TY  - JOUR
AU  - Cocić, Mira B.
AU  - Logar, Mihovil M.
AU  - Cocić, Saša
AU  - Živković, Dragana T.
AU  - Matović, Branko
AU  - Dević, Snežana S.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3814
AB  - Roasting process of sulphide copper concentrates in fluo-solid reactor is an oxidation process, and presents the first stage of copper concentrate processing in Copper Mining and Smelting Complex Bor, RTB Bor. Therefore, the importance of accurate and up to date process control is an apparent precondition for the correct treatment in the following stages and also for of high grade cathode copper. As concentrate is fed into the roaster, it is heated by a stream of hot air to about 590 degrees C. The process takes place between solid and gaseous phases without the appearance of a liquid phase. The heat generated by the exothermic oxidation reaction of sulphur from cooper and iron minerals (chalcopyrite and pyrite) is sufficient to carry out the entire process autogenously at temperature from 620 to 670 degrees C. The temperature of sulphur firing which defines the start of roasting depends on physical traits, particle size of sulfides and characteristic product of oxidation. The obtained products of the roasting process are: calcine, ready for smelting in the furnace and gas-rich sulphure dioxide (SO(2)) well suited for the production of sulfuric acid. The relationship between the quantitative mineral composition of the charge and of the calcine directly points out to the efficiency of the roasting process in fluo-solid reactor. The amount of bornite and magnetite, resulting from the sulfide oxidation is the most important parameter. Hence, quantitative determination of mineral composition is of great interest. In this work, the results of the determination of quantitative mineral composition of the copper sulphide concentrate (charge) and products of their roasting (calcine and overflow) in fluo-solid reactor in the RTB; Bor are presented. The aim was to compare the results of the iron, copper, sulfur and oxygen contents determined by two independent techniques, the chemical (HA) and X-ray powder diffraction analysis (XRPD) that is based on the quantitative mineral composition. Differences in the obtained results are evident, but small enough to confirm the reliability of measurement.
T2  - Hemijska industrija
T1  - Determination of Sulphide Concentrates of Ore Copper By Xrpd and Chemical Analysis
VL  - 63
IS  - 4
SP  - 319
EP  - 324
DO  - 10.2298/HEMIND0904319C
ER  - 

@article{
author = "Cocić, Mira B. and Logar, Mihovil M. and Cocić, Saša and Živković, Dragana T. and Matović, Branko and Dević, Snežana S.",
year = "2009",
abstract = "Roasting process of sulphide copper concentrates in fluo-solid reactor is an oxidation process, and presents the first stage of copper concentrate processing in Copper Mining and Smelting Complex Bor, RTB Bor. Therefore, the importance of accurate and up to date process control is an apparent precondition for the correct treatment in the following stages and also for of high grade cathode copper. As concentrate is fed into the roaster, it is heated by a stream of hot air to about 590 degrees C. The process takes place between solid and gaseous phases without the appearance of a liquid phase. The heat generated by the exothermic oxidation reaction of sulphur from cooper and iron minerals (chalcopyrite and pyrite) is sufficient to carry out the entire process autogenously at temperature from 620 to 670 degrees C. The temperature of sulphur firing which defines the start of roasting depends on physical traits, particle size of sulfides and characteristic product of oxidation. The obtained products of the roasting process are: calcine, ready for smelting in the furnace and gas-rich sulphure dioxide (SO(2)) well suited for the production of sulfuric acid. The relationship between the quantitative mineral composition of the charge and of the calcine directly points out to the efficiency of the roasting process in fluo-solid reactor. The amount of bornite and magnetite, resulting from the sulfide oxidation is the most important parameter. Hence, quantitative determination of mineral composition is of great interest. In this work, the results of the determination of quantitative mineral composition of the copper sulphide concentrate (charge) and products of their roasting (calcine and overflow) in fluo-solid reactor in the RTB; Bor are presented. The aim was to compare the results of the iron, copper, sulfur and oxygen contents determined by two independent techniques, the chemical (HA) and X-ray powder diffraction analysis (XRPD) that is based on the quantitative mineral composition. Differences in the obtained results are evident, but small enough to confirm the reliability of measurement.",
journal = "Hemijska industrija",
title = "Determination of Sulphide Concentrates of Ore Copper By Xrpd and Chemical Analysis",
volume = "63",
number = "4",
pages = "319-324",
doi = "10.2298/HEMIND0904319C"
}

Cocić, M. B., Logar, M. M., Cocić, S., Živković, D. T., Matović, B.,& Dević, S. S.. (2009). Determination of Sulphide Concentrates of Ore Copper By Xrpd and Chemical Analysis. in Hemijska industrija, 63(4), 319-324.
https://doi.org/10.2298/HEMIND0904319C

Cocić MB, Logar MM, Cocić S, Živković DT, Matović B, Dević SS. Determination of Sulphide Concentrates of Ore Copper By Xrpd and Chemical Analysis. in Hemijska industrija. 2009;63(4):319-324.
doi:10.2298/HEMIND0904319C .

Cocić, Mira B., Logar, Mihovil M., Cocić, Saša, Živković, Dragana T., Matović, Branko, Dević, Snežana S., "Determination of Sulphide Concentrates of Ore Copper By Xrpd and Chemical Analysis" in Hemijska industrija, 63, no. 4 (2009):319-324,
https://doi.org/10.2298/HEMIND0904319C . .