TY  - JOUR
AU  - Gilić, Martina D.
AU  - Petrović, Milica S.
AU  - Kostić, Radmila
AU  - Stojanović, Dušanka
AU  - Barudžija, Tanja
AU  - Mitrić, Miodrag
AU  - Romčević, Nebojša Ž.
AU  - Ralević, Uroš
AU  - Trajić, Jelena
AU  - Romčević, Maja J.
AU  - Yahia, Ibrahim S.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1116
AB  - This paper describes the structural and optical properties of Cu-Se thin films. The surface morphology of thin films was investigated by atomic force microscopy (AFM) and scanning electron microscopy (SEM). Formation of Cu-Se thin films is concluded to proceed unevenly, in the form of islands which later grew into agglomerates. The structural characterization of Cu-Se thin film was investigated using X-ray diffraction pattern (XRD). The presence of two-phase system is observed. One is the solid solution of Cu in Se and the other is low-pressure modification of CuSe2. The Raman spectroscopy was used to identify and quantify the individual phases present in the Cu-Se films. Red shift and asymmetry of Raman mode characteristic for CuSe2 enable us to estimate nanocrystal dimension. In the analysis of the far infrared reflection spectra, numerical model for calculating the reflectivity coefficient of layered system, which includes film with nanocrystalite inclusions (modeled by Maxwell -Garnett approximation) and substrate, has been applied. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Infrared Physics and Technology
T1  - Structural and optical properties of CuSe2 nanocrystals formed in thin solid Cu-Se film
VL  - 76
SP  - 276
EP  - 284
DO  - 10.1016/j.infrared.2016.03.008
ER  - 

@article{
author = "Gilić, Martina D. and Petrović, Milica S. and Kostić, Radmila and Stojanović, Dušanka and Barudžija, Tanja and Mitrić, Miodrag and Romčević, Nebojša Ž. and Ralević, Uroš and Trajić, Jelena and Romčević, Maja J. and Yahia, Ibrahim S.",
year = "2016",
abstract = "This paper describes the structural and optical properties of Cu-Se thin films. The surface morphology of thin films was investigated by atomic force microscopy (AFM) and scanning electron microscopy (SEM). Formation of Cu-Se thin films is concluded to proceed unevenly, in the form of islands which later grew into agglomerates. The structural characterization of Cu-Se thin film was investigated using X-ray diffraction pattern (XRD). The presence of two-phase system is observed. One is the solid solution of Cu in Se and the other is low-pressure modification of CuSe2. The Raman spectroscopy was used to identify and quantify the individual phases present in the Cu-Se films. Red shift and asymmetry of Raman mode characteristic for CuSe2 enable us to estimate nanocrystal dimension. In the analysis of the far infrared reflection spectra, numerical model for calculating the reflectivity coefficient of layered system, which includes film with nanocrystalite inclusions (modeled by Maxwell -Garnett approximation) and substrate, has been applied. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Infrared Physics and Technology",
title = "Structural and optical properties of CuSe2 nanocrystals formed in thin solid Cu-Se film",
volume = "76",
pages = "276-284",
doi = "10.1016/j.infrared.2016.03.008"
}

Gilić, M. D., Petrović, M. S., Kostić, R., Stojanović, D., Barudžija, T., Mitrić, M., Romčević, N. Ž., Ralević, U., Trajić, J., Romčević, M. J.,& Yahia, I. S.. (2016). Structural and optical properties of CuSe2 nanocrystals formed in thin solid Cu-Se film. in Infrared Physics and Technology, 76, 276-284.
https://doi.org/10.1016/j.infrared.2016.03.008

Gilić MD, Petrović MS, Kostić R, Stojanović D, Barudžija T, Mitrić M, Romčević NŽ, Ralević U, Trajić J, Romčević MJ, Yahia IS. Structural and optical properties of CuSe2 nanocrystals formed in thin solid Cu-Se film. in Infrared Physics and Technology. 2016;76:276-284.
doi:10.1016/j.infrared.2016.03.008 .

Gilić, Martina D., Petrović, Milica S., Kostić, Radmila, Stojanović, Dušanka, Barudžija, Tanja, Mitrić, Miodrag, Romčević, Nebojša Ž., Ralević, Uroš, Trajić, Jelena, Romčević, Maja J., Yahia, Ibrahim S., "Structural and optical properties of CuSe2 nanocrystals formed in thin solid Cu-Se film" in Infrared Physics and Technology, 76 (2016):276-284,
https://doi.org/10.1016/j.infrared.2016.03.008 . .

TY  - JOUR
AU  - Trajić, Jelena
AU  - Kostić, Radmila
AU  - Romčević, Nebojša Ž.
AU  - Romčević, Maja J.
AU  - Mitrić, Miodrag
AU  - Lazović, Vladimir M.
AU  - Balaž, Peter
AU  - Stojanović, Dušanka
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/509
AB  - ZnS nanoparticles were synthesized mechanochemically by high-energy milling. In order to investigate influence off milling time to sample properties, samples were produced in three different milling times (5 min, 10 min and 20 min). The morphology of samples has been investigated by scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). X-ray diffraction (XRD) investigation of synthesized nanocrystals identified cubic structure. From XRD, ZnS size of crystallites was estimated as 1.9 nm (after 5 min milling time), 2.3 nm (10 min) and 2.4 nm (20 min), implying that we are in strong confinement regime. The optical properties were studied by Raman spectroscopy, in spectral region 100-500 cm(-1), excitation source was 514.5 nm (E-L = 2.41 eV), which means that we are in off resonant regime. Dominant spectral structures, of comparable intensity, are registered in spectral region 130-180 cm(-1), around 265 cm(-1) and around 345 cm(-1). First two are assigned as second-order ZnS modes. A theoretical model of continuum medium was used to calculate frequencies of the confined optical phonons in ZnS. Satisfactory agreement with experimental results was found and mode at 345 cm(-)1 is assigned as LO type phonon confined in ZnS nanocrystal. (C) 2015 Elsevier B.V. All rights reserved.
T2  - Journal of Alloys and Compounds
T1  - Raman spectroscopy of ZnS quantum dots
VL  - 637
SP  - 401
EP  - 406
DO  - 10.1016/j.jallcom.2015.03.027
ER  - 

@article{
author = "Trajić, Jelena and Kostić, Radmila and Romčević, Nebojša Ž. and Romčević, Maja J. and Mitrić, Miodrag and Lazović, Vladimir M. and Balaž, Peter and Stojanović, Dušanka",
year = "2015",
abstract = "ZnS nanoparticles were synthesized mechanochemically by high-energy milling. In order to investigate influence off milling time to sample properties, samples were produced in three different milling times (5 min, 10 min and 20 min). The morphology of samples has been investigated by scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). X-ray diffraction (XRD) investigation of synthesized nanocrystals identified cubic structure. From XRD, ZnS size of crystallites was estimated as 1.9 nm (after 5 min milling time), 2.3 nm (10 min) and 2.4 nm (20 min), implying that we are in strong confinement regime. The optical properties were studied by Raman spectroscopy, in spectral region 100-500 cm(-1), excitation source was 514.5 nm (E-L = 2.41 eV), which means that we are in off resonant regime. Dominant spectral structures, of comparable intensity, are registered in spectral region 130-180 cm(-1), around 265 cm(-1) and around 345 cm(-1). First two are assigned as second-order ZnS modes. A theoretical model of continuum medium was used to calculate frequencies of the confined optical phonons in ZnS. Satisfactory agreement with experimental results was found and mode at 345 cm(-)1 is assigned as LO type phonon confined in ZnS nanocrystal. (C) 2015 Elsevier B.V. All rights reserved.",
journal = "Journal of Alloys and Compounds",
title = "Raman spectroscopy of ZnS quantum dots",
volume = "637",
pages = "401-406",
doi = "10.1016/j.jallcom.2015.03.027"
}

Trajić, J., Kostić, R., Romčević, N. Ž., Romčević, M. J., Mitrić, M., Lazović, V. M., Balaž, P.,& Stojanović, D.. (2015). Raman spectroscopy of ZnS quantum dots. in Journal of Alloys and Compounds, 637, 401-406.
https://doi.org/10.1016/j.jallcom.2015.03.027

Trajić J, Kostić R, Romčević NŽ, Romčević MJ, Mitrić M, Lazović VM, Balaž P, Stojanović D. Raman spectroscopy of ZnS quantum dots. in Journal of Alloys and Compounds. 2015;637:401-406.
doi:10.1016/j.jallcom.2015.03.027 .

Trajić, Jelena, Kostić, Radmila, Romčević, Nebojša Ž., Romčević, Maja J., Mitrić, Miodrag, Lazović, Vladimir M., Balaž, Peter, Stojanović, Dušanka, "Raman spectroscopy of ZnS quantum dots" in Journal of Alloys and Compounds, 637 (2015):401-406,
https://doi.org/10.1016/j.jallcom.2015.03.027 . .

TY  - JOUR
AU  - Kostić, Radmila
AU  - Damjanovic, M. Petrovic
AU  - Romčević, Nebojša Ž.
AU  - Romčević, Maja J.
AU  - Stojanović, Dušanka
AU  - Čomor, Mirjana
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4714
AB  - Far-infrared reflectivity spectra, in spectral region 50-600 cm(-1) and temperature region 80-300 K, of CdS and Cd1-xMnxS nanocrystals embedded in hexametaphosphate, are presented. The analysis of the far-infrared experimental reflectivity spectrum was made by the fitting procedure. The Maxwell-Garnet effective medium theory is used for modeling an effective dielectric function as well as to separate respond from nanoparticles. To analyze spectra in CdS omega(TO)(approximate to 238 cm(-1)) to omega(TO)(approximate to 305 cm(-1)) spectral region, quantized dipolar modes in a spherical isotropic material quantum dot (QD) are considered in the framework of a continuum model. As to the mechanical boundary conditions rigid sphere is concerned. Experimental far-infrared reflectivity spectra of our samples are in general agreement with the predictions of this model. Experimentally registered and through fitting procedure located features for CdS nanoparticles in spectral region below CdS omega(TO) at: approximate to 102 cm(-1), approximate to 135 cm(-1), approximate to 170 cm(-1) and approximate to 210 cm(-1) are associated to defect induced modes, especially to defects located near the surface of CdS QD. In region over CdS omega(LO), modes are identified as multiphonons. In Cd1-xMnxS QD spectra new reflectivity peaks are at: approximate to 85 cm(-1), approximate to 110 cm(-1) and approximate to 180 cm(-1) in spectral region below CdS omega(TO), approximate to 270 cm(-1) inside CdS omega(TO)-omega(LO) spectral region and approximate to 356 cm(-1) and approximate to 376 cm(-1) in region over CdS omega(LO). First two registered modes are associated to both mass and force constant defects at the surface, and rest four modes are consequence of MnS phases present in the sample. (C) 2012 Published by Elsevier B.V.
T2  - Journal of Alloys and Compounds
T1  - Far-infrared spectroscopy of Cd1-xMnxS quantum dots
VL  - 521
SP  - 134
EP  - 140
DO  - 10.1016/j.jallcom.2012.01.079
ER  - 

@article{
author = "Kostić, Radmila and Damjanovic, M. Petrovic and Romčević, Nebojša Ž. and Romčević, Maja J. and Stojanović, Dušanka and Čomor, Mirjana",
year = "2012",
abstract = "Far-infrared reflectivity spectra, in spectral region 50-600 cm(-1) and temperature region 80-300 K, of CdS and Cd1-xMnxS nanocrystals embedded in hexametaphosphate, are presented. The analysis of the far-infrared experimental reflectivity spectrum was made by the fitting procedure. The Maxwell-Garnet effective medium theory is used for modeling an effective dielectric function as well as to separate respond from nanoparticles. To analyze spectra in CdS omega(TO)(approximate to 238 cm(-1)) to omega(TO)(approximate to 305 cm(-1)) spectral region, quantized dipolar modes in a spherical isotropic material quantum dot (QD) are considered in the framework of a continuum model. As to the mechanical boundary conditions rigid sphere is concerned. Experimental far-infrared reflectivity spectra of our samples are in general agreement with the predictions of this model. Experimentally registered and through fitting procedure located features for CdS nanoparticles in spectral region below CdS omega(TO) at: approximate to 102 cm(-1), approximate to 135 cm(-1), approximate to 170 cm(-1) and approximate to 210 cm(-1) are associated to defect induced modes, especially to defects located near the surface of CdS QD. In region over CdS omega(LO), modes are identified as multiphonons. In Cd1-xMnxS QD spectra new reflectivity peaks are at: approximate to 85 cm(-1), approximate to 110 cm(-1) and approximate to 180 cm(-1) in spectral region below CdS omega(TO), approximate to 270 cm(-1) inside CdS omega(TO)-omega(LO) spectral region and approximate to 356 cm(-1) and approximate to 376 cm(-1) in region over CdS omega(LO). First two registered modes are associated to both mass and force constant defects at the surface, and rest four modes are consequence of MnS phases present in the sample. (C) 2012 Published by Elsevier B.V.",
journal = "Journal of Alloys and Compounds",
title = "Far-infrared spectroscopy of Cd1-xMnxS quantum dots",
volume = "521",
pages = "134-140",
doi = "10.1016/j.jallcom.2012.01.079"
}

Kostić, R., Damjanovic, M. P., Romčević, N. Ž., Romčević, M. J., Stojanović, D.,& Čomor, M.. (2012). Far-infrared spectroscopy of Cd1-xMnxS quantum dots. in Journal of Alloys and Compounds, 521, 134-140.
https://doi.org/10.1016/j.jallcom.2012.01.079

Kostić R, Damjanovic MP, Romčević NŽ, Romčević MJ, Stojanović D, Čomor M. Far-infrared spectroscopy of Cd1-xMnxS quantum dots. in Journal of Alloys and Compounds. 2012;521:134-140.
doi:10.1016/j.jallcom.2012.01.079 .

Kostić, Radmila, Damjanovic, M. Petrovic, Romčević, Nebojša Ž., Romčević, Maja J., Stojanović, Dušanka, Čomor, Mirjana, "Far-infrared spectroscopy of Cd1-xMnxS quantum dots" in Journal of Alloys and Compounds, 521 (2012):134-140,
https://doi.org/10.1016/j.jallcom.2012.01.079 . .