TY  - JOUR
AU  - Sovilj, Sofija P.
AU  - Babic-Samardzija, K
AU  - Minic, DM
AU  - Stojić, Dragica Lj.
PY  - 2000
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6316
AB  - The thermal properties of four cobalt(III) complexes with cyclam (1,4,8,11-tetraazacyclotetradecane) and the heterocyclic dithiocarbamates Rdtc(-) [2-, 3-, 4-methylpiperidine (2-, 3-, 4-Mepipdtc(-)) or 4-thiomorpholine (Timdtc(-)) dithiocarbamates], of the general formula [Co(Rdtc)cyclam](ClO4)(2), have been investigated by thermogravimetry (TG) and differential scanning calorimetry (DSC). The thermal decomposition pathways of these complexes were also proposed. The following thermal stability order can be recognized for the examined complexes. depending on the position of the methyl group on the piperidine ring coordinating dithiocarbamates 2- GT 3- GT 4 -Mepipdtc(-). Generally, the same order was found to affect the decrease in kinetic and activation parameters.
T2  - Materials Science Forum
T1  - Thermal stability and kinetic studies of new cobalt(III) complexes with a tetraazamacrocyclic and dithiocarbamate ligands
VL  - 352
SP  - 271
EP  - 276
DO  - 10.4028/www.scientific.net/MSF.352.271
ER  - 

@article{
author = "Sovilj, Sofija P. and Babic-Samardzija, K and Minic, DM and Stojić, Dragica Lj.",
year = "2000",
abstract = "The thermal properties of four cobalt(III) complexes with cyclam (1,4,8,11-tetraazacyclotetradecane) and the heterocyclic dithiocarbamates Rdtc(-) [2-, 3-, 4-methylpiperidine (2-, 3-, 4-Mepipdtc(-)) or 4-thiomorpholine (Timdtc(-)) dithiocarbamates], of the general formula [Co(Rdtc)cyclam](ClO4)(2), have been investigated by thermogravimetry (TG) and differential scanning calorimetry (DSC). The thermal decomposition pathways of these complexes were also proposed. The following thermal stability order can be recognized for the examined complexes. depending on the position of the methyl group on the piperidine ring coordinating dithiocarbamates 2- GT 3- GT 4 -Mepipdtc(-). Generally, the same order was found to affect the decrease in kinetic and activation parameters.",
journal = "Materials Science Forum",
title = "Thermal stability and kinetic studies of new cobalt(III) complexes with a tetraazamacrocyclic and dithiocarbamate ligands",
volume = "352",
pages = "271-276",
doi = "10.4028/www.scientific.net/MSF.352.271"
}

Sovilj, S. P., Babic-Samardzija, K., Minic, D.,& Stojić, D. Lj.. (2000). Thermal stability and kinetic studies of new cobalt(III) complexes with a tetraazamacrocyclic and dithiocarbamate ligands. in Materials Science Forum, 352, 271-276.
https://doi.org/10.4028/www.scientific.net/MSF.352.271

Sovilj SP, Babic-Samardzija K, Minic D, Stojić DL. Thermal stability and kinetic studies of new cobalt(III) complexes with a tetraazamacrocyclic and dithiocarbamate ligands. in Materials Science Forum. 2000;352:271-276.
doi:10.4028/www.scientific.net/MSF.352.271 .

Sovilj, Sofija P., Babic-Samardzija, K, Minic, DM, Stojić, Dragica Lj., "Thermal stability and kinetic studies of new cobalt(III) complexes with a tetraazamacrocyclic and dithiocarbamate ligands" in Materials Science Forum, 352 (2000):271-276,
https://doi.org/10.4028/www.scientific.net/MSF.352.271 . .