Đačanin Far, Ljubica

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Authority KeyName Variants
orcid::0000-0002-0760-3758
  • Đačanin Far, Ljubica (12)
  • Đačanin, Ljubica (8)
  • Đačanin-Far, Ljubica (1)
Projects
Physics of amorphous and nanostructural materials Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200125 (University of Novi Sad, Faculty of Science)
Ministry of Education, Science and Technological Development of the Republic of Serbia APV Provincial Secretariat for Higher Education and Scientific Research, project title “Development of new highly sensitive sensors for monitoring of gas pollution and humidity in Vojvodina” [Project no. 142-451-3154/2022-01/2]
Chongqing University of Posts and Telecommunications (CQUPT) - National High-end Foreign Experts Recruitment Program [Grant GDT20185200479] Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites
Amorphous and nanostructural chalcogenides Sinteza i karakterizacija nanočestica i nanokompozita
Ministry of Education in Saudi Arabia [ project no. IFKSUOR3–099–2] Ministry of Education, Science and Technological Development of the Republic of Serbia.
Ministry of Science and Technological Development of the Republic of Serbia, Provincial Secretariat for Science and Technological Development of the Government of Vojvodina. Ministry of Science of the Republic of Serbia [141026, 142066]
NATO Science for Peace and Security Programme [G5751] NATO Science for Peace and Security Programme [grant id. G5751]
Provincial Secretariat for Science and Technological Development, Government of Vojvodina [114-450-2187-2011] Provincial Secretariat for Science and Technological Development of the Government of Vojvodina [114-451-2187]
Provincial Secretariat for Science and Tehnological Development of the Automomous Province of Vojvodina Provincial Secretary for Science and Technological Development [114-451-2187-2011]

Author's Bibliography

Emission color tunability of dysprosium-activated YNbO4–LuNbO4-mixed phosphors

Đačanin-Far, Ljubica; Dramićanin, Tatjana; Medić, Mina; Ristić, Zoran; Periša, Jovana; Đorđević, Vesna; Antić, Željka; Dramićanin, Miroslav

(2024)

TY  - JOUR
AU  - Đačanin-Far, Ljubica
AU  - Dramićanin, Tatjana
AU  - Medić, Mina
AU  - Ristić, Zoran
AU  - Periša, Jovana
AU  - Đorđević, Vesna
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12568
AB  - Herein, we demonstrate the photoluminescence properties of Dy3+-activated YNbO4, LuNbO4, and mixed YxLu1−xNbO4:Dy3+ (x=0.25, 0.5, 0.75) phosphors. For this purpose, fve samples with a fxed Dy3+ concentration (2 mol%) were prepared by the solid-state reaction method. X-ray difraction measurements showed that all phosphors crystallize in a monoclinic fergusonite-beta-(Y) structure with a C2/c space group. Scanning electron microscopy clearly shows that samples are composed of dense, well-developed micron-sized, cube-shaped grains with rounded edges. The photoluminescent emission spectra feature Dy3+ peaks at standard positions corresponding to transitions from the 4 F9/2 excited emitting level to the 6 HJ (J=15/2; 13/2; 11/2 and 9/2) lower levels with two dominant emission bands placed in the blue (~479 nm, B) and yellow (~576 nm, Y) spectral region. It is observed that with Lu increase in the host lattice Y/B ratio decreases toward the desired ratio of unity to obtain white light. To evaluate the suitability of these phosphors for use in solid-state lighting, their photoluminescence emission was analyzed in detail by calculating CIE coordinates, correlated color temperature (CCT) and Delta u,v (DUV). It is shown that CIE chromaticity coordinates of all Dy3+-activated YxLu1−xNbO4 samples (x=0, 0.25, 0.5, 0.75, and 1) fall into the white portion of the diagram and that with the increase of Lu in the host lattice color becomes whiter. CCT values for all samples are in the cooler 4000–4500 K range with positive DUVs indicating that color points are placed above the black body curve. The average lifetime of 4 F9/2 level is calculated to be~0.2 ms for all Dy3+-activated YxLu1−xNbO4 samples, indicating that there is no infuence of the Y-to-Lu ratio in the host niobate material on the luminescence kinetics.
T2  - Applied Physics A
T1  - Emission color tunability of dysprosium-activated YNbO4–LuNbO4-mixed phosphors
VL  - 130
IS  - 2
SP  - 107
DO  - 10.1007/s00339-023-07271-z
ER  - 
@article{
author = "Đačanin-Far, Ljubica and Dramićanin, Tatjana and Medić, Mina and Ristić, Zoran and Periša, Jovana and Đorđević, Vesna and Antić, Željka and Dramićanin, Miroslav",
year = "2024",
abstract = "Herein, we demonstrate the photoluminescence properties of Dy3+-activated YNbO4, LuNbO4, and mixed YxLu1−xNbO4:Dy3+ (x=0.25, 0.5, 0.75) phosphors. For this purpose, fve samples with a fxed Dy3+ concentration (2 mol%) were prepared by the solid-state reaction method. X-ray difraction measurements showed that all phosphors crystallize in a monoclinic fergusonite-beta-(Y) structure with a C2/c space group. Scanning electron microscopy clearly shows that samples are composed of dense, well-developed micron-sized, cube-shaped grains with rounded edges. The photoluminescent emission spectra feature Dy3+ peaks at standard positions corresponding to transitions from the 4 F9/2 excited emitting level to the 6 HJ (J=15/2; 13/2; 11/2 and 9/2) lower levels with two dominant emission bands placed in the blue (~479 nm, B) and yellow (~576 nm, Y) spectral region. It is observed that with Lu increase in the host lattice Y/B ratio decreases toward the desired ratio of unity to obtain white light. To evaluate the suitability of these phosphors for use in solid-state lighting, their photoluminescence emission was analyzed in detail by calculating CIE coordinates, correlated color temperature (CCT) and Delta u,v (DUV). It is shown that CIE chromaticity coordinates of all Dy3+-activated YxLu1−xNbO4 samples (x=0, 0.25, 0.5, 0.75, and 1) fall into the white portion of the diagram and that with the increase of Lu in the host lattice color becomes whiter. CCT values for all samples are in the cooler 4000–4500 K range with positive DUVs indicating that color points are placed above the black body curve. The average lifetime of 4 F9/2 level is calculated to be~0.2 ms for all Dy3+-activated YxLu1−xNbO4 samples, indicating that there is no infuence of the Y-to-Lu ratio in the host niobate material on the luminescence kinetics.",
journal = "Applied Physics A",
title = "Emission color tunability of dysprosium-activated YNbO4–LuNbO4-mixed phosphors",
volume = "130",
number = "2",
pages = "107",
doi = "10.1007/s00339-023-07271-z"
}
Đačanin-Far, L., Dramićanin, T., Medić, M., Ristić, Z., Periša, J., Đorđević, V., Antić, Ž.,& Dramićanin, M.. (2024). Emission color tunability of dysprosium-activated YNbO4–LuNbO4-mixed phosphors. in Applied Physics A, 130(2), 107.
https://doi.org/10.1007/s00339-023-07271-z
Đačanin-Far L, Dramićanin T, Medić M, Ristić Z, Periša J, Đorđević V, Antić Ž, Dramićanin M. Emission color tunability of dysprosium-activated YNbO4–LuNbO4-mixed phosphors. in Applied Physics A. 2024;130(2):107.
doi:10.1007/s00339-023-07271-z .
Đačanin-Far, Ljubica, Dramićanin, Tatjana, Medić, Mina, Ristić, Zoran, Periša, Jovana, Đorđević, Vesna, Antić, Željka, Dramićanin, Miroslav, "Emission color tunability of dysprosium-activated YNbO4–LuNbO4-mixed phosphors" in Applied Physics A, 130, no. 2 (2024):107,
https://doi.org/10.1007/s00339-023-07271-z . .
1

Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations

Đačanin Far, Ljubica; Ćirić, Aleksandar; Sekulić, Milica; Periša, Jovana; Ristić, Zoran; Antić, Željka; Dramićanin, Miroslav

(2023)

TY  - JOUR
AU  - Đačanin Far, Ljubica
AU  - Ćirić, Aleksandar
AU  - Sekulić, Milica
AU  - Periša, Jovana
AU  - Ristić, Zoran
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10551
AB  - YNbO4:xEu3+ powders (0.1, 0.25, 0.5, 0.75, 1, 3, 5, 7.5, 10, 15, 20 mol %) were synthesized by a solid-state reaction, after homogenization in a vibrational mill. All the samples crystallize in a monoclinic Fergusonite-beta-(Y) structure (C2/c space group), with 45–65 nm crystallite sizes and show a strong orange/red luminescence with 5D0 excited state lifetimes of around 0.6 ms. Photoluminescence emission spectra showed no concentration quenching within the examined concentration range. Judd–Ofelt intensity parameters show a slight increase with rising concentration, up to Ω2 = 8.13∙10−20 cm2, Ω4 = 2.67∙10−20 cm2, and Ω6 is concentration invariant with the 0.35∙10−20 cm2 value. Emission lifetimes of the 5D0 state are almost constant with ∼0.6 ms, and a slight decrease is observed with the highest concentrations. The intrinsic quantum yield of all the samples is about 0.5.
T2  - Optik
T1  - Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations
VL  - 272
SP  - 170398
DO  - 10.1016/j.ijleo.2022.170398
ER  - 
@article{
author = "Đačanin Far, Ljubica and Ćirić, Aleksandar and Sekulić, Milica and Periša, Jovana and Ristić, Zoran and Antić, Željka and Dramićanin, Miroslav",
year = "2023",
abstract = "YNbO4:xEu3+ powders (0.1, 0.25, 0.5, 0.75, 1, 3, 5, 7.5, 10, 15, 20 mol %) were synthesized by a solid-state reaction, after homogenization in a vibrational mill. All the samples crystallize in a monoclinic Fergusonite-beta-(Y) structure (C2/c space group), with 45–65 nm crystallite sizes and show a strong orange/red luminescence with 5D0 excited state lifetimes of around 0.6 ms. Photoluminescence emission spectra showed no concentration quenching within the examined concentration range. Judd–Ofelt intensity parameters show a slight increase with rising concentration, up to Ω2 = 8.13∙10−20 cm2, Ω4 = 2.67∙10−20 cm2, and Ω6 is concentration invariant with the 0.35∙10−20 cm2 value. Emission lifetimes of the 5D0 state are almost constant with ∼0.6 ms, and a slight decrease is observed with the highest concentrations. The intrinsic quantum yield of all the samples is about 0.5.",
journal = "Optik",
title = "Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations",
volume = "272",
pages = "170398",
doi = "10.1016/j.ijleo.2022.170398"
}
Đačanin Far, L., Ćirić, A., Sekulić, M., Periša, J., Ristić, Z., Antić, Ž.,& Dramićanin, M.. (2023). Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations. in Optik, 272, 170398.
https://doi.org/10.1016/j.ijleo.2022.170398
Đačanin Far L, Ćirić A, Sekulić M, Periša J, Ristić Z, Antić Ž, Dramićanin M. Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations. in Optik. 2023;272:170398.
doi:10.1016/j.ijleo.2022.170398 .
Đačanin Far, Ljubica, Ćirić, Aleksandar, Sekulić, Milica, Periša, Jovana, Ristić, Zoran, Antić, Željka, Dramićanin, Miroslav, "Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations" in Optik, 272 (2023):170398,
https://doi.org/10.1016/j.ijleo.2022.170398 . .
1
1

Luminescent Eu3+ doped SrF2 nanoparticles for fluorescent detection of fertilizers

Đačanin Far, Ljubica; Zeković, Ivana; Periša, Jovana; Ristić, Zoran; Alodhayb, Abdullah; Dramićanin, Miroslav; Antić, Željka

(2023)

TY  - JOUR
AU  - Đačanin Far, Ljubica
AU  - Zeković, Ivana
AU  - Periša, Jovana
AU  - Ristić, Zoran
AU  - Alodhayb, Abdullah
AU  - Dramićanin, Miroslav
AU  - Antić, Željka
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11339
AB  - Luminescent Eu3+-doped SrF2 nanoparticles were synthesized using microwave-assisted synthesis. Their surfaces were modified either by polyethylene glycol or mercaptopropionic acid to enhance their dispersibility in aqueous media and colloidal formation. X-ray diffraction analysis confirmed single-phase cubic structure in both types of hydrophilic-modified Sr0.9Eu0.1F2 luminescent powders. The average crystallite size of nanoparticles is found to be ∼13 nm. Scanning electron microscopy of the representative PEG2000-modified sample revealed that particles form agglomerates composed of densely packed nanoparticles. The microstructure at a local level was investigated by transmission electron microscopy showing the presence of sphere-like nanoparticles with an average particle size of 12.5 nm and 14 nm for PEG-modified and MPA-modified Sr0.9Eu0.1F2, respectively. Both PEG2000 and MPA-modified Sr0.9Eu0.1F2 water dispersions show strong red Eu3+ emission under 405 nm excitation that is quenched in the presence of the primary NP fertilizer, ammonium dihydrogen phosphate, NH4H2PO4. The limit of detection was calculated to be ∼19 mM for both hydrophilic-modified Sr0.9Eu0.1F2 luminescent nanoparticles.
T2  - Optical Materials
T1  - Luminescent Eu3+ doped SrF2 nanoparticles for fluorescent detection of fertilizers
VL  - 142
SP  - 114061
DO  - 10.1016/j.optmat.2023.114061
ER  - 
@article{
author = "Đačanin Far, Ljubica and Zeković, Ivana and Periša, Jovana and Ristić, Zoran and Alodhayb, Abdullah and Dramićanin, Miroslav and Antić, Željka",
year = "2023",
abstract = "Luminescent Eu3+-doped SrF2 nanoparticles were synthesized using microwave-assisted synthesis. Their surfaces were modified either by polyethylene glycol or mercaptopropionic acid to enhance their dispersibility in aqueous media and colloidal formation. X-ray diffraction analysis confirmed single-phase cubic structure in both types of hydrophilic-modified Sr0.9Eu0.1F2 luminescent powders. The average crystallite size of nanoparticles is found to be ∼13 nm. Scanning electron microscopy of the representative PEG2000-modified sample revealed that particles form agglomerates composed of densely packed nanoparticles. The microstructure at a local level was investigated by transmission electron microscopy showing the presence of sphere-like nanoparticles with an average particle size of 12.5 nm and 14 nm for PEG-modified and MPA-modified Sr0.9Eu0.1F2, respectively. Both PEG2000 and MPA-modified Sr0.9Eu0.1F2 water dispersions show strong red Eu3+ emission under 405 nm excitation that is quenched in the presence of the primary NP fertilizer, ammonium dihydrogen phosphate, NH4H2PO4. The limit of detection was calculated to be ∼19 mM for both hydrophilic-modified Sr0.9Eu0.1F2 luminescent nanoparticles.",
journal = "Optical Materials",
title = "Luminescent Eu3+ doped SrF2 nanoparticles for fluorescent detection of fertilizers",
volume = "142",
pages = "114061",
doi = "10.1016/j.optmat.2023.114061"
}
Đačanin Far, L., Zeković, I., Periša, J., Ristić, Z., Alodhayb, A., Dramićanin, M.,& Antić, Ž.. (2023). Luminescent Eu3+ doped SrF2 nanoparticles for fluorescent detection of fertilizers. in Optical Materials, 142, 114061.
https://doi.org/10.1016/j.optmat.2023.114061
Đačanin Far L, Zeković I, Periša J, Ristić Z, Alodhayb A, Dramićanin M, Antić Ž. Luminescent Eu3+ doped SrF2 nanoparticles for fluorescent detection of fertilizers. in Optical Materials. 2023;142:114061.
doi:10.1016/j.optmat.2023.114061 .
Đačanin Far, Ljubica, Zeković, Ivana, Periša, Jovana, Ristić, Zoran, Alodhayb, Abdullah, Dramićanin, Miroslav, Antić, Željka, "Luminescent Eu3+ doped SrF2 nanoparticles for fluorescent detection of fertilizers" in Optical Materials, 142 (2023):114061,
https://doi.org/10.1016/j.optmat.2023.114061 . .
1
1

Luminescence Thermometry with Nanoparticles: A Review

Đačanin Far, Ljubica; Dramićanin, Miroslav

(2023)

TY  - JOUR
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12043
AB  - Luminescence thermometry has emerged as a very versatile optical technique for remote temperature measurements, exhibiting a wide range of applicability spanning from cryogenic temperatures to 2000 K. This technology has found extensive utilization across many disciplines. In the last thirty years, there has been significant growth in the field of luminous thermometry. This growth has been accompanied by the development of temperature read-out procedures, the creation of luminescent materials for very sensitive temperature probes, and advancements in theoretical understanding. This review article primarily centers on luminescent nanoparticles employed in the field of luminescence thermometry. In this paper, we provide a comprehensive survey of the recent literature pertaining to the utilization of lanthanide and transition metal nanophosphors, semiconductor quantum dots, polymer nanoparticles, carbon dots, and nanodiamonds for luminescence thermometry. In addition, we engage in a discussion regarding the benefits and limitations of nanoparticles in comparison with conventional, microsized probes for their application in luminescent thermometry.
T2  - Nanomaterials
T1  - Luminescence Thermometry with Nanoparticles: A Review
VL  - 13
IS  - 21
SP  - 2904
DO  - 10.3390/nano13212904
ER  - 
@article{
author = "Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2023",
abstract = "Luminescence thermometry has emerged as a very versatile optical technique for remote temperature measurements, exhibiting a wide range of applicability spanning from cryogenic temperatures to 2000 K. This technology has found extensive utilization across many disciplines. In the last thirty years, there has been significant growth in the field of luminous thermometry. This growth has been accompanied by the development of temperature read-out procedures, the creation of luminescent materials for very sensitive temperature probes, and advancements in theoretical understanding. This review article primarily centers on luminescent nanoparticles employed in the field of luminescence thermometry. In this paper, we provide a comprehensive survey of the recent literature pertaining to the utilization of lanthanide and transition metal nanophosphors, semiconductor quantum dots, polymer nanoparticles, carbon dots, and nanodiamonds for luminescence thermometry. In addition, we engage in a discussion regarding the benefits and limitations of nanoparticles in comparison with conventional, microsized probes for their application in luminescent thermometry.",
journal = "Nanomaterials",
title = "Luminescence Thermometry with Nanoparticles: A Review",
volume = "13",
number = "21",
pages = "2904",
doi = "10.3390/nano13212904"
}
Đačanin Far, L.,& Dramićanin, M.. (2023). Luminescence Thermometry with Nanoparticles: A Review. in Nanomaterials, 13(21), 2904.
https://doi.org/10.3390/nano13212904
Đačanin Far L, Dramićanin M. Luminescence Thermometry with Nanoparticles: A Review. in Nanomaterials. 2023;13(21):2904.
doi:10.3390/nano13212904 .
Đačanin Far, Ljubica, Dramićanin, Miroslav, "Luminescence Thermometry with Nanoparticles: A Review" in Nanomaterials, 13, no. 21 (2023):2904,
https://doi.org/10.3390/nano13212904 . .
1
3

Experimental and computational study of polycrystalline LiInO2 structure vibration properties

Vigi, Robert; Ivetić, Tamara B.; Đačanin Far, Ljubica; Raonić, Radoš R.; Jović, Branislav; Kordić, Branko; Lukić-Petrović, Svetlana R.

(2023)

TY  - JOUR
AU  - Vigi, Robert
AU  - Ivetić, Tamara B.
AU  - Đačanin Far, Ljubica
AU  - Raonić, Radoš R.
AU  - Jović, Branislav
AU  - Kordić, Branko
AU  - Lukić-Petrović, Svetlana R.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11207
AB  - Polycrystalline LiInO2 was synthesized by the solid-state method and was characterized using combined experimental and computational methods. The results of experimental measurements were compared with the computational analysis of lattice vibrations based on DFT calculations. A good agreement between experimental and theoretical frequencies of LiInO2 structure vibration mode was obtained. © 2023, Publishing House of the Romanian Academy. All rights reserved.
T2  - Romanian Reports in Physics
T1  - Experimental and computational study of polycrystalline LiInO2 structure vibration properties
VL  - 75
IS  - 2
DO  - 10.2139/ssrn.4233106
ER  - 
@article{
author = "Vigi, Robert and Ivetić, Tamara B. and Đačanin Far, Ljubica and Raonić, Radoš R. and Jović, Branislav and Kordić, Branko and Lukić-Petrović, Svetlana R.",
year = "2023",
abstract = "Polycrystalline LiInO2 was synthesized by the solid-state method and was characterized using combined experimental and computational methods. The results of experimental measurements were compared with the computational analysis of lattice vibrations based on DFT calculations. A good agreement between experimental and theoretical frequencies of LiInO2 structure vibration mode was obtained. © 2023, Publishing House of the Romanian Academy. All rights reserved.",
journal = "Romanian Reports in Physics",
title = "Experimental and computational study of polycrystalline LiInO2 structure vibration properties",
volume = "75",
number = "2",
doi = "10.2139/ssrn.4233106"
}
Vigi, R., Ivetić, T. B., Đačanin Far, L., Raonić, R. R., Jović, B., Kordić, B.,& Lukić-Petrović, S. R.. (2023). Experimental and computational study of polycrystalline LiInO2 structure vibration properties. in Romanian Reports in Physics, 75(2).
https://doi.org/10.2139/ssrn.4233106
Vigi R, Ivetić TB, Đačanin Far L, Raonić RR, Jović B, Kordić B, Lukić-Petrović SR. Experimental and computational study of polycrystalline LiInO2 structure vibration properties. in Romanian Reports in Physics. 2023;75(2).
doi:10.2139/ssrn.4233106 .
Vigi, Robert, Ivetić, Tamara B., Đačanin Far, Ljubica, Raonić, Radoš R., Jović, Branislav, Kordić, Branko, Lukić-Petrović, Svetlana R., "Experimental and computational study of polycrystalline LiInO2 structure vibration properties" in Romanian Reports in Physics, 75, no. 2 (2023),
https://doi.org/10.2139/ssrn.4233106 . .

Photoluminescence of the Eu3+-Activated YxLu1−xNbO4 (x = 0, 0.25, 0.5, 0.75, 1) Solid-Solution Phosphors

Sekulić, Milica; Dramićanin, Tatjana; Ćirić, Aleksandar; Đačanin Far, Ljubica; Dramićanin, Miroslav; Đorđević, Vesna R.

(2022)

TY  - JOUR
AU  - Sekulić, Milica
AU  - Dramićanin, Tatjana
AU  - Ćirić, Aleksandar
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
AU  - Đorđević, Vesna R.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10238
AB  - Eu3+-doped YxLu1−xNbO4 (x = 0, 0.25, 0.5, 0.75, 1) were prepared by the solid-state reaction method. YNbO4:Eu3+ and LuNbO4:Eu3+ crystallize as beta-Fergusonite (SG no. 15) in 1–10 μm diameter particles. Photoluminescence emission spectra show a slight linear variation of emission energies and intensities with the solid-solution composition in terms of Y/Lu content. The energy difference between Stark sublevels of 5D0→7F1 emission increases, while the asymmetry ratio decreases with the composition. From the dispersion relations of pure YNbO4 and LuNbO4, the refractive index values for each concentration and emission wavelength are estimated. The Ω2 Judd–Ofelt parameter shows a linear increase from 6.75 to 7.48 × 10−20 cm2 from x = 0 to 1, respectively, and Ω4 from 2.69 to 2.95 × 10−20 cm2. The lowest non-radiative deexcitation rate was observed with x = 1, and thus LuNbO4:Eu3+ is more efficient phosphor than YNbO4:Eu3+.
T2  - Crystals
T1  - Photoluminescence of the Eu3+-Activated YxLu1−xNbO4 (x = 0, 0.25, 0.5, 0.75, 1) Solid-Solution Phosphors
VL  - 12
IS  - 3
SP  - 427
DO  - 10.3390/cryst12030427
ER  - 
@article{
author = "Sekulić, Milica and Dramićanin, Tatjana and Ćirić, Aleksandar and Đačanin Far, Ljubica and Dramićanin, Miroslav and Đorđević, Vesna R.",
year = "2022",
abstract = "Eu3+-doped YxLu1−xNbO4 (x = 0, 0.25, 0.5, 0.75, 1) were prepared by the solid-state reaction method. YNbO4:Eu3+ and LuNbO4:Eu3+ crystallize as beta-Fergusonite (SG no. 15) in 1–10 μm diameter particles. Photoluminescence emission spectra show a slight linear variation of emission energies and intensities with the solid-solution composition in terms of Y/Lu content. The energy difference between Stark sublevels of 5D0→7F1 emission increases, while the asymmetry ratio decreases with the composition. From the dispersion relations of pure YNbO4 and LuNbO4, the refractive index values for each concentration and emission wavelength are estimated. The Ω2 Judd–Ofelt parameter shows a linear increase from 6.75 to 7.48 × 10−20 cm2 from x = 0 to 1, respectively, and Ω4 from 2.69 to 2.95 × 10−20 cm2. The lowest non-radiative deexcitation rate was observed with x = 1, and thus LuNbO4:Eu3+ is more efficient phosphor than YNbO4:Eu3+.",
journal = "Crystals",
title = "Photoluminescence of the Eu3+-Activated YxLu1−xNbO4 (x = 0, 0.25, 0.5, 0.75, 1) Solid-Solution Phosphors",
volume = "12",
number = "3",
pages = "427",
doi = "10.3390/cryst12030427"
}
Sekulić, M., Dramićanin, T., Ćirić, A., Đačanin Far, L., Dramićanin, M.,& Đorđević, V. R.. (2022). Photoluminescence of the Eu3+-Activated YxLu1−xNbO4 (x = 0, 0.25, 0.5, 0.75, 1) Solid-Solution Phosphors. in Crystals, 12(3), 427.
https://doi.org/10.3390/cryst12030427
Sekulić M, Dramićanin T, Ćirić A, Đačanin Far L, Dramićanin M, Đorđević VR. Photoluminescence of the Eu3+-Activated YxLu1−xNbO4 (x = 0, 0.25, 0.5, 0.75, 1) Solid-Solution Phosphors. in Crystals. 2022;12(3):427.
doi:10.3390/cryst12030427 .
Sekulić, Milica, Dramićanin, Tatjana, Ćirić, Aleksandar, Đačanin Far, Ljubica, Dramićanin, Miroslav, Đorđević, Vesna R., "Photoluminescence of the Eu3+-Activated YxLu1−xNbO4 (x = 0, 0.25, 0.5, 0.75, 1) Solid-Solution Phosphors" in Crystals, 12, no. 3 (2022):427,
https://doi.org/10.3390/cryst12030427 . .
8
6

Photoluminescence of Y3NbO7:Eu3+ powders

Đačanin Far, Ljubica; Ćirić, Aleksandar; Ristić, Zoran; Periša, Jovana; Dramićanin, Tatjana; Lukić-Petrović, Svetlana R.; Dramićanin, Miroslav

(2022)

TY  - JOUR
AU  - Đačanin Far, Ljubica
AU  - Ćirić, Aleksandar
AU  - Ristić, Zoran
AU  - Periša, Jovana
AU  - Dramićanin, Tatjana
AU  - Lukić-Petrović, Svetlana R.
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10342
AB  - Y3NbO7:xEu3+ powders (x = 0.25, 0.5, 0.75, 2, 3, 5, 10 at%) were synthesized by a two-step vibrational milling, alternating with annealing. All the samples crystallize as fluorite-type structure (space group Fm3‾m), with crystallite size 50–60 nm and show a strong orange/red luminescence with an excited state lifetime around 1.2 ms. Photoluminescence excitation and emission spectra show rapid intensity decline after 3 at% of Eu3+ content, indicating this concentration as critical for the concentration quenching, and we predicted multipolar interaction as the dominant mechanism behind it. Judd–Ofelt intensity parameters (Ω2 = 0.941∙10−20 cm2, Ω4 = 0.277∙10−20 cm2, Ω6 = 0.277∙10−20 cm2) were obtained from the excitation spectrum of Y3NbO7:3 at%Eu3+. The emission of this luminescent powder is characterized by radiative and nonradiative lifetimes of 2.3 ms and 2.4 ms, respectively, and an intrinsic quantum yield of 51.5%.
T2  - Ceramics International
T1  - Photoluminescence of Y3NbO7:Eu3+ powders
DO  - 10.1016/j.ceramint.2022.06.130
ER  - 
@article{
author = "Đačanin Far, Ljubica and Ćirić, Aleksandar and Ristić, Zoran and Periša, Jovana and Dramićanin, Tatjana and Lukić-Petrović, Svetlana R. and Dramićanin, Miroslav",
year = "2022",
abstract = "Y3NbO7:xEu3+ powders (x = 0.25, 0.5, 0.75, 2, 3, 5, 10 at%) were synthesized by a two-step vibrational milling, alternating with annealing. All the samples crystallize as fluorite-type structure (space group Fm3‾m), with crystallite size 50–60 nm and show a strong orange/red luminescence with an excited state lifetime around 1.2 ms. Photoluminescence excitation and emission spectra show rapid intensity decline after 3 at% of Eu3+ content, indicating this concentration as critical for the concentration quenching, and we predicted multipolar interaction as the dominant mechanism behind it. Judd–Ofelt intensity parameters (Ω2 = 0.941∙10−20 cm2, Ω4 = 0.277∙10−20 cm2, Ω6 = 0.277∙10−20 cm2) were obtained from the excitation spectrum of Y3NbO7:3 at%Eu3+. The emission of this luminescent powder is characterized by radiative and nonradiative lifetimes of 2.3 ms and 2.4 ms, respectively, and an intrinsic quantum yield of 51.5%.",
journal = "Ceramics International",
title = "Photoluminescence of Y3NbO7:Eu3+ powders",
doi = "10.1016/j.ceramint.2022.06.130"
}
Đačanin Far, L., Ćirić, A., Ristić, Z., Periša, J., Dramićanin, T., Lukić-Petrović, S. R.,& Dramićanin, M.. (2022). Photoluminescence of Y3NbO7:Eu3+ powders. in Ceramics International.
https://doi.org/10.1016/j.ceramint.2022.06.130
Đačanin Far L, Ćirić A, Ristić Z, Periša J, Dramićanin T, Lukić-Petrović SR, Dramićanin M. Photoluminescence of Y3NbO7:Eu3+ powders. in Ceramics International. 2022;.
doi:10.1016/j.ceramint.2022.06.130 .
Đačanin Far, Ljubica, Ćirić, Aleksandar, Ristić, Zoran, Periša, Jovana, Dramićanin, Tatjana, Lukić-Petrović, Svetlana R., Dramićanin, Miroslav, "Photoluminescence of Y3NbO7:Eu3+ powders" in Ceramics International (2022),
https://doi.org/10.1016/j.ceramint.2022.06.130 . .
7
4

Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range

Kuzman, Sanja; Ristić, Zoran; Antić, Željka; Đačanin Far, Ljubica; Dramićanin, Miroslav

(Society for science development of Serbia, Belgrade, 2022)

TY  - CONF
AU  - Kuzman, Sanja
AU  - Ristić, Zoran
AU  - Antić, Željka
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11340
AB  - The Mn5+-activated Ca6Ba(PO4)4O phosphor is described in this paper as a versatile nearinfrared luminescence thermometry probe in a physiological temperature range. It is focused on several steady-state approaches to luminescence thermometry operating entirely in the first (excitation ex=635 nm) and the second (emission) biological transparency windows. This material was synthesized by a solid-state reaction using CaCO3, BaCO3, (NH4)H2PO4 and MnO as precursor materials. Starting chemicals were thoroughly mixed in an agate mortar for 1 hour with an appropriate amount of etanol. A mixture of the raw materials was heated at 600⁰C for 6 hours, ground in an agate mortar, and further calcinated at 1280⁰C for 10h. The exploited features of Ca6Ba(PO4)4O:Mn5+ emission spectra were (Figure 1): i) luminescence intensity ratio (LIR) between spin-allowed 3T2 → 3A2 and spin forbidden 1E → 3A2 (Sr MAX=2.04%K-1 @ 20 oC, dT<0.36 K); ii) LIR between Stokes peak corresponding to the bending deformation vibronic mode (O-Mn-O) and spin forbidden 1E → 3A2 (Sr MAX=0.57 %K-1 @ 100 oC, dT<2 K above 50 oC); iii) LIR between Stokes and Anti-Stokes peaks corresponding to the bending deformation vibronic mode (O-Mn-O) (Sr MAX=0.52 %K-1 @ 100 oC, dT3 K); iv) red-shift of the position of the 1E → 3A2 peak (Sa=0.21 cm-1K -1, dT<0.33 K) and v) the broadening of the full with at half maximum (FWHM) of the same peak with the temperature increase (Sr MAX=0.34 %K-1 @ 100 oC, dT<0.38 K). The steady-state approach facilitated quick measurements of emission spectra and, consequently, a large number of acquired spectra (50) for each temperature point, which were used to experimentally determine the temperature resolution for each thermometry method.
PB  - Society for science development of Serbia, Belgrade
C3  - The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors
T1  - Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11340
ER  - 
@conference{
author = "Kuzman, Sanja and Ristić, Zoran and Antić, Željka and Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2022",
abstract = "The Mn5+-activated Ca6Ba(PO4)4O phosphor is described in this paper as a versatile nearinfrared luminescence thermometry probe in a physiological temperature range. It is focused on several steady-state approaches to luminescence thermometry operating entirely in the first (excitation ex=635 nm) and the second (emission) biological transparency windows. This material was synthesized by a solid-state reaction using CaCO3, BaCO3, (NH4)H2PO4 and MnO as precursor materials. Starting chemicals were thoroughly mixed in an agate mortar for 1 hour with an appropriate amount of etanol. A mixture of the raw materials was heated at 600⁰C for 6 hours, ground in an agate mortar, and further calcinated at 1280⁰C for 10h. The exploited features of Ca6Ba(PO4)4O:Mn5+ emission spectra were (Figure 1): i) luminescence intensity ratio (LIR) between spin-allowed 3T2 → 3A2 and spin forbidden 1E → 3A2 (Sr MAX=2.04%K-1 @ 20 oC, dT<0.36 K); ii) LIR between Stokes peak corresponding to the bending deformation vibronic mode (O-Mn-O) and spin forbidden 1E → 3A2 (Sr MAX=0.57 %K-1 @ 100 oC, dT<2 K above 50 oC); iii) LIR between Stokes and Anti-Stokes peaks corresponding to the bending deformation vibronic mode (O-Mn-O) (Sr MAX=0.52 %K-1 @ 100 oC, dT3 K); iv) red-shift of the position of the 1E → 3A2 peak (Sa=0.21 cm-1K -1, dT<0.33 K) and v) the broadening of the full with at half maximum (FWHM) of the same peak with the temperature increase (Sr MAX=0.34 %K-1 @ 100 oC, dT<0.38 K). The steady-state approach facilitated quick measurements of emission spectra and, consequently, a large number of acquired spectra (50) for each temperature point, which were used to experimentally determine the temperature resolution for each thermometry method.",
publisher = "Society for science development of Serbia, Belgrade",
journal = "The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors",
title = "Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11340"
}
Kuzman, S., Ristić, Z., Antić, Ž., Đačanin Far, L.,& Dramićanin, M.. (2022). Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range. in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors
Society for science development of Serbia, Belgrade..
https://hdl.handle.net/21.15107/rcub_vinar_11340
Kuzman S, Ristić Z, Antić Ž, Đačanin Far L, Dramićanin M. Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range. in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors. 2022;.
https://hdl.handle.net/21.15107/rcub_vinar_11340 .
Kuzman, Sanja, Ristić, Zoran, Antić, Željka, Đačanin Far, Ljubica, Dramićanin, Miroslav, "Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range" in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors (2022),
https://hdl.handle.net/21.15107/rcub_vinar_11340 .

Photoluminescent Properties of the Eu3+ ion in YNbO4-LuNbO4 Solid Solution

Sekulić, Milica; Đačanin Far, Ljubica; Dramićanin, Tatjana; Ćirić, Aleksandar; Dramićanin, Miroslav; Đorđević, Vesna

(Society for science development of Serbia, Belgrade, 2022)

TY  - CONF
AU  - Sekulić, Milica
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Tatjana
AU  - Ćirić, Aleksandar
AU  - Dramićanin, Miroslav
AU  - Đorđević, Vesna
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11341
AB  - Lanthanide (Ln) activated phosphors are a major topic in both basic and applied science. The trivalent europium ion (Eu3+) is well recognized for its intense luminescence in the orange/red spectral region, making it useful for a wide range of applications. Because Eu3+ has an even number of electrons in its 4f shell ([Xe]4f 6 ), the ion has non-degenerated ground (7F0) and excited (5D0) energy states, as well as non-overlapping 2S+1LJ multiplets, resulting in emission spectra that are predictable in relation to the host material site symmetry. The solid-state reaction synthesis method was used to make a set of five Eu-doped YxLu1- xNbO4 samples (x=0–1) with a fixed Eu concentration (5%). All the structures crystallize as beta-Fergusonite, in which the Eu ion replaces the Y or Lu ion in a large, low-symmetry octahedron. The excitation and emission spectra of the Eu3+ ion in all composition hosts show characteristic f-f transitions from which Stark energy levels were calculated. Specific features and energy positions of the distinctive 5D0→7F1 magnetic dipole transition were determined when measured with higher resolution and spectra deconvolution was utilized. The maximum ΔE splitting of the 7F1 manifold's Stark splitting and the asymmetry ratio R all show Y/Lu content-dependent trends. Calculations based on Judd-Ofelt theory were utilized to determine specific quantities. The lowest non-radiative deexcitation rate was observed with x = 1, resulting in the conclusion that LuNbO4 is a better host-matrix for Eu3+ emission than other compositions.
PB  - Society for science development of Serbia, Belgrade
C3  - The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors
T1  - Photoluminescent Properties of the Eu3+ ion in YNbO4-LuNbO4 Solid Solution
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11341
ER  - 
@conference{
author = "Sekulić, Milica and Đačanin Far, Ljubica and Dramićanin, Tatjana and Ćirić, Aleksandar and Dramićanin, Miroslav and Đorđević, Vesna",
year = "2022",
abstract = "Lanthanide (Ln) activated phosphors are a major topic in both basic and applied science. The trivalent europium ion (Eu3+) is well recognized for its intense luminescence in the orange/red spectral region, making it useful for a wide range of applications. Because Eu3+ has an even number of electrons in its 4f shell ([Xe]4f 6 ), the ion has non-degenerated ground (7F0) and excited (5D0) energy states, as well as non-overlapping 2S+1LJ multiplets, resulting in emission spectra that are predictable in relation to the host material site symmetry. The solid-state reaction synthesis method was used to make a set of five Eu-doped YxLu1- xNbO4 samples (x=0–1) with a fixed Eu concentration (5%). All the structures crystallize as beta-Fergusonite, in which the Eu ion replaces the Y or Lu ion in a large, low-symmetry octahedron. The excitation and emission spectra of the Eu3+ ion in all composition hosts show characteristic f-f transitions from which Stark energy levels were calculated. Specific features and energy positions of the distinctive 5D0→7F1 magnetic dipole transition were determined when measured with higher resolution and spectra deconvolution was utilized. The maximum ΔE splitting of the 7F1 manifold's Stark splitting and the asymmetry ratio R all show Y/Lu content-dependent trends. Calculations based on Judd-Ofelt theory were utilized to determine specific quantities. The lowest non-radiative deexcitation rate was observed with x = 1, resulting in the conclusion that LuNbO4 is a better host-matrix for Eu3+ emission than other compositions.",
publisher = "Society for science development of Serbia, Belgrade",
journal = "The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors",
title = "Photoluminescent Properties of the Eu3+ ion in YNbO4-LuNbO4 Solid Solution",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11341"
}
Sekulić, M., Đačanin Far, L., Dramićanin, T., Ćirić, A., Dramićanin, M.,& Đorđević, V.. (2022). Photoluminescent Properties of the Eu3+ ion in YNbO4-LuNbO4 Solid Solution. in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors
Society for science development of Serbia, Belgrade..
https://hdl.handle.net/21.15107/rcub_vinar_11341
Sekulić M, Đačanin Far L, Dramićanin T, Ćirić A, Dramićanin M, Đorđević V. Photoluminescent Properties of the Eu3+ ion in YNbO4-LuNbO4 Solid Solution. in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors. 2022;.
https://hdl.handle.net/21.15107/rcub_vinar_11341 .
Sekulić, Milica, Đačanin Far, Ljubica, Dramićanin, Tatjana, Ćirić, Aleksandar, Dramićanin, Miroslav, Đorđević, Vesna, "Photoluminescent Properties of the Eu3+ ion in YNbO4-LuNbO4 Solid Solution" in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors (2022),
https://hdl.handle.net/21.15107/rcub_vinar_11341 .

Combined experimental and DFT study of lithium-indium-oxide structure and vibrational properties

Vigi, Robert; Đačanin Far, Ljubica; Lukić-Petrović, Svetlana; Ivetić, Tamara

(Szeged : University of Szeged, 2021)

TY  - CONF
AU  - Vigi, Robert
AU  - Đačanin Far, Ljubica
AU  - Lukić-Petrović, Svetlana
AU  - Ivetić, Tamara
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11430
AB  - A promising lithium-indium-oxide (LiInO2) wide band-gap semiconductor for scintillating detection, photoluminescence, and photocatalysis [1-3] was prepared by a mechanochemical solid-state synthetic procedure that can be found elsewhere [3]. Its structure and morphology were investigated by using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectroscopy. SEM images show agglomerates of relatively uniform size of around 300 nm spherical-shaped particles of LiInO2 powder, while the XRD pattern confirmed the formation of the nanocrystalline tetragonal structure withamdI /41 space group (no. 141) symmetry. Detailed vibration analysis, together with the assignments of the band modes, was performed through the best-fit match of the experimental and density functional theory (DFT) calculated Raman spectrum. Geometry optimizations and vibrational frequencies calculations were conducted using B97-1 functional correlation [4] and LanL2DZ was used as a basis set.
PB  - Szeged : University of Szeged
C3  - 27th International Symposium on Analytical and Environmental Problems : Proceedings; November 22-23, 2021; Szeged, Hungary
T1  - Combined experimental and DFT study of lithium-indium-oxide structure and vibrational properties
SP  - 362
EP  - 362
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11430
ER  - 
@conference{
author = "Vigi, Robert and Đačanin Far, Ljubica and Lukić-Petrović, Svetlana and Ivetić, Tamara",
year = "2021",
abstract = "A promising lithium-indium-oxide (LiInO2) wide band-gap semiconductor for scintillating detection, photoluminescence, and photocatalysis [1-3] was prepared by a mechanochemical solid-state synthetic procedure that can be found elsewhere [3]. Its structure and morphology were investigated by using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectroscopy. SEM images show agglomerates of relatively uniform size of around 300 nm spherical-shaped particles of LiInO2 powder, while the XRD pattern confirmed the formation of the nanocrystalline tetragonal structure withamdI /41 space group (no. 141) symmetry. Detailed vibration analysis, together with the assignments of the band modes, was performed through the best-fit match of the experimental and density functional theory (DFT) calculated Raman spectrum. Geometry optimizations and vibrational frequencies calculations were conducted using B97-1 functional correlation [4] and LanL2DZ was used as a basis set.",
publisher = "Szeged : University of Szeged",
journal = "27th International Symposium on Analytical and Environmental Problems : Proceedings; November 22-23, 2021; Szeged, Hungary",
title = "Combined experimental and DFT study of lithium-indium-oxide structure and vibrational properties",
pages = "362-362",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11430"
}
Vigi, R., Đačanin Far, L., Lukić-Petrović, S.,& Ivetić, T.. (2021). Combined experimental and DFT study of lithium-indium-oxide structure and vibrational properties. in 27th International Symposium on Analytical and Environmental Problems : Proceedings; November 22-23, 2021; Szeged, Hungary
Szeged : University of Szeged., 362-362.
https://hdl.handle.net/21.15107/rcub_vinar_11430
Vigi R, Đačanin Far L, Lukić-Petrović S, Ivetić T. Combined experimental and DFT study of lithium-indium-oxide structure and vibrational properties. in 27th International Symposium on Analytical and Environmental Problems : Proceedings; November 22-23, 2021; Szeged, Hungary. 2021;:362-362.
https://hdl.handle.net/21.15107/rcub_vinar_11430 .
Vigi, Robert, Đačanin Far, Ljubica, Lukić-Petrović, Svetlana, Ivetić, Tamara, "Combined experimental and DFT study of lithium-indium-oxide structure and vibrational properties" in 27th International Symposium on Analytical and Environmental Problems : Proceedings; November 22-23, 2021; Szeged, Hungary (2021):362-362,
https://hdl.handle.net/21.15107/rcub_vinar_11430 .

Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders

Kuzman, Sanja; Medić, Mina M.; Đorđević, Vesna R.; Zeković, Ivana Lj.; Ristić, Zoran; Đačanin Far, Ljubica; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Kuzman, Sanja
AU  - Medić, Mina M.
AU  - Đorđević, Vesna R.
AU  - Zeković, Ivana Lj.
AU  - Ristić, Zoran
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8936
AB  - When activated by Dy3+, Na0.25K0.25Bi0.50TiO3 (NKBT), piezoelectric powders show strong luminescence in the blue and yellow spectral range. Emissions of this material can be effectively utilized for both luminescence intensity ratio and lifetime-based readouts of temperature. Photoluminescence measurements over a temperature range of 293–483 K show that the luminescence intensity ratio temperature readout has maximal relative sensitivity of 1.93% K−1 at 380 K, while the relative sensitivity of the lifetime temperature readout reaches 1.1% K−1 at 480 K. For this study, materials were synthesized by a solid-state reaction using TiO2, Bi2O3, Na2CO3, K2CO3 and Dy2O3 as precursors. X-ray diffraction measurements showed that the NKBT sample crystallized in the A-site substituted distorted perovskite rhombohedral structure (R3c symmetry). The photoluminescence spectra showed characteristic emission bands of Dy3+ ions centered at 457 nm (4I15/2 → 6H15/2), 478 nm (4F9/2 → 6H15/2), 574 nm (4F9/2 → 6H13/2) and 663 nm (4F9/2 → 6H11/2). The ratio of emissions from 4F9/2 and 4I15/2 excited states to the 6H15/2 ground state was used as a luminescence intensity ratio indicator of temperature, while the decay of emission from 4F9/2 → 6H13/2 transition was used as a lifetime indicator of temperature. CIE coordinates x = 0.326 and y = 0.361 calculated from room temperature emission spectra show the perspective of this material for use in white light emission devices.
T2  - Journal of Electronic Materials
T1  - Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders
VL  - 49
IS  - 6
SP  - 4002
EP  - 4009
DO  - 10.1007/s11664-020-08109-7
ER  - 
@article{
author = "Kuzman, Sanja and Medić, Mina M. and Đorđević, Vesna R. and Zeković, Ivana Lj. and Ristić, Zoran and Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2020",
abstract = "When activated by Dy3+, Na0.25K0.25Bi0.50TiO3 (NKBT), piezoelectric powders show strong luminescence in the blue and yellow spectral range. Emissions of this material can be effectively utilized for both luminescence intensity ratio and lifetime-based readouts of temperature. Photoluminescence measurements over a temperature range of 293–483 K show that the luminescence intensity ratio temperature readout has maximal relative sensitivity of 1.93% K−1 at 380 K, while the relative sensitivity of the lifetime temperature readout reaches 1.1% K−1 at 480 K. For this study, materials were synthesized by a solid-state reaction using TiO2, Bi2O3, Na2CO3, K2CO3 and Dy2O3 as precursors. X-ray diffraction measurements showed that the NKBT sample crystallized in the A-site substituted distorted perovskite rhombohedral structure (R3c symmetry). The photoluminescence spectra showed characteristic emission bands of Dy3+ ions centered at 457 nm (4I15/2 → 6H15/2), 478 nm (4F9/2 → 6H15/2), 574 nm (4F9/2 → 6H13/2) and 663 nm (4F9/2 → 6H11/2). The ratio of emissions from 4F9/2 and 4I15/2 excited states to the 6H15/2 ground state was used as a luminescence intensity ratio indicator of temperature, while the decay of emission from 4F9/2 → 6H13/2 transition was used as a lifetime indicator of temperature. CIE coordinates x = 0.326 and y = 0.361 calculated from room temperature emission spectra show the perspective of this material for use in white light emission devices.",
journal = "Journal of Electronic Materials",
title = "Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders",
volume = "49",
number = "6",
pages = "4002-4009",
doi = "10.1007/s11664-020-08109-7"
}
Kuzman, S., Medić, M. M., Đorđević, V. R., Zeković, I. Lj., Ristić, Z., Đačanin Far, L.,& Dramićanin, M.. (2020). Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders. in Journal of Electronic Materials, 49(6), 4002-4009.
https://doi.org/10.1007/s11664-020-08109-7
Kuzman S, Medić MM, Đorđević VR, Zeković IL, Ristić Z, Đačanin Far L, Dramićanin M. Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders. in Journal of Electronic Materials. 2020;49(6):4002-4009.
doi:10.1007/s11664-020-08109-7 .
Kuzman, Sanja, Medić, Mina M., Đorđević, Vesna R., Zeković, Ivana Lj., Ristić, Zoran, Đačanin Far, Ljubica, Dramićanin, Miroslav, "Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders" in Journal of Electronic Materials, 49, no. 6 (2020):4002-4009,
https://doi.org/10.1007/s11664-020-08109-7 . .
5
1
4

Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate

Dolić, Slobodan D; Jovanović, Dragana J.; Štrbac, Dragana; Đačanin Far, Ljubica; Dramićanin, Miroslav

(2018)

TY  - JOUR
AU  - Dolić, Slobodan D
AU  - Jovanović, Dragana J.
AU  - Štrbac, Dragana
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0272884218325227
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7960
AB  - Herein, fine powders of yellow pigments based on BiVO4 were successfully prepared in two crystalline forms, tetragonal zircon-structured and monoclinic scheelite-structured, through a ethylene glycol-assisted method subjected to a thermal treatment at two different temperatures. The obtained materials were brightly colored with different hues of yellow, exhibited high reflection in the near-infrared region and showed visible luminescence under excitation by UV light. The new preparation method had a considerable effect on chromatic properties of the prepared scheelite-structured BiVO4 pigments. The sample with the most vivid and bright shade of yellow was found to have the L*a*b* and L*C* ab h* ab color coordinates of (87.28, 0.37, 91.53) and (87.28, 91.53, 89.79), which are indicative of exceptionally good chromatic properties superior and/or comparable to those of other inorganic yellow pigments, both commercially available and recently described. In addition, the NIR reflectance of this powder was very high (≥ 80%). © 2018 Elsevier Ltd and Techna Group S.r.l.
T2  - Ceramics International
T1  - Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate
VL  - 44
IS  - 18
SP  - 22731
EP  - 22737
DO  - 10.1016/j.ceramint.2018.09.057
ER  - 
@article{
author = "Dolić, Slobodan D and Jovanović, Dragana J. and Štrbac, Dragana and Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2018",
abstract = "Herein, fine powders of yellow pigments based on BiVO4 were successfully prepared in two crystalline forms, tetragonal zircon-structured and monoclinic scheelite-structured, through a ethylene glycol-assisted method subjected to a thermal treatment at two different temperatures. The obtained materials were brightly colored with different hues of yellow, exhibited high reflection in the near-infrared region and showed visible luminescence under excitation by UV light. The new preparation method had a considerable effect on chromatic properties of the prepared scheelite-structured BiVO4 pigments. The sample with the most vivid and bright shade of yellow was found to have the L*a*b* and L*C* ab h* ab color coordinates of (87.28, 0.37, 91.53) and (87.28, 91.53, 89.79), which are indicative of exceptionally good chromatic properties superior and/or comparable to those of other inorganic yellow pigments, both commercially available and recently described. In addition, the NIR reflectance of this powder was very high (≥ 80%). © 2018 Elsevier Ltd and Techna Group S.r.l.",
journal = "Ceramics International",
title = "Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate",
volume = "44",
number = "18",
pages = "22731-22737",
doi = "10.1016/j.ceramint.2018.09.057"
}
Dolić, S. D., Jovanović, D. J., Štrbac, D., Đačanin Far, L.,& Dramićanin, M.. (2018). Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate. in Ceramics International, 44(18), 22731-22737.
https://doi.org/10.1016/j.ceramint.2018.09.057
Dolić SD, Jovanović DJ, Štrbac D, Đačanin Far L, Dramićanin M. Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate. in Ceramics International. 2018;44(18):22731-22737.
doi:10.1016/j.ceramint.2018.09.057 .
Dolić, Slobodan D, Jovanović, Dragana J., Štrbac, Dragana, Đačanin Far, Ljubica, Dramićanin, Miroslav, "Improved coloristic properties and high NIR reflectance of environment-friendly yellow pigments based on bismuth vanadate" in Ceramics International, 44, no. 18 (2018):22731-22737,
https://doi.org/10.1016/j.ceramint.2018.09.057 . .
29
14
27

Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4

(2018)

TY  - JOUR
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7587
AB  - Dy3+-and Nd3+-doped YNbO4 powders were prepared using a mechanochemical method followed by annealing, and their photoluminescent properties were examined to assess the possibility of their use in phosphor thermometry. Luminescence intensity ratio technique was used as a temperature readout scheme for both YNba(4):Dy3+ and YNbO4:Nd3+ samples. The crystalline structure of the samples is confirmed by XRD measurements, while SEM was used for the microstructural and compositional characterization. Sample doped with Dy3+ ions emitting in the blue region has been investigated in the 293-773 K temperature range and exhibits maximal relative sensitivity of 1.97% K-1 at 300 K. YNbO4:Nd3+ sample showed intense NIR emission which fall into the first biological window. When heated from 303 up to 473 K relative temperature sensitivity of 0.28%K-1 at 300 K was achieved. Values of temperature sensitivities show that YNbO4 has a large potential for the development of thermographic phosphors in the blue and NIR spectral ranges when doped with trivalent Dy and Nd, respectively. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Sensors and Actuators A: Physical
T1  - Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4
VL  - 270
SP  - 89
EP  - 96
DO  - 10.1016/j.sna.2017.12.044
ER  - 
@article{
year = "2018",
abstract = "Dy3+-and Nd3+-doped YNbO4 powders were prepared using a mechanochemical method followed by annealing, and their photoluminescent properties were examined to assess the possibility of their use in phosphor thermometry. Luminescence intensity ratio technique was used as a temperature readout scheme for both YNba(4):Dy3+ and YNbO4:Nd3+ samples. The crystalline structure of the samples is confirmed by XRD measurements, while SEM was used for the microstructural and compositional characterization. Sample doped with Dy3+ ions emitting in the blue region has been investigated in the 293-773 K temperature range and exhibits maximal relative sensitivity of 1.97% K-1 at 300 K. YNbO4:Nd3+ sample showed intense NIR emission which fall into the first biological window. When heated from 303 up to 473 K relative temperature sensitivity of 0.28%K-1 at 300 K was achieved. Values of temperature sensitivities show that YNbO4 has a large potential for the development of thermographic phosphors in the blue and NIR spectral ranges when doped with trivalent Dy and Nd, respectively. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Sensors and Actuators A: Physical",
title = "Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4",
volume = "270",
pages = "89-96",
doi = "10.1016/j.sna.2017.12.044"
}
(2018). Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4. in Sensors and Actuators A: Physical, 270, 89-96.
https://doi.org/10.1016/j.sna.2017.12.044
Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4. in Sensors and Actuators A: Physical. 2018;270:89-96.
doi:10.1016/j.sna.2017.12.044 .
"Luminescence temperature sensing in visible and NIR spectral range using Dy3+ and Nd3+ doped YNbO4" in Sensors and Actuators A: Physical, 270 (2018):89-96,
https://doi.org/10.1016/j.sna.2017.12.044 . .
62
25
54

Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties

Đačanin, Ljubica; Dramićanin, Miroslav; Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, Marko G.; Ivetić, Tamara B.; Guth, Imre O.

(2014)

TY  - JOUR
AU  - Đačanin, Ljubica
AU  - Dramićanin, Miroslav
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, Marko G.
AU  - Ivetić, Tamara B.
AU  - Guth, Imre O.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5971
AB  - In this research we prepared nanocrystalline YNbO4:Eu3+ phosphor, i.e. nanophosphor, powder using an efficient mechanochemical method followed by annealing. X-ray diffraction analysis revealed that YNbO4:Eu3+ crystallizes in monoclinic structure C2/c where, from the point of view of A and B in ABO(4) compounds, cation coordination can be noted as [6+2, 4+2]. Crystallite size of about 40 nm, was estimated using Debye Scherrers equation. Raman spectroscopy with 785 and 532 rim excitation wavelengths is performed to record a majority of materials phonon modes and to provide more in depth understanding of the YNbO4 structure. Scanning electron microscopy observations indicate that the mechanical treatment during synthesis is causing non-uniformity of the powder microstructure. High resolution photoluminescent measurements upon UV excitation showed intense emission coming from f-f transitions of the europium ion with the lifetime of 0.68 ms, suggesting that the obtained YNbO4:Eu3+ is a good potential phosphor. A comparison of emissive properties with microcrystalline YNbO4:Eu3+ was made and it showed higher values of emission intensity and lifetime of the nanocrystalline sample.(C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties
VL  - 40
IS  - 6
SP  - 8281
EP  - 8286
DO  - 10.1016/j.ceramint.2014.01.028
ER  - 
@article{
author = "Đačanin, Ljubica and Dramićanin, Miroslav and Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, Marko G. and Ivetić, Tamara B. and Guth, Imre O.",
year = "2014",
abstract = "In this research we prepared nanocrystalline YNbO4:Eu3+ phosphor, i.e. nanophosphor, powder using an efficient mechanochemical method followed by annealing. X-ray diffraction analysis revealed that YNbO4:Eu3+ crystallizes in monoclinic structure C2/c where, from the point of view of A and B in ABO(4) compounds, cation coordination can be noted as [6+2, 4+2]. Crystallite size of about 40 nm, was estimated using Debye Scherrers equation. Raman spectroscopy with 785 and 532 rim excitation wavelengths is performed to record a majority of materials phonon modes and to provide more in depth understanding of the YNbO4 structure. Scanning electron microscopy observations indicate that the mechanical treatment during synthesis is causing non-uniformity of the powder microstructure. High resolution photoluminescent measurements upon UV excitation showed intense emission coming from f-f transitions of the europium ion with the lifetime of 0.68 ms, suggesting that the obtained YNbO4:Eu3+ is a good potential phosphor. A comparison of emissive properties with microcrystalline YNbO4:Eu3+ was made and it showed higher values of emission intensity and lifetime of the nanocrystalline sample.(C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties",
volume = "40",
number = "6",
pages = "8281-8286",
doi = "10.1016/j.ceramint.2014.01.028"
}
Đačanin, L., Dramićanin, M., Lukić-Petrović, S. R., Petrović, D. M., Nikolić, M. G., Ivetić, T. B.,& Guth, I. O.. (2014). Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties. in Ceramics International, 40(6), 8281-8286.
https://doi.org/10.1016/j.ceramint.2014.01.028
Đačanin L, Dramićanin M, Lukić-Petrović SR, Petrović DM, Nikolić MG, Ivetić TB, Guth IO. Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties. in Ceramics International. 2014;40(6):8281-8286.
doi:10.1016/j.ceramint.2014.01.028 .
Đačanin, Ljubica, Dramićanin, Miroslav, Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, Marko G., Ivetić, Tamara B., Guth, Imre O., "Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties" in Ceramics International, 40, no. 6 (2014):8281-8286,
https://doi.org/10.1016/j.ceramint.2014.01.028 . .
14
9
14

Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders

Đačanin, Ljubica; Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, Marko G.; Dramićanin, Miroslav

(2014)

TY  - JOUR
AU  - Đačanin, Ljubica
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, Marko G.
AU  - Dramićanin, Miroslav
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6006
AB  - We prepared Eu3+- and Sm3+-doped YNbO4 phosphor powders using a simple solid-state reaction method and examined their photoluminescence properties in order to investigate the possibility for their usage in phosphor thermometry. Photoluminescence measurements were performed in the temperature range 303-773 K, and the fluorescence intensity ratio of the paired emissions lines was studied as a function of temperature. The results have shown that YNbO4:Eu3+ possesses the absolute sensitivity of approximately 3 Chi 10(-3) K-1 at about 700 K, while relative sensitivity changes within the range of 0.5-2.7% K-1. YNbO4:Sm3+ has the maximum sensitivity of around 7 Chi 10(-4) K-1 at about 700 K with the relative sensitivity of 0.43% K-1 around 500 K. Calculated temperature sensitivities of samples show that these materials have a good potential for the development of therrnographic phosphors. Experimental lifetime measurements recorded at 303-773 K were fitted using a temperature dependent charge transfer model, TDCT. This model yields good agreement between experimental and fitted lifetime data. The sample crystalline structure is confirmed by XRD measurements. (C) 2014 Elsevier B.V. All rights reserved.
T2  - Journal of Luminescence
T1  - Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders
VL  - 151
SP  - 82
EP  - 87
DO  - 10.1016/j.jlumin.2014.02.008
ER  - 
@article{
author = "Đačanin, Ljubica and Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, Marko G. and Dramićanin, Miroslav",
year = "2014",
abstract = "We prepared Eu3+- and Sm3+-doped YNbO4 phosphor powders using a simple solid-state reaction method and examined their photoluminescence properties in order to investigate the possibility for their usage in phosphor thermometry. Photoluminescence measurements were performed in the temperature range 303-773 K, and the fluorescence intensity ratio of the paired emissions lines was studied as a function of temperature. The results have shown that YNbO4:Eu3+ possesses the absolute sensitivity of approximately 3 Chi 10(-3) K-1 at about 700 K, while relative sensitivity changes within the range of 0.5-2.7% K-1. YNbO4:Sm3+ has the maximum sensitivity of around 7 Chi 10(-4) K-1 at about 700 K with the relative sensitivity of 0.43% K-1 around 500 K. Calculated temperature sensitivities of samples show that these materials have a good potential for the development of therrnographic phosphors. Experimental lifetime measurements recorded at 303-773 K were fitted using a temperature dependent charge transfer model, TDCT. This model yields good agreement between experimental and fitted lifetime data. The sample crystalline structure is confirmed by XRD measurements. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "Journal of Luminescence",
title = "Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders",
volume = "151",
pages = "82-87",
doi = "10.1016/j.jlumin.2014.02.008"
}
Đačanin, L., Lukić-Petrović, S. R., Petrović, D. M., Nikolić, M. G.,& Dramićanin, M.. (2014). Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders. in Journal of Luminescence, 151, 82-87.
https://doi.org/10.1016/j.jlumin.2014.02.008
Đačanin L, Lukić-Petrović SR, Petrović DM, Nikolić MG, Dramićanin M. Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders. in Journal of Luminescence. 2014;151:82-87.
doi:10.1016/j.jlumin.2014.02.008 .
Đačanin, Ljubica, Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, Marko G., Dramićanin, Miroslav, "Temperature quenching of luminescence emission in Eu3+- and Sm3+-doped YNbO4 powders" in Journal of Luminescence, 151 (2014):82-87,
https://doi.org/10.1016/j.jlumin.2014.02.008 . .
62
36
60

Eu3+ doped YNbO4 phosphor properties for fluorescence thermometry

Đačanin, Ljubica; Dramićanin, Miroslav; Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, Marko G.

(2013)

TY  - JOUR
AU  - Đačanin, Ljubica
AU  - Dramićanin, Miroslav
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, Marko G.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7007
AB  - We prepared an efficient YNbO4:Eu3+ phosphor using a simple solid-state reaction method and examined its photoluminescent properties in order to investigate the possibility for its usage in phosphor thermometry. Photoluminescence measurements were performed in the temperature range 303-803 K, and the fluorescence intensity ratio (FIR) of the paired emissions lines of Eu3+ (D-5(1) - GT F-7(1) and D-5(0) - GT F-7(1) transitions) was studied as a function of temperature. The sample crystalline structure is confirmed by XRD measurements. The material is proved to have a good potential for the development of thermographic phosphors. It exhibits maximum temperature sensitivity of approximately 3.5 x 10(-3) K-1 in the temperature region around 700 K. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Radiation Measurements
T1  - Eu3+ doped YNbO4 phosphor properties for fluorescence thermometry
VL  - 56
SP  - 143
EP  - 146
DO  - 10.1016/j.radmeas.2013.01.038
ER  - 
@article{
author = "Đačanin, Ljubica and Dramićanin, Miroslav and Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, Marko G.",
year = "2013",
abstract = "We prepared an efficient YNbO4:Eu3+ phosphor using a simple solid-state reaction method and examined its photoluminescent properties in order to investigate the possibility for its usage in phosphor thermometry. Photoluminescence measurements were performed in the temperature range 303-803 K, and the fluorescence intensity ratio (FIR) of the paired emissions lines of Eu3+ (D-5(1) - GT F-7(1) and D-5(0) - GT F-7(1) transitions) was studied as a function of temperature. The sample crystalline structure is confirmed by XRD measurements. The material is proved to have a good potential for the development of thermographic phosphors. It exhibits maximum temperature sensitivity of approximately 3.5 x 10(-3) K-1 in the temperature region around 700 K. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Radiation Measurements",
title = "Eu3+ doped YNbO4 phosphor properties for fluorescence thermometry",
volume = "56",
pages = "143-146",
doi = "10.1016/j.radmeas.2013.01.038"
}
Đačanin, L., Dramićanin, M., Lukić-Petrović, S. R., Petrović, D. M.,& Nikolić, M. G.. (2013). Eu3+ doped YNbO4 phosphor properties for fluorescence thermometry. in Radiation Measurements, 56, 143-146.
https://doi.org/10.1016/j.radmeas.2013.01.038
Đačanin L, Dramićanin M, Lukić-Petrović SR, Petrović DM, Nikolić MG. Eu3+ doped YNbO4 phosphor properties for fluorescence thermometry. in Radiation Measurements. 2013;56:143-146.
doi:10.1016/j.radmeas.2013.01.038 .
Đačanin, Ljubica, Dramićanin, Miroslav, Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, Marko G., "Eu3+ doped YNbO4 phosphor properties for fluorescence thermometry" in Radiation Measurements, 56 (2013):143-146,
https://doi.org/10.1016/j.radmeas.2013.01.038 . .
44
31
43

Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder

Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, M.; Đačanin, Ljubica; Dramićanin, Miroslav

(2013)

TY  - JOUR
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, M.
AU  - Đačanin, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5530
AB  - Phosphor materials are of special interest due to their important applications ranging from solid state lightning and displays to biomedicine. Understanding the spectroscopic properties of these materials is important for optimizing their emission for technological applications. Zinc silicate (Zn2SiO4) has been identified as a very suitable host matrix for many rare-earth and transition metal dopant ions with excellent luminescent properties in the blue, green and red spectral zones. Here, we present high resolution measurements of low-temperature photoluminescence of trivalent europium doped zinc silicate particles prepared by combination of so-gel and combustion synthesis route. We observed and analyzed 5D(0) - GT F-7(J) spin forbidden f-f electronic transitions at low temperatures, as well as emission kinetics from D-5(0) level and lifetime-temperature dependence.
T2  - Optoelectronics and Advanced Materials - Rapid Communications
T1  - Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder
VL  - 7
IS  - 3-4
SP  - 290
EP  - 292
UR  - https://hdl.handle.net/21.15107/rcub_vinar_5530
ER  - 
@article{
author = "Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, M. and Đačanin, Ljubica and Dramićanin, Miroslav",
year = "2013",
abstract = "Phosphor materials are of special interest due to their important applications ranging from solid state lightning and displays to biomedicine. Understanding the spectroscopic properties of these materials is important for optimizing their emission for technological applications. Zinc silicate (Zn2SiO4) has been identified as a very suitable host matrix for many rare-earth and transition metal dopant ions with excellent luminescent properties in the blue, green and red spectral zones. Here, we present high resolution measurements of low-temperature photoluminescence of trivalent europium doped zinc silicate particles prepared by combination of so-gel and combustion synthesis route. We observed and analyzed 5D(0) - GT F-7(J) spin forbidden f-f electronic transitions at low temperatures, as well as emission kinetics from D-5(0) level and lifetime-temperature dependence.",
journal = "Optoelectronics and Advanced Materials - Rapid Communications",
title = "Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder",
volume = "7",
number = "3-4",
pages = "290-292",
url = "https://hdl.handle.net/21.15107/rcub_vinar_5530"
}
Lukić-Petrović, S. R., Petrović, D. M., Nikolić, M., Đačanin, L.,& Dramićanin, M.. (2013). Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder. in Optoelectronics and Advanced Materials - Rapid Communications, 7(3-4), 290-292.
https://hdl.handle.net/21.15107/rcub_vinar_5530
Lukić-Petrović SR, Petrović DM, Nikolić M, Đačanin L, Dramićanin M. Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder. in Optoelectronics and Advanced Materials - Rapid Communications. 2013;7(3-4):290-292.
https://hdl.handle.net/21.15107/rcub_vinar_5530 .
Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, M., Đačanin, Ljubica, Dramićanin, Miroslav, "Low temperature photoluminescence emission of Zn2SiO4:Eu3+ phosphor powder" in Optoelectronics and Advanced Materials - Rapid Communications, 7, no. 3-4 (2013):290-292,
https://hdl.handle.net/21.15107/rcub_vinar_5530 .

PMMA/Zn2SiO4:Eu3+(Mn2+) Composites: Preparation, Optical, and Thermal Properties

Đačanin, Ljubica; Lukić, Svetlana R.; Petrović, Dragoslav M.; Antić, Željka; Krsmanović, Radenka; Marinović-Cincović, Milena; Dramićanin, Miroslav

(2012)

TY  - JOUR
AU  - Đačanin, Ljubica
AU  - Lukić, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Antić, Željka
AU  - Krsmanović, Radenka
AU  - Marinović-Cincović, Milena
AU  - Dramićanin, Miroslav
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4897
AB  - Luminescent composites of poly(methylmethacrylate) (PMMA) and nanophosphors (Zn2SiO4:Mn2+, Zn2SiO4:Eu3+) were prepared by dispersion casting method. It was found that nanoparticles embedded in PMMA matrix preserve their typical phosphorescence emission. The influence of Zn2SiO4 nanofillers on thermal properties of PMMA was also investigated. A shift towards higher glass transition temperatures and slight improvements in thermal stability of the nanocomposites compared to pure PMMA were observed and are discussed herein.
T2  - Journal of Materials Engineering and Performance
T1  - PMMA/Zn2SiO4:Eu3+(Mn2+) Composites: Preparation, Optical, and Thermal Properties
VL  - 21
IS  - 7
SP  - 1509
EP  - 1513
DO  - 10.1007/s11665-011-0049-3
ER  - 
@article{
author = "Đačanin, Ljubica and Lukić, Svetlana R. and Petrović, Dragoslav M. and Antić, Željka and Krsmanović, Radenka and Marinović-Cincović, Milena and Dramićanin, Miroslav",
year = "2012",
abstract = "Luminescent composites of poly(methylmethacrylate) (PMMA) and nanophosphors (Zn2SiO4:Mn2+, Zn2SiO4:Eu3+) were prepared by dispersion casting method. It was found that nanoparticles embedded in PMMA matrix preserve their typical phosphorescence emission. The influence of Zn2SiO4 nanofillers on thermal properties of PMMA was also investigated. A shift towards higher glass transition temperatures and slight improvements in thermal stability of the nanocomposites compared to pure PMMA were observed and are discussed herein.",
journal = "Journal of Materials Engineering and Performance",
title = "PMMA/Zn2SiO4:Eu3+(Mn2+) Composites: Preparation, Optical, and Thermal Properties",
volume = "21",
number = "7",
pages = "1509-1513",
doi = "10.1007/s11665-011-0049-3"
}
Đačanin, L., Lukić, S. R., Petrović, D. M., Antić, Ž., Krsmanović, R., Marinović-Cincović, M.,& Dramićanin, M.. (2012). PMMA/Zn2SiO4:Eu3+(Mn2+) Composites: Preparation, Optical, and Thermal Properties. in Journal of Materials Engineering and Performance, 21(7), 1509-1513.
https://doi.org/10.1007/s11665-011-0049-3
Đačanin L, Lukić SR, Petrović DM, Antić Ž, Krsmanović R, Marinović-Cincović M, Dramićanin M. PMMA/Zn2SiO4:Eu3+(Mn2+) Composites: Preparation, Optical, and Thermal Properties. in Journal of Materials Engineering and Performance. 2012;21(7):1509-1513.
doi:10.1007/s11665-011-0049-3 .
Đačanin, Ljubica, Lukić, Svetlana R., Petrović, Dragoslav M., Antić, Željka, Krsmanović, Radenka, Marinović-Cincović, Milena, Dramićanin, Miroslav, "PMMA/Zn2SiO4:Eu3+(Mn2+) Composites: Preparation, Optical, and Thermal Properties" in Journal of Materials Engineering and Performance, 21, no. 7 (2012):1509-1513,
https://doi.org/10.1007/s11665-011-0049-3 . .
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Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2

Đačanin, Ljubica; Dramićanin, Miroslav; Lukić-Petrović, Svetlana R.; Petrović, Dragoslav M.; Nikolić, Marko G.

(2012)

TY  - JOUR
AU  - Đačanin, Ljubica
AU  - Dramićanin, Miroslav
AU  - Lukić-Petrović, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Nikolić, Marko G.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4356
AB  - Lithium-indium oxide is a high-density (5.9 g center dot cm(-3)), wide band-gap semiconductor with promising applications for scintillating detection of solar neutrinos as well as for efficient phosphorescence when doped with Er3+ or Sm3+ ions. In this report, we demonstrate visible upconversion emission of Er3+-doped LiInO2 synthesized by a simple solid-state chemistry procedure and discuss mechanisms responsible for pumping the Er3+ ions to upper levels. Intense upconversion emission is observed in the green and red spectral regions under near-infrared excitation, and it is greatly enhanced by co-doping with Yb3+ ions. We also examined the upconversion intensity change as a function of temperature, and, consequently, possible applications of this material as a low-temperature sensor.
T2  - Central European Journal of Physics
T1  - Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2
VL  - 10
IS  - 2
SP  - 519
EP  - 523
DO  - 10.2478/s11534-012-0009-z
ER  - 
@article{
author = "Đačanin, Ljubica and Dramićanin, Miroslav and Lukić-Petrović, Svetlana R. and Petrović, Dragoslav M. and Nikolić, Marko G.",
year = "2012",
abstract = "Lithium-indium oxide is a high-density (5.9 g center dot cm(-3)), wide band-gap semiconductor with promising applications for scintillating detection of solar neutrinos as well as for efficient phosphorescence when doped with Er3+ or Sm3+ ions. In this report, we demonstrate visible upconversion emission of Er3+-doped LiInO2 synthesized by a simple solid-state chemistry procedure and discuss mechanisms responsible for pumping the Er3+ ions to upper levels. Intense upconversion emission is observed in the green and red spectral regions under near-infrared excitation, and it is greatly enhanced by co-doping with Yb3+ ions. We also examined the upconversion intensity change as a function of temperature, and, consequently, possible applications of this material as a low-temperature sensor.",
journal = "Central European Journal of Physics",
title = "Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2",
volume = "10",
number = "2",
pages = "519-523",
doi = "10.2478/s11534-012-0009-z"
}
Đačanin, L., Dramićanin, M., Lukić-Petrović, S. R., Petrović, D. M.,& Nikolić, M. G.. (2012). Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2. in Central European Journal of Physics, 10(2), 519-523.
https://doi.org/10.2478/s11534-012-0009-z
Đačanin L, Dramićanin M, Lukić-Petrović SR, Petrović DM, Nikolić MG. Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2. in Central European Journal of Physics. 2012;10(2):519-523.
doi:10.2478/s11534-012-0009-z .
Đačanin, Ljubica, Dramićanin, Miroslav, Lukić-Petrović, Svetlana R., Petrović, Dragoslav M., Nikolić, Marko G., "Vaaisible upconversion emission of Er3+-doped and Er3+/Yb3+-codoped LiInO2" in Central European Journal of Physics, 10, no. 2 (2012):519-523,
https://doi.org/10.2478/s11534-012-0009-z . .
1
1
3
4

Photoluminescence of europium doped LiInO2 powder

Đačanin, Ljubica; Dramićanin, Miroslav; Nikolić, Marko G.; Mitrić, Miodrag; Petrović, Dragoslav M.; Lukić, Svetlana R.

(2011)

TY  - CONF
AU  - Đačanin, Ljubica
AU  - Dramićanin, Miroslav
AU  - Nikolić, Marko G.
AU  - Mitrić, Miodrag
AU  - Petrović, Dragoslav M.
AU  - Lukić, Svetlana R.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6944
AB  - Lithium-indium oxide is one of the candidate materials as solid-state scintillators for solar neutrinos due to an inverse beta -decay of In-115 to Sn-115. On the other hand, when doped with rare-earth ions such as Eu3+ or Sm3+, it becomes a promising phosphor material. In this report we present a simple solid-state procedure for preparation of LiInO2:Eu3+ powders. X-ray diffraction confirmed product in tetragonal structural form (space group: I4(1)/amd) and no impurity phases were detected. Then, high resolution photoluminescence emission measurements were performed at room and low temperatures to find D-5(0) - GT F-7(J). Emission kinetics from D-5(0) level exhibited pure single exponential behavior with lifetime of about 1.5 ms. Maximum energy splitting of F-7(1) manifold is recorded as a function of temperature. (C) 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim
C3  - Physica status solidi. C: Current topics in solid state physics
T1  - Photoluminescence of europium doped LiInO2 powder
VL  - 8
IS  - 9
DO  - 10.1002/pssc.201084138
ER  - 
@conference{
author = "Đačanin, Ljubica and Dramićanin, Miroslav and Nikolić, Marko G. and Mitrić, Miodrag and Petrović, Dragoslav M. and Lukić, Svetlana R.",
year = "2011",
abstract = "Lithium-indium oxide is one of the candidate materials as solid-state scintillators for solar neutrinos due to an inverse beta -decay of In-115 to Sn-115. On the other hand, when doped with rare-earth ions such as Eu3+ or Sm3+, it becomes a promising phosphor material. In this report we present a simple solid-state procedure for preparation of LiInO2:Eu3+ powders. X-ray diffraction confirmed product in tetragonal structural form (space group: I4(1)/amd) and no impurity phases were detected. Then, high resolution photoluminescence emission measurements were performed at room and low temperatures to find D-5(0) - GT F-7(J). Emission kinetics from D-5(0) level exhibited pure single exponential behavior with lifetime of about 1.5 ms. Maximum energy splitting of F-7(1) manifold is recorded as a function of temperature. (C) 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim",
journal = "Physica status solidi. C: Current topics in solid state physics",
title = "Photoluminescence of europium doped LiInO2 powder",
volume = "8",
number = "9",
doi = "10.1002/pssc.201084138"
}
Đačanin, L., Dramićanin, M., Nikolić, M. G., Mitrić, M., Petrović, D. M.,& Lukić, S. R.. (2011). Photoluminescence of europium doped LiInO2 powder. in Physica status solidi. C: Current topics in solid state physics, 8(9).
https://doi.org/10.1002/pssc.201084138
Đačanin L, Dramićanin M, Nikolić MG, Mitrić M, Petrović DM, Lukić SR. Photoluminescence of europium doped LiInO2 powder. in Physica status solidi. C: Current topics in solid state physics. 2011;8(9).
doi:10.1002/pssc.201084138 .
Đačanin, Ljubica, Dramićanin, Miroslav, Nikolić, Marko G., Mitrić, Miodrag, Petrović, Dragoslav M., Lukić, Svetlana R., "Photoluminescence of europium doped LiInO2 powder" in Physica status solidi. C: Current topics in solid state physics, 8, no. 9 (2011),
https://doi.org/10.1002/pssc.201084138 . .
3
2
5

Gel combustion synthesis of transition metal ions doped Zn2SiO4 powder

Lukić, Svetlana R.; Petrović, Dragoslav M.; Đačanin, Ljubica; Marinović-Cincović, Milena; Antić, Željka; Krsmanović, Radenka; Dramićanin, Miroslav

(2008)

TY  - JOUR
AU  - Lukić, Svetlana R.
AU  - Petrović, Dragoslav M.
AU  - Đačanin, Ljubica
AU  - Marinović-Cincović, Milena
AU  - Antić, Željka
AU  - Krsmanović, Radenka
AU  - Dramićanin, Miroslav
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3556
AB  - We present here the synthesis procedure for obtaining Zn2SiO4:M2+ (M = Mn, Ni, Co) powder based on the combination of so-gel and combustion methods. Combustion is performed both in a conventional furnace and in a microwave oven in order to evaluate the influence of combustion conditions on the properties of synthesized material. X-ray diffraction analysis confirmed that obtained material has crystallized in rhombohedral structure of Zn2SiO4 (willemite) with traces of ZnO. The effects of combustion conditions are investigated further by means of thermogravimetric analysis, differential thermal analysis, infrared spectroscopy, diffuse reflectance optical spectroscopy and photoluminescence spectroscopy. Based on these results we could conclude that microwave combustion synthesis can be successfully applied for Zn2SiO4-based products.
T2  - Journal of Optoelectronics and Advanced Materials
T1  - Gel combustion synthesis of transition metal ions doped Zn2SiO4 powder
VL  - 10
IS  - 10
SP  - 2748
EP  - 2752
UR  - https://hdl.handle.net/21.15107/rcub_vinar_3556
ER  - 
@article{
author = "Lukić, Svetlana R. and Petrović, Dragoslav M. and Đačanin, Ljubica and Marinović-Cincović, Milena and Antić, Željka and Krsmanović, Radenka and Dramićanin, Miroslav",
year = "2008",
abstract = "We present here the synthesis procedure for obtaining Zn2SiO4:M2+ (M = Mn, Ni, Co) powder based on the combination of so-gel and combustion methods. Combustion is performed both in a conventional furnace and in a microwave oven in order to evaluate the influence of combustion conditions on the properties of synthesized material. X-ray diffraction analysis confirmed that obtained material has crystallized in rhombohedral structure of Zn2SiO4 (willemite) with traces of ZnO. The effects of combustion conditions are investigated further by means of thermogravimetric analysis, differential thermal analysis, infrared spectroscopy, diffuse reflectance optical spectroscopy and photoluminescence spectroscopy. Based on these results we could conclude that microwave combustion synthesis can be successfully applied for Zn2SiO4-based products.",
journal = "Journal of Optoelectronics and Advanced Materials",
title = "Gel combustion synthesis of transition metal ions doped Zn2SiO4 powder",
volume = "10",
number = "10",
pages = "2748-2752",
url = "https://hdl.handle.net/21.15107/rcub_vinar_3556"
}
Lukić, S. R., Petrović, D. M., Đačanin, L., Marinović-Cincović, M., Antić, Ž., Krsmanović, R.,& Dramićanin, M.. (2008). Gel combustion synthesis of transition metal ions doped Zn2SiO4 powder. in Journal of Optoelectronics and Advanced Materials, 10(10), 2748-2752.
https://hdl.handle.net/21.15107/rcub_vinar_3556
Lukić SR, Petrović DM, Đačanin L, Marinović-Cincović M, Antić Ž, Krsmanović R, Dramićanin M. Gel combustion synthesis of transition metal ions doped Zn2SiO4 powder. in Journal of Optoelectronics and Advanced Materials. 2008;10(10):2748-2752.
https://hdl.handle.net/21.15107/rcub_vinar_3556 .
Lukić, Svetlana R., Petrović, Dragoslav M., Đačanin, Ljubica, Marinović-Cincović, Milena, Antić, Željka, Krsmanović, Radenka, Dramićanin, Miroslav, "Gel combustion synthesis of transition metal ions doped Zn2SiO4 powder" in Journal of Optoelectronics and Advanced Materials, 10, no. 10 (2008):2748-2752,
https://hdl.handle.net/21.15107/rcub_vinar_3556 .
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