TY  - JOUR
AU  - Zarubica, Aleksandra R.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Radulovic, N.
AU  - Putanov, P.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5749
AB  - The quality of a straight-run fuel oil can be improved if saturated n-hydrocarbons of low octane number are converted to their branched counterparts. Poor reactivity of traditional catalysts in isomerization reactions imposed the need for the development of new catalysts among which noble metal promoted acid catalysts, liquid and/or solid acid catalysts take a prominent place. Sulfated zirconia and metal promoted sulfated zirconia exhibit high activity for the isomerization of light alkanes at low temperatures. The present paper highlights the original results which indicate that the modification of sulfated zirconia by incorporation of metals (platinum and rhenium) significantly affects catalytic performances in n-hydrocarbon conversion reactions. Favourable activity/selectivity of the promoted sulfated zirconia depends on the crystal phase composition, critical crystallites sizes, platinum dispersion, total acidity and type of acidity. Attention is also paid to the recently developed solid acid catalysts used in other conversion reactions of hydrocarbons.
T2  - Russian Journal of Physical Chemistry A
T1  - n-hydrocarbons conversions over metal-modified solid acid catalysts
VL  - 87
IS  - 13
SP  - 2166
EP  - 2175
DO  - 10.1134/S0036024413130281
ER  - 

@article{
author = "Zarubica, Aleksandra R. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Radulovic, N. and Putanov, P.",
year = "2013",
abstract = "The quality of a straight-run fuel oil can be improved if saturated n-hydrocarbons of low octane number are converted to their branched counterparts. Poor reactivity of traditional catalysts in isomerization reactions imposed the need for the development of new catalysts among which noble metal promoted acid catalysts, liquid and/or solid acid catalysts take a prominent place. Sulfated zirconia and metal promoted sulfated zirconia exhibit high activity for the isomerization of light alkanes at low temperatures. The present paper highlights the original results which indicate that the modification of sulfated zirconia by incorporation of metals (platinum and rhenium) significantly affects catalytic performances in n-hydrocarbon conversion reactions. Favourable activity/selectivity of the promoted sulfated zirconia depends on the crystal phase composition, critical crystallites sizes, platinum dispersion, total acidity and type of acidity. Attention is also paid to the recently developed solid acid catalysts used in other conversion reactions of hydrocarbons.",
journal = "Russian Journal of Physical Chemistry A",
title = "n-hydrocarbons conversions over metal-modified solid acid catalysts",
volume = "87",
number = "13",
pages = "2166-2175",
doi = "10.1134/S0036024413130281"
}

Zarubica, A. R., Ranđelović, M. S., Momčilović, M. Z., Radulovic, N.,& Putanov, P.. (2013). n-hydrocarbons conversions over metal-modified solid acid catalysts. in Russian Journal of Physical Chemistry A, 87(13), 2166-2175.
https://doi.org/10.1134/S0036024413130281

Zarubica AR, Ranđelović MS, Momčilović MZ, Radulovic N, Putanov P. n-hydrocarbons conversions over metal-modified solid acid catalysts. in Russian Journal of Physical Chemistry A. 2013;87(13):2166-2175.
doi:10.1134/S0036024413130281 .

Zarubica, Aleksandra R., Ranđelović, Marjan S., Momčilović, Milan Z., Radulovic, N., Putanov, P., "n-hydrocarbons conversions over metal-modified solid acid catalysts" in Russian Journal of Physical Chemistry A, 87, no. 13 (2013):2166-2175,
https://doi.org/10.1134/S0036024413130281 . .