Jacimovic, Zeljko K.

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441c1063-36e2-4b6a-bfd1-b48e54486c64
  • Jacimovic, Zeljko K. (9)
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Author's Bibliography

Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds

Jacimovic, Zeljko K.; Giester, Gerald; Kosovic, Milica; Bogdanović, Goran A.; Novaković, Slađana B.; Leovac, Vukadin M.; Latinović, Nedeljko; Hollo, Berta Barta; Szecsenyi, Katalin Meszaros

(2017)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Giester, Gerald
AU  - Kosovic, Milica
AU  - Bogdanović, Goran A.
AU  - Novaković, Slađana B.
AU  - Leovac, Vukadin M.
AU  - Latinović, Nedeljko
AU  - Hollo, Berta Barta
AU  - Szecsenyi, Katalin Meszaros
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1428
AB  - New nickel(II) and copper(II) coordination compounds were synthesized by the reaction of N-(benzyloxycarbonyl)-1H-pyrazole-1-carboxamidine ligand (HL) with Ni(II) and Cu(II) acetate in methanolic solution. The crystal and molecular structures of the complexes as well as those of the ligand were determined by single-crystal X-ray structure analysis. The octahedral surrounding around the metal centers in the isostructural complexes [ML2(MeOH)(2)], M = Ni(II), Cu(II), MeOH = methanol, is established by the bidentate coordination of two ligand molecules through the pyrazole nitrogen and the deprotonated nitrogen atom of the carboxamidine group along with the oxygen atoms from two MeOH molecules. Despite that the molecular structure of the complexes was determined by X-ray structure analysis, in the FT-IR spectra of the compounds the characteristic bands for MeOH were missing. By coupled TG-MS measurements, it was found that compounds during the transport and storage exchanged MeOH by water molecules. The amount of the water was calculated on the basis of thermogravimetric data. The antifungal activity of the compounds was tested against fungi Ph. viticola and B. dothidea and compared to that of a commercial fungicide. Depending on the fungi and on the structure, the compounds showed different, but somewhat lower activity than the commercial fungicide.
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds
VL  - 127
IS  - 2
SP  - 1501
EP  - 1509
DO  - 10.1007/s10973-016-5549-9
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Giester, Gerald and Kosovic, Milica and Bogdanović, Goran A. and Novaković, Slađana B. and Leovac, Vukadin M. and Latinović, Nedeljko and Hollo, Berta Barta and Szecsenyi, Katalin Meszaros",
year = "2017",
abstract = "New nickel(II) and copper(II) coordination compounds were synthesized by the reaction of N-(benzyloxycarbonyl)-1H-pyrazole-1-carboxamidine ligand (HL) with Ni(II) and Cu(II) acetate in methanolic solution. The crystal and molecular structures of the complexes as well as those of the ligand were determined by single-crystal X-ray structure analysis. The octahedral surrounding around the metal centers in the isostructural complexes [ML2(MeOH)(2)], M = Ni(II), Cu(II), MeOH = methanol, is established by the bidentate coordination of two ligand molecules through the pyrazole nitrogen and the deprotonated nitrogen atom of the carboxamidine group along with the oxygen atoms from two MeOH molecules. Despite that the molecular structure of the complexes was determined by X-ray structure analysis, in the FT-IR spectra of the compounds the characteristic bands for MeOH were missing. By coupled TG-MS measurements, it was found that compounds during the transport and storage exchanged MeOH by water molecules. The amount of the water was calculated on the basis of thermogravimetric data. The antifungal activity of the compounds was tested against fungi Ph. viticola and B. dothidea and compared to that of a commercial fungicide. Depending on the fungi and on the structure, the compounds showed different, but somewhat lower activity than the commercial fungicide.",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds",
volume = "127",
number = "2",
pages = "1501-1509",
doi = "10.1007/s10973-016-5549-9"
}
Jacimovic, Z. K., Giester, G., Kosovic, M., Bogdanović, G. A., Novaković, S. B., Leovac, V. M., Latinović, N., Hollo, B. B.,& Szecsenyi, K. M.. (2017). Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds. in Journal of Thermal Analysis and Calorimetry, 127(2), 1501-1509.
https://doi.org/10.1007/s10973-016-5549-9
Jacimovic ZK, Giester G, Kosovic M, Bogdanović GA, Novaković SB, Leovac VM, Latinović N, Hollo BB, Szecsenyi KM. Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds. in Journal of Thermal Analysis and Calorimetry. 2017;127(2):1501-1509.
doi:10.1007/s10973-016-5549-9 .
Jacimovic, Zeljko K., Giester, Gerald, Kosovic, Milica, Bogdanović, Goran A., Novaković, Slađana B., Leovac, Vukadin M., Latinović, Nedeljko, Hollo, Berta Barta, Szecsenyi, Katalin Meszaros, "Pyrazole-type complexes with Ni(II) and Cu(II) Solvent exchange reactions in coordination compounds" in Journal of Thermal Analysis and Calorimetry, 127, no. 2 (2017):1501-1509,
https://doi.org/10.1007/s10973-016-5549-9 . .
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The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4

Jacimovic, Zeljko K.; Kosovic, Milica; Bogdanović, Goran A.; Novaković, Slađana B.; Giester, Gerald; Bigovie, Miljan

(2017)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Kosovic, Milica
AU  - Bogdanović, Goran A.
AU  - Novaković, Slađana B.
AU  - Giester, Gerald
AU  - Bigovie, Miljan
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1639
AB  - C13H10F3N3O4, triclinic, P (1) over bar (no. 2), a = 7.0524(14) angstrom, b = 7.8044(16) angstrom, c = 12.954(3) angstrom, alpha = 97.93(3)degrees, beta = 96.29(3)degrees, gamma = 100.11(3)degrees, V = 688.6(3) angstrom(3), Z = 2, R-gt(F) = 0.0478, wR(ref)(F-2) = 0.1140, T = 200 K.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4
VL  - 232
IS  - 4
SP  - 651
EP  - 653
DO  - 10.1515/ncrs-2016-0393
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Kosovic, Milica and Bogdanović, Goran A. and Novaković, Slađana B. and Giester, Gerald and Bigovie, Miljan",
year = "2017",
abstract = "C13H10F3N3O4, triclinic, P (1) over bar (no. 2), a = 7.0524(14) angstrom, b = 7.8044(16) angstrom, c = 12.954(3) angstrom, alpha = 97.93(3)degrees, beta = 96.29(3)degrees, gamma = 100.11(3)degrees, V = 688.6(3) angstrom(3), Z = 2, R-gt(F) = 0.0478, wR(ref)(F-2) = 0.1140, T = 200 K.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4",
volume = "232",
number = "4",
pages = "651-653",
doi = "10.1515/ncrs-2016-0393"
}
Jacimovic, Z. K., Kosovic, M., Bogdanović, G. A., Novaković, S. B., Giester, G.,& Bigovie, M.. (2017). The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4. in Zeitschrift fur Kristallographie = New Crystal Structures, 232(4), 651-653.
https://doi.org/10.1515/ncrs-2016-0393
Jacimovic ZK, Kosovic M, Bogdanović GA, Novaković SB, Giester G, Bigovie M. The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4. in Zeitschrift fur Kristallographie = New Crystal Structures. 2017;232(4):651-653.
doi:10.1515/ncrs-2016-0393 .
Jacimovic, Zeljko K., Kosovic, Milica, Bogdanović, Goran A., Novaković, Slađana B., Giester, Gerald, Bigovie, Miljan, "The crystal structure of ethyl 1-(4-nitropheny)-5-(trifluoromethy)-1H-pyrazole-4-carboxylate, C13H10F3N3O4" in Zeitschrift fur Kristallographie = New Crystal Structures, 232, no. 4 (2017):651-653,
https://doi.org/10.1515/ncrs-2016-0393 . .
2
1
2

Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O

Jacimovic, Zeljko K.; Kosovic, Milica; Novaković, Slađana B.; Bogdanović, Goran A.; Giester, Gerald; Kastratović, Vlatko

(2017)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Kosovic, Milica
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Giester, Gerald
AU  - Kastratović, Vlatko
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1602
AB  - C9H7BrN2O, triclinic, C2/c (no. 15), a = 16.255(3) angstrom, b = 4.4119(9) angstrom, c = 25.923(5) angstrom, beta = 107.99(3)degrees, V = 1768.2(7) angstrom(3), Z = 8, R-gt(F) = 0.0450, wR(ref)(F-2) = 0.0960, T= 150 K.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O
VL  - 232
IS  - 3
SP  - 507
EP  - 509
DO  - 10.1515/ncrs-2016-0392
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Kosovic, Milica and Novaković, Slađana B. and Bogdanović, Goran A. and Giester, Gerald and Kastratović, Vlatko",
year = "2017",
abstract = "C9H7BrN2O, triclinic, C2/c (no. 15), a = 16.255(3) angstrom, b = 4.4119(9) angstrom, c = 25.923(5) angstrom, beta = 107.99(3)degrees, V = 1768.2(7) angstrom(3), Z = 8, R-gt(F) = 0.0450, wR(ref)(F-2) = 0.0960, T= 150 K.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O",
volume = "232",
number = "3",
pages = "507-509",
doi = "10.1515/ncrs-2016-0392"
}
Jacimovic, Z. K., Kosovic, M., Novaković, S. B., Bogdanović, G. A., Giester, G.,& Kastratović, V.. (2017). Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O. in Zeitschrift fur Kristallographie = New Crystal Structures, 232(3), 507-509.
https://doi.org/10.1515/ncrs-2016-0392
Jacimovic ZK, Kosovic M, Novaković SB, Bogdanović GA, Giester G, Kastratović V. Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O. in Zeitschrift fur Kristallographie = New Crystal Structures. 2017;232(3):507-509.
doi:10.1515/ncrs-2016-0392 .
Jacimovic, Zeljko K., Kosovic, Milica, Novaković, Slađana B., Bogdanović, Goran A., Giester, Gerald, Kastratović, Vlatko, "Crystal structure of 4-bromo-2-(1H-pyrazol-3-yl)phenol, C9H7BrN2O" in Zeitschrift fur Kristallographie = New Crystal Structures, 232, no. 3 (2017):507-509,
https://doi.org/10.1515/ncrs-2016-0392 . .
1
1
1

Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand

Jacimovic, Zeljko K.; Kosovic, Milica; Novaković, Slađana B.; Giester, Gerald; Radović, Ana

(2015)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Kosovic, Milica
AU  - Novaković, Slađana B.
AU  - Giester, Gerald
AU  - Radović, Ana
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/695
AB  - In the reaction of 1,3-dimethylpyrazole-5-carboxylic acid (HL) with M(OAc)(2)center dot 4H(2)O, (M = Cu or Co), two novel complexes were prepared, the square-planar [CuL2(H2O)(2)] and the octahedral [CoL2(MeOH)(4)]. The crystal structures were determined by single-crystal X-ray diffraction. In both complexes, the deprotonated acid displays monodentate coordination to the metal ions. According to the results of a CSD survey, this is the first structural report on the metal complexes with an N-1-substituted pyrazole-5-carboxylic ligand.
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand
VL  - 80
IS  - 7
SP  - 867
EP  - 875
DO  - 10.2298/JSC140722009J
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Kosovic, Milica and Novaković, Slađana B. and Giester, Gerald and Radović, Ana",
year = "2015",
abstract = "In the reaction of 1,3-dimethylpyrazole-5-carboxylic acid (HL) with M(OAc)(2)center dot 4H(2)O, (M = Cu or Co), two novel complexes were prepared, the square-planar [CuL2(H2O)(2)] and the octahedral [CoL2(MeOH)(4)]. The crystal structures were determined by single-crystal X-ray diffraction. In both complexes, the deprotonated acid displays monodentate coordination to the metal ions. According to the results of a CSD survey, this is the first structural report on the metal complexes with an N-1-substituted pyrazole-5-carboxylic ligand.",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand",
volume = "80",
number = "7",
pages = "867-875",
doi = "10.2298/JSC140722009J"
}
Jacimovic, Z. K., Kosovic, M., Novaković, S. B., Giester, G.,& Radović, A.. (2015). Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand. in Journal of the Serbian Chemical Society, 80(7), 867-875.
https://doi.org/10.2298/JSC140722009J
Jacimovic ZK, Kosovic M, Novaković SB, Giester G, Radović A. Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand. in Journal of the Serbian Chemical Society. 2015;80(7):867-875.
doi:10.2298/JSC140722009J .
Jacimovic, Zeljko K., Kosovic, Milica, Novaković, Slađana B., Giester, Gerald, Radović, Ana, "Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand" in Journal of the Serbian Chemical Society, 80, no. 7 (2015):867-875,
https://doi.org/10.2298/JSC140722009J . .
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5

Crystal structure of chlorido-tris(3-amino-5-phenyl-1H-pyrazole-N-2)zinc(II) chloride, [ZnCl(C9H9N3)(3)]Cl

Jacimovic, Zeljko K.; Novaković, Slađana B.; Bogdanović, Goran A.; Belosevic, Svetlana; Jokic, Anja; Leovac, Vukadin M.

(2011)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Belosevic, Svetlana
AU  - Jokic, Anja
AU  - Leovac, Vukadin M.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4532
AB  - C27H27Cl2N9Zn, tetragonal, P (4) over bar2(1)c (no. 114), a = 17.522(2) angstrom, C = 18.583(3) angstrom, V= 5705.4 angstrom(3), Z = 8, R-gt(F) = 0.040, wR(ref)(F-2) = 0.114, T = 293 K.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - Crystal structure of chlorido-tris(3-amino-5-phenyl-1H-pyrazole-N-2)zinc(II) chloride, [ZnCl(C9H9N3)(3)]Cl
VL  - 226
IS  - 3
SP  - 397
EP  - 399
DO  - 10.1524/ncrs.2011.0178
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Novaković, Slađana B. and Bogdanović, Goran A. and Belosevic, Svetlana and Jokic, Anja and Leovac, Vukadin M.",
year = "2011",
abstract = "C27H27Cl2N9Zn, tetragonal, P (4) over bar2(1)c (no. 114), a = 17.522(2) angstrom, C = 18.583(3) angstrom, V= 5705.4 angstrom(3), Z = 8, R-gt(F) = 0.040, wR(ref)(F-2) = 0.114, T = 293 K.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "Crystal structure of chlorido-tris(3-amino-5-phenyl-1H-pyrazole-N-2)zinc(II) chloride, [ZnCl(C9H9N3)(3)]Cl",
volume = "226",
number = "3",
pages = "397-399",
doi = "10.1524/ncrs.2011.0178"
}
Jacimovic, Z. K., Novaković, S. B., Bogdanović, G. A., Belosevic, S., Jokic, A.,& Leovac, V. M.. (2011). Crystal structure of chlorido-tris(3-amino-5-phenyl-1H-pyrazole-N-2)zinc(II) chloride, [ZnCl(C9H9N3)(3)]Cl. in Zeitschrift fur Kristallographie = New Crystal Structures, 226(3), 397-399.
https://doi.org/10.1524/ncrs.2011.0178
Jacimovic ZK, Novaković SB, Bogdanović GA, Belosevic S, Jokic A, Leovac VM. Crystal structure of chlorido-tris(3-amino-5-phenyl-1H-pyrazole-N-2)zinc(II) chloride, [ZnCl(C9H9N3)(3)]Cl. in Zeitschrift fur Kristallographie = New Crystal Structures. 2011;226(3):397-399.
doi:10.1524/ncrs.2011.0178 .
Jacimovic, Zeljko K., Novaković, Slađana B., Bogdanović, Goran A., Belosevic, Svetlana, Jokic, Anja, Leovac, Vukadin M., "Crystal structure of chlorido-tris(3-amino-5-phenyl-1H-pyrazole-N-2)zinc(II) chloride, [ZnCl(C9H9N3)(3)]Cl" in Zeitschrift fur Kristallographie = New Crystal Structures, 226, no. 3 (2011):397-399,
https://doi.org/10.1524/ncrs.2011.0178 . .
1
1
1

Crystal structure of dicholoro-(3,5-dimethyl-1H-pyrazole-1-carboxamidine-N,N )copper(II), Cu(C6H10N4)Cl-2

Jacimovic, Zeljko K.; Leovac, Vukadin M.; Francuski, Đorđe D.; Draskovic, Bojana M.; Bogdanović, Goran A.

(2009)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Leovac, Vukadin M.
AU  - Francuski, Đorđe D.
AU  - Draskovic, Bojana M.
AU  - Bogdanović, Goran A.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3882
AB  - C6H10Cl2CuN4, monoclinic, P2(1)/n (no. 14), a = 7.316(2) angstrom b = 16.002(2) angstrom, c = 9.202(6) angstrom, beta = 113.15 (2)degrees, V = 990.6 angstrom(3), Z = 4, R-gt(F) = 0.054, wR(ref)(F-2) = 0.125, T = 293 K.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - Crystal structure of dicholoro-(3,5-dimethyl-1H-pyrazole-1-carboxamidine-N,N )copper(II), Cu(C6H10N4)Cl-2
VL  - 224
IS  - 4
SP  - 569
EP  - 570
DO  - 10.1524/ncrs.2009.0249
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Leovac, Vukadin M. and Francuski, Đorđe D. and Draskovic, Bojana M. and Bogdanović, Goran A.",
year = "2009",
abstract = "C6H10Cl2CuN4, monoclinic, P2(1)/n (no. 14), a = 7.316(2) angstrom b = 16.002(2) angstrom, c = 9.202(6) angstrom, beta = 113.15 (2)degrees, V = 990.6 angstrom(3), Z = 4, R-gt(F) = 0.054, wR(ref)(F-2) = 0.125, T = 293 K.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "Crystal structure of dicholoro-(3,5-dimethyl-1H-pyrazole-1-carboxamidine-N,N )copper(II), Cu(C6H10N4)Cl-2",
volume = "224",
number = "4",
pages = "569-570",
doi = "10.1524/ncrs.2009.0249"
}
Jacimovic, Z. K., Leovac, V. M., Francuski, Đ. D., Draskovic, B. M.,& Bogdanović, G. A.. (2009). Crystal structure of dicholoro-(3,5-dimethyl-1H-pyrazole-1-carboxamidine-N,N )copper(II), Cu(C6H10N4)Cl-2. in Zeitschrift fur Kristallographie = New Crystal Structures, 224(4), 569-570.
https://doi.org/10.1524/ncrs.2009.0249
Jacimovic ZK, Leovac VM, Francuski ĐD, Draskovic BM, Bogdanović GA. Crystal structure of dicholoro-(3,5-dimethyl-1H-pyrazole-1-carboxamidine-N,N )copper(II), Cu(C6H10N4)Cl-2. in Zeitschrift fur Kristallographie = New Crystal Structures. 2009;224(4):569-570.
doi:10.1524/ncrs.2009.0249 .
Jacimovic, Zeljko K., Leovac, Vukadin M., Francuski, Đorđe D., Draskovic, Bojana M., Bogdanović, Goran A., "Crystal structure of dicholoro-(3,5-dimethyl-1H-pyrazole-1-carboxamidine-N,N )copper(II), Cu(C6H10N4)Cl-2" in Zeitschrift fur Kristallographie = New Crystal Structures, 224, no. 4 (2009):569-570,
https://doi.org/10.1524/ncrs.2009.0249 . .
1
1

Transition metal complexes with pyrazole-based ligands. Part 29. Reactions of zinc(II) and mercury(II) thiocyanate with 4-acetyl-3-amino-5-methylpyrazole

Jacimovic, Zeljko K.; Bogdanović, Goran A.; Hollo, Berta; Leovac, Vukadin M.; Szecsenyi, Katalin Meszaros

(2009)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Bogdanović, Goran A.
AU  - Hollo, Berta
AU  - Leovac, Vukadin M.
AU  - Szecsenyi, Katalin Meszaros
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3843
AB  - The work is concerned with the crystal and molecular structures of zinc(II) and mercury(II) complexes with 4-acetyl-3-amino-5-methylpyrazole (aamp) of the coordination formulae [Zn(NCS)(2)(aaMP)(2)] and (HaaMP)(2)[Hg(SCN)(4)]. The zinc(II) complex was obtained by the reaction of a warm methanolic solution of aamp with a mixture of zinc(II) nitrate and ammonium thiocyanate, whereas the mercury(II) complex was prepared by the reaction of a warm methanolic solution of aamp and a warm, slightly acidified aqueous solution of [Hg(SCN)(4)](2-). Both complexes have a tetrahedral geometry, which in the case of zinc complex is formed by monodentate coordination of two aamp molecules and two isothiocyanate groups. The Zn(II) and Hg(II) atoms have significantly deformed coordination geometry. In both crystal structures the pyrazole derivative has a planar form, probably stabilized by an intramolecular N-H center dot center dot center dot O hydrogen bond. Apart from the X-ray structural analysis, the isolated complexes were characterized by elemental analysis, IR spectroscopy, conductometric measurements and thermal analysis.
T2  - Journal of the Serbian Chemical Society
T1  - Transition metal complexes with pyrazole-based ligands. Part 29. Reactions of zinc(II) and mercury(II) thiocyanate with 4-acetyl-3-amino-5-methylpyrazole
VL  - 74
IS  - 11
SP  - 1259
EP  - 1271
DO  - 10.2298/JSC0911259J
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Bogdanović, Goran A. and Hollo, Berta and Leovac, Vukadin M. and Szecsenyi, Katalin Meszaros",
year = "2009",
abstract = "The work is concerned with the crystal and molecular structures of zinc(II) and mercury(II) complexes with 4-acetyl-3-amino-5-methylpyrazole (aamp) of the coordination formulae [Zn(NCS)(2)(aaMP)(2)] and (HaaMP)(2)[Hg(SCN)(4)]. The zinc(II) complex was obtained by the reaction of a warm methanolic solution of aamp with a mixture of zinc(II) nitrate and ammonium thiocyanate, whereas the mercury(II) complex was prepared by the reaction of a warm methanolic solution of aamp and a warm, slightly acidified aqueous solution of [Hg(SCN)(4)](2-). Both complexes have a tetrahedral geometry, which in the case of zinc complex is formed by monodentate coordination of two aamp molecules and two isothiocyanate groups. The Zn(II) and Hg(II) atoms have significantly deformed coordination geometry. In both crystal structures the pyrazole derivative has a planar form, probably stabilized by an intramolecular N-H center dot center dot center dot O hydrogen bond. Apart from the X-ray structural analysis, the isolated complexes were characterized by elemental analysis, IR spectroscopy, conductometric measurements and thermal analysis.",
journal = "Journal of the Serbian Chemical Society",
title = "Transition metal complexes with pyrazole-based ligands. Part 29. Reactions of zinc(II) and mercury(II) thiocyanate with 4-acetyl-3-amino-5-methylpyrazole",
volume = "74",
number = "11",
pages = "1259-1271",
doi = "10.2298/JSC0911259J"
}
Jacimovic, Z. K., Bogdanović, G. A., Hollo, B., Leovac, V. M.,& Szecsenyi, K. M.. (2009). Transition metal complexes with pyrazole-based ligands. Part 29. Reactions of zinc(II) and mercury(II) thiocyanate with 4-acetyl-3-amino-5-methylpyrazole. in Journal of the Serbian Chemical Society, 74(11), 1259-1271.
https://doi.org/10.2298/JSC0911259J
Jacimovic ZK, Bogdanović GA, Hollo B, Leovac VM, Szecsenyi KM. Transition metal complexes with pyrazole-based ligands. Part 29. Reactions of zinc(II) and mercury(II) thiocyanate with 4-acetyl-3-amino-5-methylpyrazole. in Journal of the Serbian Chemical Society. 2009;74(11):1259-1271.
doi:10.2298/JSC0911259J .
Jacimovic, Zeljko K., Bogdanović, Goran A., Hollo, Berta, Leovac, Vukadin M., Szecsenyi, Katalin Meszaros, "Transition metal complexes with pyrazole-based ligands. Part 29. Reactions of zinc(II) and mercury(II) thiocyanate with 4-acetyl-3-amino-5-methylpyrazole" in Journal of the Serbian Chemical Society, 74, no. 11 (2009):1259-1271,
https://doi.org/10.2298/JSC0911259J . .
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Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH

Jacimovic, Zeljko K.; Radović, Ana; Leovac, Vukadin M.; Tomić, Zoran D.; Radosavjević Evans, Ivana

(2007)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Radović, Ana
AU  - Leovac, Vukadin M.
AU  - Tomić, Zoran D.
AU  - Radosavjević Evans, Ivana
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3397
AB  - C30H48Cl2N14Ni2O2S6, monoclinic, P12/c1 (no. 14), a = 12.0407(7) angstrom,k, b = 11.8861(6) angstrom, c = 15.7389(9) angstrom, beta = 93.904(1)degrees, V = 2247.3 angstrom(3) Z = 2, R-gt(F) = 0.032, wR(ref) f(F-2) = 0.069, T = 120.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH
VL  - 222
IS  - 4
SP  - 430
EP  - 432
DO  - 10.1524/ncrs.2007.0182
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Radović, Ana and Leovac, Vukadin M. and Tomić, Zoran D. and Radosavjević Evans, Ivana",
year = "2007",
abstract = "C30H48Cl2N14Ni2O2S6, monoclinic, P12/c1 (no. 14), a = 12.0407(7) angstrom,k, b = 11.8861(6) angstrom, c = 15.7389(9) angstrom, beta = 93.904(1)degrees, V = 2247.3 angstrom(3) Z = 2, R-gt(F) = 0.032, wR(ref) f(F-2) = 0.069, T = 120.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH",
volume = "222",
number = "4",
pages = "430-432",
doi = "10.1524/ncrs.2007.0182"
}
Jacimovic, Z. K., Radović, A., Leovac, V. M., Tomić, Z. D.,& Radosavjević Evans, I.. (2007). Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH. in Zeitschrift fur Kristallographie = New Crystal Structures, 222(4), 430-432.
https://doi.org/10.1524/ncrs.2007.0182
Jacimovic ZK, Radović A, Leovac VM, Tomić ZD, Radosavjević Evans I. Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH. in Zeitschrift fur Kristallographie = New Crystal Structures. 2007;222(4):430-432.
doi:10.1524/ncrs.2007.0182 .
Jacimovic, Zeljko K., Radović, Ana, Leovac, Vukadin M., Tomić, Zoran D., Radosavjević Evans, Ivana, "Crystal structure of bis(mu(2)-thiocyanato)tetrakis(3,5-dimethyl-t(thiocarbamoy)pyrazole)dinickel(II) dichloride ethanol disolvate, [Ni(NCS)(2)(C6H6N3S)(4)] [Cl](2)center dot 2C(2)H(5)OH" in Zeitschrift fur Kristallographie = New Crystal Structures, 222, no. 4 (2007):430-432,
https://doi.org/10.1524/ncrs.2007.0182 . .
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3

Crystal structure of hexakis(mu(2)-chloro)-mu(4)-oxo-tetrakis((3,5-dimethylpyrazole)copper(II)) ethanol tetrasolvate,Cu4OCl6(C5H8N2)(4)center dot 4C(2)H(5)OH

Jacimovic, Zeljko K.; Leovac, Vukadin M.; Tomić, Zoran D.

(2007)

TY  - JOUR
AU  - Jacimovic, Zeljko K.
AU  - Leovac, Vukadin M.
AU  - Tomić, Zoran D.
PY  - 2007
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3341
AB  - C28H56Cl6Cu4N8O5, triclinic, P (1) over bar (no. 2), a = 8.863(1) angstrom, b = 13.939(8) angstrom, c = 17.06(1) angstrom, alpha = 81.67(5)degrees, beta = 85.68(3)degrees, gamma = 84.91(3)degrees, V = 2073.0 angstrom(3), Z = 2, R-gt(F) = 0.080, wR(ref)(F-2) = 0.194, T = 293 K.
T2  - Zeitschrift fur Kristallographie = New Crystal Structures
T1  - Crystal structure of hexakis(mu(2)-chloro)-mu(4)-oxo-tetrakis((3,5-dimethylpyrazole)copper(II)) ethanol tetrasolvate,Cu4OCl6(C5H8N2)(4)center dot 4C(2)H(5)OH
VL  - 222
IS  - 3
SP  - 246
EP  - 248
DO  - 10.1524/ncrs.2007.0103
ER  - 
@article{
author = "Jacimovic, Zeljko K. and Leovac, Vukadin M. and Tomić, Zoran D.",
year = "2007",
abstract = "C28H56Cl6Cu4N8O5, triclinic, P (1) over bar (no. 2), a = 8.863(1) angstrom, b = 13.939(8) angstrom, c = 17.06(1) angstrom, alpha = 81.67(5)degrees, beta = 85.68(3)degrees, gamma = 84.91(3)degrees, V = 2073.0 angstrom(3), Z = 2, R-gt(F) = 0.080, wR(ref)(F-2) = 0.194, T = 293 K.",
journal = "Zeitschrift fur Kristallographie = New Crystal Structures",
title = "Crystal structure of hexakis(mu(2)-chloro)-mu(4)-oxo-tetrakis((3,5-dimethylpyrazole)copper(II)) ethanol tetrasolvate,Cu4OCl6(C5H8N2)(4)center dot 4C(2)H(5)OH",
volume = "222",
number = "3",
pages = "246-248",
doi = "10.1524/ncrs.2007.0103"
}
Jacimovic, Z. K., Leovac, V. M.,& Tomić, Z. D.. (2007). Crystal structure of hexakis(mu(2)-chloro)-mu(4)-oxo-tetrakis((3,5-dimethylpyrazole)copper(II)) ethanol tetrasolvate,Cu4OCl6(C5H8N2)(4)center dot 4C(2)H(5)OH. in Zeitschrift fur Kristallographie = New Crystal Structures, 222(3), 246-248.
https://doi.org/10.1524/ncrs.2007.0103
Jacimovic ZK, Leovac VM, Tomić ZD. Crystal structure of hexakis(mu(2)-chloro)-mu(4)-oxo-tetrakis((3,5-dimethylpyrazole)copper(II)) ethanol tetrasolvate,Cu4OCl6(C5H8N2)(4)center dot 4C(2)H(5)OH. in Zeitschrift fur Kristallographie = New Crystal Structures. 2007;222(3):246-248.
doi:10.1524/ncrs.2007.0103 .
Jacimovic, Zeljko K., Leovac, Vukadin M., Tomić, Zoran D., "Crystal structure of hexakis(mu(2)-chloro)-mu(4)-oxo-tetrakis((3,5-dimethylpyrazole)copper(II)) ethanol tetrasolvate,Cu4OCl6(C5H8N2)(4)center dot 4C(2)H(5)OH" in Zeitschrift fur Kristallographie = New Crystal Structures, 222, no. 3 (2007):246-248,
https://doi.org/10.1524/ncrs.2007.0103 . .
3
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