Vukićević, Rastko D.

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95003cc0-1119-4bef-8e29-fe4795c9312e
  • Vukićević, Rastko D. (20)
  • Vukićević, Rastko (1)
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Author's Bibliography

Synthesis of novel 4-ferrocenyl-1,2,3,4-tetrahydroquinolines and 4-ferrocenylquinolines via alpha-ferrocenyl carbenium ions as key intermediates

Minić, Aleksandra; Stevanović, Dragana D.; Vukićević, Mirjana; Bogdanović, Goran A.; D'hooghe, Matthias; Radulović, Niko S.; Vukićević, Rastko D.

(2017)

TY  - JOUR
AU  - Minić, Aleksandra
AU  - Stevanović, Dragana D.
AU  - Vukićević, Mirjana
AU  - Bogdanović, Goran A.
AU  - D'hooghe, Matthias
AU  - Radulović, Niko S.
AU  - Vukićević, Rastko D.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1797
AB  - A series of novel 4-ferrocenyl-1,2,3,4-tetrahydroquinolines were synthesized in high-to-excellent yields (up to 99%) starting from the corresponding ferrocenoylethyl aryl amines. These Mannich bases were reduced (NaBH4) to the corresponding 3-(arylamino)-1-ferrocenylpropan-1-ols and submitted to an intramolecular cyclization prompted by acetic acid, proceeding via the corresponding alpha-ferrocenyl carbenium ion intermediates. Subsequently, the obtained tetrahydroquinolines were smoothly oxidized (aromatized) by means of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) to provide the corresponding 4-ferrocenylquinolines (up to 93%). (C) 2017 Elsevier Ltd. All rights reserved.
T2  - Tetrahedron
T1  - Synthesis of novel 4-ferrocenyl-1,2,3,4-tetrahydroquinolines and 4-ferrocenylquinolines via alpha-ferrocenyl carbenium ions as key intermediates
VL  - 73
IS  - 44
SP  - 6268
EP  - 6274
DO  - 10.1016/j.tet.2017.09.014
ER  - 
@article{
author = "Minić, Aleksandra and Stevanović, Dragana D. and Vukićević, Mirjana and Bogdanović, Goran A. and D'hooghe, Matthias and Radulović, Niko S. and Vukićević, Rastko D.",
year = "2017",
abstract = "A series of novel 4-ferrocenyl-1,2,3,4-tetrahydroquinolines were synthesized in high-to-excellent yields (up to 99%) starting from the corresponding ferrocenoylethyl aryl amines. These Mannich bases were reduced (NaBH4) to the corresponding 3-(arylamino)-1-ferrocenylpropan-1-ols and submitted to an intramolecular cyclization prompted by acetic acid, proceeding via the corresponding alpha-ferrocenyl carbenium ion intermediates. Subsequently, the obtained tetrahydroquinolines were smoothly oxidized (aromatized) by means of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) to provide the corresponding 4-ferrocenylquinolines (up to 93%). (C) 2017 Elsevier Ltd. All rights reserved.",
journal = "Tetrahedron",
title = "Synthesis of novel 4-ferrocenyl-1,2,3,4-tetrahydroquinolines and 4-ferrocenylquinolines via alpha-ferrocenyl carbenium ions as key intermediates",
volume = "73",
number = "44",
pages = "6268-6274",
doi = "10.1016/j.tet.2017.09.014"
}
Minić, A., Stevanović, D. D., Vukićević, M., Bogdanović, G. A., D'hooghe, M., Radulović, N. S.,& Vukićević, R. D.. (2017). Synthesis of novel 4-ferrocenyl-1,2,3,4-tetrahydroquinolines and 4-ferrocenylquinolines via alpha-ferrocenyl carbenium ions as key intermediates. in Tetrahedron, 73(44), 6268-6274.
https://doi.org/10.1016/j.tet.2017.09.014
Minić A, Stevanović DD, Vukićević M, Bogdanović GA, D'hooghe M, Radulović NS, Vukićević RD. Synthesis of novel 4-ferrocenyl-1,2,3,4-tetrahydroquinolines and 4-ferrocenylquinolines via alpha-ferrocenyl carbenium ions as key intermediates. in Tetrahedron. 2017;73(44):6268-6274.
doi:10.1016/j.tet.2017.09.014 .
Minić, Aleksandra, Stevanović, Dragana D., Vukićević, Mirjana, Bogdanović, Goran A., D'hooghe, Matthias, Radulović, Niko S., Vukićević, Rastko D., "Synthesis of novel 4-ferrocenyl-1,2,3,4-tetrahydroquinolines and 4-ferrocenylquinolines via alpha-ferrocenyl carbenium ions as key intermediates" in Tetrahedron, 73, no. 44 (2017):6268-6274,
https://doi.org/10.1016/j.tet.2017.09.014 . .
18
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Dehydrozingerone based 1-acetyl-5-aryl-4,5-dihydro-1H-pyrazoles: Synthesis, characterization and anticancer activity

Ratković, Zoran R.; Muškinja, Jovana; Burmudžija, Adrijana; Ranković, Branislav; Kosanić, Marijana; Bogdanović, Goran A.; Marković-Simović, Bojana; Nikolić, Aleksandar; Arsenijević, Nebojša N.; Đorđević, Snežana; Vukićević, Rastko D.

(2016)

TY  - JOUR
AU  - Ratković, Zoran R.
AU  - Muškinja, Jovana
AU  - Burmudžija, Adrijana
AU  - Ranković, Branislav
AU  - Kosanić, Marijana
AU  - Bogdanović, Goran A.
AU  - Marković-Simović, Bojana
AU  - Nikolić, Aleksandar
AU  - Arsenijević, Nebojša N.
AU  - Đorđević, Snežana
AU  - Vukićević, Rastko D.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1127
AB  - A small series of 1-acetyl-5-aryl-4,5-dihydro-1H-pyrazoles (aryl = 4-hydroxy-3-methoxyphenyl and 4-alkoxy-3-methoxyphenyl) was prepared, starting from 4-(4-hydroxy-3-methoxyphenyl)-3-buten-2-one, dehydrozingerone, and its alkyl derivatives. Their in vitro cytotoxic activity against some cancer cell lines was tested, showing significant anticancer activity. All the new compounds were well characterized by IR, H-1, C-13 NMR and ESI-MS spectroscopy and physical data, whereas structures of two of them were determined by single crystal X-ray analysis. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Journal of Molecular Structure
T1  - Dehydrozingerone based 1-acetyl-5-aryl-4,5-dihydro-1H-pyrazoles: Synthesis, characterization and anticancer activity
VL  - 1109
SP  - 82
EP  - 88
DO  - 10.1016/j.molstruc.2015.12.079
ER  - 
@article{
author = "Ratković, Zoran R. and Muškinja, Jovana and Burmudžija, Adrijana and Ranković, Branislav and Kosanić, Marijana and Bogdanović, Goran A. and Marković-Simović, Bojana and Nikolić, Aleksandar and Arsenijević, Nebojša N. and Đorđević, Snežana and Vukićević, Rastko D.",
year = "2016",
abstract = "A small series of 1-acetyl-5-aryl-4,5-dihydro-1H-pyrazoles (aryl = 4-hydroxy-3-methoxyphenyl and 4-alkoxy-3-methoxyphenyl) was prepared, starting from 4-(4-hydroxy-3-methoxyphenyl)-3-buten-2-one, dehydrozingerone, and its alkyl derivatives. Their in vitro cytotoxic activity against some cancer cell lines was tested, showing significant anticancer activity. All the new compounds were well characterized by IR, H-1, C-13 NMR and ESI-MS spectroscopy and physical data, whereas structures of two of them were determined by single crystal X-ray analysis. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Journal of Molecular Structure",
title = "Dehydrozingerone based 1-acetyl-5-aryl-4,5-dihydro-1H-pyrazoles: Synthesis, characterization and anticancer activity",
volume = "1109",
pages = "82-88",
doi = "10.1016/j.molstruc.2015.12.079"
}
Ratković, Z. R., Muškinja, J., Burmudžija, A., Ranković, B., Kosanić, M., Bogdanović, G. A., Marković-Simović, B., Nikolić, A., Arsenijević, N. N., Đorđević, S.,& Vukićević, R. D.. (2016). Dehydrozingerone based 1-acetyl-5-aryl-4,5-dihydro-1H-pyrazoles: Synthesis, characterization and anticancer activity. in Journal of Molecular Structure, 1109, 82-88.
https://doi.org/10.1016/j.molstruc.2015.12.079
Ratković ZR, Muškinja J, Burmudžija A, Ranković B, Kosanić M, Bogdanović GA, Marković-Simović B, Nikolić A, Arsenijević NN, Đorđević S, Vukićević RD. Dehydrozingerone based 1-acetyl-5-aryl-4,5-dihydro-1H-pyrazoles: Synthesis, characterization and anticancer activity. in Journal of Molecular Structure. 2016;1109:82-88.
doi:10.1016/j.molstruc.2015.12.079 .
Ratković, Zoran R., Muškinja, Jovana, Burmudžija, Adrijana, Ranković, Branislav, Kosanić, Marijana, Bogdanović, Goran A., Marković-Simović, Bojana, Nikolić, Aleksandar, Arsenijević, Nebojša N., Đorđević, Snežana, Vukićević, Rastko D., "Dehydrozingerone based 1-acetyl-5-aryl-4,5-dihydro-1H-pyrazoles: Synthesis, characterization and anticancer activity" in Journal of Molecular Structure, 1109 (2016):82-88,
https://doi.org/10.1016/j.molstruc.2015.12.079 . .
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Ferrier rearrangement promoted by an electrochemically generated zirconium catalyst

Stevanović, Dragana D.; Pejović, Anka; Damljanović, Ivan S.; Minić, Aleksandra; Bogdanović, Goran A.; Vukićević, Mirjana; Radulović, Niko S.; Vukićević, Rastko D.

(2015)

TY  - JOUR
AU  - Stevanović, Dragana D.
AU  - Pejović, Anka
AU  - Damljanović, Ivan S.
AU  - Minić, Aleksandra
AU  - Bogdanović, Goran A.
AU  - Vukićević, Mirjana
AU  - Radulović, Niko S.
AU  - Vukićević, Rastko D.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/489
AB  - In situ generated zirconium catalyst from a sacrificial zirconium anode was successfully applied to promote Ferrier rearrangement of 3,4,5-tri-O-acetyl-D-glucal and 6-deoxy-3,4-di-O-acetyl-L-glucal (3,4-di- O-acetyl-L-rhamnal) in the presence of three thiols and eleven thiophenols as nucleophiles. A simple constant current electrolysis (20 mA, 0.4 F mol(-1)) of an acetonitrile solution of lithium perchlorate (0.1 M) containing the corresponding glycal and S-nucleophiles, using a zirconium anode and a platinum cathode resulted in the successful synthesis of the corresponding 2,3-unsaturated peracetylated thioglycosides (with an average anomer ratio alpha/beta-4.129 in the case of peracetylated D-glucal and 8.740 in the case of L-rhamnal). The same procedure proved to be appropriate in synthesizing dihydropyran derivatives (C-glycosides) using allyltrimethylsilane as the nucleophile (only alpha-anomers were obtained). All new compounds were fully characterized by spectral data, whereas single-crystal X-ray analysis was performed for two thioglycosides. (C) 2015 Elsevier Ltd. All rights reserved.
T2  - Carbohydrate Research
T1  - Ferrier rearrangement promoted by an electrochemically generated zirconium catalyst
VL  - 407
SP  - 111
EP  - 121
DO  - 10.1016/j.carres.2015.02.001
ER  - 
@article{
author = "Stevanović, Dragana D. and Pejović, Anka and Damljanović, Ivan S. and Minić, Aleksandra and Bogdanović, Goran A. and Vukićević, Mirjana and Radulović, Niko S. and Vukićević, Rastko D.",
year = "2015",
abstract = "In situ generated zirconium catalyst from a sacrificial zirconium anode was successfully applied to promote Ferrier rearrangement of 3,4,5-tri-O-acetyl-D-glucal and 6-deoxy-3,4-di-O-acetyl-L-glucal (3,4-di- O-acetyl-L-rhamnal) in the presence of three thiols and eleven thiophenols as nucleophiles. A simple constant current electrolysis (20 mA, 0.4 F mol(-1)) of an acetonitrile solution of lithium perchlorate (0.1 M) containing the corresponding glycal and S-nucleophiles, using a zirconium anode and a platinum cathode resulted in the successful synthesis of the corresponding 2,3-unsaturated peracetylated thioglycosides (with an average anomer ratio alpha/beta-4.129 in the case of peracetylated D-glucal and 8.740 in the case of L-rhamnal). The same procedure proved to be appropriate in synthesizing dihydropyran derivatives (C-glycosides) using allyltrimethylsilane as the nucleophile (only alpha-anomers were obtained). All new compounds were fully characterized by spectral data, whereas single-crystal X-ray analysis was performed for two thioglycosides. (C) 2015 Elsevier Ltd. All rights reserved.",
journal = "Carbohydrate Research",
title = "Ferrier rearrangement promoted by an electrochemically generated zirconium catalyst",
volume = "407",
pages = "111-121",
doi = "10.1016/j.carres.2015.02.001"
}
Stevanović, D. D., Pejović, A., Damljanović, I. S., Minić, A., Bogdanović, G. A., Vukićević, M., Radulović, N. S.,& Vukićević, R. D.. (2015). Ferrier rearrangement promoted by an electrochemically generated zirconium catalyst. in Carbohydrate Research, 407, 111-121.
https://doi.org/10.1016/j.carres.2015.02.001
Stevanović DD, Pejović A, Damljanović IS, Minić A, Bogdanović GA, Vukićević M, Radulović NS, Vukićević RD. Ferrier rearrangement promoted by an electrochemically generated zirconium catalyst. in Carbohydrate Research. 2015;407:111-121.
doi:10.1016/j.carres.2015.02.001 .
Stevanović, Dragana D., Pejović, Anka, Damljanović, Ivan S., Minić, Aleksandra, Bogdanović, Goran A., Vukićević, Mirjana, Radulović, Niko S., Vukićević, Rastko D., "Ferrier rearrangement promoted by an electrochemically generated zirconium catalyst" in Carbohydrate Research, 407 (2015):111-121,
https://doi.org/10.1016/j.carres.2015.02.001 . .
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Synthesis of ferrocene-containing six-membered cyclic ureas via alpha-ferrocenyl carbocations

Minić, Aleksandra; Stevanović, Dragana D.; Damljanović, Ivan S.; Pejović, Anka; Vukićević, Mirjana; Bogdanović, Goran A.; Radulović, Niko S.; Vukićević, Rastko D.

(2015)

TY  - JOUR
AU  - Minić, Aleksandra
AU  - Stevanović, Dragana D.
AU  - Damljanović, Ivan S.
AU  - Pejović, Anka
AU  - Vukićević, Mirjana
AU  - Bogdanović, Goran A.
AU  - Radulović, Niko S.
AU  - Vukićević, Rastko D.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/456
AB  - A series of ferrocene-containing six-membered cyclic ureas (1-aryl-4-ferrocenyl-3-phenyltetrahydropyrimidin-2(1H)-ones) was synthesized (in high-to-excellent yields) by reacting the corresponding amino-propanols with phenyl isocyanate and the subsequent intramolecular cyclization of the thus obtained beta-hydroxy ureas (prompted by acetic acid), via an alpha-ferrocenyl carbocation.
T2  - RSC Advances
T1  - Synthesis of ferrocene-containing six-membered cyclic ureas via alpha-ferrocenyl carbocations
VL  - 5
IS  - 32
SP  - 24915
EP  - 24919
DO  - 10.1039/c5ra01383f
ER  - 
@article{
author = "Minić, Aleksandra and Stevanović, Dragana D. and Damljanović, Ivan S. and Pejović, Anka and Vukićević, Mirjana and Bogdanović, Goran A. and Radulović, Niko S. and Vukićević, Rastko D.",
year = "2015",
abstract = "A series of ferrocene-containing six-membered cyclic ureas (1-aryl-4-ferrocenyl-3-phenyltetrahydropyrimidin-2(1H)-ones) was synthesized (in high-to-excellent yields) by reacting the corresponding amino-propanols with phenyl isocyanate and the subsequent intramolecular cyclization of the thus obtained beta-hydroxy ureas (prompted by acetic acid), via an alpha-ferrocenyl carbocation.",
journal = "RSC Advances",
title = "Synthesis of ferrocene-containing six-membered cyclic ureas via alpha-ferrocenyl carbocations",
volume = "5",
number = "32",
pages = "24915-24919",
doi = "10.1039/c5ra01383f"
}
Minić, A., Stevanović, D. D., Damljanović, I. S., Pejović, A., Vukićević, M., Bogdanović, G. A., Radulović, N. S.,& Vukićević, R. D.. (2015). Synthesis of ferrocene-containing six-membered cyclic ureas via alpha-ferrocenyl carbocations. in RSC Advances, 5(32), 24915-24919.
https://doi.org/10.1039/c5ra01383f
Minić A, Stevanović DD, Damljanović IS, Pejović A, Vukićević M, Bogdanović GA, Radulović NS, Vukićević RD. Synthesis of ferrocene-containing six-membered cyclic ureas via alpha-ferrocenyl carbocations. in RSC Advances. 2015;5(32):24915-24919.
doi:10.1039/c5ra01383f .
Minić, Aleksandra, Stevanović, Dragana D., Damljanović, Ivan S., Pejović, Anka, Vukićević, Mirjana, Bogdanović, Goran A., Radulović, Niko S., Vukićević, Rastko D., "Synthesis of ferrocene-containing six-membered cyclic ureas via alpha-ferrocenyl carbocations" in RSC Advances, 5, no. 32 (2015):24915-24919,
https://doi.org/10.1039/c5ra01383f . .
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Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene

Stevanović, Dragana; Pejović, Anka; Damljanović, Ivan S.; Vukićević, Mirjana; Novaković, Slađana B.; Bogdanović, Goran A.; Vukićević, Rastko

(2015)

TY  - JOUR
AU  - Stevanović, Dragana
AU  - Pejović, Anka
AU  - Damljanović, Ivan S.
AU  - Vukićević, Mirjana
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Vukićević, Rastko
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11003
AB  - Michael addition of diethyl malonate, ethyl acetoacetate, acetylacetone, and cyanide anion to acryloylferrocene promoted by a catalyst in situ generated from a sacrificial zirconium anode is described. Most of the obtained compounds were identified by comparison of their spectral and physical data with those published elsewhere, whereas the only newly synthesized compound - diethyl 2,2-bis(3-ferrocenyl-3-oxopropyl)malonate - was completely characterized by spectral (IR, 1H- and 13C-NMR), physical and crystallographic (single-crystal X-ray) data.
AB  - Opisana je Majklova adicija dietil-malonata, etil-acetoacetata, acetilacetona i cijanidnog anjona na akriloilferocen pomoću katalizatora generisanog in situ sa rastvorne anode od cirkonijuma. Većina dobijenih jedinjenja je identifikovana poređenjem njihovih fizičkih i spektroskopskih podataka sa literaturnim, a jedino novo jedinjenje je potpuno opisano spektroskopskim (IR, 1H- i 13C-NMR) i fizičkim podacima, kao i podacima iz kristalografske analize X-zracima.
T2  - Facta universitatis - series: Physics, Chemistry and Technology
T1  - Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene
T1  - Elektrohemijsko generisanje katalizatora za Majklovu adiciju dikarbonilnih jedinjenja i cijanida na akriloilferocen
VL  - 13
IS  - 2
SP  - 67
EP  - 76
DO  - 10.2298/FUPCT1502067S
ER  - 
@article{
author = "Stevanović, Dragana and Pejović, Anka and Damljanović, Ivan S. and Vukićević, Mirjana and Novaković, Slađana B. and Bogdanović, Goran A. and Vukićević, Rastko",
year = "2015",
abstract = "Michael addition of diethyl malonate, ethyl acetoacetate, acetylacetone, and cyanide anion to acryloylferrocene promoted by a catalyst in situ generated from a sacrificial zirconium anode is described. Most of the obtained compounds were identified by comparison of their spectral and physical data with those published elsewhere, whereas the only newly synthesized compound - diethyl 2,2-bis(3-ferrocenyl-3-oxopropyl)malonate - was completely characterized by spectral (IR, 1H- and 13C-NMR), physical and crystallographic (single-crystal X-ray) data., Opisana je Majklova adicija dietil-malonata, etil-acetoacetata, acetilacetona i cijanidnog anjona na akriloilferocen pomoću katalizatora generisanog in situ sa rastvorne anode od cirkonijuma. Većina dobijenih jedinjenja je identifikovana poređenjem njihovih fizičkih i spektroskopskih podataka sa literaturnim, a jedino novo jedinjenje je potpuno opisano spektroskopskim (IR, 1H- i 13C-NMR) i fizičkim podacima, kao i podacima iz kristalografske analize X-zracima.",
journal = "Facta universitatis - series: Physics, Chemistry and Technology",
title = "Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene, Elektrohemijsko generisanje katalizatora za Majklovu adiciju dikarbonilnih jedinjenja i cijanida na akriloilferocen",
volume = "13",
number = "2",
pages = "67-76",
doi = "10.2298/FUPCT1502067S"
}
Stevanović, D., Pejović, A., Damljanović, I. S., Vukićević, M., Novaković, S. B., Bogdanović, G. A.,& Vukićević, R.. (2015). Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene. in Facta universitatis - series: Physics, Chemistry and Technology, 13(2), 67-76.
https://doi.org/10.2298/FUPCT1502067S
Stevanović D, Pejović A, Damljanović IS, Vukićević M, Novaković SB, Bogdanović GA, Vukićević R. Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene. in Facta universitatis - series: Physics, Chemistry and Technology. 2015;13(2):67-76.
doi:10.2298/FUPCT1502067S .
Stevanović, Dragana, Pejović, Anka, Damljanović, Ivan S., Vukićević, Mirjana, Novaković, Slađana B., Bogdanović, Goran A., Vukićević, Rastko, "Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene" in Facta universitatis - series: Physics, Chemistry and Technology, 13, no. 2 (2015):67-76,
https://doi.org/10.2298/FUPCT1502067S . .
1

The palladium(II) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki-Miyaura reaction

Damljanović, Ivan S.; Stevanović, Dragana D.; Pejović, Anka; Ilic, Danijela; Živković, Marija D.; Jovanović, Jovana P.; Vukićević, Mirjana; Bogdanović, Goran A.; Radulović, Niko S.; Vukićević, Rastko D.

(2014)

TY  - JOUR
AU  - Damljanović, Ivan S.
AU  - Stevanović, Dragana D.
AU  - Pejović, Anka
AU  - Ilic, Danijela
AU  - Živković, Marija D.
AU  - Jovanović, Jovana P.
AU  - Vukićević, Mirjana
AU  - Bogdanović, Goran A.
AU  - Radulović, Niko S.
AU  - Vukićević, Rastko D.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/193
AB  - In this paper we wish to present the first results on the synthesis of N, N-diethyl-1-ferrocenyl-3-thiabutanamine, its coordination with palladium(II), the complete characterization of the thus obtained complex (including single crystal X-ray analysis for the complex in two polymorphic forms) and screening of its catalytic activity in Suzuki-Miyaura coupling of phenylboronic acid with several aryl bromides. The complex, either purified and then added to the reaction mixture or generated in situ, proved to be an excellent precatalyst in Suzuki-Miyaura coupling. The chemical behavior of the complex in solution was assessed by detailed NMR analyses and cyclic voltammetry measurements which allowed us to draw a number of mechanistic conclusions.
T2  - RSC Advances
T1  - The palladium(II) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki-Miyaura reaction
VL  - 4
IS  - 82
SP  - 43792
EP  - 43799
DO  - 10.1039/c4ra08140d
ER  - 
@article{
author = "Damljanović, Ivan S. and Stevanović, Dragana D. and Pejović, Anka and Ilic, Danijela and Živković, Marija D. and Jovanović, Jovana P. and Vukićević, Mirjana and Bogdanović, Goran A. and Radulović, Niko S. and Vukićević, Rastko D.",
year = "2014",
abstract = "In this paper we wish to present the first results on the synthesis of N, N-diethyl-1-ferrocenyl-3-thiabutanamine, its coordination with palladium(II), the complete characterization of the thus obtained complex (including single crystal X-ray analysis for the complex in two polymorphic forms) and screening of its catalytic activity in Suzuki-Miyaura coupling of phenylboronic acid with several aryl bromides. The complex, either purified and then added to the reaction mixture or generated in situ, proved to be an excellent precatalyst in Suzuki-Miyaura coupling. The chemical behavior of the complex in solution was assessed by detailed NMR analyses and cyclic voltammetry measurements which allowed us to draw a number of mechanistic conclusions.",
journal = "RSC Advances",
title = "The palladium(II) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki-Miyaura reaction",
volume = "4",
number = "82",
pages = "43792-43799",
doi = "10.1039/c4ra08140d"
}
Damljanović, I. S., Stevanović, D. D., Pejović, A., Ilic, D., Živković, M. D., Jovanović, J. P., Vukićević, M., Bogdanović, G. A., Radulović, N. S.,& Vukićević, R. D.. (2014). The palladium(II) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki-Miyaura reaction. in RSC Advances, 4(82), 43792-43799.
https://doi.org/10.1039/c4ra08140d
Damljanović IS, Stevanović DD, Pejović A, Ilic D, Živković MD, Jovanović JP, Vukićević M, Bogdanović GA, Radulović NS, Vukićević RD. The palladium(II) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki-Miyaura reaction. in RSC Advances. 2014;4(82):43792-43799.
doi:10.1039/c4ra08140d .
Damljanović, Ivan S., Stevanović, Dragana D., Pejović, Anka, Ilic, Danijela, Živković, Marija D., Jovanović, Jovana P., Vukićević, Mirjana, Bogdanović, Goran A., Radulović, Niko S., Vukićević, Rastko D., "The palladium(II) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki-Miyaura reaction" in RSC Advances, 4, no. 82 (2014):43792-43799,
https://doi.org/10.1039/c4ra08140d . .
7
6
7

4-[(Dimethylamino)methylene]-2-ferrocenyl-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde: Synthesis, spectral characterization and single crystal X-ray analysis

Ratković, Zoran R.; Muškinja, Jovana; Novaković, Slađana B.; Bogdanović, Goran A.; Micskei, Karoly; Vukićević, Rastko D.

(2014)

TY  - JOUR
AU  - Ratković, Zoran R.
AU  - Muškinja, Jovana
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Micskei, Karoly
AU  - Vukićević, Rastko D.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/101
AB  - The title compound 4-[(dimethylamino)methylene]-2-ferrocenyl-5-oxo-4,5-dihydrofuran-3-carboxaldehyde was synthesized by reacting 3-ferrocenoylpropionic acid with Vilsmeier reagent. This result is rather unexpected, since 3-aroylpropanoic acids under these conditions usually give the corresponding 2-aryl-4-chloro-3-formylfurans. 3-Ferrocenoylpropanoic acid is not the only 3-aroylpropanoic acid that exhibit an unusual behavior under the same conditions: 3-thenoylpropanoic acid gave 4-[(dimethylamino)-methylene]-2-(2-thienyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 4-[(dimethylamino) methylene]-2-(2-thienyl-5-formyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde, whereas 3-(4-methoxybenzoyl)propanoic acid yielded 4-[(dimethylamino)methylene]-2-(4-methoxyphenyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 2-(4-methoxyphenyl)-5-chloro-furan-3,4-dicarboxaldehyde. Single crystal X-ray analysis was successfully performed for 4-[(dimethylamino)methylene]-2-ferrocenyl-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 4-[(dimethylamino)methylene]-2-(2-thienyl)-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde and their structures were compared. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - 4-[(Dimethylamino)methylene]-2-ferrocenyl-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde: Synthesis, spectral characterization and single crystal X-ray analysis
VL  - 80
IS  - SI
SP  - 193
EP  - 197
DO  - 10.1016/j.poly.2014.03.038
ER  - 
@article{
author = "Ratković, Zoran R. and Muškinja, Jovana and Novaković, Slađana B. and Bogdanović, Goran A. and Micskei, Karoly and Vukićević, Rastko D.",
year = "2014",
abstract = "The title compound 4-[(dimethylamino)methylene]-2-ferrocenyl-5-oxo-4,5-dihydrofuran-3-carboxaldehyde was synthesized by reacting 3-ferrocenoylpropionic acid with Vilsmeier reagent. This result is rather unexpected, since 3-aroylpropanoic acids under these conditions usually give the corresponding 2-aryl-4-chloro-3-formylfurans. 3-Ferrocenoylpropanoic acid is not the only 3-aroylpropanoic acid that exhibit an unusual behavior under the same conditions: 3-thenoylpropanoic acid gave 4-[(dimethylamino)-methylene]-2-(2-thienyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 4-[(dimethylamino) methylene]-2-(2-thienyl-5-formyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde, whereas 3-(4-methoxybenzoyl)propanoic acid yielded 4-[(dimethylamino)methylene]-2-(4-methoxyphenyl)-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 2-(4-methoxyphenyl)-5-chloro-furan-3,4-dicarboxaldehyde. Single crystal X-ray analysis was successfully performed for 4-[(dimethylamino)methylene]-2-ferrocenyl-5-oxo-4,5-dihydrofuran-3-carboxaldehyde and 4-[(dimethylamino)methylene]-2-(2-thienyl)-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde and their structures were compared. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "4-[(Dimethylamino)methylene]-2-ferrocenyl-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde: Synthesis, spectral characterization and single crystal X-ray analysis",
volume = "80",
number = "SI",
pages = "193-197",
doi = "10.1016/j.poly.2014.03.038"
}
Ratković, Z. R., Muškinja, J., Novaković, S. B., Bogdanović, G. A., Micskei, K.,& Vukićević, R. D.. (2014). 4-[(Dimethylamino)methylene]-2-ferrocenyl-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde: Synthesis, spectral characterization and single crystal X-ray analysis. in Polyhedron, 80(SI), 193-197.
https://doi.org/10.1016/j.poly.2014.03.038
Ratković ZR, Muškinja J, Novaković SB, Bogdanović GA, Micskei K, Vukićević RD. 4-[(Dimethylamino)methylene]-2-ferrocenyl-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde: Synthesis, spectral characterization and single crystal X-ray analysis. in Polyhedron. 2014;80(SI):193-197.
doi:10.1016/j.poly.2014.03.038 .
Ratković, Zoran R., Muškinja, Jovana, Novaković, Slađana B., Bogdanović, Goran A., Micskei, Karoly, Vukićević, Rastko D., "4-[(Dimethylamino)methylene]-2-ferrocenyl-5-oxo-4, 5-dihydrofuran-3-carboxaldehyde: Synthesis, spectral characterization and single crystal X-ray analysis" in Polyhedron, 80, no. SI (2014):193-197,
https://doi.org/10.1016/j.poly.2014.03.038 . .

New ferrocene containing 3-(arylthio)propan-1-ones: Synthesis, spectral characterization and crystal structure of 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one, 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1-one and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one

Stevanović, Dragana D.; Bogdanović, Goran A.; Vukićević, Rastko D.

(2014)

TY  - JOUR
AU  - Stevanović, Dragana D.
AU  - Bogdanović, Goran A.
AU  - Vukićević, Rastko D.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/98
AB  - Three series of ferrocene containing 3-(arylthio)propan-1-ones (each of eight examples) have been synthesized by thia-Michael addition of the corresponding thiophenols to acryloylferrocene, 1-ferroceny1-3-phenylprop-2-en-1-one and 3-ferrocenyl-1-phenylprop-2-en-1-one promoted by the catalyst generated from a sacrificial zirconium anode. All the newly synthesized compounds (16 in total) were characterized by spectral data, whereas single crystal X-ray structure analysis was performed for 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one (1h), 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1 one (2h) and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one (3h). Molecular geometry and structural characteristics of three thiaketones (1h, 2h and 3h) were analysed and compared in detail. It was found that all three molecules do not form classical H-bonds and pi center dot center dot center dot pi interactions (regardless of the presence of 3 or 4 aromatic rings per a molecule). However, all three crystal structures abound in intermolecular C-H center dot center dot center dot pi interactions while 2h and 3h in addition form intramolecular C-H center dot center dot center dot pi as only evident interaction within the molecules. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - New ferrocene containing 3-(arylthio)propan-1-ones: Synthesis, spectral characterization and crystal structure of 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one, 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1-one and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one
VL  - 80
IS  - SI
SP  - 10
EP  - 19
DO  - 10.1016/j.poly.2013.12.012
ER  - 
@article{
author = "Stevanović, Dragana D. and Bogdanović, Goran A. and Vukićević, Rastko D.",
year = "2014",
abstract = "Three series of ferrocene containing 3-(arylthio)propan-1-ones (each of eight examples) have been synthesized by thia-Michael addition of the corresponding thiophenols to acryloylferrocene, 1-ferroceny1-3-phenylprop-2-en-1-one and 3-ferrocenyl-1-phenylprop-2-en-1-one promoted by the catalyst generated from a sacrificial zirconium anode. All the newly synthesized compounds (16 in total) were characterized by spectral data, whereas single crystal X-ray structure analysis was performed for 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one (1h), 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1 one (2h) and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one (3h). Molecular geometry and structural characteristics of three thiaketones (1h, 2h and 3h) were analysed and compared in detail. It was found that all three molecules do not form classical H-bonds and pi center dot center dot center dot pi interactions (regardless of the presence of 3 or 4 aromatic rings per a molecule). However, all three crystal structures abound in intermolecular C-H center dot center dot center dot pi interactions while 2h and 3h in addition form intramolecular C-H center dot center dot center dot pi as only evident interaction within the molecules. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "New ferrocene containing 3-(arylthio)propan-1-ones: Synthesis, spectral characterization and crystal structure of 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one, 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1-one and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one",
volume = "80",
number = "SI",
pages = "10-19",
doi = "10.1016/j.poly.2013.12.012"
}
Stevanović, D. D., Bogdanović, G. A.,& Vukićević, R. D.. (2014). New ferrocene containing 3-(arylthio)propan-1-ones: Synthesis, spectral characterization and crystal structure of 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one, 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1-one and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one. in Polyhedron, 80(SI), 10-19.
https://doi.org/10.1016/j.poly.2013.12.012
Stevanović DD, Bogdanović GA, Vukićević RD. New ferrocene containing 3-(arylthio)propan-1-ones: Synthesis, spectral characterization and crystal structure of 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one, 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1-one and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one. in Polyhedron. 2014;80(SI):10-19.
doi:10.1016/j.poly.2013.12.012 .
Stevanović, Dragana D., Bogdanović, Goran A., Vukićević, Rastko D., "New ferrocene containing 3-(arylthio)propan-1-ones: Synthesis, spectral characterization and crystal structure of 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one, 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1-one and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one" in Polyhedron, 80, no. SI (2014):10-19,
https://doi.org/10.1016/j.poly.2013.12.012 . .
1
1
1

Discovery of anxiolytic 2-ferrocenyl-1,3-thiazolidin-4-ones exerting GABA(A) receptor interaction via the benzodiazepine-binding site

Pejović, Anka; Denic, Marija S.; Stevanović, Dragana D.; Damljanović, Ivan S.; Vukićević, Mirjana; Kostova, Kalina; Tavlinova-Kirilova, Maya; Randjelovi, Pavle; Stojanović, Nikola M.; Bogdanović, Goran A.; Blagojevic, Polina; D'hooghe, Matthias; Radulović, Niko S.; Vukićević, Rastko D.

(2014)

TY  - JOUR
AU  - Pejović, Anka
AU  - Denic, Marija S.
AU  - Stevanović, Dragana D.
AU  - Damljanović, Ivan S.
AU  - Vukićević, Mirjana
AU  - Kostova, Kalina
AU  - Tavlinova-Kirilova, Maya
AU  - Randjelovi, Pavle
AU  - Stojanović, Nikola M.
AU  - Bogdanović, Goran A.
AU  - Blagojevic, Polina
AU  - D'hooghe, Matthias
AU  - Radulović, Niko S.
AU  - Vukićević, Rastko D.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/76
AB  - Herein, we report on the synthesis, spectral, crystallographic and electrochemical properties of a small library of N-substituted 2-ferrocenyl-1,3-thiazolidin-4-ones, designed as novel GABA(A) benzodiazepine-binding site ligands. The anxiolytic properties of the title compounds were evaluated in several different in vivo models, whereas the involvement of the GABAA receptor complex in the activity of the most potent compound, 2-ferrocenyl-3-(4-methoxyphenylethyl)-1,3-thiazolidin-4-one, was inferred from experiments with known GABA(A)-targeting agents. Ligand docking experiments revealed that the high, dose-dependent, anxiolytic activity of the new compounds might be due to their favorable interactions with the benzodiazepine-binding site of the GABA(A) receptor complex. The incorporation of the ferrocene core and fine tuning of the distance between the thiazolidinone core and an additional aromatic ring were judged to be crucial structural requirements for the observed anxiolytic effect. (C) 2014 Elsevier Masson SAS. All rights reserved.
T2  - European Journal of Medicinal Chemistry
T1  - Discovery of anxiolytic 2-ferrocenyl-1,3-thiazolidin-4-ones exerting GABA(A) receptor interaction via the benzodiazepine-binding site
VL  - 83
SP  - 57
EP  - 73
DO  - 10.1016/j.ejmech.2014.05.062
ER  - 
@article{
author = "Pejović, Anka and Denic, Marija S. and Stevanović, Dragana D. and Damljanović, Ivan S. and Vukićević, Mirjana and Kostova, Kalina and Tavlinova-Kirilova, Maya and Randjelovi, Pavle and Stojanović, Nikola M. and Bogdanović, Goran A. and Blagojevic, Polina and D'hooghe, Matthias and Radulović, Niko S. and Vukićević, Rastko D.",
year = "2014",
abstract = "Herein, we report on the synthesis, spectral, crystallographic and electrochemical properties of a small library of N-substituted 2-ferrocenyl-1,3-thiazolidin-4-ones, designed as novel GABA(A) benzodiazepine-binding site ligands. The anxiolytic properties of the title compounds were evaluated in several different in vivo models, whereas the involvement of the GABAA receptor complex in the activity of the most potent compound, 2-ferrocenyl-3-(4-methoxyphenylethyl)-1,3-thiazolidin-4-one, was inferred from experiments with known GABA(A)-targeting agents. Ligand docking experiments revealed that the high, dose-dependent, anxiolytic activity of the new compounds might be due to their favorable interactions with the benzodiazepine-binding site of the GABA(A) receptor complex. The incorporation of the ferrocene core and fine tuning of the distance between the thiazolidinone core and an additional aromatic ring were judged to be crucial structural requirements for the observed anxiolytic effect. (C) 2014 Elsevier Masson SAS. All rights reserved.",
journal = "European Journal of Medicinal Chemistry",
title = "Discovery of anxiolytic 2-ferrocenyl-1,3-thiazolidin-4-ones exerting GABA(A) receptor interaction via the benzodiazepine-binding site",
volume = "83",
pages = "57-73",
doi = "10.1016/j.ejmech.2014.05.062"
}
Pejović, A., Denic, M. S., Stevanović, D. D., Damljanović, I. S., Vukićević, M., Kostova, K., Tavlinova-Kirilova, M., Randjelovi, P., Stojanović, N. M., Bogdanović, G. A., Blagojevic, P., D'hooghe, M., Radulović, N. S.,& Vukićević, R. D.. (2014). Discovery of anxiolytic 2-ferrocenyl-1,3-thiazolidin-4-ones exerting GABA(A) receptor interaction via the benzodiazepine-binding site. in European Journal of Medicinal Chemistry, 83, 57-73.
https://doi.org/10.1016/j.ejmech.2014.05.062
Pejović A, Denic MS, Stevanović DD, Damljanović IS, Vukićević M, Kostova K, Tavlinova-Kirilova M, Randjelovi P, Stojanović NM, Bogdanović GA, Blagojevic P, D'hooghe M, Radulović NS, Vukićević RD. Discovery of anxiolytic 2-ferrocenyl-1,3-thiazolidin-4-ones exerting GABA(A) receptor interaction via the benzodiazepine-binding site. in European Journal of Medicinal Chemistry. 2014;83:57-73.
doi:10.1016/j.ejmech.2014.05.062 .
Pejović, Anka, Denic, Marija S., Stevanović, Dragana D., Damljanović, Ivan S., Vukićević, Mirjana, Kostova, Kalina, Tavlinova-Kirilova, Maya, Randjelovi, Pavle, Stojanović, Nikola M., Bogdanović, Goran A., Blagojevic, Polina, D'hooghe, Matthias, Radulović, Niko S., Vukićević, Rastko D., "Discovery of anxiolytic 2-ferrocenyl-1,3-thiazolidin-4-ones exerting GABA(A) receptor interaction via the benzodiazepine-binding site" in European Journal of Medicinal Chemistry, 83 (2014):57-73,
https://doi.org/10.1016/j.ejmech.2014.05.062 . .
28
22
25

Synthesis, characterization, and antimicrobial evaluation of a small library of ferrocene-containing acetoacetates and phenyl analogs: the discovery of a potent anticandidal agent

Radulović, Niko S.; Mladenovic, Marko Z.; Stojanovic-Radic, Zorica; Bogdanović, Goran A.; Stevanović, Dragana D.; Vukićević, Rastko D.

(2014)

TY  - JOUR
AU  - Radulović, Niko S.
AU  - Mladenovic, Marko Z.
AU  - Stojanovic-Radic, Zorica
AU  - Bogdanović, Goran A.
AU  - Stevanović, Dragana D.
AU  - Vukićević, Rastko D.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6064
AB  - A library of 16 2-substituted methyl acetoacetates containing ferrocenyl or phenyl units was designed to disclose differences in the antimicrobial activity of ferrocene-containing compounds and their phenyl analogs. Two methyl acetoacetates, whose structures do not contain an aromatic nucleus, were also included in order to probe the inherent activity of the scaffold itself. The acetoacetates were synthesized (low-to-good yields) and fully characterized by spectral (MS, IR, UV-Vis, 1D and 2D NMR) and electrochemical (cyclic voltammetry) techniques. Single-crystal X-ray analysis has been performed for methyl 2-acetyl-2-(ferrocenylmethyl)-5-methylhex-4-enoate. All compounds have demonstrated in vitro antimicrobial activity against six bacterial (three Gram-positive and three Gram-negative) and two fungal strains with minimal inhibitory concentration values of 0.0050-20.6 . The most active compound was 2-acetyl-2-(ferrocenylmethyl)-4-methylpent-4-enoate whose activity was comparable to that of nystatin against the yeast Candida albicans. Agglomerative hierarchical clustering statistical analysis of the antimicrobial assay data demonstrated that ferrocene-containing compounds have statistically different and greater antimicrobial activity when compared to their phenyl analogs.
T2  - Molecular Diversity
T1  - Synthesis, characterization, and antimicrobial evaluation of a small library of ferrocene-containing acetoacetates and phenyl analogs: the discovery of a potent anticandidal agent
VL  - 18
IS  - 3
SP  - 497
EP  - 510
DO  - 10.1007/s11030-014-9511-0
ER  - 
@article{
author = "Radulović, Niko S. and Mladenovic, Marko Z. and Stojanovic-Radic, Zorica and Bogdanović, Goran A. and Stevanović, Dragana D. and Vukićević, Rastko D.",
year = "2014",
abstract = "A library of 16 2-substituted methyl acetoacetates containing ferrocenyl or phenyl units was designed to disclose differences in the antimicrobial activity of ferrocene-containing compounds and their phenyl analogs. Two methyl acetoacetates, whose structures do not contain an aromatic nucleus, were also included in order to probe the inherent activity of the scaffold itself. The acetoacetates were synthesized (low-to-good yields) and fully characterized by spectral (MS, IR, UV-Vis, 1D and 2D NMR) and electrochemical (cyclic voltammetry) techniques. Single-crystal X-ray analysis has been performed for methyl 2-acetyl-2-(ferrocenylmethyl)-5-methylhex-4-enoate. All compounds have demonstrated in vitro antimicrobial activity against six bacterial (three Gram-positive and three Gram-negative) and two fungal strains with minimal inhibitory concentration values of 0.0050-20.6 . The most active compound was 2-acetyl-2-(ferrocenylmethyl)-4-methylpent-4-enoate whose activity was comparable to that of nystatin against the yeast Candida albicans. Agglomerative hierarchical clustering statistical analysis of the antimicrobial assay data demonstrated that ferrocene-containing compounds have statistically different and greater antimicrobial activity when compared to their phenyl analogs.",
journal = "Molecular Diversity",
title = "Synthesis, characterization, and antimicrobial evaluation of a small library of ferrocene-containing acetoacetates and phenyl analogs: the discovery of a potent anticandidal agent",
volume = "18",
number = "3",
pages = "497-510",
doi = "10.1007/s11030-014-9511-0"
}
Radulović, N. S., Mladenovic, M. Z., Stojanovic-Radic, Z., Bogdanović, G. A., Stevanović, D. D.,& Vukićević, R. D.. (2014). Synthesis, characterization, and antimicrobial evaluation of a small library of ferrocene-containing acetoacetates and phenyl analogs: the discovery of a potent anticandidal agent. in Molecular Diversity, 18(3), 497-510.
https://doi.org/10.1007/s11030-014-9511-0
Radulović NS, Mladenovic MZ, Stojanovic-Radic Z, Bogdanović GA, Stevanović DD, Vukićević RD. Synthesis, characterization, and antimicrobial evaluation of a small library of ferrocene-containing acetoacetates and phenyl analogs: the discovery of a potent anticandidal agent. in Molecular Diversity. 2014;18(3):497-510.
doi:10.1007/s11030-014-9511-0 .
Radulović, Niko S., Mladenovic, Marko Z., Stojanovic-Radic, Zorica, Bogdanović, Goran A., Stevanović, Dragana D., Vukićević, Rastko D., "Synthesis, characterization, and antimicrobial evaluation of a small library of ferrocene-containing acetoacetates and phenyl analogs: the discovery of a potent anticandidal agent" in Molecular Diversity, 18, no. 3 (2014):497-510,
https://doi.org/10.1007/s11030-014-9511-0 . .
13
12
12

Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide

Pejović, Anka; Damljanović, Ivan S.; Stevanović, Dragana D.; Ilic, Danijela; Vukićević, Mirjana; Bogdanović, Goran A.; Vukićević, Rastko D.

(2013)

TY  - JOUR
AU  - Pejović, Anka
AU  - Damljanović, Ivan S.
AU  - Stevanović, Dragana D.
AU  - Ilic, Danijela
AU  - Vukićević, Mirjana
AU  - Bogdanović, Goran A.
AU  - Vukićević, Rastko D.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5623
AB  - Dimethyl(2-ferrocenoylethyl)sulfonium iodide was synthesized by reacting 1-ferroceny1-4-thiapentan-1-one with iodomethane and characterized from spectral data and single crystal X-ray structure analysis. This compound was capable of reacting with different N-, S-, and O-nucleophiles giving the corresponding beta-functionalized ferrocene-containing ketones. Furthermore, dimethyl sulfide can be displaced from the dimethyl(2-ferrocenoylethyl)sulfonium ion with cyanide or carbanions derived from 1,3-bifunctional compounds and nitropropane, leading to products with a new carbon-carbon bond. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Tetrahedron Letters
T1  - Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide
VL  - 54
IS  - 35
SP  - 4776
EP  - 4780
DO  - 10.1016/j.tetlet.2013.06.130
ER  - 
@article{
author = "Pejović, Anka and Damljanović, Ivan S. and Stevanović, Dragana D. and Ilic, Danijela and Vukićević, Mirjana and Bogdanović, Goran A. and Vukićević, Rastko D.",
year = "2013",
abstract = "Dimethyl(2-ferrocenoylethyl)sulfonium iodide was synthesized by reacting 1-ferroceny1-4-thiapentan-1-one with iodomethane and characterized from spectral data and single crystal X-ray structure analysis. This compound was capable of reacting with different N-, S-, and O-nucleophiles giving the corresponding beta-functionalized ferrocene-containing ketones. Furthermore, dimethyl sulfide can be displaced from the dimethyl(2-ferrocenoylethyl)sulfonium ion with cyanide or carbanions derived from 1,3-bifunctional compounds and nitropropane, leading to products with a new carbon-carbon bond. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Tetrahedron Letters",
title = "Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide",
volume = "54",
number = "35",
pages = "4776-4780",
doi = "10.1016/j.tetlet.2013.06.130"
}
Pejović, A., Damljanović, I. S., Stevanović, D. D., Ilic, D., Vukićević, M., Bogdanović, G. A.,& Vukićević, R. D.. (2013). Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide. in Tetrahedron Letters, 54(35), 4776-4780.
https://doi.org/10.1016/j.tetlet.2013.06.130
Pejović A, Damljanović IS, Stevanović DD, Ilic D, Vukićević M, Bogdanović GA, Vukićević RD. Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide. in Tetrahedron Letters. 2013;54(35):4776-4780.
doi:10.1016/j.tetlet.2013.06.130 .
Pejović, Anka, Damljanović, Ivan S., Stevanović, Dragana D., Ilic, Danijela, Vukićević, Mirjana, Bogdanović, Goran A., Vukićević, Rastko D., "Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide" in Tetrahedron Letters, 54, no. 35 (2013):4776-4780,
https://doi.org/10.1016/j.tetlet.2013.06.130 . .
5
3
4

Anodic generation of a zirconium catalyst for Ferrier rearrangement and hetero Michael addition

Stevanović, Dragana D.; Pejović, Anka; Damljanović, Ivan S.; Vukićević, Mirjana; Bogdanović, Goran A.; Vukićević, Rastko D.

(2012)

TY  - JOUR
AU  - Stevanović, Dragana D.
AU  - Pejović, Anka
AU  - Damljanović, Ivan S.
AU  - Vukićević, Mirjana
AU  - Bogdanović, Goran A.
AU  - Vukićević, Rastko D.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5163
AB  - An efficient catalyst for Ferrier rearrangement and hetero-Michael addition was successfully generated from a sacrificial zirconium anode into media containing reactants for these reactions. Thus, the catalyst generated, successfully promoted the allylic rearrangement of peracetylated D-glucal in the presence of a suitable S-nucleophile, giving the corresponding 2,3-unsaturated D-glucopyranose (pseudoglycal) in good to high yields. This catalyst was also shown to be capable of promoting hetero-Michael conjugate addition of S- and N-nucleophiles to the carbon-carbon double bond of methyl vinyl ketone, resulting in new carbon-sulfur and carbon-nitrogen bond formation. (C) 2012 Elsevier Ltd. All rights reserved.
T2  - Tetrahedron Letters
T1  - Anodic generation of a zirconium catalyst for Ferrier rearrangement and hetero Michael addition
VL  - 53
IS  - 46
SP  - 6257
EP  - 6260
DO  - 10.1016/j.tetlet.2012.09.023
ER  - 
@article{
author = "Stevanović, Dragana D. and Pejović, Anka and Damljanović, Ivan S. and Vukićević, Mirjana and Bogdanović, Goran A. and Vukićević, Rastko D.",
year = "2012",
abstract = "An efficient catalyst for Ferrier rearrangement and hetero-Michael addition was successfully generated from a sacrificial zirconium anode into media containing reactants for these reactions. Thus, the catalyst generated, successfully promoted the allylic rearrangement of peracetylated D-glucal in the presence of a suitable S-nucleophile, giving the corresponding 2,3-unsaturated D-glucopyranose (pseudoglycal) in good to high yields. This catalyst was also shown to be capable of promoting hetero-Michael conjugate addition of S- and N-nucleophiles to the carbon-carbon double bond of methyl vinyl ketone, resulting in new carbon-sulfur and carbon-nitrogen bond formation. (C) 2012 Elsevier Ltd. All rights reserved.",
journal = "Tetrahedron Letters",
title = "Anodic generation of a zirconium catalyst for Ferrier rearrangement and hetero Michael addition",
volume = "53",
number = "46",
pages = "6257-6260",
doi = "10.1016/j.tetlet.2012.09.023"
}
Stevanović, D. D., Pejović, A., Damljanović, I. S., Vukićević, M., Bogdanović, G. A.,& Vukićević, R. D.. (2012). Anodic generation of a zirconium catalyst for Ferrier rearrangement and hetero Michael addition. in Tetrahedron Letters, 53(46), 6257-6260.
https://doi.org/10.1016/j.tetlet.2012.09.023
Stevanović DD, Pejović A, Damljanović IS, Vukićević M, Bogdanović GA, Vukićević RD. Anodic generation of a zirconium catalyst for Ferrier rearrangement and hetero Michael addition. in Tetrahedron Letters. 2012;53(46):6257-6260.
doi:10.1016/j.tetlet.2012.09.023 .
Stevanović, Dragana D., Pejović, Anka, Damljanović, Ivan S., Vukićević, Mirjana, Bogdanović, Goran A., Vukićević, Rastko D., "Anodic generation of a zirconium catalyst for Ferrier rearrangement and hetero Michael addition" in Tetrahedron Letters, 53, no. 46 (2012):6257-6260,
https://doi.org/10.1016/j.tetlet.2012.09.023 . .
15
12
15

Ultrasound-Assisted Synthesis of 3-(Arylamino)-1-ferrocenylpropan-1-ones

Pejović, Anka; Stevanović, Dragana D.; Damljanović, Ivan S.; Vukićević, Mirjana; Novaković, Slađana B.; Bogdanović, Goran A.; Mihajilov-Krstev, Tatjana; Radulovic, Niko; Vukićević, Rastko D.

(2012)

TY  - JOUR
AU  - Pejović, Anka
AU  - Stevanović, Dragana D.
AU  - Damljanović, Ivan S.
AU  - Vukićević, Mirjana
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Mihajilov-Krstev, Tatjana
AU  - Radulovic, Niko
AU  - Vukićević, Rastko D.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5014
AB  - A successful aza-Michael addition of arylamines to a conjugated enone, acryloylferrocene, has been achieved by ultrasonic irradiation of the mixture of these reactants and the catalyst, i.e., montmorillonite K-10. This solvent-free reaction, yielding ferrocene containing Mannich bases, 3-(arylamino)-1-ferrocenylpropan-1-ones, considered as valuable precursors in organic synthesis, has been performed by using a simple ultrasonic cleaner. Among 17 synthesized beta-amino ketones, three were new ones, and these were fully characterized by spectroscopic means. X-Ray crystallographic analysis of three of these crystalline products enabled the insight into the conformational details of these compounds. All compounds were evaluated for their antibacterial activities against six Gram-positive and five Gram-negative strains in a microdilution assay. The observed promising antibacterial activity (with a MIC value of 25 mu g/ml (ca. 0.07 mu mol/ml) as the best result for almost all tested compounds against Micrococcus flavus) seems not only to be compound but also bacterial species-specific.
T2  - Helvetica Chimica Acta
T1  - Ultrasound-Assisted Synthesis of 3-(Arylamino)-1-ferrocenylpropan-1-ones
VL  - 95
IS  - 8
SP  - 1425
EP  - 1441
DO  - 10.1002/hlca.201200009
ER  - 
@article{
author = "Pejović, Anka and Stevanović, Dragana D. and Damljanović, Ivan S. and Vukićević, Mirjana and Novaković, Slađana B. and Bogdanović, Goran A. and Mihajilov-Krstev, Tatjana and Radulovic, Niko and Vukićević, Rastko D.",
year = "2012",
abstract = "A successful aza-Michael addition of arylamines to a conjugated enone, acryloylferrocene, has been achieved by ultrasonic irradiation of the mixture of these reactants and the catalyst, i.e., montmorillonite K-10. This solvent-free reaction, yielding ferrocene containing Mannich bases, 3-(arylamino)-1-ferrocenylpropan-1-ones, considered as valuable precursors in organic synthesis, has been performed by using a simple ultrasonic cleaner. Among 17 synthesized beta-amino ketones, three were new ones, and these were fully characterized by spectroscopic means. X-Ray crystallographic analysis of three of these crystalline products enabled the insight into the conformational details of these compounds. All compounds were evaluated for their antibacterial activities against six Gram-positive and five Gram-negative strains in a microdilution assay. The observed promising antibacterial activity (with a MIC value of 25 mu g/ml (ca. 0.07 mu mol/ml) as the best result for almost all tested compounds against Micrococcus flavus) seems not only to be compound but also bacterial species-specific.",
journal = "Helvetica Chimica Acta",
title = "Ultrasound-Assisted Synthesis of 3-(Arylamino)-1-ferrocenylpropan-1-ones",
volume = "95",
number = "8",
pages = "1425-1441",
doi = "10.1002/hlca.201200009"
}
Pejović, A., Stevanović, D. D., Damljanović, I. S., Vukićević, M., Novaković, S. B., Bogdanović, G. A., Mihajilov-Krstev, T., Radulovic, N.,& Vukićević, R. D.. (2012). Ultrasound-Assisted Synthesis of 3-(Arylamino)-1-ferrocenylpropan-1-ones. in Helvetica Chimica Acta, 95(8), 1425-1441.
https://doi.org/10.1002/hlca.201200009
Pejović A, Stevanović DD, Damljanović IS, Vukićević M, Novaković SB, Bogdanović GA, Mihajilov-Krstev T, Radulovic N, Vukićević RD. Ultrasound-Assisted Synthesis of 3-(Arylamino)-1-ferrocenylpropan-1-ones. in Helvetica Chimica Acta. 2012;95(8):1425-1441.
doi:10.1002/hlca.201200009 .
Pejović, Anka, Stevanović, Dragana D., Damljanović, Ivan S., Vukićević, Mirjana, Novaković, Slađana B., Bogdanović, Goran A., Mihajilov-Krstev, Tatjana, Radulovic, Niko, Vukićević, Rastko D., "Ultrasound-Assisted Synthesis of 3-(Arylamino)-1-ferrocenylpropan-1-ones" in Helvetica Chimica Acta, 95, no. 8 (2012):1425-1441,
https://doi.org/10.1002/hlca.201200009 . .
21
15
16

Antimicrobial ferrocene containing quinolinones: Synthesis, spectral, electrochemical and structural characterization of 2-ferrocenyl-2, 3-dihydroquinolin-4(1H)-one and its 6-chloro and 6-bromo derivatives

Pejović, Anka; Damljanović, Ivan S.; Stevanović, Dragana D.; Vukićević, Mirjana; Novaković, Slađana B.; Bogdanović, Goran A.; Radulovic, Niko; Vukićević, Rastko D.

(2012)

TY  - JOUR
AU  - Pejović, Anka
AU  - Damljanović, Ivan S.
AU  - Stevanović, Dragana D.
AU  - Vukićević, Mirjana
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Radulovic, Niko
AU  - Vukićević, Rastko D.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4710
AB  - Syntheses of three new ferrocene containing heterocycles - 2-ferroceny1-2,3-dihydroquinolin-4(1H)-one and its 6-chloro and 6-bromo derivatives - starting from 2-aminoacetophenones and ferrocenecarboxaldehyde was achieved in two steps. The aldol condensation of these substrates gave the corresponding 2-aminochalcones in the first stage, whereas a further intramolecular cyclization gives the final products. This cyclization was performed by either a solvent-free microwave irradiation (500 W/5 min) of a mixture of chalcones and mortmorillonite K-10 or by using an acidic catalyst (the mixture of acetic and orthophosphoric acid). The latter method, which can be performed by simple stirring at room temperature or by irradiation in an ultrasonic bath, gave much better results. The obtained compounds were spectrally and electrochemically (cyclic voltammetry) fully characterized, as well as by single-crystal X-ray analysis. A microdilution assay revealed that the three dihydroquinolinones can be regarded as potential lead compounds in the discovery of new antimicrobial drugs due to their very strong and unselective activity towards pathogenic bacteria and one yeast with MIC values (0.01-10.0 mu/mL) lower than that of tetracycline. (C) 2011 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - Antimicrobial ferrocene containing quinolinones: Synthesis, spectral, electrochemical and structural characterization of 2-ferrocenyl-2, 3-dihydroquinolin-4(1H)-one and its 6-chloro and 6-bromo derivatives
VL  - 31
IS  - 1
SP  - 789
EP  - 795
DO  - 10.1016/j.poly.2011.11.006
ER  - 
@article{
author = "Pejović, Anka and Damljanović, Ivan S. and Stevanović, Dragana D. and Vukićević, Mirjana and Novaković, Slađana B. and Bogdanović, Goran A. and Radulovic, Niko and Vukićević, Rastko D.",
year = "2012",
abstract = "Syntheses of three new ferrocene containing heterocycles - 2-ferroceny1-2,3-dihydroquinolin-4(1H)-one and its 6-chloro and 6-bromo derivatives - starting from 2-aminoacetophenones and ferrocenecarboxaldehyde was achieved in two steps. The aldol condensation of these substrates gave the corresponding 2-aminochalcones in the first stage, whereas a further intramolecular cyclization gives the final products. This cyclization was performed by either a solvent-free microwave irradiation (500 W/5 min) of a mixture of chalcones and mortmorillonite K-10 or by using an acidic catalyst (the mixture of acetic and orthophosphoric acid). The latter method, which can be performed by simple stirring at room temperature or by irradiation in an ultrasonic bath, gave much better results. The obtained compounds were spectrally and electrochemically (cyclic voltammetry) fully characterized, as well as by single-crystal X-ray analysis. A microdilution assay revealed that the three dihydroquinolinones can be regarded as potential lead compounds in the discovery of new antimicrobial drugs due to their very strong and unselective activity towards pathogenic bacteria and one yeast with MIC values (0.01-10.0 mu/mL) lower than that of tetracycline. (C) 2011 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Antimicrobial ferrocene containing quinolinones: Synthesis, spectral, electrochemical and structural characterization of 2-ferrocenyl-2, 3-dihydroquinolin-4(1H)-one and its 6-chloro and 6-bromo derivatives",
volume = "31",
number = "1",
pages = "789-795",
doi = "10.1016/j.poly.2011.11.006"
}
Pejović, A., Damljanović, I. S., Stevanović, D. D., Vukićević, M., Novaković, S. B., Bogdanović, G. A., Radulovic, N.,& Vukićević, R. D.. (2012). Antimicrobial ferrocene containing quinolinones: Synthesis, spectral, electrochemical and structural characterization of 2-ferrocenyl-2, 3-dihydroquinolin-4(1H)-one and its 6-chloro and 6-bromo derivatives. in Polyhedron, 31(1), 789-795.
https://doi.org/10.1016/j.poly.2011.11.006
Pejović A, Damljanović IS, Stevanović DD, Vukićević M, Novaković SB, Bogdanović GA, Radulovic N, Vukićević RD. Antimicrobial ferrocene containing quinolinones: Synthesis, spectral, electrochemical and structural characterization of 2-ferrocenyl-2, 3-dihydroquinolin-4(1H)-one and its 6-chloro and 6-bromo derivatives. in Polyhedron. 2012;31(1):789-795.
doi:10.1016/j.poly.2011.11.006 .
Pejović, Anka, Damljanović, Ivan S., Stevanović, Dragana D., Vukićević, Mirjana, Novaković, Slađana B., Bogdanović, Goran A., Radulovic, Niko, Vukićević, Rastko D., "Antimicrobial ferrocene containing quinolinones: Synthesis, spectral, electrochemical and structural characterization of 2-ferrocenyl-2, 3-dihydroquinolin-4(1H)-one and its 6-chloro and 6-bromo derivatives" in Polyhedron, 31, no. 1 (2012):789-795,
https://doi.org/10.1016/j.poly.2011.11.006 . .
35
39
39

A new polymorph of 1-ferrocenyl-3-(3-nitroanilino)propan-1-one

Stevanović, Dragana D.; Pejović, Anka; Novaković, Slađana B.; Bogdanović, Goran A.; Divjakovic, Vladimir; Vukićević, Rastko D.

(2012)

TY  - JOUR
AU  - Stevanović, Dragana D.
AU  - Pejović, Anka
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Divjakovic, Vladimir
AU  - Vukićević, Rastko D.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4674
AB  - Recrystallization of the title compound, [Fe(C5H5)(C14H13N2O3)], from a mixture of n-hexane and dichloromethane gave the new polymorph, denoted (I), which crystallizes in the same space group (P (1) over bar) as the previously reported structure, denoted (II). The Fe-C distances in (I) range from 2.015 (3) to 2.048 (2) angstrom and the average value of the C-C bond lengths in the two cyclopentadienyl (Cp) rings is 1.403 (13) angstrom. As indicated by the smallest C-Cg1-Cg2-C torsion angle of 1.4 degrees (Cg1 and Cg2 are the centroids of the two Cp rings), the orientation of the Cp rings in (I) is more eclipsed than in the case of (II), for which the value was 15.3 degrees. Despite the pronounced conformational similarity between (I) and (II), the formation of self-complementary N-H center dot center dot center dot O hydrogen-bonded dimers represents the only structural motif common to the two polymorphs. In the extended structure, molecules of (I) utilize C-H center dot center dot center dot O hydrogen bonds and, unlike (II), an extensive set of intermolecular C-H center dot center dot center dot pi interactions. Finger-print plots based on Hirshfeld surfaces are used to compare the packing of the two polymorphs.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - A new polymorph of 1-ferrocenyl-3-(3-nitroanilino)propan-1-one
VL  - 68
SP  - M37
EP  - M40
DO  - 10.1107/S0108270112000765
ER  - 
@article{
author = "Stevanović, Dragana D. and Pejović, Anka and Novaković, Slađana B. and Bogdanović, Goran A. and Divjakovic, Vladimir and Vukićević, Rastko D.",
year = "2012",
abstract = "Recrystallization of the title compound, [Fe(C5H5)(C14H13N2O3)], from a mixture of n-hexane and dichloromethane gave the new polymorph, denoted (I), which crystallizes in the same space group (P (1) over bar) as the previously reported structure, denoted (II). The Fe-C distances in (I) range from 2.015 (3) to 2.048 (2) angstrom and the average value of the C-C bond lengths in the two cyclopentadienyl (Cp) rings is 1.403 (13) angstrom. As indicated by the smallest C-Cg1-Cg2-C torsion angle of 1.4 degrees (Cg1 and Cg2 are the centroids of the two Cp rings), the orientation of the Cp rings in (I) is more eclipsed than in the case of (II), for which the value was 15.3 degrees. Despite the pronounced conformational similarity between (I) and (II), the formation of self-complementary N-H center dot center dot center dot O hydrogen-bonded dimers represents the only structural motif common to the two polymorphs. In the extended structure, molecules of (I) utilize C-H center dot center dot center dot O hydrogen bonds and, unlike (II), an extensive set of intermolecular C-H center dot center dot center dot pi interactions. Finger-print plots based on Hirshfeld surfaces are used to compare the packing of the two polymorphs.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "A new polymorph of 1-ferrocenyl-3-(3-nitroanilino)propan-1-one",
volume = "68",
pages = "M37-M40",
doi = "10.1107/S0108270112000765"
}
Stevanović, D. D., Pejović, A., Novaković, S. B., Bogdanović, G. A., Divjakovic, V.,& Vukićević, R. D.. (2012). A new polymorph of 1-ferrocenyl-3-(3-nitroanilino)propan-1-one. in Acta Crystallographica. Section C: Crystal Structure Communications, 68, M37-M40.
https://doi.org/10.1107/S0108270112000765
Stevanović DD, Pejović A, Novaković SB, Bogdanović GA, Divjakovic V, Vukićević RD. A new polymorph of 1-ferrocenyl-3-(3-nitroanilino)propan-1-one. in Acta Crystallographica. Section C: Crystal Structure Communications. 2012;68:M37-M40.
doi:10.1107/S0108270112000765 .
Stevanović, Dragana D., Pejović, Anka, Novaković, Slađana B., Bogdanović, Goran A., Divjakovic, Vladimir, Vukićević, Rastko D., "A new polymorph of 1-ferrocenyl-3-(3-nitroanilino)propan-1-one" in Acta Crystallographica. Section C: Crystal Structure Communications, 68 (2012):M37-M40,
https://doi.org/10.1107/S0108270112000765 . .
1
5
5
5

3-Anilino-1-ferrocenylpropan-1-one

Leka, Zorica; Novaković, Slađana B.; Stevanović, Dragana D.; Bogdanović, Goran A.; Vukićević, Rastko D.

(2012)

TY  - JOUR
AU  - Leka, Zorica
AU  - Novaković, Slađana B.
AU  - Stevanović, Dragana D.
AU  - Bogdanović, Goran A.
AU  - Vukićević, Rastko D.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4722
AB  - In the title ferrocene derivative, [Fe(C5H5)(C14H14NO)], the dihedral angle between the mean planes of the phenyl ring and the substituted cyclopentadienyl ring is 84.4 (1)degrees. The molecules are connected into centrosymmetric dimers via N-H center dot center dot center dot O hydrogen bonds. In addition, C-H center dot center dot center dot O and C-H center dot center dot center dot N contacts stabilize the crystal packing.
T2  - Acta Crystallographica. Section E: Structure Reports Online
T1  - 3-Anilino-1-ferrocenylpropan-1-one
VL  - 68
SP  - M229
EP  - U1342
DO  - 10.1107/S1600536812003492
ER  - 
@article{
author = "Leka, Zorica and Novaković, Slađana B. and Stevanović, Dragana D. and Bogdanović, Goran A. and Vukićević, Rastko D.",
year = "2012",
abstract = "In the title ferrocene derivative, [Fe(C5H5)(C14H14NO)], the dihedral angle between the mean planes of the phenyl ring and the substituted cyclopentadienyl ring is 84.4 (1)degrees. The molecules are connected into centrosymmetric dimers via N-H center dot center dot center dot O hydrogen bonds. In addition, C-H center dot center dot center dot O and C-H center dot center dot center dot N contacts stabilize the crystal packing.",
journal = "Acta Crystallographica. Section E: Structure Reports Online",
title = "3-Anilino-1-ferrocenylpropan-1-one",
volume = "68",
pages = "M229-U1342",
doi = "10.1107/S1600536812003492"
}
Leka, Z., Novaković, S. B., Stevanović, D. D., Bogdanović, G. A.,& Vukićević, R. D.. (2012). 3-Anilino-1-ferrocenylpropan-1-one. in Acta Crystallographica. Section E: Structure Reports Online, 68, M229-U1342.
https://doi.org/10.1107/S1600536812003492
Leka Z, Novaković SB, Stevanović DD, Bogdanović GA, Vukićević RD. 3-Anilino-1-ferrocenylpropan-1-one. in Acta Crystallographica. Section E: Structure Reports Online. 2012;68:M229-U1342.
doi:10.1107/S1600536812003492 .
Leka, Zorica, Novaković, Slađana B., Stevanović, Dragana D., Bogdanović, Goran A., Vukićević, Rastko D., "3-Anilino-1-ferrocenylpropan-1-one" in Acta Crystallographica. Section E: Structure Reports Online, 68 (2012):M229-U1342,
https://doi.org/10.1107/S1600536812003492 . .
5
5
5

1-Ferrocenyl-3-(4-methylanilino)propan-1-one

Leka, Zorica; Novaković, Slađana B.; Stevanović, Dragana D.; Bogdanović, Goran A.; Vukićević, Rastko D.

(2012)

TY  - JOUR
AU  - Leka, Zorica
AU  - Novaković, Slađana B.
AU  - Stevanović, Dragana D.
AU  - Bogdanović, Goran A.
AU  - Vukićević, Rastko D.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4723
AB  - In the title ferrocene derivative, [Fe(C5H5)(C15H16NO)], the dihedral angle between the best planes of the benzene and the substituted cyclopentadienyl ring is 83.4 (1)degrees. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compared to that of 3-anilino- 1-ferrocenylpropan-1-one [Leka et al. (2012). Acta Cryst. E68, m229]. The molecules are connected into centrosymmetric dimers via N-H center dot center dot center dot O hydrogen bonds. In addition, C-H center dot center dot center dot O and C-H center dot center dot center dot N contacts stabilize the crystal packing.
T2  - Acta Crystallographica. Section E: Structure Reports Online
T1  - 1-Ferrocenyl-3-(4-methylanilino)propan-1-one
VL  - 68
SP  - M230
EP  - U1355
DO  - 10.1107/S1600536812003509
ER  - 
@article{
author = "Leka, Zorica and Novaković, Slađana B. and Stevanović, Dragana D. and Bogdanović, Goran A. and Vukićević, Rastko D.",
year = "2012",
abstract = "In the title ferrocene derivative, [Fe(C5H5)(C15H16NO)], the dihedral angle between the best planes of the benzene and the substituted cyclopentadienyl ring is 83.4 (1)degrees. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compared to that of 3-anilino- 1-ferrocenylpropan-1-one [Leka et al. (2012). Acta Cryst. E68, m229]. The molecules are connected into centrosymmetric dimers via N-H center dot center dot center dot O hydrogen bonds. In addition, C-H center dot center dot center dot O and C-H center dot center dot center dot N contacts stabilize the crystal packing.",
journal = "Acta Crystallographica. Section E: Structure Reports Online",
title = "1-Ferrocenyl-3-(4-methylanilino)propan-1-one",
volume = "68",
pages = "M230-U1355",
doi = "10.1107/S1600536812003509"
}
Leka, Z., Novaković, S. B., Stevanović, D. D., Bogdanović, G. A.,& Vukićević, R. D.. (2012). 1-Ferrocenyl-3-(4-methylanilino)propan-1-one. in Acta Crystallographica. Section E: Structure Reports Online, 68, M230-U1355.
https://doi.org/10.1107/S1600536812003509
Leka Z, Novaković SB, Stevanović DD, Bogdanović GA, Vukićević RD. 1-Ferrocenyl-3-(4-methylanilino)propan-1-one. in Acta Crystallographica. Section E: Structure Reports Online. 2012;68:M230-U1355.
doi:10.1107/S1600536812003509 .
Leka, Zorica, Novaković, Slađana B., Stevanović, Dragana D., Bogdanović, Goran A., Vukićević, Rastko D., "1-Ferrocenyl-3-(4-methylanilino)propan-1-one" in Acta Crystallographica. Section E: Structure Reports Online, 68 (2012):M230-U1355,
https://doi.org/10.1107/S1600536812003509 . .
5
5
5

1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one

Leka, Zorica; Novaković, Slađana B.; Pejović, Anka; Bogdanović, Goran A.; Vukićević, Rastko D.

(2012)

TY  - JOUR
AU  - Leka, Zorica
AU  - Novaković, Slađana B.
AU  - Pejović, Anka
AU  - Bogdanović, Goran A.
AU  - Vukićević, Rastko D.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4724
AB  - The title ferrocene derivative, [Fe(C5H5)(C14H13FNO)], crystallizes in the same space group with similar unit-cell parameters as the derivatives 3-anilino-1-ferrocenylpropan-1- one [Leka et al. (2012). Acta Cryst. E68, m229] and 1-ferrocenyl- 3-(4-methylanilino) propan-1-one [Leka et al. (2012). Acta Cryst. E68, m230]. The dihedral angle between the best planes of the benzene ring and the substituted cyclopentadienyl ring is 83.4 (1)degrees. The presence of the electronegative fluoro substituent in the meta position of the aniline group does not alter the crystal packing compared to the other two derivatives. The molecules are connected into centrosymmetric dimers via N-H center dot center dot center dot O hydrogen bonds. In addition, C-H center dot center dot center dot O and C-H center dot center dot center dot N contacts stabilize the crystal packing.
T2  - Acta Crystallographica. Section E: Structure Reports Online
T1  - 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one
VL  - 68
SP  - M231
EP  - U1368
DO  - 10.1107/S1600536812003510
ER  - 
@article{
author = "Leka, Zorica and Novaković, Slađana B. and Pejović, Anka and Bogdanović, Goran A. and Vukićević, Rastko D.",
year = "2012",
abstract = "The title ferrocene derivative, [Fe(C5H5)(C14H13FNO)], crystallizes in the same space group with similar unit-cell parameters as the derivatives 3-anilino-1-ferrocenylpropan-1- one [Leka et al. (2012). Acta Cryst. E68, m229] and 1-ferrocenyl- 3-(4-methylanilino) propan-1-one [Leka et al. (2012). Acta Cryst. E68, m230]. The dihedral angle between the best planes of the benzene ring and the substituted cyclopentadienyl ring is 83.4 (1)degrees. The presence of the electronegative fluoro substituent in the meta position of the aniline group does not alter the crystal packing compared to the other two derivatives. The molecules are connected into centrosymmetric dimers via N-H center dot center dot center dot O hydrogen bonds. In addition, C-H center dot center dot center dot O and C-H center dot center dot center dot N contacts stabilize the crystal packing.",
journal = "Acta Crystallographica. Section E: Structure Reports Online",
title = "1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one",
volume = "68",
pages = "M231-U1368",
doi = "10.1107/S1600536812003510"
}
Leka, Z., Novaković, S. B., Pejović, A., Bogdanović, G. A.,& Vukićević, R. D.. (2012). 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one. in Acta Crystallographica. Section E: Structure Reports Online, 68, M231-U1368.
https://doi.org/10.1107/S1600536812003510
Leka Z, Novaković SB, Pejović A, Bogdanović GA, Vukićević RD. 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one. in Acta Crystallographica. Section E: Structure Reports Online. 2012;68:M231-U1368.
doi:10.1107/S1600536812003510 .
Leka, Zorica, Novaković, Slađana B., Pejović, Anka, Bogdanović, Goran A., Vukićević, Rastko D., "1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one" in Acta Crystallographica. Section E: Structure Reports Online, 68 (2012):M231-U1368,
https://doi.org/10.1107/S1600536812003510 . .
4
4
4

Antibacterial 3-(arylamino)-1-ferrocenylpropan-1-ones: Synthesis, spectral, electrochemical and structural characterization

Damljanović, Ivan S.; Stevanović, Dragana D.; Pejović, Anka; Vukićević, Mirjana; Novaković, Slađana B.; Bogdanović, Goran A.; Mihajlov-Krstev, Tatjana; Radulovic, Niko; Vukićević, Rastko D.

(2011)

TY  - JOUR
AU  - Damljanović, Ivan S.
AU  - Stevanović, Dragana D.
AU  - Pejović, Anka
AU  - Vukićević, Mirjana
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Mihajlov-Krstev, Tatjana
AU  - Radulovic, Niko
AU  - Vukićević, Rastko D.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4552
AB  - Syntheses of fourteen new 3-(arylamino)-1-ferrocenylpropan-1-ones have been achieved in good to excellent yields by an aza-Michael addition of different arylamines to acryloylferrocene. The reaction was performed by microwave (MW) irradiation (500 W/5 min) of a mixture of reactants and montmorillonite K-10, without a solvent. The obtained compounds were spectrally and electrochemically (cyclic voltammetry) fully characterized, whereas single-crystal X-ray analysis has been performed for three of them. In a microdilution assay, all of the compounds were shown to have a broad-spectrum effect on Gram-negative and -positive bacteria, although the degree of inhibition varied. A notable activity was observed for all compounds in inhibiting the growth of an important human pathogen Staphylococcus aureus. (C) 2011 Elsevier B.V. All rights reserved.
T2  - Journal of Organometallic Chemistry
T1  - Antibacterial 3-(arylamino)-1-ferrocenylpropan-1-ones: Synthesis, spectral, electrochemical and structural characterization
VL  - 696
IS  - 23
SP  - 3703
EP  - 3713
DO  - 10.1016/j.jorganchem.2011.08.016
ER  - 
@article{
author = "Damljanović, Ivan S. and Stevanović, Dragana D. and Pejović, Anka and Vukićević, Mirjana and Novaković, Slađana B. and Bogdanović, Goran A. and Mihajlov-Krstev, Tatjana and Radulovic, Niko and Vukićević, Rastko D.",
year = "2011",
abstract = "Syntheses of fourteen new 3-(arylamino)-1-ferrocenylpropan-1-ones have been achieved in good to excellent yields by an aza-Michael addition of different arylamines to acryloylferrocene. The reaction was performed by microwave (MW) irradiation (500 W/5 min) of a mixture of reactants and montmorillonite K-10, without a solvent. The obtained compounds were spectrally and electrochemically (cyclic voltammetry) fully characterized, whereas single-crystal X-ray analysis has been performed for three of them. In a microdilution assay, all of the compounds were shown to have a broad-spectrum effect on Gram-negative and -positive bacteria, although the degree of inhibition varied. A notable activity was observed for all compounds in inhibiting the growth of an important human pathogen Staphylococcus aureus. (C) 2011 Elsevier B.V. All rights reserved.",
journal = "Journal of Organometallic Chemistry",
title = "Antibacterial 3-(arylamino)-1-ferrocenylpropan-1-ones: Synthesis, spectral, electrochemical and structural characterization",
volume = "696",
number = "23",
pages = "3703-3713",
doi = "10.1016/j.jorganchem.2011.08.016"
}
Damljanović, I. S., Stevanović, D. D., Pejović, A., Vukićević, M., Novaković, S. B., Bogdanović, G. A., Mihajlov-Krstev, T., Radulovic, N.,& Vukićević, R. D.. (2011). Antibacterial 3-(arylamino)-1-ferrocenylpropan-1-ones: Synthesis, spectral, electrochemical and structural characterization. in Journal of Organometallic Chemistry, 696(23), 3703-3713.
https://doi.org/10.1016/j.jorganchem.2011.08.016
Damljanović IS, Stevanović DD, Pejović A, Vukićević M, Novaković SB, Bogdanović GA, Mihajlov-Krstev T, Radulovic N, Vukićević RD. Antibacterial 3-(arylamino)-1-ferrocenylpropan-1-ones: Synthesis, spectral, electrochemical and structural characterization. in Journal of Organometallic Chemistry. 2011;696(23):3703-3713.
doi:10.1016/j.jorganchem.2011.08.016 .
Damljanović, Ivan S., Stevanović, Dragana D., Pejović, Anka, Vukićević, Mirjana, Novaković, Slađana B., Bogdanović, Goran A., Mihajlov-Krstev, Tatjana, Radulovic, Niko, Vukićević, Rastko D., "Antibacterial 3-(arylamino)-1-ferrocenylpropan-1-ones: Synthesis, spectral, electrochemical and structural characterization" in Journal of Organometallic Chemistry, 696, no. 23 (2011):3703-3713,
https://doi.org/10.1016/j.jorganchem.2011.08.016 . .
35
35
33

Could X-Ray Analysis Explain for the Differing Antimicrobial and Antioxidant Activity of Two 2-Arylamino-3-Nitro-Coumarins?

Radulović, Niko S.; Bogdanović, Goran A.; Blagojevic, Polina D.; Dekic, Vidosav S.; Vukićević, Rastko D.

(2011)

TY  - JOUR
AU  - Radulović, Niko S.
AU  - Bogdanović, Goran A.
AU  - Blagojevic, Polina D.
AU  - Dekic, Vidosav S.
AU  - Vukićević, Rastko D.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4243
AB  - X-Ray analyses of 4-(naphthalen-1-ylamino)-3-nitro-chromen-2-one and 3-nitro-4-phenylamino-chromen-2-one showed that the mentioned compounds crystallize in the space groups P1- (triclinic crystal system; unit cell parameters: a = 8.087(2) , b = 9.241(3) , c = 10.911(3) , alpha = 93.77(3)A degrees, beta = 102.51(3)A degrees, gamma = 106.44(2)A degrees, V = 756.4(4) (3) and Z = 2) and P2(1)2(1)2(1) (orthorhombic crystal system; unit cell parameters: a = 4.9274(9) , b = 14.725(3) , c = 17.866(4) , alpha = beta = gamma = 90A degrees, V = 1296.3(5) (3) and Z = 4), respectively. The analyses of crystal structures and gas phase conformations, inferred from single X-ray crystallographic and molecular modeling experiments, respectively, showed that the changes in pi delocalization of the farmacoactive formal 3-amino-2-nitro-acrylic acid derivatives might explain the observed significant difference of the antimicrobial and antioxidant activities and spectral properties of two 4-arylamino-3-nitro-coumarin derivatives.
T2  - Journal of Chemical Crystallography
T1  - Could X-Ray Analysis Explain for the Differing Antimicrobial and Antioxidant Activity of Two 2-Arylamino-3-Nitro-Coumarins?
VL  - 41
IS  - 4
SP  - 545
EP  - 551
DO  - 10.1007/s10870-010-9918-0
ER  - 
@article{
author = "Radulović, Niko S. and Bogdanović, Goran A. and Blagojevic, Polina D. and Dekic, Vidosav S. and Vukićević, Rastko D.",
year = "2011",
abstract = "X-Ray analyses of 4-(naphthalen-1-ylamino)-3-nitro-chromen-2-one and 3-nitro-4-phenylamino-chromen-2-one showed that the mentioned compounds crystallize in the space groups P1- (triclinic crystal system; unit cell parameters: a = 8.087(2) , b = 9.241(3) , c = 10.911(3) , alpha = 93.77(3)A degrees, beta = 102.51(3)A degrees, gamma = 106.44(2)A degrees, V = 756.4(4) (3) and Z = 2) and P2(1)2(1)2(1) (orthorhombic crystal system; unit cell parameters: a = 4.9274(9) , b = 14.725(3) , c = 17.866(4) , alpha = beta = gamma = 90A degrees, V = 1296.3(5) (3) and Z = 4), respectively. The analyses of crystal structures and gas phase conformations, inferred from single X-ray crystallographic and molecular modeling experiments, respectively, showed that the changes in pi delocalization of the farmacoactive formal 3-amino-2-nitro-acrylic acid derivatives might explain the observed significant difference of the antimicrobial and antioxidant activities and spectral properties of two 4-arylamino-3-nitro-coumarin derivatives.",
journal = "Journal of Chemical Crystallography",
title = "Could X-Ray Analysis Explain for the Differing Antimicrobial and Antioxidant Activity of Two 2-Arylamino-3-Nitro-Coumarins?",
volume = "41",
number = "4",
pages = "545-551",
doi = "10.1007/s10870-010-9918-0"
}
Radulović, N. S., Bogdanović, G. A., Blagojevic, P. D., Dekic, V. S.,& Vukićević, R. D.. (2011). Could X-Ray Analysis Explain for the Differing Antimicrobial and Antioxidant Activity of Two 2-Arylamino-3-Nitro-Coumarins?. in Journal of Chemical Crystallography, 41(4), 545-551.
https://doi.org/10.1007/s10870-010-9918-0
Radulović NS, Bogdanović GA, Blagojevic PD, Dekic VS, Vukićević RD. Could X-Ray Analysis Explain for the Differing Antimicrobial and Antioxidant Activity of Two 2-Arylamino-3-Nitro-Coumarins?. in Journal of Chemical Crystallography. 2011;41(4):545-551.
doi:10.1007/s10870-010-9918-0 .
Radulović, Niko S., Bogdanović, Goran A., Blagojevic, Polina D., Dekic, Vidosav S., Vukićević, Rastko D., "Could X-Ray Analysis Explain for the Differing Antimicrobial and Antioxidant Activity of Two 2-Arylamino-3-Nitro-Coumarins?" in Journal of Chemical Crystallography, 41, no. 4 (2011):545-551,
https://doi.org/10.1007/s10870-010-9918-0 . .
5
11
12

Synthesis, spectral characterization and electrochemical properties of (2-alkylthiobenzoyl)ferrocenes. Crystal structures of 2-methylthio, 2-ethylthio and 2-isopropylthio derivatives

Ratković, Zoran R.; Novaković, Slađana B.; Bogdanović, Goran A.; Segan, Dejan; Vukićević, Rastko D.

(2010)

TY  - JOUR
AU  - Ratković, Zoran R.
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Segan, Dejan
AU  - Vukićević, Rastko D.
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3957
AB  - The one-pot synthesis of seven new (2-alkylthiobenzoyl)ferrocenes has been achieved by Friedel-Crafts acylation of ferrocene with acid chlorides generated in situ from the corresponding carboxylic acids and phosphorous trichloride. The obtained compounds were characterized by spectroscopic data (UV, IR, (1)H and (13)C NMR), whereas their electrochemical properties have been investigated by cyclic voltammetry. The single-crystal X-ray structure determinations for three of them are also reported. Each of the three derivatives exhibits the intramolecular C-H center dot center dot center dot O interaction which involves the donor from the cyclopentadienyl (Cp) ring and the carbonyl oxygen as acceptor. This interaction favors the coplanar arrangement of the two moieties. The angles between the vectors coinciding the C-O bonds and the corresponding Cp planes are all below 6.4 degrees. Conventional hydrogen bonds do not exist in any of the three crystal structures but some weak intermolecular interactions of the C-H center dot center dot center dot, C-H center dot center dot center dot S and C-H center dot center dot center dot pi types have been found and analyzed in detail. Different geometrical parameters for these crystal structures as well as for 22 similar ones extracted from Cambridge Structural Database (CSD) have been compared and analyzed. (C) 2010 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - Synthesis, spectral characterization and electrochemical properties of (2-alkylthiobenzoyl)ferrocenes. Crystal structures of 2-methylthio, 2-ethylthio and 2-isopropylthio derivatives
VL  - 29
IS  - 11
SP  - 2311
EP  - 2317
DO  - 10.1016/j.poly.2010.04.034
ER  - 
@article{
author = "Ratković, Zoran R. and Novaković, Slađana B. and Bogdanović, Goran A. and Segan, Dejan and Vukićević, Rastko D.",
year = "2010",
abstract = "The one-pot synthesis of seven new (2-alkylthiobenzoyl)ferrocenes has been achieved by Friedel-Crafts acylation of ferrocene with acid chlorides generated in situ from the corresponding carboxylic acids and phosphorous trichloride. The obtained compounds were characterized by spectroscopic data (UV, IR, (1)H and (13)C NMR), whereas their electrochemical properties have been investigated by cyclic voltammetry. The single-crystal X-ray structure determinations for three of them are also reported. Each of the three derivatives exhibits the intramolecular C-H center dot center dot center dot O interaction which involves the donor from the cyclopentadienyl (Cp) ring and the carbonyl oxygen as acceptor. This interaction favors the coplanar arrangement of the two moieties. The angles between the vectors coinciding the C-O bonds and the corresponding Cp planes are all below 6.4 degrees. Conventional hydrogen bonds do not exist in any of the three crystal structures but some weak intermolecular interactions of the C-H center dot center dot center dot, C-H center dot center dot center dot S and C-H center dot center dot center dot pi types have been found and analyzed in detail. Different geometrical parameters for these crystal structures as well as for 22 similar ones extracted from Cambridge Structural Database (CSD) have been compared and analyzed. (C) 2010 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Synthesis, spectral characterization and electrochemical properties of (2-alkylthiobenzoyl)ferrocenes. Crystal structures of 2-methylthio, 2-ethylthio and 2-isopropylthio derivatives",
volume = "29",
number = "11",
pages = "2311-2317",
doi = "10.1016/j.poly.2010.04.034"
}
Ratković, Z. R., Novaković, S. B., Bogdanović, G. A., Segan, D.,& Vukićević, R. D.. (2010). Synthesis, spectral characterization and electrochemical properties of (2-alkylthiobenzoyl)ferrocenes. Crystal structures of 2-methylthio, 2-ethylthio and 2-isopropylthio derivatives. in Polyhedron, 29(11), 2311-2317.
https://doi.org/10.1016/j.poly.2010.04.034
Ratković ZR, Novaković SB, Bogdanović GA, Segan D, Vukićević RD. Synthesis, spectral characterization and electrochemical properties of (2-alkylthiobenzoyl)ferrocenes. Crystal structures of 2-methylthio, 2-ethylthio and 2-isopropylthio derivatives. in Polyhedron. 2010;29(11):2311-2317.
doi:10.1016/j.poly.2010.04.034 .
Ratković, Zoran R., Novaković, Slađana B., Bogdanović, Goran A., Segan, Dejan, Vukićević, Rastko D., "Synthesis, spectral characterization and electrochemical properties of (2-alkylthiobenzoyl)ferrocenes. Crystal structures of 2-methylthio, 2-ethylthio and 2-isopropylthio derivatives" in Polyhedron, 29, no. 11 (2010):2311-2317,
https://doi.org/10.1016/j.poly.2010.04.034 . .
10
10
10