Cvijović-Alagić, Ivana

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Authority KeyName Variants
orcid::0000-0002-3554-4003
  • Cvijović-Alagić, Ivana (82)
  • Cvijović, Ivana (10)
Projects
Micromechanical criteria of damage and fracture Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy)
Synthesis, processing and applications of nanostructured multifunctional materials with defined properties Effects of laser radiation and plasma on novel materials in their synthesis, modification, and analysis
Novel encapsulation and enzyme technologies for designing of new biocatalysts and biologically active compounds targeting enhancement of food quality, safety and competitiveness Ministry of Science and Technological Development of the Republic of Serbia [144027]
Sinteza i osobine nanostrukturnih metalnih, intermetalnih i kompozitnih materijala Ministry of Education, Science and Technological Development of the Republic of Serbia
Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals Development of the tribological micro/nano two component and hybrid selflubricating composites
Laboratory for Advanced Nuclear Energy, Institute of Innovative Research, Tokyo Institute of Technology, Tokyo, Japan [2-12-1-N1-29] Chinese Academy of Sciences [2021VEA0003]
The effect of nano- and microconstituents on the synthesis and characteristics of novel composite materials with metal matrix Molecular mechanisms of physiological and pharmacological control of inflammation and cancer
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200129 (University of Belgrade, Faculty of Dental Medicine)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200287 (Innovation Center of the Faculty of Technology and Metallurgy) Physics and Chemistry with Ion Beams
Investigation and Optimization of the Technological and Functional Performance of the Ventilation Mill in the Thermal Power Plant Kostolac B Sustainability and improvement of mechanical systems in energetic, material handling and conveying by using forensic engineering, environmental and robust design
Institute of Technical Sciences of the Serbian Academy of Sciences and Arts (SASA) JINR Dubna, Russian Federation
Ministry of Science and Environmental Protection [OI144027], Slo-Ser Ministry of Science and Techonological Development of the Republic of Serbia [144027]
Ministry of Science of the Republic of Serbia [144027] Ministry of Science, Technological Development and Innovation of the Republic of Serbia and the OeAD- Austria’s Agency for Education and Internationalization through the BilateralSerbia-Austria Scientific and Technological Cooperation Program [Contract No.337-00-577/2021-09/39]
Slovak Research and Development Agency [APVV-SK-SRB-0022, APVV-17-0328] Slovak Research and Development Agency [Contract No. APVV- 21-0402]

Author's Bibliography

Program and Book of Abstracts of the 2nd International Conference on Innovative Materials in Extreme Conditions (IMEC2024)

Matović, Branko; Cvijović-Alagić, Ivana; Maksimović, Vesna; Zagorac, Dejan

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2024)

TY  - CONF
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13138
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
T1  - Program and Book of Abstracts of the 2nd International Conference on Innovative Materials in Extreme Conditions (IMEC2024)
SP  - 82
ER  - 
@conference{
editor = "Matović, Branko, Cvijović-Alagić, Ivana, Maksimović, Vesna, Zagorac, Dejan",
year = "2024",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
title = "Program and Book of Abstracts of the 2nd International Conference on Innovative Materials in Extreme Conditions (IMEC2024)",
pages = "82"
}
Matović, B., Cvijović-Alagić, I., Maksimović, V.,& Zagorac, D.. (2024). Program and Book of Abstracts of the 2nd International Conference on Innovative Materials in Extreme Conditions (IMEC2024). 
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 82.
Matović B, Cvijović-Alagić I, Maksimović V, Zagorac D. Program and Book of Abstracts of the 2nd International Conference on Innovative Materials in Extreme Conditions (IMEC2024). 2024;:82..
Matović, Branko, Cvijović-Alagić, Ivana, Maksimović, Vesna, Zagorac, Dejan, "Program and Book of Abstracts of the 2nd International Conference on Innovative Materials in Extreme Conditions (IMEC2024)" (2024):82.

The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash

Savić, Veljko; Dojčinović, M.; Topalović, V.; Cvijović-Alagić, Ivana; Stojanović, J.; Matijašević, S.; Grujić, S.

(2024)

TY  - JOUR
AU  - Savić, Veljko
AU  - Dojčinović, M.
AU  - Topalović, V.
AU  - Cvijović-Alagić, Ivana
AU  - Stojanović, J.
AU  - Matijašević, S.
AU  - Grujić, S.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12447
AB  - The incombustible portion of coal that remains after burning is known as bottom or fly ash, and it has a detrimental influence on the environment. One of the possible alternatives for reducing the amount of ash deposited in landfills might be the production of useful glass–ceramic from vitrified fly ash. Glass–ceramic was synthesized using fly ash from the thermal power plant "Nikola Tesla" and fluxing additives. Sinter crystallization of the parent glass resulted in glass ceramics. The glass was created by melting a combination of coal fly ash (CFA), Na2CO3, and CaCO3 at T = 1500 °C and quenching the melt in the air. Glass powders were sintered at temperatures 850 and 900 °C. The resulting glass–ceramics were characterized microstructurally, physically, and mechanically. The cavitation erosion of samples was evaluated. The cavitation rate was 0.015 mg/min for the sample sintered at 850 °C and 0.0053 mg/min for the sample sintered at 900 °C. The leaching of heavy metals in glass–ceramic samples was determined using Toxicity Characteristic Leaching Procedure. A low concentration of heavy metals in the leaching solution showed that heavy metals were successfully incorporated in the glass matrix and that obtained glass–ceramics are ecologically safe for usage. Both samples exhibit good resistance to cavitation erosion, suggesting their potential as possible replacements for structural ceramics commonly employed components of hydraulic machinery.
T2  - International Journal of Environmental Science and Technology
T1  - The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash
DO  - 10.1007/s13762-023-05411-9
ER  - 
@article{
author = "Savić, Veljko and Dojčinović, M. and Topalović, V. and Cvijović-Alagić, Ivana and Stojanović, J. and Matijašević, S. and Grujić, S.",
year = "2024",
abstract = "The incombustible portion of coal that remains after burning is known as bottom or fly ash, and it has a detrimental influence on the environment. One of the possible alternatives for reducing the amount of ash deposited in landfills might be the production of useful glass–ceramic from vitrified fly ash. Glass–ceramic was synthesized using fly ash from the thermal power plant "Nikola Tesla" and fluxing additives. Sinter crystallization of the parent glass resulted in glass ceramics. The glass was created by melting a combination of coal fly ash (CFA), Na2CO3, and CaCO3 at T = 1500 °C and quenching the melt in the air. Glass powders were sintered at temperatures 850 and 900 °C. The resulting glass–ceramics were characterized microstructurally, physically, and mechanically. The cavitation erosion of samples was evaluated. The cavitation rate was 0.015 mg/min for the sample sintered at 850 °C and 0.0053 mg/min for the sample sintered at 900 °C. The leaching of heavy metals in glass–ceramic samples was determined using Toxicity Characteristic Leaching Procedure. A low concentration of heavy metals in the leaching solution showed that heavy metals were successfully incorporated in the glass matrix and that obtained glass–ceramics are ecologically safe for usage. Both samples exhibit good resistance to cavitation erosion, suggesting their potential as possible replacements for structural ceramics commonly employed components of hydraulic machinery.",
journal = "International Journal of Environmental Science and Technology",
title = "The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash",
doi = "10.1007/s13762-023-05411-9"
}
Savić, V., Dojčinović, M., Topalović, V., Cvijović-Alagić, I., Stojanović, J., Matijašević, S.,& Grujić, S.. (2024). The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash. in International Journal of Environmental Science and Technology.
https://doi.org/10.1007/s13762-023-05411-9
Savić V, Dojčinović M, Topalović V, Cvijović-Alagić I, Stojanović J, Matijašević S, Grujić S. The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash. in International Journal of Environmental Science and Technology. 2024;.
doi:10.1007/s13762-023-05411-9 .
Savić, Veljko, Dojčinović, M., Topalović, V., Cvijović-Alagić, Ivana, Stojanović, J., Matijašević, S., Grujić, S., "The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash" in International Journal of Environmental Science and Technology (2024),
https://doi.org/10.1007/s13762-023-05411-9 . .

Densification of additive-free B4C-SiC composites by spark plasma sintering

Matović, Branko; Tatarko, Peter; Maksimović, Vesna; Maletaškić, Jelena; Stoiljković, Milovan; Hanzel, Ondrej; Cvijović-Alagić, Ivana

(2023)

TY  - JOUR
AU  - Matović, Branko
AU  - Tatarko, Peter
AU  - Maksimović, Vesna
AU  - Maletaškić, Jelena
AU  - Stoiljković, Milovan
AU  - Hanzel, Ondrej
AU  - Cvijović-Alagić, Ivana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12284
AB  - The B4C-SiC composites were obtained through densification of B4C and β-SiC powders with different ratios using Spark Plasma Sintering (SPS). Thermal treatment was conducted in the 1850–2000 °C temperature range under pressure of 70 MPa. Starting powder ratio effect on sintering behavior, relative density, microstructural development, and mechanical properties of obtained composites was investigated. Results showed that only starting compounds were observed in sintered ceramics with uniformly distributed and densely compacted B4C and SiC grains. Maximal relative density (100 %) was achieved for 25 % B4C-75 % SiC sample densified at 2000 °C. Obtained composites' microhardness ranged from 33 to 43 GPa, depending on constituents' content and densification temperature. Maximal microhardness was achieved for composite with the maximal amount (75 %) of B4C densified at 2000 °C. Composites' behavior in extreme conditions was evaluated through their interactions with laser beam and obtained results showed that SPS is effective densification method for obtainment of additive-free B4C-SiC composites applicable in extreme radiation environments.
T2  - Journal of the European Ceramic Society
T1  - Densification of additive-free B4C-SiC composites by spark plasma sintering
IS  - InPress
DO  - 10.1016/j.jeurceramsoc.2023.12.024
ER  - 
@article{
author = "Matović, Branko and Tatarko, Peter and Maksimović, Vesna and Maletaškić, Jelena and Stoiljković, Milovan and Hanzel, Ondrej and Cvijović-Alagić, Ivana",
year = "2023",
abstract = "The B4C-SiC composites were obtained through densification of B4C and β-SiC powders with different ratios using Spark Plasma Sintering (SPS). Thermal treatment was conducted in the 1850–2000 °C temperature range under pressure of 70 MPa. Starting powder ratio effect on sintering behavior, relative density, microstructural development, and mechanical properties of obtained composites was investigated. Results showed that only starting compounds were observed in sintered ceramics with uniformly distributed and densely compacted B4C and SiC grains. Maximal relative density (100 %) was achieved for 25 % B4C-75 % SiC sample densified at 2000 °C. Obtained composites' microhardness ranged from 33 to 43 GPa, depending on constituents' content and densification temperature. Maximal microhardness was achieved for composite with the maximal amount (75 %) of B4C densified at 2000 °C. Composites' behavior in extreme conditions was evaluated through their interactions with laser beam and obtained results showed that SPS is effective densification method for obtainment of additive-free B4C-SiC composites applicable in extreme radiation environments.",
journal = "Journal of the European Ceramic Society",
title = "Densification of additive-free B4C-SiC composites by spark plasma sintering",
number = "InPress",
doi = "10.1016/j.jeurceramsoc.2023.12.024"
}
Matović, B., Tatarko, P., Maksimović, V., Maletaškić, J., Stoiljković, M., Hanzel, O.,& Cvijović-Alagić, I.. (2023). Densification of additive-free B4C-SiC composites by spark plasma sintering. in Journal of the European Ceramic Society(InPress).
https://doi.org/10.1016/j.jeurceramsoc.2023.12.024
Matović B, Tatarko P, Maksimović V, Maletaškić J, Stoiljković M, Hanzel O, Cvijović-Alagić I. Densification of additive-free B4C-SiC composites by spark plasma sintering. in Journal of the European Ceramic Society. 2023;(InPress).
doi:10.1016/j.jeurceramsoc.2023.12.024 .
Matović, Branko, Tatarko, Peter, Maksimović, Vesna, Maletaškić, Jelena, Stoiljković, Milovan, Hanzel, Ondrej, Cvijović-Alagić, Ivana, "Densification of additive-free B4C-SiC composites by spark plasma sintering" in Journal of the European Ceramic Society, no. InPress (2023),
https://doi.org/10.1016/j.jeurceramsoc.2023.12.024 . .
1

Multicomponent solid solution with pyrochlore structure

Matović, Branko; Maletaškić, Jelena; Maksimović, Vesna; Dimitrijević, Stevan P.; Todorović, Bratislav; Pejić, Milan; Zagorac, Dejan; Zagorac, Jelena B.; Zeng, Yu-Ping; Cvijović-Alagić, Ivana

(2023)

TY  - JOUR
AU  - Matović, Branko
AU  - Maletaškić, Jelena
AU  - Maksimović, Vesna
AU  - Dimitrijević, Stevan P.
AU  - Todorović, Bratislav
AU  - Pejić, Milan
AU  - Zagorac, Dejan
AU  - Zagorac, Jelena B.
AU  - Zeng, Yu-Ping
AU  - Cvijović-Alagić, Ivana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10697
AB  - Multicomponent oxide with pyrochlore structure (A2B2O7), containing 7 different A-site cations and 3 B-site cations in equiatomic amounts, was synthesized. Powders with nominal composition (La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 were fabricated through a reaction of metal nitrates (A-site) and metal chlorides (B-site) with sodium hydroxide during the solid state displacement reaction. Room temperature synthesis initially resulted in the obtainment of amorphous powders, which crystallized after subsequent calcination to form single crystalline compounds. Crystalline high-entropy ceramic powders formation took place at temperatures as low as 750 °C. During calcination, defective fluorite (F-A2B2O7) and crystal pyrochlore (Py-A2B2O7) structures coexist. A large number of cations induce the obtainment of stable high-entropy pyrochlores. Results showed that sintering at 1650 °C lead to pure crystalline single-phase pyrochlore formation. High-density ceramic, free of additives, was obtained after powders were compacted and subjected to pressureless sintering at 1650 °C. Multicomponent pyrochlore structure was investigated using the theoretical and experimental multi-methodological approach.
T2  - Boletin de la Sociedad Espanola de Ceramica y Vidrio
T1  - Multicomponent solid solution with pyrochlore structure
T1  - Solución sólida multicomponente con estructura de pirocloro
VL  - 62
IS  - 6
SP  - 515
EP  - 526
DO  - 10.1016/j.bsecv.2023.01.005
ER  - 
@article{
author = "Matović, Branko and Maletaškić, Jelena and Maksimović, Vesna and Dimitrijević, Stevan P. and Todorović, Bratislav and Pejić, Milan and Zagorac, Dejan and Zagorac, Jelena B. and Zeng, Yu-Ping and Cvijović-Alagić, Ivana",
year = "2023",
abstract = "Multicomponent oxide with pyrochlore structure (A2B2O7), containing 7 different A-site cations and 3 B-site cations in equiatomic amounts, was synthesized. Powders with nominal composition (La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 were fabricated through a reaction of metal nitrates (A-site) and metal chlorides (B-site) with sodium hydroxide during the solid state displacement reaction. Room temperature synthesis initially resulted in the obtainment of amorphous powders, which crystallized after subsequent calcination to form single crystalline compounds. Crystalline high-entropy ceramic powders formation took place at temperatures as low as 750 °C. During calcination, defective fluorite (F-A2B2O7) and crystal pyrochlore (Py-A2B2O7) structures coexist. A large number of cations induce the obtainment of stable high-entropy pyrochlores. Results showed that sintering at 1650 °C lead to pure crystalline single-phase pyrochlore formation. High-density ceramic, free of additives, was obtained after powders were compacted and subjected to pressureless sintering at 1650 °C. Multicomponent pyrochlore structure was investigated using the theoretical and experimental multi-methodological approach.",
journal = "Boletin de la Sociedad Espanola de Ceramica y Vidrio",
title = "Multicomponent solid solution with pyrochlore structure, Solución sólida multicomponente con estructura de pirocloro",
volume = "62",
number = "6",
pages = "515-526",
doi = "10.1016/j.bsecv.2023.01.005"
}
Matović, B., Maletaškić, J., Maksimović, V., Dimitrijević, S. P., Todorović, B., Pejić, M., Zagorac, D., Zagorac, J. B., Zeng, Y.,& Cvijović-Alagić, I.. (2023). Multicomponent solid solution with pyrochlore structure. in Boletin de la Sociedad Espanola de Ceramica y Vidrio, 62(6), 515-526.
https://doi.org/10.1016/j.bsecv.2023.01.005
Matović B, Maletaškić J, Maksimović V, Dimitrijević SP, Todorović B, Pejić M, Zagorac D, Zagorac JB, Zeng Y, Cvijović-Alagić I. Multicomponent solid solution with pyrochlore structure. in Boletin de la Sociedad Espanola de Ceramica y Vidrio. 2023;62(6):515-526.
doi:10.1016/j.bsecv.2023.01.005 .
Matović, Branko, Maletaškić, Jelena, Maksimović, Vesna, Dimitrijević, Stevan P., Todorović, Bratislav, Pejić, Milan, Zagorac, Dejan, Zagorac, Jelena B., Zeng, Yu-Ping, Cvijović-Alagić, Ivana, "Multicomponent solid solution with pyrochlore structure" in Boletin de la Sociedad Espanola de Ceramica y Vidrio, 62, no. 6 (2023):515-526,
https://doi.org/10.1016/j.bsecv.2023.01.005 . .
1

Heavily doped high-entropy A2B2O7 pyrochlore

Matović, Branko; Maletaškić, Jelena; Maksimović, Vesna; Zagorac, Jelena; Luković, Aleksa; Zeng, Yu-Ping; Cvijović-Alagić, Ivana

(2023)

TY  - JOUR
AU  - Matović, Branko
AU  - Maletaškić, Jelena
AU  - Maksimović, Vesna
AU  - Zagorac, Jelena
AU  - Luković, Aleksa
AU  - Zeng, Yu-Ping
AU  - Cvijović-Alagić, Ivana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11324
AB  - A novel class of high-entropy pyrochlore compounds with multiple elements at the A and B site positions (A2B2O7) was successfully obtained. Powders with (La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 nominal composition were fabricated from pure metal oxides obtained through a reaction of metal nitrates (for site A) and metal chlorides (for site B) with sodium hydroxide during the solid-state displacement reaction (SSDR). The phase evolution was analyzed using XRD method. During the thermal treatment of ten individual metal oxides, the single pyrochlore phase was created. The present study showed that the highdensity (98%TD) ceramics with a hardness of 8.1GPa was successfully obtained after pressureless sintering at 1650 °C for 4 h. Results of the Raman study and the Rietveld structural refinement showed that sintered highentropy ceramics is characterized by a single-phase pyrochlore structure, which was investigated in detail.
T2  - Processing and Application of Ceramics
T1  - Heavily doped high-entropy A2B2O7 pyrochlore
VL  - 17
IS  - 2
SP  - 113
EP  - 117
DO  - 10.2298/PAC2302113M
ER  - 
@article{
author = "Matović, Branko and Maletaškić, Jelena and Maksimović, Vesna and Zagorac, Jelena and Luković, Aleksa and Zeng, Yu-Ping and Cvijović-Alagić, Ivana",
year = "2023",
abstract = "A novel class of high-entropy pyrochlore compounds with multiple elements at the A and B site positions (A2B2O7) was successfully obtained. Powders with (La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 nominal composition were fabricated from pure metal oxides obtained through a reaction of metal nitrates (for site A) and metal chlorides (for site B) with sodium hydroxide during the solid-state displacement reaction (SSDR). The phase evolution was analyzed using XRD method. During the thermal treatment of ten individual metal oxides, the single pyrochlore phase was created. The present study showed that the highdensity (98%TD) ceramics with a hardness of 8.1GPa was successfully obtained after pressureless sintering at 1650 °C for 4 h. Results of the Raman study and the Rietveld structural refinement showed that sintered highentropy ceramics is characterized by a single-phase pyrochlore structure, which was investigated in detail.",
journal = "Processing and Application of Ceramics",
title = "Heavily doped high-entropy A2B2O7 pyrochlore",
volume = "17",
number = "2",
pages = "113-117",
doi = "10.2298/PAC2302113M"
}
Matović, B., Maletaškić, J., Maksimović, V., Zagorac, J., Luković, A., Zeng, Y.,& Cvijović-Alagić, I.. (2023). Heavily doped high-entropy A2B2O7 pyrochlore. in Processing and Application of Ceramics, 17(2), 113-117.
https://doi.org/10.2298/PAC2302113M
Matović B, Maletaškić J, Maksimović V, Zagorac J, Luković A, Zeng Y, Cvijović-Alagić I. Heavily doped high-entropy A2B2O7 pyrochlore. in Processing and Application of Ceramics. 2023;17(2):113-117.
doi:10.2298/PAC2302113M .
Matović, Branko, Maletaškić, Jelena, Maksimović, Vesna, Zagorac, Jelena, Luković, Aleksa, Zeng, Yu-Ping, Cvijović-Alagić, Ivana, "Heavily doped high-entropy A2B2O7 pyrochlore" in Processing and Application of Ceramics, 17, no. 2 (2023):113-117,
https://doi.org/10.2298/PAC2302113M . .

Characterization of High-Entropy A2B2O7 Pyrochlore Obtained via Combustion Synthesis and Post-Calcination

Matović, Branko; Maletaškić, Jelena; Maksimović, Vesna; Dimitrijević, Silvana; Todorović, Branislav; Zagorac, Jelena; Zeng, Yu-Ping; Cvijović-Alagić, Ivana

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2023)

TY  - CONF
AU  - Matović, Branko
AU  - Maletaškić, Jelena
AU  - Maksimović, Vesna
AU  - Dimitrijević, Silvana
AU  - Todorović, Branislav
AU  - Zagorac, Jelena
AU  - Zeng, Yu-Ping
AU  - Cvijović-Alagić, Ivana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11346
AB  - The goal of this research was to obtain a chemically complex multicomponent
oxide with the A2B2O7 pyrochlore structure with nominal composition
(La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 that contains 10 different
cations in equiatomic amounts which was obtained by reacting metal nitrates (site
A) and metal chlorides (site B) with glycine during the combustion reaction. The
powder synthesized initially was found to be amorphous based on XRD analysis. To
convert the powder into a crystalline pyrochlore structure, the powder underwent
post-calcination at various temperatures ranging from 600–1500 °C. It was
discovered that the desired monophase pyrochlore structure (A2B2O7) was obtained
after calcination at 900 °C. To create a high-density ceramic pellet, the powder
calcined at 900 °C was subjected to pressureless sintering at 1650 °C for four hours
in the presence of air. The resulting pellet had a density of 97% of the theoretical
density and was free from any additives. This process likely caused the powder
particles to fuse together, creating a solid, dense pellet.
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
T1  - Characterization of High-Entropy A2B2O7 Pyrochlore Obtained via Combustion Synthesis and Post-Calcination
SP  - 84
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11346
ER  - 
@conference{
author = "Matović, Branko and Maletaškić, Jelena and Maksimović, Vesna and Dimitrijević, Silvana and Todorović, Branislav and Zagorac, Jelena and Zeng, Yu-Ping and Cvijović-Alagić, Ivana",
year = "2023",
abstract = "The goal of this research was to obtain a chemically complex multicomponent
oxide with the A2B2O7 pyrochlore structure with nominal composition
(La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 that contains 10 different
cations in equiatomic amounts which was obtained by reacting metal nitrates (site
A) and metal chlorides (site B) with glycine during the combustion reaction. The
powder synthesized initially was found to be amorphous based on XRD analysis. To
convert the powder into a crystalline pyrochlore structure, the powder underwent
post-calcination at various temperatures ranging from 600–1500 °C. It was
discovered that the desired monophase pyrochlore structure (A2B2O7) was obtained
after calcination at 900 °C. To create a high-density ceramic pellet, the powder
calcined at 900 °C was subjected to pressureless sintering at 1650 °C for four hours
in the presence of air. The resulting pellet had a density of 97% of the theoretical
density and was free from any additives. This process likely caused the powder
particles to fuse together, creating a solid, dense pellet.",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts",
title = "Characterization of High-Entropy A2B2O7 Pyrochlore Obtained via Combustion Synthesis and Post-Calcination",
pages = "84",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11346"
}
Matović, B., Maletaškić, J., Maksimović, V., Dimitrijević, S., Todorović, B., Zagorac, J., Zeng, Y.,& Cvijović-Alagić, I.. (2023). Characterization of High-Entropy A2B2O7 Pyrochlore Obtained via Combustion Synthesis and Post-Calcination. in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 84.
https://hdl.handle.net/21.15107/rcub_vinar_11346
Matović B, Maletaškić J, Maksimović V, Dimitrijević S, Todorović B, Zagorac J, Zeng Y, Cvijović-Alagić I. Characterization of High-Entropy A2B2O7 Pyrochlore Obtained via Combustion Synthesis and Post-Calcination. in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts. 2023;:84.
https://hdl.handle.net/21.15107/rcub_vinar_11346 .
Matović, Branko, Maletaškić, Jelena, Maksimović, Vesna, Dimitrijević, Silvana, Todorović, Branislav, Zagorac, Jelena, Zeng, Yu-Ping, Cvijović-Alagić, Ivana, "Characterization of High-Entropy A2B2O7 Pyrochlore Obtained via Combustion Synthesis and Post-Calcination" in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts (2023):84,
https://hdl.handle.net/21.15107/rcub_vinar_11346 .

Synthesis and characterization of high-entropy A2B2O7 pyrochlore with multiple elements at A and B sites

Matović, Branko; Maletaškić, Jelena; Maksimović, Vesna; Dimitrijević, Silvana; Todorović, Bratislav; Zagorac, Jelena; Luković, Aleksa; Zeng, Yu-Ping; Cvijović-Alagić, Ivana

(2023)

TY  - JOUR
AU  - Matović, Branko
AU  - Maletaškić, Jelena
AU  - Maksimović, Vesna
AU  - Dimitrijević, Silvana
AU  - Todorović, Bratislav
AU  - Zagorac, Jelena
AU  - Luković, Aleksa
AU  - Zeng, Yu-Ping
AU  - Cvijović-Alagić, Ivana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11350
AB  - Single nano high-entropy pyrochlore-type compound (A2B2O7) with 7 different
rare-earth cations at site A and 3 different metal cations at site B with equiatomic
amounts (7A1/7)2(3B1/3)2O7 is successfully obtained. The powder with nominal
composition (La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 was fabricated by
reacting metal nitrates (site A) and metal chlorides (site B) with glycine during the
combustion reaction. The XRD analysis revealed that the powder attained during
synthesis is in an amorphous state. To induce crystallization of the obtained pyrochlore structure, the post-calcination process at 600-1500 °C was conducted and studied.
Results of this study showed that the monophase pyrochlore (A2B2O7) structure is
obtained during the calcination at 900 °C. The high-density ceramic pellet with 97% of
theoretical density and free of any additives was obtained through pressureless sintering
at 1650 °C for 4 h in the air using the powder calcined at 900 °C.
T2  - Science of Sintering
T1  - Synthesis and characterization of high-entropy A2B2O7 pyrochlore with multiple elements at A and B sites
IS  - InPress
SP  - 23
DO  - 10.2298/SOS220802023M
ER  - 
@article{
author = "Matović, Branko and Maletaškić, Jelena and Maksimović, Vesna and Dimitrijević, Silvana and Todorović, Bratislav and Zagorac, Jelena and Luković, Aleksa and Zeng, Yu-Ping and Cvijović-Alagić, Ivana",
year = "2023",
abstract = "Single nano high-entropy pyrochlore-type compound (A2B2O7) with 7 different
rare-earth cations at site A and 3 different metal cations at site B with equiatomic
amounts (7A1/7)2(3B1/3)2O7 is successfully obtained. The powder with nominal
composition (La1/7Sm1/7Nd1/7Pr1/7Y1/7Gd1/7Yb1/7)2(Sn1/3Hf1/3Zr1/3)2O7 was fabricated by
reacting metal nitrates (site A) and metal chlorides (site B) with glycine during the
combustion reaction. The XRD analysis revealed that the powder attained during
synthesis is in an amorphous state. To induce crystallization of the obtained pyrochlore structure, the post-calcination process at 600-1500 °C was conducted and studied.
Results of this study showed that the monophase pyrochlore (A2B2O7) structure is
obtained during the calcination at 900 °C. The high-density ceramic pellet with 97% of
theoretical density and free of any additives was obtained through pressureless sintering
at 1650 °C for 4 h in the air using the powder calcined at 900 °C.",
journal = "Science of Sintering",
title = "Synthesis and characterization of high-entropy A2B2O7 pyrochlore with multiple elements at A and B sites",
number = "InPress",
pages = "23",
doi = "10.2298/SOS220802023M"
}
Matović, B., Maletaškić, J., Maksimović, V., Dimitrijević, S., Todorović, B., Zagorac, J., Luković, A., Zeng, Y.,& Cvijović-Alagić, I.. (2023). Synthesis and characterization of high-entropy A2B2O7 pyrochlore with multiple elements at A and B sites. in Science of Sintering(InPress), 23.
https://doi.org/10.2298/SOS220802023M
Matović B, Maletaškić J, Maksimović V, Dimitrijević S, Todorović B, Zagorac J, Luković A, Zeng Y, Cvijović-Alagić I. Synthesis and characterization of high-entropy A2B2O7 pyrochlore with multiple elements at A and B sites. in Science of Sintering. 2023;(InPress):23.
doi:10.2298/SOS220802023M .
Matović, Branko, Maletaškić, Jelena, Maksimović, Vesna, Dimitrijević, Silvana, Todorović, Bratislav, Zagorac, Jelena, Luković, Aleksa, Zeng, Yu-Ping, Cvijović-Alagić, Ivana, "Synthesis and characterization of high-entropy A2B2O7 pyrochlore with multiple elements at A and B sites" in Science of Sintering, no. InPress (2023):23,
https://doi.org/10.2298/SOS220802023M . .

Fabrication and characterization of high entropy pyrochlore ceramics

Matović, Branko; Zagorac, Dejan; Cvijović-Alagić, Ivana; Zagorac, Jelena B.; Butulija, Svetlana; Erčić, Jelena; Hanzel, Ondrej; Sedlák, Richard; Lisnichuk, Maksym; Tatarko, Peter

(2023)

TY  - JOUR
AU  - Matović, Branko
AU  - Zagorac, Dejan
AU  - Cvijović-Alagić, Ivana
AU  - Zagorac, Jelena B.
AU  - Butulija, Svetlana
AU  - Erčić, Jelena
AU  - Hanzel, Ondrej
AU  - Sedlák, Richard
AU  - Lisnichuk, Maksym
AU  - Tatarko, Peter
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10083
AB  - High-entropy rare-earth (RE) zirconates with pyrochlore structure were successfully fabricated by pressureless and spark plasma sintering. RE2Zr2O7 compound with nominal composition (La0.2Y0.2Gd0.2Nd0.2Sm0.2)Zr2O7 was prepared by simple glycine nitrate procedure (GNP). GNP process yielded powders with low crystallinity and after subsequent calcination, well crystalline ceramics were formed. During calcination defective fluorite (F-RE2Zr2O7) and crystal pyrochlore (Py-RE2Zr2O7) structures coexist. Formation of pure crystalline pyrochlore occurs after sintering at 1450°C. High-density ceramics, free of any additives, were obtained after powders compaction and pressureless (PS), as well as field assisted sintering technique (FAST) at 1450°C. Theoretical investigations of the high-entropy RE2Zr2O7 pyrochlore systems were performed. Unit cell parameter of the obtained Py-RE2Zr2O7 is 10.5892(2)Å and 10.5999(2)Å for PS and FAST sintering, respectively, which is in good agreement with the results of Density Functional Theory (DFT) calculations. The thermal diffusivity of sintered samples at room temperature was ∼0.7mm2/s for both sintering methods.ResumenSe fabricaron con éxito, mediante sinterización por plasma sin presión y por chispa, los circonatos de tierras raras (RE) de alta entropía con estructura de pirocloro. El compuesto RE2Zr2O7 con composición nominal (La0,2Y0,2Gd0,2Nd0,2Sm0,2)Zr2O7 se preparó mediante un procedimiento simple de nitrato de glicina (GNP). El proceso GNP produjo polvos con baja cristalinidad y después de la posterior calcinación, se formaron cerámicas bien cristalinas. Durante la calcinación coexisten estructuras defectuosas de fluorita (F-RE2Zr2O7) y pirocloro cristalino (Py-RE2Zr2O7). La formación de pirocloro cristalino puro se produce después de la sinterización a 1.450°C. Después de la compactación de polvos y sin presión (PS), así como por la técnica de sinterización asistida en campo (FAST) a 1.450 oC, se obtuvieron cerámicas de alta densidad, libres de aditivos. Se realizaron investigaciones teóricas de los sistemas de pirocloro RE2Zr2O7 de alta entropía. El parámetro de celda unitaria del Py-RE2Zr2O7 obtenido es 105.892(2) Å y 105.999(2) Å para la sinterización PS y FAST, respectivamente, lo que está de acuerdo con los resultados de los cálculos de la teoría funcional de la densidad (DFT). La difusividad térmica de las muestras sinterizadas a temperatura ambiente fue de ∼ 0,7 mm2/s para ambos métodos de sinterización.
T2  - Boletín de la Sociedad Española de Cerámica y Vidrio
T1  - Fabrication and characterization of high entropy pyrochlore ceramics
T1  - Fabricación y caracterización de cerámicas de pirocloro de alta entropía
VL  - 62
IS  - 1
SP  - 66
EP  - 76
DO  - 10.1016/j.bsecv.2021.11.002
ER  - 
@article{
author = "Matović, Branko and Zagorac, Dejan and Cvijović-Alagić, Ivana and Zagorac, Jelena B. and Butulija, Svetlana and Erčić, Jelena and Hanzel, Ondrej and Sedlák, Richard and Lisnichuk, Maksym and Tatarko, Peter",
year = "2023",
abstract = "High-entropy rare-earth (RE) zirconates with pyrochlore structure were successfully fabricated by pressureless and spark plasma sintering. RE2Zr2O7 compound with nominal composition (La0.2Y0.2Gd0.2Nd0.2Sm0.2)Zr2O7 was prepared by simple glycine nitrate procedure (GNP). GNP process yielded powders with low crystallinity and after subsequent calcination, well crystalline ceramics were formed. During calcination defective fluorite (F-RE2Zr2O7) and crystal pyrochlore (Py-RE2Zr2O7) structures coexist. Formation of pure crystalline pyrochlore occurs after sintering at 1450°C. High-density ceramics, free of any additives, were obtained after powders compaction and pressureless (PS), as well as field assisted sintering technique (FAST) at 1450°C. Theoretical investigations of the high-entropy RE2Zr2O7 pyrochlore systems were performed. Unit cell parameter of the obtained Py-RE2Zr2O7 is 10.5892(2)Å and 10.5999(2)Å for PS and FAST sintering, respectively, which is in good agreement with the results of Density Functional Theory (DFT) calculations. The thermal diffusivity of sintered samples at room temperature was ∼0.7mm2/s for both sintering methods.ResumenSe fabricaron con éxito, mediante sinterización por plasma sin presión y por chispa, los circonatos de tierras raras (RE) de alta entropía con estructura de pirocloro. El compuesto RE2Zr2O7 con composición nominal (La0,2Y0,2Gd0,2Nd0,2Sm0,2)Zr2O7 se preparó mediante un procedimiento simple de nitrato de glicina (GNP). El proceso GNP produjo polvos con baja cristalinidad y después de la posterior calcinación, se formaron cerámicas bien cristalinas. Durante la calcinación coexisten estructuras defectuosas de fluorita (F-RE2Zr2O7) y pirocloro cristalino (Py-RE2Zr2O7). La formación de pirocloro cristalino puro se produce después de la sinterización a 1.450°C. Después de la compactación de polvos y sin presión (PS), así como por la técnica de sinterización asistida en campo (FAST) a 1.450 oC, se obtuvieron cerámicas de alta densidad, libres de aditivos. Se realizaron investigaciones teóricas de los sistemas de pirocloro RE2Zr2O7 de alta entropía. El parámetro de celda unitaria del Py-RE2Zr2O7 obtenido es 105.892(2) Å y 105.999(2) Å para la sinterización PS y FAST, respectivamente, lo que está de acuerdo con los resultados de los cálculos de la teoría funcional de la densidad (DFT). La difusividad térmica de las muestras sinterizadas a temperatura ambiente fue de ∼ 0,7 mm2/s para ambos métodos de sinterización.",
journal = "Boletín de la Sociedad Española de Cerámica y Vidrio",
title = "Fabrication and characterization of high entropy pyrochlore ceramics, Fabricación y caracterización de cerámicas de pirocloro de alta entropía",
volume = "62",
number = "1",
pages = "66-76",
doi = "10.1016/j.bsecv.2021.11.002"
}
Matović, B., Zagorac, D., Cvijović-Alagić, I., Zagorac, J. B., Butulija, S., Erčić, J., Hanzel, O., Sedlák, R., Lisnichuk, M.,& Tatarko, P.. (2023). Fabrication and characterization of high entropy pyrochlore ceramics. in Boletín de la Sociedad Española de Cerámica y Vidrio, 62(1), 66-76.
https://doi.org/10.1016/j.bsecv.2021.11.002
Matović B, Zagorac D, Cvijović-Alagić I, Zagorac JB, Butulija S, Erčić J, Hanzel O, Sedlák R, Lisnichuk M, Tatarko P. Fabrication and characterization of high entropy pyrochlore ceramics. in Boletín de la Sociedad Española de Cerámica y Vidrio. 2023;62(1):66-76.
doi:10.1016/j.bsecv.2021.11.002 .
Matović, Branko, Zagorac, Dejan, Cvijović-Alagić, Ivana, Zagorac, Jelena B., Butulija, Svetlana, Erčić, Jelena, Hanzel, Ondrej, Sedlák, Richard, Lisnichuk, Maksym, Tatarko, Peter, "Fabrication and characterization of high entropy pyrochlore ceramics" in Boletín de la Sociedad Española de Cerámica y Vidrio, 62, no. 1 (2023):66-76,
https://doi.org/10.1016/j.bsecv.2021.11.002 . .
11
6

Laser-modified Ti-45Nb alloy’s response to bio-environment

Cvijović-Alagić, Ivana; Laketić, Slađana; Momčilović, M.; Ciganović, Jovan; Veljović, Đorđe; Bajat, Jelena; Kojić, Vesna; Rakin, Marko

(Slovak Republic : Institute of Inorganic Chemistry, SAS, 2023)

TY  - CONF
AU  - Cvijović-Alagić, Ivana
AU  - Laketić, Slađana
AU  - Momčilović, M.
AU  - Ciganović, Jovan
AU  - Veljović, Đorđe
AU  - Bajat, Jelena
AU  - Kojić, Vesna
AU  - Rakin, Marko
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11343
AB  - Modern hard tissue replacements, used in orthopedic and dental surgery, are most commonly produced using commercially pure titanium (CP-Ti) and the (α+β) Ti-based alloys since their biomechanical compatibility is superior in comparison to other metallic biomaterials. However, these materials are still unable to meet all implantation requirements primarily due to their somewhat limited resistance to degradation in harsh bio-environment and/or presence of cytotoxic elements in their composition that can cause adverse health effects. Therefore, the potential biomedical application of the β-type Ti alloys, which contain non-toxic elements, is considered since these alloys can exhibit lower elastic modulus and improved biocompatibility compared with other Ti-based materials. The β-type Ti-45Nb (wt%) alloy shows significant potential for application as hard tissue implant material. Nevertheless, an additional improvement of its response in the bio-environment is necessary to maximize its medical applicability. Modification of the alloy’s microstructural and surface characteristics through the careful selection of the appropriate processing parameters can ensure the obtainment of favorable alloy biocompatible properties. High-pressure torsion (HPT), as a processing method for the obtainment of ultra-fine grained (UFG) microstructure with higher compatibility with biological systems, and laser surface scanning, as an easy-to-apply surface modification technique for the obtainment of developed bio-active surface, are singled-out as potential methods for the attainment of more durable orthopedic and dental implants. Having all this in mind, the present research aimed to attain improved corrosive and biocompatible response of the Ti-45Nb alloy in simulated physiological conditions through the alloy grain refinement and the formation of protective surface scales by the alloy combined HPT and laser irradiation processing. For that purpose, the alloy microstructural, electrochemical, and in vitro testing were conducted before and after its additional processing. Attained results indicated that the achieved grain size reduction from 2.76 µm to ~200 nm during HPT processing and the appearance of laser-induced morphologically altered and highly oxidized surface led to the significant improvement of the alloy corrosion resistance and the cellsimplant interaction. Moreover, an additional increase of the laser pulse energy from 5 mJ to 15 mJ during the alloy irradiation in air led to an increase in oxygen content at the alloy surface from 13.64% to 23.89% accompanied by an increase of cell viability from excellent 127.18% to superior 134.42%. Furthermore, as a result of the controlled alloy microstructural and surface morphological and chemical modifications, the formation of a thick, compact and protective bi-modal external scale, composed of mixed Ti- and Nboxides, was enabled in the simulated body conditions. Presence of this surface oxide scale, which consists of inner barrier and outer porous layer, enhanced the alloy’s resistance to corrosion deterioration and simultaneously boosted the cell viability and proliferation. Results of the present study showed that the additional HPT and laser surface processing can be successfully utilized to improve the biometallic’s response to a bio-environment
PB  - Slovak Republic : Institute of Inorganic Chemistry, SAS
C3  - EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics
T1  - Laser-modified Ti-45Nb alloy’s response to bio-environment
SP  - 12
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11343
ER  - 
@conference{
author = "Cvijović-Alagić, Ivana and Laketić, Slađana and Momčilović, M. and Ciganović, Jovan and Veljović, Đorđe and Bajat, Jelena and Kojić, Vesna and Rakin, Marko",
year = "2023",
abstract = "Modern hard tissue replacements, used in orthopedic and dental surgery, are most commonly produced using commercially pure titanium (CP-Ti) and the (α+β) Ti-based alloys since their biomechanical compatibility is superior in comparison to other metallic biomaterials. However, these materials are still unable to meet all implantation requirements primarily due to their somewhat limited resistance to degradation in harsh bio-environment and/or presence of cytotoxic elements in their composition that can cause adverse health effects. Therefore, the potential biomedical application of the β-type Ti alloys, which contain non-toxic elements, is considered since these alloys can exhibit lower elastic modulus and improved biocompatibility compared with other Ti-based materials. The β-type Ti-45Nb (wt%) alloy shows significant potential for application as hard tissue implant material. Nevertheless, an additional improvement of its response in the bio-environment is necessary to maximize its medical applicability. Modification of the alloy’s microstructural and surface characteristics through the careful selection of the appropriate processing parameters can ensure the obtainment of favorable alloy biocompatible properties. High-pressure torsion (HPT), as a processing method for the obtainment of ultra-fine grained (UFG) microstructure with higher compatibility with biological systems, and laser surface scanning, as an easy-to-apply surface modification technique for the obtainment of developed bio-active surface, are singled-out as potential methods for the attainment of more durable orthopedic and dental implants. Having all this in mind, the present research aimed to attain improved corrosive and biocompatible response of the Ti-45Nb alloy in simulated physiological conditions through the alloy grain refinement and the formation of protective surface scales by the alloy combined HPT and laser irradiation processing. For that purpose, the alloy microstructural, electrochemical, and in vitro testing were conducted before and after its additional processing. Attained results indicated that the achieved grain size reduction from 2.76 µm to ~200 nm during HPT processing and the appearance of laser-induced morphologically altered and highly oxidized surface led to the significant improvement of the alloy corrosion resistance and the cellsimplant interaction. Moreover, an additional increase of the laser pulse energy from 5 mJ to 15 mJ during the alloy irradiation in air led to an increase in oxygen content at the alloy surface from 13.64% to 23.89% accompanied by an increase of cell viability from excellent 127.18% to superior 134.42%. Furthermore, as a result of the controlled alloy microstructural and surface morphological and chemical modifications, the formation of a thick, compact and protective bi-modal external scale, composed of mixed Ti- and Nboxides, was enabled in the simulated body conditions. Presence of this surface oxide scale, which consists of inner barrier and outer porous layer, enhanced the alloy’s resistance to corrosion deterioration and simultaneously boosted the cell viability and proliferation. Results of the present study showed that the additional HPT and laser surface processing can be successfully utilized to improve the biometallic’s response to a bio-environment",
publisher = "Slovak Republic : Institute of Inorganic Chemistry, SAS",
journal = "EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics",
title = "Laser-modified Ti-45Nb alloy’s response to bio-environment",
pages = "12",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11343"
}
Cvijović-Alagić, I., Laketić, S., Momčilović, M., Ciganović, J., Veljović, Đ., Bajat, J., Kojić, V.,& Rakin, M.. (2023). Laser-modified Ti-45Nb alloy’s response to bio-environment. in EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics
Slovak Republic : Institute of Inorganic Chemistry, SAS., 12.
https://hdl.handle.net/21.15107/rcub_vinar_11343
Cvijović-Alagić I, Laketić S, Momčilović M, Ciganović J, Veljović Đ, Bajat J, Kojić V, Rakin M. Laser-modified Ti-45Nb alloy’s response to bio-environment. in EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics. 2023;:12.
https://hdl.handle.net/21.15107/rcub_vinar_11343 .
Cvijović-Alagić, Ivana, Laketić, Slađana, Momčilović, M., Ciganović, Jovan, Veljović, Đorđe, Bajat, Jelena, Kojić, Vesna, Rakin, Marko, "Laser-modified Ti-45Nb alloy’s response to bio-environment" in EngCer 2023 : The Advanced Research Workshop: Engineering Ceramics (2023):12,
https://hdl.handle.net/21.15107/rcub_vinar_11343 .

Novel basalt-stainless steel composite materials with improved fracture toughness

Pavkov, Vladimir; Bakić, Gordana; Maksimović, Vesna; Cvijović-Alagić, Ivana; Bučevac, Dušan; Matović, Branko

(2023)

TY  - JOUR
AU  - Pavkov, Vladimir
AU  - Bakić, Gordana
AU  - Maksimović, Vesna
AU  - Cvijović-Alagić, Ivana
AU  - Bučevac, Dušan
AU  - Matović, Branko
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11323
AB  - This paper presents the technological process for obtaining basalt-stainless steel composite materials and testing their physical and mechanical properties. The phases of the technological process consist of: milling, homogenization, pressing, and sintering to obtain composite materials with improved fracture toughness. Andesite basalt from the deposit site "Donje Jarinje", Serbia, was used as a matrix in the composites, while commercial austenitic stainless steel 316L in the amount of 0-30 wt.% was used as a reinforcement. Although the increase of 316L amount caused a continuous decrease in the relative density of sintered samples, the relative density of sample containing 30 wt.% of 316L was above 94%. The 316L grains, which possess a larger coefficient of thermal expansion than the basalt matrix, shrinking faster during cooling from sintering temperature resulting in the formation of compressive residual stress in the basalt matrix surrounding the spherical steel grains. The presence of this stress activated toughening mechanisms such as crack deflection and toughening due to compressive residual stress. The addition of 20 wt.% of reinforcing 316L particles increased the fracture toughness of basalt by more than 30%. The relative density of these samples was measured to be 97%, whereas macrohardness was found to be 6.2 GPa.
T2  - Science of Sintering
T1  - Novel basalt-stainless steel composite materials with improved fracture toughness
VL  - 55
IS  - 2
SP  - 145
EP  - 158
DO  - 10.2298/SOS220429002P
ER  - 
@article{
author = "Pavkov, Vladimir and Bakić, Gordana and Maksimović, Vesna and Cvijović-Alagić, Ivana and Bučevac, Dušan and Matović, Branko",
year = "2023",
abstract = "This paper presents the technological process for obtaining basalt-stainless steel composite materials and testing their physical and mechanical properties. The phases of the technological process consist of: milling, homogenization, pressing, and sintering to obtain composite materials with improved fracture toughness. Andesite basalt from the deposit site "Donje Jarinje", Serbia, was used as a matrix in the composites, while commercial austenitic stainless steel 316L in the amount of 0-30 wt.% was used as a reinforcement. Although the increase of 316L amount caused a continuous decrease in the relative density of sintered samples, the relative density of sample containing 30 wt.% of 316L was above 94%. The 316L grains, which possess a larger coefficient of thermal expansion than the basalt matrix, shrinking faster during cooling from sintering temperature resulting in the formation of compressive residual stress in the basalt matrix surrounding the spherical steel grains. The presence of this stress activated toughening mechanisms such as crack deflection and toughening due to compressive residual stress. The addition of 20 wt.% of reinforcing 316L particles increased the fracture toughness of basalt by more than 30%. The relative density of these samples was measured to be 97%, whereas macrohardness was found to be 6.2 GPa.",
journal = "Science of Sintering",
title = "Novel basalt-stainless steel composite materials with improved fracture toughness",
volume = "55",
number = "2",
pages = "145-158",
doi = "10.2298/SOS220429002P"
}
Pavkov, V., Bakić, G., Maksimović, V., Cvijović-Alagić, I., Bučevac, D.,& Matović, B.. (2023). Novel basalt-stainless steel composite materials with improved fracture toughness. in Science of Sintering, 55(2), 145-158.
https://doi.org/10.2298/SOS220429002P
Pavkov V, Bakić G, Maksimović V, Cvijović-Alagić I, Bučevac D, Matović B. Novel basalt-stainless steel composite materials with improved fracture toughness. in Science of Sintering. 2023;55(2):145-158.
doi:10.2298/SOS220429002P .
Pavkov, Vladimir, Bakić, Gordana, Maksimović, Vesna, Cvijović-Alagić, Ivana, Bučevac, Dušan, Matović, Branko, "Novel basalt-stainless steel composite materials with improved fracture toughness" in Science of Sintering, 55, no. 2 (2023):145-158,
https://doi.org/10.2298/SOS220429002P . .

Microstructure, hardness and fracture resistance of P235TR1 seam steel pipes of different diameters

Musrati, Walid; Međo, Bojan; Cvijović-Alagić, Ivana; Gubeljak, Nenad; Štefane, Primož; Radosavljević, Zoran; Rakin, Marko

(2023)

TY  - JOUR
AU  - Musrati, Walid
AU  - Međo, Bojan
AU  - Cvijović-Alagić, Ivana
AU  - Gubeljak, Nenad
AU  - Štefane, Primož
AU  - Radosavljević, Zoran
AU  - Rakin, Marko
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11325
AB  - Steel pipelines in industrial plants consist of different elements, including seamless and/or welded (seam) pipes. Properties of welded pipes, including their fracture behaviour, depend on the characteristics of both, the base metal, and the weld metal. In this work, two seam pipes are considered having different diameters and manufactured of P235TR1 steel. Hardness and microstructure were examined on the samples which contained the seam zone, to capture the influence of heterogeneity. Fracture resistance of the pipeline material, i.e. of both base metals and both seams, was determined by experimental examination of the recently proposed Pipe ring notch bending specimens with sharp stress concentrators. Differences between the two tested pipes, including the influence of the heterogeneity caused by the welded joint, were determined by comparison of the crack growth resistance curves. Effects of the initial stress concentrator shape, sharp machined notch or fatigue pre-crack are discussed.
AB  - Čelični cevovodi u industrijskim postrojenjima se sastoje od različitih elemenata, uključujući bešavne i/ili zavarene (šavne) cevi. Osobine šavnih cevi, uključujući ponašanje materijala cevi pri lomu, zavise i od osnovnog metala i od metala šava. U ovom radu razmatrane su dve šavne cevi različitih prečnika, izrađene od čelika P235TR1. Tvrdoća i mikrostruktura su analizirane na uzorcima isečenim iz cevi u zoni šava, da bi se odredio uticaj heterogenosti. Otpornost prema lomu materijala cevovoda, tj. oba osnovna metala i oba šava, je određena na osnovu ispitivanja epruveta oblika prstena sa oštrim koncentratorima napona, predloženih u prethodnim studijama. Poređenjem krivih otpornosti prema rastu prsline određene su razlike između dve ispitivane cevi, kao i uticaj heterogenosti izazvan postojanjem zavarenog spoja. Razmotren je uticaj oblika početnog koncentratora napona, oštrog žleba odnosno zamorne početne prsline.
T2  - Hemijska industrija
T1  - Microstructure, hardness and fracture resistance of P235TR1 seam steel pipes of different diameters
T1  - Otpornost prema lomu, tvrdoća i mikrostruktura šavnih cevi različitog prečnika izrađenih od čelika P235TR1
VL  - 77
IS  - 2
SP  - 155
EP  - 165
DO  - 10.2298/HEMIND230222016M
ER  - 
@article{
author = "Musrati, Walid and Međo, Bojan and Cvijović-Alagić, Ivana and Gubeljak, Nenad and Štefane, Primož and Radosavljević, Zoran and Rakin, Marko",
year = "2023",
abstract = "Steel pipelines in industrial plants consist of different elements, including seamless and/or welded (seam) pipes. Properties of welded pipes, including their fracture behaviour, depend on the characteristics of both, the base metal, and the weld metal. In this work, two seam pipes are considered having different diameters and manufactured of P235TR1 steel. Hardness and microstructure were examined on the samples which contained the seam zone, to capture the influence of heterogeneity. Fracture resistance of the pipeline material, i.e. of both base metals and both seams, was determined by experimental examination of the recently proposed Pipe ring notch bending specimens with sharp stress concentrators. Differences between the two tested pipes, including the influence of the heterogeneity caused by the welded joint, were determined by comparison of the crack growth resistance curves. Effects of the initial stress concentrator shape, sharp machined notch or fatigue pre-crack are discussed., Čelični cevovodi u industrijskim postrojenjima se sastoje od različitih elemenata, uključujući bešavne i/ili zavarene (šavne) cevi. Osobine šavnih cevi, uključujući ponašanje materijala cevi pri lomu, zavise i od osnovnog metala i od metala šava. U ovom radu razmatrane su dve šavne cevi različitih prečnika, izrađene od čelika P235TR1. Tvrdoća i mikrostruktura su analizirane na uzorcima isečenim iz cevi u zoni šava, da bi se odredio uticaj heterogenosti. Otpornost prema lomu materijala cevovoda, tj. oba osnovna metala i oba šava, je određena na osnovu ispitivanja epruveta oblika prstena sa oštrim koncentratorima napona, predloženih u prethodnim studijama. Poređenjem krivih otpornosti prema rastu prsline određene su razlike između dve ispitivane cevi, kao i uticaj heterogenosti izazvan postojanjem zavarenog spoja. Razmotren je uticaj oblika početnog koncentratora napona, oštrog žleba odnosno zamorne početne prsline.",
journal = "Hemijska industrija",
title = "Microstructure, hardness and fracture resistance of P235TR1 seam steel pipes of different diameters, Otpornost prema lomu, tvrdoća i mikrostruktura šavnih cevi različitog prečnika izrađenih od čelika P235TR1",
volume = "77",
number = "2",
pages = "155-165",
doi = "10.2298/HEMIND230222016M"
}
Musrati, W., Međo, B., Cvijović-Alagić, I., Gubeljak, N., Štefane, P., Radosavljević, Z.,& Rakin, M.. (2023). Microstructure, hardness and fracture resistance of P235TR1 seam steel pipes of different diameters. in Hemijska industrija, 77(2), 155-165.
https://doi.org/10.2298/HEMIND230222016M
Musrati W, Međo B, Cvijović-Alagić I, Gubeljak N, Štefane P, Radosavljević Z, Rakin M. Microstructure, hardness and fracture resistance of P235TR1 seam steel pipes of different diameters. in Hemijska industrija. 2023;77(2):155-165.
doi:10.2298/HEMIND230222016M .
Musrati, Walid, Međo, Bojan, Cvijović-Alagić, Ivana, Gubeljak, Nenad, Štefane, Primož, Radosavljević, Zoran, Rakin, Marko, "Microstructure, hardness and fracture resistance of P235TR1 seam steel pipes of different diameters" in Hemijska industrija, 77, no. 2 (2023):155-165,
https://doi.org/10.2298/HEMIND230222016M . .

Ultrafine-grained microstructure effect on the biomedical Ti-based alloy performance

Cvijović-Alagić, Ivana; Laketić, Slađana; Veljović, Đorđe; Kojić, Vesna; Bajat, Jelena; Rakin, Marko

(2023)

TY  - CONF
AU  - Cvijović-Alagić, Ivana
AU  - Laketić, Slađana
AU  - Veljović, Đorđe
AU  - Kojić, Vesna
AU  - Bajat, Jelena
AU  - Rakin, Marko
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11344
C3  - NANOSTRUC 2023 : International Conference on Structural Nano Composites
T1  - Ultrafine-grained microstructure effect on the biomedical Ti-based alloy performance
SP  - 31
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11344
ER  - 
@conference{
author = "Cvijović-Alagić, Ivana and Laketić, Slađana and Veljović, Đorđe and Kojić, Vesna and Bajat, Jelena and Rakin, Marko",
year = "2023",
journal = "NANOSTRUC 2023 : International Conference on Structural Nano Composites",
title = "Ultrafine-grained microstructure effect on the biomedical Ti-based alloy performance",
pages = "31",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11344"
}
Cvijović-Alagić, I., Laketić, S., Veljović, Đ., Kojić, V., Bajat, J.,& Rakin, M.. (2023). Ultrafine-grained microstructure effect on the biomedical Ti-based alloy performance. in NANOSTRUC 2023 : International Conference on Structural Nano Composites, 31.
https://hdl.handle.net/21.15107/rcub_vinar_11344
Cvijović-Alagić I, Laketić S, Veljović Đ, Kojić V, Bajat J, Rakin M. Ultrafine-grained microstructure effect on the biomedical Ti-based alloy performance. in NANOSTRUC 2023 : International Conference on Structural Nano Composites. 2023;:31.
https://hdl.handle.net/21.15107/rcub_vinar_11344 .
Cvijović-Alagić, Ivana, Laketić, Slađana, Veljović, Đorđe, Kojić, Vesna, Bajat, Jelena, Rakin, Marko, "Ultrafine-grained microstructure effect on the biomedical Ti-based alloy performance" in NANOSTRUC 2023 : International Conference on Structural Nano Composites (2023):31,
https://hdl.handle.net/21.15107/rcub_vinar_11344 .

High-Density Glass-Ceramic Materials Obtained by Powder Metallurgy

Pavkov, Vladimir; Bakić, Gordana; Maksimović, Vesna; Cvijović-Alagić, Ivana; Prekajski-Đorđević, Marija D.; Bučevac, Dušan; Matović, Branko; Rakin, Marko

(Belgrade : Association of Metallurgical Engineers of Serbia (AMES), 2023)

TY  - CONF
AU  - Pavkov, Vladimir
AU  - Bakić, Gordana
AU  - Maksimović, Vesna
AU  - Cvijović-Alagić, Ivana
AU  - Prekajski-Đorđević, Marija D.
AU  - Bučevac, Dušan
AU  - Matović, Branko
AU  - Rakin, Marko
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11345
AB  - In modern industry, there is an increasing demand for environmentally friendly and light structural materials with good physical and mechanical properties, produced from cheap natural raw materials available in large quantities. One of the materials that meet the mentioned criteria is basalt. Basalt is a natural igneous rock of volcanic origin, created by the pouring of magma on the Earth's surface, the amount of which is significant in the territory of Serbia. Since basalt does not exhibit toxic, carcinogenic, or mutagenic effects, it is in the true sense a non-hazardous material and belongs to the group of eco-friendly materials. In this research, andesite basalt aggregate from the "Donje Jarinje" site, in Serbia, was used to obtain high-density glass-ceramic materials. High-density glass-ceramic materials were obtained by powder metallurgy process, which consisted of the following methods: dry grinding, homogenization, cold uniaxial and isostatic powder pressing and sintering in the air. In order to achieve a high-density of the materials, the green compacts were sintered in the temperature range from 1040 to 1080 °C. After confirming that the highest density materials were achieved at the sintering temperature of 1060 °C, the sintering time was optimized in the time interval from 30 to 240 min. After the experimental test, the optimal sintering parameters for obtaining high-density glass-ceramic material at the temperature of 1060 °C for 60 min were achieved, whose relative density is 99.50%, and hardness is 6.70 GPa. The characterization of andesite basalt powder was performed using the laser light diffraction method, scanning electron microscopy and X-ray diffraction method, while the characterization of sintered glass-ceramic materials was performed using the Archimedes method, X-ray diffraction method, optical light microscopy and Vickers hardness test. The results of this research confirmed that by applying powder metallurgy and sintering in the air, high-density glass-ceramic materials could be obtained for various industrial applications in the civil engineering, chemical and food industries, as well as for the making of containers for the storage of nuclear waste. Also, high-density glass-ceramic materials would be suitable for making a matrix in modern composite materials.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia (AMES)
C3  - MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina
T1  - High-Density Glass-Ceramic Materials Obtained by Powder Metallurgy
SP  - 48
EP  - 48
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11345
ER  - 
@conference{
author = "Pavkov, Vladimir and Bakić, Gordana and Maksimović, Vesna and Cvijović-Alagić, Ivana and Prekajski-Đorđević, Marija D. and Bučevac, Dušan and Matović, Branko and Rakin, Marko",
year = "2023",
abstract = "In modern industry, there is an increasing demand for environmentally friendly and light structural materials with good physical and mechanical properties, produced from cheap natural raw materials available in large quantities. One of the materials that meet the mentioned criteria is basalt. Basalt is a natural igneous rock of volcanic origin, created by the pouring of magma on the Earth's surface, the amount of which is significant in the territory of Serbia. Since basalt does not exhibit toxic, carcinogenic, or mutagenic effects, it is in the true sense a non-hazardous material and belongs to the group of eco-friendly materials. In this research, andesite basalt aggregate from the "Donje Jarinje" site, in Serbia, was used to obtain high-density glass-ceramic materials. High-density glass-ceramic materials were obtained by powder metallurgy process, which consisted of the following methods: dry grinding, homogenization, cold uniaxial and isostatic powder pressing and sintering in the air. In order to achieve a high-density of the materials, the green compacts were sintered in the temperature range from 1040 to 1080 °C. After confirming that the highest density materials were achieved at the sintering temperature of 1060 °C, the sintering time was optimized in the time interval from 30 to 240 min. After the experimental test, the optimal sintering parameters for obtaining high-density glass-ceramic material at the temperature of 1060 °C for 60 min were achieved, whose relative density is 99.50%, and hardness is 6.70 GPa. The characterization of andesite basalt powder was performed using the laser light diffraction method, scanning electron microscopy and X-ray diffraction method, while the characterization of sintered glass-ceramic materials was performed using the Archimedes method, X-ray diffraction method, optical light microscopy and Vickers hardness test. The results of this research confirmed that by applying powder metallurgy and sintering in the air, high-density glass-ceramic materials could be obtained for various industrial applications in the civil engineering, chemical and food industries, as well as for the making of containers for the storage of nuclear waste. Also, high-density glass-ceramic materials would be suitable for making a matrix in modern composite materials.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia (AMES)",
journal = "MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina",
title = "High-Density Glass-Ceramic Materials Obtained by Powder Metallurgy",
pages = "48-48",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11345"
}
Pavkov, V., Bakić, G., Maksimović, V., Cvijović-Alagić, I., Prekajski-Đorđević, M. D., Bučevac, D., Matović, B.,& Rakin, M.. (2023). High-Density Glass-Ceramic Materials Obtained by Powder Metallurgy. in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina
Belgrade : Association of Metallurgical Engineers of Serbia (AMES)., 48-48.
https://hdl.handle.net/21.15107/rcub_vinar_11345
Pavkov V, Bakić G, Maksimović V, Cvijović-Alagić I, Prekajski-Đorđević MD, Bučevac D, Matović B, Rakin M. High-Density Glass-Ceramic Materials Obtained by Powder Metallurgy. in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina. 2023;:48-48.
https://hdl.handle.net/21.15107/rcub_vinar_11345 .
Pavkov, Vladimir, Bakić, Gordana, Maksimović, Vesna, Cvijović-Alagić, Ivana, Prekajski-Đorđević, Marija D., Bučevac, Dušan, Matović, Branko, Rakin, Marko, "High-Density Glass-Ceramic Materials Obtained by Powder Metallurgy" in MME SEE : 5th Metallurgical & Materials Engineering Congress of South-East Europe, June 7-10, 2023; Trebinje, Bosnia and Herzegovina (2023):48-48,
https://hdl.handle.net/21.15107/rcub_vinar_11345 .

Andesite Basalt as a Natural Raw Material for Obtaining Glass-Ceramics

Pavkov, Vladimir; Bakić, Gordana; Maksimović, Vesna; Bučevac, Dušan; Prekajski-Đorđević, Marija D.; Cvijović-Alagić, Ivana; Matović, Branko

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2023)

TY  - CONF
AU  - Pavkov, Vladimir
AU  - Bakić, Gordana
AU  - Maksimović, Vesna
AU  - Bučevac, Dušan
AU  - Prekajski-Đorđević, Marija D.
AU  - Cvijović-Alagić, Ivana
AU  - Matović, Branko
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11347
AB  - The industrial requirements in the 21st century are environmentally friendly and light construction materials with good physical-mechanical properties manufactured from cheap natural raw materials available in large quantities. One of these materials is basalt. Basalt is a natural igneous rock of volcanic origin, with a significant amount in Serbia. Basalt belongs to the group of non-hazardous and eco-friendly materials. Andesite basalt aggregate from the "Donje Jarinje" site, Serbia, was used as the starting natural raw material for obtaining the glass-ceramic material. The aggregate is from 2 to 5 mm in size. The aggregate was milled in the tungsten-carbide vibrating cup mill for 30 min to obtain a fine powder for synthesis. The homogenization of andesite basalt powder and binder was carried out in the mortar and pestle for 10 min. The paraplast was used as a binder with a content of 0.6 wt.%. After that, uniaxial pressing of the powder at a pressure of 50 MPa was performed. A forming green compact, cold isostatic pressing was performed with a pressure of 230 MPa to increase its density. The sintering was carried out at the temperature of 1060 °C for 60 min in the air. The sintered glass-ceramic sample was a relative density of 99.5%, a macrohardness of 6.7 GPa and a fracture toughness of 2.2 MPa·m1/2 [1]. The andesite basalt powder was characterized using the laser light diffraction method, X-ray diffraction method and scanning electron microscopy. Sintered glassceramic material was characterized using the X-ray diffraction method, Archimedes principle, scanning electron and optical light microscopy and the Vickers hardness test. The glass-ceramic material obtained by sintering andesite basalt powder could be used for various industrial applications in the civil engineering, mechanical, chemical, and petrochemical industries, as well as for the making of containers to store nuclear waste.
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
T1  - Andesite Basalt as a Natural Raw Material for Obtaining Glass-Ceramics
SP  - 87
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11347
ER  - 
@conference{
author = "Pavkov, Vladimir and Bakić, Gordana and Maksimović, Vesna and Bučevac, Dušan and Prekajski-Đorđević, Marija D. and Cvijović-Alagić, Ivana and Matović, Branko",
year = "2023",
abstract = "The industrial requirements in the 21st century are environmentally friendly and light construction materials with good physical-mechanical properties manufactured from cheap natural raw materials available in large quantities. One of these materials is basalt. Basalt is a natural igneous rock of volcanic origin, with a significant amount in Serbia. Basalt belongs to the group of non-hazardous and eco-friendly materials. Andesite basalt aggregate from the "Donje Jarinje" site, Serbia, was used as the starting natural raw material for obtaining the glass-ceramic material. The aggregate is from 2 to 5 mm in size. The aggregate was milled in the tungsten-carbide vibrating cup mill for 30 min to obtain a fine powder for synthesis. The homogenization of andesite basalt powder and binder was carried out in the mortar and pestle for 10 min. The paraplast was used as a binder with a content of 0.6 wt.%. After that, uniaxial pressing of the powder at a pressure of 50 MPa was performed. A forming green compact, cold isostatic pressing was performed with a pressure of 230 MPa to increase its density. The sintering was carried out at the temperature of 1060 °C for 60 min in the air. The sintered glass-ceramic sample was a relative density of 99.5%, a macrohardness of 6.7 GPa and a fracture toughness of 2.2 MPa·m1/2 [1]. The andesite basalt powder was characterized using the laser light diffraction method, X-ray diffraction method and scanning electron microscopy. Sintered glassceramic material was characterized using the X-ray diffraction method, Archimedes principle, scanning electron and optical light microscopy and the Vickers hardness test. The glass-ceramic material obtained by sintering andesite basalt powder could be used for various industrial applications in the civil engineering, mechanical, chemical, and petrochemical industries, as well as for the making of containers to store nuclear waste.",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts",
title = "Andesite Basalt as a Natural Raw Material for Obtaining Glass-Ceramics",
pages = "87",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11347"
}
Pavkov, V., Bakić, G., Maksimović, V., Bučevac, D., Prekajski-Đorđević, M. D., Cvijović-Alagić, I.,& Matović, B.. (2023). Andesite Basalt as a Natural Raw Material for Obtaining Glass-Ceramics. in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 87.
https://hdl.handle.net/21.15107/rcub_vinar_11347
Pavkov V, Bakić G, Maksimović V, Bučevac D, Prekajski-Đorđević MD, Cvijović-Alagić I, Matović B. Andesite Basalt as a Natural Raw Material for Obtaining Glass-Ceramics. in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts. 2023;:87.
https://hdl.handle.net/21.15107/rcub_vinar_11347 .
Pavkov, Vladimir, Bakić, Gordana, Maksimović, Vesna, Bučevac, Dušan, Prekajski-Đorđević, Marija D., Cvijović-Alagić, Ivana, Matović, Branko, "Andesite Basalt as a Natural Raw Material for Obtaining Glass-Ceramics" in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts (2023):87,
https://hdl.handle.net/21.15107/rcub_vinar_11347 .

Aluminum-Based Composites Reinforced with Ceramic Fibers

Maksimović, Danica; Pavkov, Vladimir; Maksimović, Vesna; Putz, Barbara; Cvijović-Alagić, Ivana

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2023)

TY  - CONF
AU  - Maksimović, Danica
AU  - Pavkov, Vladimir
AU  - Maksimović, Vesna
AU  - Putz, Barbara
AU  - Cvijović-Alagić, Ivana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11348
AB  - The modern transportation industry is in high demand for lightweight structural components with exceptional mechanical properties that can be obtained by a costeffective production process. These specific industrial requirements can be achieved through the attainment of innovative aluminum matrix composites (AMCs) with improved characteristics in accordance with the circular economy. Solid-state recycling is considered a good solution to attain the above-mentioned industrialdemands since it enables the obtainment of usable and inexpensive raw materials with known chemical composition from industrial waste and therefore supports the cost-effective production of structural components. The present research was, therefore, directed toward the repurposing of waste materials derived from the metal industry and the civil engineering sector through a simple and economical solid-state recycling procedure to obtain raw materials for the production of innovative AMCs with required characteristics. The aluminum 2xxx series alloy, i.e. 2024 alloy, in the form of metallic chips generated during the industrial machining was selected for the obtainment of composite base, while basalt fibers derived from stone mineral wool, as waste material in civil engineering, were used to produce the composite reinforcing phase. Basalt, characterized by high strength and low density, provides improved resistance to chemical and mechanical damage, while the 2024 alloy contributes to good fatigue properties of the final fiber-reinforced AMCs. To obtain usable raw materials for the AMCs preparation from the solid industrial waste the basalt fibers were thermally treated, while aluminum-based metallic chips were ballmilled. Treated aluminum alloy powder and basalt fibers were mixed in a 3D tumbler mixer in a 9:1 ratio, isostatically pressed, and sintered in a protective argon atmosphere at 550 °C. Isostatic pressure and sintering duration were varied during the AMCs preparation to determine the optimal processing parameters for the obtainment of AMCs with the required characteristics for a predetermined purpose. The scanning electron microscopic (SEM), energy dispersive spectroscopic (EDS), and X-ray diffraction (XRD) analyses complemented with hardness and density measurements were conducted to characterize starting and final materials. Obtained composites showed improved mechanical properties compared to the starting aluminum alloy, regardless of the processing conditions. The AMCs processed at a higher pressure and for longer sintering times showed higher density and hardness. The results of the presented research undoubtedly indicated that solid-state recycling, as a simple, energy- and cost-efficient process, can be successfully used for the attainment of innovative composites for lightweight structural components in the transportation industry.
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
T1  - Aluminum-Based Composites Reinforced with Ceramic Fibers
SP  - 115
EP  - 116
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11348
ER  - 
@conference{
author = "Maksimović, Danica and Pavkov, Vladimir and Maksimović, Vesna and Putz, Barbara and Cvijović-Alagić, Ivana",
year = "2023",
abstract = "The modern transportation industry is in high demand for lightweight structural components with exceptional mechanical properties that can be obtained by a costeffective production process. These specific industrial requirements can be achieved through the attainment of innovative aluminum matrix composites (AMCs) with improved characteristics in accordance with the circular economy. Solid-state recycling is considered a good solution to attain the above-mentioned industrialdemands since it enables the obtainment of usable and inexpensive raw materials with known chemical composition from industrial waste and therefore supports the cost-effective production of structural components. The present research was, therefore, directed toward the repurposing of waste materials derived from the metal industry and the civil engineering sector through a simple and economical solid-state recycling procedure to obtain raw materials for the production of innovative AMCs with required characteristics. The aluminum 2xxx series alloy, i.e. 2024 alloy, in the form of metallic chips generated during the industrial machining was selected for the obtainment of composite base, while basalt fibers derived from stone mineral wool, as waste material in civil engineering, were used to produce the composite reinforcing phase. Basalt, characterized by high strength and low density, provides improved resistance to chemical and mechanical damage, while the 2024 alloy contributes to good fatigue properties of the final fiber-reinforced AMCs. To obtain usable raw materials for the AMCs preparation from the solid industrial waste the basalt fibers were thermally treated, while aluminum-based metallic chips were ballmilled. Treated aluminum alloy powder and basalt fibers were mixed in a 3D tumbler mixer in a 9:1 ratio, isostatically pressed, and sintered in a protective argon atmosphere at 550 °C. Isostatic pressure and sintering duration were varied during the AMCs preparation to determine the optimal processing parameters for the obtainment of AMCs with the required characteristics for a predetermined purpose. The scanning electron microscopic (SEM), energy dispersive spectroscopic (EDS), and X-ray diffraction (XRD) analyses complemented with hardness and density measurements were conducted to characterize starting and final materials. Obtained composites showed improved mechanical properties compared to the starting aluminum alloy, regardless of the processing conditions. The AMCs processed at a higher pressure and for longer sintering times showed higher density and hardness. The results of the presented research undoubtedly indicated that solid-state recycling, as a simple, energy- and cost-efficient process, can be successfully used for the attainment of innovative composites for lightweight structural components in the transportation industry.",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts",
title = "Aluminum-Based Composites Reinforced with Ceramic Fibers",
pages = "115-116",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11348"
}
Maksimović, D., Pavkov, V., Maksimović, V., Putz, B.,& Cvijović-Alagić, I.. (2023). Aluminum-Based Composites Reinforced with Ceramic Fibers. in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 115-116.
https://hdl.handle.net/21.15107/rcub_vinar_11348
Maksimović D, Pavkov V, Maksimović V, Putz B, Cvijović-Alagić I. Aluminum-Based Composites Reinforced with Ceramic Fibers. in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts. 2023;:115-116.
https://hdl.handle.net/21.15107/rcub_vinar_11348 .
Maksimović, Danica, Pavkov, Vladimir, Maksimović, Vesna, Putz, Barbara, Cvijović-Alagić, Ivana, "Aluminum-Based Composites Reinforced with Ceramic Fibers" in 7CSCS-2023 : 7th Conference of The Serbian Society for Ceramic Materials : Book of abstracts (2023):115-116,
https://hdl.handle.net/21.15107/rcub_vinar_11348 .

Program and Book of Abstracts of the 1st International Conference on Innovative Materials in Extreme Conditions (IMEC2022)

Matović, Branko; Cvijović-Alagić, Ivana; Maksimović, Vesna

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2022)

TY  - CONF
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13137
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
T1  - Program and Book of Abstracts of the 1st International Conference on Innovative Materials in Extreme Conditions (IMEC2022)
SP  - 65
ER  - 
@conference{
editor = "Matović, Branko, Cvijović-Alagić, Ivana, Maksimović, Vesna",
year = "2022",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
title = "Program and Book of Abstracts of the 1st International Conference on Innovative Materials in Extreme Conditions (IMEC2022)",
pages = "65"
}
Matović, B., Cvijović-Alagić, I.,& Maksimović, V.. (2022). Program and Book of Abstracts of the 1st International Conference on Innovative Materials in Extreme Conditions (IMEC2022). 
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 65.
Matović B, Cvijović-Alagić I, Maksimović V. Program and Book of Abstracts of the 1st International Conference on Innovative Materials in Extreme Conditions (IMEC2022). 2022;:65..
Matović, Branko, Cvijović-Alagić, Ivana, Maksimović, Vesna, "Program and Book of Abstracts of the 1st International Conference on Innovative Materials in Extreme Conditions (IMEC2022)" (2022):65.

Carbon cryogel preparation and characterization

Matović, Branko; Gorshkova, Yulia E.; Kottsov, Sergey Yu; Kopitsa, Gennady; Butulija, Svetlana; Minović Arsić, T.; Cvijović-Alagić, Ivana

(2022)

TY  - JOUR
AU  - Matović, Branko
AU  - Gorshkova, Yulia E.
AU  - Kottsov, Sergey Yu
AU  - Kopitsa, Gennady
AU  - Butulija, Svetlana
AU  - Minović Arsić, T.
AU  - Cvijović-Alagić, Ivana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10073
AB  - The carbon cryogels (CCs) show significant potential for application in a wide variety of applications, from absorbents and catalysts to supercapacitors and fuel cells, due to their high specific surface area, multimodal pore-size distribution, electrical conductivity, and thermo-mechanical stability. In the present study, the CC material was prepared by a sol-gel process from resorcinol with formaldehyde and heat treatment in an inert atmosphere. The Brunauer Emmett Teller (BET) measurements, X-ray diffraction (XRD), Raman spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), differential thermal analysis with thermogravimetric measurements (DTA-TG), scanning electron microscopy (SEM), and small-angle X-ray scattering (SAXS) analysis, as complementary techniques, were used to characterize the obtained CC. It was found that the obtained CC is a porous amorphous material with high open porosity (≈82.5%) and complex porous structure organization. Using the small-angle neutron scattering (SANS) with the contrast variation technique and the adsorption of deuterated water by carbon cryogel it was possible to separately study the structure of open and closed pores, as well as to estimate both the volume fraction of closed pores (φclose pore ≈ 1%) and the total porosity (φtotal ≈ 83.5%) of the obtained CC.
T2  - Diamond and Related Materials
T1  - Carbon cryogel preparation and characterization
VL  - 121
SP  - 108727
DO  - 10.1016/j.diamond.2021.108727
ER  - 
@article{
author = "Matović, Branko and Gorshkova, Yulia E. and Kottsov, Sergey Yu and Kopitsa, Gennady and Butulija, Svetlana and Minović Arsić, T. and Cvijović-Alagić, Ivana",
year = "2022",
abstract = "The carbon cryogels (CCs) show significant potential for application in a wide variety of applications, from absorbents and catalysts to supercapacitors and fuel cells, due to their high specific surface area, multimodal pore-size distribution, electrical conductivity, and thermo-mechanical stability. In the present study, the CC material was prepared by a sol-gel process from resorcinol with formaldehyde and heat treatment in an inert atmosphere. The Brunauer Emmett Teller (BET) measurements, X-ray diffraction (XRD), Raman spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), differential thermal analysis with thermogravimetric measurements (DTA-TG), scanning electron microscopy (SEM), and small-angle X-ray scattering (SAXS) analysis, as complementary techniques, were used to characterize the obtained CC. It was found that the obtained CC is a porous amorphous material with high open porosity (≈82.5%) and complex porous structure organization. Using the small-angle neutron scattering (SANS) with the contrast variation technique and the adsorption of deuterated water by carbon cryogel it was possible to separately study the structure of open and closed pores, as well as to estimate both the volume fraction of closed pores (φclose pore ≈ 1%) and the total porosity (φtotal ≈ 83.5%) of the obtained CC.",
journal = "Diamond and Related Materials",
title = "Carbon cryogel preparation and characterization",
volume = "121",
pages = "108727",
doi = "10.1016/j.diamond.2021.108727"
}
Matović, B., Gorshkova, Y. E., Kottsov, S. Y., Kopitsa, G., Butulija, S., Minović Arsić, T.,& Cvijović-Alagić, I.. (2022). Carbon cryogel preparation and characterization. in Diamond and Related Materials, 121, 108727.
https://doi.org/10.1016/j.diamond.2021.108727
Matović B, Gorshkova YE, Kottsov SY, Kopitsa G, Butulija S, Minović Arsić T, Cvijović-Alagić I. Carbon cryogel preparation and characterization. in Diamond and Related Materials. 2022;121:108727.
doi:10.1016/j.diamond.2021.108727 .
Matović, Branko, Gorshkova, Yulia E., Kottsov, Sergey Yu, Kopitsa, Gennady, Butulija, Svetlana, Minović Arsić, T., Cvijović-Alagić, Ivana, "Carbon cryogel preparation and characterization" in Diamond and Related Materials, 121 (2022):108727,
https://doi.org/10.1016/j.diamond.2021.108727 . .
5
2

DFT study of structural stability and mechanical properties: High-Entropy Alloys (HEAs) - Ultra-High Temperature Ceramics (UHTC)

Zagorac, Dejan; Cvijović-Alagić, Ivana; Zagorac, Jelena; Butulija, Svetlana; Erčić, Jelena; Hanzel, Ondrej; Sedlak, Richard; Lisnichuk, Maksym; Škundrić, Tamara; Pejić, Milan; Jovanović, Dušica; Tatarko, Peter; Matović, Branko

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2022)

TY  - CONF
AU  - Zagorac, Dejan
AU  - Cvijović-Alagić, Ivana
AU  - Zagorac, Jelena
AU  - Butulija, Svetlana
AU  - Erčić, Jelena
AU  - Hanzel, Ondrej
AU  - Sedlak, Richard
AU  - Lisnichuk, Maksym
AU  - Škundrić, Tamara
AU  - Pejić, Milan
AU  - Jovanović, Dušica
AU  - Tatarko, Peter
AU  - Matović, Branko
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11329
AB  - High-Entropy Alloys (HEAs) have attracted considerable interest due to the combination of useful properties and enhanced applications, and a few HEAs have already been shown to possess exceptional properties under extreme conditions (e.g. Ultra-High Temperature Ceramic (UHTC)). However, predicting the formation, structures, and stability of HEAs is one of the major goals of recent studies, which is expected to bring discovery of new systems with enhanced properties of the material, with special attention on high temperature and mechanical load. Here, we show an example of high-entropy rare-earth (RE) zirconates with a pyrochlore structure that was examined theoretically and experimentally observed. Theoretical methods were applied to investigate the variable composition of the ordered and disordered pyrochlore structures using quantum mechanics, group action theory, PCAE, and supercell methods. The investigated RE2Zr2O7 compound was successfully fabricated by pressureless and spark plasma sintering. with nominal composition (La0.2Y0.2Gd0.2Nd0.2Sm0.2)Zr2O7, prepared by simple glycine nitrate procedure (GNP) and characterized using various experimental methods (XRD, SEM, TEM, Raman, etc.). [1] Pyrochlore structures were generated using the Primitive Cell Approach for Atom Exchange (PCAE) method [2] or the supercell approach using the Crystal17 program package [3], and investigation of disordered systems and solid solutions was conducted using the group action theory [4]. Structural optimization on the ab initio level was performed using the Crystal17 code, based on a Linear Combination of Atomic Orbitals (LCAO). Density functional theory (DFT) calculations were utilized in the present study, using the local density approximation (LDA) with Perdew–Zunger (PZ) correlation functional.
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
C3  - IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts
T1  - DFT study of structural stability and mechanical properties: High-Entropy Alloys (HEAs) - Ultra-High Temperature Ceramics (UHTC)
SP  - 43
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11329
ER  - 
@conference{
author = "Zagorac, Dejan and Cvijović-Alagić, Ivana and Zagorac, Jelena and Butulija, Svetlana and Erčić, Jelena and Hanzel, Ondrej and Sedlak, Richard and Lisnichuk, Maksym and Škundrić, Tamara and Pejić, Milan and Jovanović, Dušica and Tatarko, Peter and Matović, Branko",
year = "2022",
abstract = "High-Entropy Alloys (HEAs) have attracted considerable interest due to the combination of useful properties and enhanced applications, and a few HEAs have already been shown to possess exceptional properties under extreme conditions (e.g. Ultra-High Temperature Ceramic (UHTC)). However, predicting the formation, structures, and stability of HEAs is one of the major goals of recent studies, which is expected to bring discovery of new systems with enhanced properties of the material, with special attention on high temperature and mechanical load. Here, we show an example of high-entropy rare-earth (RE) zirconates with a pyrochlore structure that was examined theoretically and experimentally observed. Theoretical methods were applied to investigate the variable composition of the ordered and disordered pyrochlore structures using quantum mechanics, group action theory, PCAE, and supercell methods. The investigated RE2Zr2O7 compound was successfully fabricated by pressureless and spark plasma sintering. with nominal composition (La0.2Y0.2Gd0.2Nd0.2Sm0.2)Zr2O7, prepared by simple glycine nitrate procedure (GNP) and characterized using various experimental methods (XRD, SEM, TEM, Raman, etc.). [1] Pyrochlore structures were generated using the Primitive Cell Approach for Atom Exchange (PCAE) method [2] or the supercell approach using the Crystal17 program package [3], and investigation of disordered systems and solid solutions was conducted using the group action theory [4]. Structural optimization on the ab initio level was performed using the Crystal17 code, based on a Linear Combination of Atomic Orbitals (LCAO). Density functional theory (DFT) calculations were utilized in the present study, using the local density approximation (LDA) with Perdew–Zunger (PZ) correlation functional.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
journal = "IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts",
title = "DFT study of structural stability and mechanical properties: High-Entropy Alloys (HEAs) - Ultra-High Temperature Ceramics (UHTC)",
pages = "43",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11329"
}
Zagorac, D., Cvijović-Alagić, I., Zagorac, J., Butulija, S., Erčić, J., Hanzel, O., Sedlak, R., Lisnichuk, M., Škundrić, T., Pejić, M., Jovanović, D., Tatarko, P.,& Matović, B.. (2022). DFT study of structural stability and mechanical properties: High-Entropy Alloys (HEAs) - Ultra-High Temperature Ceramics (UHTC). in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 43.
https://hdl.handle.net/21.15107/rcub_vinar_11329
Zagorac D, Cvijović-Alagić I, Zagorac J, Butulija S, Erčić J, Hanzel O, Sedlak R, Lisnichuk M, Škundrić T, Pejić M, Jovanović D, Tatarko P, Matović B. DFT study of structural stability and mechanical properties: High-Entropy Alloys (HEAs) - Ultra-High Temperature Ceramics (UHTC). in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts. 2022;:43.
https://hdl.handle.net/21.15107/rcub_vinar_11329 .
Zagorac, Dejan, Cvijović-Alagić, Ivana, Zagorac, Jelena, Butulija, Svetlana, Erčić, Jelena, Hanzel, Ondrej, Sedlak, Richard, Lisnichuk, Maksym, Škundrić, Tamara, Pejić, Milan, Jovanović, Dušica, Tatarko, Peter, Matović, Branko, "DFT study of structural stability and mechanical properties: High-Entropy Alloys (HEAs) - Ultra-High Temperature Ceramics (UHTC)" in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts (2022):43,
https://hdl.handle.net/21.15107/rcub_vinar_11329 .

Structural and mechanical properties of highentropy alloys (HEAS) - ultra-high temperature ceramics (UHTC) on DFT level

Cvijović-Alagić, Ivana; Zagorac, Dejan; Zagorac, Jelena; Butulija, Svetlana; Erčić, Jelena; Hanzel, Ondrej; Sedlak, Richard; Lisnichuk, Maksym; Škundrić, Tamara; Pejić, Milan; Jovanović, Dušica; Tatarko, Peter; Matović, Branko

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2022)

TY  - CONF
AU  - Cvijović-Alagić, Ivana
AU  - Zagorac, Dejan
AU  - Zagorac, Jelena
AU  - Butulija, Svetlana
AU  - Erčić, Jelena
AU  - Hanzel, Ondrej
AU  - Sedlak, Richard
AU  - Lisnichuk, Maksym
AU  - Škundrić, Tamara
AU  - Pejić, Milan
AU  - Jovanović, Dušica
AU  - Tatarko, Peter
AU  - Matović, Branko
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11331
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
T1  - Structural and mechanical properties of highentropy alloys (HEAS) - ultra-high temperature ceramics (UHTC) on DFT level
SP  - 80
EP  - 81
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11331
ER  - 
@conference{
author = "Cvijović-Alagić, Ivana and Zagorac, Dejan and Zagorac, Jelena and Butulija, Svetlana and Erčić, Jelena and Hanzel, Ondrej and Sedlak, Richard and Lisnichuk, Maksym and Škundrić, Tamara and Pejić, Milan and Jovanović, Dušica and Tatarko, Peter and Matović, Branko",
year = "2022",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia",
title = "Structural and mechanical properties of highentropy alloys (HEAS) - ultra-high temperature ceramics (UHTC) on DFT level",
pages = "80-81",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11331"
}
Cvijović-Alagić, I., Zagorac, D., Zagorac, J., Butulija, S., Erčić, J., Hanzel, O., Sedlak, R., Lisnichuk, M., Škundrić, T., Pejić, M., Jovanović, D., Tatarko, P.,& Matović, B.. (2022). Structural and mechanical properties of highentropy alloys (HEAS) - ultra-high temperature ceramics (UHTC) on DFT level. in Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 80-81.
https://hdl.handle.net/21.15107/rcub_vinar_11331
Cvijović-Alagić I, Zagorac D, Zagorac J, Butulija S, Erčić J, Hanzel O, Sedlak R, Lisnichuk M, Škundrić T, Pejić M, Jovanović D, Tatarko P, Matović B. Structural and mechanical properties of highentropy alloys (HEAS) - ultra-high temperature ceramics (UHTC) on DFT level. in Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia. 2022;:80-81.
https://hdl.handle.net/21.15107/rcub_vinar_11331 .
Cvijović-Alagić, Ivana, Zagorac, Dejan, Zagorac, Jelena, Butulija, Svetlana, Erčić, Jelena, Hanzel, Ondrej, Sedlak, Richard, Lisnichuk, Maksym, Škundrić, Tamara, Pejić, Milan, Jovanović, Dušica, Tatarko, Peter, Matović, Branko, "Structural and mechanical properties of highentropy alloys (HEAS) - ultra-high temperature ceramics (UHTC) on DFT level" in Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia (2022):80-81,
https://hdl.handle.net/21.15107/rcub_vinar_11331 .

Fabrication and characterization of high entropy pyrochlore ceramics

Matović, Branko; Zagorac, Dejan; Cvijović-Alagić, Ivana; Zagorac, Jelena; Butulija, Svetlana; Erčić, Jelena; Hanzel, Ondrej; Sedlak, Richard; Lisnichuk, Maksym; Tatarko, Peter

(Belgrade : Materials Research Society of Serbia – MRS-Serbia, 2022)

TY  - CONF
AU  - Matović, Branko
AU  - Zagorac, Dejan
AU  - Cvijović-Alagić, Ivana
AU  - Zagorac, Jelena
AU  - Butulija, Svetlana
AU  - Erčić, Jelena
AU  - Hanzel, Ondrej
AU  - Sedlak, Richard
AU  - Lisnichuk, Maksym
AU  - Tatarko, Peter
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11332
AB  - High-entropy rare-earth (RE) zirconates with pyrochlore structure were successfully fabricated by pressureless and spark plasma sintering. RE2Zr2O7 compound with nominal composition (La0.2Y0.2Gd0.2Nd0.2Sm0.2)Zr2O7 was prepared by simple glycine nitrate procedure (GNP). GNP process yielded powders with low crystallinity and after subsequent calcination, well crystalline ceramics were formed. During calcination defective fluorite (F-RE2Zr2O7) and crystal pyrochlore (Py-RE2Zr2O7) structures coexist. Formation of pure crystalline pyrochlore occurs after sintering at 1450 C. High-density ceramics, free of any additives, were obtained after powders compaction and pressureless (PS), as well as Field Assisted Sintering Technique (FAST) at 1450 C. Theoretical investigations of the high-entropy RE2Zr2O7 pyrochlore systems were performed. Unit cell parameter of the obtained Py-RE2Zr2O7 is 10.5892(2) Å and 10.5999(2) Å for PS and FAST sintering, respectively, which is in good agreement with the results of Density Functional Theory (DFT) calculations. The thermal diffusivity of sintered samples at room temperature was ~0.7 mm2 /s for both sintering methods.
PB  - Belgrade : Materials Research Society of Serbia – MRS-Serbia
C3  - 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts
T1  - Fabrication and characterization of high entropy pyrochlore ceramics
VL  - XLV
SP  - 115
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11332
ER  - 
@conference{
author = "Matović, Branko and Zagorac, Dejan and Cvijović-Alagić, Ivana and Zagorac, Jelena and Butulija, Svetlana and Erčić, Jelena and Hanzel, Ondrej and Sedlak, Richard and Lisnichuk, Maksym and Tatarko, Peter",
year = "2022",
abstract = "High-entropy rare-earth (RE) zirconates with pyrochlore structure were successfully fabricated by pressureless and spark plasma sintering. RE2Zr2O7 compound with nominal composition (La0.2Y0.2Gd0.2Nd0.2Sm0.2)Zr2O7 was prepared by simple glycine nitrate procedure (GNP). GNP process yielded powders with low crystallinity and after subsequent calcination, well crystalline ceramics were formed. During calcination defective fluorite (F-RE2Zr2O7) and crystal pyrochlore (Py-RE2Zr2O7) structures coexist. Formation of pure crystalline pyrochlore occurs after sintering at 1450 C. High-density ceramics, free of any additives, were obtained after powders compaction and pressureless (PS), as well as Field Assisted Sintering Technique (FAST) at 1450 C. Theoretical investigations of the high-entropy RE2Zr2O7 pyrochlore systems were performed. Unit cell parameter of the obtained Py-RE2Zr2O7 is 10.5892(2) Å and 10.5999(2) Å for PS and FAST sintering, respectively, which is in good agreement with the results of Density Functional Theory (DFT) calculations. The thermal diffusivity of sintered samples at room temperature was ~0.7 mm2 /s for both sintering methods.",
publisher = "Belgrade : Materials Research Society of Serbia – MRS-Serbia",
journal = "23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts",
title = "Fabrication and characterization of high entropy pyrochlore ceramics",
volume = "XLV",
pages = "115",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11332"
}
Matović, B., Zagorac, D., Cvijović-Alagić, I., Zagorac, J., Butulija, S., Erčić, J., Hanzel, O., Sedlak, R., Lisnichuk, M.,& Tatarko, P.. (2022). Fabrication and characterization of high entropy pyrochlore ceramics. in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts
Belgrade : Materials Research Society of Serbia – MRS-Serbia., XLV, 115.
https://hdl.handle.net/21.15107/rcub_vinar_11332
Matović B, Zagorac D, Cvijović-Alagić I, Zagorac J, Butulija S, Erčić J, Hanzel O, Sedlak R, Lisnichuk M, Tatarko P. Fabrication and characterization of high entropy pyrochlore ceramics. in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts. 2022;XLV:115.
https://hdl.handle.net/21.15107/rcub_vinar_11332 .
Matović, Branko, Zagorac, Dejan, Cvijović-Alagić, Ivana, Zagorac, Jelena, Butulija, Svetlana, Erčić, Jelena, Hanzel, Ondrej, Sedlak, Richard, Lisnichuk, Maksym, Tatarko, Peter, "Fabrication and characterization of high entropy pyrochlore ceramics" in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts, XLV (2022):115,
https://hdl.handle.net/21.15107/rcub_vinar_11332 .

Phase transformations during cyclic annealing of Ti3Al-based intermetallic

Cvijović-Alagić, Ivana; Zagorac, Dejan

(Belgrade : Institute for Multidisciplinary Research, University of Belgrade, 2022)

TY  - CONF
AU  - Cvijović-Alagić, Ivana
AU  - Zagorac, Dejan
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11330
PB  - Belgrade : Institute for Multidisciplinary Research, University of Belgrade
C3  - Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
T1  - Phase transformations during cyclic annealing of Ti3Al-based intermetallic
SP  - 86
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11330
ER  - 
@conference{
author = "Cvijović-Alagić, Ivana and Zagorac, Dejan",
year = "2022",
publisher = "Belgrade : Institute for Multidisciplinary Research, University of Belgrade",
journal = "Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia",
title = "Phase transformations during cyclic annealing of Ti3Al-based intermetallic",
pages = "86",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11330"
}
Cvijović-Alagić, I.,& Zagorac, D.. (2022). Phase transformations during cyclic annealing of Ti3Al-based intermetallic. in Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research, University of Belgrade., 86.
https://hdl.handle.net/21.15107/rcub_vinar_11330
Cvijović-Alagić I, Zagorac D. Phase transformations during cyclic annealing of Ti3Al-based intermetallic. in Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia. 2022;:86.
https://hdl.handle.net/21.15107/rcub_vinar_11330 .
Cvijović-Alagić, Ivana, Zagorac, Dejan, "Phase transformations during cyclic annealing of Ti3Al-based intermetallic" in Advanced Ceramics and Application : 6th Conference of The Serbian Society for Ceramic Materials, 6CSCS-2022, June 28-29, 2022, Belgrade, Serbia (2022):86,
https://hdl.handle.net/21.15107/rcub_vinar_11330 .

Laser irradiation as an easy-to-apply method for Ti-based implant materials enhancement

Cvijović-Alagić, Ivana; Laketić, Slađana; Momčilović, Miloš; Ciganović, Jovan; Veljović, Đorđe; Rakin, Marko

(Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, 2022)

TY  - CONF
AU  - Cvijović-Alagić, Ivana
AU  - Laketić, Slađana
AU  - Momčilović, Miloš
AU  - Ciganović, Jovan
AU  - Veljović, Đorđe
AU  - Rakin, Marko
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11326
AB  - Hard-tissue replacements are most commonly made from the Ti-based materials, such ascommercially pure titanium (CP-Ti) and Ti-6Al-4V (mass%) alloy, because of their exceptionalbiocompatible properties combined with the excellent corrosive and mechanical characteristics [1].More recently, efforts have been made to additionally enhance the properties of the metallicimplants through the careful selection of the alloy composition and surface modification technics[2,3]. As a result, second-generation β-type Ti alloys, containing non-toxic elements, have beendeveloped. One of the promising β-type implant alloys is Ti-13Nb-13Zr (mass%). Even though thecorrosion resistance and mechanical properties of this alloy are improved in comparison to thecommonly used metallic implant materials, its biocompatible and osseointegration properties canand must be additionally enhanced. For that purpose several surface modification technics can beused, however, laser irradiation stands out as the most promising one. Because of that scope of thepresent research was to investigate the possibility of successful surface modification of the mostcommonly used implant material, i.e. CP-Ti, and the second-generation Ti-13Nb-13Zr alloy byutilizing the easy-to-apply laser irradiation method in order to obtain improved implant tribocorrosiveproperties and enhanced biointegration and bioactivity.Laser surface modifications were conducted using the Nd:YAG system in the air and argonatmosphere under different laser output energies. Implant materials surface morphologies after thelaser irradiation treatment were investigated using the field-emission scanning electron microscopy(FE-SEM) and optical profilometry, while the impact of the laser irradiation on the implantmaterials surface characteristics were examined using the energy dispersive spectrometry (EDS)and microhardness measurements.Conducted research showed that utilization of the Nd:YAG laser irradiation resulted in significantalterations of the CP-Ti and Ti-13Nb-13Zr alloy surface chemistry, morphology and microhardness.Laser irradiation of both investigated materials led to the formation of visible microcracks andhydrodynamic effects in the central part of the irradiated area, while traces of melted and solidifiedmaterial were observed at its periphery. More pronounced morphological changes were inducedduring the laser irradiation in an argon atmosphere, while a higher degree of texturing was recordedat the surface of the Ti-13Nb-13Zr alloy. At the irradiated surfaces, the formation of the oxide layer,predominantly composed of Ti-oxide particles, was detected. Surface oxides are desirable sincetheir presence can improve the implant material bioactivity with a simultaneous increase of thetribo-corrosive properties through the formation of the hard corrosion resistance surface film. Laserinducedchemical and morphological alterations were more distinctive in the case of the Ti-13Nb-13Zr alloy.
PB  - Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade
PB  - Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)
C3  - IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts
T1  - Laser irradiation as an easy-to-apply method for Ti-based implant materials enhancement
SP  - 20
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11326
ER  - 
@conference{
author = "Cvijović-Alagić, Ivana and Laketić, Slađana and Momčilović, Miloš and Ciganović, Jovan and Veljović, Đorđe and Rakin, Marko",
year = "2022",
abstract = "Hard-tissue replacements are most commonly made from the Ti-based materials, such ascommercially pure titanium (CP-Ti) and Ti-6Al-4V (mass%) alloy, because of their exceptionalbiocompatible properties combined with the excellent corrosive and mechanical characteristics [1].More recently, efforts have been made to additionally enhance the properties of the metallicimplants through the careful selection of the alloy composition and surface modification technics[2,3]. As a result, second-generation β-type Ti alloys, containing non-toxic elements, have beendeveloped. One of the promising β-type implant alloys is Ti-13Nb-13Zr (mass%). Even though thecorrosion resistance and mechanical properties of this alloy are improved in comparison to thecommonly used metallic implant materials, its biocompatible and osseointegration properties canand must be additionally enhanced. For that purpose several surface modification technics can beused, however, laser irradiation stands out as the most promising one. Because of that scope of thepresent research was to investigate the possibility of successful surface modification of the mostcommonly used implant material, i.e. CP-Ti, and the second-generation Ti-13Nb-13Zr alloy byutilizing the easy-to-apply laser irradiation method in order to obtain improved implant tribocorrosiveproperties and enhanced biointegration and bioactivity.Laser surface modifications were conducted using the Nd:YAG system in the air and argonatmosphere under different laser output energies. Implant materials surface morphologies after thelaser irradiation treatment were investigated using the field-emission scanning electron microscopy(FE-SEM) and optical profilometry, while the impact of the laser irradiation on the implantmaterials surface characteristics were examined using the energy dispersive spectrometry (EDS)and microhardness measurements.Conducted research showed that utilization of the Nd:YAG laser irradiation resulted in significantalterations of the CP-Ti and Ti-13Nb-13Zr alloy surface chemistry, morphology and microhardness.Laser irradiation of both investigated materials led to the formation of visible microcracks andhydrodynamic effects in the central part of the irradiated area, while traces of melted and solidifiedmaterial were observed at its periphery. More pronounced morphological changes were inducedduring the laser irradiation in an argon atmosphere, while a higher degree of texturing was recordedat the surface of the Ti-13Nb-13Zr alloy. At the irradiated surfaces, the formation of the oxide layer,predominantly composed of Ti-oxide particles, was detected. Surface oxides are desirable sincetheir presence can improve the implant material bioactivity with a simultaneous increase of thetribo-corrosive properties through the formation of the hard corrosion resistance surface film. Laserinducedchemical and morphological alterations were more distinctive in the case of the Ti-13Nb-13Zr alloy.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade : Serbian Society for Innovative Materials in Extreme Conditions (SIM-EXTREME)",
journal = "IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts",
title = "Laser irradiation as an easy-to-apply method for Ti-based implant materials enhancement",
pages = "20",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11326"
}
Cvijović-Alagić, I., Laketić, S., Momčilović, M., Ciganović, J., Veljović, Đ.,& Rakin, M.. (2022). Laser irradiation as an easy-to-apply method for Ti-based implant materials enhancement. in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade., 20.
https://hdl.handle.net/21.15107/rcub_vinar_11326
Cvijović-Alagić I, Laketić S, Momčilović M, Ciganović J, Veljović Đ, Rakin M. Laser irradiation as an easy-to-apply method for Ti-based implant materials enhancement. in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts. 2022;:20.
https://hdl.handle.net/21.15107/rcub_vinar_11326 .
Cvijović-Alagić, Ivana, Laketić, Slađana, Momčilović, Miloš, Ciganović, Jovan, Veljović, Đorđe, Rakin, Marko, "Laser irradiation as an easy-to-apply method for Ti-based implant materials enhancement" in IMEC 2022 : 1st Intentational conference on innovativ materials in extreme conditions : Program and Book of abstracts (2022):20,
https://hdl.handle.net/21.15107/rcub_vinar_11326 .

Laser-induced chemical and mophological changes of the titanium alloy surface under different irradiation parameters

Laketić, Slađana; Rakin, Marko; Momčilović, Miloš; Ciganović, Jovan; Veljović, Đorđe; Cvijović-Alagić, Ivana

(Belgrade : Materials Research Society of Serbia – MRS-Serbia, 2022)

TY  - CONF
AU  - Laketić, Slađana
AU  - Rakin, Marko
AU  - Momčilović, Miloš
AU  - Ciganović, Jovan
AU  - Veljović, Đorđe
AU  - Cvijović-Alagić, Ivana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11328
AB  - Titanium alloys are finding increasing use as biomaterials due to their low elastic modulus and high damage tolerance. However, the somewhat inadequate alloy surface performance can impede their biomedical application. Surface modification methods have been therefore developed to improve the alloys' surface bioactivity and osseointegration. Laser treatment allows the alloy surface to be modified, providing it with new functionalized surface chemistry and morphology, without compromising the rest of the material properties. Thus, the aim of the study was to examine the laser-induced alterations generated on the Ti-45Nb alloy surface by an ultrashort pulsed laser. The obtained results reveal that laser beam interaction with the target material led to the formation of significant alterations in surface morphology. Surface craters, microcracks, and surface features in the form of periodic and rippled structures and solidified droplets can be observed in the irradiated area. Also, it was found that the higher damage degree along with the material depth and the higher surface roughness were achieved during the irradiation in the argon atmosphere due to the formation of the more pronounced morphological changes on the alloy surface that are induced by higher laser ablation. Furthermore, obtained results showed that alloy surface modification in air, argon, and nitrogen atmosphere additionally caused changes in the surface chemical composition. Namely, after irradiation, the presence of oxygen was observed in the central irradiated area indicating the formation of bioactive Ti-oxide surface film with content that varies with the irradiation parameters variation. Therefore, laser beam irradiation can be singled out as the surface modification method for efficient inducement of the specific surface characteristics that can provide titanium alloys with enhanced osseointegration properties.
PB  - Belgrade : Materials Research Society of Serbia – MRS-Serbia
C3  - 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts
T1  - Laser-induced chemical and mophological changes of the titanium alloy surface under different irradiation parameters
VL  - XLV
SP  - 92
EP  - 92
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11328
ER  - 
@conference{
author = "Laketić, Slađana and Rakin, Marko and Momčilović, Miloš and Ciganović, Jovan and Veljović, Đorđe and Cvijović-Alagić, Ivana",
year = "2022",
abstract = "Titanium alloys are finding increasing use as biomaterials due to their low elastic modulus and high damage tolerance. However, the somewhat inadequate alloy surface performance can impede their biomedical application. Surface modification methods have been therefore developed to improve the alloys' surface bioactivity and osseointegration. Laser treatment allows the alloy surface to be modified, providing it with new functionalized surface chemistry and morphology, without compromising the rest of the material properties. Thus, the aim of the study was to examine the laser-induced alterations generated on the Ti-45Nb alloy surface by an ultrashort pulsed laser. The obtained results reveal that laser beam interaction with the target material led to the formation of significant alterations in surface morphology. Surface craters, microcracks, and surface features in the form of periodic and rippled structures and solidified droplets can be observed in the irradiated area. Also, it was found that the higher damage degree along with the material depth and the higher surface roughness were achieved during the irradiation in the argon atmosphere due to the formation of the more pronounced morphological changes on the alloy surface that are induced by higher laser ablation. Furthermore, obtained results showed that alloy surface modification in air, argon, and nitrogen atmosphere additionally caused changes in the surface chemical composition. Namely, after irradiation, the presence of oxygen was observed in the central irradiated area indicating the formation of bioactive Ti-oxide surface film with content that varies with the irradiation parameters variation. Therefore, laser beam irradiation can be singled out as the surface modification method for efficient inducement of the specific surface characteristics that can provide titanium alloys with enhanced osseointegration properties.",
publisher = "Belgrade : Materials Research Society of Serbia – MRS-Serbia",
journal = "23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts",
title = "Laser-induced chemical and mophological changes of the titanium alloy surface under different irradiation parameters",
volume = "XLV",
pages = "92-92",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11328"
}
Laketić, S., Rakin, M., Momčilović, M., Ciganović, J., Veljović, Đ.,& Cvijović-Alagić, I.. (2022). Laser-induced chemical and mophological changes of the titanium alloy surface under different irradiation parameters. in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts
Belgrade : Materials Research Society of Serbia – MRS-Serbia., XLV, 92-92.
https://hdl.handle.net/21.15107/rcub_vinar_11328
Laketić S, Rakin M, Momčilović M, Ciganović J, Veljović Đ, Cvijović-Alagić I. Laser-induced chemical and mophological changes of the titanium alloy surface under different irradiation parameters. in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts. 2022;XLV:92-92.
https://hdl.handle.net/21.15107/rcub_vinar_11328 .
Laketić, Slađana, Rakin, Marko, Momčilović, Miloš, Ciganović, Jovan, Veljović, Đorđe, Cvijović-Alagić, Ivana, "Laser-induced chemical and mophological changes of the titanium alloy surface under different irradiation parameters" in 23rd annual conference - YUCOMAT 2022 & 12th World Round Table Conference on Sintering - WRTCS 2022 : Program and Book of Abstracts, XLV (2022):92-92,
https://hdl.handle.net/21.15107/rcub_vinar_11328 .

Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes

Matić, Tamara; Zebić, M. Ležaja; Miletić, Vesna; Cvijović-Alagić, Ivana; Petrović, Rada D.; Janaćković, Đorđe T.; Veljović, Đorđe N.

(2022)

TY  - JOUR
AU  - Matić, Tamara
AU  - Zebić, M. Ležaja
AU  - Miletić, Vesna
AU  - Cvijović-Alagić, Ivana
AU  - Petrović, Rada D.
AU  - Janaćković, Đorđe T.
AU  - Veljović, Đorđe N.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10114
AB  - The aim of this study was to investigate the influence of binary Sr, Mg ion-doping compared to the single-ion doping effects on the phase composition and morphology of hydrothermally obtained calcium hydroxyapatite (HAP) powders and on the phase composition, microstructure, and mechanical properties of the sintered materials. Additionally, the focus of this study was to investigate the possible utilization of the binary doped Sr,Mg-HAP compacts as dentin substitutes in restorative dentistry by evaluating their bonding ability with commercially available restorative materials using the shear bond strength test (SBS). The hydrothermally obtained mono-doped Mg5 and Sr5 showed the monophasic apatite structure, while in all co-doped samples β-TCP phase was formed, resulting in biphasic calcium phosphate (BCP) powders. It was confirmed that co-doping with Sr and Mg ions led to the thermal stabilization of the β-TCP phase by suppressing the phase transition into α-TCP when sintered at 1200 °C. Moreover, the co-presence of Mg ions significantly improved the hardness of Sr-doped HAP from 3.74 to 5.02 GPa. Sr,Mg-HAP dental inserts were found to achieve sufficient bonding (13.53 MPa) through the micromechanical interlocking with Z250 dental composite and Single Bond Universal dental adhesive applied with a total etch approach. The SBS values obtained for the SrMg-HAP insert were similar to the literature data on bonding ability with human dentin, indicating that binary doped Sr,Mg-HAP ceramics present a promising material for application in restorative dentistry as dentin substitutes.
T2  - Ceramics International
T1  - Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes
DO  - 10.1016/j.ceramint.2021.12.335
ER  - 
@article{
author = "Matić, Tamara and Zebić, M. Ležaja and Miletić, Vesna and Cvijović-Alagić, Ivana and Petrović, Rada D. and Janaćković, Đorđe T. and Veljović, Đorđe N.",
year = "2022",
abstract = "The aim of this study was to investigate the influence of binary Sr, Mg ion-doping compared to the single-ion doping effects on the phase composition and morphology of hydrothermally obtained calcium hydroxyapatite (HAP) powders and on the phase composition, microstructure, and mechanical properties of the sintered materials. Additionally, the focus of this study was to investigate the possible utilization of the binary doped Sr,Mg-HAP compacts as dentin substitutes in restorative dentistry by evaluating their bonding ability with commercially available restorative materials using the shear bond strength test (SBS). The hydrothermally obtained mono-doped Mg5 and Sr5 showed the monophasic apatite structure, while in all co-doped samples β-TCP phase was formed, resulting in biphasic calcium phosphate (BCP) powders. It was confirmed that co-doping with Sr and Mg ions led to the thermal stabilization of the β-TCP phase by suppressing the phase transition into α-TCP when sintered at 1200 °C. Moreover, the co-presence of Mg ions significantly improved the hardness of Sr-doped HAP from 3.74 to 5.02 GPa. Sr,Mg-HAP dental inserts were found to achieve sufficient bonding (13.53 MPa) through the micromechanical interlocking with Z250 dental composite and Single Bond Universal dental adhesive applied with a total etch approach. The SBS values obtained for the SrMg-HAP insert were similar to the literature data on bonding ability with human dentin, indicating that binary doped Sr,Mg-HAP ceramics present a promising material for application in restorative dentistry as dentin substitutes.",
journal = "Ceramics International",
title = "Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes",
doi = "10.1016/j.ceramint.2021.12.335"
}
Matić, T., Zebić, M. L., Miletić, V., Cvijović-Alagić, I., Petrović, R. D., Janaćković, Đ. T.,& Veljović, Đ. N.. (2022). Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes. in Ceramics International.
https://doi.org/10.1016/j.ceramint.2021.12.335
Matić T, Zebić ML, Miletić V, Cvijović-Alagić I, Petrović RD, Janaćković ĐT, Veljović ĐN. Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes. in Ceramics International. 2022;.
doi:10.1016/j.ceramint.2021.12.335 .
Matić, Tamara, Zebić, M. Ležaja, Miletić, Vesna, Cvijović-Alagić, Ivana, Petrović, Rada D., Janaćković, Đorđe T., Veljović, Đorđe N., "Sr,Mg co-doping of calcium hydroxyapatite: Hydrothermal synthesis, processing, characterization and possible application as dentin substitutes" in Ceramics International (2022),
https://doi.org/10.1016/j.ceramint.2021.12.335 . .
8
6

Densification of boron carbide under high pressure

Matović, Branko; Urbanovich, Vladimir; Girman, Vladimir; Lisnichuk, Maksym; Nikolić, Dobrica; Erčić, Jelena; Cvijović-Alagić, Ivana

(2022)

TY  - JOUR
AU  - Matović, Branko
AU  - Urbanovich, Vladimir
AU  - Girman, Vladimir
AU  - Lisnichuk, Maksym
AU  - Nikolić, Dobrica
AU  - Erčić, Jelena
AU  - Cvijović-Alagić, Ivana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10160
AB  - Additive-free boron carbide (B4C) powders were densified at 4 GPa using the high-pressure “anvil-type with hollows” apparatus in the temperature range of 1500–1900 °C. The boron carbide ceramics prepared by this method showed a hardness of 37 GPa, which is very close to the hardness of mono-crystal boron carbide. The study showed that the boron carbide grains are uniformly sized without observed grain growth in the sintered materials. Obtained results revealed that high-pressure sintering can be a very effective low-temperature densification method for the obtainment of additive-free B4C ceramics. Moreover, the process can be scaled-up for the production of large-size composites required in various cutting tools and other extreme condition applications.
T2  - Materials Letters
T1  - Densification of boron carbide under high pressure
VL  - 314
SP  - 131877
DO  - 10.1016/j.matlet.2022.131877
ER  - 
@article{
author = "Matović, Branko and Urbanovich, Vladimir and Girman, Vladimir and Lisnichuk, Maksym and Nikolić, Dobrica and Erčić, Jelena and Cvijović-Alagić, Ivana",
year = "2022",
abstract = "Additive-free boron carbide (B4C) powders were densified at 4 GPa using the high-pressure “anvil-type with hollows” apparatus in the temperature range of 1500–1900 °C. The boron carbide ceramics prepared by this method showed a hardness of 37 GPa, which is very close to the hardness of mono-crystal boron carbide. The study showed that the boron carbide grains are uniformly sized without observed grain growth in the sintered materials. Obtained results revealed that high-pressure sintering can be a very effective low-temperature densification method for the obtainment of additive-free B4C ceramics. Moreover, the process can be scaled-up for the production of large-size composites required in various cutting tools and other extreme condition applications.",
journal = "Materials Letters",
title = "Densification of boron carbide under high pressure",
volume = "314",
pages = "131877",
doi = "10.1016/j.matlet.2022.131877"
}
Matović, B., Urbanovich, V., Girman, V., Lisnichuk, M., Nikolić, D., Erčić, J.,& Cvijović-Alagić, I.. (2022). Densification of boron carbide under high pressure. in Materials Letters, 314, 131877.
https://doi.org/10.1016/j.matlet.2022.131877
Matović B, Urbanovich V, Girman V, Lisnichuk M, Nikolić D, Erčić J, Cvijović-Alagić I. Densification of boron carbide under high pressure. in Materials Letters. 2022;314:131877.
doi:10.1016/j.matlet.2022.131877 .
Matović, Branko, Urbanovich, Vladimir, Girman, Vladimir, Lisnichuk, Maksym, Nikolić, Dobrica, Erčić, Jelena, Cvijović-Alagić, Ivana, "Densification of boron carbide under high pressure" in Materials Letters, 314 (2022):131877,
https://doi.org/10.1016/j.matlet.2022.131877 . .
4
4