TY  - JOUR
AU  - Mitrović, Jelena
AU  - Bjelošević Žiberna, Maja
AU  - Vukadinović, Aleksandar
AU  - Knutson, Daniel E.
AU  - Sharmin, Dishary
AU  - Kremenović, Aleksandar
AU  - Ahlin Grabnar, Pegi
AU  - Planinšek, Odon
AU  - Lunter, Dominique
AU  - Cook, James M
AU  - Savić, Miroslav
AU  - Savić, Snežana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11440
AB  - Recently, nanocrystal dispersions have been considered as a promising formulation strategy to improve the bioavailability of the deuterated pyrazoloquinolinone ligand DK-I-56-1 (7‑methoxy-2-(4‑methoxy-d3-phenyl)-2,5-dihydro-3H-pyrazolo[4,3-c]quinolin-3-one). In the current study, the freeze-drying process (formulation and process parameters) was investigated to improve the storage stability of the previously developed formulation. Different combinations of lyoprotectant (sucrose or trehalose) and bulking agent (mannitol) were varied while formulations were freeze-dried under two conditions (primary drying at -10 or -45 °C). The obtained lyophilizates were characterized in terms of particle size, solid state properties and morphology, while the interactions within the samples were analyzed by Fourier transform infrared spectroscopy. In the preliminary study, three formulations were selected based on the high redispersibility index values (around 95%). The temperature of primary drying had no significant effect on particle size, but stability during storage was impaired for samples dried at -10 °C. Samples dried at lower temperature were more homogeneous and remained stable for three months. It was found that the optimal ratio of sucrose or trehalose to mannitol was 3:2 at a total concentration of 10% to achieve the best stability (particle size < 1.0 μm, polydispersity index < 0.250). The amorphous state of lyoprotectants probably provided a high degree of interaction with nanocrystals, while the crystalline mannitol provided an elegant cake structure. Sucrose was superior to trehalose in maintaining particle size during freeze-drying, while trehalose was more effective in keeping particle size within limits during storage. In conclusion, results demonstrated that the appropriate combination of sucrose/trehalose and mannitol together with the appropriate selection of lyophilization process parameters could yield nanocrystals with satisfactory stability.
T2  - European Journal of Pharmaceutical Sciences
T1  - Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study
VL  - 189
DO  - 10.1016/j.ejps.2023.106557
ER  - 

@article{
author = "Mitrović, Jelena and Bjelošević Žiberna, Maja and Vukadinović, Aleksandar and Knutson, Daniel E. and Sharmin, Dishary and Kremenović, Aleksandar and Ahlin Grabnar, Pegi and Planinšek, Odon and Lunter, Dominique and Cook, James M and Savić, Miroslav and Savić, Snežana",
year = "2023",
abstract = "Recently, nanocrystal dispersions have been considered as a promising formulation strategy to improve the bioavailability of the deuterated pyrazoloquinolinone ligand DK-I-56-1 (7‑methoxy-2-(4‑methoxy-d3-phenyl)-2,5-dihydro-3H-pyrazolo[4,3-c]quinolin-3-one). In the current study, the freeze-drying process (formulation and process parameters) was investigated to improve the storage stability of the previously developed formulation. Different combinations of lyoprotectant (sucrose or trehalose) and bulking agent (mannitol) were varied while formulations were freeze-dried under two conditions (primary drying at -10 or -45 °C). The obtained lyophilizates were characterized in terms of particle size, solid state properties and morphology, while the interactions within the samples were analyzed by Fourier transform infrared spectroscopy. In the preliminary study, three formulations were selected based on the high redispersibility index values (around 95%). The temperature of primary drying had no significant effect on particle size, but stability during storage was impaired for samples dried at -10 °C. Samples dried at lower temperature were more homogeneous and remained stable for three months. It was found that the optimal ratio of sucrose or trehalose to mannitol was 3:2 at a total concentration of 10% to achieve the best stability (particle size < 1.0 μm, polydispersity index < 0.250). The amorphous state of lyoprotectants probably provided a high degree of interaction with nanocrystals, while the crystalline mannitol provided an elegant cake structure. Sucrose was superior to trehalose in maintaining particle size during freeze-drying, while trehalose was more effective in keeping particle size within limits during storage. In conclusion, results demonstrated that the appropriate combination of sucrose/trehalose and mannitol together with the appropriate selection of lyophilization process parameters could yield nanocrystals with satisfactory stability.",
journal = "European Journal of Pharmaceutical Sciences",
title = "Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study",
volume = "189",
doi = "10.1016/j.ejps.2023.106557"
}

Mitrović, J., Bjelošević Žiberna, M., Vukadinović, A., Knutson, D. E., Sharmin, D., Kremenović, A., Ahlin Grabnar, P., Planinšek, O., Lunter, D., Cook, J. M., Savić, M.,& Savić, S.. (2023). Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study. in European Journal of Pharmaceutical Sciences, 189.
https://doi.org/10.1016/j.ejps.2023.106557

Mitrović J, Bjelošević Žiberna M, Vukadinović A, Knutson DE, Sharmin D, Kremenović A, Ahlin Grabnar P, Planinšek O, Lunter D, Cook JM, Savić M, Savić S. Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study. in European Journal of Pharmaceutical Sciences. 2023;189.
doi:10.1016/j.ejps.2023.106557 .

Mitrović, Jelena, Bjelošević Žiberna, Maja, Vukadinović, Aleksandar, Knutson, Daniel E., Sharmin, Dishary, Kremenović, Aleksandar, Ahlin Grabnar, Pegi, Planinšek, Odon, Lunter, Dominique, Cook, James M, Savić, Miroslav, Savić, Snežana, "Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study" in European Journal of Pharmaceutical Sciences, 189 (2023),
https://doi.org/10.1016/j.ejps.2023.106557 . .

TY  - JOUR
AU  - Divović Matović, Branka
AU  - Knutson, Dan
AU  - Mitrović, Jelena
AU  - Stevanović, Vladimir
AU  - Stanojević, Boban
AU  - Savić, Snežana
AU  - Cook, James M.
AU  - Savić, Miroslav M.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10454
AB  - Several pyrazoloquinolinone (PQ) ligands were recently discovered as functionally selective positive modulators at the PQ site of α6-containing GABAA receptors. PQs are also neutral modulators at the benzodiazepine site. We assessed the influence of PQ compounds from three structural groups (PZ-II-029 and related deuterated analogues DK-I-56-1, RV-I-029, DK-I-60-3 and DK-I-86-1; LAU 463 and related analogues DK-I-58-1 and DK-II-58-1; and DK-I-87-1), alone and in combination with diazepam, on the behaviour of male Sprague–Dawley rats. An excellent behavioural safety profile of all tested PQs was demonstrated in the spontaneous locomotor activity, rotarod, loss of righting reflex and pentylenetetrazol tests. In interaction studies, only PZ-II-029 and its analogues prevented the ataxic effects of the benzodiazepine, as assessed in the rotarod test and during monitoring of rat locomotor activity after awakening from the loss of righting reflex. Published electrophysiological profiles of PQ ligands imply that positive modulation elicited at α6-GABAA receptors that contain the γ2 and δ subunit, rather than their neutral modulatory action at the benzodiazepine site, may prevent the ataxic action of diazepam. Thus, PZ-II-029 and its deuterated analogues are not prone to untoward interactions with benzodiazepines and may indeed completely abolish their ataxic action, seen at therapeutic, and especially toxic concentrations.
T2  - Basic & Clinical Pharmacology & Toxicology
T1  - Behavioural interaction of pyrazoloquinolinone positive allosteric modulators at α6GABAA receptors and diazepam in rats: Anti-diazepam-induced ataxia action as a structure-dependent feature
VL  - 131
IS  - 6
SP  - 514
EP  - 524
DO  - 10.1111/bcpt.13801
ER  - 

@article{
author = "Divović Matović, Branka and Knutson, Dan and Mitrović, Jelena and Stevanović, Vladimir and Stanojević, Boban and Savić, Snežana and Cook, James M. and Savić, Miroslav M.",
year = "2022",
abstract = "Several pyrazoloquinolinone (PQ) ligands were recently discovered as functionally selective positive modulators at the PQ site of α6-containing GABAA receptors. PQs are also neutral modulators at the benzodiazepine site. We assessed the influence of PQ compounds from three structural groups (PZ-II-029 and related deuterated analogues DK-I-56-1, RV-I-029, DK-I-60-3 and DK-I-86-1; LAU 463 and related analogues DK-I-58-1 and DK-II-58-1; and DK-I-87-1), alone and in combination with diazepam, on the behaviour of male Sprague–Dawley rats. An excellent behavioural safety profile of all tested PQs was demonstrated in the spontaneous locomotor activity, rotarod, loss of righting reflex and pentylenetetrazol tests. In interaction studies, only PZ-II-029 and its analogues prevented the ataxic effects of the benzodiazepine, as assessed in the rotarod test and during monitoring of rat locomotor activity after awakening from the loss of righting reflex. Published electrophysiological profiles of PQ ligands imply that positive modulation elicited at α6-GABAA receptors that contain the γ2 and δ subunit, rather than their neutral modulatory action at the benzodiazepine site, may prevent the ataxic action of diazepam. Thus, PZ-II-029 and its deuterated analogues are not prone to untoward interactions with benzodiazepines and may indeed completely abolish their ataxic action, seen at therapeutic, and especially toxic concentrations.",
journal = "Basic & Clinical Pharmacology & Toxicology",
title = "Behavioural interaction of pyrazoloquinolinone positive allosteric modulators at α6GABAA receptors and diazepam in rats: Anti-diazepam-induced ataxia action as a structure-dependent feature",
volume = "131",
number = "6",
pages = "514-524",
doi = "10.1111/bcpt.13801"
}

Divović Matović, B., Knutson, D., Mitrović, J., Stevanović, V., Stanojević, B., Savić, S., Cook, J. M.,& Savić, M. M.. (2022). Behavioural interaction of pyrazoloquinolinone positive allosteric modulators at α6GABAA receptors and diazepam in rats: Anti-diazepam-induced ataxia action as a structure-dependent feature. in Basic & Clinical Pharmacology & Toxicology, 131(6), 514-524.
https://doi.org/10.1111/bcpt.13801

Divović Matović B, Knutson D, Mitrović J, Stevanović V, Stanojević B, Savić S, Cook JM, Savić MM. Behavioural interaction of pyrazoloquinolinone positive allosteric modulators at α6GABAA receptors and diazepam in rats: Anti-diazepam-induced ataxia action as a structure-dependent feature. in Basic & Clinical Pharmacology & Toxicology. 2022;131(6):514-524.
doi:10.1111/bcpt.13801 .

Divović Matović, Branka, Knutson, Dan, Mitrović, Jelena, Stevanović, Vladimir, Stanojević, Boban, Savić, Snežana, Cook, James M., Savić, Miroslav M., "Behavioural interaction of pyrazoloquinolinone positive allosteric modulators at α6GABAA receptors and diazepam in rats: Anti-diazepam-induced ataxia action as a structure-dependent feature" in Basic & Clinical Pharmacology & Toxicology, 131, no. 6 (2022):514-524,
https://doi.org/10.1111/bcpt.13801 . .

TY  - JOUR
AU  - Najdanović, Slobodan M.
AU  - Petrović, Milica M.
AU  - Slipper, Ian J.
AU  - Kostić, Miloš M.
AU  - Prekajski, Marija D.
AU  - Mitrović, Jelena Z.
AU  - Bojić, Aleksandar Lj.
PY  - 2018
UR  - http://www.ingentaconnect.com/content/10.2175/106143017X15131012152924
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7869
AB  - A new photocatalyst bismuth oxo citrate was synthesized by facile precipitation process with calcination at 200 8C. The photocatalyst was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fouriertransform infrared (FTIR) spectroscopy, N2 sorptometry, and elemental analysis. Morphologically, it is composed of polyhedral particles with different, irregular shapes and sizes. The specific surface area (SSA) of the photocatalyst was 8.92 m2 g-1. It showed very good photocatalytic performance and reusability. Total decolorization of Reactive Blue 19 (RB19) was achieved in less than 10 minutes, which is much faster in comparison with TiO2 P25. Also, bismuth oxo citrate showed higher photocatalytic activity than other photocatalysts based on bismuth compounds reported by other authors. Optimal photocatalysis parameters were pH 2 and photocatalyst dose of 250 mg dm-3. The decolorization rate was found to decrease as initial dye concentration increased. The photocatalytic data best fitted to L-H kinetic model with pseudo-first order reaction rate. Chrastil diffusion model showed that diffusion has not influence on the process. Water Environ. Res., 90, 719 (2018). © 2018 Water Environment Federation.
T2  - Water Environment Research
T1  - A New Photocatalyst Bismuth Oxo Citrate: Synthesis, Characterization, and Photocatalytic Performance
VL  - 90
IS  - 8
SP  - 719
EP  - 728
DO  - 10.2175/106143017X15131012152924
ER  - 

@article{
author = "Najdanović, Slobodan M. and Petrović, Milica M. and Slipper, Ian J. and Kostić, Miloš M. and Prekajski, Marija D. and Mitrović, Jelena Z. and Bojić, Aleksandar Lj.",
year = "2018",
abstract = "A new photocatalyst bismuth oxo citrate was synthesized by facile precipitation process with calcination at 200 8C. The photocatalyst was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fouriertransform infrared (FTIR) spectroscopy, N2 sorptometry, and elemental analysis. Morphologically, it is composed of polyhedral particles with different, irregular shapes and sizes. The specific surface area (SSA) of the photocatalyst was 8.92 m2 g-1. It showed very good photocatalytic performance and reusability. Total decolorization of Reactive Blue 19 (RB19) was achieved in less than 10 minutes, which is much faster in comparison with TiO2 P25. Also, bismuth oxo citrate showed higher photocatalytic activity than other photocatalysts based on bismuth compounds reported by other authors. Optimal photocatalysis parameters were pH 2 and photocatalyst dose of 250 mg dm-3. The decolorization rate was found to decrease as initial dye concentration increased. The photocatalytic data best fitted to L-H kinetic model with pseudo-first order reaction rate. Chrastil diffusion model showed that diffusion has not influence on the process. Water Environ. Res., 90, 719 (2018). © 2018 Water Environment Federation.",
journal = "Water Environment Research",
title = "A New Photocatalyst Bismuth Oxo Citrate: Synthesis, Characterization, and Photocatalytic Performance",
volume = "90",
number = "8",
pages = "719-728",
doi = "10.2175/106143017X15131012152924"
}

Najdanović, S. M., Petrović, M. M., Slipper, I. J., Kostić, M. M., Prekajski, M. D., Mitrović, J. Z.,& Bojić, A. Lj.. (2018). A New Photocatalyst Bismuth Oxo Citrate: Synthesis, Characterization, and Photocatalytic Performance. in Water Environment Research, 90(8), 719-728.
https://doi.org/10.2175/106143017X15131012152924

Najdanović SM, Petrović MM, Slipper IJ, Kostić MM, Prekajski MD, Mitrović JZ, Bojić AL. A New Photocatalyst Bismuth Oxo Citrate: Synthesis, Characterization, and Photocatalytic Performance. in Water Environment Research. 2018;90(8):719-728.
doi:10.2175/106143017X15131012152924 .

Najdanović, Slobodan M., Petrović, Milica M., Slipper, Ian J., Kostić, Miloš M., Prekajski, Marija D., Mitrović, Jelena Z., Bojić, Aleksandar Lj., "A New Photocatalyst Bismuth Oxo Citrate: Synthesis, Characterization, and Photocatalytic Performance" in Water Environment Research, 90, no. 8 (2018):719-728,
https://doi.org/10.2175/106143017X15131012152924 . .

TY  - JOUR
AU  - Bojić, Danijela V.
AU  - Momčilović, Milan Z.
AU  - Milenković, Dragan D.
AU  - Mitrović, Jelena Z.
AU  - Bankovic, Predrag
AU  - Velinov, Nena D.
AU  - Nikolić, Goran
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1811
AB  - Practical aspects of Lagenaria vulgaris shell conversion to activated carbon were examined along with its use in ranitidine adsorption. Kinetics and isotherms of adsorption onto Lagenaria vulgaris carbon (LVC) were correlated to several theoretical adsorption models. The best fit was found in the case of Langmuir and pseudo-second-order model indicating monolayer adsorption. The influence of pH under kinetic study showed slightly hindered adsorption below pH 4. The optimal adsorbent dosage was set to 1 g/L. LVC was characterized by several complementary techniques, including wet chemical techniques such as Boehms titrations and determination of pH(pzc) and pH of LVC, which revealed neutral nature of the adsorbent. N-2 sorptometry determined specific surface area of 665 m(2)/g and significant ratio of micropores in the sample with maximum walls diameter of 2.2 nm. Fourier transform infrared spectroscopy (FTIR) confirmed the role of lignin and cellulose in the formation of the final LVC structure. Porous structure of the material was proved by using scanning electron microscopy. Preparation of LVC material drew attention as an easy and low-cost process for production of a highly efficient adsorbent which exhibited fast kinetics of ranitidine removal in the first minutes of contacting and large adsorption capacity (315.5 mg/g) at equilibrium. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.
T2  - Arabian Journal of Chemistry
T1  - Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions
VL  - 10
IS  - 7
SP  - 956
EP  - 964
DO  - 10.1016/j.arabjc.2014.12.018
ER  - 

@article{
author = "Bojić, Danijela V. and Momčilović, Milan Z. and Milenković, Dragan D. and Mitrović, Jelena Z. and Bankovic, Predrag and Velinov, Nena D. and Nikolić, Goran",
year = "2017",
abstract = "Practical aspects of Lagenaria vulgaris shell conversion to activated carbon were examined along with its use in ranitidine adsorption. Kinetics and isotherms of adsorption onto Lagenaria vulgaris carbon (LVC) were correlated to several theoretical adsorption models. The best fit was found in the case of Langmuir and pseudo-second-order model indicating monolayer adsorption. The influence of pH under kinetic study showed slightly hindered adsorption below pH 4. The optimal adsorbent dosage was set to 1 g/L. LVC was characterized by several complementary techniques, including wet chemical techniques such as Boehms titrations and determination of pH(pzc) and pH of LVC, which revealed neutral nature of the adsorbent. N-2 sorptometry determined specific surface area of 665 m(2)/g and significant ratio of micropores in the sample with maximum walls diameter of 2.2 nm. Fourier transform infrared spectroscopy (FTIR) confirmed the role of lignin and cellulose in the formation of the final LVC structure. Porous structure of the material was proved by using scanning electron microscopy. Preparation of LVC material drew attention as an easy and low-cost process for production of a highly efficient adsorbent which exhibited fast kinetics of ranitidine removal in the first minutes of contacting and large adsorption capacity (315.5 mg/g) at equilibrium. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.",
journal = "Arabian Journal of Chemistry",
title = "Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions",
volume = "10",
number = "7",
pages = "956-964",
doi = "10.1016/j.arabjc.2014.12.018"
}

Bojić, D. V., Momčilović, M. Z., Milenković, D. D., Mitrović, J. Z., Bankovic, P., Velinov, N. D.,& Nikolić, G.. (2017). Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions. in Arabian Journal of Chemistry, 10(7), 956-964.
https://doi.org/10.1016/j.arabjc.2014.12.018

Bojić DV, Momčilović MZ, Milenković DD, Mitrović JZ, Bankovic P, Velinov ND, Nikolić G. Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions. in Arabian Journal of Chemistry. 2017;10(7):956-964.
doi:10.1016/j.arabjc.2014.12.018 .

Bojić, Danijela V., Momčilović, Milan Z., Milenković, Dragan D., Mitrović, Jelena Z., Bankovic, Predrag, Velinov, Nena D., Nikolić, Goran, "Characterization of a low cost Lagenaria vulgaris based carbon for ranitidine removal from aqueous solutions" in Arabian Journal of Chemistry, 10, no. 7 (2017):956-964,
https://doi.org/10.1016/j.arabjc.2014.12.018 . .

TY  - JOUR
AU  - Vasić, Marija B.
AU  - Ranđelović, Marjan S.
AU  - Mitrović, Jelena Z.
AU  - Stojkovć, Nikola I.
AU  - Matović, Branko
AU  - Zarubica, Aleksandra R.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1671
AB  - Titania based catalyst and TiO2 doped with zirconia were prepared by modified sol-gel method. The synthesized catalysts samples were characterized by BET, XRD, SEM and FTIR techniques. Photocatalytic activity was tested in the reaction of crystal violet (CV) dye decolorization/decomposition under UV light irradiation. The effect of several operational parameters, such as catalyst dosage, initial dye concentrations, duration of UV irradiation treatment and number of reaction cycles were also considered. The obtained results indicated faster dye decolorization with the increase of the catalyst amount and a decrease of initial CV concentrations. An influence of doping with zirconia on the physico-chemical properties of bare titania was studied. The doping procedure had affected photocatalytic properties of the final catalytic material, and had improved photocatalytic performances of doped catalyst on crystal violet decolorization/degradation in comparison to bare titania.
T2  - Hemijska industrija
T1  - Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts
VL  - 71
IS  - 3
SP  - 259
EP  - 269
DO  - 10.2298/HEMIND160521036V
ER  - 

@article{
author = "Vasić, Marija B. and Ranđelović, Marjan S. and Mitrović, Jelena Z. and Stojkovć, Nikola I. and Matović, Branko and Zarubica, Aleksandra R.",
year = "2017",
abstract = "Titania based catalyst and TiO2 doped with zirconia were prepared by modified sol-gel method. The synthesized catalysts samples were characterized by BET, XRD, SEM and FTIR techniques. Photocatalytic activity was tested in the reaction of crystal violet (CV) dye decolorization/decomposition under UV light irradiation. The effect of several operational parameters, such as catalyst dosage, initial dye concentrations, duration of UV irradiation treatment and number of reaction cycles were also considered. The obtained results indicated faster dye decolorization with the increase of the catalyst amount and a decrease of initial CV concentrations. An influence of doping with zirconia on the physico-chemical properties of bare titania was studied. The doping procedure had affected photocatalytic properties of the final catalytic material, and had improved photocatalytic performances of doped catalyst on crystal violet decolorization/degradation in comparison to bare titania.",
journal = "Hemijska industrija",
title = "Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts",
volume = "71",
number = "3",
pages = "259-269",
doi = "10.2298/HEMIND160521036V"
}

Vasić, M. B., Ranđelović, M. S., Mitrović, J. Z., Stojkovć, N. I., Matović, B.,& Zarubica, A. R.. (2017). Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts. in Hemijska industrija, 71(3), 259-269.
https://doi.org/10.2298/HEMIND160521036V

Vasić MB, Ranđelović MS, Mitrović JZ, Stojkovć NI, Matović B, Zarubica AR. Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts. in Hemijska industrija. 2017;71(3):259-269.
doi:10.2298/HEMIND160521036V .

Vasić, Marija B., Ranđelović, Marjan S., Mitrović, Jelena Z., Stojkovć, Nikola I., Matović, Branko, Zarubica, Aleksandra R., "Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts" in Hemijska industrija, 71, no. 3 (2017):259-269,
https://doi.org/10.2298/HEMIND160521036V . .

TY  - JOUR
AU  - Petrović, Milica M.
AU  - Mitrović, Jelena Z.
AU  - Antonijevic, Milan D.
AU  - Matović, Branko
AU  - Bojić, Danijela V.
AU  - Bojić, Aleksandar Lj.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/518
AB  - This paper reports the synthesis, characterization and application of a Ti-Bi2O3 anode for the electrochemical decolorization of the textile dye Reactive Red 2. The anode was synthesized by electrodeposition on a Ti substrate immersed in an acidic bismuth (III) solution at constant potential, followed by calcination in air at 600 degrees C. Thermogravithetric Analysis (TGA), Energy-dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD) analysis revealed that the electrodeposited material was predominantly metallic bismuth, which was oxidized to pure alpha-Bi2O3 during the calcination in air. SEM micrographs revealed that the Bi2O3 coat at the anode surface was inhomogeneous and porous. Reactive Red 2 was completely electrochemically decolorized at the synthesized anode in the presence of H2O2. The applied current density, H2O2 and Na2SO4 concentration, medium pH and initial dye concentration affected the dye decolorization rate. The optimal process parameters were found to be as follows: an applied current density of 40 mA cm(-2) using a mixture of 10 mmol dm(-3) H2O2 and 10 mmol dm(-3) Na2SO4 at pH 7. The dye decolorization rate was shown to decrease as its initial concentration increased. The decolorization reactions were found to follow pseudo-first order kinetics. (C) 2015 Elsevier B.V. All rights reserved.
T2  - Materials Chemistry and Physics
T1  - Synthesis and characterization of new Ti-Bi2O3 anode and its use for reactive dye degradation
VL  - 158
SP  - 31
EP  - 37
DO  - 10.1016/j.matchemphys.2015.03.030
ER  - 

@article{
author = "Petrović, Milica M. and Mitrović, Jelena Z. and Antonijevic, Milan D. and Matović, Branko and Bojić, Danijela V. and Bojić, Aleksandar Lj.",
year = "2015",
abstract = "This paper reports the synthesis, characterization and application of a Ti-Bi2O3 anode for the electrochemical decolorization of the textile dye Reactive Red 2. The anode was synthesized by electrodeposition on a Ti substrate immersed in an acidic bismuth (III) solution at constant potential, followed by calcination in air at 600 degrees C. Thermogravithetric Analysis (TGA), Energy-dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD) analysis revealed that the electrodeposited material was predominantly metallic bismuth, which was oxidized to pure alpha-Bi2O3 during the calcination in air. SEM micrographs revealed that the Bi2O3 coat at the anode surface was inhomogeneous and porous. Reactive Red 2 was completely electrochemically decolorized at the synthesized anode in the presence of H2O2. The applied current density, H2O2 and Na2SO4 concentration, medium pH and initial dye concentration affected the dye decolorization rate. The optimal process parameters were found to be as follows: an applied current density of 40 mA cm(-2) using a mixture of 10 mmol dm(-3) H2O2 and 10 mmol dm(-3) Na2SO4 at pH 7. The dye decolorization rate was shown to decrease as its initial concentration increased. The decolorization reactions were found to follow pseudo-first order kinetics. (C) 2015 Elsevier B.V. All rights reserved.",
journal = "Materials Chemistry and Physics",
title = "Synthesis and characterization of new Ti-Bi2O3 anode and its use for reactive dye degradation",
volume = "158",
pages = "31-37",
doi = "10.1016/j.matchemphys.2015.03.030"
}

Petrović, M. M., Mitrović, J. Z., Antonijevic, M. D., Matović, B., Bojić, D. V.,& Bojić, A. Lj.. (2015). Synthesis and characterization of new Ti-Bi2O3 anode and its use for reactive dye degradation. in Materials Chemistry and Physics, 158, 31-37.
https://doi.org/10.1016/j.matchemphys.2015.03.030

Petrović MM, Mitrović JZ, Antonijevic MD, Matović B, Bojić DV, Bojić AL. Synthesis and characterization of new Ti-Bi2O3 anode and its use for reactive dye degradation. in Materials Chemistry and Physics. 2015;158:31-37.
doi:10.1016/j.matchemphys.2015.03.030 .

Petrović, Milica M., Mitrović, Jelena Z., Antonijevic, Milan D., Matović, Branko, Bojić, Danijela V., Bojić, Aleksandar Lj., "Synthesis and characterization of new Ti-Bi2O3 anode and its use for reactive dye degradation" in Materials Chemistry and Physics, 158 (2015):31-37,
https://doi.org/10.1016/j.matchemphys.2015.03.030 . .