TY  - JOUR
AU  - Marciniak, Lukasz
AU  - Kniec, Karolina
AU  - Elżbieciak-Piecka, Karolina
AU  - Trejgis, Karolina
AU  - Stefanska, Joanna Z.
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10358
AB  - Transition metal (TM) ion activated phosphors are increasingly being used as probes for luminescence thermometry. Their luminescence is characterized by strong absorption and emission bands that span the visible and near-infrared spectral ranges and are highly susceptible to temperature variations. Due to the latter characteristic, sensitive and reliable remote temperature measurements can be performed by observing temperature-induced changes in TM ion emission intensities, emission bandwidths and bandshifts, and excited state lifetimes, as well as the temperature dependences of the intensity ratios between various emission bands in single or double activated phosphors. This review provides a systematic analysis of the performances of luminescent thermometers based on different TM ions and discusses the relations among the TM spectroscopic properties, characteristics of the host material structure, and thermometric performance. Particular attention is given to the engineering of energy transfer between TM and other dopant ions to obtain highly sensitive thermometers. Finally, several typical application examples from recent literature are highlighted. © 2022 The Author(s)
T2  - Coordination Chemistry Reviews
T2  - Coordination Chemistry Reviews
T1  - Luminescence thermometry with transition metal ions. A review
VL  - 469
DO  - 10.1016/j.ccr.2022.214671
ER  - 

@article{
author = "Marciniak, Lukasz and Kniec, Karolina and Elżbieciak-Piecka, Karolina and Trejgis, Karolina and Stefanska, Joanna Z. and Dramićanin, Miroslav",
year = "2022",
abstract = "Transition metal (TM) ion activated phosphors are increasingly being used as probes for luminescence thermometry. Their luminescence is characterized by strong absorption and emission bands that span the visible and near-infrared spectral ranges and are highly susceptible to temperature variations. Due to the latter characteristic, sensitive and reliable remote temperature measurements can be performed by observing temperature-induced changes in TM ion emission intensities, emission bandwidths and bandshifts, and excited state lifetimes, as well as the temperature dependences of the intensity ratios between various emission bands in single or double activated phosphors. This review provides a systematic analysis of the performances of luminescent thermometers based on different TM ions and discusses the relations among the TM spectroscopic properties, characteristics of the host material structure, and thermometric performance. Particular attention is given to the engineering of energy transfer between TM and other dopant ions to obtain highly sensitive thermometers. Finally, several typical application examples from recent literature are highlighted. © 2022 The Author(s)",
journal = "Coordination Chemistry Reviews, Coordination Chemistry Reviews",
title = "Luminescence thermometry with transition metal ions. A review",
volume = "469",
doi = "10.1016/j.ccr.2022.214671"
}

Marciniak, L., Kniec, K., Elżbieciak-Piecka, K., Trejgis, K., Stefanska, J. Z.,& Dramićanin, M.. (2022). Luminescence thermometry with transition metal ions. A review. in Coordination Chemistry Reviews, 469.
https://doi.org/10.1016/j.ccr.2022.214671

Marciniak L, Kniec K, Elżbieciak-Piecka K, Trejgis K, Stefanska JZ, Dramićanin M. Luminescence thermometry with transition metal ions. A review. in Coordination Chemistry Reviews. 2022;469.
doi:10.1016/j.ccr.2022.214671 .

Marciniak, Lukasz, Kniec, Karolina, Elżbieciak-Piecka, Karolina, Trejgis, Karolina, Stefanska, Joanna Z., Dramićanin, Miroslav, "Luminescence thermometry with transition metal ions. A review" in Coordination Chemistry Reviews, 469 (2022),
https://doi.org/10.1016/j.ccr.2022.214671 . .

TY  - JOUR
AU  - Trejgis, Karolina
AU  - Dramićanin, Miroslav
AU  - Marciniak, Lukasz
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9796
AB  - The constant striving to improve the quality of thermal imaging with the use of luminescent thermometers imposes the search for new materials with better and better thermometric properties. The facility in the modulation of the spectroscopic properties of transition metal doped materials makes them particularly attractive for this type of application. Therefore, in response to this expectation, in this manuscript we report the novel SrTiO3:Mn4+ nanocrystals as a thermographic phosphor of extraordinary thermometric properties in the biologically relevant temperatures. The high relative sensitivity of the SrTiO3:Mn4+ nanocrystals to temperature changes in each of the three temperature readout modes presented in this manuscript, namely 8.67%/K at 313 K in the intensity mode, 3.5%/K at 348 K in the lifetime mode and 5.64%/K at 303 K in the ratiometric mode, make this material one of the most promising candidates for highly sensitive temperature imaging. © 2021 Elsevier B.V.
T2  - Journal of Alloys and Compounds
T1  - Highly sensitive multiparametric luminescent thermometer for biologically-relevant temperatures based on Mn4+, Ln3+ co-doped SrTiO3 nanocrystals
VL  - 875
DO  - 10.1016/j.jallcom.2021.159973
ER  - 

@article{
author = "Trejgis, Karolina and Dramićanin, Miroslav and Marciniak, Lukasz",
year = "2021",
abstract = "The constant striving to improve the quality of thermal imaging with the use of luminescent thermometers imposes the search for new materials with better and better thermometric properties. The facility in the modulation of the spectroscopic properties of transition metal doped materials makes them particularly attractive for this type of application. Therefore, in response to this expectation, in this manuscript we report the novel SrTiO3:Mn4+ nanocrystals as a thermographic phosphor of extraordinary thermometric properties in the biologically relevant temperatures. The high relative sensitivity of the SrTiO3:Mn4+ nanocrystals to temperature changes in each of the three temperature readout modes presented in this manuscript, namely 8.67%/K at 313 K in the intensity mode, 3.5%/K at 348 K in the lifetime mode and 5.64%/K at 303 K in the ratiometric mode, make this material one of the most promising candidates for highly sensitive temperature imaging. © 2021 Elsevier B.V.",
journal = "Journal of Alloys and Compounds",
title = "Highly sensitive multiparametric luminescent thermometer for biologically-relevant temperatures based on Mn4+, Ln3+ co-doped SrTiO3 nanocrystals",
volume = "875",
doi = "10.1016/j.jallcom.2021.159973"
}

Trejgis, K., Dramićanin, M.,& Marciniak, L.. (2021). Highly sensitive multiparametric luminescent thermometer for biologically-relevant temperatures based on Mn4+, Ln3+ co-doped SrTiO3 nanocrystals. in Journal of Alloys and Compounds, 875.
https://doi.org/10.1016/j.jallcom.2021.159973

Trejgis K, Dramićanin M, Marciniak L. Highly sensitive multiparametric luminescent thermometer for biologically-relevant temperatures based on Mn4+, Ln3+ co-doped SrTiO3 nanocrystals. in Journal of Alloys and Compounds. 2021;875.
doi:10.1016/j.jallcom.2021.159973 .

Trejgis, Karolina, Dramićanin, Miroslav, Marciniak, Lukasz, "Highly sensitive multiparametric luminescent thermometer for biologically-relevant temperatures based on Mn4+, Ln3+ co-doped SrTiO3 nanocrystals" in Journal of Alloys and Compounds, 875 (2021),
https://doi.org/10.1016/j.jallcom.2021.159973 . .

TY  - JOUR
AU  - Piotrowski, Wojciech M.
AU  - Trejgis, Karolina
AU  - Dramićanin, Miroslav
AU  - Marciniak, Lukasz
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9917
AB  - The co-doping of SrTiO3:Mn4+ luminescent nanocrystals with trivalent lanthanide ions (Ln3+ = Lu3+, Tm3+, Er3+, Ho3+, Dy3+, Eu3+, and La3+) is demonstrated as a new strategy for significant sensitivity improvement of lifetime-based luminescent thermometers. SrTiO3:Mn4+:Ln3+ nanocrystals of about 25 nm diameter were prepared by the modified Pechini method and characterized using X-ray powder diffraction and electron microscopy techniques. The temperature dependence of Mn4+ emission in SrTiO3 was considerably altered by the co-doping of Ln3+ due to the cooperating effects of Mn4+ → Ti3+ and Mn4+ → Ln3+ energy transfers. A substantial enhancement of the relative sensitivity of lifetime-based thermometry as high as 145% with respect to the unco-doped nanocrystals reveals the success of the approach. The obtained values of maximal relative sensitivity for different Ln3+ co-dopants are 5.10% K−1 at 290 K for Er3+, 5.00% K−1 at 301 K for Eu3+, 4.84% K−1 at 303 K for Dy3+, 4.71% K−1 at 289 K for Ho3+, and 3.87% K−1 at 290.7 K for Lu3+.
T2  - Journal of Materials Chemistry C
T1  - Strong sensitivity enhancement in lifetime-based luminescence thermometry by co-doping of SrTiO3:Mn4+ nanocrystals with trivalent lanthanide ions
VL  - 9
IS  - 32
SP  - 10309
EP  - 10316
DO  - 10.1039/D1TC02814F
ER  - 

@article{
author = "Piotrowski, Wojciech M. and Trejgis, Karolina and Dramićanin, Miroslav and Marciniak, Lukasz",
year = "2021",
abstract = "The co-doping of SrTiO3:Mn4+ luminescent nanocrystals with trivalent lanthanide ions (Ln3+ = Lu3+, Tm3+, Er3+, Ho3+, Dy3+, Eu3+, and La3+) is demonstrated as a new strategy for significant sensitivity improvement of lifetime-based luminescent thermometers. SrTiO3:Mn4+:Ln3+ nanocrystals of about 25 nm diameter were prepared by the modified Pechini method and characterized using X-ray powder diffraction and electron microscopy techniques. The temperature dependence of Mn4+ emission in SrTiO3 was considerably altered by the co-doping of Ln3+ due to the cooperating effects of Mn4+ → Ti3+ and Mn4+ → Ln3+ energy transfers. A substantial enhancement of the relative sensitivity of lifetime-based thermometry as high as 145% with respect to the unco-doped nanocrystals reveals the success of the approach. The obtained values of maximal relative sensitivity for different Ln3+ co-dopants are 5.10% K−1 at 290 K for Er3+, 5.00% K−1 at 301 K for Eu3+, 4.84% K−1 at 303 K for Dy3+, 4.71% K−1 at 289 K for Ho3+, and 3.87% K−1 at 290.7 K for Lu3+.",
journal = "Journal of Materials Chemistry C",
title = "Strong sensitivity enhancement in lifetime-based luminescence thermometry by co-doping of SrTiO3:Mn4+ nanocrystals with trivalent lanthanide ions",
volume = "9",
number = "32",
pages = "10309-10316",
doi = "10.1039/D1TC02814F"
}

Piotrowski, W. M., Trejgis, K., Dramićanin, M.,& Marciniak, L.. (2021). Strong sensitivity enhancement in lifetime-based luminescence thermometry by co-doping of SrTiO3:Mn4+ nanocrystals with trivalent lanthanide ions. in Journal of Materials Chemistry C, 9(32), 10309-10316.
https://doi.org/10.1039/D1TC02814F

Piotrowski WM, Trejgis K, Dramićanin M, Marciniak L. Strong sensitivity enhancement in lifetime-based luminescence thermometry by co-doping of SrTiO3:Mn4+ nanocrystals with trivalent lanthanide ions. in Journal of Materials Chemistry C. 2021;9(32):10309-10316.
doi:10.1039/D1TC02814F .

Piotrowski, Wojciech M., Trejgis, Karolina, Dramićanin, Miroslav, Marciniak, Lukasz, "Strong sensitivity enhancement in lifetime-based luminescence thermometry by co-doping of SrTiO3:Mn4+ nanocrystals with trivalent lanthanide ions" in Journal of Materials Chemistry C, 9, no. 32 (2021):10309-10316,
https://doi.org/10.1039/D1TC02814F . .