Kijevčanin, Mirjana Lj.

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orcid::0000-0001-7126-3965
  • Kijevčanin, Mirjana Lj. (15)
  • Kijevčanin, Mirjana (1)

Author's Bibliography

Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia

Cvetković, Slobodan M.; Kaluđerović-Radoičić, Tatjana; Kijevčanin, Mirjana; Grbović-Novaković, Jasmina

(2021)

TY  - JOUR
AU  - Cvetković, Slobodan M.
AU  - Kaluđerović-Radoičić, Tatjana
AU  - Kijevčanin, Mirjana
AU  - Grbović-Novaković, Jasmina
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9128
AB  - The aim of this paper is to demonstrate and to quantify energy flows in a life cycle of biogas to biohydrogen production, starting from feedstock materials via anaerobic digestion, biogas upgrading, biohydrogen production, to the end of biogas system (application of digestate as fertilizer in agriculture). The performance of the biogas plant of Mirotin dairy farm in Serbia has been assessed. According to Life Cycle Energy Assessment approach, results obtained in this study have shown that biohydrogen production via biogas steam reforming has negative energy balance (with −16,837 GJ). It has also been demonstrated that this process is energy unsustainable in an environmental context. In future analysis it would be necessary to consider the other aspects of sustainability, e.g. the economical and social factors in order to estimate the overall sustainability of the biogas utilization pathways, especially having in mind that the technology of converting biogas to hydrogen is still in the development phase. © 2021 Hydrogen Energy Publications LLC
T2  - International Journal of Hydrogen Energy
T1  - Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia
VL  - 46
IS  - 27
SP  - 14130
EP  - 14137
DO  - 10.1016/j.ijhydene.2021.01.181
ER  - 
@article{
author = "Cvetković, Slobodan M. and Kaluđerović-Radoičić, Tatjana and Kijevčanin, Mirjana and Grbović-Novaković, Jasmina",
year = "2021",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9128",
abstract = "The aim of this paper is to demonstrate and to quantify energy flows in a life cycle of biogas to biohydrogen production, starting from feedstock materials via anaerobic digestion, biogas upgrading, biohydrogen production, to the end of biogas system (application of digestate as fertilizer in agriculture). The performance of the biogas plant of Mirotin dairy farm in Serbia has been assessed. According to Life Cycle Energy Assessment approach, results obtained in this study have shown that biohydrogen production via biogas steam reforming has negative energy balance (with −16,837 GJ). It has also been demonstrated that this process is energy unsustainable in an environmental context. In future analysis it would be necessary to consider the other aspects of sustainability, e.g. the economical and social factors in order to estimate the overall sustainability of the biogas utilization pathways, especially having in mind that the technology of converting biogas to hydrogen is still in the development phase. © 2021 Hydrogen Energy Publications LLC",
journal = "International Journal of Hydrogen Energy",
title = "Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia",
volume = "46",
number = "27",
pages = "14130-14137",
doi = "10.1016/j.ijhydene.2021.01.181"
}
Cvetković, S. M., Kaluđerović-Radoičić, T., Kijevčanin, M.,& Grbović-Novaković, J. (2021). Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia.
International Journal of Hydrogen Energy, 46(27), 14130-14137.
https://doi.org/10.1016/j.ijhydene.2021.01.181
Cvetković SM, Kaluđerović-Radoičić T, Kijevčanin M, Grbović-Novaković J. Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia. International Journal of Hydrogen Energy. 2021;46(27):14130-14137
Cvetković Slobodan M., Kaluđerović-Radoičić Tatjana, Kijevčanin Mirjana, Grbović-Novaković Jasmina, "Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia" International Journal of Hydrogen Energy, 46, no. 27 (2021):14130-14137,
https://doi.org/10.1016/j.ijhydene.2021.01.181 .

Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling

Živković, Nikola V.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2020)

TY  - BOOK
AU  - Živković, Nikola V.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9037
AB  - Supporting Information for the article: Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. Journal of Chemical & Engineering Data, 65(6), 3044-3062. [https://doi.org/10.1021/acs.jced.0c00083]
T2  - Journal of Chemical & Engineering Data
T1  - Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling
VL  - 65
IS  - 6
SP  - 3044
EP  - 3062
DO  - 10.1021/acs.jced.0c00083
ER  - 
@book{
author = "Živković, Nikola V. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9037",
abstract = "Supporting Information for the article: Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. Journal of Chemical & Engineering Data, 65(6), 3044-3062. [https://doi.org/10.1021/acs.jced.0c00083]",
journal = "Journal of Chemical & Engineering Data",
title = "Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling",
volume = "65",
number = "6",
pages = "3044-3062",
doi = "10.1021/acs.jced.0c00083"
}
Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M. (2020). Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling.
Journal of Chemical & Engineering Data, 65(6), 3044-3062.
https://doi.org/10.1021/acs.jced.0c00083
Živković NV, Majstorović DM, Kijevčanin ML, Živković EM. Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. Journal of Chemical & Engineering Data. 2020;65(6):3044-3062
Živković Nikola V., Majstorović Divna M., Kijevčanin Mirjana Lj., Živković Emila M., "Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling" Journal of Chemical & Engineering Data, 65, no. 6 (2020):3044-3062,
https://doi.org/10.1021/acs.jced.0c00083 .

Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling

Živković, Nikola V.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2020)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9032
AB  - Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.
T2  - Journal of Chemical & Engineering Data
T1  - Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling
VL  - 65
IS  - 6
SP  - 3044
EP  - 3062
DO  - 10.1021/acs.jced.0c00083
ER  - 
@article{
author = "Živković, Nikola V. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2020",
url = "https://vinar.vin.bg.ac.rs/handle/123456789/9032",
abstract = "Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.",
journal = "Journal of Chemical & Engineering Data",
title = "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling",
volume = "65",
number = "6",
pages = "3044-3062",
doi = "10.1021/acs.jced.0c00083"
}
Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling.
Journal of Chemical & Engineering Data, 65(6), 3044-3062.
https://doi.org/10.1021/acs.jced.0c00083
Živković NV, Majstorović DM, Kijevčanin ML, Živković EM. Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. Journal of Chemical & Engineering Data. 2020;65(6):3044-3062
Živković Nikola V., Majstorović Divna M., Kijevčanin Mirjana Lj., Živković Emila M., "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling" Journal of Chemical & Engineering Data, 65, no. 6 (2020):3044-3062,
https://doi.org/10.1021/acs.jced.0c00083 .

The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes

Jovanović, Jovan D.; Majstorović, Divna M.; Živković, Nikola V.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2018)

TY  - JOUR
AU  - Jovanović, Jovan D.
AU  - Majstorović, Divna M.
AU  - Živković, Nikola V.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0167732218329441
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7885
AB  - In this study, applicability of the friction theory for the viscosity estimation of pure substances and binary liquid mixtures, used in regenerative flue gas desulphurization processes, was investigated. Theory was tested on the selected solvents that have already found commercial application, tetraethylene glycol dimethyl ether, n‑methyl‑2‑pyrrolidone and n,n‑dimethylaniline, in mixtures with alcohols 1‑butanol, 2‑butanol or 1‑hexanol. The results were compared with experimental viscosity data for eleven systems. In the calculation procedure, friction theory was coupled both with the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) equations of state (EoS). Almost identical deviations, under 0.2% with both EoS, were obtained for pure compounds. For viscosity of mixtures, in almost all cases, better results were obtained using PR EoS, with values of percentage deviations less than 4%. Additionally, the possibility of simultaneous density calculations was checked and the obtained values were compared with experimental data. Application of this model for viscosity modeling of the investigated systems was justified by comparison of the obtained results with other commonly used predictive models, UNIFAC-VISCO and ASOG-VISCO. © 2018 Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes
VL  - 271
SP  - 696
EP  - 703
DO  - 10.1016/j.molliq.2018.09.043
ER  - 
@article{
author = "Jovanović, Jovan D. and Majstorović, Divna M. and Živković, Nikola V. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2018",
url = "https://linkinghub.elsevier.com/retrieve/pii/S0167732218329441, http://vinar.vin.bg.ac.rs/handle/123456789/7885",
abstract = "In this study, applicability of the friction theory for the viscosity estimation of pure substances and binary liquid mixtures, used in regenerative flue gas desulphurization processes, was investigated. Theory was tested on the selected solvents that have already found commercial application, tetraethylene glycol dimethyl ether, n‑methyl‑2‑pyrrolidone and n,n‑dimethylaniline, in mixtures with alcohols 1‑butanol, 2‑butanol or 1‑hexanol. The results were compared with experimental viscosity data for eleven systems. In the calculation procedure, friction theory was coupled both with the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) equations of state (EoS). Almost identical deviations, under 0.2% with both EoS, were obtained for pure compounds. For viscosity of mixtures, in almost all cases, better results were obtained using PR EoS, with values of percentage deviations less than 4%. Additionally, the possibility of simultaneous density calculations was checked and the obtained values were compared with experimental data. Application of this model for viscosity modeling of the investigated systems was justified by comparison of the obtained results with other commonly used predictive models, UNIFAC-VISCO and ASOG-VISCO. © 2018 Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes",
volume = "271",
pages = "696-703",
doi = "10.1016/j.molliq.2018.09.043"
}
Jovanović, J. D., Majstorović, D. M., Živković, N. V., Kijevčanin, M. Lj.,& Živković, E. M. (2018). The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes.
Journal of Molecular Liquids, 271, 696-703.
https://doi.org/10.1016/j.molliq.2018.09.043
Jovanović JD, Majstorović DM, Živković NV, Kijevčanin ML, Živković EM. The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes. Journal of Molecular Liquids. 2018;271:696-703
Jovanović Jovan D., Majstorović Divna M., Živković Nikola V., Kijevčanin Mirjana Lj., Živković Emila M., "The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes" Journal of Molecular Liquids, 271 (2018):696-703,
https://doi.org/10.1016/j.molliq.2018.09.043 .

Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes

(2018)

TY  - JOUR
PY  - 2018
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7579
AB  - This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models. (C) 2018 Elsevier Ltd.
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes
VL  - 119
SP  - 135
EP  - 154
DO  - 10.1016/j.jct.2017.12.023
ER  - 
@article{
year = "2018",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/7579",
abstract = "This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models. (C) 2018 Elsevier Ltd.",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes",
volume = "119",
pages = "135-154",
doi = "10.1016/j.jct.2017.12.023"
}
 (2018). Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes.
Journal of Chemical Thermodynamics, 119, 135-154.
https://doi.org/10.1016/j.jct.2017.12.023
 Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. Journal of Chemical Thermodynamics. 2018;119:135-154
, "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes" Journal of Chemical Thermodynamics, 119 (2018):135-154,
https://doi.org/10.1016/j.jct.2017.12.023 .
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Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids

Stanimirovic, Andrej M.; Zivkovic, Emila M.; Miloavic, Nenad D.; Kijevčanin, Mirjana Lj.

(2017)

TY  - JOUR
AU  - Stanimirovic, Andrej M.
AU  - Zivkovic, Emila M.
AU  - Miloavic, Nenad D.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1629
AB  - Transient hot wire method is considered a reliable and precise technique for measuring the thermal conductivity of liquids. The present paper describes a new transient hot wire experimental set-up and its initial testing. The new apparatus was tested by performing thermal conductivity measurements on substances whose reference thermophysical properties data existed in literature, namely on pure toluene and double distilled deionized water. The values of thermal conductivity measured in the temperature range 25 to 45 degrees C deviated +2.2% to +3% from the literature data, while the expanded measurement uncertainty was estimated to be +/- 4%.
T2  - Thermal Science
T1  - Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids
VL  - 21
IS  - 3
SP  - 1195
EP  - 1202
DO  - 10.2298/TSCI160324219S
ER  - 
@article{
author = "Stanimirovic, Andrej M. and Zivkovic, Emila M. and Miloavic, Nenad D. and Kijevčanin, Mirjana Lj.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1629",
abstract = "Transient hot wire method is considered a reliable and precise technique for measuring the thermal conductivity of liquids. The present paper describes a new transient hot wire experimental set-up and its initial testing. The new apparatus was tested by performing thermal conductivity measurements on substances whose reference thermophysical properties data existed in literature, namely on pure toluene and double distilled deionized water. The values of thermal conductivity measured in the temperature range 25 to 45 degrees C deviated +2.2% to +3% from the literature data, while the expanded measurement uncertainty was estimated to be +/- 4%.",
journal = "Thermal Science",
title = "Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids",
volume = "21",
number = "3",
pages = "1195-1202",
doi = "10.2298/TSCI160324219S"
}
Stanimirovic, A. M., Zivkovic, E. M., Miloavic, N. D.,& Kijevčanin, M. Lj. (2017). Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids.
Thermal Science, 21(3), 1195-1202.
https://doi.org/10.2298/TSCI160324219S
Stanimirovic AM, Zivkovic EM, Miloavic ND, Kijevčanin ML. Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids. Thermal Science. 2017;21(3):1195-1202
Stanimirovic Andrej M., Zivkovic Emila M., Miloavic Nenad D., Kijevčanin Mirjana Lj., "Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids" Thermal Science, 21, no. 3 (2017):1195-1202,
https://doi.org/10.2298/TSCI160324219S .
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Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study

Maslovara, Slađana Lj.; Vasić Anićijević, Dragana D.; Kijevčanin, Mirjana Lj.; Radovic, Ivona R.; Nikolić, Vladimir M.; Laušević, Petar; Marčeta Kaninski, Milica

(2017)

TY  - JOUR
AU  - Maslovara, Slađana Lj.
AU  - Vasić Anićijević, Dragana D.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radovic, Ivona R.
AU  - Nikolić, Vladimir M.
AU  - Laušević, Petar
AU  - Marčeta Kaninski, Milica
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1610
AB  - In this paper we discussed various factors contributing to the improvement of hydrogen evolution reaction (HER) activity of Ni and stainless steel electrodes activated by in situ addition of NiCoMo activators, using a combination of experimental techniques and DFT calculations. By comparing energy consumption of stainless steel (SS) electrodes in a lab scale alkaline electrolyzer with and without ionic activation, we obtained reduction of energy consumption by 21% at industrial conditions (high current density and temperature). We recorded U-I curves for activated and non-activated stainless steel electrodes in the current density range from 40 to 500 mA cm(2) and in the temperature range 298-343 K, and the obtained results were used in an electrochemical model of the laboratory alkaline electrolyzer. Increase of the electrode surface upon addition of ionic activators was confirmed by profilometric measurements and SEM analysis. Finally, we applied density functional theory (DFT) to discuss partial roles of applied ionic activators (Ni, Co and Mo) in the modification and improvement of the intrinsic properties of the cathode towards the HER in alkaline medium. From the combination of profilometric, SEM and DFT results, we conclude that the main factor contributing to the improvement of HER activity of Ni electrodes upon NiCoMo activation is the increase of electrode surface area. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study
VL  - 42
IS  - 8
SP  - 5072
EP  - 5082
DO  - 10.1016/j.ijhydene.2016.12.116
ER  - 
@article{
author = "Maslovara, Slađana Lj. and Vasić Anićijević, Dragana D. and Kijevčanin, Mirjana Lj. and Radovic, Ivona R. and Nikolić, Vladimir M. and Laušević, Petar and Marčeta Kaninski, Milica",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1610",
abstract = "In this paper we discussed various factors contributing to the improvement of hydrogen evolution reaction (HER) activity of Ni and stainless steel electrodes activated by in situ addition of NiCoMo activators, using a combination of experimental techniques and DFT calculations. By comparing energy consumption of stainless steel (SS) electrodes in a lab scale alkaline electrolyzer with and without ionic activation, we obtained reduction of energy consumption by 21% at industrial conditions (high current density and temperature). We recorded U-I curves for activated and non-activated stainless steel electrodes in the current density range from 40 to 500 mA cm(2) and in the temperature range 298-343 K, and the obtained results were used in an electrochemical model of the laboratory alkaline electrolyzer. Increase of the electrode surface upon addition of ionic activators was confirmed by profilometric measurements and SEM analysis. Finally, we applied density functional theory (DFT) to discuss partial roles of applied ionic activators (Ni, Co and Mo) in the modification and improvement of the intrinsic properties of the cathode towards the HER in alkaline medium. From the combination of profilometric, SEM and DFT results, we conclude that the main factor contributing to the improvement of HER activity of Ni electrodes upon NiCoMo activation is the increase of electrode surface area. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study",
volume = "42",
number = "8",
pages = "5072-5082",
doi = "10.1016/j.ijhydene.2016.12.116"
}
Maslovara, S. Lj., Vasić Anićijević, D. D., Kijevčanin, M. Lj., Radovic, I. R., Nikolić, V. M., Laušević, P.,& Marčeta Kaninski, M. (2017). Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study.
International Journal of Hydrogen Energy, 42(8), 5072-5082.
https://doi.org/10.1016/j.ijhydene.2016.12.116
Maslovara SL, Vasić Anićijević DD, Kijevčanin ML, Radovic IR, Nikolić VM, Laušević P, Marčeta Kaninski M. Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study. International Journal of Hydrogen Energy. 2017;42(8):5072-5082
Maslovara Slađana Lj., Vasić Anićijević Dragana D., Kijevčanin Mirjana Lj., Radovic Ivona R., Nikolić Vladimir M., Laušević Petar, Marčeta Kaninski Milica, "Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study" International Journal of Hydrogen Energy, 42, no. 8 (2017):5072-5082,
https://doi.org/10.1016/j.ijhydene.2016.12.116 .
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5

Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit

Škobalj, Predrag D.; Kijevčanin, Mirjana Lj.; Jovanović, Marina P.; Afgan, Naim H.; Erić, Milić D.

(2017)

TY  - JOUR
AU  - Škobalj, Predrag D.
AU  - Kijevčanin, Mirjana Lj.
AU  - Jovanović, Marina P.
AU  - Afgan, Naim H.
AU  - Erić, Milić D.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1550
AB  - This paper presents method for sustainability assessment of thermal power plant unit using multi-criteria analysis with aim to create base for business decision. Seven options of possible status of thermal power plant Kolubara A unit No. 2 with energy indicators of sustainable development were shown. Energy indicators of sustainable development consists of sets of resource preservation, economic, environmental, and social indicators. Sustainability assessment often fails to account for social influence on energy system. Considering to this, special focus will be on social indicators, their definition, forming, and impact on multi-criteria sustainability analysis. Analysis of quality of the selected options (energy systems) in respect to sustainable development by compare of their general index of sustainability is presented. Methodology of multi-criteria analyse of thermal power plant unit can show decision makers how to find best available options when the social indicators impact is leading. The aim of this paper is to choose the criteria for the evaluation of the available options, determine the relative importance of specific criteria and present methodology of multi-criteria analysis in the decision-making process.
T2  - Thermal Science
T1  - Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit
VL  - 21
IS  - 2
SP  - 1143
EP  - 1151
DO  - 10.2298/TSCI160215178S
ER  - 
@article{
author = "Škobalj, Predrag D. and Kijevčanin, Mirjana Lj. and Jovanović, Marina P. and Afgan, Naim H. and Erić, Milić D.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1550",
abstract = "This paper presents method for sustainability assessment of thermal power plant unit using multi-criteria analysis with aim to create base for business decision. Seven options of possible status of thermal power plant Kolubara A unit No. 2 with energy indicators of sustainable development were shown. Energy indicators of sustainable development consists of sets of resource preservation, economic, environmental, and social indicators. Sustainability assessment often fails to account for social influence on energy system. Considering to this, special focus will be on social indicators, their definition, forming, and impact on multi-criteria sustainability analysis. Analysis of quality of the selected options (energy systems) in respect to sustainable development by compare of their general index of sustainability is presented. Methodology of multi-criteria analyse of thermal power plant unit can show decision makers how to find best available options when the social indicators impact is leading. The aim of this paper is to choose the criteria for the evaluation of the available options, determine the relative importance of specific criteria and present methodology of multi-criteria analysis in the decision-making process.",
journal = "Thermal Science",
title = "Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit",
volume = "21",
number = "2",
pages = "1143-1151",
doi = "10.2298/TSCI160215178S"
}
Škobalj, P. D., Kijevčanin, M. Lj., Jovanović, M. P., Afgan, N. H.,& Erić, M. D. (2017). Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit.
Thermal Science, 21(2), 1143-1151.
https://doi.org/10.2298/TSCI160215178S
Škobalj PD, Kijevčanin ML, Jovanović MP, Afgan NH, Erić MD. Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit. Thermal Science. 2017;21(2):1143-1151
Škobalj Predrag D., Kijevčanin Mirjana Lj., Jovanović Marina P., Afgan Naim H., Erić Milić D., "Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit" Thermal Science, 21, no. 2 (2017):1143-1151,
https://doi.org/10.2298/TSCI160215178S .
1

Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes

Živković, Nikola V.; Zivkovic, Emila M.; Serbanovic, Slobodan P.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.

(2017)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Zivkovic, Emila M.
AU  - Serbanovic, Slobodan P.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1443
AB  - Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations. (C) 2017 Elsevier Ltd.
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes
VL  - 108
SP  - 162
EP  - 180
DO  - 10.1016/j.jct.2017.01.018
ER  - 
@article{
author = "Živković, Nikola V. and Zivkovic, Emila M. and Serbanovic, Slobodan P. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1443",
abstract = "Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations. (C) 2017 Elsevier Ltd.",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes",
volume = "108",
pages = "162-180",
doi = "10.1016/j.jct.2017.01.018"
}
Živković, N. V., Zivkovic, E. M., Serbanovic, S. P., Majstorović, D. M.,& Kijevčanin, M. Lj. (2017). Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes.
Journal of Chemical Thermodynamics, 108, 162-180.
https://doi.org/10.1016/j.jct.2017.01.018
Živković NV, Zivkovic EM, Serbanovic SP, Majstorović DM, Kijevčanin ML. Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. Journal of Chemical Thermodynamics. 2017;108:162-180
Živković Nikola V., Zivkovic Emila M., Serbanovic Slobodan P., Majstorović Divna M., Kijevčanin Mirjana Lj., "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes" Journal of Chemical Thermodynamics, 108 (2017):162-180,
https://doi.org/10.1016/j.jct.2017.01.018 .
3
4
4

Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2

Škobalj, Predrag D.; Kijevčanin, Mirjana Lj.; Afgan, Naim H.; Jovanović, Marina P.; Turanjanin, Valentina; Vučićević, Biljana S.

(2017)

TY  - JOUR
AU  - Škobalj, Predrag D.
AU  - Kijevčanin, Mirjana Lj.
AU  - Afgan, Naim H.
AU  - Jovanović, Marina P.
AU  - Turanjanin, Valentina
AU  - Vučićević, Biljana S.
PY  - 2017
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/1574
AB  - The paper presents a possible approach for creating business decisions based on multi-criteria analysis. Seven options for a possible revitalization of the thermal power plant Kolubara-A Unit No. 2 with energy indicators of sustainable development (EISD) are presented in this paper. The chosen EISD numerically express the essential features of the analyzed options, while the sustainability criteria indicate the option quality within the limits of these indicators. In this paper, the criteria for assessing the sustainability options are defined based on several aspects: economic, social, environmental and technological. In the process of assessing the sustainability of the considered options the Analysis and Synthesis of Parameters under Information Deficiency (ASPID) method was used. In this paper, the EISD show that production and energy consumption are closely linked to economic, environmental and other indicators, such as economic and technological development of local communities with employment being one of the most important social parameter. Multi-criteria analysis for the case study of the TPP Kolubara-A clearly indicated recommendations to decision makers on the choice of the best available options in dependence on the energy policy. (C) 2017 Elsevier Ltd. All rights reserved.
T2  - Energy
T1  - Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2
VL  - 125
SP  - 837
EP  - 847
DO  - 10.1016/j.energy.2017.02.027
ER  - 
@article{
author = "Škobalj, Predrag D. and Kijevčanin, Mirjana Lj. and Afgan, Naim H. and Jovanović, Marina P. and Turanjanin, Valentina and Vučićević, Biljana S.",
year = "2017",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/1574",
abstract = "The paper presents a possible approach for creating business decisions based on multi-criteria analysis. Seven options for a possible revitalization of the thermal power plant Kolubara-A Unit No. 2 with energy indicators of sustainable development (EISD) are presented in this paper. The chosen EISD numerically express the essential features of the analyzed options, while the sustainability criteria indicate the option quality within the limits of these indicators. In this paper, the criteria for assessing the sustainability options are defined based on several aspects: economic, social, environmental and technological. In the process of assessing the sustainability of the considered options the Analysis and Synthesis of Parameters under Information Deficiency (ASPID) method was used. In this paper, the EISD show that production and energy consumption are closely linked to economic, environmental and other indicators, such as economic and technological development of local communities with employment being one of the most important social parameter. Multi-criteria analysis for the case study of the TPP Kolubara-A clearly indicated recommendations to decision makers on the choice of the best available options in dependence on the energy policy. (C) 2017 Elsevier Ltd. All rights reserved.",
journal = "Energy",
title = "Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2",
volume = "125",
pages = "837-847",
doi = "10.1016/j.energy.2017.02.027"
}
Škobalj, P. D., Kijevčanin, M. Lj., Afgan, N. H., Jovanović, M. P., Turanjanin, V.,& Vučićević, B. S. (2017). Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2.
Energy, 125, 837-847.
https://doi.org/10.1016/j.energy.2017.02.027
Škobalj PD, Kijevčanin ML, Afgan NH, Jovanović MP, Turanjanin V, Vučićević BS. Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2. Energy. 2017;125:837-847
Škobalj Predrag D., Kijevčanin Mirjana Lj., Afgan Naim H., Jovanović Marina P., Turanjanin Valentina, Vučićević Biljana S., "Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2" Energy, 125 (2017):837-847,
https://doi.org/10.1016/j.energy.2017.02.027 .
7
5
6

Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options

Škobalj, Predrag D.; Jovanović, Marina P.; Vučićević, Biljana S.; Turanjanin, Valentina; Kijevčanin, Mirjana Lj.

(2016)

TY  - CONF
AU  - Škobalj, Predrag D.
AU  - Jovanović, Marina P.
AU  - Vučićević, Biljana S.
AU  - Turanjanin, Valentina
AU  - Kijevčanin, Mirjana Lj.
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/7138
AB  - Coal combustion power plant Kolubara A has five thermal units with total installed capacity of 270 MW operates as a part of Public Enterprise which has planned to accept and apply the Clean Development Mechanism (new power plants on lignite and natural gas with higher energy efficiency as well as activities related to the rehabilitation and modernization of existing facilities). Two units were put in operation before more than fifty years and in order to extend the lifetime of these blocks in the process of revitalization, in this paper, beside an existing option which considers coal (lignite) combustion, are analysed possible options of thermal power units with gas and renewable energy sources: biomass, renewable solid fuels, waste materials, wind and sun. Paper presents seven energy system options of the thermal unit status which are described with suitable chosen indicators in respect to different aspects of sustainability: economical, ecological, social and resources indicators. In this paper energy indicators are defined as a tool for the sustainability assessment of energy system options. ASPID method of multi-criteria assessment was used to calculate general index of sustainability and obtained ranking of options. This study presented and analysed cases, with predefined constraints when priority has environmental indicator and different conditions where one of sub-indicators have priority, as an example of applying multi-criteria method.
T1  - Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options
ER  - 
@conference{
author = "Škobalj, Predrag D. and Jovanović, Marina P. and Vučićević, Biljana S. and Turanjanin, Valentina and Kijevčanin, Mirjana Lj.",
year = "2016",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/7138",
abstract = "Coal combustion power plant Kolubara A has five thermal units with total installed capacity of 270 MW operates as a part of Public Enterprise which has planned to accept and apply the Clean Development Mechanism (new power plants on lignite and natural gas with higher energy efficiency as well as activities related to the rehabilitation and modernization of existing facilities). Two units were put in operation before more than fifty years and in order to extend the lifetime of these blocks in the process of revitalization, in this paper, beside an existing option which considers coal (lignite) combustion, are analysed possible options of thermal power units with gas and renewable energy sources: biomass, renewable solid fuels, waste materials, wind and sun. Paper presents seven energy system options of the thermal unit status which are described with suitable chosen indicators in respect to different aspects of sustainability: economical, ecological, social and resources indicators. In this paper energy indicators are defined as a tool for the sustainability assessment of energy system options. ASPID method of multi-criteria assessment was used to calculate general index of sustainability and obtained ranking of options. This study presented and analysed cases, with predefined constraints when priority has environmental indicator and different conditions where one of sub-indicators have priority, as an example of applying multi-criteria method.",
title = "Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options"
}
Škobalj, P. D., Jovanović, M. P., Vučićević, B. S., Turanjanin, V.,& Kijevčanin, M. Lj. (2016). Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options.
.
Škobalj PD, Jovanović MP, Vučićević BS, Turanjanin V, Kijevčanin ML. Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options. 2016;
Škobalj Predrag D., Jovanović Marina P., Vučićević Biljana S., Turanjanin Valentina, Kijevčanin Mirjana Lj., "Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options" (2016)

Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases

Spasojević, Vuk D.; Serbanovic, Slobodan P.; Stefanović, Predrag Lj.; Kijevčanin, Mirjana Lj.

(2014)

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Serbanovic, Slobodan P.
AU  - Stefanović, Predrag Lj.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2014
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/5980
AB  - In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.
T2  - Hemijska industrija
T1  - Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases
VL  - 68
IS  - 1
SP  - 123
EP  - 134
DO  - 10.2298/HEMIND130312039S
ER  - 
@article{
author = "Spasojević, Vuk D. and Serbanovic, Slobodan P. and Stefanović, Predrag Lj. and Kijevčanin, Mirjana Lj.",
year = "2014",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/5980",
abstract = "In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.",
journal = "Hemijska industrija",
title = "Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases",
volume = "68",
number = "1",
pages = "123-134",
doi = "10.2298/HEMIND130312039S"
}
Spasojević, V. D., Serbanovic, S. P., Stefanović, P. Lj.,& Kijevčanin, M. Lj. (2014). Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases.
Hemijska industrija, 68(1), 123-134.
https://doi.org/10.2298/HEMIND130312039S
Spasojević VD, Serbanovic SP, Stefanović PL, Kijevčanin ML. Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. Hemijska industrija. 2014;68(1):123-134
Spasojević Vuk D., Serbanovic Slobodan P., Stefanović Predrag Lj., Kijevčanin Mirjana Lj., "Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases" Hemijska industrija, 68, no. 1 (2014):123-134,
https://doi.org/10.2298/HEMIND130312039S .
1
1

Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination

Živković, Nikola V.; Serbanovic, Slobodan P.; Zivkovic, Emila M.; Kijevčanin, Mirjana Lj.; Stefanović, Predrag Lj.

(2014)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Serbanovic, Slobodan P.
AU  - Zivkovic, Emila M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Stefanović, Predrag Lj.
PY  - 2014
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/162
AB  - In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.
T2  - Hemijska industrija
T1  - Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination
VL  - 68
IS  - 4
SP  - 491
EP  - 500
DO  - 10.2298/HEMIND130610074Z
ER  - 
@article{
author = "Živković, Nikola V. and Serbanovic, Slobodan P. and Zivkovic, Emila M. and Kijevčanin, Mirjana Lj. and Stefanović, Predrag Lj.",
year = "2014",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/162",
abstract = "In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.",
journal = "Hemijska industrija",
title = "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination",
volume = "68",
number = "4",
pages = "491-500",
doi = "10.2298/HEMIND130610074Z"
}
Živković, N. V., Serbanovic, S. P., Zivkovic, E. M., Kijevčanin, M. Lj.,& Stefanović, P. Lj. (2014). Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination.
Hemijska industrija, 68(4), 491-500.
https://doi.org/10.2298/HEMIND130610074Z
Živković NV, Serbanovic SP, Zivkovic EM, Kijevčanin ML, Stefanović PL. Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. Hemijska industrija. 2014;68(4):491-500
Živković Nikola V., Serbanovic Slobodan P., Zivkovic Emila M., Kijevčanin Mirjana Lj., Stefanović Predrag Lj., "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination" Hemijska industrija, 68, no. 4 (2014):491-500,
https://doi.org/10.2298/HEMIND130610074Z .

Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K

Spasojević, Vuk D.; Djordjevic, Bojan D.; Serbanovic, Slobodan P.; Radovic, Ivona R.; Kijevčanin, Mirjana Lj.

(2014)

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Djordjevic, Bojan D.
AU  - Serbanovic, Slobodan P.
AU  - Radovic, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2014
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/6039
AB  - Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.
T2  - Journal of Chemical and Engineering Data
T1  - Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K
VL  - 59
IS  - 6
SP  - 1817
EP  - 1829
DO  - 10.1021/je401036f
ER  - 
@article{
author = "Spasojević, Vuk D. and Djordjevic, Bojan D. and Serbanovic, Slobodan P. and Radovic, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2014",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/6039",
abstract = "Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.",
journal = "Journal of Chemical and Engineering Data",
title = "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K",
volume = "59",
number = "6",
pages = "1817-1829",
doi = "10.1021/je401036f"
}
Spasojević, V. D., Djordjevic, B. D., Serbanovic, S. P., Radovic, I. R.,& Kijevčanin, M. Lj. (2014). Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K.
Journal of Chemical and Engineering Data, 59(6), 1817-1829.
https://doi.org/10.1021/je401036f
Spasojević VD, Djordjevic BD, Serbanovic SP, Radovic IR, Kijevčanin ML. Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. Journal of Chemical and Engineering Data. 2014;59(6):1817-1829
Spasojević Vuk D., Djordjevic Bojan D., Serbanovic Slobodan P., Radovic Ivona R., Kijevčanin Mirjana Lj., "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K" Journal of Chemical and Engineering Data, 59, no. 6 (2014):1817-1829,
https://doi.org/10.1021/je401036f .
31
31
33

Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME

Živković, Nikola V.; Serbanovic, S.; Kijevčanin, Mirjana Lj.; Zivkovic, E.

(2013)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Serbanovic, S.
AU  - Kijevčanin, Mirjana Lj.
AU  - Zivkovic, E.
PY  - 2013
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/5586
AB  - Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg-Nissan, Eyring-UNIQUAC, three-body McAlister, and Eyring-NRTL models.
T2  - International Journal of Thermophysics
T1  - Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME
VL  - 34
IS  - 6
SP  - 1002
EP  - 1020
DO  - 10.1007/s10765-013-1469-0
ER  - 
@article{
author = "Živković, Nikola V. and Serbanovic, S. and Kijevčanin, Mirjana Lj. and Zivkovic, E.",
year = "2013",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/5586",
abstract = "Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg-Nissan, Eyring-UNIQUAC, three-body McAlister, and Eyring-NRTL models.",
journal = "International Journal of Thermophysics",
title = "Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME",
volume = "34",
number = "6",
pages = "1002-1020",
doi = "10.1007/s10765-013-1469-0"
}
Živković, N. V., Serbanovic, S., Kijevčanin, M. Lj.,& Zivkovic, E. (2013). Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME.
International Journal of Thermophysics, 34(6), 1002-1020.
https://doi.org/10.1007/s10765-013-1469-0
Živković NV, Serbanovic S, Kijevčanin ML, Zivkovic E. Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME. International Journal of Thermophysics. 2013;34(6):1002-1020
Živković Nikola V., Serbanovic S., Kijevčanin Mirjana Lj., Zivkovic E., "Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME" International Journal of Thermophysics, 34, no. 6 (2013):1002-1020,
https://doi.org/10.1007/s10765-013-1469-0 .
27
24
25

Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone

Živković, Nikola V.; Serbanovic, Slobodanh S.; Kijevčanin, Mirjana Lj.; Zivkovic, E. M.

(2013)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Serbanovic, Slobodanh S.
AU  - Kijevčanin, Mirjana Lj.
AU  - Zivkovic, E. M.
PY  - 2013
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/5805
AB  - Experimental data on densities, viscosities, and refractive indices of binary mixtures with 2-butanol and polyethylene glycols of different molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in refractive indices were computed from these data and correlated with the Redlich-Kister polynomial equation. The obtained results allowed the interpretation of specific inter- and intramolecular interactions.
T2  - Journal of Chemical and Engineering Data
T1  - Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone
VL  - 58
IS  - 12
SP  - 3332
EP  - 3341
DO  - 10.1021/je400486p
ER  - 
@article{
author = "Živković, Nikola V. and Serbanovic, Slobodanh S. and Kijevčanin, Mirjana Lj. and Zivkovic, E. M.",
year = "2013",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/5805",
abstract = "Experimental data on densities, viscosities, and refractive indices of binary mixtures with 2-butanol and polyethylene glycols of different molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in refractive indices were computed from these data and correlated with the Redlich-Kister polynomial equation. The obtained results allowed the interpretation of specific inter- and intramolecular interactions.",
journal = "Journal of Chemical and Engineering Data",
title = "Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone",
volume = "58",
number = "12",
pages = "3332-3341",
doi = "10.1021/je400486p"
}
Živković, N. V., Serbanovic, S. S., Kijevčanin, M. Lj.,& Zivkovic, E. M. (2013). Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone.
Journal of Chemical and Engineering Data, 58(12), 3332-3341.
https://doi.org/10.1021/je400486p
Živković NV, Serbanovic SS, Kijevčanin ML, Zivkovic EM. Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone. Journal of Chemical and Engineering Data. 2013;58(12):3332-3341
Živković Nikola V., Serbanovic Slobodanh S., Kijevčanin Mirjana Lj., Zivkovic E. M., "Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone" Journal of Chemical and Engineering Data, 58, no. 12 (2013):3332-3341,
https://doi.org/10.1021/je400486p .
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31
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