the purified h-BN powder was extensively characterized for its structure, morphology and porosity using X-ray diffraction, scanning electron microscopy and nitrogen gas adsorption/desorption measurements at 77 respectively. As briefly discussed, purity and SSA seem to have a crucial role in the thermal stability and oxidation resistance of BN materials in general. (C) 2016 Elsevier Ltd. All rights reserved.
T2  - Materials and Design
T1  - Few-step synthesis, thermal purification and structural characterization of porous boron nitride nanoplatelets
VL  - 110
SP  - 540
EP  - 548
DO  - 10.1016/j.matdes.2016.08.011
ER  - 
@article{
author = "Kostoglou, Nikolaos and Luković, Jelena M. and Babić, Biljana M. and Matović, Branko and Photiou, Demetris and Constantinides, Georgios and Polychronopoulou, Kyriaki and Ryzhkov, Vladislav and Grossmann, Birgit and Mitterer, Christian and Rebholz, Claus",
year = "2016",
abstract = "Hexagonal boron nitride (h-BN) nanoplatelets with similar to 99 wt.% purity, 900 to 2000 nm particle width, 30 to 90 nm particle thickness, similar to 213 m(2)/g specific surface area (SSA), similar to 66% micropore SSA and similar to 0.85 nm average pore size were synthesized in a powder form using H3BO3 and CO(NH2)(2) as precursors followed by consecutive thermal treatments under inert and oxidized atmospheres. Thermal gravimetric analysis (TGA) combined with differential scanning calorimetry (DSC), under synthetic air-flow and up to similar to 1300 degrees C, were employed to evaluate both purity and oxidation resistance of the product directly upon its synthesis. The h-BN powder was collected at the stage of its highest purity which, based on TGA-DSC data, corresponded to an additional heat treatment up to similar to 700 degrees C. The active oxidation seems to occur in the temperature range between similar to 860 and similar to 1000 degrees C, followed by formation of B2O3 in the final residue. Subsequently, the purified h-BN powder was extensively characterized for its structure, morphology and porosity using X-ray diffraction, scanning electron microscopy and nitrogen gas adsorption/desorption measurements at 77 respectively. As briefly discussed, purity and SSA seem to have a crucial role in the thermal stability and oxidation resistance of BN materials in general. (C) 2016 Elsevier Ltd. All rights reserved.",
journal = "Materials and Design",
title = "Few-step synthesis, thermal purification and structural characterization of porous boron nitride nanoplatelets",
volume = "110",
pages = "540-548",
doi = "10.1016/j.matdes.2016.08.011"
}
Kostoglou, N., Luković, J. M., Babić, B. M., Matović, B., Photiou, D., Constantinides, G., Polychronopoulou, K., Ryzhkov, V., Grossmann, B., Mitterer, C.,& Rebholz, C.. (2016). Few-step synthesis, thermal purification and structural characterization of porous boron nitride nanoplatelets. in Materials and Design, 110, 540-548.
https://doi.org/10.1016/j.matdes.2016.08.011
Kostoglou N, Luković JM, Babić BM, Matović B, Photiou D, Constantinides G, Polychronopoulou K, Ryzhkov V, Grossmann B, Mitterer C, Rebholz C. Few-step synthesis, thermal purification and structural characterization of porous boron nitride nanoplatelets. in Materials and Design. 2016;110:540-548.
doi:10.1016/j.matdes.2016.08.011 .
Kostoglou, Nikolaos, Luković, Jelena M., Babić, Biljana M., Matović, Branko, Photiou, Demetris, Constantinides, Georgios, Polychronopoulou, Kyriaki, Ryzhkov, Vladislav, Grossmann, Birgit, Mitterer, Christian, Rebholz, Claus, "Few-step synthesis, thermal purification and structural characterization of porous boron nitride nanoplatelets" in Materials and Design, 110 (2016):540-548,
https://doi.org/10.1016/j.matdes.2016.08.011 . .
23
17
21

Monolithic nanocrystalline SiC ceramics

Matović, Branko; Bučevac, Dušan; Urbanović, Vladimir; Stanković, Nadežda; Daneu, Nina; Volkov-Husović, Tatjana; Babić, Biljana M.

(2016)

TY  - JOUR
AU  - Matović, Branko
AU  - Bučevac, Dušan
AU  - Urbanović, Vladimir
AU  - Stanković, Nadežda
AU  - Daneu, Nina
AU  - Volkov-Husović, Tatjana
AU  - Babić, Biljana M.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1134
AB  - Additive-free beta-SiC nanopowders were densified by using high-pressure anvil-type with hollows apparatus at the pressure of 4 GPa in the range of 1500-1900 degrees C. The starting powder with average particle size of 10 nm was synthesized by a sol-gel process. Crystallite size and lattice parameters of the samples have been studied at room temperature by X-ray diffraction (XRD) and transmission electron microscopy (TEM). It was found that the size of the crystallites gradually increases from 16 to 51 nm with increasing sintering temperature (1500 to 1900 degrees C). Fully densified sample ( GT 99%) was obtained at a sintering temperature of 1900 degrees C for 60 s. This sample exhibits nano-hardness and Youngs modulus of elasticity of 35 GPa and 450 GPa, respectively. Modified vibratory cavitation test method was used for laboratory testing of the cavitation resistance. A very low erosion level with mass loss 0.1% after 10 h was exhibited during the cavitation test. (C) 2015 Elsevier Ltd. All rights reserved.
T2  - Journal of the European Ceramic Society
T1  - Monolithic nanocrystalline SiC ceramics
VL  - 36
IS  - 12
SP  - 3005
EP  - 3010
DO  - 10.1016/j.jeurceramsoc.2015.10.031
ER  - 
@article{
author = "Matović, Branko and Bučevac, Dušan and Urbanović, Vladimir and Stanković, Nadežda and Daneu, Nina and Volkov-Husović, Tatjana and Babić, Biljana M.",
year = "2016",
abstract = "Additive-free beta-SiC nanopowders were densified by using high-pressure anvil-type with hollows apparatus at the pressure of 4 GPa in the range of 1500-1900 degrees C. The starting powder with average particle size of 10 nm was synthesized by a sol-gel process. Crystallite size and lattice parameters of the samples have been studied at room temperature by X-ray diffraction (XRD) and transmission electron microscopy (TEM). It was found that the size of the crystallites gradually increases from 16 to 51 nm with increasing sintering temperature (1500 to 1900 degrees C). Fully densified sample ( GT 99%) was obtained at a sintering temperature of 1900 degrees C for 60 s. This sample exhibits nano-hardness and Youngs modulus of elasticity of 35 GPa and 450 GPa, respectively. Modified vibratory cavitation test method was used for laboratory testing of the cavitation resistance. A very low erosion level with mass loss 0.1% after 10 h was exhibited during the cavitation test. (C) 2015 Elsevier Ltd. All rights reserved.",
journal = "Journal of the European Ceramic Society",
title = "Monolithic nanocrystalline SiC ceramics",
volume = "36",
number = "12",
pages = "3005-3010",
doi = "10.1016/j.jeurceramsoc.2015.10.031"
}
Matović, B., Bučevac, D., Urbanović, V., Stanković, N., Daneu, N., Volkov-Husović, T.,& Babić, B. M.. (2016). Monolithic nanocrystalline SiC ceramics. in Journal of the European Ceramic Society, 36(12), 3005-3010.
https://doi.org/10.1016/j.jeurceramsoc.2015.10.031
Matović B, Bučevac D, Urbanović V, Stanković N, Daneu N, Volkov-Husović T, Babić BM. Monolithic nanocrystalline SiC ceramics. in Journal of the European Ceramic Society. 2016;36(12):3005-3010.
doi:10.1016/j.jeurceramsoc.2015.10.031 .
Matović, Branko, Bučevac, Dušan, Urbanović, Vladimir, Stanković, Nadežda, Daneu, Nina, Volkov-Husović, Tatjana, Babić, Biljana M., "Monolithic nanocrystalline SiC ceramics" in Journal of the European Ceramic Society, 36, no. 12 (2016):3005-3010,
https://doi.org/10.1016/j.jeurceramsoc.2015.10.031 . .
17
11
17

Microstructural Characterization and Adsorption Properties of Alkali-Activated Materials Based on Metakaolin

Trivunac, Katarina V.; Kljajević, Ljiljana M.; Nenadović, Snežana S.; Gulicovski, Jelena J.; Mirković, Miljana M.; Babić, Biljana M.; Stevanović, Slavica

(2016)

TY  - JOUR
AU  - Trivunac, Katarina V.
AU  - Kljajević, Ljiljana M.
AU  - Nenadović, Snežana S.
AU  - Gulicovski, Jelena J.
AU  - Mirković, Miljana M.
AU  - Babić, Biljana M.
AU  - Stevanović, Slavica
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1229
AB  - The microstructural characterization and adsorption properties of metakaolin (MK) and alkali-activated metakaolin, known as geopolymer materials (GP) were investigated. The structure and properties of the metakaolin and obtained geopolymer were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. Furthermore, based on the analysis of adsorption efficiency, microstructure and mineral structure, the difference between geopolymer and metakaolin on the performance of immobilizing heavy metals have been discussed. The kinetics of adsorption can be represented by pseudo-second order equation. The results of lead ions adsorption experiments were best fitted by Freundlich adsorption isotherm for both investigated adsorbents. The highest removal efficiencies of alkali-activated material based on metakaolin was found 97.5% at pH 4 and metakaolin removal efficiencies was found 92% at pH 5.5.
T2  - Science of Sintering
T1  - Microstructural Characterization and Adsorption Properties of Alkali-Activated Materials Based on Metakaolin
VL  - 48
IS  - 2
SP  - 209
EP  - 220
DO  - 10.2298/SOS1602209T
ER  - 
@article{
author = "Trivunac, Katarina V. and Kljajević, Ljiljana M. and Nenadović, Snežana S. and Gulicovski, Jelena J. and Mirković, Miljana M. and Babić, Biljana M. and Stevanović, Slavica",
year = "2016",
abstract = "The microstructural characterization and adsorption properties of metakaolin (MK) and alkali-activated metakaolin, known as geopolymer materials (GP) were investigated. The structure and properties of the metakaolin and obtained geopolymer were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. Furthermore, based on the analysis of adsorption efficiency, microstructure and mineral structure, the difference between geopolymer and metakaolin on the performance of immobilizing heavy metals have been discussed. The kinetics of adsorption can be represented by pseudo-second order equation. The results of lead ions adsorption experiments were best fitted by Freundlich adsorption isotherm for both investigated adsorbents. The highest removal efficiencies of alkali-activated material based on metakaolin was found 97.5% at pH 4 and metakaolin removal efficiencies was found 92% at pH 5.5.",
journal = "Science of Sintering",
title = "Microstructural Characterization and Adsorption Properties of Alkali-Activated Materials Based on Metakaolin",
volume = "48",
number = "2",
pages = "209-220",
doi = "10.2298/SOS1602209T"
}
Trivunac, K. V., Kljajević, L. M., Nenadović, S. S., Gulicovski, J. J., Mirković, M. M., Babić, B. M.,& Stevanović, S.. (2016). Microstructural Characterization and Adsorption Properties of Alkali-Activated Materials Based on Metakaolin. in Science of Sintering, 48(2), 209-220.
https://doi.org/10.2298/SOS1602209T
Trivunac KV, Kljajević LM, Nenadović SS, Gulicovski JJ, Mirković MM, Babić BM, Stevanović S. Microstructural Characterization and Adsorption Properties of Alkali-Activated Materials Based on Metakaolin. in Science of Sintering. 2016;48(2):209-220.
doi:10.2298/SOS1602209T .
Trivunac, Katarina V., Kljajević, Ljiljana M., Nenadović, Snežana S., Gulicovski, Jelena J., Mirković, Miljana M., Babić, Biljana M., Stevanović, Slavica, "Microstructural Characterization and Adsorption Properties of Alkali-Activated Materials Based on Metakaolin" in Science of Sintering, 48, no. 2 (2016):209-220,
https://doi.org/10.2298/SOS1602209T . .
9
8
14

Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag

Nikolić, Irena; Marković, Smilja; Janković-Častvan, Ivona; Radmilović, Vuk V.; Karanović, Ljiljana; Babić, Biljana M.; Radmilovíć, Velimir R.

(Elsevier, 2016)

TY  - JOUR
AU  - Nikolić, Irena
AU  - Marković, Smilja
AU  - Janković-Častvan, Ivona
AU  - Radmilović, Vuk V.
AU  - Karanović, Ljiljana
AU  - Babić, Biljana M.
AU  - Radmilovíć, Velimir R.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1073
AB  - Geopolymeric binders (GB) were produced using fly ash (FA) and electric arc furnace slag (EAFS). The slag has been added in the range of 0-40%. The effects of slag content on the strength, microstructure and thermal resistance were evaluated. It was found that the amount of EAFS up to 30% positively affects the strength evolution of GB. The main reaction product of FA/EAFS blends was amorphous N-(C)-A-S-H gel along with geopolymer-type gel (N-A-S-H). Thermal resistance of GB was considered from the standpoint of their mechanical and dimensional stability after heating in the temperature interval of 600800 C. The changes in mechanical and thermal properties of GB after heating are attributed to the changes in their structure. The results have shown that EAFS negatively affects the thermal resistance of GB above 600 degrees C due to the phase transition and morphological transformation of the amorphous gel phase. (C) 2016 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Materials Letters
T1  - Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag
VL  - 176
SP  - 301
EP  - 305
DO  - 10.1016/j.matlet.2016.04.121
ER  - 
@article{
author = "Nikolić, Irena and Marković, Smilja and Janković-Častvan, Ivona and Radmilović, Vuk V. and Karanović, Ljiljana and Babić, Biljana M. and Radmilovíć, Velimir R.",
year = "2016",
abstract = "Geopolymeric binders (GB) were produced using fly ash (FA) and electric arc furnace slag (EAFS). The slag has been added in the range of 0-40%. The effects of slag content on the strength, microstructure and thermal resistance were evaluated. It was found that the amount of EAFS up to 30% positively affects the strength evolution of GB. The main reaction product of FA/EAFS blends was amorphous N-(C)-A-S-H gel along with geopolymer-type gel (N-A-S-H). Thermal resistance of GB was considered from the standpoint of their mechanical and dimensional stability after heating in the temperature interval of 600800 C. The changes in mechanical and thermal properties of GB after heating are attributed to the changes in their structure. The results have shown that EAFS negatively affects the thermal resistance of GB above 600 degrees C due to the phase transition and morphological transformation of the amorphous gel phase. (C) 2016 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Materials Letters",
title = "Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag",
volume = "176",
pages = "301-305",
doi = "10.1016/j.matlet.2016.04.121"
}
Nikolić, I., Marković, S., Janković-Častvan, I., Radmilović, V. V., Karanović, L., Babić, B. M.,& Radmilovíć, V. R.. (2016). Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag. in Materials Letters
Elsevier., 176, 301-305.
https://doi.org/10.1016/j.matlet.2016.04.121
Nikolić I, Marković S, Janković-Častvan I, Radmilović VV, Karanović L, Babić BM, Radmilovíć VR. Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag. in Materials Letters. 2016;176:301-305.
doi:10.1016/j.matlet.2016.04.121 .
Nikolić, Irena, Marković, Smilja, Janković-Častvan, Ivona, Radmilović, Vuk V., Karanović, Ljiljana, Babić, Biljana M., Radmilovíć, Velimir R., "Modification of mechanical and thermal properties of fly ash-based geopolymer by the incorporation of steel slag" in Materials Letters, 176 (2016):301-305,
https://doi.org/10.1016/j.matlet.2016.04.121 . .
50
26
49

Adsorption of malathion on mesoporous monetite obtained by mechanochemical treatment of brushite

Mirković, Miljana M.; Lazarević-Pašti, Tamara; Došen, Anja M.; Čebela, Maria; Rosić, Aleksandra; Matović, Branko; Babić, Biljana M.

(2016)

TY  - JOUR
AU  - Mirković, Miljana M.
AU  - Lazarević-Pašti, Tamara
AU  - Došen, Anja M.
AU  - Čebela, Maria
AU  - Rosić, Aleksandra
AU  - Matović, Branko
AU  - Babić, Biljana M.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/930
AB  - Mesoporous monetite (CaHPO4), obtained by mechanochemical treatment of previously synthesized brushite (CaHPO4 center dot 2H(2)O), was used as efficient adsorbent for the organic pesticide malathion. The structure of brushite was confirmed by Raman spectroscopy. The phase transformation process was investigated by X-ray powder diffraction (XRD) and Fourier transformation infra-red spectroscopy (FTIR). The microstructure and morphology were determined by scanning electron microscopy (SEM) and the nitrogen adsorption-desorption method. It was found that five minutes of milling induces brushite-monetite phase transformation. Adsorption of malathion from aqueous solutions showed that this pesticide can be successfully adsorbed on surface of this material.
T2  - RSC Advances
T1  - Adsorption of malathion on mesoporous monetite obtained by mechanochemical treatment of brushite
VL  - 6
IS  - 15
SP  - 12219
EP  - 12225
DO  - 10.1039/c5ra27554g
ER  - 
@article{
author = "Mirković, Miljana M. and Lazarević-Pašti, Tamara and Došen, Anja M. and Čebela, Maria and Rosić, Aleksandra and Matović, Branko and Babić, Biljana M.",
year = "2016",
abstract = "Mesoporous monetite (CaHPO4), obtained by mechanochemical treatment of previously synthesized brushite (CaHPO4 center dot 2H(2)O), was used as efficient adsorbent for the organic pesticide malathion. The structure of brushite was confirmed by Raman spectroscopy. The phase transformation process was investigated by X-ray powder diffraction (XRD) and Fourier transformation infra-red spectroscopy (FTIR). The microstructure and morphology were determined by scanning electron microscopy (SEM) and the nitrogen adsorption-desorption method. It was found that five minutes of milling induces brushite-monetite phase transformation. Adsorption of malathion from aqueous solutions showed that this pesticide can be successfully adsorbed on surface of this material.",
journal = "RSC Advances",
title = "Adsorption of malathion on mesoporous monetite obtained by mechanochemical treatment of brushite",
volume = "6",
number = "15",
pages = "12219-12225",
doi = "10.1039/c5ra27554g"
}
Mirković, M. M., Lazarević-Pašti, T., Došen, A. M., Čebela, M., Rosić, A., Matović, B.,& Babić, B. M.. (2016). Adsorption of malathion on mesoporous monetite obtained by mechanochemical treatment of brushite. in RSC Advances, 6(15), 12219-12225.
https://doi.org/10.1039/c5ra27554g
Mirković MM, Lazarević-Pašti T, Došen AM, Čebela M, Rosić A, Matović B, Babić BM. Adsorption of malathion on mesoporous monetite obtained by mechanochemical treatment of brushite. in RSC Advances. 2016;6(15):12219-12225.
doi:10.1039/c5ra27554g .
Mirković, Miljana M., Lazarević-Pašti, Tamara, Došen, Anja M., Čebela, Maria, Rosić, Aleksandra, Matović, Branko, Babić, Biljana M., "Adsorption of malathion on mesoporous monetite obtained by mechanochemical treatment of brushite" in RSC Advances, 6, no. 15 (2016):12219-12225,
https://doi.org/10.1039/c5ra27554g . .
42
31
45

Far-infrared spectra of mesoporous ZnS nanoparticles

Trajić, Jelena; Romčević, Maja J.; Romčević, Nebojša Ž.; Babić, Biljana M.; Matović, Branko; Balaž, Peter

(2016)

TY  - JOUR
AU  - Trajić, Jelena
AU  - Romčević, Maja J.
AU  - Romčević, Nebojša Ž.
AU  - Babić, Biljana M.
AU  - Matović, Branko
AU  - Balaž, Peter
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1135
AB  - ZnS nanoparticles were synthesized mechanochemically by high-energy milling, with three different milling times (5 min, 10 min and 20 min). Nitrogen adsorption method was used for examining specific surface area and texture of obtained powders. It was found that all samples are completely mesoporous. The optical properties were studied by far-infrared spectroscopy at room temperature in spectral region of 50-600 cm(-1). The analysis of the far-infrared reflectivity spectra was made by the fitting procedure. The dielectric function of ZnS nanoparticles is modeled as a mixture of homogenous spherical inclusions in air by the Maxwell-Garnet formula. In the analysis of the far-infrared reflection spectra, appearance of combined plasmon-LO phonon modes (CPPMs) with high phonon damping are observed, which causes decrease of coupled plasmon-phonon frequencies. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Far-infrared spectra of mesoporous ZnS nanoparticles
VL  - 57
SP  - 225
EP  - 230
DO  - 10.1016/j.optmat.2016.05.004
ER  - 
@article{
author = "Trajić, Jelena and Romčević, Maja J. and Romčević, Nebojša Ž. and Babić, Biljana M. and Matović, Branko and Balaž, Peter",
year = "2016",
abstract = "ZnS nanoparticles were synthesized mechanochemically by high-energy milling, with three different milling times (5 min, 10 min and 20 min). Nitrogen adsorption method was used for examining specific surface area and texture of obtained powders. It was found that all samples are completely mesoporous. The optical properties were studied by far-infrared spectroscopy at room temperature in spectral region of 50-600 cm(-1). The analysis of the far-infrared reflectivity spectra was made by the fitting procedure. The dielectric function of ZnS nanoparticles is modeled as a mixture of homogenous spherical inclusions in air by the Maxwell-Garnet formula. In the analysis of the far-infrared reflection spectra, appearance of combined plasmon-LO phonon modes (CPPMs) with high phonon damping are observed, which causes decrease of coupled plasmon-phonon frequencies. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Far-infrared spectra of mesoporous ZnS nanoparticles",
volume = "57",
pages = "225-230",
doi = "10.1016/j.optmat.2016.05.004"
}
Trajić, J., Romčević, M. J., Romčević, N. Ž., Babić, B. M., Matović, B.,& Balaž, P.. (2016). Far-infrared spectra of mesoporous ZnS nanoparticles. in Optical Materials, 57, 225-230.
https://doi.org/10.1016/j.optmat.2016.05.004
Trajić J, Romčević MJ, Romčević NŽ, Babić BM, Matović B, Balaž P. Far-infrared spectra of mesoporous ZnS nanoparticles. in Optical Materials. 2016;57:225-230.
doi:10.1016/j.optmat.2016.05.004 .
Trajić, Jelena, Romčević, Maja J., Romčević, Nebojša Ž., Babić, Biljana M., Matović, Branko, Balaž, Peter, "Far-infrared spectra of mesoporous ZnS nanoparticles" in Optical Materials, 57 (2016):225-230,
https://doi.org/10.1016/j.optmat.2016.05.004 . .
4
3
5

Far-infrared spectra of dysprosium doped yttrium aluminum garnet nanopowder

Trajić, Jelena; Rabasović, Maja S.; Savić-Šević, Svetlana N.; Šević, Dragutin M.; Babić, Biljana M.; Romčević, Maja J.; Ristić-Đurović, Jasna L.; Paunović, Novica M.; Križan, Janez; Romčević, Nebojša Ž.

(2016)

TY  - JOUR
AU  - Trajić, Jelena
AU  - Rabasović, Maja S.
AU  - Savić-Šević, Svetlana N.
AU  - Šević, Dragutin M.
AU  - Babić, Biljana M.
AU  - Romčević, Maja J.
AU  - Ristić-Đurović, Jasna L.
AU  - Paunović, Novica M.
AU  - Križan, Janez
AU  - Romčević, Nebojša Ž.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1210
AB  - The solution combustion synthesis was used to prepare nanopowders of yttrium aluminum garnet (YAG) and YAG doped with dysprosium ions, Dy3+, (YAG:Dy). The morphology, specific surface area, texture, and optical properties of the prepared materials were studied by the means of scanning electron microscopy (SEM), nitrogen adsorption method, and far-infrared spectroscopy at room temperature in the spectral region between 80 and 600 cm(-1). It was established that all the examined samples were microporous. The Maxwell-Garnet formula was used to model dielectric function of YAG and YAG:Dy nanopowders as mixtures of homogenous spherical inclusions in air. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Infrared Physics and Technology
T1  - Far-infrared spectra of dysprosium doped yttrium aluminum garnet nanopowder
VL  - 77
SP  - 226
EP  - 229
DO  - 10.1016/j.infrared.2016.06.003
ER  - 
@article{
author = "Trajić, Jelena and Rabasović, Maja S. and Savić-Šević, Svetlana N. and Šević, Dragutin M. and Babić, Biljana M. and Romčević, Maja J. and Ristić-Đurović, Jasna L. and Paunović, Novica M. and Križan, Janez and Romčević, Nebojša Ž.",
year = "2016",
abstract = "The solution combustion synthesis was used to prepare nanopowders of yttrium aluminum garnet (YAG) and YAG doped with dysprosium ions, Dy3+, (YAG:Dy). The morphology, specific surface area, texture, and optical properties of the prepared materials were studied by the means of scanning electron microscopy (SEM), nitrogen adsorption method, and far-infrared spectroscopy at room temperature in the spectral region between 80 and 600 cm(-1). It was established that all the examined samples were microporous. The Maxwell-Garnet formula was used to model dielectric function of YAG and YAG:Dy nanopowders as mixtures of homogenous spherical inclusions in air. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Infrared Physics and Technology",
title = "Far-infrared spectra of dysprosium doped yttrium aluminum garnet nanopowder",
volume = "77",
pages = "226-229",
doi = "10.1016/j.infrared.2016.06.003"
}
Trajić, J., Rabasović, M. S., Savić-Šević, S. N., Šević, D. M., Babić, B. M., Romčević, M. J., Ristić-Đurović, J. L., Paunović, N. M., Križan, J.,& Romčević, N. Ž.. (2016). Far-infrared spectra of dysprosium doped yttrium aluminum garnet nanopowder. in Infrared Physics and Technology, 77, 226-229.
https://doi.org/10.1016/j.infrared.2016.06.003
Trajić J, Rabasović MS, Savić-Šević SN, Šević DM, Babić BM, Romčević MJ, Ristić-Đurović JL, Paunović NM, Križan J, Romčević NŽ. Far-infrared spectra of dysprosium doped yttrium aluminum garnet nanopowder. in Infrared Physics and Technology. 2016;77:226-229.
doi:10.1016/j.infrared.2016.06.003 .
Trajić, Jelena, Rabasović, Maja S., Savić-Šević, Svetlana N., Šević, Dragutin M., Babić, Biljana M., Romčević, Maja J., Ristić-Đurović, Jasna L., Paunović, Novica M., Križan, Janez, Romčević, Nebojša Ž., "Far-infrared spectra of dysprosium doped yttrium aluminum garnet nanopowder" in Infrared Physics and Technology, 77 (2016):226-229,
https://doi.org/10.1016/j.infrared.2016.06.003 . .
11
7
10

Heteroatom-doped mesoporous carbons as efficient adsorbents for removal of dimethoate and omethoate from water

Lazarević-Pašti, Tamara; Pašti, Igor A.; Jokić, Bojan M.; Babić, Biljana M.; Vasić, Vesna M.

(2016)

TY  - JOUR
AU  - Lazarević-Pašti, Tamara
AU  - Pašti, Igor A.
AU  - Jokić, Bojan M.
AU  - Babić, Biljana M.
AU  - Vasić, Vesna M.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1178
AB  - Extensive use of organophosphate pesticides (OPs) invokes development of efficient procedures for their removal from the environment. By introducing low levels ( LT 1 at%) of B, N or P into the structure of mesoporous carbons, we have produced a series of materials with different surface chemical composition, textural properties and level of structural disorder. These adsorbents were applied for removal of dimethoate and its oxo-analogue omethoate from aqueous solutions under batch adsorption conditions and by filtration using modified nylon membrane filters. Adsorption capacities up to 164 mg g(-1) were measured, with OPs uptake typically above 80% for dimethoate concentration as high as 5 x 10(-3) mol dm(-3). After the adsorption, neurotoxic effects of OP-containing water samples were significantly reduced or completely removed. The level of structural disorder was identified as a key parameter for efficient removal of dimethoate and omethoate while in the filtration experiments surface area of adsorbents also played an important role. While the presented research appeals to new fundamental studies of OP-carbon surface interactions, it also indicates a possible strategy in designing new efficient adsorbents for OPs removal from water.
T2  - RSC Advances
T1  - Heteroatom-doped mesoporous carbons as efficient adsorbents for removal of dimethoate and omethoate from water
VL  - 6
IS  - 67
SP  - 62128
EP  - 62139
DO  - 10.1039/c6ra06736k
ER  - 
@article{
author = "Lazarević-Pašti, Tamara and Pašti, Igor A. and Jokić, Bojan M. and Babić, Biljana M. and Vasić, Vesna M.",
year = "2016",
abstract = "Extensive use of organophosphate pesticides (OPs) invokes development of efficient procedures for their removal from the environment. By introducing low levels ( LT 1 at%) of B, N or P into the structure of mesoporous carbons, we have produced a series of materials with different surface chemical composition, textural properties and level of structural disorder. These adsorbents were applied for removal of dimethoate and its oxo-analogue omethoate from aqueous solutions under batch adsorption conditions and by filtration using modified nylon membrane filters. Adsorption capacities up to 164 mg g(-1) were measured, with OPs uptake typically above 80% for dimethoate concentration as high as 5 x 10(-3) mol dm(-3). After the adsorption, neurotoxic effects of OP-containing water samples were significantly reduced or completely removed. The level of structural disorder was identified as a key parameter for efficient removal of dimethoate and omethoate while in the filtration experiments surface area of adsorbents also played an important role. While the presented research appeals to new fundamental studies of OP-carbon surface interactions, it also indicates a possible strategy in designing new efficient adsorbents for OPs removal from water.",
journal = "RSC Advances",
title = "Heteroatom-doped mesoporous carbons as efficient adsorbents for removal of dimethoate and omethoate from water",
volume = "6",
number = "67",
pages = "62128-62139",
doi = "10.1039/c6ra06736k"
}
Lazarević-Pašti, T., Pašti, I. A., Jokić, B. M., Babić, B. M.,& Vasić, V. M.. (2016). Heteroatom-doped mesoporous carbons as efficient adsorbents for removal of dimethoate and omethoate from water. in RSC Advances, 6(67), 62128-62139.
https://doi.org/10.1039/c6ra06736k
Lazarević-Pašti T, Pašti IA, Jokić BM, Babić BM, Vasić VM. Heteroatom-doped mesoporous carbons as efficient adsorbents for removal of dimethoate and omethoate from water. in RSC Advances. 2016;6(67):62128-62139.
doi:10.1039/c6ra06736k .
Lazarević-Pašti, Tamara, Pašti, Igor A., Jokić, Bojan M., Babić, Biljana M., Vasić, Vesna M., "Heteroatom-doped mesoporous carbons as efficient adsorbents for removal of dimethoate and omethoate from water" in RSC Advances, 6, no. 67 (2016):62128-62139,
https://doi.org/10.1039/c6ra06736k . .
32
18
33

Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media

Stojmenović, Marija; Momčilović, Milan Z.; Gavrilov, Nemanja M.; Pašti, Igor A.; Mentus, Slavko V.; Jokić, Bojan M.; Babić, Biljana M.

(2015)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Momčilović, Milan Z.
AU  - Gavrilov, Nemanja M.
AU  - Pašti, Igor A.
AU  - Mentus, Slavko V.
AU  - Jokić, Bojan M.
AU  - Babić, Biljana M.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/371
AB  - Ordered mesoporous carbon, volume-doped up to 3w.% with Pt, Ru and Pt-Ru nanoparticles was synthesized by evaporation-induced self-assembly method, under acidic conditions. The content of incorporated metal was determined by EDX analysis. The X-ray diffractometry confirmed the existence of highly dispersed metallic phases in doped samples. Specific surface area was determined by N-2-physisorption measurements to range between 452 and 545m(2) g(-1). Raman spectroscopy of investigated materials indicated highly disordered carbon structure with crystallite sizes around 1.4 nm. In a form of thin-layer electrode on glassy carbon support, in 0.1M KOH solution, the prepared materials displayed high activity toward oxygen reduction reaction (ORR) in alkaline media, with onset potentials more positive than -0.10 V vs. SCE. The kinetics of O-2 reduction was found to be affected by both the specific surface area and the concentration of metal dopants. The ethanol tolerance of (Pt, Ru)-doped OMCs was found to be higher than that of common Pt/C ORR catalysts. Presented study provides a new route for the synthesis of active and selective ORR catalysts in alkaline media, being competitive with, or superior to, the existing ones in terms of performance and price. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media
VL  - 153
SP  - 130
EP  - 139
DO  - 10.1016/j.electacta.2014.11.080
ER  - 
@article{
author = "Stojmenović, Marija and Momčilović, Milan Z. and Gavrilov, Nemanja M. and Pašti, Igor A. and Mentus, Slavko V. and Jokić, Bojan M. and Babić, Biljana M.",
year = "2015",
abstract = "Ordered mesoporous carbon, volume-doped up to 3w.% with Pt, Ru and Pt-Ru nanoparticles was synthesized by evaporation-induced self-assembly method, under acidic conditions. The content of incorporated metal was determined by EDX analysis. The X-ray diffractometry confirmed the existence of highly dispersed metallic phases in doped samples. Specific surface area was determined by N-2-physisorption measurements to range between 452 and 545m(2) g(-1). Raman spectroscopy of investigated materials indicated highly disordered carbon structure with crystallite sizes around 1.4 nm. In a form of thin-layer electrode on glassy carbon support, in 0.1M KOH solution, the prepared materials displayed high activity toward oxygen reduction reaction (ORR) in alkaline media, with onset potentials more positive than -0.10 V vs. SCE. The kinetics of O-2 reduction was found to be affected by both the specific surface area and the concentration of metal dopants. The ethanol tolerance of (Pt, Ru)-doped OMCs was found to be higher than that of common Pt/C ORR catalysts. Presented study provides a new route for the synthesis of active and selective ORR catalysts in alkaline media, being competitive with, or superior to, the existing ones in terms of performance and price. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media",
volume = "153",
pages = "130-139",
doi = "10.1016/j.electacta.2014.11.080"
}
Stojmenović, M., Momčilović, M. Z., Gavrilov, N. M., Pašti, I. A., Mentus, S. V., Jokić, B. M.,& Babić, B. M.. (2015). Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media. in Electrochimica Acta, 153, 130-139.
https://doi.org/10.1016/j.electacta.2014.11.080
Stojmenović M, Momčilović MZ, Gavrilov NM, Pašti IA, Mentus SV, Jokić BM, Babić BM. Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media. in Electrochimica Acta. 2015;153:130-139.
doi:10.1016/j.electacta.2014.11.080 .
Stojmenović, Marija, Momčilović, Milan Z., Gavrilov, Nemanja M., Pašti, Igor A., Mentus, Slavko V., Jokić, Bojan M., Babić, Biljana M., "Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media" in Electrochimica Acta, 153 (2015):130-139,
https://doi.org/10.1016/j.electacta.2014.11.080 . .
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23

The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons

Pašti, Igor A.; Gavrilov, Nemanja M.; Dobrota, Ana S.; Momčilović, Milan Z.; Stojmenović, Marija; Topalov, Angel; Stanković, Dalibor M.; Babić, Biljana M.; Ćirić-Marjanović, Gordana N.; Mentus, Slavko V.

(2015)

TY  - JOUR
AU  - Pašti, Igor A.
AU  - Gavrilov, Nemanja M.
AU  - Dobrota, Ana S.
AU  - Momčilović, Milan Z.
AU  - Stojmenović, Marija
AU  - Topalov, Angel
AU  - Stanković, Dalibor M.
AU  - Babić, Biljana M.
AU  - Ćirić-Marjanović, Gordana N.
AU  - Mentus, Slavko V.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/769
AB  - In order to elucidate the role of B, N, and P dopants in carbon materials on the kinetics of oxygen reduction reaction (ORR) and to provide a fair comparison of the effects of each dopant, a series of ordered mesoporous carbons (OMCs) with low concentration of heteroatoms ( LT 1 at%) has been prepared. Doped OMCs were characterized using X-ray photoelectron spectroscopy (XPS), inductively coupled plasma optical emission spectroscopy (ICP-OES), Raman spectroscopy, X-ray powder diffraction (XRD), and N-2 physisorption measurements. Comparative study of the ORR activity of these materials in alkaline solution was performed using rotating disk electrode voltammetry. The experiments evidenced that, compared to non-doped OMC, charge transfer kinetics was improved independently on the nature of the heteroatom. The decrease of the ORR overvoltage and the increase of the mass activity upon doping are similar for B and P and less prominent for N. On the other hand, OMCs doped with low levels of B and N were found to be selective for O-2 reduction to peroxide, while for P-doped OMCs, the apparent number of electrons consumed per O-2 molecule was up to 3.1. Experimental measurements were complemented by density functional theory (DFT) calculations.
T2  - Electrocatalysis
T1  - The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons
VL  - 6
IS  - 6
SP  - 498
EP  - 511
DO  - 10.1007/s12678-015-0271-0
ER  - 
@article{
author = "Pašti, Igor A. and Gavrilov, Nemanja M. and Dobrota, Ana S. and Momčilović, Milan Z. and Stojmenović, Marija and Topalov, Angel and Stanković, Dalibor M. and Babić, Biljana M. and Ćirić-Marjanović, Gordana N. and Mentus, Slavko V.",
year = "2015",
abstract = "In order to elucidate the role of B, N, and P dopants in carbon materials on the kinetics of oxygen reduction reaction (ORR) and to provide a fair comparison of the effects of each dopant, a series of ordered mesoporous carbons (OMCs) with low concentration of heteroatoms ( LT 1 at%) has been prepared. Doped OMCs were characterized using X-ray photoelectron spectroscopy (XPS), inductively coupled plasma optical emission spectroscopy (ICP-OES), Raman spectroscopy, X-ray powder diffraction (XRD), and N-2 physisorption measurements. Comparative study of the ORR activity of these materials in alkaline solution was performed using rotating disk electrode voltammetry. The experiments evidenced that, compared to non-doped OMC, charge transfer kinetics was improved independently on the nature of the heteroatom. The decrease of the ORR overvoltage and the increase of the mass activity upon doping are similar for B and P and less prominent for N. On the other hand, OMCs doped with low levels of B and N were found to be selective for O-2 reduction to peroxide, while for P-doped OMCs, the apparent number of electrons consumed per O-2 molecule was up to 3.1. Experimental measurements were complemented by density functional theory (DFT) calculations.",
journal = "Electrocatalysis",
title = "The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons",
volume = "6",
number = "6",
pages = "498-511",
doi = "10.1007/s12678-015-0271-0"
}
Pašti, I. A., Gavrilov, N. M., Dobrota, A. S., Momčilović, M. Z., Stojmenović, M., Topalov, A., Stanković, D. M., Babić, B. M., Ćirić-Marjanović, G. N.,& Mentus, S. V.. (2015). The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons. in Electrocatalysis, 6(6), 498-511.
https://doi.org/10.1007/s12678-015-0271-0
Pašti IA, Gavrilov NM, Dobrota AS, Momčilović MZ, Stojmenović M, Topalov A, Stanković DM, Babić BM, Ćirić-Marjanović GN, Mentus SV. The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons. in Electrocatalysis. 2015;6(6):498-511.
doi:10.1007/s12678-015-0271-0 .
Pašti, Igor A., Gavrilov, Nemanja M., Dobrota, Ana S., Momčilović, Milan Z., Stojmenović, Marija, Topalov, Angel, Stanković, Dalibor M., Babić, Biljana M., Ćirić-Marjanović, Gordana N., Mentus, Slavko V., "The Effects of a Low-Level Boron, Phosphorus, and Nitrogen Doping on the Oxygen Reduction Activity of Ordered Mesoporous Carbons" in Electrocatalysis, 6, no. 6 (2015):498-511,
https://doi.org/10.1007/s12678-015-0271-0 . .
36
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37

Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres

Ranđelović, Marjan S.; Momčilović, Milan Z.; Matović, Branko; Babić, Biljana M.; Barek, Jiri

(Elsevier, 2015)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Matović, Branko
AU  - Babić, Biljana M.
AU  - Barek, Jiri
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/850
AB  - This paper deals with comparison of modified carbon electrodes prepared from Pt- and Ag-doped carbon microspheres using cyclic voltammetry of [Fe(CN)(6)](3-)/[Fe(CN)(6)](4-) redox pair as a probe under various experimental conditions. Spherical particles ranging from 0.5 to 8 mu m in average as evidenced by SEM showed slight influence of dopant nature onto their microstructure. FTIR analysis revealed that the involvement of metal species in the carbon structure was followed by their subsequent reduction and rising of oxidized carbon functionalities in the spectra. Electrochemical study showed that all the examined electrodes performed reversible processes with chemically stable generated products and no side chemical reactions. Among them, Pt-doped electrode showed superior electrocatalytic behavior in terms of heterogeneous transfer rate constant and other kinetic parameters. Since minimal addition of Pt in the hydrothermal synthesis resulted in powerful electrocatalytic effect as precious advantage, benevolent impact of carbon microspheres as catalyst support was put into focus of this research. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres
VL  - 757
SP  - 176
EP  - 182
DO  - 10.1016/j.jelechem.2015.09.035
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Matović, Branko and Babić, Biljana M. and Barek, Jiri",
year = "2015",
abstract = "This paper deals with comparison of modified carbon electrodes prepared from Pt- and Ag-doped carbon microspheres using cyclic voltammetry of [Fe(CN)(6)](3-)/[Fe(CN)(6)](4-) redox pair as a probe under various experimental conditions. Spherical particles ranging from 0.5 to 8 mu m in average as evidenced by SEM showed slight influence of dopant nature onto their microstructure. FTIR analysis revealed that the involvement of metal species in the carbon structure was followed by their subsequent reduction and rising of oxidized carbon functionalities in the spectra. Electrochemical study showed that all the examined electrodes performed reversible processes with chemically stable generated products and no side chemical reactions. Among them, Pt-doped electrode showed superior electrocatalytic behavior in terms of heterogeneous transfer rate constant and other kinetic parameters. Since minimal addition of Pt in the hydrothermal synthesis resulted in powerful electrocatalytic effect as precious advantage, benevolent impact of carbon microspheres as catalyst support was put into focus of this research. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres",
volume = "757",
pages = "176-182",
doi = "10.1016/j.jelechem.2015.09.035"
}
Ranđelović, M. S., Momčilović, M. Z., Matović, B., Babić, B. M.,& Barek, J.. (2015). Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres. in Journal of Electroanalytical Chemistry
Elsevier., 757, 176-182.
https://doi.org/10.1016/j.jelechem.2015.09.035
Ranđelović MS, Momčilović MZ, Matović B, Babić BM, Barek J. Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres. in Journal of Electroanalytical Chemistry. 2015;757:176-182.
doi:10.1016/j.jelechem.2015.09.035 .
Ranđelović, Marjan S., Momčilović, Milan Z., Matović, Branko, Babić, Biljana M., Barek, Jiri, "Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres" in Journal of Electroanalytical Chemistry, 757 (2015):176-182,
https://doi.org/10.1016/j.jelechem.2015.09.035 . .
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