Kijevčanin, Mirjana Lj.

Link to this page

Authority KeyName Variants
orcid::0000-0001-7126-3965
  • Kijevčanin, Mirjana Lj. (19)
  • Kijevčanin, Mirjana (5)
Projects

Author's Bibliography

Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems

Maslovara, Slađana; Vasić Anićijević, Dragana; Nikolić, Vladimir; Kijevčanin, Mirjana; Marčeta, Milica

(Belgrade : Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Maslovara, Slađana
AU  - Vasić Anićijević, Dragana
AU  - Nikolić, Vladimir
AU  - Kijevčanin, Mirjana
AU  - Marčeta, Milica
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11635
AB  - The utilization of renewable energy sources such as wind and solar increases the available options for a decentralized electricity grid. Water electrolysis is among the most perspective methods of technical development. Cost reduction in electrolyzers is possible only through the development of electrocatalysts and cathode materials. The primary outcomes of the research were the characterization and testing of ionic activators added in a standard solution of 6M KOH in alkaline electrolyzers and integrated into combined heat and power systems. We found that ionic activators based on d-metals such as Ni, Cu, Co or Cr and Mo salt in a standard solution of 6M KOH improve the reduction in energy consumption by about 18%, compared to a non-activated system. The energy efficiencies of the electrolyzer with an activated system were about 70% on the different applied current densities. Increasing the energy efficiency of the electrolytic process is achieved by thermal integration, that is, by connecting the heat exchanger with the electrolyzer and the fuel cell. By establishing the connection of the heat exchanger with the alkaline electrolyzer with ionic activators and the fuel cell, it is possible to increase energy efficiency by thermal integration of the electrolytic process.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade
T1  - Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems
SP  - 47
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11635
ER  - 
@conference{
author = "Maslovara, Slađana and Vasić Anićijević, Dragana and Nikolić, Vladimir and Kijevčanin, Mirjana and Marčeta, Milica",
year = "2023",
abstract = "The utilization of renewable energy sources such as wind and solar increases the available options for a decentralized electricity grid. Water electrolysis is among the most perspective methods of technical development. Cost reduction in electrolyzers is possible only through the development of electrocatalysts and cathode materials. The primary outcomes of the research were the characterization and testing of ionic activators added in a standard solution of 6M KOH in alkaline electrolyzers and integrated into combined heat and power systems. We found that ionic activators based on d-metals such as Ni, Cu, Co or Cr and Mo salt in a standard solution of 6M KOH improve the reduction in energy consumption by about 18%, compared to a non-activated system. The energy efficiencies of the electrolyzer with an activated system were about 70% on the different applied current densities. Increasing the energy efficiency of the electrolytic process is achieved by thermal integration, that is, by connecting the heat exchanger with the electrolyzer and the fuel cell. By establishing the connection of the heat exchanger with the alkaline electrolyzer with ionic activators and the fuel cell, it is possible to increase energy efficiency by thermal integration of the electrolytic process.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade",
title = "Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems",
pages = "47",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11635"
}
Maslovara, S., Vasić Anićijević, D., Nikolić, V., Kijevčanin, M.,& Marčeta, M.. (2023). Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems. in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade
Belgrade : Serbian Ceramic Society., 47.
https://hdl.handle.net/21.15107/rcub_vinar_11635
Maslovara S, Vasić Anićijević D, Nikolić V, Kijevčanin M, Marčeta M. Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems. in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade. 2023;:47.
https://hdl.handle.net/21.15107/rcub_vinar_11635 .
Maslovara, Slađana, Vasić Anićijević, Dragana, Nikolić, Vladimir, Kijevčanin, Mirjana, Marčeta, Milica, "Possibilities of integrating alkaline electrolyzer with ionic activators in micro combined heat and power systems" in Advanced Ceramics and Application :11th Serbian Ceramic Society Conference : program and the book of abstracts; September 18-20, 2023; Belgrade (2023):47,
https://hdl.handle.net/21.15107/rcub_vinar_11635 .

A Life Cycle Energy Assessment for Biogas as Energy Carrier

Cvetković, Slobodan M.; Popović, Mina; Grbović-Novaković, Jasmina; Kijevčanin, Mirjana Lj.; Oncel, Suphi S.

(Springer International Publishing, 2023)

TY  - CHAP
AU  - Cvetković, Slobodan M.
AU  - Popović, Mina
AU  - Grbović-Novaković, Jasmina
AU  - Kijevčanin, Mirjana Lj.
AU  - Oncel, Suphi S.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11729
AB  - This chapter aims to evaluate energy flows in the life cycle of biogas utilization (i.e., production of thermal energy, cogeneration, traffic, and production of hydrogen), starting from feedstock and anaerobic digestion, up to the digestate as fertilizer for agricultural production. The analysis is based on the out-turn of a biogas plant on the dairy farm Mirotin Vrbas, Republic of Serbia. Life Cycle Energy Assessment (LCEA), presented in this chapter, has demonstrated that three scenarios – biogas for heat production, biogas in cogeneration, and biomethane in transportation have positive energy balances, which indicate that in terms of replacement of fossil fuel consumption, these energy systems are promising alternatives. In the fourth scenario, where biogas is used for hydrogen production, the energy balance is negative, therefore socio-economical factors should be considered for overall consideration to ensure sustainability.
PB  - Springer International Publishing
T2  - A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment
T2  - A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment
T1  - A Life Cycle Energy Assessment for Biogas as Energy Carrier
SP  - 595
EP  - 612
DO  - 10.1007/978-3-031-24942-6_28
ER  - 
@inbook{
author = "Cvetković, Slobodan M. and Popović, Mina and Grbović-Novaković, Jasmina and Kijevčanin, Mirjana Lj. and Oncel, Suphi S.",
year = "2023",
abstract = "This chapter aims to evaluate energy flows in the life cycle of biogas utilization (i.e., production of thermal energy, cogeneration, traffic, and production of hydrogen), starting from feedstock and anaerobic digestion, up to the digestate as fertilizer for agricultural production. The analysis is based on the out-turn of a biogas plant on the dairy farm Mirotin Vrbas, Republic of Serbia. Life Cycle Energy Assessment (LCEA), presented in this chapter, has demonstrated that three scenarios – biogas for heat production, biogas in cogeneration, and biomethane in transportation have positive energy balances, which indicate that in terms of replacement of fossil fuel consumption, these energy systems are promising alternatives. In the fourth scenario, where biogas is used for hydrogen production, the energy balance is negative, therefore socio-economical factors should be considered for overall consideration to ensure sustainability.",
publisher = "Springer International Publishing",
journal = "A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment, A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment",
booktitle = "A Life Cycle Energy Assessment for Biogas as Energy Carrier",
pages = "595-612",
doi = "10.1007/978-3-031-24942-6_28"
}
Cvetković, S. M., Popović, M., Grbović-Novaković, J., Kijevčanin, M. Lj.,& Oncel, S. S.. (2023). A Life Cycle Energy Assessment for Biogas as Energy Carrier. in A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment
Springer International Publishing., 595-612.
https://doi.org/10.1007/978-3-031-24942-6_28
Cvetković SM, Popović M, Grbović-Novaković J, Kijevčanin ML, Oncel SS. A Life Cycle Energy Assessment for Biogas as Energy Carrier. in A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment. 2023;:595-612.
doi:10.1007/978-3-031-24942-6_28 .
Cvetković, Slobodan M., Popović, Mina, Grbović-Novaković, Jasmina, Kijevčanin, Mirjana Lj., Oncel, Suphi S., "A Life Cycle Energy Assessment for Biogas as Energy Carrier" in A Sustainable Green Future: Perspectives on Energy, Economy, Industry, Cities and Environment (2023):595-612,
https://doi.org/10.1007/978-3-031-24942-6_28 . .
1
1

Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator

Mohammad, Ahmad Hakky; Radović, Ivona; Ivanović, Marija M.; Kijevčanin, Mirjana

(2022)

TY  - JOUR
AU  - Mohammad, Ahmad Hakky
AU  - Radović, Ivona
AU  - Ivanović, Marija M.
AU  - Kijevčanin, Mirjana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10444
AB  - Water hyacinth biomass was used for the synthesis of activated carbons in the process of chemical activation with H3PO4, followed by controlled carbonization. The study investigates the effect of various impregnation weight ratios of H3PO4 and dry hyacinth (0.5–3.0), as well as different carbonization temperatures (T = 400–800 °C), on the surface characteristics of the produced activated carbons (AC). The activated carbon obtained with an impregnation ratio of 1.5 and a carbonization temperature of 600 °C (1.5 AC/600) showed the highest values of specific surface area of 1421 m2 g−1, representing a selected adsorbent for metformin removal. The chosen sample was characterized by elemental analysis, adsorption–desorption isotherms of nitrogen at −196 °C, via FTIR spectroscopy and the SEM method. The modeling of the experimental adsorption data showed that metformin adsorption: (i) can be best described by the Langmuir isotherm model, with the value of qmax = 122.47 mg g−1; (ii) led the pseudo-second order kinetic model; and (iii) is a spontaneous (ΔG° = −3.44 kJ mol−1) and endothermic (ΔH° = 8.77 kJ mol−1) process. A desorption study has shown that 92% of metformin was successfully desorbed in the presence of a 0.1 MHCl/ethanol mixture (volume ratio 2:1). The recovery of the adsorbent of 84%, after five successive cycles, indicated that the 1.5 AC/600 has potential to be applied in the real systems for water treatment.
T2  - Sustainability
T1  - Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator
VL  - 14
IS  - 18
SP  - 11144
DO  - 10.3390/su141811144
ER  - 
@article{
author = "Mohammad, Ahmad Hakky and Radović, Ivona and Ivanović, Marija M. and Kijevčanin, Mirjana",
year = "2022",
abstract = "Water hyacinth biomass was used for the synthesis of activated carbons in the process of chemical activation with H3PO4, followed by controlled carbonization. The study investigates the effect of various impregnation weight ratios of H3PO4 and dry hyacinth (0.5–3.0), as well as different carbonization temperatures (T = 400–800 °C), on the surface characteristics of the produced activated carbons (AC). The activated carbon obtained with an impregnation ratio of 1.5 and a carbonization temperature of 600 °C (1.5 AC/600) showed the highest values of specific surface area of 1421 m2 g−1, representing a selected adsorbent for metformin removal. The chosen sample was characterized by elemental analysis, adsorption–desorption isotherms of nitrogen at −196 °C, via FTIR spectroscopy and the SEM method. The modeling of the experimental adsorption data showed that metformin adsorption: (i) can be best described by the Langmuir isotherm model, with the value of qmax = 122.47 mg g−1; (ii) led the pseudo-second order kinetic model; and (iii) is a spontaneous (ΔG° = −3.44 kJ mol−1) and endothermic (ΔH° = 8.77 kJ mol−1) process. A desorption study has shown that 92% of metformin was successfully desorbed in the presence of a 0.1 MHCl/ethanol mixture (volume ratio 2:1). The recovery of the adsorbent of 84%, after five successive cycles, indicated that the 1.5 AC/600 has potential to be applied in the real systems for water treatment.",
journal = "Sustainability",
title = "Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator",
volume = "14",
number = "18",
pages = "11144",
doi = "10.3390/su141811144"
}
Mohammad, A. H., Radović, I., Ivanović, M. M.,& Kijevčanin, M.. (2022). Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator. in Sustainability, 14(18), 11144.
https://doi.org/10.3390/su141811144
Mohammad AH, Radović I, Ivanović MM, Kijevčanin M. Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator. in Sustainability. 2022;14(18):11144.
doi:10.3390/su141811144 .
Mohammad, Ahmad Hakky, Radović, Ivona, Ivanović, Marija M., Kijevčanin, Mirjana, "Adsorption of Metformin on Activated Carbon Produced from the Water Hyacinth Biowaste Using H3PO4 as a Chemical Activator" in Sustainability, 14, no. 18 (2022):11144,
https://doi.org/10.3390/su141811144 . .
11
10

Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters

Cvetković, Slobodan M.; Kaluđerović-Radoičić, Tatjana; Grbović-Novaković, Jasmina; Kovačević, Vlado; Lopičić, Zorica; Adamović, Vladimir; Kijevčanin, Mirjana Lj.

(2022)

TY  - JOUR
AU  - Cvetković, Slobodan M.
AU  - Kaluđerović-Radoičić, Tatjana
AU  - Grbović-Novaković, Jasmina
AU  - Kovačević, Vlado
AU  - Lopičić, Zorica
AU  - Adamović, Vladimir
AU  - Kijevčanin, Mirjana Lj.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10300
AB  - Renewable hydrogen produced from the waste streams can be a good option for clean energy production and reduction of greenhouse gases emissions into the environment. In this study, the potential for hydrogen production from the food industry wastewaters in Serbia and the further use of the calculated potentials were investigated. This was performed through two technological routes including the biogas steam reforming process and the electrolysis after biogas cogeneration process. Furthermore, the environmental impacts of these processes were considered. The total hydrogen potential via the biogas steam reforming process was 4094.70 tons, while the total hydrogen potential via the electrolysis after biogas cogeneration process was 1751.08 tons. These potentials can be used for direct energy production in the food industry, electricity production for the national electric grid, transport, injection in the natural gas grid and/or as a resource in the chemical industry. Regarding the Greenhouse Gas emissions reduction, hydrogen production by both routes represents a promising pathway. The results of this work can serve the decision makers to plan hydrogen application in the energy sector of the Republic of Serbia defining supporting measures for its application. Also, the presented analysis is enforceable in the Western Balkan countries for the application of hydrogen as an energy source in their systems for energy production, transport and economy.
T2  - Journal of Cleaner Production
T1  - Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters
VL  - 363
SP  - 132142
DO  - 10.1016/j.jclepro.2022.132142
ER  - 
@article{
author = "Cvetković, Slobodan M. and Kaluđerović-Radoičić, Tatjana and Grbović-Novaković, Jasmina and Kovačević, Vlado and Lopičić, Zorica and Adamović, Vladimir and Kijevčanin, Mirjana Lj.",
year = "2022",
abstract = "Renewable hydrogen produced from the waste streams can be a good option for clean energy production and reduction of greenhouse gases emissions into the environment. In this study, the potential for hydrogen production from the food industry wastewaters in Serbia and the further use of the calculated potentials were investigated. This was performed through two technological routes including the biogas steam reforming process and the electrolysis after biogas cogeneration process. Furthermore, the environmental impacts of these processes were considered. The total hydrogen potential via the biogas steam reforming process was 4094.70 tons, while the total hydrogen potential via the electrolysis after biogas cogeneration process was 1751.08 tons. These potentials can be used for direct energy production in the food industry, electricity production for the national electric grid, transport, injection in the natural gas grid and/or as a resource in the chemical industry. Regarding the Greenhouse Gas emissions reduction, hydrogen production by both routes represents a promising pathway. The results of this work can serve the decision makers to plan hydrogen application in the energy sector of the Republic of Serbia defining supporting measures for its application. Also, the presented analysis is enforceable in the Western Balkan countries for the application of hydrogen as an energy source in their systems for energy production, transport and economy.",
journal = "Journal of Cleaner Production",
title = "Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters",
volume = "363",
pages = "132142",
doi = "10.1016/j.jclepro.2022.132142"
}
Cvetković, S. M., Kaluđerović-Radoičić, T., Grbović-Novaković, J., Kovačević, V., Lopičić, Z., Adamović, V.,& Kijevčanin, M. Lj.. (2022). Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters. in Journal of Cleaner Production, 363, 132142.
https://doi.org/10.1016/j.jclepro.2022.132142
Cvetković SM, Kaluđerović-Radoičić T, Grbović-Novaković J, Kovačević V, Lopičić Z, Adamović V, Kijevčanin ML. Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters. in Journal of Cleaner Production. 2022;363:132142.
doi:10.1016/j.jclepro.2022.132142 .
Cvetković, Slobodan M., Kaluđerović-Radoičić, Tatjana, Grbović-Novaković, Jasmina, Kovačević, Vlado, Lopičić, Zorica, Adamović, Vladimir, Kijevčanin, Mirjana Lj., "Renewable hydrogen production perspective in Serbia via biogas generated from food processing wastewaters" in Journal of Cleaner Production, 363 (2022):132142,
https://doi.org/10.1016/j.jclepro.2022.132142 . .
6
6

The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers

Ivanović, Marija M.; Nenadović, Snežana S.; Pavlović, Vera P.; Radović, Ivona R.; Kijevčanin, Mirjana Lj.; Pavlović, Vladimir B.; Kljajević, Ljiljana M.

(2021)

TY  - JOUR
AU  - Ivanović, Marija M.
AU  - Nenadović, Snežana S.
AU  - Pavlović, Vera P.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
AU  - Pavlović, Vladimir B.
AU  - Kljajević, Ljiljana M.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9866
AB  - Thermodynamic parameters (densities, viscosities, speed of sound, and refractive index) of four series of alkaline activators were determined over the temperature range from 15 to 60 °C for the process of geopolymerization. Mixtures of Na2SiO3and NaOH of different molar concentrations (from 2M to 8M with step 2) were used as an alkaline activator. The sample with the highest NaOH concentrationalso shows the highest values of all thermodynamic parameters.Metakaolin, obtained by calcination of kaolin at 750 °C, was used as the starting material.The samples were characterized by X-ray diffraction (XRD),FTIR and Raman spectroscopy, Scanning Electron Microscopy (SEM), and Energy-Dispersive X-Ray (EDX) Spectroscopy. Results of FTIR analysis correlated with results of Raman Spectroscopy. Due to the polymerization process, the changes in the phonon spectrum were confirmed. The different concentra-tions of activators do not notably change the Si/Al ratio.
T2  - Macedonian Journal of Chemistry and Chemical Engineering
T1  - The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers
VL  - 40
IS  - 1
SP  - 99
DO  - 10.20450/mjcce.2021.2127
ER  - 
@article{
author = "Ivanović, Marija M. and Nenadović, Snežana S. and Pavlović, Vera P. and Radović, Ivona R. and Kijevčanin, Mirjana Lj. and Pavlović, Vladimir B. and Kljajević, Ljiljana M.",
year = "2021",
abstract = "Thermodynamic parameters (densities, viscosities, speed of sound, and refractive index) of four series of alkaline activators were determined over the temperature range from 15 to 60 °C for the process of geopolymerization. Mixtures of Na2SiO3and NaOH of different molar concentrations (from 2M to 8M with step 2) were used as an alkaline activator. The sample with the highest NaOH concentrationalso shows the highest values of all thermodynamic parameters.Metakaolin, obtained by calcination of kaolin at 750 °C, was used as the starting material.The samples were characterized by X-ray diffraction (XRD),FTIR and Raman spectroscopy, Scanning Electron Microscopy (SEM), and Energy-Dispersive X-Ray (EDX) Spectroscopy. Results of FTIR analysis correlated with results of Raman Spectroscopy. Due to the polymerization process, the changes in the phonon spectrum were confirmed. The different concentra-tions of activators do not notably change the Si/Al ratio.",
journal = "Macedonian Journal of Chemistry and Chemical Engineering",
title = "The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers",
volume = "40",
number = "1",
pages = "99",
doi = "10.20450/mjcce.2021.2127"
}
Ivanović, M. M., Nenadović, S. S., Pavlović, V. P., Radović, I. R., Kijevčanin, M. Lj., Pavlović, V. B.,& Kljajević, L. M.. (2021). The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers. in Macedonian Journal of Chemistry and Chemical Engineering, 40(1), 99.
https://doi.org/10.20450/mjcce.2021.2127
Ivanović MM, Nenadović SS, Pavlović VP, Radović IR, Kijevčanin ML, Pavlović VB, Kljajević LM. The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers. in Macedonian Journal of Chemistry and Chemical Engineering. 2021;40(1):99.
doi:10.20450/mjcce.2021.2127 .
Ivanović, Marija M., Nenadović, Snežana S., Pavlović, Vera P., Radović, Ivona R., Kijevčanin, Mirjana Lj., Pavlović, Vladimir B., Kljajević, Ljiljana M., "The influence of thermodynamic parameters on alkaline activator of geopolymers and structure of geopolymers" in Macedonian Journal of Chemistry and Chemical Engineering, 40, no. 1 (2021):99,
https://doi.org/10.20450/mjcce.2021.2127 . .
6
1
5

Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia

Cvetković, Slobodan M.; Kaluđerović-Radoičić, Tatjana; Kijevčanin, Mirjana Lj.; Grbović-Novaković, Jasmina

(2021)

TY  - JOUR
AU  - Cvetković, Slobodan M.
AU  - Kaluđerović-Radoičić, Tatjana
AU  - Kijevčanin, Mirjana Lj.
AU  - Grbović-Novaković, Jasmina
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9128
AB  - The aim of this paper is to demonstrate and to quantify energy flows in a life cycle of biogas to biohydrogen production, starting from feedstock materials via anaerobic digestion, biogas upgrading, biohydrogen production, to the end of biogas system (application of digestate as fertilizer in agriculture). The performance of the biogas plant of Mirotin dairy farm in Serbia has been assessed. According to Life Cycle Energy Assessment approach, results obtained in this study have shown that biohydrogen production via biogas steam reforming has negative energy balance (with −16,837 GJ). It has also been demonstrated that this process is energy unsustainable in an environmental context. In future analysis it would be necessary to consider the other aspects of sustainability, e.g. the economical and social factors in order to estimate the overall sustainability of the biogas utilization pathways, especially having in mind that the technology of converting biogas to hydrogen is still in the development phase. © 2021 Hydrogen Energy Publications LLC
T2  - International Journal of Hydrogen Energy
T1  - Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia
VL  - 46
IS  - 27
SP  - 14130
EP  - 14137
DO  - 10.1016/j.ijhydene.2021.01.181
ER  - 
@article{
author = "Cvetković, Slobodan M. and Kaluđerović-Radoičić, Tatjana and Kijevčanin, Mirjana Lj. and Grbović-Novaković, Jasmina",
year = "2021",
abstract = "The aim of this paper is to demonstrate and to quantify energy flows in a life cycle of biogas to biohydrogen production, starting from feedstock materials via anaerobic digestion, biogas upgrading, biohydrogen production, to the end of biogas system (application of digestate as fertilizer in agriculture). The performance of the biogas plant of Mirotin dairy farm in Serbia has been assessed. According to Life Cycle Energy Assessment approach, results obtained in this study have shown that biohydrogen production via biogas steam reforming has negative energy balance (with −16,837 GJ). It has also been demonstrated that this process is energy unsustainable in an environmental context. In future analysis it would be necessary to consider the other aspects of sustainability, e.g. the economical and social factors in order to estimate the overall sustainability of the biogas utilization pathways, especially having in mind that the technology of converting biogas to hydrogen is still in the development phase. © 2021 Hydrogen Energy Publications LLC",
journal = "International Journal of Hydrogen Energy",
title = "Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia",
volume = "46",
number = "27",
pages = "14130-14137",
doi = "10.1016/j.ijhydene.2021.01.181"
}
Cvetković, S. M., Kaluđerović-Radoičić, T., Kijevčanin, M. Lj.,& Grbović-Novaković, J.. (2021). Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia. in International Journal of Hydrogen Energy, 46(27), 14130-14137.
https://doi.org/10.1016/j.ijhydene.2021.01.181
Cvetković SM, Kaluđerović-Radoičić T, Kijevčanin ML, Grbović-Novaković J. Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia. in International Journal of Hydrogen Energy. 2021;46(27):14130-14137.
doi:10.1016/j.ijhydene.2021.01.181 .
Cvetković, Slobodan M., Kaluđerović-Radoičić, Tatjana, Kijevčanin, Mirjana Lj., Grbović-Novaković, Jasmina, "Life Cycle Energy Assessment of biohydrogen production via biogas steam reforming: Case study of biogas plant on a farm in Serbia" in International Journal of Hydrogen Energy, 46, no. 27 (2021):14130-14137,
https://doi.org/10.1016/j.ijhydene.2021.01.181 . .
14
2
14

Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling

Živković, Nikola V.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2020)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9032
AB  - Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.
T2  - Journal of Chemical & Engineering Data
T1  - Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling
VL  - 65
IS  - 6
SP  - 3044
EP  - 3062
DO  - 10.1021/acs.jced.0c00083
ER  - 
@article{
author = "Živković, Nikola V. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2020",
abstract = "Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.",
journal = "Journal of Chemical & Engineering Data",
title = "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling",
volume = "65",
number = "6",
pages = "3044-3062",
doi = "10.1021/acs.jced.0c00083"
}
Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M.. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical & Engineering Data, 65(6), 3044-3062.
https://doi.org/10.1021/acs.jced.0c00083
Živković NV, Majstorović DM, Kijevčanin ML, Živković EM. Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical & Engineering Data. 2020;65(6):3044-3062.
doi:10.1021/acs.jced.0c00083 .
Živković, Nikola V., Majstorović, Divna M., Kijevčanin, Mirjana Lj., Živković, Emila M., "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling" in Journal of Chemical & Engineering Data, 65, no. 6 (2020):3044-3062,
https://doi.org/10.1021/acs.jced.0c00083 . .
4
2
3

Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling

Živković, Nikola V.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2020)

TY  - DATA
AU  - Živković, Nikola V.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9037
AB  - Supporting Information for the article: Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. Journal of Chemical & Engineering Data, 65(6), 3044-3062. [https://doi.org/10.1021/acs.jced.0c00083]
T2  - Journal of Chemical & Engineering Data
T1  - Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling
VL  - 65
IS  - 6
SP  - 3044
EP  - 3062
DO  - 10.1021/acs.jced.0c00083
ER  - 
@misc{
author = "Živković, Nikola V. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2020",
abstract = "Supporting Information for the article: Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. Journal of Chemical & Engineering Data, 65(6), 3044-3062. [https://doi.org/10.1021/acs.jced.0c00083]",
journal = "Journal of Chemical & Engineering Data",
title = "Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling",
volume = "65",
number = "6",
pages = "3044-3062",
doi = "10.1021/acs.jced.0c00083"
}
Živković, N. V., Majstorović, D. M., Kijevčanin, M. Lj.,& Živković, E. M.. (2020). Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical & Engineering Data, 65(6), 3044-3062.
https://doi.org/10.1021/acs.jced.0c00083
Živković NV, Majstorović DM, Kijevčanin ML, Živković EM. Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical & Engineering Data. 2020;65(6):3044-3062.
doi:10.1021/acs.jced.0c00083 .
Živković, Nikola V., Majstorović, Divna M., Kijevčanin, Mirjana Lj., Živković, Emila M., "Supporting information: Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling" in Journal of Chemical & Engineering Data, 65, no. 6 (2020):3044-3062,
https://doi.org/10.1021/acs.jced.0c00083 . .
4
2
3

Instrument za određivanje toplotne provodljivosti tečnih fluida na atmosferskom pritisku

Stanimirović, Andrej; Živković, Emila; Majstorović, Divna; Kijevčanin, Mirjana; Živković, Nikola

(2019)


                                            

                                            
Stanimirović, A., Živković, E., Majstorović, D., Kijevčanin, M.,& Živković, N.. (2019). Instrument za određivanje toplotne provodljivosti tečnih fluida na atmosferskom pritisku. in Univerzitet u Beogradu : Tehnološko-metalurški fakultet : Katedra za hemijsko inženjerstvo.
https://hdl.handle.net/21.15107/rcub_vinar_12109
Stanimirović A, Živković E, Majstorović D, Kijevčanin M, Živković N. Instrument za određivanje toplotne provodljivosti tečnih fluida na atmosferskom pritisku. in Univerzitet u Beogradu : Tehnološko-metalurški fakultet : Katedra za hemijsko inženjerstvo. 2019;.
https://hdl.handle.net/21.15107/rcub_vinar_12109 .
Stanimirović, Andrej, Živković, Emila, Majstorović, Divna, Kijevčanin, Mirjana, Živković, Nikola, "Instrument za određivanje toplotne provodljivosti tečnih fluida na atmosferskom pritisku" in Univerzitet u Beogradu : Tehnološko-metalurški fakultet : Katedra za hemijsko inženjerstvo (2019),
https://hdl.handle.net/21.15107/rcub_vinar_12109 .

Viscosity of binary mixture DMA + 2-butanol with potential use as solvent for regenerative flue gas desulfurization processes

Majstorović, Divna; Živković, Nikola; Kijevčanin, Mirjana; Živković, Emila

(Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), 2019)

TY  - CONF
AU  - Majstorović, Divna
AU  - Živković, Nikola
AU  - Kijevčanin, Mirjana
AU  - Živković, Emila
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12116
AB  - Sulfur dioxide (SO2) is an environmental pollutant with multiple harmful effects on biological world. One of the main emission sources are industrial activities in thermal power plants, foundries and steel mills which involve combustion of fossil fuels containing sulfur, such as coal and oil. Initial step towards removal of SO2from flue gases was the so-called limestone process, a wet non-regenerative process that even today is the mostused flue gas desulfurization method. However, wet regenerative processes with gas absorption in liquid organic solvent and thermal regeneration recently have found practical application. Processes based on n,n-dimethylaniline (DMA) have alre-ady been patented and industrially applied. This solvent has high selectivity towards SO2in compa-rison  to  the  other  components  of  flue  gas  like  CO2,  and  excellent  binding  capability  by  the 214• 32ndINTERNATIONAL CONGRESS ON PROCESS INDUSTRYmechanisms of chemical absorption, but main disadvantage is its high toxicity. On the other hand, in more ambient friendly 2-butanol binding of sulfur-dioxide occurs by means of physical absorption. Investigations have shown that mixtures of physical and chemical solvents usually show better cha-racteristics regarding binding capacityand selectivity than traditionally used aqueous solutions of amines, due to the synergetic effect.One  of  the  most  important  thermophysical  properties  of  solvents,  necessary  for  process  and equipment  design  is  dynamic  viscosity.  In  this  investigation  viscosity  of  binary  mixture  DMA  +  2-butanol  is  experimentally  determined  in  temperature  and  concentration  range  and  correlated afterwards  using  different  literature  models.  These  correlations  present  useful  method  to  acquire reliable data necessary for fluid flow analysis and mass and heat transfer calculations, since experi-mental values for desired process conditions are often not available. In this study, two or three-pa-rameter  Eyring-UNIQUAC,  Eyring-NRTL  and  McAllister  models  were  used,  while  model  that  co-uples Eyring equation, Peng-Robinson equation of state and van der Waals mixing rule, was tested for simultaneous calculation of density and viscosity. The obtained results are presented and discu-ssed regarding potential application, limitations and complexity of used approach and models.
AB  - Sumpor dioksid (SO2) je zagađivač životne sredine sa višestrukim štetnim efektima na biološki svet. Jedan od glavnih izvora emisije su industrijske aktivnosti u termoelektranama, livnicama i železarama, koje uključuju sagorevanje fosilnih goriva koja sadrže sumpor, kao što su ugalj i nafta.   Početni korak u uklanjanju SO2 iz dimnih gasova bio je takozvani krečnjački postupak, mokri neregenerativni proces koji je i danas najčešće korišćen metod odsumporavanja dimnih gasova. Međutim, mokri regenerativni procesi sa apsorpcijom gasa u tečnom organskom rastvaraču i termalnom regeneracijom nedavno su našli praktičnu primenu. Procesi zasnovani na n,n-dimetilanilinu (DMA) su već patentirani i industrijski primenjeni. Ovaj rastvarač ima visoku selektivnost prema SO2 u poređenju sa drugim komponentama dimnog gasa kao što je CO2, i odličnu sposobnost vezivanja mehanizmima hemijske apsorpcije, ali glavni nedostatak je visoka toksičnost. S druge strane, u, sa stanovišta životne sredine prihvatljivijem, 2-butanolu do vezivanja sumpor-dioksida dolazi fizičkom apsorpcijom. Istraživanja su pokazala da smeše fizičkih i hemijskih rastvarača obično pokazuju bolje karakteristike u pogledu mogućnosti vezivanja i selektivnosti od tradicionalno korišćenih vodenih rastvora amina, zbog sinergetskog efekta.   Jedno od najvažnijih termofizičkih svojstava rastvarača, neophodno za simulaciju procesa i proračun opreme, je dinamička viskoznost. U ovom istraživanju, viskoznost binarne smeše DMA + 2-butanol eksperimentalno je određena u temperaturnom i koncentracionom opsegu i nakon toga korelisana korišćenjem različitih literaturnih modela. Ove korelacije predstavljaju korisnu metodu za dobijanje pouzdanih podataka potrebnih za analizu protoka fluida i proračune prenosa mase i toplote, jer eksperimentalne vrednosti za željene uslove procesa često nisu dostupne. U ovom istraživanju korišćeni su dvo- ili troparametarski modeli Eyring-UNIQUAC, Eyring-NRTL i McAllister, dok je model koji povezuje Eyring jednačinu, Peng-Robinson jednačinu stanja i van der Waals pravilo mešanja testiran za istovremeno izračunavanje gustine i viskoznosti. Dobijeni rezultati su prikazani i diskutovani u pogledu potencijalne primene, ograničenja i složenosti korišćenog pristupa i modela.
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS)
PB  - Beograd : Društvo za procesnu tehniku
C3  - Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji
T1  - Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes
T1  - Viskoznost binarne smeše DMA + 2-butanol za potencijalnu upotrebu kao rastvarača za regenerativne procese odsumporavanja dimnih gasova
SP  - 213
EP  - 218
DO  - 10.24094/ptk.019.32.1.213
ER  - 
@conference{
author = "Majstorović, Divna and Živković, Nikola and Kijevčanin, Mirjana and Živković, Emila",
year = "2019",
abstract = "Sulfur dioxide (SO2) is an environmental pollutant with multiple harmful effects on biological world. One of the main emission sources are industrial activities in thermal power plants, foundries and steel mills which involve combustion of fossil fuels containing sulfur, such as coal and oil. Initial step towards removal of SO2from flue gases was the so-called limestone process, a wet non-regenerative process that even today is the mostused flue gas desulfurization method. However, wet regenerative processes with gas absorption in liquid organic solvent and thermal regeneration recently have found practical application. Processes based on n,n-dimethylaniline (DMA) have alre-ady been patented and industrially applied. This solvent has high selectivity towards SO2in compa-rison  to  the  other  components  of  flue  gas  like  CO2,  and  excellent  binding  capability  by  the 214• 32ndINTERNATIONAL CONGRESS ON PROCESS INDUSTRYmechanisms of chemical absorption, but main disadvantage is its high toxicity. On the other hand, in more ambient friendly 2-butanol binding of sulfur-dioxide occurs by means of physical absorption. Investigations have shown that mixtures of physical and chemical solvents usually show better cha-racteristics regarding binding capacityand selectivity than traditionally used aqueous solutions of amines, due to the synergetic effect.One  of  the  most  important  thermophysical  properties  of  solvents,  necessary  for  process  and equipment  design  is  dynamic  viscosity.  In  this  investigation  viscosity  of  binary  mixture  DMA  +  2-butanol  is  experimentally  determined  in  temperature  and  concentration  range  and  correlated afterwards  using  different  literature  models.  These  correlations  present  useful  method  to  acquire reliable data necessary for fluid flow analysis and mass and heat transfer calculations, since experi-mental values for desired process conditions are often not available. In this study, two or three-pa-rameter  Eyring-UNIQUAC,  Eyring-NRTL  and  McAllister  models  were  used,  while  model  that  co-uples Eyring equation, Peng-Robinson equation of state and van der Waals mixing rule, was tested for simultaneous calculation of density and viscosity. The obtained results are presented and discu-ssed regarding potential application, limitations and complexity of used approach and models., Sumpor dioksid (SO2) je zagađivač životne sredine sa višestrukim štetnim efektima na biološki svet. Jedan od glavnih izvora emisije su industrijske aktivnosti u termoelektranama, livnicama i železarama, koje uključuju sagorevanje fosilnih goriva koja sadrže sumpor, kao što su ugalj i nafta.   Početni korak u uklanjanju SO2 iz dimnih gasova bio je takozvani krečnjački postupak, mokri neregenerativni proces koji je i danas najčešće korišćen metod odsumporavanja dimnih gasova. Međutim, mokri regenerativni procesi sa apsorpcijom gasa u tečnom organskom rastvaraču i termalnom regeneracijom nedavno su našli praktičnu primenu. Procesi zasnovani na n,n-dimetilanilinu (DMA) su već patentirani i industrijski primenjeni. Ovaj rastvarač ima visoku selektivnost prema SO2 u poređenju sa drugim komponentama dimnog gasa kao što je CO2, i odličnu sposobnost vezivanja mehanizmima hemijske apsorpcije, ali glavni nedostatak je visoka toksičnost. S druge strane, u, sa stanovišta životne sredine prihvatljivijem, 2-butanolu do vezivanja sumpor-dioksida dolazi fizičkom apsorpcijom. Istraživanja su pokazala da smeše fizičkih i hemijskih rastvarača obično pokazuju bolje karakteristike u pogledu mogućnosti vezivanja i selektivnosti od tradicionalno korišćenih vodenih rastvora amina, zbog sinergetskog efekta.   Jedno od najvažnijih termofizičkih svojstava rastvarača, neophodno za simulaciju procesa i proračun opreme, je dinamička viskoznost. U ovom istraživanju, viskoznost binarne smeše DMA + 2-butanol eksperimentalno je određena u temperaturnom i koncentracionom opsegu i nakon toga korelisana korišćenjem različitih literaturnih modela. Ove korelacije predstavljaju korisnu metodu za dobijanje pouzdanih podataka potrebnih za analizu protoka fluida i proračune prenosa mase i toplote, jer eksperimentalne vrednosti za željene uslove procesa često nisu dostupne. U ovom istraživanju korišćeni su dvo- ili troparametarski modeli Eyring-UNIQUAC, Eyring-NRTL i McAllister, dok je model koji povezuje Eyring jednačinu, Peng-Robinson jednačinu stanja i van der Waals pravilo mešanja testiran za istovremeno izračunavanje gustine i viskoznosti. Dobijeni rezultati su prikazani i diskutovani u pogledu potencijalne primene, ograničenja i složenosti korišćenog pristupa i modela.",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS), Beograd : Društvo za procesnu tehniku",
journal = "Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji",
title = "Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes, Viskoznost binarne smeše DMA + 2-butanol za potencijalnu upotrebu kao rastvarača za regenerativne procese odsumporavanja dimnih gasova",
pages = "213-218",
doi = "10.24094/ptk.019.32.1.213"
}
Majstorović, D., Živković, N., Kijevčanin, M.,& Živković, E.. (2019). Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes. in Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS)., 213-218.
https://doi.org/10.24094/ptk.019.32.1.213
Majstorović D, Živković N, Kijevčanin M, Živković E. Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes. in Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji. 2019;:213-218.
doi:10.24094/ptk.019.32.1.213 .
Majstorović, Divna, Živković, Nikola, Kijevčanin, Mirjana, Živković, Emila, "Viscosity of binary mixture DMA + 2-butanol with potential use as solvent  for regenerative flue gas desulfurization processes" in Processing '19 : zbornik radova za 32. Međunarodni kongres o procesnoj industriji (2019):213-218,
https://doi.org/10.24094/ptk.019.32.1.213 . .

Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes

(2018)

TY  - JOUR
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7579
AB  - This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models. (C) 2018 Elsevier Ltd.
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes
VL  - 119
SP  - 135
EP  - 154
DO  - 10.1016/j.jct.2017.12.023
ER  - 
@article{
year = "2018",
abstract = "This paper presents novel data on density, viscosity and refractive index of four binary mixtures constituted of ionic liquid 1-ethyl-3-methylimidazolium ethyl sulfate and N-methyl-2-pyrrolidone/or 1-hexanol/or liquid polyethylene glycols with molar mass 200/or 400, in the temperature range from T = 288.15 K to 333.15 K and at pressure of p =.1 MPa. Thermal conductivity has been measured for mixtures of ionic liquid and polyethylene glycol 200/or polyethylene glycol 400 in the temperature range from T = 303.15 to 323.15 K and at a pressure of p =.1 MPa. All these solutions have the potential for application in regenerative flue gas desulfurization processes. From experimental values of densities, viscosities, thermal conductivities and refractive indices, excess molar volumes and deviations in viscosity, thermal conductivity and refractive index have been calculated and correlated with Redlich-Kister polynomial equation. The values of excess and deviation functions were used for analysis of molecular interactions present in the investigated solutions. In addition, modeling of transport properties, viscosity and thermal conductivity, was carried out and the obtained results were interpreted taking into account the applied approaches and models. (C) 2018 Elsevier Ltd.",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes",
volume = "119",
pages = "135-154",
doi = "10.1016/j.jct.2017.12.023"
}
(2018). Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics, 119, 135-154.
https://doi.org/10.1016/j.jct.2017.12.023
Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2018;119:135-154.
doi:10.1016/j.jct.2017.12.023 .
"Volumetric and transport properties of binary liquid mixtures with 1-ethyl-3-methylimidazolium ethyl sulfate as candidate solvents for regenerative flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 119 (2018):135-154,
https://doi.org/10.1016/j.jct.2017.12.023 . .
21
14
21

The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes

Jovanović, Jovan D.; Majstorović, Divna M.; Živković, Nikola V.; Kijevčanin, Mirjana Lj.; Živković, Emila M.

(2018)

TY  - JOUR
AU  - Jovanović, Jovan D.
AU  - Majstorović, Divna M.
AU  - Živković, Nikola V.
AU  - Kijevčanin, Mirjana Lj.
AU  - Živković, Emila M.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0167732218329441
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7885
AB  - In this study, applicability of the friction theory for the viscosity estimation of pure substances and binary liquid mixtures, used in regenerative flue gas desulphurization processes, was investigated. Theory was tested on the selected solvents that have already found commercial application, tetraethylene glycol dimethyl ether, n‑methyl‑2‑pyrrolidone and n,n‑dimethylaniline, in mixtures with alcohols 1‑butanol, 2‑butanol or 1‑hexanol. The results were compared with experimental viscosity data for eleven systems. In the calculation procedure, friction theory was coupled both with the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) equations of state (EoS). Almost identical deviations, under 0.2% with both EoS, were obtained for pure compounds. For viscosity of mixtures, in almost all cases, better results were obtained using PR EoS, with values of percentage deviations less than 4%. Additionally, the possibility of simultaneous density calculations was checked and the obtained values were compared with experimental data. Application of this model for viscosity modeling of the investigated systems was justified by comparison of the obtained results with other commonly used predictive models, UNIFAC-VISCO and ASOG-VISCO. © 2018 Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes
VL  - 271
SP  - 696
EP  - 703
DO  - 10.1016/j.molliq.2018.09.043
ER  - 
@article{
author = "Jovanović, Jovan D. and Majstorović, Divna M. and Živković, Nikola V. and Kijevčanin, Mirjana Lj. and Živković, Emila M.",
year = "2018",
abstract = "In this study, applicability of the friction theory for the viscosity estimation of pure substances and binary liquid mixtures, used in regenerative flue gas desulphurization processes, was investigated. Theory was tested on the selected solvents that have already found commercial application, tetraethylene glycol dimethyl ether, n‑methyl‑2‑pyrrolidone and n,n‑dimethylaniline, in mixtures with alcohols 1‑butanol, 2‑butanol or 1‑hexanol. The results were compared with experimental viscosity data for eleven systems. In the calculation procedure, friction theory was coupled both with the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) equations of state (EoS). Almost identical deviations, under 0.2% with both EoS, were obtained for pure compounds. For viscosity of mixtures, in almost all cases, better results were obtained using PR EoS, with values of percentage deviations less than 4%. Additionally, the possibility of simultaneous density calculations was checked and the obtained values were compared with experimental data. Application of this model for viscosity modeling of the investigated systems was justified by comparison of the obtained results with other commonly used predictive models, UNIFAC-VISCO and ASOG-VISCO. © 2018 Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes",
volume = "271",
pages = "696-703",
doi = "10.1016/j.molliq.2018.09.043"
}
Jovanović, J. D., Majstorović, D. M., Živković, N. V., Kijevčanin, M. Lj.,& Živković, E. M.. (2018). The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes. in Journal of Molecular Liquids, 271, 696-703.
https://doi.org/10.1016/j.molliq.2018.09.043
Jovanović JD, Majstorović DM, Živković NV, Kijevčanin ML, Živković EM. The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes. in Journal of Molecular Liquids. 2018;271:696-703.
doi:10.1016/j.molliq.2018.09.043 .
Jovanović, Jovan D., Majstorović, Divna M., Živković, Nikola V., Kijevčanin, Mirjana Lj., Živković, Emila M., "The friction theory for estimating viscosity of candidate solvents for flue gas desulfurization processes" in Journal of Molecular Liquids, 271 (2018):696-703,
https://doi.org/10.1016/j.molliq.2018.09.043 . .
1
1

Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids

Stanimirović, Andrej M.; Živković, Emila M.; Milošević, Nenad D.; Kijevčanin, Mirjana Lj.

(2017)

TY  - JOUR
AU  - Stanimirović, Andrej M.
AU  - Živković, Emila M.
AU  - Milošević, Nenad D.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1629
AB  - Transient hot wire method is considered a reliable and precise technique for measuring the thermal conductivity of liquids. The present paper describes a new transient hot wire experimental set-up and its initial testing. The new apparatus was tested by performing thermal conductivity measurements on substances whose reference thermophysical properties data existed in literature, namely on pure toluene and double distilled deionized water. The values of thermal conductivity measured in the temperature range 25 to 45 degrees C deviated +2.2% to +3% from the literature data, while the expanded measurement uncertainty was estimated to be +/- 4%.
T2  - Thermal Science
T1  - Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids
VL  - 21
IS  - 3
SP  - 1195
EP  - 1202
DO  - 10.2298/TSCI160324219S
ER  - 
@article{
author = "Stanimirović, Andrej M. and Živković, Emila M. and Milošević, Nenad D. and Kijevčanin, Mirjana Lj.",
year = "2017",
abstract = "Transient hot wire method is considered a reliable and precise technique for measuring the thermal conductivity of liquids. The present paper describes a new transient hot wire experimental set-up and its initial testing. The new apparatus was tested by performing thermal conductivity measurements on substances whose reference thermophysical properties data existed in literature, namely on pure toluene and double distilled deionized water. The values of thermal conductivity measured in the temperature range 25 to 45 degrees C deviated +2.2% to +3% from the literature data, while the expanded measurement uncertainty was estimated to be +/- 4%.",
journal = "Thermal Science",
title = "Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids",
volume = "21",
number = "3",
pages = "1195-1202",
doi = "10.2298/TSCI160324219S"
}
Stanimirović, A. M., Živković, E. M., Milošević, N. D.,& Kijevčanin, M. Lj.. (2017). Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids. in Thermal Science, 21(3), 1195-1202.
https://doi.org/10.2298/TSCI160324219S
Stanimirović AM, Živković EM, Milošević ND, Kijevčanin ML. Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids. in Thermal Science. 2017;21(3):1195-1202.
doi:10.2298/TSCI160324219S .
Stanimirović, Andrej M., Živković, Emila M., Milošević, Nenad D., Kijevčanin, Mirjana Lj., "Application and Testing of a New Simple Experimental Set-Up for Thermal Conductivity Measurements of Liquids" in Thermal Science, 21, no. 3 (2017):1195-1202,
https://doi.org/10.2298/TSCI160324219S . .
4
2

Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit

Škobalj, Predrag D.; Kijevčanin, Mirjana Lj.; Jovanović, Marina P.; Afgan, Naim H.; Erić, Milić D.

(2017)

TY  - JOUR
AU  - Škobalj, Predrag D.
AU  - Kijevčanin, Mirjana Lj.
AU  - Jovanović, Marina P.
AU  - Afgan, Naim H.
AU  - Erić, Milić D.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1550
AB  - This paper presents method for sustainability assessment of thermal power plant unit using multi-criteria analysis with aim to create base for business decision. Seven options of possible status of thermal power plant Kolubara A unit No. 2 with energy indicators of sustainable development were shown. Energy indicators of sustainable development consists of sets of resource preservation, economic, environmental, and social indicators. Sustainability assessment often fails to account for social influence on energy system. Considering to this, special focus will be on social indicators, their definition, forming, and impact on multi-criteria sustainability analysis. Analysis of quality of the selected options (energy systems) in respect to sustainable development by compare of their general index of sustainability is presented. Methodology of multi-criteria analyse of thermal power plant unit can show decision makers how to find best available options when the social indicators impact is leading. The aim of this paper is to choose the criteria for the evaluation of the available options, determine the relative importance of specific criteria and present methodology of multi-criteria analysis in the decision-making process.
T2  - Thermal Science
T1  - Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit
VL  - 21
IS  - 2
SP  - 1143
EP  - 1151
DO  - 10.2298/TSCI160215178S
ER  - 
@article{
author = "Škobalj, Predrag D. and Kijevčanin, Mirjana Lj. and Jovanović, Marina P. and Afgan, Naim H. and Erić, Milić D.",
year = "2017",
abstract = "This paper presents method for sustainability assessment of thermal power plant unit using multi-criteria analysis with aim to create base for business decision. Seven options of possible status of thermal power plant Kolubara A unit No. 2 with energy indicators of sustainable development were shown. Energy indicators of sustainable development consists of sets of resource preservation, economic, environmental, and social indicators. Sustainability assessment often fails to account for social influence on energy system. Considering to this, special focus will be on social indicators, their definition, forming, and impact on multi-criteria sustainability analysis. Analysis of quality of the selected options (energy systems) in respect to sustainable development by compare of their general index of sustainability is presented. Methodology of multi-criteria analyse of thermal power plant unit can show decision makers how to find best available options when the social indicators impact is leading. The aim of this paper is to choose the criteria for the evaluation of the available options, determine the relative importance of specific criteria and present methodology of multi-criteria analysis in the decision-making process.",
journal = "Thermal Science",
title = "Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit",
volume = "21",
number = "2",
pages = "1143-1151",
doi = "10.2298/TSCI160215178S"
}
Škobalj, P. D., Kijevčanin, M. Lj., Jovanović, M. P., Afgan, N. H.,& Erić, M. D.. (2017). Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit. in Thermal Science, 21(2), 1143-1151.
https://doi.org/10.2298/TSCI160215178S
Škobalj PD, Kijevčanin ML, Jovanović MP, Afgan NH, Erić MD. Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit. in Thermal Science. 2017;21(2):1143-1151.
doi:10.2298/TSCI160215178S .
Škobalj, Predrag D., Kijevčanin, Mirjana Lj., Jovanović, Marina P., Afgan, Naim H., Erić, Milić D., "Energy Indicators Impact in Multi-Criteria Sustainability Analyse of Thermal Power Plant Unit" in Thermal Science, 21, no. 2 (2017):1143-1151,
https://doi.org/10.2298/TSCI160215178S . .
1
2

Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes

Živković, Nikola V.; Zivkovic, Emila M.; Šerbanović, Slobodan P.; Majstorović, Divna M.; Kijevčanin, Mirjana Lj.

(2017)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Zivkovic, Emila M.
AU  - Šerbanović, Slobodan P.
AU  - Majstorović, Divna M.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1443
AB  - Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations. (C) 2017 Elsevier Ltd.
T2  - Journal of Chemical Thermodynamics
T1  - Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes
VL  - 108
SP  - 162
EP  - 180
DO  - 10.1016/j.jct.2017.01.018
ER  - 
@article{
author = "Živković, Nikola V. and Zivkovic, Emila M. and Šerbanović, Slobodan P. and Majstorović, Divna M. and Kijevčanin, Mirjana Lj.",
year = "2017",
abstract = "Desulphurization processes (FGD) of flue gases from the thermal power and industrial plants, based on organic liquid solvents with mechanism of physical absorption (tetraethylene glycol dimethyl ether) or combination of physical and chemical absorption (N-methyl-2-pyrrolidone), recently gained its significance. The research results presented in this paper include density and dynamic viscosity measurements of following binary systems at atmospheric pressure: polyethylene glycol 200 + tetraethylene glycol dimethyl ether, polyethylene glycol 400 + tetraethylene glycol dimethyl ether, in temperature range from 288.15 to 333.15 K, and binary systems polyethylene glycol 200 + N-methyl-2-pyrrolidone and polyethylene glycol 400 + N-methyl-2-pyrrolidone, in temperature range from 288.15 to 323.15 K. In order to analyze and comment intermolecular interactions, calculated values of excess molar volumes and viscosity deviations were used. Strong, physical interactions of dipole-dipole type or formation of intermolecular hydrogen bonds lead and contribute to negative V-E values that occur in these systems. Calculated values of excess and deviation properties were interpolated using the Redlich-Kister polynomial equation. Viscosity modeling has been performed, using predictive, group contribution models (UNIFAC - VISCO and ASOG- VISCO) as well as correlative models (McAlister, Eyring - UNIQUAC and Eyring - NRTL). For simultaneous modeling of excess molar volumes and viscosities, model based on the equation of state was used. For investigated systems, correlative McAllister models gave the best results and can be used for viscosity calculations. (C) 2017 Elsevier Ltd.",
journal = "Journal of Chemical Thermodynamics",
title = "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes",
volume = "108",
pages = "162-180",
doi = "10.1016/j.jct.2017.01.018"
}
Živković, N. V., Zivkovic, E. M., Šerbanović, S. P., Majstorović, D. M.,& Kijevčanin, M. Lj.. (2017). Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. in Journal of Chemical Thermodynamics, 108, 162-180.
https://doi.org/10.1016/j.jct.2017.01.018
Živković NV, Zivkovic EM, Šerbanović SP, Majstorović DM, Kijevčanin ML. Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes. in Journal of Chemical Thermodynamics. 2017;108:162-180.
doi:10.1016/j.jct.2017.01.018 .
Živković, Nikola V., Zivkovic, Emila M., Šerbanović, Slobodan P., Majstorović, Divna M., Kijevčanin, Mirjana Lj., "Volumetric and viscometric properties of binary liquid mixtures as potential solvents for flue gas desulfurization processes" in Journal of Chemical Thermodynamics, 108 (2017):162-180,
https://doi.org/10.1016/j.jct.2017.01.018 . .
5
4
5

Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study

Maslovara, Slađana Lj.; Vasić Anićijević, Dragana D.; Kijevčanin, Mirjana Lj.; Radović, Ivona R.; Nikolić, Vladimir M.; Laušević, Petar; Marčeta Kaninski, Milica

(2017)

TY  - JOUR
AU  - Maslovara, Slađana Lj.
AU  - Vasić Anićijević, Dragana D.
AU  - Kijevčanin, Mirjana Lj.
AU  - Radović, Ivona R.
AU  - Nikolić, Vladimir M.
AU  - Laušević, Petar
AU  - Marčeta Kaninski, Milica
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1610
AB  - In this paper we discussed various factors contributing to the improvement of hydrogen evolution reaction (HER) activity of Ni and stainless steel electrodes activated by in situ addition of NiCoMo activators, using a combination of experimental techniques and DFT calculations. By comparing energy consumption of stainless steel (SS) electrodes in a lab scale alkaline electrolyzer with and without ionic activation, we obtained reduction of energy consumption by 21% at industrial conditions (high current density and temperature). We recorded U-I curves for activated and non-activated stainless steel electrodes in the current density range from 40 to 500 mA cm(2) and in the temperature range 298-343 K, and the obtained results were used in an electrochemical model of the laboratory alkaline electrolyzer. Increase of the electrode surface upon addition of ionic activators was confirmed by profilometric measurements and SEM analysis. Finally, we applied density functional theory (DFT) to discuss partial roles of applied ionic activators (Ni, Co and Mo) in the modification and improvement of the intrinsic properties of the cathode towards the HER in alkaline medium. From the combination of profilometric, SEM and DFT results, we conclude that the main factor contributing to the improvement of HER activity of Ni electrodes upon NiCoMo activation is the increase of electrode surface area. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study
VL  - 42
IS  - 8
SP  - 5072
EP  - 5082
DO  - 10.1016/j.ijhydene.2016.12.116
ER  - 
@article{
author = "Maslovara, Slađana Lj. and Vasić Anićijević, Dragana D. and Kijevčanin, Mirjana Lj. and Radović, Ivona R. and Nikolić, Vladimir M. and Laušević, Petar and Marčeta Kaninski, Milica",
year = "2017",
abstract = "In this paper we discussed various factors contributing to the improvement of hydrogen evolution reaction (HER) activity of Ni and stainless steel electrodes activated by in situ addition of NiCoMo activators, using a combination of experimental techniques and DFT calculations. By comparing energy consumption of stainless steel (SS) electrodes in a lab scale alkaline electrolyzer with and without ionic activation, we obtained reduction of energy consumption by 21% at industrial conditions (high current density and temperature). We recorded U-I curves for activated and non-activated stainless steel electrodes in the current density range from 40 to 500 mA cm(2) and in the temperature range 298-343 K, and the obtained results were used in an electrochemical model of the laboratory alkaline electrolyzer. Increase of the electrode surface upon addition of ionic activators was confirmed by profilometric measurements and SEM analysis. Finally, we applied density functional theory (DFT) to discuss partial roles of applied ionic activators (Ni, Co and Mo) in the modification and improvement of the intrinsic properties of the cathode towards the HER in alkaline medium. From the combination of profilometric, SEM and DFT results, we conclude that the main factor contributing to the improvement of HER activity of Ni electrodes upon NiCoMo activation is the increase of electrode surface area. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study",
volume = "42",
number = "8",
pages = "5072-5082",
doi = "10.1016/j.ijhydene.2016.12.116"
}
Maslovara, S. Lj., Vasić Anićijević, D. D., Kijevčanin, M. Lj., Radović, I. R., Nikolić, V. M., Laušević, P.,& Marčeta Kaninski, M.. (2017). Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study. in International Journal of Hydrogen Energy, 42(8), 5072-5082.
https://doi.org/10.1016/j.ijhydene.2016.12.116
Maslovara SL, Vasić Anićijević DD, Kijevčanin ML, Radović IR, Nikolić VM, Laušević P, Marčeta Kaninski M. Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study. in International Journal of Hydrogen Energy. 2017;42(8):5072-5082.
doi:10.1016/j.ijhydene.2016.12.116 .
Maslovara, Slađana Lj., Vasić Anićijević, Dragana D., Kijevčanin, Mirjana Lj., Radović, Ivona R., Nikolić, Vladimir M., Laušević, Petar, Marčeta Kaninski, Milica, "Improved HER activity of Ni and stainless steel electrodes activated by NiCoMo ionic activator - A combined DFT and experimental study" in International Journal of Hydrogen Energy, 42, no. 8 (2017):5072-5082,
https://doi.org/10.1016/j.ijhydene.2016.12.116 . .
6
4
7

Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2

Škobalj, Predrag D.; Kijevčanin, Mirjana Lj.; Afgan, Naim H.; Jovanović, Marina P.; Turanjanin, Valentina; Vučićević, Biljana S.

(2017)

TY  - JOUR
AU  - Škobalj, Predrag D.
AU  - Kijevčanin, Mirjana Lj.
AU  - Afgan, Naim H.
AU  - Jovanović, Marina P.
AU  - Turanjanin, Valentina
AU  - Vučićević, Biljana S.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1574
AB  - The paper presents a possible approach for creating business decisions based on multi-criteria analysis. Seven options for a possible revitalization of the thermal power plant Kolubara-A Unit No. 2 with energy indicators of sustainable development (EISD) are presented in this paper. The chosen EISD numerically express the essential features of the analyzed options, while the sustainability criteria indicate the option quality within the limits of these indicators. In this paper, the criteria for assessing the sustainability options are defined based on several aspects: economic, social, environmental and technological. In the process of assessing the sustainability of the considered options the Analysis and Synthesis of Parameters under Information Deficiency (ASPID) method was used. In this paper, the EISD show that production and energy consumption are closely linked to economic, environmental and other indicators, such as economic and technological development of local communities with employment being one of the most important social parameter. Multi-criteria analysis for the case study of the TPP Kolubara-A clearly indicated recommendations to decision makers on the choice of the best available options in dependence on the energy policy. (C) 2017 Elsevier Ltd. All rights reserved.
T2  - Energy
T1  - Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2
VL  - 125
SP  - 837
EP  - 847
DO  - 10.1016/j.energy.2017.02.027
ER  - 
@article{
author = "Škobalj, Predrag D. and Kijevčanin, Mirjana Lj. and Afgan, Naim H. and Jovanović, Marina P. and Turanjanin, Valentina and Vučićević, Biljana S.",
year = "2017",
abstract = "The paper presents a possible approach for creating business decisions based on multi-criteria analysis. Seven options for a possible revitalization of the thermal power plant Kolubara-A Unit No. 2 with energy indicators of sustainable development (EISD) are presented in this paper. The chosen EISD numerically express the essential features of the analyzed options, while the sustainability criteria indicate the option quality within the limits of these indicators. In this paper, the criteria for assessing the sustainability options are defined based on several aspects: economic, social, environmental and technological. In the process of assessing the sustainability of the considered options the Analysis and Synthesis of Parameters under Information Deficiency (ASPID) method was used. In this paper, the EISD show that production and energy consumption are closely linked to economic, environmental and other indicators, such as economic and technological development of local communities with employment being one of the most important social parameter. Multi-criteria analysis for the case study of the TPP Kolubara-A clearly indicated recommendations to decision makers on the choice of the best available options in dependence on the energy policy. (C) 2017 Elsevier Ltd. All rights reserved.",
journal = "Energy",
title = "Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2",
volume = "125",
pages = "837-847",
doi = "10.1016/j.energy.2017.02.027"
}
Škobalj, P. D., Kijevčanin, M. Lj., Afgan, N. H., Jovanović, M. P., Turanjanin, V.,& Vučićević, B. S.. (2017). Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2. in Energy, 125, 837-847.
https://doi.org/10.1016/j.energy.2017.02.027
Škobalj PD, Kijevčanin ML, Afgan NH, Jovanović MP, Turanjanin V, Vučićević BS. Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2. in Energy. 2017;125:837-847.
doi:10.1016/j.energy.2017.02.027 .
Škobalj, Predrag D., Kijevčanin, Mirjana Lj., Afgan, Naim H., Jovanović, Marina P., Turanjanin, Valentina, Vučićević, Biljana S., "Multi-criteria sustainability analysis of thermal power plant Kolubara-A Unit 2" in Energy, 125 (2017):837-847,
https://doi.org/10.1016/j.energy.2017.02.027 . .
10
5
9

Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption

Živković, Nikola; Stefanović, Predrag; Kijevčanin, Mirjana; Živković, Emila; Spasojević, Vuk

(2016)

TY  - CONF
AU  - Živković, Nikola
AU  - Stefanović, Predrag
AU  - Kijevčanin, Mirjana
AU  - Živković, Emila
AU  - Spasojević, Vuk
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12114
AB  - In addition to lime / limestone process, the most common procedure for sulfur-dioxide (SO2) removal from flue gases, separation processes with physical absorption and liquid organic solvent thermal regeneration recently gained importance. Organic liquid solvent selection, ahead of other process parameters, is crucial for process separation efficiency, in terms of the amount of SO2 absorbed by the solvent. The paper presents literature review and analysis of SO2 solubility in currently used and potential liquid organic solvents, polyethylene glycols (PEG 200 and PEG 400), tetraethylene glycol dimethyl ether (TEGDME), 1-methyl-2-pyrrolidone (NMP) as well as their binary mixtures with other components. The solvents in question bind SO2 by physical absorption mechanism, with the exception of NMP which binds SO2 by two parallel mechanisms, physical and chemical absorption. Research have even shown that mixtures of physical and chemical solvents or presence of both absorption mechanisms sometimes show better characteristics regarding binding capacity and selectivity. The importance of ionic liquids, as future solvents for separation processes, is particularly highlighted, due to their favorable thermophysical properties.
AB  - Pored najrasprostranjenijeg, krečnjačkog postupka, za uklanjnje sumpor-dioksida (SO2) iz dimnih gasova, u novije vreme sve veći značaj dobijaju separacioni postupci sa fizičkom apsorpcijom i termičkom regeneracijom tečnog organskog solventa. Izbor solventa, ispred drugih procesnih parametara, ključan je za efikasnost procesa u pogledu stepena izdvajanja SO2. U radu je dat literaturni pregled i analiza rastvoljivosti SO2 u trenutno korišćenim i potencijalnim tečnim organskim solventima, polietilen glikolima (PEG 200 i PEG 400), tetraetilen glikol dimetil etru (TEGDME), 1-metil-2-pirolidonu (NMP) i za njihove binarne smeše sa drugim komponentama. Razmatrani solventi vezuju SO2 mehanizmom fizičke apsorpcije, sa izuzetkom NMP-a kod koga su prisutna dva paralelna mehanizma, fizička i hemijska apsorpcija. Istraživanja su čak pokazala da smeše fizičkih i hemijskih solvenata ili smeše u kojima su prisutni mehanizmi i fizičke i hemijska apsorpcije ponekad pokazuju bolje karaktristike u pogledu stepena izdvajanja i selektivnosti. Posebno je istaknut značaj jonskih tečnosti kao solvenata budućnosti za separacione proces, zbog svojih povoljnih termofizičkih svojstava.
C3  - Power Plants 2016 : Proceeding of International Conference
T1  - Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption
SP  - 896
EP  - 905
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12114
ER  - 
@conference{
author = "Živković, Nikola and Stefanović, Predrag and Kijevčanin, Mirjana and Živković, Emila and Spasojević, Vuk",
year = "2016",
abstract = "In addition to lime / limestone process, the most common procedure for sulfur-dioxide (SO2) removal from flue gases, separation processes with physical absorption and liquid organic solvent thermal regeneration recently gained importance. Organic liquid solvent selection, ahead of other process parameters, is crucial for process separation efficiency, in terms of the amount of SO2 absorbed by the solvent. The paper presents literature review and analysis of SO2 solubility in currently used and potential liquid organic solvents, polyethylene glycols (PEG 200 and PEG 400), tetraethylene glycol dimethyl ether (TEGDME), 1-methyl-2-pyrrolidone (NMP) as well as their binary mixtures with other components. The solvents in question bind SO2 by physical absorption mechanism, with the exception of NMP which binds SO2 by two parallel mechanisms, physical and chemical absorption. Research have even shown that mixtures of physical and chemical solvents or presence of both absorption mechanisms sometimes show better characteristics regarding binding capacity and selectivity. The importance of ionic liquids, as future solvents for separation processes, is particularly highlighted, due to their favorable thermophysical properties., Pored najrasprostranjenijeg, krečnjačkog postupka, za uklanjnje sumpor-dioksida (SO2) iz dimnih gasova, u novije vreme sve veći značaj dobijaju separacioni postupci sa fizičkom apsorpcijom i termičkom regeneracijom tečnog organskog solventa. Izbor solventa, ispred drugih procesnih parametara, ključan je za efikasnost procesa u pogledu stepena izdvajanja SO2. U radu je dat literaturni pregled i analiza rastvoljivosti SO2 u trenutno korišćenim i potencijalnim tečnim organskim solventima, polietilen glikolima (PEG 200 i PEG 400), tetraetilen glikol dimetil etru (TEGDME), 1-metil-2-pirolidonu (NMP) i za njihove binarne smeše sa drugim komponentama. Razmatrani solventi vezuju SO2 mehanizmom fizičke apsorpcije, sa izuzetkom NMP-a kod koga su prisutna dva paralelna mehanizma, fizička i hemijska apsorpcija. Istraživanja su čak pokazala da smeše fizičkih i hemijskih solvenata ili smeše u kojima su prisutni mehanizmi i fizičke i hemijska apsorpcije ponekad pokazuju bolje karaktristike u pogledu stepena izdvajanja i selektivnosti. Posebno je istaknut značaj jonskih tečnosti kao solvenata budućnosti za separacione proces, zbog svojih povoljnih termofizičkih svojstava.",
journal = "Power Plants 2016 : Proceeding of International Conference",
title = "Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption",
pages = "896-905",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12114"
}
Živković, N., Stefanović, P., Kijevčanin, M., Živković, E.,& Spasojević, V.. (2016). Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption. in Power Plants 2016 : Proceeding of International Conference, 896-905.
https://hdl.handle.net/21.15107/rcub_vinar_12114
Živković N, Stefanović P, Kijevčanin M, Živković E, Spasojević V. Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption. in Power Plants 2016 : Proceeding of International Conference. 2016;:896-905.
https://hdl.handle.net/21.15107/rcub_vinar_12114 .
Živković, Nikola, Stefanović, Predrag, Kijevčanin, Mirjana, Živković, Emila, Spasojević, Vuk, "Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption" in Power Plants 2016 : Proceeding of International Conference (2016):896-905,
https://hdl.handle.net/21.15107/rcub_vinar_12114 .

Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options

Škobalj, Predrag D.; Jovanović, Marina P.; Vučićević, Biljana S.; Turanjanin, Valentina; Kijevčanin, Mirjana Lj.

(2016)

TY  - CONF
AU  - Škobalj, Predrag D.
AU  - Jovanović, Marina P.
AU  - Vučićević, Biljana S.
AU  - Turanjanin, Valentina
AU  - Kijevčanin, Mirjana Lj.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7138
AB  - Coal combustion power plant Kolubara A has five thermal units with total installed capacity of 270 MW operates as a part of Public Enterprise which has planned to accept and apply the Clean Development Mechanism (new power plants on lignite and natural gas with higher energy efficiency as well as activities related to the rehabilitation and modernization of existing facilities). Two units were put in operation before more than fifty years and in order to extend the lifetime of these blocks in the process of revitalization, in this paper, beside an existing option which considers coal (lignite) combustion, are analysed possible options of thermal power units with gas and renewable energy sources: biomass, renewable solid fuels, waste materials, wind and sun. Paper presents seven energy system options of the thermal unit status which are described with suitable chosen indicators in respect to different aspects of sustainability: economical, ecological, social and resources indicators. In this paper energy indicators are defined as a tool for the sustainability assessment of energy system options. ASPID method of multi-criteria assessment was used to calculate general index of sustainability and obtained ranking of options. This study presented and analysed cases, with predefined constraints when priority has environmental indicator and different conditions where one of sub-indicators have priority, as an example of applying multi-criteria method.
T1  - Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7138
ER  - 
@conference{
author = "Škobalj, Predrag D. and Jovanović, Marina P. and Vučićević, Biljana S. and Turanjanin, Valentina and Kijevčanin, Mirjana Lj.",
year = "2016",
abstract = "Coal combustion power plant Kolubara A has five thermal units with total installed capacity of 270 MW operates as a part of Public Enterprise which has planned to accept and apply the Clean Development Mechanism (new power plants on lignite and natural gas with higher energy efficiency as well as activities related to the rehabilitation and modernization of existing facilities). Two units were put in operation before more than fifty years and in order to extend the lifetime of these blocks in the process of revitalization, in this paper, beside an existing option which considers coal (lignite) combustion, are analysed possible options of thermal power units with gas and renewable energy sources: biomass, renewable solid fuels, waste materials, wind and sun. Paper presents seven energy system options of the thermal unit status which are described with suitable chosen indicators in respect to different aspects of sustainability: economical, ecological, social and resources indicators. In this paper energy indicators are defined as a tool for the sustainability assessment of energy system options. ASPID method of multi-criteria assessment was used to calculate general index of sustainability and obtained ranking of options. This study presented and analysed cases, with predefined constraints when priority has environmental indicator and different conditions where one of sub-indicators have priority, as an example of applying multi-criteria method.",
title = "Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7138"
}
Škobalj, P. D., Jovanović, M. P., Vučićević, B. S., Turanjanin, V.,& Kijevčanin, M. Lj.. (2016). Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options. .
https://hdl.handle.net/21.15107/rcub_vinar_7138
Škobalj PD, Jovanović MP, Vučićević BS, Turanjanin V, Kijevčanin ML. Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options. 2016;.
https://hdl.handle.net/21.15107/rcub_vinar_7138 .
Škobalj, Predrag D., Jovanović, Marina P., Vučićević, Biljana S., Turanjanin, Valentina, Kijevčanin, Mirjana Lj., "Application of multi-criteria assessment in decision-making proces in planning of sustainable development of energy system options" (2016),
https://hdl.handle.net/21.15107/rcub_vinar_7138 .

Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases

Spasojević, Vuk D.; Šerbanović, Slobodan P.; Stefanović, Predrag Lj.; Kijevčanin, Mirjana Lj.

(2014)

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Šerbanović, Slobodan P.
AU  - Stefanović, Predrag Lj.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5980
AB  - In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.
T2  - Hemijska industrija
T1  - Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases
VL  - 68
IS  - 1
SP  - 123
EP  - 134
DO  - 10.2298/HEMIND130312039S
ER  - 
@article{
author = "Spasojević, Vuk D. and Šerbanović, Slobodan P. and Stefanović, Predrag Lj. and Kijevčanin, Mirjana Lj.",
year = "2014",
abstract = "In this work a review of the currently available methods for carbon dioxide removal from flue gasses is given. Some of them are commercially available, while others are still under development. Special attention is given to detailed description of the methods based on hemi sorption by aqueous solutions of alkanolamines, which found wide commercial use in industry. Selection of appropriate absorbent, process equipment, methods, working parameters, combustion processes, etc., are some of the key points that will be reviewed within this work in order to present advantages and limitations of carbon dioxide removal methods. In the experimental section we have provided data on density, viscosity and refractive index of insufficiently investigated carbon dioxide removal agents, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA), triisopropanolamine (TIPA) and currently widely used dietanolamine (DEA). The data obtained are crucial for the equipment design and process optimization.",
journal = "Hemijska industrija",
title = "Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases",
volume = "68",
number = "1",
pages = "123-134",
doi = "10.2298/HEMIND130312039S"
}
Spasojević, V. D., Šerbanović, S. P., Stefanović, P. Lj.,& Kijevčanin, M. Lj.. (2014). Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. in Hemijska industrija, 68(1), 123-134.
https://doi.org/10.2298/HEMIND130312039S
Spasojević VD, Šerbanović SP, Stefanović PL, Kijevčanin ML. Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases. in Hemijska industrija. 2014;68(1):123-134.
doi:10.2298/HEMIND130312039S .
Spasojević, Vuk D., Šerbanović, Slobodan P., Stefanović, Predrag Lj., Kijevčanin, Mirjana Lj., "Review of techological methods and experimental determination of thermodynamic and transport properties of reagents for carbon dioxide removal from flue gases" in Hemijska industrija, 68, no. 1 (2014):123-134,
https://doi.org/10.2298/HEMIND130312039S . .
1
1

Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination

Živković, Nikola V.; Šerbanović, Slobodan P.; Zivkovic, Emila M.; Kijevčanin, Mirjana Lj.; Stefanović, Predrag Lj.

(2014)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Šerbanović, Slobodan P.
AU  - Zivkovic, Emila M.
AU  - Kijevčanin, Mirjana Lj.
AU  - Stefanović, Predrag Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/162
AB  - In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.
T2  - Hemijska industrija
T1  - Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination
VL  - 68
IS  - 4
SP  - 491
EP  - 500
DO  - 10.2298/HEMIND130610074Z
ER  - 
@article{
author = "Živković, Nikola V. and Šerbanović, Slobodan P. and Zivkovic, Emila M. and Kijevčanin, Mirjana Lj. and Stefanović, Predrag Lj.",
year = "2014",
abstract = "In order to mitigate climate change, the priority task is to reduce emissions of greenhouse gases, including sulfur oxides, from stationary power plants. The legal framework of the European Union has limited the allowable emissions of gases with harmful effects and fulfillment of this obligation is also ahead of the Republic of Serbia in the following years. In this paper the categorization of wet procedures for sulfur oxides removal is given. Wet procedure with the most widespread industrial application, lime/limestone process, has been described in detail. In addition, the procedures with chemical and physical absorption and solvent thermal regeneration, which recently gained more importance, have been presented. Experimentally determined thermophysical and transport properties of commercially used and alternative solvents, necessary for the equipment design and process optimization, are also given in the paper. The obtained values of densities and viscosities of pure chemicals - solvents, polyethylene glycol 200 (PEG 200), polyethylene glycol 400 (PEG 400), tetraethylene glycol dimethyl ether (TEGDMA), N-methyl-2-pyrolidon (NMP) and dimethylaniline (DMA), measured at the atmospheric pressure, are presented as a function of temperature.",
journal = "Hemijska industrija",
title = "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination",
volume = "68",
number = "4",
pages = "491-500",
doi = "10.2298/HEMIND130610074Z"
}
Živković, N. V., Šerbanović, S. P., Zivkovic, E. M., Kijevčanin, M. Lj.,& Stefanović, P. Lj.. (2014). Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. in Hemijska industrija, 68(4), 491-500.
https://doi.org/10.2298/HEMIND130610074Z
Živković NV, Šerbanović SP, Zivkovic EM, Kijevčanin ML, Stefanović PL. Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination. in Hemijska industrija. 2014;68(4):491-500.
doi:10.2298/HEMIND130610074Z .
Živković, Nikola V., Šerbanović, Slobodan P., Zivkovic, Emila M., Kijevčanin, Mirjana Lj., Stefanović, Predrag Lj., "Wet flue gas desulphurisation procedures and relevant solvents thermophysical properties determination" in Hemijska industrija, 68, no. 4 (2014):491-500,
https://doi.org/10.2298/HEMIND130610074Z . .
2
2

Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K

Spasojević, Vuk D.; Djordjevic, Bojan D.; Šerbanović, Slobodan P.; Radović, Ivona R.; Kijevčanin, Mirjana Lj.

(2014)

TY  - JOUR
AU  - Spasojević, Vuk D.
AU  - Djordjevic, Bojan D.
AU  - Šerbanović, Slobodan P.
AU  - Radović, Ivona R.
AU  - Kijevčanin, Mirjana Lj.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6039
AB  - Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.
T2  - Journal of Chemical and Engineering Data
T1  - Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K
VL  - 59
IS  - 6
SP  - 1817
EP  - 1829
DO  - 10.1021/je401036f
ER  - 
@article{
author = "Spasojević, Vuk D. and Djordjevic, Bojan D. and Šerbanović, Slobodan P. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.",
year = "2014",
abstract = "Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.",
journal = "Journal of Chemical and Engineering Data",
title = "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K",
volume = "59",
number = "6",
pages = "1817-1829",
doi = "10.1021/je401036f"
}
Spasojević, V. D., Djordjevic, B. D., Šerbanović, S. P., Radović, I. R.,& Kijevčanin, M. Lj.. (2014). Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data, 59(6), 1817-1829.
https://doi.org/10.1021/je401036f
Spasojević VD, Djordjevic BD, Šerbanović SP, Radović IR, Kijevčanin ML. Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data. 2014;59(6):1817-1829.
doi:10.1021/je401036f .
Spasojević, Vuk D., Djordjevic, Bojan D., Šerbanović, Slobodan P., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K" in Journal of Chemical and Engineering Data, 59, no. 6 (2014):1817-1829,
https://doi.org/10.1021/je401036f . .
56
42
56

Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME

Živković, Nikola V.; Serbanovic, S.; Kijevčanin, Mirjana Lj.; Zivkovic, E.

(2013)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Serbanovic, S.
AU  - Kijevčanin, Mirjana Lj.
AU  - Zivkovic, E.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5586
AB  - Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg-Nissan, Eyring-UNIQUAC, three-body McAlister, and Eyring-NRTL models.
T2  - International Journal of Thermophysics
T1  - Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME
VL  - 34
IS  - 6
SP  - 1002
EP  - 1020
DO  - 10.1007/s10765-013-1469-0
ER  - 
@article{
author = "Živković, Nikola V. and Serbanovic, S. and Kijevčanin, Mirjana Lj. and Zivkovic, E.",
year = "2013",
abstract = "Densities, viscosities, and refractive indices of three binary systems consisting of 1-butanol with polyethylene glycols of different molecular weights (PEG 200 and PEG 400) or tetraethylene glycol dimethyl ether (TEGDME) were measured at ten temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and atmospheric pressure. Densities of the selected binary mixtures were measured with an Anton Paar DMA 5000 digital vibrating U-tube densimeter, refractive indices were measured with an automatic Anton Paar RXA-156 refractometer, while for viscosity measurements, a digital Stabinger SVM 3000/G2 viscometer was used. From these data, excess molar volumes were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of specific molecular interactions and mixing behavior between mixture components, as well as the influence of temperature on them. Viscosity data were also correlated by Grunberg-Nissan, Eyring-UNIQUAC, three-body McAlister, and Eyring-NRTL models.",
journal = "International Journal of Thermophysics",
title = "Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME",
volume = "34",
number = "6",
pages = "1002-1020",
doi = "10.1007/s10765-013-1469-0"
}
Živković, N. V., Serbanovic, S., Kijevčanin, M. Lj.,& Zivkovic, E.. (2013). Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME. in International Journal of Thermophysics, 34(6), 1002-1020.
https://doi.org/10.1007/s10765-013-1469-0
Živković NV, Serbanovic S, Kijevčanin ML, Zivkovic E. Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME. in International Journal of Thermophysics. 2013;34(6):1002-1020.
doi:10.1007/s10765-013-1469-0 .
Živković, Nikola V., Serbanovic, S., Kijevčanin, Mirjana Lj., Zivkovic, E., "Volumetric Properties, Viscosities, and Refractive Indices of the Binary Systems 1-Butanol + PEG 200, + PEG 400, and + TEGDME" in International Journal of Thermophysics, 34, no. 6 (2013):1002-1020,
https://doi.org/10.1007/s10765-013-1469-0 . .
41
29
35

Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone

Živković, Nikola V.; Serbanovic, Slobodanh S.; Kijevčanin, Mirjana Lj.; Zivkovic, E. M.

(2013)

TY  - JOUR
AU  - Živković, Nikola V.
AU  - Serbanovic, Slobodanh S.
AU  - Kijevčanin, Mirjana Lj.
AU  - Zivkovic, E. M.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5805
AB  - Experimental data on densities, viscosities, and refractive indices of binary mixtures with 2-butanol and polyethylene glycols of different molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in refractive indices were computed from these data and correlated with the Redlich-Kister polynomial equation. The obtained results allowed the interpretation of specific inter- and intramolecular interactions.
T2  - Journal of Chemical and Engineering Data
T1  - Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone
VL  - 58
IS  - 12
SP  - 3332
EP  - 3341
DO  - 10.1021/je400486p
ER  - 
@article{
author = "Živković, Nikola V. and Serbanovic, Slobodanh S. and Kijevčanin, Mirjana Lj. and Zivkovic, E. M.",
year = "2013",
abstract = "Experimental data on densities, viscosities, and refractive indices of binary mixtures with 2-butanol and polyethylene glycols of different molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess molar volumes, viscosity deviations, and deviations in refractive indices were computed from these data and correlated with the Redlich-Kister polynomial equation. The obtained results allowed the interpretation of specific inter- and intramolecular interactions.",
journal = "Journal of Chemical and Engineering Data",
title = "Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone",
volume = "58",
number = "12",
pages = "3332-3341",
doi = "10.1021/je400486p"
}
Živković, N. V., Serbanovic, S. S., Kijevčanin, M. Lj.,& Zivkovic, E. M.. (2013). Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone. in Journal of Chemical and Engineering Data, 58(12), 3332-3341.
https://doi.org/10.1021/je400486p
Živković NV, Serbanovic SS, Kijevčanin ML, Zivkovic EM. Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone. in Journal of Chemical and Engineering Data. 2013;58(12):3332-3341.
doi:10.1021/je400486p .
Živković, Nikola V., Serbanovic, Slobodanh S., Kijevčanin, Mirjana Lj., Zivkovic, E. M., "Volumetric and Viscometric Behavior of Binary Systems 2-Butanol + PEG 200, + PEG 400, + Tetraethylene Glycol Dimethyl Ether, and plus N-Methyl-2-pyrrolidone" in Journal of Chemical and Engineering Data, 58, no. 12 (2013):3332-3341,
https://doi.org/10.1021/je400486p . .
68
46
61