Kragović, Milan M.

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Authority KeyName Variants
orcid::0000-0003-0286-9079
  • Kragović, Milan M. (10)
  • Kragović, Milan (3)
Projects
Development of technological processes for obtaining of ecological materials based on nonmetallic minerals Oxide-based environmentally-friendly porous materials for genotoxic substances removal
Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine Functional, Functionalized and Advanced Nanomaterials
Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) Fizičko-hemijski fenomeni površina alumosilikatnih minerala - osnova za razvoj novih ekoloških materijala
Razvoj materijala – akceptora, donora, i nosača aktivnih materija na bazi zeolita, bentonita i krečnjaka Improvement Of Lignite Opencast Mining Technology In Order To Increase Energy Efficiency And Occupational Safety
Predefined functional properties polymer composite materials processes and equipment development Ministry of Education, Science and Technological Development of the Republic of Serbia
Ministry of Education, Science and Technological Development of the Republic of Serbia [1702103, 1702105] Ministry of Science and Technological Development of the Republic of Serbia [142057, 19022]

Author's Bibliography

Application of Lignite Combustion Waste Slag Generated in Heating Plants as a Partial Replacement for Cement. Part II: Physical–Mechanical and Physical–Chemical Characterization of Mortar and Concrete

Kragović, Milan; Ristić, Nenad; Gulicovski, Jelena J.; Nedeljković, Andrijana; Pašalić, Snežana; Ristović, Ivica; Stojmenović, Marija

(2021)

TY  - JOUR
AU  - Kragović, Milan
AU  - Ristić, Nenad
AU  - Gulicovski, Jelena J.
AU  - Nedeljković, Andrijana
AU  - Pašalić, Snežana
AU  - Ristović, Ivica
AU  - Stojmenović, Marija
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9914
AB  - The presented study is a continuation of the research with the aim of finding a useful
value of hazardous waste slag generated by the combustion of lignite in heating plants and its
application in the construction industry. The different amounts of cement (10%, 15%, 20% and
25%) were replaced with waste slag and silica fumes in mortars and concrete production. Detailed
physical–mechanical characterization was performed on the mortar and concrete samples according
to standard procedures. Test results indicated that the replacement of cement with slag and silica
fumes reduces the physical and mechanical properties of mortar and concrete, but cement composites
retained the required structural properties. If 15–20% is considered an acceptable level of compressive
strength decrease, then it can be concluded that waste slag can be implemented in practice and be
used as a construction material, with cement replacement in the maximal amount of 20% (17.8%
of slag and 2.2% of silica fumes). On hardened mortar samples with maximal possible cement
replacement (20%), physical–chemical characterizations were performed and included X-ray and
infrared spectrophotometry, scanning electron microscopy, and thermal analysis. Results showed the
absence of new phases and the presence of only those which were characteristic for starting samples,
predominantly portlandite, quartz, calcite and calcium silicate-oxide
T2  - Minerals
T1  - Application of Lignite Combustion Waste Slag Generated in Heating Plants as a Partial Replacement for Cement. Part II: Physical–Mechanical and Physical–Chemical Characterization of Mortar and Concrete
DO  - 10.3390/min11090925
ER  - 
@article{
author = "Kragović, Milan and Ristić, Nenad and Gulicovski, Jelena J. and Nedeljković, Andrijana and Pašalić, Snežana and Ristović, Ivica and Stojmenović, Marija",
year = "2021",
abstract = "The presented study is a continuation of the research with the aim of finding a useful
value of hazardous waste slag generated by the combustion of lignite in heating plants and its
application in the construction industry. The different amounts of cement (10%, 15%, 20% and
25%) were replaced with waste slag and silica fumes in mortars and concrete production. Detailed
physical–mechanical characterization was performed on the mortar and concrete samples according
to standard procedures. Test results indicated that the replacement of cement with slag and silica
fumes reduces the physical and mechanical properties of mortar and concrete, but cement composites
retained the required structural properties. If 15–20% is considered an acceptable level of compressive
strength decrease, then it can be concluded that waste slag can be implemented in practice and be
used as a construction material, with cement replacement in the maximal amount of 20% (17.8%
of slag and 2.2% of silica fumes). On hardened mortar samples with maximal possible cement
replacement (20%), physical–chemical characterizations were performed and included X-ray and
infrared spectrophotometry, scanning electron microscopy, and thermal analysis. Results showed the
absence of new phases and the presence of only those which were characteristic for starting samples,
predominantly portlandite, quartz, calcite and calcium silicate-oxide",
journal = "Minerals",
title = "Application of Lignite Combustion Waste Slag Generated in Heating Plants as a Partial Replacement for Cement. Part II: Physical–Mechanical and Physical–Chemical Characterization of Mortar and Concrete",
doi = "10.3390/min11090925"
}
Kragović, M., Ristić, N., Gulicovski, J. J., Nedeljković, A., Pašalić, S., Ristović, I.,& Stojmenović, M.. (2021). Application of Lignite Combustion Waste Slag Generated in Heating Plants as a Partial Replacement for Cement. Part II: Physical–Mechanical and Physical–Chemical Characterization of Mortar and Concrete. in Minerals.
https://doi.org/10.3390/min11090925
Kragović M, Ristić N, Gulicovski JJ, Nedeljković A, Pašalić S, Ristović I, Stojmenović M. Application of Lignite Combustion Waste Slag Generated in Heating Plants as a Partial Replacement for Cement. Part II: Physical–Mechanical and Physical–Chemical Characterization of Mortar and Concrete. in Minerals. 2021;.
doi:10.3390/min11090925 .
Kragović, Milan, Ristić, Nenad, Gulicovski, Jelena J., Nedeljković, Andrijana, Pašalić, Snežana, Ristović, Ivica, Stojmenović, Marija, "Application of Lignite Combustion Waste Slag Generated in Heating Plants as a Partial Replacement for Cement. Part II: Physical–Mechanical and Physical–Chemical Characterization of Mortar and Concrete" in Minerals (2021),
https://doi.org/10.3390/min11090925 . .

Waste Slag from Heating Plants as a Partial Replacement for Cement in Mortar and Concrete Production. Part I—Physical–Chemical and Physical–Mechanical Characterization of Slag

Nedeljković, Andrijana; Stojmenović, Marija; Gulicovski, Jelena; Ristić, Nenad; Milićević, Sonja; Krstić, Jugoslav B.; Kragović, Milan

(MDPI, 2020)

TY  - JOUR
AU  - Nedeljković, Andrijana
AU  - Stojmenović, Marija
AU  - Gulicovski, Jelena
AU  - Ristić, Nenad
AU  - Milićević, Sonja
AU  - Krstić, Jugoslav B.
AU  - Kragović, Milan
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9730
AB  - Numerous factors influence the complexity of environmental and waste management problems, and the most significant goal is the reuse of materials that have completed their “life cycle” and the reduction in the use of new resources. In order to reduce impact of waste slag on the environment, in the present study, waste slag, generated in heating plants after lignite combustion, was characterized in detail and tested for application as a replacement for cement in mortar or concrete production. For physical–chemical characterization of slag, different experimental and instrumental techniques were used such as chemical composition and determination of the content of heavy metals, investigation of morphological and textural properties, thermal analysis, X-ray, and infrared spectroscopy. Physical–mechanical characterization of slag was also performed and included determination of activity index, water requirement, setting time and soundness. A leaching test was also performed. Presented results show that waste slag may be used in mortar and concrete production as a partial cement replacement, but after additional combustion at 650 °C and partial replacement of slag with silica fume in the minimal amount of 12%. The maximal obtained cement replacement was 20% (17.8% slag and 2.2% of silica fume).
PB  - MDPI
T2  - Minerals
T1  - Waste Slag from Heating Plants as a Partial Replacement for Cement in Mortar and Concrete Production. Part I—Physical–Chemical and Physical–Mechanical Characterization of Slag
VL  - 10
IS  - 11
SP  - 992
DO  - 10.3390/min10110992
ER  - 
@article{
author = "Nedeljković, Andrijana and Stojmenović, Marija and Gulicovski, Jelena and Ristić, Nenad and Milićević, Sonja and Krstić, Jugoslav B. and Kragović, Milan",
year = "2020",
abstract = "Numerous factors influence the complexity of environmental and waste management problems, and the most significant goal is the reuse of materials that have completed their “life cycle” and the reduction in the use of new resources. In order to reduce impact of waste slag on the environment, in the present study, waste slag, generated in heating plants after lignite combustion, was characterized in detail and tested for application as a replacement for cement in mortar or concrete production. For physical–chemical characterization of slag, different experimental and instrumental techniques were used such as chemical composition and determination of the content of heavy metals, investigation of morphological and textural properties, thermal analysis, X-ray, and infrared spectroscopy. Physical–mechanical characterization of slag was also performed and included determination of activity index, water requirement, setting time and soundness. A leaching test was also performed. Presented results show that waste slag may be used in mortar and concrete production as a partial cement replacement, but after additional combustion at 650 °C and partial replacement of slag with silica fume in the minimal amount of 12%. The maximal obtained cement replacement was 20% (17.8% slag and 2.2% of silica fume).",
publisher = "MDPI",
journal = "Minerals",
title = "Waste Slag from Heating Plants as a Partial Replacement for Cement in Mortar and Concrete Production. Part I—Physical–Chemical and Physical–Mechanical Characterization of Slag",
volume = "10",
number = "11",
pages = "992",
doi = "10.3390/min10110992"
}
Nedeljković, A., Stojmenović, M., Gulicovski, J., Ristić, N., Milićević, S., Krstić, J. B.,& Kragović, M.. (2020). Waste Slag from Heating Plants as a Partial Replacement for Cement in Mortar and Concrete Production. Part I—Physical–Chemical and Physical–Mechanical Characterization of Slag. in Minerals
MDPI., 10(11), 992.
https://doi.org/10.3390/min10110992
Nedeljković A, Stojmenović M, Gulicovski J, Ristić N, Milićević S, Krstić JB, Kragović M. Waste Slag from Heating Plants as a Partial Replacement for Cement in Mortar and Concrete Production. Part I—Physical–Chemical and Physical–Mechanical Characterization of Slag. in Minerals. 2020;10(11):992.
doi:10.3390/min10110992 .
Nedeljković, Andrijana, Stojmenović, Marija, Gulicovski, Jelena, Ristić, Nenad, Milićević, Sonja, Krstić, Jugoslav B., Kragović, Milan, "Waste Slag from Heating Plants as a Partial Replacement for Cement in Mortar and Concrete Production. Part I—Physical–Chemical and Physical–Mechanical Characterization of Slag" in Minerals, 10, no. 11 (2020):992,
https://doi.org/10.3390/min10110992 . .
2
2
2

Geopolymer/CeO2 as Solid Electrolyte for IT-SOFC

Gulicovski, Jelena J.; Nenadović, Snežana S.; Kljajević, Ljiljana M.; Mirković, Miljana M.; Nišavić, Marija; Kragović, Milan M.; Stojmenović, Marija

(2020)

TY  - JOUR
AU  - Gulicovski, Jelena J.
AU  - Nenadović, Snežana S.
AU  - Kljajević, Ljiljana M.
AU  - Mirković, Miljana M.
AU  - Nišavić, Marija
AU  - Kragović, Milan M.
AU  - Stojmenović, Marija
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8480
AB  - As a material for application in the life sciences, a new composite material, geopolymer/CeO2 (GP_CeO2), was synthesized as a potential low-cost solid electrolyte for application in solid oxide fuel cells operating in intermediate temperature (IT-SOFC). The new materials were obtained from alkali-activated metakaolin (calcined clay) in the presence of CeO2 powders (x = 10%). Besides the commercial CeO2 powder, as a source of ceria, two differently synthesized CeO2 powders also were used: CeO2 synthesized by modified glycine nitrate procedure (MGNP) and self-propagating reaction at room temperature (SPRT). The structural, morphological, and electrical properties of pure and GP_CeO2-type samples were investigated by X-ray powder diffraction (XRPD), Fourier transform infrared (FTIR), BET, differential thermal and thermogravimetric analysis (DTA/TGA), scanning electron microscopy (FE-SEM), energy dispersive spectrometer (EDS), and method complex impedance (EIS). XRPD and matrix-assisted laser desorption and ionization time-of-flight (MALDI-TOF) analysis confirmed the formation of solid phase CeO2. The BET, DTA/TGA, FE-SEM, and EDS results indicated that particles of CeO2 were stabile interconnected and form a continuous conductive path, which was confirmed by the EIS method. The highest conductivity of 1.86 × 10−2 Ω−1 cm−1 was obtained for the sample GP_CeO2_MGNP at 700 °C. The corresponding value of activation energy for conductivity was 0.26 eV in the temperature range 500–700 °C.
T2  - Polymers
T1  - Geopolymer/CeO2 as Solid Electrolyte for IT-SOFC
VL  - 12
IS  - 1
SP  - 248
DO  - 10.3390/polym12010248
ER  - 
@article{
author = "Gulicovski, Jelena J. and Nenadović, Snežana S. and Kljajević, Ljiljana M. and Mirković, Miljana M. and Nišavić, Marija and Kragović, Milan M. and Stojmenović, Marija",
year = "2020",
abstract = "As a material for application in the life sciences, a new composite material, geopolymer/CeO2 (GP_CeO2), was synthesized as a potential low-cost solid electrolyte for application in solid oxide fuel cells operating in intermediate temperature (IT-SOFC). The new materials were obtained from alkali-activated metakaolin (calcined clay) in the presence of CeO2 powders (x = 10%). Besides the commercial CeO2 powder, as a source of ceria, two differently synthesized CeO2 powders also were used: CeO2 synthesized by modified glycine nitrate procedure (MGNP) and self-propagating reaction at room temperature (SPRT). The structural, morphological, and electrical properties of pure and GP_CeO2-type samples were investigated by X-ray powder diffraction (XRPD), Fourier transform infrared (FTIR), BET, differential thermal and thermogravimetric analysis (DTA/TGA), scanning electron microscopy (FE-SEM), energy dispersive spectrometer (EDS), and method complex impedance (EIS). XRPD and matrix-assisted laser desorption and ionization time-of-flight (MALDI-TOF) analysis confirmed the formation of solid phase CeO2. The BET, DTA/TGA, FE-SEM, and EDS results indicated that particles of CeO2 were stabile interconnected and form a continuous conductive path, which was confirmed by the EIS method. The highest conductivity of 1.86 × 10−2 Ω−1 cm−1 was obtained for the sample GP_CeO2_MGNP at 700 °C. The corresponding value of activation energy for conductivity was 0.26 eV in the temperature range 500–700 °C.",
journal = "Polymers",
title = "Geopolymer/CeO2 as Solid Electrolyte for IT-SOFC",
volume = "12",
number = "1",
pages = "248",
doi = "10.3390/polym12010248"
}
Gulicovski, J. J., Nenadović, S. S., Kljajević, L. M., Mirković, M. M., Nišavić, M., Kragović, M. M.,& Stojmenović, M.. (2020). Geopolymer/CeO2 as Solid Electrolyte for IT-SOFC. in Polymers, 12(1), 248.
https://doi.org/10.3390/polym12010248
Gulicovski JJ, Nenadović SS, Kljajević LM, Mirković MM, Nišavić M, Kragović MM, Stojmenović M. Geopolymer/CeO2 as Solid Electrolyte for IT-SOFC. in Polymers. 2020;12(1):248.
doi:10.3390/polym12010248 .
Gulicovski, Jelena J., Nenadović, Snežana S., Kljajević, Ljiljana M., Mirković, Miljana M., Nišavić, Marija, Kragović, Milan M., Stojmenović, Marija, "Geopolymer/CeO2 as Solid Electrolyte for IT-SOFC" in Polymers, 12, no. 1 (2020):248,
https://doi.org/10.3390/polym12010248 . .
7
6
9

Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application

Dodevski, Vladimir; Janković, Bojan Ž.; Mirković, Miljana M.; Kragović, Milan M.; Radović, Ivana; Veljković, Filip M.; Stojmenović, Marija

(2020)

TY  - JOUR
AU  - Dodevski, Vladimir
AU  - Janković, Bojan Ž.
AU  - Mirković, Miljana M.
AU  - Kragović, Milan M.
AU  - Radović, Ivana
AU  - Veljković, Filip M.
AU  - Stojmenović, Marija
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8922
AB  - Goal of this work is to establish technical feasibility and fundamentals of producing activated carbon from plane tree seeds biomass for porous materials derivation. Bio-chars produced via carbonization from plane tree seeds precursor were activated in CO2 at 750 and 850?C, during various residence times. Their surface area and porosity were characterized by N2 adsorption at 77 K. Surface areas of activated carbons can be correlated with kinetics mechanism and activation energy magnitudes of oxidation reaction by CO2, which are closely related to applied activation temperature. Result showed that high temperature activated carbon had higher gas adsorption as compared to activated carbon obtained from lower temperature during two-hour residence time. Breakthrough behavior was detected at 850?C where surface reactions dominate, and it is characterized by autocatalytic kinetic model under designed conditions. Both, temperature and CO2 concentration in vicinity of solid surface effect on breakthrough time of adsorbent. Derived bio-chars are converted into high quality activated carbons, with surface area of 776.55 m2/g, where micro-pores with pore diameters less than 2 nm prevail. Produced activated carbons have properties comparable with commercially available activated carbons, which can be successfully used for removal of harmful gaseous pollutants toward air purification.
T2  - Thermal Science
T1  - Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application
VL  - 24
IS  - 6 (Part A)
SP  - 3807
EP  - 3821
DO  - 10.2298/TSCI190913064D
ER  - 
@article{
author = "Dodevski, Vladimir and Janković, Bojan Ž. and Mirković, Miljana M. and Kragović, Milan M. and Radović, Ivana and Veljković, Filip M. and Stojmenović, Marija",
year = "2020",
abstract = "Goal of this work is to establish technical feasibility and fundamentals of producing activated carbon from plane tree seeds biomass for porous materials derivation. Bio-chars produced via carbonization from plane tree seeds precursor were activated in CO2 at 750 and 850?C, during various residence times. Their surface area and porosity were characterized by N2 adsorption at 77 K. Surface areas of activated carbons can be correlated with kinetics mechanism and activation energy magnitudes of oxidation reaction by CO2, which are closely related to applied activation temperature. Result showed that high temperature activated carbon had higher gas adsorption as compared to activated carbon obtained from lower temperature during two-hour residence time. Breakthrough behavior was detected at 850?C where surface reactions dominate, and it is characterized by autocatalytic kinetic model under designed conditions. Both, temperature and CO2 concentration in vicinity of solid surface effect on breakthrough time of adsorbent. Derived bio-chars are converted into high quality activated carbons, with surface area of 776.55 m2/g, where micro-pores with pore diameters less than 2 nm prevail. Produced activated carbons have properties comparable with commercially available activated carbons, which can be successfully used for removal of harmful gaseous pollutants toward air purification.",
journal = "Thermal Science",
title = "Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application",
volume = "24",
number = "6 (Part A)",
pages = "3807-3821",
doi = "10.2298/TSCI190913064D"
}
Dodevski, V., Janković, B. Ž., Mirković, M. M., Kragović, M. M., Radović, I., Veljković, F. M.,& Stojmenović, M.. (2020). Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application. in Thermal Science, 24(6 (Part A)), 3807-3821.
https://doi.org/10.2298/TSCI190913064D
Dodevski V, Janković BŽ, Mirković MM, Kragović MM, Radović I, Veljković FM, Stojmenović M. Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application. in Thermal Science. 2020;24(6 (Part A)):3807-3821.
doi:10.2298/TSCI190913064D .
Dodevski, Vladimir, Janković, Bojan Ž., Mirković, Miljana M., Kragović, Milan M., Radović, Ivana, Veljković, Filip M., Stojmenović, Marija, "Carbon dioxide activation of the plane tree seeds derived bio-char: Kinetic properties and application" in Thermal Science, 24, no. 6 (Part A) (2020):3807-3821,
https://doi.org/10.2298/TSCI190913064D . .

Removal of Copper from Mining Wastewater Using Natural Raw Material—Comparative Study between the Synthetic and Natural Wastewater Samples

Milićević, Sonja; Vlahović, Milica; Kragović, Milan; Martinović, Sanja; Milošević, Vladan; Jovanović, Ivana; Stojmenović, Marija

(2020)

TY  - JOUR
AU  - Milićević, Sonja
AU  - Vlahović, Milica
AU  - Kragović, Milan
AU  - Martinović, Sanja
AU  - Milošević, Vladan
AU  - Jovanović, Ivana
AU  - Stojmenović, Marija
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9639
AB  - The intent in this paper is to define how the batch equilibrium results of copper removal from a synthetic solution on natural zeolite can be used for prediction of the breakthrough curves in the fixed-bed system for both a synthetic solution and wastewater. Natural zeolite from the Vranjska Banja deposit, Serbia, has been fully characterized (XRD, chemical composition, DTA/TG, SEM/EDS) as a clinoptilolite with cation exchange capacity of 146 meq/100 g. The maximum adsorption capacity (qm) in the batch of the mono-component system (synthetic copper solution) obtained using the Langmuir isotherm model was 7.30 and 6.10 mg/g for particle size below 0.043 and 0.6–0.8 mm, respectively. Using the flow-through system with the 0.6–0.8 mm zeolite fixed-bed, almost double the adsorption capacity (11.2–12.2 mg/g) has been achieved in a saturation point for the copper removal from the synthetic solution, compared to the batch. Better results are attributed to the constant high concentration gradient in flow-through systems compared to the batch. The complex composition of wastewater and large amounts of earth alkaline metals disturb free adsorption sights on the zeolite surface. This results in a less effective adsorption in flow-through systems with adsorption capacity in breakthrough point of 5.84 mg/g (~0.95 × qm) and in a saturation point of 7.10 mg/g (~1.15 × qm).
T2  - Minerals
T1  - Removal of Copper from Mining Wastewater Using Natural Raw Material—Comparative Study between the Synthetic and Natural Wastewater Samples
VL  - 10
IS  - 9
SP  - 753
DO  - 10.3390/min10090753
ER  - 
@article{
author = "Milićević, Sonja and Vlahović, Milica and Kragović, Milan and Martinović, Sanja and Milošević, Vladan and Jovanović, Ivana and Stojmenović, Marija",
year = "2020",
abstract = "The intent in this paper is to define how the batch equilibrium results of copper removal from a synthetic solution on natural zeolite can be used for prediction of the breakthrough curves in the fixed-bed system for both a synthetic solution and wastewater. Natural zeolite from the Vranjska Banja deposit, Serbia, has been fully characterized (XRD, chemical composition, DTA/TG, SEM/EDS) as a clinoptilolite with cation exchange capacity of 146 meq/100 g. The maximum adsorption capacity (qm) in the batch of the mono-component system (synthetic copper solution) obtained using the Langmuir isotherm model was 7.30 and 6.10 mg/g for particle size below 0.043 and 0.6–0.8 mm, respectively. Using the flow-through system with the 0.6–0.8 mm zeolite fixed-bed, almost double the adsorption capacity (11.2–12.2 mg/g) has been achieved in a saturation point for the copper removal from the synthetic solution, compared to the batch. Better results are attributed to the constant high concentration gradient in flow-through systems compared to the batch. The complex composition of wastewater and large amounts of earth alkaline metals disturb free adsorption sights on the zeolite surface. This results in a less effective adsorption in flow-through systems with adsorption capacity in breakthrough point of 5.84 mg/g (~0.95 × qm) and in a saturation point of 7.10 mg/g (~1.15 × qm).",
journal = "Minerals",
title = "Removal of Copper from Mining Wastewater Using Natural Raw Material—Comparative Study between the Synthetic and Natural Wastewater Samples",
volume = "10",
number = "9",
pages = "753",
doi = "10.3390/min10090753"
}
Milićević, S., Vlahović, M., Kragović, M., Martinović, S., Milošević, V., Jovanović, I.,& Stojmenović, M.. (2020). Removal of Copper from Mining Wastewater Using Natural Raw Material—Comparative Study between the Synthetic and Natural Wastewater Samples. in Minerals, 10(9), 753.
https://doi.org/10.3390/min10090753
Milićević S, Vlahović M, Kragović M, Martinović S, Milošević V, Jovanović I, Stojmenović M. Removal of Copper from Mining Wastewater Using Natural Raw Material—Comparative Study between the Synthetic and Natural Wastewater Samples. in Minerals. 2020;10(9):753.
doi:10.3390/min10090753 .
Milićević, Sonja, Vlahović, Milica, Kragović, Milan, Martinović, Sanja, Milošević, Vladan, Jovanović, Ivana, Stojmenović, Marija, "Removal of Copper from Mining Wastewater Using Natural Raw Material—Comparative Study between the Synthetic and Natural Wastewater Samples" in Minerals, 10, no. 9 (2020):753,
https://doi.org/10.3390/min10090753 . .
5
2
2

Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite

Kragović, Milan M.; Stojmenović, Marija; Petrović, Jelena T.; Loredo, Jorge; Pašalić, Snežana; Nedeljković, Andrijana; Ristović, Ivica

(2019)

TY  - CONF
AU  - Kragović, Milan M.
AU  - Stojmenović, Marija
AU  - Petrović, Jelena T.
AU  - Loredo, Jorge
AU  - Pašalić, Snežana
AU  - Nedeljković, Andrijana
AU  - Ristović, Ivica
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S2351978919302513
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8198
AB  - In this paper influence of alginate encapsulation on point of zero charge (pH pzc ) and thermodynamic properties of the natural and Fe(III)- modified zeolite were investigated. The pH pzc was determined by using 0.1000 g of the samples and 50 cm 3 of the solution containing KNO 3 in concentrations of 0.0001-0.01 mol/dm 3 for initial pH (pH i ) in range between 2 and 12. The obtained pH pzc were 6.2 for natural (NZA) and 6.5 for modified zeolite encapsulated with alginate (FeA). Influence of the temperature on the adsorption of lead was investigated for different initial lead ions concentrations (180-3200 mgPb 2+ /dm 3 ) and temperatures of 30, 40 and 60 o C. For both adsorbents, adsorption of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. Also, the best fits of the experimental data were obtained by Freundlich isotherm. The temperature had positive influence adsorption and removal of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. The thermodynamic parameters (the standard free energy of adsorption, standard enthalpy and standard entropy) were also determined. The results showed that lead ions removal from aqueous solutions is much favourable for FeA then NZA. © 2019 The Authors.
C3  - Procedia Manufacturing
T1  - Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite
VL  - 32
SP  - 286
EP  - 293
DO  - 10.1016/j.promfg.2019.02.216
ER  - 
@conference{
author = "Kragović, Milan M. and Stojmenović, Marija and Petrović, Jelena T. and Loredo, Jorge and Pašalić, Snežana and Nedeljković, Andrijana and Ristović, Ivica",
year = "2019",
abstract = "In this paper influence of alginate encapsulation on point of zero charge (pH pzc ) and thermodynamic properties of the natural and Fe(III)- modified zeolite were investigated. The pH pzc was determined by using 0.1000 g of the samples and 50 cm 3 of the solution containing KNO 3 in concentrations of 0.0001-0.01 mol/dm 3 for initial pH (pH i ) in range between 2 and 12. The obtained pH pzc were 6.2 for natural (NZA) and 6.5 for modified zeolite encapsulated with alginate (FeA). Influence of the temperature on the adsorption of lead was investigated for different initial lead ions concentrations (180-3200 mgPb 2+ /dm 3 ) and temperatures of 30, 40 and 60 o C. For both adsorbents, adsorption of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. Also, the best fits of the experimental data were obtained by Freundlich isotherm. The temperature had positive influence adsorption and removal of lead ions increased with increasing its initial concentration as well as with increasing of the temperature. The thermodynamic parameters (the standard free energy of adsorption, standard enthalpy and standard entropy) were also determined. The results showed that lead ions removal from aqueous solutions is much favourable for FeA then NZA. © 2019 The Authors.",
journal = "Procedia Manufacturing",
title = "Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite",
volume = "32",
pages = "286-293",
doi = "10.1016/j.promfg.2019.02.216"
}
Kragović, M. M., Stojmenović, M., Petrović, J. T., Loredo, J., Pašalić, S., Nedeljković, A.,& Ristović, I.. (2019). Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite. in Procedia Manufacturing, 32, 286-293.
https://doi.org/10.1016/j.promfg.2019.02.216
Kragović MM, Stojmenović M, Petrović JT, Loredo J, Pašalić S, Nedeljković A, Ristović I. Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite. in Procedia Manufacturing. 2019;32:286-293.
doi:10.1016/j.promfg.2019.02.216 .
Kragović, Milan M., Stojmenović, Marija, Petrović, Jelena T., Loredo, Jorge, Pašalić, Snežana, Nedeljković, Andrijana, Ristović, Ivica, "Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) - Modified Zeolite" in Procedia Manufacturing, 32 (2019):286-293,
https://doi.org/10.1016/j.promfg.2019.02.216 . .
15
14
17

Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC

Egelja, Adela; Pašalić, Snežana; Dodevski, Vladimir; Kragović, Milan M.; Stojković-Simatović, Ivana; Radovanović, Željko; Stojmenović, Marija

(2018)

TY  - JOUR
AU  - Egelja, Adela
AU  - Pašalić, Snežana
AU  - Dodevski, Vladimir
AU  - Kragović, Milan M.
AU  - Stojković-Simatović, Ivana
AU  - Radovanović, Željko
AU  - Stojmenović, Marija
PY  - 2018
UR  - http://www.doiserbia.nb.rs/Article.aspx?ID=0350-820X1803357E
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8070
AB  - Alumina/YAG composites (AYX_t) with high relative density (99.2 %TD) were successfully obtained by mixing commercial alumina powder with different volume fractions of yttrium aluminium garnet (Y3Al5O12-YAG; 7, 14, 21 and 28). YAG was synthetized by nitrate glycine reaction in the form of precursor powder. Polycrystalline YAG powder was obtained by calcination at 950 degrees C for 2 h. Additionally, obtained compositions were characterized by XRD, SEM, EDX and electrochemical impedance spectroscopy. By XRPD analysis was found that the particle size of YAG powders lies in the nanometric range (being lower than 35 nm). By SEM microphotographs of composites were confirmed the formation of a conductive path consisting from mutually interconnected YAG particles. This was confirmed by the electrochemical impedance spectroscopy. The highest electrical conductivity of grain (K-g) and grain boundary (K-gb) at 700 degrees C amounted to 2.22x10(-2) ohm(-1)cm(-1) and 9.44x10(-3) ohm(-1) cm(-1), respectively, was measured in the composite containing 21 vol% of YAG.
T2  - Science of Sintering
T1  - Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC
VL  - 50
IS  - 3
SP  - 357
EP  - 369
DO  - 10.2298/SOS1803357E
ER  - 
@article{
author = "Egelja, Adela and Pašalić, Snežana and Dodevski, Vladimir and Kragović, Milan M. and Stojković-Simatović, Ivana and Radovanović, Željko and Stojmenović, Marija",
year = "2018",
abstract = "Alumina/YAG composites (AYX_t) with high relative density (99.2 %TD) were successfully obtained by mixing commercial alumina powder with different volume fractions of yttrium aluminium garnet (Y3Al5O12-YAG; 7, 14, 21 and 28). YAG was synthetized by nitrate glycine reaction in the form of precursor powder. Polycrystalline YAG powder was obtained by calcination at 950 degrees C for 2 h. Additionally, obtained compositions were characterized by XRD, SEM, EDX and electrochemical impedance spectroscopy. By XRPD analysis was found that the particle size of YAG powders lies in the nanometric range (being lower than 35 nm). By SEM microphotographs of composites were confirmed the formation of a conductive path consisting from mutually interconnected YAG particles. This was confirmed by the electrochemical impedance spectroscopy. The highest electrical conductivity of grain (K-g) and grain boundary (K-gb) at 700 degrees C amounted to 2.22x10(-2) ohm(-1)cm(-1) and 9.44x10(-3) ohm(-1) cm(-1), respectively, was measured in the composite containing 21 vol% of YAG.",
journal = "Science of Sintering",
title = "Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC",
volume = "50",
number = "3",
pages = "357-369",
doi = "10.2298/SOS1803357E"
}
Egelja, A., Pašalić, S., Dodevski, V., Kragović, M. M., Stojković-Simatović, I., Radovanović, Ž.,& Stojmenović, M.. (2018). Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC. in Science of Sintering, 50(3), 357-369.
https://doi.org/10.2298/SOS1803357E
Egelja A, Pašalić S, Dodevski V, Kragović MM, Stojković-Simatović I, Radovanović Ž, Stojmenović M. Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC. in Science of Sintering. 2018;50(3):357-369.
doi:10.2298/SOS1803357E .
Egelja, Adela, Pašalić, Snežana, Dodevski, Vladimir, Kragović, Milan M., Stojković-Simatović, Ivana, Radovanović, Željko, Stojmenović, Marija, "Structural, morphological and electrical properties of alumina/YAG composites as solid electrolyte for IT - SOFC" in Science of Sintering, 50, no. 3 (2018):357-369,
https://doi.org/10.2298/SOS1803357E . .
1
1
1

Influence of temperature and different hydroxides on properties of activated carbon prepared from saccharose. Characterization, thermal degradation kinetic and dyes removal from water solutions

Krstić, Sanja S.; Kragović, Milan M.; Dodevski, Vladimir; Marinković, Aleksandar D.; Kaluđerović, Branka V.; Zerjav, Gregor; Pintar, Albin; Pagnacco, Maja C.; Stojmenović, Marija

(2018)

TY  - JOUR
AU  - Krstić, Sanja S.
AU  - Kragović, Milan M.
AU  - Dodevski, Vladimir
AU  - Marinković, Aleksandar D.
AU  - Kaluđerović, Branka V.
AU  - Zerjav, Gregor
AU  - Pintar, Albin
AU  - Pagnacco, Maja C.
AU  - Stojmenović, Marija
PY  - 2018
UR  - http://www.doiserbia.nb.rs/Article.aspx?ID=0350-820X1802255K
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7823
AB  - In presented paper, influence of temperature, precursor concentration and different hydroxides on properties of activated carbon obtained from saccharose were investigated. The samples were prepared by hydrothermal treatment and activated using KOH, NaOH and LiOH. Two saccharose concentrations (0.5, 1.0 mol/dm3) and three temperatures (160, 200, 240 ºC) were changed in hydrothermal treatment. Activation processes were performed at 750 ºC under N2 atmosphere. Samples were characterized by X-ray powder diffractometry, elemental analysis, N2 adsorption-desorption measurements, Fourier-transform infrared spectrometry, scanning electron microscopy and thermal analysis. The obtained samples were tested for potential application in dyes removal from water solutions.
AB  - У представљеном раду испитани су утицај температуре, концентрације полазног материјала и различитих хидроксида на својства активираних угљеничних материјала добијених из сахарозе. Узорци су припремљени хидротермалним третманом и активирани помоћу KOH, NaOH и LiOH. Две различите концентрације воденог раствора сахарозе (0,5 1,0 mol/dm3) и три температуре (160, 200, 240 ºC) су примењене у хидротермалном третману. Процеси активације су изведени на 750 ºC у атмосфери азота. Узорци су карактерисани рендгендском дифрактометријском анализом, елементарном анализом, адсорпционо-десорпционим мерењем азота, инфрацрвеном спектрометријом са Фуријеовом трансформацијом, скенирајућом електронском микроскопијом и термијском анализом. Добијени узорци су такође тестирани за потенцијалну примену у уклањању боја из водених раствора.
T2  - Science of Sintering
T1  - Influence of temperature and different hydroxides on properties of activated carbon prepared from saccharose. Characterization, thermal degradation kinetic and dyes removal from water solutions
VL  - 50
IS  - 2
SP  - 255
EP  - 273
DO  - 10.2298/SOS1802255K
ER  - 
@article{
author = "Krstić, Sanja S. and Kragović, Milan M. and Dodevski, Vladimir and Marinković, Aleksandar D. and Kaluđerović, Branka V. and Zerjav, Gregor and Pintar, Albin and Pagnacco, Maja C. and Stojmenović, Marija",
year = "2018",
abstract = "In presented paper, influence of temperature, precursor concentration and different hydroxides on properties of activated carbon obtained from saccharose were investigated. The samples were prepared by hydrothermal treatment and activated using KOH, NaOH and LiOH. Two saccharose concentrations (0.5, 1.0 mol/dm3) and three temperatures (160, 200, 240 ºC) were changed in hydrothermal treatment. Activation processes were performed at 750 ºC under N2 atmosphere. Samples were characterized by X-ray powder diffractometry, elemental analysis, N2 adsorption-desorption measurements, Fourier-transform infrared spectrometry, scanning electron microscopy and thermal analysis. The obtained samples were tested for potential application in dyes removal from water solutions., У представљеном раду испитани су утицај температуре, концентрације полазног материјала и различитих хидроксида на својства активираних угљеничних материјала добијених из сахарозе. Узорци су припремљени хидротермалним третманом и активирани помоћу KOH, NaOH и LiOH. Две различите концентрације воденог раствора сахарозе (0,5 1,0 mol/dm3) и три температуре (160, 200, 240 ºC) су примењене у хидротермалном третману. Процеси активације су изведени на 750 ºC у атмосфери азота. Узорци су карактерисани рендгендском дифрактометријском анализом, елементарном анализом, адсорпционо-десорпционим мерењем азота, инфрацрвеном спектрометријом са Фуријеовом трансформацијом, скенирајућом електронском микроскопијом и термијском анализом. Добијени узорци су такође тестирани за потенцијалну примену у уклањању боја из водених раствора.",
journal = "Science of Sintering",
title = "Influence of temperature and different hydroxides on properties of activated carbon prepared from saccharose. Characterization, thermal degradation kinetic and dyes removal from water solutions",
volume = "50",
number = "2",
pages = "255-273",
doi = "10.2298/SOS1802255K"
}
Krstić, S. S., Kragović, M. M., Dodevski, V., Marinković, A. D., Kaluđerović, B. V., Zerjav, G., Pintar, A., Pagnacco, M. C.,& Stojmenović, M.. (2018). Influence of temperature and different hydroxides on properties of activated carbon prepared from saccharose. Characterization, thermal degradation kinetic and dyes removal from water solutions. in Science of Sintering, 50(2), 255-273.
https://doi.org/10.2298/SOS1802255K
Krstić SS, Kragović MM, Dodevski V, Marinković AD, Kaluđerović BV, Zerjav G, Pintar A, Pagnacco MC, Stojmenović M. Influence of temperature and different hydroxides on properties of activated carbon prepared from saccharose. Characterization, thermal degradation kinetic and dyes removal from water solutions. in Science of Sintering. 2018;50(2):255-273.
doi:10.2298/SOS1802255K .
Krstić, Sanja S., Kragović, Milan M., Dodevski, Vladimir, Marinković, Aleksandar D., Kaluđerović, Branka V., Zerjav, Gregor, Pintar, Albin, Pagnacco, Maja C., Stojmenović, Marija, "Influence of temperature and different hydroxides on properties of activated carbon prepared from saccharose. Characterization, thermal degradation kinetic and dyes removal from water solutions" in Science of Sintering, 50, no. 2 (2018):255-273,
https://doi.org/10.2298/SOS1802255K . .
3
4
4

Natural and Modified Zeolite-Alginate Composites. Application for Removal of Heavy Metal Cations from Contaminated Water Solutions

Kragović, Milan M.; Pašalić, Snežana; Markovic, Marija; Petrović, Marija; Nedeljkovic, Blagoje; Momčilović, Miloš; Stojmenović, Marija

(2018)

TY  - JOUR
AU  - Kragović, Milan M.
AU  - Pašalić, Snežana
AU  - Markovic, Marija
AU  - Petrović, Marija
AU  - Nedeljkovic, Blagoje
AU  - Momčilović, Miloš
AU  - Stojmenović, Marija
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1946
AB  - In present paper, the influence of the initial pH and concentration of Pb2+ on its adsorption by the natural (NZA) and Fe(III)-modified zeolite-alginate beads (FeA) was studied. Results showed that modification of the starting materials have a positive effect on their adsorption capacities (102 and 136 mg/g for the NZA and FeA, respectively). After encapsulation, the mechanism of lead adsorption by both adsorbents was changed and ion exchange dominates. The best adsorption was achieved for initial pH GT 3.8. Cation exchange capacity, structural properties, and hydrophobicity of samples were also determined, and the presence of the alginate has no significant influence on investigated properties of samples. Experiments on wastewater from tailings of lead and zinc mine Grot, Serbia, showed that after treatment with both adsorbents, the content of the most abundant heavy metals (Pb, Zn, Hg, and Mn) significantly decreased.
T2  - Minerals
T1  - Natural and Modified Zeolite-Alginate Composites. Application for Removal of Heavy Metal Cations from Contaminated Water Solutions
VL  - 8
IS  - 1
DO  - 10.3390/min8010011
ER  - 
@article{
author = "Kragović, Milan M. and Pašalić, Snežana and Markovic, Marija and Petrović, Marija and Nedeljkovic, Blagoje and Momčilović, Miloš and Stojmenović, Marija",
year = "2018",
abstract = "In present paper, the influence of the initial pH and concentration of Pb2+ on its adsorption by the natural (NZA) and Fe(III)-modified zeolite-alginate beads (FeA) was studied. Results showed that modification of the starting materials have a positive effect on their adsorption capacities (102 and 136 mg/g for the NZA and FeA, respectively). After encapsulation, the mechanism of lead adsorption by both adsorbents was changed and ion exchange dominates. The best adsorption was achieved for initial pH GT 3.8. Cation exchange capacity, structural properties, and hydrophobicity of samples were also determined, and the presence of the alginate has no significant influence on investigated properties of samples. Experiments on wastewater from tailings of lead and zinc mine Grot, Serbia, showed that after treatment with both adsorbents, the content of the most abundant heavy metals (Pb, Zn, Hg, and Mn) significantly decreased.",
journal = "Minerals",
title = "Natural and Modified Zeolite-Alginate Composites. Application for Removal of Heavy Metal Cations from Contaminated Water Solutions",
volume = "8",
number = "1",
doi = "10.3390/min8010011"
}
Kragović, M. M., Pašalić, S., Markovic, M., Petrović, M., Nedeljkovic, B., Momčilović, M.,& Stojmenović, M.. (2018). Natural and Modified Zeolite-Alginate Composites. Application for Removal of Heavy Metal Cations from Contaminated Water Solutions. in Minerals, 8(1).
https://doi.org/10.3390/min8010011
Kragović MM, Pašalić S, Markovic M, Petrović M, Nedeljkovic B, Momčilović M, Stojmenović M. Natural and Modified Zeolite-Alginate Composites. Application for Removal of Heavy Metal Cations from Contaminated Water Solutions. in Minerals. 2018;8(1).
doi:10.3390/min8010011 .
Kragović, Milan M., Pašalić, Snežana, Markovic, Marija, Petrović, Marija, Nedeljkovic, Blagoje, Momčilović, Miloš, Stojmenović, Marija, "Natural and Modified Zeolite-Alginate Composites. Application for Removal of Heavy Metal Cations from Contaminated Water Solutions" in Minerals, 8, no. 1 (2018),
https://doi.org/10.3390/min8010011 . .
23
10
21

Hydrothermal Synthesized and Alkaline Activated Carbons Prepared from Glucose and Fructose—Detailed Characterization and Testing in Heavy Metals and Methylene Blue Removal

Krstić, Sanja S.; Kragović, Milan M.; Pagnacco, Maja C.; Dodevski, Vladimir; Kaluđerović, Branka V.; Momčilović, Miloš; Ristović, Ivica; Stojmenović, Marija

(2018)

TY  - JOUR
AU  - Krstić, Sanja S.
AU  - Kragović, Milan M.
AU  - Pagnacco, Maja C.
AU  - Dodevski, Vladimir
AU  - Kaluđerović, Branka V.
AU  - Momčilović, Miloš
AU  - Ristović, Ivica
AU  - Stojmenović, Marija
PY  - 2018
UR  - http://www.mdpi.com/2075-163X/8/6/246
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7733
AB  - In the presented paper, activated carbons were prepared from fructose and glucose, and activating agents (KOH, NaOH, LiOH) by hydrothermal treatment (HTC) treatment. After preparation, samples were characterized in details. Different techniques were used: x-ray powder diffraction analysis, Raman spectral analysis, elemental analysis, and determination of textural and morphological properties. Obtained results showed dependence of investigated properties and the nature of precursors (glucose or fructose) as well as the type of hydroxides used as activating agents. After characterization, samples were tested as materials for heavy metals (Pb2+, Cd2+and Zn2+) and methylene blue removal. Also, adsorption experiments were performed on wastewaters taken from tailings of the lead and zinc mine and kinetic of the methylene blue removal was studied. The factors which distinguished the KOH activated samples were high yield (~14%), content of organic carbon (63–74%), porosity and specific surface area (SBET~700–1360 m2/g), a low degree of the crystal phase, indications that potassium ions may be included in heavy metals removal, good removal of the heavy metal ions (~47–59 mg/g for Pb2+, ~21–27 mg/g for Cd2+and ~6–10 mg/g for Zn2+) and fast (~10–30 min) and good methylene blue (~60–200 mg/g) removal.
T2  - Minerals
T1  - Hydrothermal Synthesized and Alkaline Activated Carbons Prepared from Glucose and Fructose—Detailed Characterization and Testing in Heavy Metals and Methylene Blue Removal
VL  - 8
IS  - 6
SP  - 246
DO  - 10.3390/min8060246
ER  - 
@article{
author = "Krstić, Sanja S. and Kragović, Milan M. and Pagnacco, Maja C. and Dodevski, Vladimir and Kaluđerović, Branka V. and Momčilović, Miloš and Ristović, Ivica and Stojmenović, Marija",
year = "2018",
abstract = "In the presented paper, activated carbons were prepared from fructose and glucose, and activating agents (KOH, NaOH, LiOH) by hydrothermal treatment (HTC) treatment. After preparation, samples were characterized in details. Different techniques were used: x-ray powder diffraction analysis, Raman spectral analysis, elemental analysis, and determination of textural and morphological properties. Obtained results showed dependence of investigated properties and the nature of precursors (glucose or fructose) as well as the type of hydroxides used as activating agents. After characterization, samples were tested as materials for heavy metals (Pb2+, Cd2+and Zn2+) and methylene blue removal. Also, adsorption experiments were performed on wastewaters taken from tailings of the lead and zinc mine and kinetic of the methylene blue removal was studied. The factors which distinguished the KOH activated samples were high yield (~14%), content of organic carbon (63–74%), porosity and specific surface area (SBET~700–1360 m2/g), a low degree of the crystal phase, indications that potassium ions may be included in heavy metals removal, good removal of the heavy metal ions (~47–59 mg/g for Pb2+, ~21–27 mg/g for Cd2+and ~6–10 mg/g for Zn2+) and fast (~10–30 min) and good methylene blue (~60–200 mg/g) removal.",
journal = "Minerals",
title = "Hydrothermal Synthesized and Alkaline Activated Carbons Prepared from Glucose and Fructose—Detailed Characterization and Testing in Heavy Metals and Methylene Blue Removal",
volume = "8",
number = "6",
pages = "246",
doi = "10.3390/min8060246"
}
Krstić, S. S., Kragović, M. M., Pagnacco, M. C., Dodevski, V., Kaluđerović, B. V., Momčilović, M., Ristović, I.,& Stojmenović, M.. (2018). Hydrothermal Synthesized and Alkaline Activated Carbons Prepared from Glucose and Fructose—Detailed Characterization and Testing in Heavy Metals and Methylene Blue Removal. in Minerals, 8(6), 246.
https://doi.org/10.3390/min8060246
Krstić SS, Kragović MM, Pagnacco MC, Dodevski V, Kaluđerović BV, Momčilović M, Ristović I, Stojmenović M. Hydrothermal Synthesized and Alkaline Activated Carbons Prepared from Glucose and Fructose—Detailed Characterization and Testing in Heavy Metals and Methylene Blue Removal. in Minerals. 2018;8(6):246.
doi:10.3390/min8060246 .
Krstić, Sanja S., Kragović, Milan M., Pagnacco, Maja C., Dodevski, Vladimir, Kaluđerović, Branka V., Momčilović, Miloš, Ristović, Ivica, Stojmenović, Marija, "Hydrothermal Synthesized and Alkaline Activated Carbons Prepared from Glucose and Fructose—Detailed Characterization and Testing in Heavy Metals and Methylene Blue Removal" in Minerals, 8, no. 6 (2018):246,
https://doi.org/10.3390/min8060246 . .
4
4
3

Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent

Dakovic, Aleksandra; Kragović, Milan M.; Rottinghaus, George E.; Ledoux, David R.; Butkeraitis, Paula; Vojislavljevic, Dubravka Z.; Zarić, Snežana D.; Stamenić, Ljubisav

(2012)

TY  - JOUR
AU  - Dakovic, Aleksandra
AU  - Kragović, Milan M.
AU  - Rottinghaus, George E.
AU  - Ledoux, David R.
AU  - Butkeraitis, Paula
AU  - Vojislavljevic, Dubravka Z.
AU  - Zarić, Snežana D.
AU  - Stamenić, Ljubisav
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4363
AB  - A zinc-exchanged montmorillonite (Zn-MONT) was prepared from a natural montmorillonite (MONT) and the adsorption of aflatoxin B-1 (AFB(1)) was investigated at pH 3 and 7. Characterization of Zn-MONT was done by determination of chemical composition, the point of the zero charge (pH(pzc)), thermal (DTA/TGA/DTG) and X-ray powder diffraction (XRPD) analysis. Adsorption of AFB(1) (C-0 = 4 ppm) by Zn-MONT, at different solid/liquid ratios (10, 1 and 0.5 g L-1), at pH 3 or 7, showed that its adsorption was high (over 96%) and independent of pH, similar to MONT. No desorption of AFB(1) from MONT-AFB(1) and Zn-MONT-AFB(1) complexes occurred at pH 6.5, suggesting strong binding of AFB(1) by both adsorbents. Furthermore, AFB(1) adsorption by Zn-MONT followed a nonlinear (Langmuir) type of isotherm at pH 3 with a calculated maximum capacity of 60.17 mg g(-1). The stability of MONT-AFB(1) and Zn-MONT-AFB(1) complexes was evaluated by calculating the binding energies between AFB(1) and metal cations using quantum chemical methods. The evaluated interaction energies of AFB(1) with hydrated Zn2+, Mg2+, and Ca2+ cations showed that the strongest interaction was the interaction of the Zn2+ system, -70.2 kcal mol(-1), whereas energies for Mg-2 and Ca2+ systems were -68.8 and -62.9 kcal mol(-1), respectively. The results indicate that Zn-MONT can be suitable for potential practical application as both, an antibacterial and an aflatoxin binding agent. (C) 2012 Elsevier B.V. All rights reserved.
T2  - Materials Chemistry and Physics
T1  - Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent
VL  - 137
IS  - 1
SP  - 213
EP  - 220
DO  - 10.1016/j.matchemphys.2012.09.010
ER  - 
@article{
author = "Dakovic, Aleksandra and Kragović, Milan M. and Rottinghaus, George E. and Ledoux, David R. and Butkeraitis, Paula and Vojislavljevic, Dubravka Z. and Zarić, Snežana D. and Stamenić, Ljubisav",
year = "2012",
abstract = "A zinc-exchanged montmorillonite (Zn-MONT) was prepared from a natural montmorillonite (MONT) and the adsorption of aflatoxin B-1 (AFB(1)) was investigated at pH 3 and 7. Characterization of Zn-MONT was done by determination of chemical composition, the point of the zero charge (pH(pzc)), thermal (DTA/TGA/DTG) and X-ray powder diffraction (XRPD) analysis. Adsorption of AFB(1) (C-0 = 4 ppm) by Zn-MONT, at different solid/liquid ratios (10, 1 and 0.5 g L-1), at pH 3 or 7, showed that its adsorption was high (over 96%) and independent of pH, similar to MONT. No desorption of AFB(1) from MONT-AFB(1) and Zn-MONT-AFB(1) complexes occurred at pH 6.5, suggesting strong binding of AFB(1) by both adsorbents. Furthermore, AFB(1) adsorption by Zn-MONT followed a nonlinear (Langmuir) type of isotherm at pH 3 with a calculated maximum capacity of 60.17 mg g(-1). The stability of MONT-AFB(1) and Zn-MONT-AFB(1) complexes was evaluated by calculating the binding energies between AFB(1) and metal cations using quantum chemical methods. The evaluated interaction energies of AFB(1) with hydrated Zn2+, Mg2+, and Ca2+ cations showed that the strongest interaction was the interaction of the Zn2+ system, -70.2 kcal mol(-1), whereas energies for Mg-2 and Ca2+ systems were -68.8 and -62.9 kcal mol(-1), respectively. The results indicate that Zn-MONT can be suitable for potential practical application as both, an antibacterial and an aflatoxin binding agent. (C) 2012 Elsevier B.V. All rights reserved.",
journal = "Materials Chemistry and Physics",
title = "Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent",
volume = "137",
number = "1",
pages = "213-220",
doi = "10.1016/j.matchemphys.2012.09.010"
}
Dakovic, A., Kragović, M. M., Rottinghaus, G. E., Ledoux, D. R., Butkeraitis, P., Vojislavljevic, D. Z., Zarić, S. D.,& Stamenić, L.. (2012). Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent. in Materials Chemistry and Physics, 137(1), 213-220.
https://doi.org/10.1016/j.matchemphys.2012.09.010
Dakovic A, Kragović MM, Rottinghaus GE, Ledoux DR, Butkeraitis P, Vojislavljevic DZ, Zarić SD, Stamenić L. Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent. in Materials Chemistry and Physics. 2012;137(1):213-220.
doi:10.1016/j.matchemphys.2012.09.010 .
Dakovic, Aleksandra, Kragović, Milan M., Rottinghaus, George E., Ledoux, David R., Butkeraitis, Paula, Vojislavljevic, Dubravka Z., Zarić, Snežana D., Stamenić, Ljubisav, "Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent" in Materials Chemistry and Physics, 137, no. 1 (2012):213-220,
https://doi.org/10.1016/j.matchemphys.2012.09.010 . .
12
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11

Influence of natural zeolitic tuff and organozeolites surface charge on sorption of ionizable fumonisin B-1

Dakovic, Aleksandra; Kragović, Milan M.; Rottinghaus, George E.; Sekulic, Zivko; Milicevic, Sonja; Milonjić, Slobodan K.; Zarić, Snežana D.

(2010)

TY  - JOUR
AU  - Dakovic, Aleksandra
AU  - Kragović, Milan M.
AU  - Rottinghaus, George E.
AU  - Sekulic, Zivko
AU  - Milicevic, Sonja
AU  - Milonjić, Slobodan K.
AU  - Zarić, Snežana D.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3912
AB  - Natural Zeolitic tuff was modified with 2, 5 and 10 mmol M+/100 g of octadecyldimethylbenzyl ammonium (ODMBA) ions and the products were denoted as OZ-2, OZ-5 and OZ-10. The starting material and organozeolites were characterized by determination of the point of zero charge (pH(pzc)) and by thermal analysis. in vitro sorption of fumonisin B-1 (FB1) was studied for all sorbents at pH 3, 7 and 9. The pH(pzc) for the zeolitic tuff was 6.8 +/- 0.1, while the pH(pzc) for OZ-2, OZ-5 and OZ-10 pH(pzc) was 7.0 +/- 0.1. The curves pH(final) = f(pH(initial)) suggest that the surfaces of all sorbents are positively charged at pH 3 and uncharged at pH 7 and 9. High sorption of FB1 by the zeolitic tuff in acidic solution Suggests electrostatic Interactions between the anionic FB1 and the positively charged surface. At pH 7 and 9, adsorption of FB1 is prevented because anionic FB1 cannot be adsorbed at the uncharged surface. From the pH(pzc) for the organozeolites, it is possible that with lower amounts of ODMBA (OZ-2 and OZ-5), at pH 3, beside interactions between head groups of ODMBA and its alkyl chains and anionic FB1, electrostatic interactions between positive uncovered surface and anionic FB1 contribute to the sorption, while at pH 7 and 9 there is only the possibility for interactions between FB1 and ODMBA. When the zeolitic surface was completely covered with ODMBA (OZ-10), FB1 sorption was independent of the form of FB1 suggesting only interactions between ODMBA and FB1. (C) 2009 Elsevier B.V. All rights reserved.
T2  - Colloids and Surfaces. B: Biointerfaces
T1  - Influence of natural zeolitic tuff and organozeolites surface charge on sorption of ionizable fumonisin B-1
VL  - 76
IS  - 1
SP  - 272
EP  - 278
DO  - 10.1016/j.colsurfb.2009.11.003
ER  - 
@article{
author = "Dakovic, Aleksandra and Kragović, Milan M. and Rottinghaus, George E. and Sekulic, Zivko and Milicevic, Sonja and Milonjić, Slobodan K. and Zarić, Snežana D.",
year = "2010",
abstract = "Natural Zeolitic tuff was modified with 2, 5 and 10 mmol M+/100 g of octadecyldimethylbenzyl ammonium (ODMBA) ions and the products were denoted as OZ-2, OZ-5 and OZ-10. The starting material and organozeolites were characterized by determination of the point of zero charge (pH(pzc)) and by thermal analysis. in vitro sorption of fumonisin B-1 (FB1) was studied for all sorbents at pH 3, 7 and 9. The pH(pzc) for the zeolitic tuff was 6.8 +/- 0.1, while the pH(pzc) for OZ-2, OZ-5 and OZ-10 pH(pzc) was 7.0 +/- 0.1. The curves pH(final) = f(pH(initial)) suggest that the surfaces of all sorbents are positively charged at pH 3 and uncharged at pH 7 and 9. High sorption of FB1 by the zeolitic tuff in acidic solution Suggests electrostatic Interactions between the anionic FB1 and the positively charged surface. At pH 7 and 9, adsorption of FB1 is prevented because anionic FB1 cannot be adsorbed at the uncharged surface. From the pH(pzc) for the organozeolites, it is possible that with lower amounts of ODMBA (OZ-2 and OZ-5), at pH 3, beside interactions between head groups of ODMBA and its alkyl chains and anionic FB1, electrostatic interactions between positive uncovered surface and anionic FB1 contribute to the sorption, while at pH 7 and 9 there is only the possibility for interactions between FB1 and ODMBA. When the zeolitic surface was completely covered with ODMBA (OZ-10), FB1 sorption was independent of the form of FB1 suggesting only interactions between ODMBA and FB1. (C) 2009 Elsevier B.V. All rights reserved.",
journal = "Colloids and Surfaces. B: Biointerfaces",
title = "Influence of natural zeolitic tuff and organozeolites surface charge on sorption of ionizable fumonisin B-1",
volume = "76",
number = "1",
pages = "272-278",
doi = "10.1016/j.colsurfb.2009.11.003"
}
Dakovic, A., Kragović, M. M., Rottinghaus, G. E., Sekulic, Z., Milicevic, S., Milonjić, S. K.,& Zarić, S. D.. (2010). Influence of natural zeolitic tuff and organozeolites surface charge on sorption of ionizable fumonisin B-1. in Colloids and Surfaces. B: Biointerfaces, 76(1), 272-278.
https://doi.org/10.1016/j.colsurfb.2009.11.003
Dakovic A, Kragović MM, Rottinghaus GE, Sekulic Z, Milicevic S, Milonjić SK, Zarić SD. Influence of natural zeolitic tuff and organozeolites surface charge on sorption of ionizable fumonisin B-1. in Colloids and Surfaces. B: Biointerfaces. 2010;76(1):272-278.
doi:10.1016/j.colsurfb.2009.11.003 .
Dakovic, Aleksandra, Kragović, Milan M., Rottinghaus, George E., Sekulic, Zivko, Milicevic, Sonja, Milonjić, Slobodan K., Zarić, Snežana D., "Influence of natural zeolitic tuff and organozeolites surface charge on sorption of ionizable fumonisin B-1" in Colloids and Surfaces. B: Biointerfaces, 76, no. 1 (2010):272-278,
https://doi.org/10.1016/j.colsurfb.2009.11.003 . .
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20
23

Influence of Organic Cations Sorption on the Point of Zero Charge of Natural Zeolite

Kragović, Milan M.; Dakovic, Aleksandra S.; Milicevic, Sonja Z.; Sekulic, Zivko T.; Milonjić, Slobodan K.

(2009)

TY  - JOUR
AU  - Kragović, Milan M.
AU  - Dakovic, Aleksandra S.
AU  - Milicevic, Sonja Z.
AU  - Sekulic, Zivko T.
AU  - Milonjić, Slobodan K.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3815
AB  - In this paper, the results of the surface modification of natural zeolite with different amounts (2, 5 and 10 mmol M(+)/100 g) of octadecyldimethylbenzyl ammonium ions (ODMBA) are presented. The obtained organozeohtes were denoted as OZ-2, OZ-5 and OZ-10. The degree of ion exchange was followed by determination of amounts of inorganic cations released from zeolite. Results confirmed that reaction between ODMBA and starting zeolite has occurred via ion exchange mechanism. The obtained value for point of zero charge, pH(pzc), of natural zeolite was 6.8 +/- 0.1, while for OZ-2, OZ-5 and OZ-10 pH(pzc) was 7.0 +/- 0.1. Below the pH(pzc), the surfaces of materials are positive while at pH values higher than pH(pzc) their surfaces are negative. Compared to the pHpzc of natural zeolite, no significant differences in pH(pzc) was observed for all three organozeolites indicating that obtained products have similar functional groups with similar acid and basic characteristics as starting zeolite. The pH(pzc) was not dependent on the amount of ODMBA ions at the zeolitic surface and the value of pH(pzc) for all investigated sorbents is the same for all three electrolyte concentrations indicating that the pH(pzc) of each material is independent of the ionic strength of KNO(3).
T2  - Hemijska industrija
T1  - Influence of Organic Cations Sorption on the Point of Zero Charge of Natural Zeolite
VL  - 63
IS  - 4
SP  - 325
EP  - 330
DO  - 10.2298/HEMIND0904325K
ER  - 
@article{
author = "Kragović, Milan M. and Dakovic, Aleksandra S. and Milicevic, Sonja Z. and Sekulic, Zivko T. and Milonjić, Slobodan K.",
year = "2009",
abstract = "In this paper, the results of the surface modification of natural zeolite with different amounts (2, 5 and 10 mmol M(+)/100 g) of octadecyldimethylbenzyl ammonium ions (ODMBA) are presented. The obtained organozeohtes were denoted as OZ-2, OZ-5 and OZ-10. The degree of ion exchange was followed by determination of amounts of inorganic cations released from zeolite. Results confirmed that reaction between ODMBA and starting zeolite has occurred via ion exchange mechanism. The obtained value for point of zero charge, pH(pzc), of natural zeolite was 6.8 +/- 0.1, while for OZ-2, OZ-5 and OZ-10 pH(pzc) was 7.0 +/- 0.1. Below the pH(pzc), the surfaces of materials are positive while at pH values higher than pH(pzc) their surfaces are negative. Compared to the pHpzc of natural zeolite, no significant differences in pH(pzc) was observed for all three organozeolites indicating that obtained products have similar functional groups with similar acid and basic characteristics as starting zeolite. The pH(pzc) was not dependent on the amount of ODMBA ions at the zeolitic surface and the value of pH(pzc) for all investigated sorbents is the same for all three electrolyte concentrations indicating that the pH(pzc) of each material is independent of the ionic strength of KNO(3).",
journal = "Hemijska industrija",
title = "Influence of Organic Cations Sorption on the Point of Zero Charge of Natural Zeolite",
volume = "63",
number = "4",
pages = "325-330",
doi = "10.2298/HEMIND0904325K"
}
Kragović, M. M., Dakovic, A. S., Milicevic, S. Z., Sekulic, Z. T.,& Milonjić, S. K.. (2009). Influence of Organic Cations Sorption on the Point of Zero Charge of Natural Zeolite. in Hemijska industrija, 63(4), 325-330.
https://doi.org/10.2298/HEMIND0904325K
Kragović MM, Dakovic AS, Milicevic SZ, Sekulic ZT, Milonjić SK. Influence of Organic Cations Sorption on the Point of Zero Charge of Natural Zeolite. in Hemijska industrija. 2009;63(4):325-330.
doi:10.2298/HEMIND0904325K .
Kragović, Milan M., Dakovic, Aleksandra S., Milicevic, Sonja Z., Sekulic, Zivko T., Milonjić, Slobodan K., "Influence of Organic Cations Sorption on the Point of Zero Charge of Natural Zeolite" in Hemijska industrija, 63, no. 4 (2009):325-330,
https://doi.org/10.2298/HEMIND0904325K . .
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