Stoiljković, Milovan

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Authority KeyName Variants
orcid::0000-0002-2794-3231
  • Stoiljković, Milovan (109)
Projects
Effects of laser radiation and plasma on novel materials in their synthesis, modification, and analysis Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion
Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine Spektroskopska i laserska istraživanja površina, plazme i životne sredine
Functional, Functionalized and Advanced Nanomaterials Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200040 (Maize Research Institute 'Zemun Polje', Belgrade-Zemun)
Application of biotechnological methods for sustainable exploitation of by-products of agro-industry COST Action [FA 0905]
Mechanistic studies of the reactions of transition metal ion complexes with biologically relevant molecules Electroconducting and redox-active polymers and oligomers: synthesis, structure, properties and applications
Physics and Chemistry with Ion Beams Nanostructured multifunctional materials and nanocomposites
Integrated field crop production: conservation of biodiversity and soil fertility Improvment of maize and soybean traits by molecular and conventional breeding
Ministry of Education, Science and Technological Development of the Republic of Serbia [1995]
Bilateral project between the Republic of Slovenia and the Republic of Serbia (No. 44) COST Action [CA20130]
COST action (Developing the Physics and the Scientific Community for Inertial Confinement Fusion at the Time of NIF Ignition) [MP1208] COST Action Developing the Physics and the Scientific Community for Inertial Confinement Fusion at the Time of NIF ignition [MP1208]
COST Action [MP1106] EPSCoR of the United States (Award IIA-1355423)
European Scientific Foundation European Union's Horizon Europe [101059942 CREDIT Vibes]
Impact of agents with potential use in functional foods on biomarkers for induction of age related diseases Micromechanical criteria of damage and fracture
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200043 (Institute of Oncology and Radiology of Serbia, Belgrade) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200052 (Mining and Metallurgy Institute, Bor)

Author's Bibliography

Densification of additive-free B4C-SiC composites by spark plasma sintering

Matović, Branko; Tatarko, Peter; Maksimović, Vesna; Maletaškić, Jelena; Stoiljković, Milovan; Hanzel, Ondrej; Cvijović-Alagić, Ivana

(2023)

TY  - JOUR
AU  - Matović, Branko
AU  - Tatarko, Peter
AU  - Maksimović, Vesna
AU  - Maletaškić, Jelena
AU  - Stoiljković, Milovan
AU  - Hanzel, Ondrej
AU  - Cvijović-Alagić, Ivana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12284
AB  - The B4C-SiC composites were obtained through densification of B4C and β-SiC powders with different ratios using Spark Plasma Sintering (SPS). Thermal treatment was conducted in the 1850–2000 °C temperature range under pressure of 70 MPa. Starting powder ratio effect on sintering behavior, relative density, microstructural development, and mechanical properties of obtained composites was investigated. Results showed that only starting compounds were observed in sintered ceramics with uniformly distributed and densely compacted B4C and SiC grains. Maximal relative density (100 %) was achieved for 25 % B4C-75 % SiC sample densified at 2000 °C. Obtained composites' microhardness ranged from 33 to 43 GPa, depending on constituents' content and densification temperature. Maximal microhardness was achieved for composite with the maximal amount (75 %) of B4C densified at 2000 °C. Composites' behavior in extreme conditions was evaluated through their interactions with laser beam and obtained results showed that SPS is effective densification method for obtainment of additive-free B4C-SiC composites applicable in extreme radiation environments.
T2  - Journal of the European Ceramic Society
T1  - Densification of additive-free B4C-SiC composites by spark plasma sintering
IS  - InPress
DO  - 10.1016/j.jeurceramsoc.2023.12.024
ER  - 
@article{
author = "Matović, Branko and Tatarko, Peter and Maksimović, Vesna and Maletaškić, Jelena and Stoiljković, Milovan and Hanzel, Ondrej and Cvijović-Alagić, Ivana",
year = "2023",
abstract = "The B4C-SiC composites were obtained through densification of B4C and β-SiC powders with different ratios using Spark Plasma Sintering (SPS). Thermal treatment was conducted in the 1850–2000 °C temperature range under pressure of 70 MPa. Starting powder ratio effect on sintering behavior, relative density, microstructural development, and mechanical properties of obtained composites was investigated. Results showed that only starting compounds were observed in sintered ceramics with uniformly distributed and densely compacted B4C and SiC grains. Maximal relative density (100 %) was achieved for 25 % B4C-75 % SiC sample densified at 2000 °C. Obtained composites' microhardness ranged from 33 to 43 GPa, depending on constituents' content and densification temperature. Maximal microhardness was achieved for composite with the maximal amount (75 %) of B4C densified at 2000 °C. Composites' behavior in extreme conditions was evaluated through their interactions with laser beam and obtained results showed that SPS is effective densification method for obtainment of additive-free B4C-SiC composites applicable in extreme radiation environments.",
journal = "Journal of the European Ceramic Society",
title = "Densification of additive-free B4C-SiC composites by spark plasma sintering",
number = "InPress",
doi = "10.1016/j.jeurceramsoc.2023.12.024"
}
Matović, B., Tatarko, P., Maksimović, V., Maletaškić, J., Stoiljković, M., Hanzel, O.,& Cvijović-Alagić, I.. (2023). Densification of additive-free B4C-SiC composites by spark plasma sintering. in Journal of the European Ceramic Society(InPress).
https://doi.org/10.1016/j.jeurceramsoc.2023.12.024
Matović B, Tatarko P, Maksimović V, Maletaškić J, Stoiljković M, Hanzel O, Cvijović-Alagić I. Densification of additive-free B4C-SiC composites by spark plasma sintering. in Journal of the European Ceramic Society. 2023;(InPress).
doi:10.1016/j.jeurceramsoc.2023.12.024 .
Matović, Branko, Tatarko, Peter, Maksimović, Vesna, Maletaškić, Jelena, Stoiljković, Milovan, Hanzel, Ondrej, Cvijović-Alagić, Ivana, "Densification of additive-free B4C-SiC composites by spark plasma sintering" in Journal of the European Ceramic Society, no. InPress (2023),
https://doi.org/10.1016/j.jeurceramsoc.2023.12.024 . .
1

Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles

Zarubica, Aleksandra; Sredojević, Dušan; Ljupković, Radomir; Ranđelović, Marjan; Murafa, Natalija; Stoiljković, Milovan; Lazić, Vesna; Nedeljković, Jovan

(2023)

TY  - JOUR
AU  - Zarubica, Aleksandra
AU  - Sredojević, Dušan
AU  - Ljupković, Radomir
AU  - Ranđelović, Marjan
AU  - Murafa, Natalija
AU  - Stoiljković, Milovan
AU  - Lazić, Vesna
AU  - Nedeljković, Jovan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10874
AB  - The interfacial charge transfer (ICT) complex formation between zirconium dioxide (ZrO2), the material absorbing below 250 nm, and 5-aminosalicylic acid (5-ASA) leads to the formation of visible-light-absorbing inorganic–organic hybrids. The free amino groups, present on the hybrid's surface after the ICT complex formation, were used to reduce silver ions and link silver particles to ZrO2. The prepared samples were characterized by using transmission electron microscopy, X-ray diffraction analysis, and nitrogen adsorption–desorption isotherms. Density functional theory (DFT) calculations using a cluster model are applied to explain optical changes in hybrids, i.e., absorption redshift induced by the ICT complex formation. Decolorization of an organic dye crystal violet (CV), under ultraviolet-C or visible light, was used to compare the photocatalytic ability of the prepared samples. The ICT complex formation transformed ZrO2 into a hybrid material able to induce photocatalytic reactions under exclusive visible light excitation.
T2  - Sustainable Energy and Fuels
T1  - Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles
VL  - 7
IS  - 9
SP  - 2279
EP  - 2287
DO  - 10.1039/D3SE00175J
ER  - 
@article{
author = "Zarubica, Aleksandra and Sredojević, Dušan and Ljupković, Radomir and Ranđelović, Marjan and Murafa, Natalija and Stoiljković, Milovan and Lazić, Vesna and Nedeljković, Jovan",
year = "2023",
abstract = "The interfacial charge transfer (ICT) complex formation between zirconium dioxide (ZrO2), the material absorbing below 250 nm, and 5-aminosalicylic acid (5-ASA) leads to the formation of visible-light-absorbing inorganic–organic hybrids. The free amino groups, present on the hybrid's surface after the ICT complex formation, were used to reduce silver ions and link silver particles to ZrO2. The prepared samples were characterized by using transmission electron microscopy, X-ray diffraction analysis, and nitrogen adsorption–desorption isotherms. Density functional theory (DFT) calculations using a cluster model are applied to explain optical changes in hybrids, i.e., absorption redshift induced by the ICT complex formation. Decolorization of an organic dye crystal violet (CV), under ultraviolet-C or visible light, was used to compare the photocatalytic ability of the prepared samples. The ICT complex formation transformed ZrO2 into a hybrid material able to induce photocatalytic reactions under exclusive visible light excitation.",
journal = "Sustainable Energy and Fuels",
title = "Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles",
volume = "7",
number = "9",
pages = "2279-2287",
doi = "10.1039/D3SE00175J"
}
Zarubica, A., Sredojević, D., Ljupković, R., Ranđelović, M., Murafa, N., Stoiljković, M., Lazić, V.,& Nedeljković, J.. (2023). Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles. in Sustainable Energy and Fuels, 7(9), 2279-2287.
https://doi.org/10.1039/D3SE00175J
Zarubica A, Sredojević D, Ljupković R, Ranđelović M, Murafa N, Stoiljković M, Lazić V, Nedeljković J. Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles. in Sustainable Energy and Fuels. 2023;7(9):2279-2287.
doi:10.1039/D3SE00175J .
Zarubica, Aleksandra, Sredojević, Dušan, Ljupković, Radomir, Ranđelović, Marjan, Murafa, Natalija, Stoiljković, Milovan, Lazić, Vesna, Nedeljković, Jovan, "Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles" in Sustainable Energy and Fuels, 7, no. 9 (2023):2279-2287,
https://doi.org/10.1039/D3SE00175J . .
1
1

Anticancer effect of novel luteolin capped gold nanoparticles selectively cytotoxic towards human cervical adenocarcinoma HeLa cells: An in vitro approach

Matić, Ivana Z.; Mraković, Ana; Rakočević, Zlatko; Stoiljković, Milovan; Pavlović, Vladimir B.; Momić, Tatjana

(2023)

TY  - JOUR
AU  - Matić, Ivana Z.
AU  - Mraković, Ana
AU  - Rakočević, Zlatko
AU  - Stoiljković, Milovan
AU  - Pavlović, Vladimir B.
AU  - Momić, Tatjana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11544
AB  - Background: Although luteolin has been confirmed as potent anticancer agent, its potential application as therapeutic is limited by its water solubility. To overcome this shortcoming nanoparticle technology approach was applied. Owing to their proven low toxicity and the possibility to be easily functionalized gold nanoparticles (AuNP) were the nanosystem of choice used in this study. Novel luteolin capped gold nanoparticles (AuNPL) were synthesized and their anticancer effect towards human cervical adenocarcinoma HeLa cells was investigated in vitro. Methods: AuNPL were synthesized by reducing chloroauric acid by trisodium citrate with subsequent addition of luteoline during synthesis and their physicochemical characterization was done. AuNPL cytotoxicity against HeLa, human malignant melanoma A375, and normal human keratinocytes HaCaT cells was tested by MTT cell survival assay, and their IC50 values were determined. The capability of AuNPL to induce cell cycle arrest and apoptosis in HeLa cells were demonstrated by flow cytometry. The antioxidant activity of AuNPL was assessed by DPPH⋅ and ABTS⋅þ scavenging assays. Cytoprotective properties of AuNPL towards HaCaT cells were examined by measuring the physiological and H2O2 induced intracellular reactive oxygen species (ROS) levels using flow cytometry. Also, genotoxicity of AuNPL in HaCaT cells was investigated by the single cell alkaline comet assay. Results: Spherical AuNPL, stable in aqueous solution up to six months at 4 ◦C were obtained in the synthesis. The selectivity in the cytotoxic action of AuNPL on HeLa and A375 cancer cells compared with their cytotoxicity on normal keratinocytes HaCaT was observed. AuNPL exerted their cytotoxic activity against HeLa cells through accumulation of the cells in the subG1 phase of the cell cycle, inducing the apoptotic cell death mediated by the activation of caspase-3 − 8, and − 9. AuNPL antioxidative potential was confirmed by DPPH⋅ and ABTS⋅þ scavenging assays. IC50 concentration of AuNPL exerted cytoprotective effect against HaCaT cells by the significant reduction of the physiological intracellular ROS level. Additionally, AuNPL were shown as more cytoprotective towards HaCaT cells then luteolin due to the more successful elimination of H2O2 induced intracellular ROS. Moreover, nontoxic concentrations of AuNPL did not cause considerable DNA damage of HaCaT cells, indicating low genotoxicity of the nanoparticles.
T2  - Journal of Trace Elements in Medicine and Biology
T1  - Anticancer effect of novel luteolin capped gold nanoparticles selectively cytotoxic towards human cervical adenocarcinoma HeLa cells: An in vitro approach
VL  - 80
SP  - 127286
DO  - 10.1016/j.jtemb.2023.127286
ER  - 
@article{
author = "Matić, Ivana Z. and Mraković, Ana and Rakočević, Zlatko and Stoiljković, Milovan and Pavlović, Vladimir B. and Momić, Tatjana",
year = "2023",
abstract = "Background: Although luteolin has been confirmed as potent anticancer agent, its potential application as therapeutic is limited by its water solubility. To overcome this shortcoming nanoparticle technology approach was applied. Owing to their proven low toxicity and the possibility to be easily functionalized gold nanoparticles (AuNP) were the nanosystem of choice used in this study. Novel luteolin capped gold nanoparticles (AuNPL) were synthesized and their anticancer effect towards human cervical adenocarcinoma HeLa cells was investigated in vitro. Methods: AuNPL were synthesized by reducing chloroauric acid by trisodium citrate with subsequent addition of luteoline during synthesis and their physicochemical characterization was done. AuNPL cytotoxicity against HeLa, human malignant melanoma A375, and normal human keratinocytes HaCaT cells was tested by MTT cell survival assay, and their IC50 values were determined. The capability of AuNPL to induce cell cycle arrest and apoptosis in HeLa cells were demonstrated by flow cytometry. The antioxidant activity of AuNPL was assessed by DPPH⋅ and ABTS⋅þ scavenging assays. Cytoprotective properties of AuNPL towards HaCaT cells were examined by measuring the physiological and H2O2 induced intracellular reactive oxygen species (ROS) levels using flow cytometry. Also, genotoxicity of AuNPL in HaCaT cells was investigated by the single cell alkaline comet assay. Results: Spherical AuNPL, stable in aqueous solution up to six months at 4 ◦C were obtained in the synthesis. The selectivity in the cytotoxic action of AuNPL on HeLa and A375 cancer cells compared with their cytotoxicity on normal keratinocytes HaCaT was observed. AuNPL exerted their cytotoxic activity against HeLa cells through accumulation of the cells in the subG1 phase of the cell cycle, inducing the apoptotic cell death mediated by the activation of caspase-3 − 8, and − 9. AuNPL antioxidative potential was confirmed by DPPH⋅ and ABTS⋅þ scavenging assays. IC50 concentration of AuNPL exerted cytoprotective effect against HaCaT cells by the significant reduction of the physiological intracellular ROS level. Additionally, AuNPL were shown as more cytoprotective towards HaCaT cells then luteolin due to the more successful elimination of H2O2 induced intracellular ROS. Moreover, nontoxic concentrations of AuNPL did not cause considerable DNA damage of HaCaT cells, indicating low genotoxicity of the nanoparticles.",
journal = "Journal of Trace Elements in Medicine and Biology",
title = "Anticancer effect of novel luteolin capped gold nanoparticles selectively cytotoxic towards human cervical adenocarcinoma HeLa cells: An in vitro approach",
volume = "80",
pages = "127286",
doi = "10.1016/j.jtemb.2023.127286"
}
Matić, I. Z., Mraković, A., Rakočević, Z., Stoiljković, M., Pavlović, V. B.,& Momić, T.. (2023). Anticancer effect of novel luteolin capped gold nanoparticles selectively cytotoxic towards human cervical adenocarcinoma HeLa cells: An in vitro approach. in Journal of Trace Elements in Medicine and Biology, 80, 127286.
https://doi.org/10.1016/j.jtemb.2023.127286
Matić IZ, Mraković A, Rakočević Z, Stoiljković M, Pavlović VB, Momić T. Anticancer effect of novel luteolin capped gold nanoparticles selectively cytotoxic towards human cervical adenocarcinoma HeLa cells: An in vitro approach. in Journal of Trace Elements in Medicine and Biology. 2023;80:127286.
doi:10.1016/j.jtemb.2023.127286 .
Matić, Ivana Z., Mraković, Ana, Rakočević, Zlatko, Stoiljković, Milovan, Pavlović, Vladimir B., Momić, Tatjana, "Anticancer effect of novel luteolin capped gold nanoparticles selectively cytotoxic towards human cervical adenocarcinoma HeLa cells: An in vitro approach" in Journal of Trace Elements in Medicine and Biology, 80 (2023):127286,
https://doi.org/10.1016/j.jtemb.2023.127286 . .
1

Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system

Veljković, Filip M.; Dimitrijević, Stevan P.; Dimitrijević, Silvana B.; Vurdelja, Borislava D.; Matović, Branko; Stoiljković, Milovan; Kamberović, Željko; Veličković, Suzana

(2023)

TY  - JOUR
AU  - Veljković, Filip M.
AU  - Dimitrijević, Stevan P.
AU  - Dimitrijević, Silvana B.
AU  - Vurdelja, Borislava D.
AU  - Matović, Branko
AU  - Stoiljković, Milovan
AU  - Kamberović, Željko
AU  - Veličković, Suzana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10589
AB  - This work presents the perspective of applying the laser desorption/ionization mass spectrometry (LDI MS) for characterization the anode film of the Ag60Cu26Zn14, Ag58.5Cu31.5Pd10, and Ag63Cu27In10 alloys (at high concentrations of chloride ions in solutions). The reference LDI mass spectra of anode films of pure Ag and Cu have been used for the identification of product corrosion. Knowing the clusters detected in the reference spectra lead to the facilitating identification of the LDI mass spectrum of the sample and reduces the analysis time. The LDI MS analysis of these alloys revealed that the predominant corrosion product are AgCl (from AgnCln+1−/+, n = 1–3), and CuCl (from “superhalogen” CumCln− clusters, m = 1–2, n = 2–6); it also revealed Cu2(OH)3Cl (from Cu2(OH)(H2O)2+) and Cu2O (from Cu(H2O)+, Cu2O doped with chlorine). These results are in accordance with the X-ray diffraction and Raman analysis. The LDI MS spectra of alloys contain the additional peaks formed due to the mutual influences of different metals in the alloys (AgCuCl3− (AgCl-CuCl2−), AgCu2Cl4− (AgCl-CuCl-CuCl2−), and Ag2CuCl4− (AgCl-AgCl-CuCl−), which is consistent with the identified corrosion products. It should be noted that the LDI MS suggest the presence of CuCl2, which can be interpreted as the corrosion products retained in the porous films of alloys, and not detected by the other methods due to a small amount. The future theoretical and experimental studies of metal clusters, significant for metallurgy, can contribute that the LDI MS is becoming a powerful analytical tool for characterization the metal surfaces.
T2  - Arabian Journal of Chemistry
T1  - Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system
VL  - 16
IS  - 2
SP  - 104461
DO  - 10.1016/j.arabjc.2022.104461
ER  - 
@article{
author = "Veljković, Filip M. and Dimitrijević, Stevan P. and Dimitrijević, Silvana B. and Vurdelja, Borislava D. and Matović, Branko and Stoiljković, Milovan and Kamberović, Željko and Veličković, Suzana",
year = "2023",
abstract = "This work presents the perspective of applying the laser desorption/ionization mass spectrometry (LDI MS) for characterization the anode film of the Ag60Cu26Zn14, Ag58.5Cu31.5Pd10, and Ag63Cu27In10 alloys (at high concentrations of chloride ions in solutions). The reference LDI mass spectra of anode films of pure Ag and Cu have been used for the identification of product corrosion. Knowing the clusters detected in the reference spectra lead to the facilitating identification of the LDI mass spectrum of the sample and reduces the analysis time. The LDI MS analysis of these alloys revealed that the predominant corrosion product are AgCl (from AgnCln+1−/+, n = 1–3), and CuCl (from “superhalogen” CumCln− clusters, m = 1–2, n = 2–6); it also revealed Cu2(OH)3Cl (from Cu2(OH)(H2O)2+) and Cu2O (from Cu(H2O)+, Cu2O doped with chlorine). These results are in accordance with the X-ray diffraction and Raman analysis. The LDI MS spectra of alloys contain the additional peaks formed due to the mutual influences of different metals in the alloys (AgCuCl3− (AgCl-CuCl2−), AgCu2Cl4− (AgCl-CuCl-CuCl2−), and Ag2CuCl4− (AgCl-AgCl-CuCl−), which is consistent with the identified corrosion products. It should be noted that the LDI MS suggest the presence of CuCl2, which can be interpreted as the corrosion products retained in the porous films of alloys, and not detected by the other methods due to a small amount. The future theoretical and experimental studies of metal clusters, significant for metallurgy, can contribute that the LDI MS is becoming a powerful analytical tool for characterization the metal surfaces.",
journal = "Arabian Journal of Chemistry",
title = "Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system",
volume = "16",
number = "2",
pages = "104461",
doi = "10.1016/j.arabjc.2022.104461"
}
Veljković, F. M., Dimitrijević, S. P., Dimitrijević, S. B., Vurdelja, B. D., Matović, B., Stoiljković, M., Kamberović, Ž.,& Veličković, S.. (2023). Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system. in Arabian Journal of Chemistry, 16(2), 104461.
https://doi.org/10.1016/j.arabjc.2022.104461
Veljković FM, Dimitrijević SP, Dimitrijević SB, Vurdelja BD, Matović B, Stoiljković M, Kamberović Ž, Veličković S. Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system. in Arabian Journal of Chemistry. 2023;16(2):104461.
doi:10.1016/j.arabjc.2022.104461 .
Veljković, Filip M., Dimitrijević, Stevan P., Dimitrijević, Silvana B., Vurdelja, Borislava D., Matović, Branko, Stoiljković, Milovan, Kamberović, Željko, Veličković, Suzana, "Prospective of the LDI MS to characterization the corrosion products of silver-copper alloys on an example of the Ag-Cu-X (X- Zn, Pd, In) system" in Arabian Journal of Chemistry, 16, no. 2 (2023):104461,
https://doi.org/10.1016/j.arabjc.2022.104461 . .
1

Corrosion of Ceramic-Metal Composites in Artificial Acid Rain

Stoiljković, Milovan; Pavkov, Vladimir; Bakić, Gordana; Luković, Aleksa; Maksimović, Vesna

(Belgrade : Association of Metallurgical Engineers of Serbia (AMES), 2023)

TY  - CONF
AU  - Stoiljković, Milovan
AU  - Pavkov, Vladimir
AU  - Bakić, Gordana
AU  - Luković, Aleksa
AU  - Maksimović, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11563
AB  - In this work, the basalt deposits site from southern Serbia was used as a matrix for the composite materials. The corrosion behavior of basalt matrix composites with various ratios of commercial stainless steel 316L (5, 10, 15, and 20 wt.%) and bulk basalt produced by sintering in the air (t=1060ºC and τ=60 min) were studied by immersion corrosion technique. The samples were immersed in a solution of artificial acid rain H2SO4:HNO3 = 9:1 at ≈ pH 3 to measure the concentration of released metal ions using inductively coupled plasma-optical emission spectrometry (ICP-OES). The elements Fe, Cr, Mn, and Ni were monitored, while the others were below the limit of quantification. The concentrations of the metal ions in the solution were studied over 15 weeks. The ions release rate from all the sintered samples was found to follow the Weibull cumulative distribution function (CDF). This means that the release rate changes over time and allows us to calculate the characteristic times of ion release. The changes in the samples were monitored by light microscopy (LM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and weight loss. Sintered basalt shows high resistance to corrosion with a characteristic time of about 18 years for Fe and more than 25 years for Cr and Mn. The weight difference between the initial and after 15 weeks of exposure to the solution (sintered basalt) was not observed. On the other hand, the presence of 5 wt.% steel powder in the sintered basalt accelerates the release of metal ions by about six times. When the steel powder content in the composite materials increases, the metal release rate does not change further, but a weight loss is observed. The characteristic times for Fe, Cr, Ni, and Mn in composite materials are about 5 years. These composite materials can be investigated as materials for using in an acid environment.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia (AMES)
C3  - MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina
T1  - Corrosion of Ceramic-Metal Composites in Artificial Acid Rain
SP  - 73
EP  - 73
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11563
ER  - 
@conference{
author = "Stoiljković, Milovan and Pavkov, Vladimir and Bakić, Gordana and Luković, Aleksa and Maksimović, Vesna",
year = "2023",
abstract = "In this work, the basalt deposits site from southern Serbia was used as a matrix for the composite materials. The corrosion behavior of basalt matrix composites with various ratios of commercial stainless steel 316L (5, 10, 15, and 20 wt.%) and bulk basalt produced by sintering in the air (t=1060ºC and τ=60 min) were studied by immersion corrosion technique. The samples were immersed in a solution of artificial acid rain H2SO4:HNO3 = 9:1 at ≈ pH 3 to measure the concentration of released metal ions using inductively coupled plasma-optical emission spectrometry (ICP-OES). The elements Fe, Cr, Mn, and Ni were monitored, while the others were below the limit of quantification. The concentrations of the metal ions in the solution were studied over 15 weeks. The ions release rate from all the sintered samples was found to follow the Weibull cumulative distribution function (CDF). This means that the release rate changes over time and allows us to calculate the characteristic times of ion release. The changes in the samples were monitored by light microscopy (LM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and weight loss. Sintered basalt shows high resistance to corrosion with a characteristic time of about 18 years for Fe and more than 25 years for Cr and Mn. The weight difference between the initial and after 15 weeks of exposure to the solution (sintered basalt) was not observed. On the other hand, the presence of 5 wt.% steel powder in the sintered basalt accelerates the release of metal ions by about six times. When the steel powder content in the composite materials increases, the metal release rate does not change further, but a weight loss is observed. The characteristic times for Fe, Cr, Ni, and Mn in composite materials are about 5 years. These composite materials can be investigated as materials for using in an acid environment.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia (AMES)",
journal = "MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina",
title = "Corrosion of Ceramic-Metal Composites in Artificial Acid Rain",
pages = "73-73",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11563"
}
Stoiljković, M., Pavkov, V., Bakić, G., Luković, A.,& Maksimović, V.. (2023). Corrosion of Ceramic-Metal Composites in Artificial Acid Rain. in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina
Belgrade : Association of Metallurgical Engineers of Serbia (AMES)., 73-73.
https://hdl.handle.net/21.15107/rcub_vinar_11563
Stoiljković M, Pavkov V, Bakić G, Luković A, Maksimović V. Corrosion of Ceramic-Metal Composites in Artificial Acid Rain. in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina. 2023;:73-73.
https://hdl.handle.net/21.15107/rcub_vinar_11563 .
Stoiljković, Milovan, Pavkov, Vladimir, Bakić, Gordana, Luković, Aleksa, Maksimović, Vesna, "Corrosion of Ceramic-Metal Composites in Artificial Acid Rain" in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina (2023):73-73,
https://hdl.handle.net/21.15107/rcub_vinar_11563 .

Effect of acidic environment on glass-ceramic-metal composite materials

Maksimović, Vesna; Pavkov, Vladimir; Stoiljković, Milovan; Luković, A.; Bakić, G.

(Slovak Republic : Institute of Inorganic Chemistry, SAS, 2023)

TY  - CONF
AU  - Maksimović, Vesna
AU  - Pavkov, Vladimir
AU  - Stoiljković, Milovan
AU  - Luković, A.
AU  - Bakić, G.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11628
AB  - Ceramic materials are often used in very aggressive and corrosive environments due to their high chemical inertness and corrosion resistance. However, even if corrosion progresses slowly, it still occurs. Corrosion usually depends on the structural properties of the materials. For example, more compact or tightly bonded materials corrode less, whether glass or crystalline materials. With the dramatic increase in nitrogen and sulphide oxide emissions, acid rain pollution has become one of the world's biggest environmental problems. One of the methods used to measure the corrosion resistance of ceramic materials and ceramic matrix composites (CMCs) is the immersion method, which studies their behaviour by immersing them in corrosive media and measuring the concentration of ions released. Adding different particles to basalt before sintering to obtain CMCs can increase fracture toughness. The aim of this work was to investigate the effects of the content of 316L stainless steel powder in sintered basalt on its structural properties and resistance to the release of metal ions in acidic environments. The andesite-basalt-based samples were prepared by adding 5, 10, 15, and 20 wt.% of steel powder, respectively, before sintering. The basalt aggregate and the pure sintered basalt served as reference materials. The metal concentrations in the solution were studied for 15 weeks at room temperature and a pH of 3.13±0.01. The major elements Fe, Cr, Mn, and Ni were monitored, while the others were below the limit of quantification. We found that the concentration of metal ions released from the basalt aggregate increases exponentially, implying that the release rate is constant over time. However, the concentration of metal ions released from the sintered samples follows the Weibull cumulative distribution function (CDF), which means that the release rate changes over time and allows us to calculate the characteristic times of ion release. The presence of 5 wt.% steel powder in the sintered basalt accelerates the release of metal ions by about six times. If the steel powder content increases, the metal release rate does not change further. These findings are positive since the highest toughness of sintered basalt is expressed at 20 wt.% of steel powder. The corrosion stability of glass-ceramic-metal-based composites was found to be satisfactory compared to natural andesite-basalt aggregate. These composites can be used in conditions of acid rain exposure where higher fracture toughness is required.
PB  - Slovak Republic : Institute of Inorganic Chemistry, SAS
C3  - EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics
T1  - Effect of acidic environment on glass-ceramic-metal composite materials
SP  - 35
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11628
ER  - 
@conference{
author = "Maksimović, Vesna and Pavkov, Vladimir and Stoiljković, Milovan and Luković, A. and Bakić, G.",
year = "2023",
abstract = "Ceramic materials are often used in very aggressive and corrosive environments due to their high chemical inertness and corrosion resistance. However, even if corrosion progresses slowly, it still occurs. Corrosion usually depends on the structural properties of the materials. For example, more compact or tightly bonded materials corrode less, whether glass or crystalline materials. With the dramatic increase in nitrogen and sulphide oxide emissions, acid rain pollution has become one of the world's biggest environmental problems. One of the methods used to measure the corrosion resistance of ceramic materials and ceramic matrix composites (CMCs) is the immersion method, which studies their behaviour by immersing them in corrosive media and measuring the concentration of ions released. Adding different particles to basalt before sintering to obtain CMCs can increase fracture toughness. The aim of this work was to investigate the effects of the content of 316L stainless steel powder in sintered basalt on its structural properties and resistance to the release of metal ions in acidic environments. The andesite-basalt-based samples were prepared by adding 5, 10, 15, and 20 wt.% of steel powder, respectively, before sintering. The basalt aggregate and the pure sintered basalt served as reference materials. The metal concentrations in the solution were studied for 15 weeks at room temperature and a pH of 3.13±0.01. The major elements Fe, Cr, Mn, and Ni were monitored, while the others were below the limit of quantification. We found that the concentration of metal ions released from the basalt aggregate increases exponentially, implying that the release rate is constant over time. However, the concentration of metal ions released from the sintered samples follows the Weibull cumulative distribution function (CDF), which means that the release rate changes over time and allows us to calculate the characteristic times of ion release. The presence of 5 wt.% steel powder in the sintered basalt accelerates the release of metal ions by about six times. If the steel powder content increases, the metal release rate does not change further. These findings are positive since the highest toughness of sintered basalt is expressed at 20 wt.% of steel powder. The corrosion stability of glass-ceramic-metal-based composites was found to be satisfactory compared to natural andesite-basalt aggregate. These composites can be used in conditions of acid rain exposure where higher fracture toughness is required.",
publisher = "Slovak Republic : Institute of Inorganic Chemistry, SAS",
journal = "EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics",
title = "Effect of acidic environment on glass-ceramic-metal composite materials",
pages = "35",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11628"
}
Maksimović, V., Pavkov, V., Stoiljković, M., Luković, A.,& Bakić, G.. (2023). Effect of acidic environment on glass-ceramic-metal composite materials. in EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics
Slovak Republic : Institute of Inorganic Chemistry, SAS., 35.
https://hdl.handle.net/21.15107/rcub_vinar_11628
Maksimović V, Pavkov V, Stoiljković M, Luković A, Bakić G. Effect of acidic environment on glass-ceramic-metal composite materials. in EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics. 2023;:35.
https://hdl.handle.net/21.15107/rcub_vinar_11628 .
Maksimović, Vesna, Pavkov, Vladimir, Stoiljković, Milovan, Luković, A., Bakić, G., "Effect of acidic environment on glass-ceramic-metal composite materials" in EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics (2023):35,
https://hdl.handle.net/21.15107/rcub_vinar_11628 .

Ispitivanje LIF/B sistema korišćenjem negativnog moda LDI MS: mogući sistem za skladištenje vodonika

Veljković, Filip; Janković, Bojan; Stajčić, Ivana; Stoiljković, Milovan; Janković, Marija; Kapuran, Đorđe; Veličković, Suzana

(Beograd : Savez mašinskih i elektrotehničk ihinženjera i tehničara Srbije (SMEITS) : Društvo za obnovljive izvore električne energije, 2023)

TY  - CONF
AU  - Veljković, Filip
AU  - Janković, Bojan
AU  - Stajčić, Ivana
AU  - Stoiljković, Milovan
AU  - Janković, Marija
AU  - Kapuran, Đorđe
AU  - Veličković, Suzana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12570
AB  - Mnogi teorijski proračuni su pokazali da su litijumom dekorisni borani (BxHy) ili klasteri bora (Bn) potencijalni materijali za skladištenje vodonika. Pored toga, pokazalo se da klasteri litijumfluorida poboljšavaju kapacitet skladištenja vodonika bolje od samog litijuma. Međutim, broj eksperimentalnih studija je mnogo manji. Zbog toga je u ovom radu ispitivana mogućnost interakcije klastera litijuma ili litijumfluorida sa boranima, metodom laserske desorpcione/jonizacione masenespektrometrije (LDI MS). Preliminarni rezultati su pokazali da negativni mod LDI maseni spektri suspenzije LiF/B (1:3) u dejonizovanoj vodi sadrži Li2(BH18) - , LiF2(BH3) - , LiB2(BH3)2 - , LiF2LiB(BH4)2 - jone. Smanjenje sadržaja bora u LiF/B sistemu (1:1) rezultira malo izmenjenim masenim spektrom. Intenzitet Li2(BH18) - i LiF2(BH3) - opada, dok druga dva jona pokazuju blago izmenjen sastav: Li2F(B3H2) - i LiF2(BH5)3 - . Rezultati pokazuju da klasteri Li2 i “superhalogen” LiF2 mogu da interaguju sa boranima. U oba slučaja, najintenzivniji joni su bili kompleksi između „superhalogena“-LiF2 i borana.
AB  - Many theoretical calculations have shown that lithium decoration of borane (BxHy) or boron (Bn) clusters are potential materials for hydrogen storage. In addition, lithium fluoride clusters have been shown to improve hydrogen storage capacity better than lithium itself. However, the number of experimental studies is much smaller. Therefore, in this work, the possibility of interaction of lithium or lithium fluoride clusters with boranes was investigated by laser desorption/ionization mass spectrometry (LDI MS). The preliminary results have shown that the negative mode LDI mass spectra of the suspension of LiF/B (1:3) in deionized water include Li2(BH18) - , LiF2(BH3) - , LiB2(BH3)2 -  LiF2LiB(BH4)2 -  ions. The reducing the boron content in the LiF/B system (1:1) results in a little changed mass spectrum. The intensities of Li2(BH18) -  and LiF2(BH3) -  decrease, while two other ions show a slightly changed composition: Li2F(B3H2) -  and LiF2(BH5)3 - . The results show that the Li2 and “superhalogen” LiF2 clusters can interact with boranes. In both cases, the most intense ions were complexes between “superhalogen”-LiF2 and boranes.
PB  - Beograd : Savez mašinskih i elektrotehničk ihinženjera i tehničara Srbije (SMEITS) : Društvo za obnovljive izvore električne energije
C3  - 11th International Conference on Renewable Electrical Power Sources : Proceedings
T1  - Ispitivanje LIF/B sistema korišćenjem negativnog moda LDI MS: mogući sistem za skladištenje vodonika
T1  - Investigation of LIF/B system using the negative mode LDI MS: a possible hydrogen storage system
SP  - 115
EP  - 118
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12570
ER  - 
@conference{
author = "Veljković, Filip and Janković, Bojan and Stajčić, Ivana and Stoiljković, Milovan and Janković, Marija and Kapuran, Đorđe and Veličković, Suzana",
year = "2023",
abstract = "Mnogi teorijski proračuni su pokazali da su litijumom dekorisni borani (BxHy) ili klasteri bora (Bn) potencijalni materijali za skladištenje vodonika. Pored toga, pokazalo se da klasteri litijumfluorida poboljšavaju kapacitet skladištenja vodonika bolje od samog litijuma. Međutim, broj eksperimentalnih studija je mnogo manji. Zbog toga je u ovom radu ispitivana mogućnost interakcije klastera litijuma ili litijumfluorida sa boranima, metodom laserske desorpcione/jonizacione masenespektrometrije (LDI MS). Preliminarni rezultati su pokazali da negativni mod LDI maseni spektri suspenzije LiF/B (1:3) u dejonizovanoj vodi sadrži Li2(BH18) - , LiF2(BH3) - , LiB2(BH3)2 - , LiF2LiB(BH4)2 - jone. Smanjenje sadržaja bora u LiF/B sistemu (1:1) rezultira malo izmenjenim masenim spektrom. Intenzitet Li2(BH18) - i LiF2(BH3) - opada, dok druga dva jona pokazuju blago izmenjen sastav: Li2F(B3H2) - i LiF2(BH5)3 - . Rezultati pokazuju da klasteri Li2 i “superhalogen” LiF2 mogu da interaguju sa boranima. U oba slučaja, najintenzivniji joni su bili kompleksi između „superhalogena“-LiF2 i borana., Many theoretical calculations have shown that lithium decoration of borane (BxHy) or boron (Bn) clusters are potential materials for hydrogen storage. In addition, lithium fluoride clusters have been shown to improve hydrogen storage capacity better than lithium itself. However, the number of experimental studies is much smaller. Therefore, in this work, the possibility of interaction of lithium or lithium fluoride clusters with boranes was investigated by laser desorption/ionization mass spectrometry (LDI MS). The preliminary results have shown that the negative mode LDI mass spectra of the suspension of LiF/B (1:3) in deionized water include Li2(BH18) - , LiF2(BH3) - , LiB2(BH3)2 -  LiF2LiB(BH4)2 -  ions. The reducing the boron content in the LiF/B system (1:1) results in a little changed mass spectrum. The intensities of Li2(BH18) -  and LiF2(BH3) -  decrease, while two other ions show a slightly changed composition: Li2F(B3H2) -  and LiF2(BH5)3 - . The results show that the Li2 and “superhalogen” LiF2 clusters can interact with boranes. In both cases, the most intense ions were complexes between “superhalogen”-LiF2 and boranes.",
publisher = "Beograd : Savez mašinskih i elektrotehničk ihinženjera i tehničara Srbije (SMEITS) : Društvo za obnovljive izvore električne energije",
journal = "11th International Conference on Renewable Electrical Power Sources : Proceedings",
title = "Ispitivanje LIF/B sistema korišćenjem negativnog moda LDI MS: mogući sistem za skladištenje vodonika, Investigation of LIF/B system using the negative mode LDI MS: a possible hydrogen storage system",
pages = "115-118",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12570"
}
Veljković, F., Janković, B., Stajčić, I., Stoiljković, M., Janković, M., Kapuran, Đ.,& Veličković, S.. (2023). Ispitivanje LIF/B sistema korišćenjem negativnog moda LDI MS: mogući sistem za skladištenje vodonika. in 11th International Conference on Renewable Electrical Power Sources : Proceedings
Beograd : Savez mašinskih i elektrotehničk ihinženjera i tehničara Srbije (SMEITS) : Društvo za obnovljive izvore električne energije., 115-118.
https://hdl.handle.net/21.15107/rcub_vinar_12570
Veljković F, Janković B, Stajčić I, Stoiljković M, Janković M, Kapuran Đ, Veličković S. Ispitivanje LIF/B sistema korišćenjem negativnog moda LDI MS: mogući sistem za skladištenje vodonika. in 11th International Conference on Renewable Electrical Power Sources : Proceedings. 2023;:115-118.
https://hdl.handle.net/21.15107/rcub_vinar_12570 .
Veljković, Filip, Janković, Bojan, Stajčić, Ivana, Stoiljković, Milovan, Janković, Marija, Kapuran, Đorđe, Veličković, Suzana, "Ispitivanje LIF/B sistema korišćenjem negativnog moda LDI MS: mogući sistem za skladištenje vodonika" in 11th International Conference on Renewable Electrical Power Sources : Proceedings (2023):115-118,
https://hdl.handle.net/21.15107/rcub_vinar_12570 .

Combined effect of cover crops and bio-fertilizer on sustainable popcorn maize production

Dragičević, Vesna; Simić, Milena; Dolijanović, Željko; Đorđević, Snežana; Stoiljković, Milovan; Dimkić, Ivica; Brankov, Milan

(2023)

TY  - JOUR
AU  - Dragičević, Vesna
AU  - Simić, Milena
AU  - Dolijanović, Željko
AU  - Đorđević, Snežana
AU  - Stoiljković, Milovan
AU  - Dimkić, Ivica
AU  - Brankov, Milan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12825
AB  - Cover crops play an important role in low-input cropping systems, increasing the use of agro-ecosystem services. Due to the lack of information about the impact of cover crops and bio-fertilizers on popcorn maize (Zea mays everta Sturt.) growth and yield quality, especially the popping volume and nutritive quality, such as concentrations of protein and mineral elements, this research aimed to provide essential information. The interrelation between popcorn maize productivity and quality with important groups of soil microorganisms presents additional novelty. The results demonstrated that field pea is a beneficial cover crop, especially when combined with a bio-fertilizer, supporting the accumulation of maize biomass, chlorophyll, yield potential, and the concentrations of protein, Ca, Mg, Fe, and Zn. In addition, field pea residues promoted N-fixing bacteria, and the number of total microorganisms, especially actinomycetes and decomposing bacteria, which could promote nutrient uptake and grain quality. Residues of cover crop mixtures, common vetch + winter oats and field pea + winter oats, promoted the total number of microorganisms in the soil, and up to the end of vegetation, a greater number of decomposition and ammonification microorganisms were found, especially when the bio-fertilizer was applied, which consequently could support greater maize biomass. Popping volume, as a main trait of popcorn maize, had the highest value in the common vetch + winter oats variant, supporting again the statement that quality traits could be enhanced in sustainable production. Unlike living cover crops, mulch mainly affected soil microbial communities and promoted the development of actinomycetes and cellulolytic microorganisms during the growing season. The results of this research could contribute to the development of sustainable popcorn maize production for improved grain quality. They could also serve as a basis for isolating beneficial soil microorganisms to develop new bio-fertilizers that could improve maize production in synergy with cover crops.
T2  - Frontiers in Plant Science
T1  - Combined effect of cover crops and bio-fertilizer on sustainable popcorn maize production
VL  - 14
SP  - 1250903
DO  - 10.3389/fpls.2023.1250903
ER  - 
@article{
author = "Dragičević, Vesna and Simić, Milena and Dolijanović, Željko and Đorđević, Snežana and Stoiljković, Milovan and Dimkić, Ivica and Brankov, Milan",
year = "2023",
abstract = "Cover crops play an important role in low-input cropping systems, increasing the use of agro-ecosystem services. Due to the lack of information about the impact of cover crops and bio-fertilizers on popcorn maize (Zea mays everta Sturt.) growth and yield quality, especially the popping volume and nutritive quality, such as concentrations of protein and mineral elements, this research aimed to provide essential information. The interrelation between popcorn maize productivity and quality with important groups of soil microorganisms presents additional novelty. The results demonstrated that field pea is a beneficial cover crop, especially when combined with a bio-fertilizer, supporting the accumulation of maize biomass, chlorophyll, yield potential, and the concentrations of protein, Ca, Mg, Fe, and Zn. In addition, field pea residues promoted N-fixing bacteria, and the number of total microorganisms, especially actinomycetes and decomposing bacteria, which could promote nutrient uptake and grain quality. Residues of cover crop mixtures, common vetch + winter oats and field pea + winter oats, promoted the total number of microorganisms in the soil, and up to the end of vegetation, a greater number of decomposition and ammonification microorganisms were found, especially when the bio-fertilizer was applied, which consequently could support greater maize biomass. Popping volume, as a main trait of popcorn maize, had the highest value in the common vetch + winter oats variant, supporting again the statement that quality traits could be enhanced in sustainable production. Unlike living cover crops, mulch mainly affected soil microbial communities and promoted the development of actinomycetes and cellulolytic microorganisms during the growing season. The results of this research could contribute to the development of sustainable popcorn maize production for improved grain quality. They could also serve as a basis for isolating beneficial soil microorganisms to develop new bio-fertilizers that could improve maize production in synergy with cover crops.",
journal = "Frontiers in Plant Science",
title = "Combined effect of cover crops and bio-fertilizer on sustainable popcorn maize production",
volume = "14",
pages = "1250903",
doi = "10.3389/fpls.2023.1250903"
}
Dragičević, V., Simić, M., Dolijanović, Ž., Đorđević, S., Stoiljković, M., Dimkić, I.,& Brankov, M.. (2023). Combined effect of cover crops and bio-fertilizer on sustainable popcorn maize production. in Frontiers in Plant Science, 14, 1250903.
https://doi.org/10.3389/fpls.2023.1250903
Dragičević V, Simić M, Dolijanović Ž, Đorđević S, Stoiljković M, Dimkić I, Brankov M. Combined effect of cover crops and bio-fertilizer on sustainable popcorn maize production. in Frontiers in Plant Science. 2023;14:1250903.
doi:10.3389/fpls.2023.1250903 .
Dragičević, Vesna, Simić, Milena, Dolijanović, Željko, Đorđević, Snežana, Stoiljković, Milovan, Dimkić, Ivica, Brankov, Milan, "Combined effect of cover crops and bio-fertilizer on sustainable popcorn maize production" in Frontiers in Plant Science, 14 (2023):1250903,
https://doi.org/10.3389/fpls.2023.1250903 . .
1

Laser desorption/ionization mass spectrometry of Li1.999Ta0.005SiO3

Veljković, Filip; Matović, Branko; Butulija, Svetlana; Stoiljković, Milovan; Stajčić, Ivana; Janković, Bojan; Veličković, Suzana

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2022)

TY  - CONF
AU  - Veljković, Filip
AU  - Matović, Branko
AU  - Butulija, Svetlana
AU  - Stoiljković, Milovan
AU  - Stajčić, Ivana
AU  - Janković, Bojan
AU  - Veličković, Suzana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12622
AB  - In the last couple of decades the scientific is making great efforts to investigate the phenomenon of laser-matter interaction, because these knowledge can directly positively influence on technological innovations in the field of materials. This phenomenon are still not fully invetigate since involves a number physical and chemical processes, which take place simultaneously or separated in time and space [1]. The laser desorption/ionization (LDI) implies the following processes: the laser provide a pulse of energy to sample (for a few ns), the sample increases in temperature quickly ( to several thousand degrees), so lead to the production ions, neutrals and electrons in the gass phase [2]. The aim of this paper is to examine the products of the gas phase formed during the interaction of laser- Li1.999Ta0.005SiO3. The Li1.999Ta0.005SiO3 ceramics has a wide application because the melting of lithium metasilicate is used for the calibration of thermocouples, as a flux in glazes and ceramic enamels, dental glass, nuclear waste immobilization as well as ceramic materials for fusion reactors. The knowledge gained should contribute to a better understanding behavior of Li1.999Ta0.005SiO3 in extreme conditions. The experiments were performed on a commercial matrix-assisted laser desorption/ionization mass spectrometer (MALDI MS) with time of flight mass analyzer (Voyager-DE PRO, Sciex, USA), equipped with a nitrogen pulse laser (pulse duration of 3 ns, 20 Hz, and wavelength of 337 nm). The mass spectra were obtained using the LDI (without matrices) positive and negative reflector modes. It is known that the LDI MS is an efficient method for the production and detection of homogeneous and heterogeneous clusters [3]. Preliminary results shows that the ion signals in the negative ion LDI mass spectrum of Li1.999Ta0.005SiO3 correspond to the following species: m/z 59.89 SiO2 -  (calcd 59.97), m/z 71.90 Si2O-  (calcd 71.95), m/z 83.90 Si3 -  (calcd 83.93), m/z 95.91 Si(OH)4 - (calcd 95.99), m/z107.91 Si2(OH)2(H2O)-  (calcd 107.97), m/z 119.92 Si2O4 -  (calcd 119.93), m/z 120.95 Si2O3(OH)-  (calcd 120.94), m/z 131.93 Si3O3 -  (calcd 131.92), m/z 143.92 Si2(OH)2(H2O)3 - (calcd 143.99). The ion signals in the positive mode were attributed to the following cations: LiSi(OH)+  (m/z 52.02, calcd 51.99), Li3(OH)(H2O)+ (m/z 56.04, calcd 56.06), Li2SiO+ (m/z 58.05 calcd 58.00), Li3Si2H2(H2O)+ (m/z 97.15 calcd 97.03), Li5Si2H2O+ (m/z 109.10, calcd 109.04). The results show that silicon-oxygen cluster ions were formed in the negative mode, while lithiumsilicon clusters were detected in the positive mode.
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
C3  - IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts
T1  - Laser desorption/ionization mass spectrometry of Li1.999Ta0.005SiO3
SP  - 46
EP  - 46
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12622
ER  - 
@conference{
author = "Veljković, Filip and Matović, Branko and Butulija, Svetlana and Stoiljković, Milovan and Stajčić, Ivana and Janković, Bojan and Veličković, Suzana",
year = "2022",
abstract = "In the last couple of decades the scientific is making great efforts to investigate the phenomenon of laser-matter interaction, because these knowledge can directly positively influence on technological innovations in the field of materials. This phenomenon are still not fully invetigate since involves a number physical and chemical processes, which take place simultaneously or separated in time and space [1]. The laser desorption/ionization (LDI) implies the following processes: the laser provide a pulse of energy to sample (for a few ns), the sample increases in temperature quickly ( to several thousand degrees), so lead to the production ions, neutrals and electrons in the gass phase [2]. The aim of this paper is to examine the products of the gas phase formed during the interaction of laser- Li1.999Ta0.005SiO3. The Li1.999Ta0.005SiO3 ceramics has a wide application because the melting of lithium metasilicate is used for the calibration of thermocouples, as a flux in glazes and ceramic enamels, dental glass, nuclear waste immobilization as well as ceramic materials for fusion reactors. The knowledge gained should contribute to a better understanding behavior of Li1.999Ta0.005SiO3 in extreme conditions. The experiments were performed on a commercial matrix-assisted laser desorption/ionization mass spectrometer (MALDI MS) with time of flight mass analyzer (Voyager-DE PRO, Sciex, USA), equipped with a nitrogen pulse laser (pulse duration of 3 ns, 20 Hz, and wavelength of 337 nm). The mass spectra were obtained using the LDI (without matrices) positive and negative reflector modes. It is known that the LDI MS is an efficient method for the production and detection of homogeneous and heterogeneous clusters [3]. Preliminary results shows that the ion signals in the negative ion LDI mass spectrum of Li1.999Ta0.005SiO3 correspond to the following species: m/z 59.89 SiO2 -  (calcd 59.97), m/z 71.90 Si2O-  (calcd 71.95), m/z 83.90 Si3 -  (calcd 83.93), m/z 95.91 Si(OH)4 - (calcd 95.99), m/z107.91 Si2(OH)2(H2O)-  (calcd 107.97), m/z 119.92 Si2O4 -  (calcd 119.93), m/z 120.95 Si2O3(OH)-  (calcd 120.94), m/z 131.93 Si3O3 -  (calcd 131.92), m/z 143.92 Si2(OH)2(H2O)3 - (calcd 143.99). The ion signals in the positive mode were attributed to the following cations: LiSi(OH)+  (m/z 52.02, calcd 51.99), Li3(OH)(H2O)+ (m/z 56.04, calcd 56.06), Li2SiO+ (m/z 58.05 calcd 58.00), Li3Si2H2(H2O)+ (m/z 97.15 calcd 97.03), Li5Si2H2O+ (m/z 109.10, calcd 109.04). The results show that silicon-oxygen cluster ions were formed in the negative mode, while lithiumsilicon clusters were detected in the positive mode.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
journal = "IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts",
title = "Laser desorption/ionization mass spectrometry of Li1.999Ta0.005SiO3",
pages = "46-46",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12622"
}
Veljković, F., Matović, B., Butulija, S., Stoiljković, M., Stajčić, I., Janković, B.,& Veličković, S.. (2022). Laser desorption/ionization mass spectrometry of Li1.999Ta0.005SiO3. in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 46-46.
https://hdl.handle.net/21.15107/rcub_vinar_12622
Veljković F, Matović B, Butulija S, Stoiljković M, Stajčić I, Janković B, Veličković S. Laser desorption/ionization mass spectrometry of Li1.999Ta0.005SiO3. in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts. 2022;:46-46.
https://hdl.handle.net/21.15107/rcub_vinar_12622 .
Veljković, Filip, Matović, Branko, Butulija, Svetlana, Stoiljković, Milovan, Stajčić, Ivana, Janković, Bojan, Veličković, Suzana, "Laser desorption/ionization mass spectrometry of Li1.999Ta0.005SiO3" in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts (2022):46-46,
https://hdl.handle.net/21.15107/rcub_vinar_12622 .

Status of Essential Elements in Soil and Grain of Organically Produced Maize, Spelt, and Soybean

Dragićević, Vesna; Stoiljković, Milovan; Brankov, Milan; Tolimir, Miodrag; Tabaković, Marijenka; Dodevska, Margarita S.; Simić, Milena

(2022)

TY  - JOUR
AU  - Dragićević, Vesna
AU  - Stoiljković, Milovan
AU  - Brankov, Milan
AU  - Tolimir, Miodrag
AU  - Tabaković, Marijenka
AU  - Dodevska, Margarita S.
AU  - Simić, Milena
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10283
AB  - Organic agriculture offers many benefits through the increased nutritional quality of produced crops, agro-ecosystem preservation, and climate change mitigation. The development of an efficient nutrient management strategy in low-input systems, such as organic agriculture, which supports soil fertility and essential nutrients absorption by crops, is continually exploring. Thus, a study with maize–spelt–soybean rotation during a 5-year period in organic production was established to evaluate the variability in soil organic matter (SOM) and the status of available elements: N, P, K, Ca, Mg, Fe, Cu, Mn, Zn, and Si from the soil, as well as grain yield (GY) and the content of protein, P, K, Ca, Mg, Fe, Cu, Mn, Zn, and Si concentration in the grain of spelt, maize, and soybean. Significant variations in mineral elements in the soil, GY, and grain composition were detected. Spelt achieved the highest average GY, while soybean grain was the richest in a majority of examined nutrients. The soil Ca content was important for GY, while the protein level in grain was generally tied to the Mn level in the soil. It was recognized that soil–crop crosstalk is an important strategy for macro- and micro-nutrients management in the soil and grain of organically produced spelt, maize, and soybean. While a reduction in the GY and protein concentration in grain was present over time, it was established that a low-input system under dry-farming conditions supports nutrient availability and accumulation in grain, under semi-arid agro-ecological conditions of central Serbia.
T2  - Agriculture
T1  - Status of Essential Elements in Soil and Grain of Organically Produced Maize, Spelt, and Soybean
VL  - 12
IS  - 5
SP  - 702
DO  - 10.3390/agriculture12050702
ER  - 
@article{
author = "Dragićević, Vesna and Stoiljković, Milovan and Brankov, Milan and Tolimir, Miodrag and Tabaković, Marijenka and Dodevska, Margarita S. and Simić, Milena",
year = "2022",
abstract = "Organic agriculture offers many benefits through the increased nutritional quality of produced crops, agro-ecosystem preservation, and climate change mitigation. The development of an efficient nutrient management strategy in low-input systems, such as organic agriculture, which supports soil fertility and essential nutrients absorption by crops, is continually exploring. Thus, a study with maize–spelt–soybean rotation during a 5-year period in organic production was established to evaluate the variability in soil organic matter (SOM) and the status of available elements: N, P, K, Ca, Mg, Fe, Cu, Mn, Zn, and Si from the soil, as well as grain yield (GY) and the content of protein, P, K, Ca, Mg, Fe, Cu, Mn, Zn, and Si concentration in the grain of spelt, maize, and soybean. Significant variations in mineral elements in the soil, GY, and grain composition were detected. Spelt achieved the highest average GY, while soybean grain was the richest in a majority of examined nutrients. The soil Ca content was important for GY, while the protein level in grain was generally tied to the Mn level in the soil. It was recognized that soil–crop crosstalk is an important strategy for macro- and micro-nutrients management in the soil and grain of organically produced spelt, maize, and soybean. While a reduction in the GY and protein concentration in grain was present over time, it was established that a low-input system under dry-farming conditions supports nutrient availability and accumulation in grain, under semi-arid agro-ecological conditions of central Serbia.",
journal = "Agriculture",
title = "Status of Essential Elements in Soil and Grain of Organically Produced Maize, Spelt, and Soybean",
volume = "12",
number = "5",
pages = "702",
doi = "10.3390/agriculture12050702"
}
Dragićević, V., Stoiljković, M., Brankov, M., Tolimir, M., Tabaković, M., Dodevska, M. S.,& Simić, M.. (2022). Status of Essential Elements in Soil and Grain of Organically Produced Maize, Spelt, and Soybean. in Agriculture, 12(5), 702.
https://doi.org/10.3390/agriculture12050702
Dragićević V, Stoiljković M, Brankov M, Tolimir M, Tabaković M, Dodevska MS, Simić M. Status of Essential Elements in Soil and Grain of Organically Produced Maize, Spelt, and Soybean. in Agriculture. 2022;12(5):702.
doi:10.3390/agriculture12050702 .
Dragićević, Vesna, Stoiljković, Milovan, Brankov, Milan, Tolimir, Miodrag, Tabaković, Marijenka, Dodevska, Margarita S., Simić, Milena, "Status of Essential Elements in Soil and Grain of Organically Produced Maize, Spelt, and Soybean" in Agriculture, 12, no. 5 (2022):702,
https://doi.org/10.3390/agriculture12050702 . .
1
1

Kernel color and fertilization as factors of enhanced maize quality

Dragičević, Vesna; Brankov, Milan; Stoiljković, Milovan; Tolimir, Miodrag; Travlos, Ilias; Simić, Milena

(2022)

TY  - JOUR
AU  - Dragičević, Vesna
AU  - Brankov, Milan
AU  - Stoiljković, Milovan
AU  - Tolimir, Miodrag
AU  - Travlos, Ilias
AU  - Simić, Milena
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10578
AB  - Maize is an important staple crop and a significant source of various nutrients.We aimed to determine the macronutrients, antioxidants, and essentialelements in maize genotypes (white, yellow, and red kernel) using threedifferent fertilizers, which could be used as a basis to increase the nutrientdensity of maize. The fertilizer treatments used bio- and organic fertilizers as asustainable approach, urea, as a commonly used mineral fertilizer, and thecontrol (no fertilization). We evaluated the yield, concentration ofmacronutrient (protein, oil, and starch), nonenzymatic antioxidants(phenolics, yellow pigment, total glutathione (GSH), and phytic phosphorus),and reduction capacity of the 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical, aswell as essential elements that are commonly deficient in the diet (Mg, Ca, Fe,Mn, Zn, Cu, and S) and their relationships with phytic acid. The genotypeexpressed the strongest effect on the variability of grain yield and the analyzedgrain constituents. The red-kernel hybrid showed the greatest accumulation ofprotein, oil, phenolics, and essential elements (Ca, Fe, Cu, and S) than a yellowand white hybrid, especially in the biofertilizer treatment. The yellow kernel hadthe highest concentrations of yellow pigment, GSH, phytic phosphorous, Mg,Mn, and Zn (19.61 µg g−1, 1,134 nmol g−1, 2.63 mg g−1, 1,963 µg g−1, 11.7 µg g−1,and 33.9 µg g−1, respectively). The white kernel had a greater starchconcentration (2.5% higher than that in the red hybrid) and the potentialbioavailability of essential metals, particularly under no fertilization. Thissupports the significance of white maize as a staple food in many traditionaldiets across the world. Urea was important for the enhancement of theantioxidant status (with 88.0% reduction capacity for the DPPH radical) andincreased potential Zn bioavailability in the maize kernels (13.3% higher thanthat in the biofertilizer treatment). This study underlines the differences in theyield potential and chemical composition of red, yellow, and white-kernelmaize and their importance as a necessary part of a sustainable human diet.This information can help determine the most appropriate genotype based onthe antioxidants and/or essential elements targeted for kernel improvement.
T2  - Frontiers in Plant Science
T1  - Kernel color and fertilization as factors of enhanced maize quality
SP  - 1
EP  - 13
DO  - 10.3389/fpls.2022.1027618
ER  - 
@article{
author = "Dragičević, Vesna and Brankov, Milan and Stoiljković, Milovan and Tolimir, Miodrag and Travlos, Ilias and Simić, Milena",
year = "2022",
abstract = "Maize is an important staple crop and a significant source of various nutrients.We aimed to determine the macronutrients, antioxidants, and essentialelements in maize genotypes (white, yellow, and red kernel) using threedifferent fertilizers, which could be used as a basis to increase the nutrientdensity of maize. The fertilizer treatments used bio- and organic fertilizers as asustainable approach, urea, as a commonly used mineral fertilizer, and thecontrol (no fertilization). We evaluated the yield, concentration ofmacronutrient (protein, oil, and starch), nonenzymatic antioxidants(phenolics, yellow pigment, total glutathione (GSH), and phytic phosphorus),and reduction capacity of the 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical, aswell as essential elements that are commonly deficient in the diet (Mg, Ca, Fe,Mn, Zn, Cu, and S) and their relationships with phytic acid. The genotypeexpressed the strongest effect on the variability of grain yield and the analyzedgrain constituents. The red-kernel hybrid showed the greatest accumulation ofprotein, oil, phenolics, and essential elements (Ca, Fe, Cu, and S) than a yellowand white hybrid, especially in the biofertilizer treatment. The yellow kernel hadthe highest concentrations of yellow pigment, GSH, phytic phosphorous, Mg,Mn, and Zn (19.61 µg g−1, 1,134 nmol g−1, 2.63 mg g−1, 1,963 µg g−1, 11.7 µg g−1,and 33.9 µg g−1, respectively). The white kernel had a greater starchconcentration (2.5% higher than that in the red hybrid) and the potentialbioavailability of essential metals, particularly under no fertilization. Thissupports the significance of white maize as a staple food in many traditionaldiets across the world. Urea was important for the enhancement of theantioxidant status (with 88.0% reduction capacity for the DPPH radical) andincreased potential Zn bioavailability in the maize kernels (13.3% higher thanthat in the biofertilizer treatment). This study underlines the differences in theyield potential and chemical composition of red, yellow, and white-kernelmaize and their importance as a necessary part of a sustainable human diet.This information can help determine the most appropriate genotype based onthe antioxidants and/or essential elements targeted for kernel improvement.",
journal = "Frontiers in Plant Science",
title = "Kernel color and fertilization as factors of enhanced maize quality",
pages = "1-13",
doi = "10.3389/fpls.2022.1027618"
}
Dragičević, V., Brankov, M., Stoiljković, M., Tolimir, M., Travlos, I.,& Simić, M.. (2022). Kernel color and fertilization as factors of enhanced maize quality. in Frontiers in Plant Science, 1-13.
https://doi.org/10.3389/fpls.2022.1027618
Dragičević V, Brankov M, Stoiljković M, Tolimir M, Travlos I, Simić M. Kernel color and fertilization as factors of enhanced maize quality. in Frontiers in Plant Science. 2022;:1-13.
doi:10.3389/fpls.2022.1027618 .
Dragičević, Vesna, Brankov, Milan, Stoiljković, Milovan, Tolimir, Miodrag, Travlos, Ilias, Simić, Milena, "Kernel color and fertilization as factors of enhanced maize quality" in Frontiers in Plant Science (2022):1-13,
https://doi.org/10.3389/fpls.2022.1027618 . .
1
1

Sustainable fertilization systems as a prerequisite for improved quality of agricultural products

Dragičević, Vesna; Brankov, Milan; Stoiljković, Milovan; Šenk, Milena; Dolijanović, Željko; Tolimir, Miodrag; Simić, Milena

(Belgrade : University of Belgrade, Faculty of agriculture, 2022)

TY  - CONF
AU  - Dragičević, Vesna
AU  - Brankov, Milan
AU  - Stoiljković, Milovan
AU  - Šenk, Milena
AU  - Dolijanović, Željko
AU  - Tolimir, Miodrag
AU  - Simić, Milena
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11584
AB  - Human health is dependent not just on diet, but mainly on quality of agricultural products as a part of diet. If crops were grown on poorly fertile soils, or they are exposed to severe stresses, lesser amount of mineral elements, particularly essential elements, such as zinc, copper, manganese, magnesium, calcium, iron, and even sulphur, will be absorbed and accumulated, resulting in their deficiency in diets and increased incidence of various chronic diseases. Together with naturally low soil fertility, climate change, intensive agriculture is one of the main contributors of soil depletion. Thus, various long-term strategies, which are sustainable for agricultural plants and soils, at the same time, must be developed. It is of particular importance to increase a level of organic matter, as a source of mineral nutrients from the soil. The application through soil, as well as via plant foliage of various complex and organic fertilizers, containing macro- and micro-elements, and many stimulating compounds, enables better absorption and metabolisation of nutrients required for plants and nutrients essential for humans. Besides, bio-fertilizers, containing beneficial microorganisms have an important role in nutrients mobilization in soils, particularly from poorly accessible forms. Many bio fertilizers contain microorganisms that are able to absorb atmospheric nitrogen, thus enriching soil, delivering it to the plants, enabling reduction in amount and costs of nitrogen addition into the soil. Promoting microorganisms are also able to enhance plants ability to absorb water and nutrients by their synergy with roots, resulting in stable and better growth performances of agricultural plants, thus increasing yield and its quality. Some other cropping practices, such as crop rotation, intercropping and use of cover crops, enriches soil with organic matter, reduces losses of nutrients through recycling of harvest residues, therefore increasing soil fertility, as well as quantity and quality of crop yield, at the same time.
PB  - Belgrade : University of Belgrade, Faculty of agriculture
C3  - 1-EuSPMF - 1st European symposium on phytochemicals in medicine and food : Book of abstracts
T1  - Sustainable fertilization systems as a prerequisite for  improved quality of agricultural products
SP  - 32
EP  - 32
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11584
ER  - 
@conference{
author = "Dragičević, Vesna and Brankov, Milan and Stoiljković, Milovan and Šenk, Milena and Dolijanović, Željko and Tolimir, Miodrag and Simić, Milena",
year = "2022",
abstract = "Human health is dependent not just on diet, but mainly on quality of agricultural products as a part of diet. If crops were grown on poorly fertile soils, or they are exposed to severe stresses, lesser amount of mineral elements, particularly essential elements, such as zinc, copper, manganese, magnesium, calcium, iron, and even sulphur, will be absorbed and accumulated, resulting in their deficiency in diets and increased incidence of various chronic diseases. Together with naturally low soil fertility, climate change, intensive agriculture is one of the main contributors of soil depletion. Thus, various long-term strategies, which are sustainable for agricultural plants and soils, at the same time, must be developed. It is of particular importance to increase a level of organic matter, as a source of mineral nutrients from the soil. The application through soil, as well as via plant foliage of various complex and organic fertilizers, containing macro- and micro-elements, and many stimulating compounds, enables better absorption and metabolisation of nutrients required for plants and nutrients essential for humans. Besides, bio-fertilizers, containing beneficial microorganisms have an important role in nutrients mobilization in soils, particularly from poorly accessible forms. Many bio fertilizers contain microorganisms that are able to absorb atmospheric nitrogen, thus enriching soil, delivering it to the plants, enabling reduction in amount and costs of nitrogen addition into the soil. Promoting microorganisms are also able to enhance plants ability to absorb water and nutrients by their synergy with roots, resulting in stable and better growth performances of agricultural plants, thus increasing yield and its quality. Some other cropping practices, such as crop rotation, intercropping and use of cover crops, enriches soil with organic matter, reduces losses of nutrients through recycling of harvest residues, therefore increasing soil fertility, as well as quantity and quality of crop yield, at the same time.",
publisher = "Belgrade : University of Belgrade, Faculty of agriculture",
journal = "1-EuSPMF - 1st European symposium on phytochemicals in medicine and food : Book of abstracts",
title = "Sustainable fertilization systems as a prerequisite for  improved quality of agricultural products",
pages = "32-32",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11584"
}
Dragičević, V., Brankov, M., Stoiljković, M., Šenk, M., Dolijanović, Ž., Tolimir, M.,& Simić, M.. (2022). Sustainable fertilization systems as a prerequisite for  improved quality of agricultural products. in 1-EuSPMF - 1st European symposium on phytochemicals in medicine and food : Book of abstracts
Belgrade : University of Belgrade, Faculty of agriculture., 32-32.
https://hdl.handle.net/21.15107/rcub_vinar_11584
Dragičević V, Brankov M, Stoiljković M, Šenk M, Dolijanović Ž, Tolimir M, Simić M. Sustainable fertilization systems as a prerequisite for  improved quality of agricultural products. in 1-EuSPMF - 1st European symposium on phytochemicals in medicine and food : Book of abstracts. 2022;:32-32.
https://hdl.handle.net/21.15107/rcub_vinar_11584 .
Dragičević, Vesna, Brankov, Milan, Stoiljković, Milovan, Šenk, Milena, Dolijanović, Željko, Tolimir, Miodrag, Simić, Milena, "Sustainable fertilization systems as a prerequisite for  improved quality of agricultural products" in 1-EuSPMF - 1st European symposium on phytochemicals in medicine and food : Book of abstracts (2022):32-32,
https://hdl.handle.net/21.15107/rcub_vinar_11584 .

Visual detection of quercetin using gold nanoparticles

Nemoda, Milica; Pavlović, M.; Stoiljković, Milovan; Momić, Tatjana

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of the Republic of Serbia, 2021)

TY  - CONF
AU  - Nemoda, Milica
AU  - Pavlović, M.
AU  - Stoiljković, Milovan
AU  - Momić, Tatjana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12522
AB  - We report on the use of gold nanoparticles (AuNPs) as a colorimetric probe for quercetin (Q). The method is based on the aggregation of the AuNPs that is caused by various quercetin concentrations in the range of 4 mg/L - 15 mg/L and leads to a visually detectable color change. Concentration-dependent aggregation is confirmed by recording of UV-visible absorption spectra. The method provides a useful tool for the rapid visual quercetin determination.
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of the Republic of Serbia
C3  - Proceedings / 7th Workshop Specific Methods for Food Safety and Quality, September 22nd, 2021, Belgrade, Serbia [is an online satellite event of] 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Physical Chemistry 2021
T1  - Visual detection of quercetin using gold nanoparticles
SP  - 28
EP  - 31
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12522
ER  - 
@conference{
author = "Nemoda, Milica and Pavlović, M. and Stoiljković, Milovan and Momić, Tatjana",
year = "2021",
abstract = "We report on the use of gold nanoparticles (AuNPs) as a colorimetric probe for quercetin (Q). The method is based on the aggregation of the AuNPs that is caused by various quercetin concentrations in the range of 4 mg/L - 15 mg/L and leads to a visually detectable color change. Concentration-dependent aggregation is confirmed by recording of UV-visible absorption spectra. The method provides a useful tool for the rapid visual quercetin determination.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of the Republic of Serbia",
journal = "Proceedings / 7th Workshop Specific Methods for Food Safety and Quality, September 22nd, 2021, Belgrade, Serbia [is an online satellite event of] 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Physical Chemistry 2021",
title = "Visual detection of quercetin using gold nanoparticles",
pages = "28-31",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12522"
}
Nemoda, M., Pavlović, M., Stoiljković, M.,& Momić, T.. (2021). Visual detection of quercetin using gold nanoparticles. in Proceedings / 7th Workshop Specific Methods for Food Safety and Quality, September 22nd, 2021, Belgrade, Serbia [is an online satellite event of] 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Physical Chemistry 2021
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of the Republic of Serbia., 28-31.
https://hdl.handle.net/21.15107/rcub_vinar_12522
Nemoda M, Pavlović M, Stoiljković M, Momić T. Visual detection of quercetin using gold nanoparticles. in Proceedings / 7th Workshop Specific Methods for Food Safety and Quality, September 22nd, 2021, Belgrade, Serbia [is an online satellite event of] 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Physical Chemistry 2021. 2021;:28-31.
https://hdl.handle.net/21.15107/rcub_vinar_12522 .
Nemoda, Milica, Pavlović, M., Stoiljković, Milovan, Momić, Tatjana, "Visual detection of quercetin using gold nanoparticles" in Proceedings / 7th Workshop Specific Methods for Food Safety and Quality, September 22nd, 2021, Belgrade, Serbia [is an online satellite event of] 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry - Physical Chemistry 2021 (2021):28-31,
https://hdl.handle.net/21.15107/rcub_vinar_12522 .

Antimicrobial and biological effects of polyaniline/polyvinylpyrrolidone nanocomposites loaded with silver nanospheres/triangles

Stamenović, Una; Davidović, Slađana; Petrović, Sandra; Leskovac, Andreja; Stoiljković, Milovan; Vodnik, Vesna

(2021)

TY  - JOUR
AU  - Stamenović, Una
AU  - Davidović, Slađana
AU  - Petrović, Sandra
AU  - Leskovac, Andreja
AU  - Stoiljković, Milovan
AU  - Vodnik, Vesna
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9874
AB  - Two silver–polyaniline/polyvinylpyrrolidone (Ag–PANI/PVP) nanocomposites were prepared using in situ integration of silver nanoparticles (AgNPs) during oxidative aniline polymerization, accelerated by the presence of PVP, which as well minimized the risk of particle agglomeration and macroscopic precipitation. Both nanocomposites have similar silver content (∼44 wt% Ag) but different morphological features of AgNPs (spheres/triangles) and polymers (granular/wrinkling pattern). Several spectroscopic, macroscopic, and analytical techniques, microscopy, and surface analysis methods have been used to analyze their physical and chemical properties. Investigation of their antimicrobial potential and possible application as an effective weapon against indicator microbial strains, E. coli, S. aureus, and C. albicans, has shown inhibition of microbial growth by more than 90%, even at low composite concentrations (5 ppm) and short contact time (4 h). A biosafety assessment of Ag–PANI/PVP that comprised testing the genotoxicity and redox modulating activity was performed using human peripheral blood cells as a model system. The obtained results have shown that the investigated Ag–PANI/PVP exhibited significant prooxidant and cytostatic effects (p < 0.05) with no apparent potential to induce DNA damage. Although precautions should be taken to protect human health, the significant antimicrobial efficiency of Ag–PANI/PVP makes it suitable for further studies and applications in non-medical areas, such as wastewater treatment.
T2  - New Journal of Chemistry
T1  - Antimicrobial and biological effects of polyaniline/polyvinylpyrrolidone nanocomposites loaded with silver nanospheres/triangles
VL  - 45
IS  - 28
SP  - 12711
EP  - 12720
DO  - 10.1039/D1NJ02729H
ER  - 
@article{
author = "Stamenović, Una and Davidović, Slađana and Petrović, Sandra and Leskovac, Andreja and Stoiljković, Milovan and Vodnik, Vesna",
year = "2021",
abstract = "Two silver–polyaniline/polyvinylpyrrolidone (Ag–PANI/PVP) nanocomposites were prepared using in situ integration of silver nanoparticles (AgNPs) during oxidative aniline polymerization, accelerated by the presence of PVP, which as well minimized the risk of particle agglomeration and macroscopic precipitation. Both nanocomposites have similar silver content (∼44 wt% Ag) but different morphological features of AgNPs (spheres/triangles) and polymers (granular/wrinkling pattern). Several spectroscopic, macroscopic, and analytical techniques, microscopy, and surface analysis methods have been used to analyze their physical and chemical properties. Investigation of their antimicrobial potential and possible application as an effective weapon against indicator microbial strains, E. coli, S. aureus, and C. albicans, has shown inhibition of microbial growth by more than 90%, even at low composite concentrations (5 ppm) and short contact time (4 h). A biosafety assessment of Ag–PANI/PVP that comprised testing the genotoxicity and redox modulating activity was performed using human peripheral blood cells as a model system. The obtained results have shown that the investigated Ag–PANI/PVP exhibited significant prooxidant and cytostatic effects (p < 0.05) with no apparent potential to induce DNA damage. Although precautions should be taken to protect human health, the significant antimicrobial efficiency of Ag–PANI/PVP makes it suitable for further studies and applications in non-medical areas, such as wastewater treatment.",
journal = "New Journal of Chemistry",
title = "Antimicrobial and biological effects of polyaniline/polyvinylpyrrolidone nanocomposites loaded with silver nanospheres/triangles",
volume = "45",
number = "28",
pages = "12711-12720",
doi = "10.1039/D1NJ02729H"
}
Stamenović, U., Davidović, S., Petrović, S., Leskovac, A., Stoiljković, M.,& Vodnik, V.. (2021). Antimicrobial and biological effects of polyaniline/polyvinylpyrrolidone nanocomposites loaded with silver nanospheres/triangles. in New Journal of Chemistry, 45(28), 12711-12720.
https://doi.org/10.1039/D1NJ02729H
Stamenović U, Davidović S, Petrović S, Leskovac A, Stoiljković M, Vodnik V. Antimicrobial and biological effects of polyaniline/polyvinylpyrrolidone nanocomposites loaded with silver nanospheres/triangles. in New Journal of Chemistry. 2021;45(28):12711-12720.
doi:10.1039/D1NJ02729H .
Stamenović, Una, Davidović, Slađana, Petrović, Sandra, Leskovac, Andreja, Stoiljković, Milovan, Vodnik, Vesna, "Antimicrobial and biological effects of polyaniline/polyvinylpyrrolidone nanocomposites loaded with silver nanospheres/triangles" in New Journal of Chemistry, 45, no. 28 (2021):12711-12720,
https://doi.org/10.1039/D1NJ02729H . .
3
3

Enhanced nutritional quality of sweet maize kernel in response to cover crops and bio-fertilizer

Dragičević, Vesna; Dolijanović, Željko; Janošević, Biljana; Brankov, Milan; Stoiljković, Milovan; Dodevska, Margarita S.; Simić, Milena

(2021)

TY  - JOUR
AU  - Dragičević, Vesna
AU  - Dolijanović, Željko
AU  - Janošević, Biljana
AU  - Brankov, Milan
AU  - Stoiljković, Milovan
AU  - Dodevska, Margarita S.
AU  - Simić, Milena
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9825
AB  - Cover crops (CC) are an important low-input strategy in sustainable agricultural sys-tems. The impact of different CC (common vetch, field pea, winter oats, fodder kale, common vetch + winter oats and field pea + winter oats), organic mulch, control treatment-fallow, and bio-fertilizer (BF) application, on yield and quality of sweet maize kernel was evaluated. CC biomass was higher in mixtures: field pea + winter oats, and common vetch + winter oats, as well as in fodder kale. Kernel yield and its chemical composition varied significantly by CC, BF, year, and their interaction. Organic mulch enhanced the concentration of sugars and glutathione in maize kernel. BF increased kernel yield, the concentration of sugars, vitamin C, Mg, Fe, Zn, and reduced phytate concentration. The highest Mg and Mn concentration in maize kernel was achieved with fodder kale, Zn concentration with common vetch + winter oats + BF, and Fe concentration with winter oats. The same treatments expressed the highest impact on variability in concentration of the phytate, phenolics, and yellow pigment, thus affecting further bio-availability of essential elements. Results indicate that in a semi-arid climate, under rain-fed conditions, CC such as fodder kale and winter oats + common vetch could enhance sweet maize productivity and kernel quality, serving as an important part of a sustainable cropping system, to facilitate food security.
T2  - Agronomy
T1  - Enhanced nutritional quality of sweet maize kernel in response to cover crops and bio-fertilizer
VL  - 11
IS  - 5
SP  - 981
DO  - 10.3390/agronomy11050981
ER  - 
@article{
author = "Dragičević, Vesna and Dolijanović, Željko and Janošević, Biljana and Brankov, Milan and Stoiljković, Milovan and Dodevska, Margarita S. and Simić, Milena",
year = "2021",
abstract = "Cover crops (CC) are an important low-input strategy in sustainable agricultural sys-tems. The impact of different CC (common vetch, field pea, winter oats, fodder kale, common vetch + winter oats and field pea + winter oats), organic mulch, control treatment-fallow, and bio-fertilizer (BF) application, on yield and quality of sweet maize kernel was evaluated. CC biomass was higher in mixtures: field pea + winter oats, and common vetch + winter oats, as well as in fodder kale. Kernel yield and its chemical composition varied significantly by CC, BF, year, and their interaction. Organic mulch enhanced the concentration of sugars and glutathione in maize kernel. BF increased kernel yield, the concentration of sugars, vitamin C, Mg, Fe, Zn, and reduced phytate concentration. The highest Mg and Mn concentration in maize kernel was achieved with fodder kale, Zn concentration with common vetch + winter oats + BF, and Fe concentration with winter oats. The same treatments expressed the highest impact on variability in concentration of the phytate, phenolics, and yellow pigment, thus affecting further bio-availability of essential elements. Results indicate that in a semi-arid climate, under rain-fed conditions, CC such as fodder kale and winter oats + common vetch could enhance sweet maize productivity and kernel quality, serving as an important part of a sustainable cropping system, to facilitate food security.",
journal = "Agronomy",
title = "Enhanced nutritional quality of sweet maize kernel in response to cover crops and bio-fertilizer",
volume = "11",
number = "5",
pages = "981",
doi = "10.3390/agronomy11050981"
}
Dragičević, V., Dolijanović, Ž., Janošević, B., Brankov, M., Stoiljković, M., Dodevska, M. S.,& Simić, M.. (2021). Enhanced nutritional quality of sweet maize kernel in response to cover crops and bio-fertilizer. in Agronomy, 11(5), 981.
https://doi.org/10.3390/agronomy11050981
Dragičević V, Dolijanović Ž, Janošević B, Brankov M, Stoiljković M, Dodevska MS, Simić M. Enhanced nutritional quality of sweet maize kernel in response to cover crops and bio-fertilizer. in Agronomy. 2021;11(5):981.
doi:10.3390/agronomy11050981 .
Dragičević, Vesna, Dolijanović, Željko, Janošević, Biljana, Brankov, Milan, Stoiljković, Milovan, Dodevska, Margarita S., Simić, Milena, "Enhanced nutritional quality of sweet maize kernel in response to cover crops and bio-fertilizer" in Agronomy, 11, no. 5 (2021):981,
https://doi.org/10.3390/agronomy11050981 . .
5
4

Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride

Veljković, Filip M.; Radović, Ivana M.; Toprek, Dragan; Petrović, Đorđe; Stoiljković, Milovan; Mitić, Vojislav V.; Veličković, Suzana

(2021)

TY  - JOUR
AU  - Veljković, Filip M.
AU  - Radović, Ivana M.
AU  - Toprek, Dragan
AU  - Petrović, Đorđe
AU  - Stoiljković, Milovan
AU  - Mitić, Vojislav V.
AU  - Veličković, Suzana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10084
AB  - Due to the increased use of yttrium in agriculture and industry, there is a growing interest in the impact of yttrium on the environment and human health. Developing novel procedures to detect and quantify species of yttrium represents an important task. In this work, we apply laser desorption/ionization-mass spectrometry (LDI-MS) to detect cluster ions of the solution of yttrium(III) chloride (YCl3) at different pH values. The density functional theory (DFT) calculations were used to reveal the energetically most favored structures of the anions and cations chosen from the LDI-MS results. Examination of the positive and negative mode LDI mass spectra of YCl3 showed the presence of the heterogeneous mononuclear and polynuclear clusters, such as [YCl(OH) (H2O)3]++, [Y2(H2O)]++, [Y4H2(H2O)4]++, and [Y5O4H3]++ (at pH 2 and 5) and [Y2Cl2(H2O)2]−−, [Y2O5(HCl)(OH)]−−, and [Y3OH3(OH)2(H2O)]−− (at pH 2, 5, and 10). The variation in the pH solution of YCl3 slightly affects the LDI mass spectrum of these yttrium clusters. It has only been noticed that the [Y4H2(H2O)4]++ cluster ions were not detected at pH 10. These results can become a guide in the detection of yttrium chloride by LDI-MS in real samples in different fields (ecological, food, and human).
T2  - Modern Physics Letters B
T1  - Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride
VL  - 35
IS  - 35
SP  - 2150454
DO  - 10.1142/S0217984921504546
ER  - 
@article{
author = "Veljković, Filip M. and Radović, Ivana M. and Toprek, Dragan and Petrović, Đorđe and Stoiljković, Milovan and Mitić, Vojislav V. and Veličković, Suzana",
year = "2021",
abstract = "Due to the increased use of yttrium in agriculture and industry, there is a growing interest in the impact of yttrium on the environment and human health. Developing novel procedures to detect and quantify species of yttrium represents an important task. In this work, we apply laser desorption/ionization-mass spectrometry (LDI-MS) to detect cluster ions of the solution of yttrium(III) chloride (YCl3) at different pH values. The density functional theory (DFT) calculations were used to reveal the energetically most favored structures of the anions and cations chosen from the LDI-MS results. Examination of the positive and negative mode LDI mass spectra of YCl3 showed the presence of the heterogeneous mononuclear and polynuclear clusters, such as [YCl(OH) (H2O)3]++, [Y2(H2O)]++, [Y4H2(H2O)4]++, and [Y5O4H3]++ (at pH 2 and 5) and [Y2Cl2(H2O)2]−−, [Y2O5(HCl)(OH)]−−, and [Y3OH3(OH)2(H2O)]−− (at pH 2, 5, and 10). The variation in the pH solution of YCl3 slightly affects the LDI mass spectrum of these yttrium clusters. It has only been noticed that the [Y4H2(H2O)4]++ cluster ions were not detected at pH 10. These results can become a guide in the detection of yttrium chloride by LDI-MS in real samples in different fields (ecological, food, and human).",
journal = "Modern Physics Letters B",
title = "Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride",
volume = "35",
number = "35",
pages = "2150454",
doi = "10.1142/S0217984921504546"
}
Veljković, F. M., Radović, I. M., Toprek, D., Petrović, Đ., Stoiljković, M., Mitić, V. V.,& Veličković, S.. (2021). Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride. in Modern Physics Letters B, 35(35), 2150454.
https://doi.org/10.1142/S0217984921504546
Veljković FM, Radović IM, Toprek D, Petrović Đ, Stoiljković M, Mitić VV, Veličković S. Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride. in Modern Physics Letters B. 2021;35(35):2150454.
doi:10.1142/S0217984921504546 .
Veljković, Filip M., Radović, Ivana M., Toprek, Dragan, Petrović, Đorđe, Stoiljković, Milovan, Mitić, Vojislav V., Veličković, Suzana, "Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride" in Modern Physics Letters B, 35, no. 35 (2021):2150454,
https://doi.org/10.1142/S0217984921504546 . .

Determination of corrosion products of Ag-Cu alloy by laser desorption ionization mass spectrometry

Veljković, Filip M.; Radović, Ivana M.; Drakulić, Dunja R.; Dimitrijević, Stevan; Dimitrijević, Silvana; Stoiljković, Milovan; Veličković, Suzana

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Veljković, Filip M.
AU  - Radović, Ivana M.
AU  - Drakulić, Dunja R.
AU  - Dimitrijević, Stevan
AU  - Dimitrijević, Silvana
AU  - Stoiljković, Milovan
AU  - Veličković, Suzana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10789
AB  - Silver alloys are generally used in the different fields of industry, including chemical processing, construction, heat exchangers, etc. Although Ag-Cu-Zn-Cd type of alloys, were widely exploited in the second half of the 20th century for their excellent properties, its use is forbidden in the EU due to the high toxicity of cadmium vapors. Ag-Cu-In type of alloy is a good alternative to Ag-Cu-Zn-Cd alloys, with great properties and can be used in various fields of industry. Most common methods for characterization of surface corrosion films of Ag-Cu alloys are: X-ray diffraction (XRD), scanning electron microscopy with energy dispersion spectroscopy (SEM-EDS), Raman spectroscopy and atomic force microscopy (AFM). Our current study focuses on the application of laser desorption ionization mass spectrometry (LDI MS) for determination of corrosion products of Ag-Cu alloy. The aim of this study was to confirm LDI MS as a fast, accurate and reliable method for determination of corrosion products on the surface of Ag-Cu-In alloy.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade
T1  - Determination of corrosion products of Ag-Cu alloy by laser desorption ionization mass spectrometry
SP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10789
ER  - 
@conference{
author = "Veljković, Filip M. and Radović, Ivana M. and Drakulić, Dunja R. and Dimitrijević, Stevan and Dimitrijević, Silvana and Stoiljković, Milovan and Veličković, Suzana",
year = "2021",
abstract = "Silver alloys are generally used in the different fields of industry, including chemical processing, construction, heat exchangers, etc. Although Ag-Cu-Zn-Cd type of alloys, were widely exploited in the second half of the 20th century for their excellent properties, its use is forbidden in the EU due to the high toxicity of cadmium vapors. Ag-Cu-In type of alloy is a good alternative to Ag-Cu-Zn-Cd alloys, with great properties and can be used in various fields of industry. Most common methods for characterization of surface corrosion films of Ag-Cu alloys are: X-ray diffraction (XRD), scanning electron microscopy with energy dispersion spectroscopy (SEM-EDS), Raman spectroscopy and atomic force microscopy (AFM). Our current study focuses on the application of laser desorption ionization mass spectrometry (LDI MS) for determination of corrosion products of Ag-Cu alloy. The aim of this study was to confirm LDI MS as a fast, accurate and reliable method for determination of corrosion products on the surface of Ag-Cu-In alloy.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade",
title = "Determination of corrosion products of Ag-Cu alloy by laser desorption ionization mass spectrometry",
pages = "50",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10789"
}
Veljković, F. M., Radović, I. M., Drakulić, D. R., Dimitrijević, S., Dimitrijević, S., Stoiljković, M.,& Veličković, S.. (2021). Determination of corrosion products of Ag-Cu alloy by laser desorption ionization mass spectrometry. in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade
Belgrade : Serbian Ceramic Society., 50.
https://hdl.handle.net/21.15107/rcub_vinar_10789
Veljković FM, Radović IM, Drakulić DR, Dimitrijević S, Dimitrijević S, Stoiljković M, Veličković S. Determination of corrosion products of Ag-Cu alloy by laser desorption ionization mass spectrometry. in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade. 2021;:50.
https://hdl.handle.net/21.15107/rcub_vinar_10789 .
Veljković, Filip M., Radović, Ivana M., Drakulić, Dunja R., Dimitrijević, Stevan, Dimitrijević, Silvana, Stoiljković, Milovan, Veličković, Suzana, "Determination of corrosion products of Ag-Cu alloy by laser desorption ionization mass spectrometry" in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade (2021):50,
https://hdl.handle.net/21.15107/rcub_vinar_10789 .

Detection and isotopic distribution of oxaprozine complex containing Cu(II) ions by LDI Mass Spectrometry

Veljković, Filip; Božić, Bojan; Stoiljković, Milovan; Radović, Ivana; Janković, Bojan; Ćurčić, Milica; Veličković, Suzana

(Belgrade : Society of Physical Chemists of Serbia, 2021)

TY  - CONF
AU  - Veljković, Filip
AU  - Božić, Bojan
AU  - Stoiljković, Milovan
AU  - Radović, Ivana
AU  - Janković, Bojan
AU  - Ćurčić, Milica
AU  - Veličković, Suzana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12616
AB  - This work considers possible uses of fruit-based waste for the production of valuable chemicals and biofuel precursors through recycling by thermochemical conversion. Slow pyrolysis of Goji berry mesocarp (GBM) as sugar-rich feedstock was investigated using simultaneous thermal analysis (STA) measurements in non-isothermal conditions. Results reveal that pyrolysis of GBM represents a promising route to obtain important key platform chemical - 5-hydroxymethylfurfural (5-HMF). It was found that autocatalytic dehydration of fructose (in a presence of Lewis acids) is responsible for production of 5-HMF at a low heating rate (5.0 K/min) with a maximum 5-HMF theoretical yield of 63.20 %. Higher heating rates (10.0 and 15.0 K/min) trigger fructose autogenesis behavior which opens the transferability channel to glucose engagement for 5-HMF theoretical high yield production.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry : Proceedings
T1  - Detection and isotopic distribution of oxaprozine complex containing Cu(II) ions by LDI Mass Spectrometry
VL  - 2
SP  - 705
EP  - 708
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12616
ER  - 
@conference{
author = "Veljković, Filip and Božić, Bojan and Stoiljković, Milovan and Radović, Ivana and Janković, Bojan and Ćurčić, Milica and Veličković, Suzana",
year = "2021",
abstract = "This work considers possible uses of fruit-based waste for the production of valuable chemicals and biofuel precursors through recycling by thermochemical conversion. Slow pyrolysis of Goji berry mesocarp (GBM) as sugar-rich feedstock was investigated using simultaneous thermal analysis (STA) measurements in non-isothermal conditions. Results reveal that pyrolysis of GBM represents a promising route to obtain important key platform chemical - 5-hydroxymethylfurfural (5-HMF). It was found that autocatalytic dehydration of fructose (in a presence of Lewis acids) is responsible for production of 5-HMF at a low heating rate (5.0 K/min) with a maximum 5-HMF theoretical yield of 63.20 %. Higher heating rates (10.0 and 15.0 K/min) trigger fructose autogenesis behavior which opens the transferability channel to glucose engagement for 5-HMF theoretical high yield production.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry : Proceedings",
title = "Detection and isotopic distribution of oxaprozine complex containing Cu(II) ions by LDI Mass Spectrometry",
volume = "2",
pages = "705-708",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12616"
}
Veljković, F., Božić, B., Stoiljković, M., Radović, I., Janković, B., Ćurčić, M.,& Veličković, S.. (2021). Detection and isotopic distribution of oxaprozine complex containing Cu(II) ions by LDI Mass Spectrometry. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry : Proceedings
Belgrade : Society of Physical Chemists of Serbia., 2, 705-708.
https://hdl.handle.net/21.15107/rcub_vinar_12616
Veljković F, Božić B, Stoiljković M, Radović I, Janković B, Ćurčić M, Veličković S. Detection and isotopic distribution of oxaprozine complex containing Cu(II) ions by LDI Mass Spectrometry. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry : Proceedings. 2021;2:705-708.
https://hdl.handle.net/21.15107/rcub_vinar_12616 .
Veljković, Filip, Božić, Bojan, Stoiljković, Milovan, Radović, Ivana, Janković, Bojan, Ćurčić, Milica, Veličković, Suzana, "Detection and isotopic distribution of oxaprozine complex containing Cu(II) ions by LDI Mass Spectrometry" in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry : Proceedings, 2 (2021):705-708,
https://hdl.handle.net/21.15107/rcub_vinar_12616 .

Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders

Maksimović, Vesna; Kusigerski, Vladan; Stoiljković, Milovan; Maletaškić, Jelena; Nikolić, Nebojša D.

(2020)

TY  - JOUR
AU  - Maksimović, Vesna
AU  - Kusigerski, Vladan
AU  - Stoiljković, Milovan
AU  - Maletaškić, Jelena
AU  - Nikolić, Nebojša D.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8950
AB  - Nickel−cobalt (Ni−Co) alloy powders were produced galvanostatically by using sulphate electrolytes withvarious ratios of Ni2+/Co2+ (mole ratios). The morphology, phase structure, chemical composition and magneticproperties were examined by scanning electron microscope (SEM), X-ray diffractometer (XRD), atomic emissionspectrometer (AES), and SQUID-based magnetometer, respectively. Morphology of the particles changed fromcauliflower-like and dendritic to coral-like and spongy-like ones with increasing Ni2+/Co2+ ratio from 0.25 to 4.0. XRDanalysis of the Ni−Co powders revealed that the decrease of Ni2+/Co2+ ratios (the increase of Co content) caused achange of structure from face centered cubic (FCC) obtained for the ratios of 4.0, 1.5 and 0.67 to a mixture of FCC andhexagonal closed-packed (HCP) phases for the ratio of 0.25. The increasing content of nickel led to change ofmechanism of electrolysis from irregular (up to ~40 wt.% Ni in the electrolytes) to close to equilibrium (between~40 and 60 wt.% Ni in the electrolytes) and anomalous co-deposition (over 60 wt.% Ni in the electrolytes) type. All ofthe obtained Ni−Co alloy samples behaved as soft magnetic materials while their magnetic parameters showedimmediate composition dependence since both coercivity and saturation magnetization almost linearly increased withincrease of the Co content.
T2  - Transactions of Nonferrous Metals Society of China
T1  - Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders
VL  - 30
IS  - 4
SP  - 1046
EP  - 1057
DO  - 10.1016/S1003-6326(20)65276-1
ER  - 
@article{
author = "Maksimović, Vesna and Kusigerski, Vladan and Stoiljković, Milovan and Maletaškić, Jelena and Nikolić, Nebojša D.",
year = "2020",
abstract = "Nickel−cobalt (Ni−Co) alloy powders were produced galvanostatically by using sulphate electrolytes withvarious ratios of Ni2+/Co2+ (mole ratios). The morphology, phase structure, chemical composition and magneticproperties were examined by scanning electron microscope (SEM), X-ray diffractometer (XRD), atomic emissionspectrometer (AES), and SQUID-based magnetometer, respectively. Morphology of the particles changed fromcauliflower-like and dendritic to coral-like and spongy-like ones with increasing Ni2+/Co2+ ratio from 0.25 to 4.0. XRDanalysis of the Ni−Co powders revealed that the decrease of Ni2+/Co2+ ratios (the increase of Co content) caused achange of structure from face centered cubic (FCC) obtained for the ratios of 4.0, 1.5 and 0.67 to a mixture of FCC andhexagonal closed-packed (HCP) phases for the ratio of 0.25. The increasing content of nickel led to change ofmechanism of electrolysis from irregular (up to ~40 wt.% Ni in the electrolytes) to close to equilibrium (between~40 and 60 wt.% Ni in the electrolytes) and anomalous co-deposition (over 60 wt.% Ni in the electrolytes) type. All ofthe obtained Ni−Co alloy samples behaved as soft magnetic materials while their magnetic parameters showedimmediate composition dependence since both coercivity and saturation magnetization almost linearly increased withincrease of the Co content.",
journal = "Transactions of Nonferrous Metals Society of China",
title = "Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders",
volume = "30",
number = "4",
pages = "1046-1057",
doi = "10.1016/S1003-6326(20)65276-1"
}
Maksimović, V., Kusigerski, V., Stoiljković, M., Maletaškić, J.,& Nikolić, N. D.. (2020). Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders. in Transactions of Nonferrous Metals Society of China, 30(4), 1046-1057.
https://doi.org/10.1016/S1003-6326(20)65276-1
Maksimović V, Kusigerski V, Stoiljković M, Maletaškić J, Nikolić ND. Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders. in Transactions of Nonferrous Metals Society of China. 2020;30(4):1046-1057.
doi:10.1016/S1003-6326(20)65276-1 .
Maksimović, Vesna, Kusigerski, Vladan, Stoiljković, Milovan, Maletaškić, Jelena, Nikolić, Nebojša D., "Influence of Ni2+/Co2+ ratio in electrolyte on morphology, structure and magnetic properties of electrolytically produced Ni−Co alloy powders" in Transactions of Nonferrous Metals Society of China, 30, no. 4 (2020):1046-1057,
https://doi.org/10.1016/S1003-6326(20)65276-1 . .
3
3

Arc Plasma Deposition of TiO2 Nanoparticles from Colloidal Solution

Maksimović, Vesna; Stoiljković, Milovan; Pavkov, Vladimir; Ciganović, Jovan; Cvijović-Alagić, Ivana

(2020)

TY  - JOUR
AU  - Maksimović, Vesna
AU  - Stoiljković, Milovan
AU  - Pavkov, Vladimir
AU  - Ciganović, Jovan
AU  - Cvijović-Alagić, Ivana
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9526
AB  - Surface modifications of metallic biomaterials can in great merit, improve the properties of the hard-tissue implants and in that way contribute to the success of the surgical implantation process. Coating deposition stands out as one of the many surface-modifying techniques that can be used to improve implant surface properties and, in turn, induce successful osseointegration. Deposition of the TiO2 layer on the surface of the metallic implants has a great potential to enhance not only their osseointegration ability but also their biocompatibility and corrosion resistance. In the present study, the possibility of successful deposition of the TiO2 layer on the surface of commercially pure titanium (CP-Ti), as the most commonly used metallic implant material, by spraying the colloidal nanoparticles aqueous solution in the electric discharge plasma at atmospheric pressure was investigated. To characterize the colloidal TiO2 nanoparticle solution, used for the coating deposition process, transmission electron microscopy (TEM) was utilized, while scanning electron microscopy (SEM) and optical profilometry were used to investigate the deposited surface layer morphology and quality. Estimation of the deposited film quality and texture was used to confirm that the arc plasma deposition technique can be successfully used as an advanced and easy-to-apply method for coating the metallic implant material surface with the bioactive TiO2 layer which favors the osseointegration process through the improvement of the implant surface properties. The TiO2 coating was successfully deposited using the arc plasma deposition technique and covered the entire surface of the CP-Ti substrate without any signs of coating cracking or detachment.
T2  - Metallurgical and Materials Engineering
T1  - Arc Plasma Deposition of TiO2 Nanoparticles from Colloidal Solution
VL  - 26
IS  - 4
SP  - 341
EP  - 348
DO  - 10.30544/587
ER  - 
@article{
author = "Maksimović, Vesna and Stoiljković, Milovan and Pavkov, Vladimir and Ciganović, Jovan and Cvijović-Alagić, Ivana",
year = "2020",
abstract = "Surface modifications of metallic biomaterials can in great merit, improve the properties of the hard-tissue implants and in that way contribute to the success of the surgical implantation process. Coating deposition stands out as one of the many surface-modifying techniques that can be used to improve implant surface properties and, in turn, induce successful osseointegration. Deposition of the TiO2 layer on the surface of the metallic implants has a great potential to enhance not only their osseointegration ability but also their biocompatibility and corrosion resistance. In the present study, the possibility of successful deposition of the TiO2 layer on the surface of commercially pure titanium (CP-Ti), as the most commonly used metallic implant material, by spraying the colloidal nanoparticles aqueous solution in the electric discharge plasma at atmospheric pressure was investigated. To characterize the colloidal TiO2 nanoparticle solution, used for the coating deposition process, transmission electron microscopy (TEM) was utilized, while scanning electron microscopy (SEM) and optical profilometry were used to investigate the deposited surface layer morphology and quality. Estimation of the deposited film quality and texture was used to confirm that the arc plasma deposition technique can be successfully used as an advanced and easy-to-apply method for coating the metallic implant material surface with the bioactive TiO2 layer which favors the osseointegration process through the improvement of the implant surface properties. The TiO2 coating was successfully deposited using the arc plasma deposition technique and covered the entire surface of the CP-Ti substrate without any signs of coating cracking or detachment.",
journal = "Metallurgical and Materials Engineering",
title = "Arc Plasma Deposition of TiO2 Nanoparticles from Colloidal Solution",
volume = "26",
number = "4",
pages = "341-348",
doi = "10.30544/587"
}
Maksimović, V., Stoiljković, M., Pavkov, V., Ciganović, J.,& Cvijović-Alagić, I.. (2020). Arc Plasma Deposition of TiO2 Nanoparticles from Colloidal Solution. in Metallurgical and Materials Engineering, 26(4), 341-348.
https://doi.org/10.30544/587
Maksimović V, Stoiljković M, Pavkov V, Ciganović J, Cvijović-Alagić I. Arc Plasma Deposition of TiO2 Nanoparticles from Colloidal Solution. in Metallurgical and Materials Engineering. 2020;26(4):341-348.
doi:10.30544/587 .
Maksimović, Vesna, Stoiljković, Milovan, Pavkov, Vladimir, Ciganović, Jovan, Cvijović-Alagić, Ivana, "Arc Plasma Deposition of TiO2 Nanoparticles from Colloidal Solution" in Metallurgical and Materials Engineering, 26, no. 4 (2020):341-348,
https://doi.org/10.30544/587 . .
1

Dextran-coated silver nanoparticles for improved barrier and controlled antimicrobial properties of nanocellulose films used in food packaging

Lazić, Vesna M.; Vivod, Vera; Peršin, Zdenka; Stoiljković, Milovan; Ratnayake, Ishara S.; Ahrenkiel, Phillip S.; Nedeljković, Jovan; Kokol, Vanja

(2020)

TY  - JOUR
AU  - Lazić, Vesna M.
AU  - Vivod, Vera
AU  - Peršin, Zdenka
AU  - Stoiljković, Milovan
AU  - Ratnayake, Ishara S.
AU  - Ahrenkiel, Phillip S.
AU  - Nedeljković, Jovan
AU  - Kokol, Vanja
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9676
AB  - The effect of dextran-coated silver nanoparticles (Ag NPs 12.0 ± 1.9 nm) loading (0−0.42 wt%) on the mechanical, barrier, and antimicrobial properties of thin (50−60 μm) films prepared from cellulose nanofibrils by solvent casting method were studied as eco-friendly and food-preservative packaging materials. The presence of dextran was shown to act not only as a dispersing media for Ag NPs and controlling its release but also as a moisture-resistant sealable additive that, synergetically with reduced oxygen permeability, may preserve the food against bacteria growth. Thus, significantly reduced Oxygen Transmission Rates (from 2.07 to 1.40-0.78 cm3 m−2d−1) and hydrophilicity (from 20.8° to 52.4° for MilliQ water, and from 35-37° to 62-74° for 3 % acetic acid and 0.9 % NaCl simulant solutions), yielding a 99.9 % inhibition of Escherichia coli after five repeated cycles of 24 h exposure to 0.9 % NaCl solution was displayed, supported by a controlled release of Ag+ ions (below the toxicologically harmful threshold, <0.5 mg L-1).
T2  - Food Packaging and Shelf Life
T1  - Dextran-coated silver nanoparticles for improved barrier and controlled antimicrobial properties of nanocellulose films used in food packaging
VL  - 26
SP  - 100575
DO  - 10.1016/j.fpsl.2020.100575
ER  - 
@article{
author = "Lazić, Vesna M. and Vivod, Vera and Peršin, Zdenka and Stoiljković, Milovan and Ratnayake, Ishara S. and Ahrenkiel, Phillip S. and Nedeljković, Jovan and Kokol, Vanja",
year = "2020",
abstract = "The effect of dextran-coated silver nanoparticles (Ag NPs 12.0 ± 1.9 nm) loading (0−0.42 wt%) on the mechanical, barrier, and antimicrobial properties of thin (50−60 μm) films prepared from cellulose nanofibrils by solvent casting method were studied as eco-friendly and food-preservative packaging materials. The presence of dextran was shown to act not only as a dispersing media for Ag NPs and controlling its release but also as a moisture-resistant sealable additive that, synergetically with reduced oxygen permeability, may preserve the food against bacteria growth. Thus, significantly reduced Oxygen Transmission Rates (from 2.07 to 1.40-0.78 cm3 m−2d−1) and hydrophilicity (from 20.8° to 52.4° for MilliQ water, and from 35-37° to 62-74° for 3 % acetic acid and 0.9 % NaCl simulant solutions), yielding a 99.9 % inhibition of Escherichia coli after five repeated cycles of 24 h exposure to 0.9 % NaCl solution was displayed, supported by a controlled release of Ag+ ions (below the toxicologically harmful threshold, <0.5 mg L-1).",
journal = "Food Packaging and Shelf Life",
title = "Dextran-coated silver nanoparticles for improved barrier and controlled antimicrobial properties of nanocellulose films used in food packaging",
volume = "26",
pages = "100575",
doi = "10.1016/j.fpsl.2020.100575"
}
Lazić, V. M., Vivod, V., Peršin, Z., Stoiljković, M., Ratnayake, I. S., Ahrenkiel, P. S., Nedeljković, J.,& Kokol, V.. (2020). Dextran-coated silver nanoparticles for improved barrier and controlled antimicrobial properties of nanocellulose films used in food packaging. in Food Packaging and Shelf Life, 26, 100575.
https://doi.org/10.1016/j.fpsl.2020.100575
Lazić VM, Vivod V, Peršin Z, Stoiljković M, Ratnayake IS, Ahrenkiel PS, Nedeljković J, Kokol V. Dextran-coated silver nanoparticles for improved barrier and controlled antimicrobial properties of nanocellulose films used in food packaging. in Food Packaging and Shelf Life. 2020;26:100575.
doi:10.1016/j.fpsl.2020.100575 .
Lazić, Vesna M., Vivod, Vera, Peršin, Zdenka, Stoiljković, Milovan, Ratnayake, Ishara S., Ahrenkiel, Phillip S., Nedeljković, Jovan, Kokol, Vanja, "Dextran-coated silver nanoparticles for improved barrier and controlled antimicrobial properties of nanocellulose films used in food packaging" in Food Packaging and Shelf Life, 26 (2020):100575,
https://doi.org/10.1016/j.fpsl.2020.100575 . .
47
9
44

Photocatalytic hydrogen evolution over surface-modified titanate nanotubes by 5-aminosalicylic acid decorated with silver nanoparticles

Barbieriková, Zuzana; Lončarević, Davor; Papan, Jelena; Vukoje, Ivana D.; Stoiljković, Milovan; Ahrenkiel, Scott Phillip; Nedeljković, Jovan

(2020)

TY  - JOUR
AU  - Barbieriková, Zuzana
AU  - Lončarević, Davor
AU  - Papan, Jelena
AU  - Vukoje, Ivana D.
AU  - Stoiljković, Milovan
AU  - Ahrenkiel, Scott Phillip
AU  - Nedeljković, Jovan
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9756
AB  - The efficiency of titanate-nanotubes-based photocatalysts towards hydrogen production was studied in the presence of the sacrificial agent, 2-propanol. The highest hydrogen production rate (~120 lmol h 1 g 1 ) was observed over surface-modified titanate nanotubes by 5-amino salicylic acid decorated with nanometer-sized silver nanoparticles. The X-ray diffraction analysis, transmission electron microscopy, nitrogen adsorption–desorption isotherms, and diffuse reflection spectroscopy were applied to characterize the prepared photocatalytic materials. The better photocatalytic performance of inorganic–organic hybrid materials in comparison to the pristine titanate nanotubes is a consequence of their improved light-harvesting ability due to the formation of interfacial charge transfer (ICT) complex, as well as the presence of metallic silver nanoparticles that suppress the recombination of photo-generated charge carriers. The spin trapping EPR experiments under irradiation of prepared photocatalysts with either UV or visible light were used to monitor the appearance of hydroxyl radicals and superoxide radical anions. The generation of superoxide radical anions under visible light irradiation was detected for hybrid materials, but not for the pristine titanate nanotubes. These results are a consequence of enhanced promotion ofelectrons to the conduction band due to extended absorption in visible spectral range in hybrids and support the higher efficiency of hydrogen generation observed for surface-modified titanate nanotubes by 5-amino salicylic acid decorated with silver nanoparticles.
T2  - Advanced Powder Technology
T1  - Photocatalytic hydrogen evolution over surface-modified titanate nanotubes by 5-aminosalicylic acid decorated with silver nanoparticles
VL  - 31
IS  - 12
SP  - 4683
EP  - 4690
DO  - 10.1016/j.apt.2020.11.001
ER  - 
@article{
author = "Barbieriková, Zuzana and Lončarević, Davor and Papan, Jelena and Vukoje, Ivana D. and Stoiljković, Milovan and Ahrenkiel, Scott Phillip and Nedeljković, Jovan",
year = "2020",
abstract = "The efficiency of titanate-nanotubes-based photocatalysts towards hydrogen production was studied in the presence of the sacrificial agent, 2-propanol. The highest hydrogen production rate (~120 lmol h 1 g 1 ) was observed over surface-modified titanate nanotubes by 5-amino salicylic acid decorated with nanometer-sized silver nanoparticles. The X-ray diffraction analysis, transmission electron microscopy, nitrogen adsorption–desorption isotherms, and diffuse reflection spectroscopy were applied to characterize the prepared photocatalytic materials. The better photocatalytic performance of inorganic–organic hybrid materials in comparison to the pristine titanate nanotubes is a consequence of their improved light-harvesting ability due to the formation of interfacial charge transfer (ICT) complex, as well as the presence of metallic silver nanoparticles that suppress the recombination of photo-generated charge carriers. The spin trapping EPR experiments under irradiation of prepared photocatalysts with either UV or visible light were used to monitor the appearance of hydroxyl radicals and superoxide radical anions. The generation of superoxide radical anions under visible light irradiation was detected for hybrid materials, but not for the pristine titanate nanotubes. These results are a consequence of enhanced promotion ofelectrons to the conduction band due to extended absorption in visible spectral range in hybrids and support the higher efficiency of hydrogen generation observed for surface-modified titanate nanotubes by 5-amino salicylic acid decorated with silver nanoparticles.",
journal = "Advanced Powder Technology",
title = "Photocatalytic hydrogen evolution over surface-modified titanate nanotubes by 5-aminosalicylic acid decorated with silver nanoparticles",
volume = "31",
number = "12",
pages = "4683-4690",
doi = "10.1016/j.apt.2020.11.001"
}
Barbieriková, Z., Lončarević, D., Papan, J., Vukoje, I. D., Stoiljković, M., Ahrenkiel, S. P.,& Nedeljković, J.. (2020). Photocatalytic hydrogen evolution over surface-modified titanate nanotubes by 5-aminosalicylic acid decorated with silver nanoparticles. in Advanced Powder Technology, 31(12), 4683-4690.
https://doi.org/10.1016/j.apt.2020.11.001
Barbieriková Z, Lončarević D, Papan J, Vukoje ID, Stoiljković M, Ahrenkiel SP, Nedeljković J. Photocatalytic hydrogen evolution over surface-modified titanate nanotubes by 5-aminosalicylic acid decorated with silver nanoparticles. in Advanced Powder Technology. 2020;31(12):4683-4690.
doi:10.1016/j.apt.2020.11.001 .
Barbieriková, Zuzana, Lončarević, Davor, Papan, Jelena, Vukoje, Ivana D., Stoiljković, Milovan, Ahrenkiel, Scott Phillip, Nedeljković, Jovan, "Photocatalytic hydrogen evolution over surface-modified titanate nanotubes by 5-aminosalicylic acid decorated with silver nanoparticles" in Advanced Powder Technology, 31, no. 12 (2020):4683-4690,
https://doi.org/10.1016/j.apt.2020.11.001 . .
5
1
5

Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior

Vranješ, Mila; Kuljanin-Jakovljević, Jadranka Ž.; Milošević, Milica V.; Ćirić-Marjanović, Gordana N.; Stoiljković, Milovan; Konstantinović, Zorica; Pavlović, Vladimir B.; Milivojević, Dušan; Šaponjić, Zoran

(2019)

TY  - JOUR
AU  - Vranješ, Mila
AU  - Kuljanin-Jakovljević, Jadranka Ž.
AU  - Milošević, Milica V.
AU  - Ćirić-Marjanović, Gordana N.
AU  - Stoiljković, Milovan
AU  - Konstantinović, Zorica
AU  - Pavlović, Vladimir B.
AU  - Milivojević, Dušan
AU  - Šaponjić, Zoran
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8358
AB  - Hydrothermal synthesis of Mn2+ doped titanate nanotubes (TNTs), which exhibited room temperature ferromagnetism (RTFM), is reported. Dispersions of 1 and 5 at.% Mn2+ doped anatase TiO2 nanocrystals were used as precursors. Size and shape of Mn2+ doped TNTs and precursor nanocrystals were studied by transmission electron microscopy (TEM). The relatively uniform size distribution of transverse dimension of nanotubes of about 10 nm was observed while their lengths varied up to few hundred nanometers. The X-Ray Diffraction (XRD) analysis and Raman spectroscopy of resultant powder confirmed the hydrogen dititanate (H2Ti2O5 x H2O) crystal phase of Mn2+ doped TNTs with the presence of small amount of sodium titanates. Electron paramagnetic resonance (EPR) experiments were performed to probe the local atomic and electronic structure of Mn in the nanotubes. Room temperature ferromagnetic ordering with saturation magnetic moment (Ms) in the range of 0.6–1.5 μB per Mn atom was observed. © 2019 Elsevier Masson SAS
T2  - Solid State Sciences
T1  - Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior
VL  - 94
SP  - 155
EP  - 161
DO  - 10.1016/j.solidstatesciences.2019.06.008
ER  - 
@article{
author = "Vranješ, Mila and Kuljanin-Jakovljević, Jadranka Ž. and Milošević, Milica V. and Ćirić-Marjanović, Gordana N. and Stoiljković, Milovan and Konstantinović, Zorica and Pavlović, Vladimir B. and Milivojević, Dušan and Šaponjić, Zoran",
year = "2019",
abstract = "Hydrothermal synthesis of Mn2+ doped titanate nanotubes (TNTs), which exhibited room temperature ferromagnetism (RTFM), is reported. Dispersions of 1 and 5 at.% Mn2+ doped anatase TiO2 nanocrystals were used as precursors. Size and shape of Mn2+ doped TNTs and precursor nanocrystals were studied by transmission electron microscopy (TEM). The relatively uniform size distribution of transverse dimension of nanotubes of about 10 nm was observed while their lengths varied up to few hundred nanometers. The X-Ray Diffraction (XRD) analysis and Raman spectroscopy of resultant powder confirmed the hydrogen dititanate (H2Ti2O5 x H2O) crystal phase of Mn2+ doped TNTs with the presence of small amount of sodium titanates. Electron paramagnetic resonance (EPR) experiments were performed to probe the local atomic and electronic structure of Mn in the nanotubes. Room temperature ferromagnetic ordering with saturation magnetic moment (Ms) in the range of 0.6–1.5 μB per Mn atom was observed. © 2019 Elsevier Masson SAS",
journal = "Solid State Sciences",
title = "Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior",
volume = "94",
pages = "155-161",
doi = "10.1016/j.solidstatesciences.2019.06.008"
}
Vranješ, M., Kuljanin-Jakovljević, J. Ž., Milošević, M. V., Ćirić-Marjanović, G. N., Stoiljković, M., Konstantinović, Z., Pavlović, V. B., Milivojević, D.,& Šaponjić, Z.. (2019). Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior. in Solid State Sciences, 94, 155-161.
https://doi.org/10.1016/j.solidstatesciences.2019.06.008
Vranješ M, Kuljanin-Jakovljević JŽ, Milošević MV, Ćirić-Marjanović GN, Stoiljković M, Konstantinović Z, Pavlović VB, Milivojević D, Šaponjić Z. Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior. in Solid State Sciences. 2019;94:155-161.
doi:10.1016/j.solidstatesciences.2019.06.008 .
Vranješ, Mila, Kuljanin-Jakovljević, Jadranka Ž., Milošević, Milica V., Ćirić-Marjanović, Gordana N., Stoiljković, Milovan, Konstantinović, Zorica, Pavlović, Vladimir B., Milivojević, Dušan, Šaponjić, Zoran, "Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior" in Solid State Sciences, 94 (2019):155-161,
https://doi.org/10.1016/j.solidstatesciences.2019.06.008 . .
13
5
14

Antimicrobial activity of silver nanoparticles supported by magnetite

Lazić, Vesna M.; Mihajlovski, Katarina ; Lazić, Vesna M.; Illés, Erzsébet; Stoiljković, Milovan; Ahrenkiel, Scott Phillip; Nedeljković, Jovan

(2019)

TY  - JOUR
AU  - Lazić, Vesna M.
AU  - Mihajlovski, Katarina 
AU  - Lazić, Vesna M.
AU  - Illés, Erzsébet
AU  - Stoiljković, Milovan
AU  - Ahrenkiel, Scott Phillip
AU  - Nedeljković, Jovan
PY  - 2019
UR  - https://onlinelibrary.wiley.com/doi/abs/10.1002/slct.201900628
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8162
AB  - Antibacterial and antifungal ability of silver nanoparticles (Ag NPs) supported by functionalized magnetite (Fe 3 O 4 ) with 5-aminosalicylic acid (5-ASA) was tested against Gram-negative bacteria Escherichia coli, Gram-positive bacteria Staphylococcus aureus and yeast Candida albicans. Characterization of materials including transmission electron microscopy, X-ray diffraction analysis, and inductively coupled plasma optic emission spectroscopy technique followed each step during the course of nanocomposite preparation. The synthesized powder consists of 30–50 nm in size silver particles surrounded by clusters of smaller (∼10 nm) Fe 3 O 4 particles. The content of silver in the nanocomposite powder was found to be slightly above 40 wt.–%. Concentration-dependent and time-dependent bacterial reduction measurements in dark indicated that use of Ag NPs leads to the complete reduction of E. coli and S. aureus even at the concentration level of silver as low as 40 μg/mL. However, the negligible antifungal ability of synthesized nanocomposite was found against yeast C. albicans in the entire investigated concentration range (0.1-2.0 mg/mL of the nanocomposite, i. e., 40–800 μg/mL of silver). Complete inactivation of E. coli and S. aureus was achieved in five repeated cycles indicated that synthesized nanocomposite can perform under long-run working conditions. From the technological point of view, magnetic separation is the additional advantage of synthesized nanocomposite for potential use as an antibacterial agent. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - ChemistrySelect
T1  - Antimicrobial activity of silver nanoparticles supported by magnetite
VL  - 4
IS  - 14
SP  - 4018
EP  - 4024
DO  - 10.1002/slct.201900628
ER  - 
@article{
author = "Lazić, Vesna M. and Mihajlovski, Katarina  and Lazić, Vesna M. and Illés, Erzsébet and Stoiljković, Milovan and Ahrenkiel, Scott Phillip and Nedeljković, Jovan",
year = "2019",
abstract = "Antibacterial and antifungal ability of silver nanoparticles (Ag NPs) supported by functionalized magnetite (Fe 3 O 4 ) with 5-aminosalicylic acid (5-ASA) was tested against Gram-negative bacteria Escherichia coli, Gram-positive bacteria Staphylococcus aureus and yeast Candida albicans. Characterization of materials including transmission electron microscopy, X-ray diffraction analysis, and inductively coupled plasma optic emission spectroscopy technique followed each step during the course of nanocomposite preparation. The synthesized powder consists of 30–50 nm in size silver particles surrounded by clusters of smaller (∼10 nm) Fe 3 O 4 particles. The content of silver in the nanocomposite powder was found to be slightly above 40 wt.–%. Concentration-dependent and time-dependent bacterial reduction measurements in dark indicated that use of Ag NPs leads to the complete reduction of E. coli and S. aureus even at the concentration level of silver as low as 40 μg/mL. However, the negligible antifungal ability of synthesized nanocomposite was found against yeast C. albicans in the entire investigated concentration range (0.1-2.0 mg/mL of the nanocomposite, i. e., 40–800 μg/mL of silver). Complete inactivation of E. coli and S. aureus was achieved in five repeated cycles indicated that synthesized nanocomposite can perform under long-run working conditions. From the technological point of view, magnetic separation is the additional advantage of synthesized nanocomposite for potential use as an antibacterial agent. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "ChemistrySelect",
title = "Antimicrobial activity of silver nanoparticles supported by magnetite",
volume = "4",
number = "14",
pages = "4018-4024",
doi = "10.1002/slct.201900628"
}
Lazić, V. M., Mihajlovski, K., Lazić, V. M., Illés, E., Stoiljković, M., Ahrenkiel, S. P.,& Nedeljković, J.. (2019). Antimicrobial activity of silver nanoparticles supported by magnetite. in ChemistrySelect, 4(14), 4018-4024.
https://doi.org/10.1002/slct.201900628
Lazić VM, Mihajlovski K, Lazić VM, Illés E, Stoiljković M, Ahrenkiel SP, Nedeljković J. Antimicrobial activity of silver nanoparticles supported by magnetite. in ChemistrySelect. 2019;4(14):4018-4024.
doi:10.1002/slct.201900628 .
Lazić, Vesna M., Mihajlovski, Katarina , Lazić, Vesna M., Illés, Erzsébet, Stoiljković, Milovan, Ahrenkiel, Scott Phillip, Nedeljković, Jovan, "Antimicrobial activity of silver nanoparticles supported by magnetite" in ChemistrySelect, 4, no. 14 (2019):4018-4024,
https://doi.org/10.1002/slct.201900628 . .
1
11
5
11

Multi-year project: Explosive trace detection sensor (extras)

Palucci, A; Colao, F; Stoiljković, Milovan; Kolobrodov, V; Boonaker, B; Schnürer, F; Stifini, C; Carnevale, L; Cassioli, L C L; De Muro, S; Antuofermo, P

(2019)

TY  - JOUR
AU  - Palucci, A
AU  - Colao, F
AU  - Stoiljković, Milovan
AU  - Kolobrodov, V
AU  - Boonaker, B
AU  - Schnürer, F
AU  - Stifini, C
AU  - Carnevale, L
AU  - Cassioli, L C L
AU  - De Muro, S
AU  - Antuofermo, P
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8939
T2  - NATO Science for Peace and Security Series B: Physics and Biophysics
T1  - Multi-year project: Explosive trace detection sensor (extras)
SP  - 63
EP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8939
ER  - 
@article{
author = "Palucci, A and Colao, F and Stoiljković, Milovan and Kolobrodov, V and Boonaker, B and Schnürer, F and Stifini, C and Carnevale, L and Cassioli, L C L and De Muro, S and Antuofermo, P",
year = "2019",
journal = "NATO Science for Peace and Security Series B: Physics and Biophysics",
title = "Multi-year project: Explosive trace detection sensor (extras)",
pages = "63-77",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8939"
}
Palucci, A., Colao, F., Stoiljković, M., Kolobrodov, V., Boonaker, B., Schnürer, F., Stifini, C., Carnevale, L., Cassioli, L. C. L., De Muro, S.,& Antuofermo, P.. (2019). Multi-year project: Explosive trace detection sensor (extras). in NATO Science for Peace and Security Series B: Physics and Biophysics, 63-77.
https://hdl.handle.net/21.15107/rcub_vinar_8939
Palucci A, Colao F, Stoiljković M, Kolobrodov V, Boonaker B, Schnürer F, Stifini C, Carnevale L, Cassioli LCL, De Muro S, Antuofermo P. Multi-year project: Explosive trace detection sensor (extras). in NATO Science for Peace and Security Series B: Physics and Biophysics. 2019;:63-77.
https://hdl.handle.net/21.15107/rcub_vinar_8939 .
Palucci, A, Colao, F, Stoiljković, Milovan, Kolobrodov, V, Boonaker, B, Schnürer, F, Stifini, C, Carnevale, L, Cassioli, L C L, De Muro, S, Antuofermo, P, "Multi-year project: Explosive trace detection sensor (extras)" in NATO Science for Peace and Security Series B: Physics and Biophysics (2019):63-77,
https://hdl.handle.net/21.15107/rcub_vinar_8939 .