TY  - JOUR
AU  - Ilić, A.
AU  - Antić, Bratislav
AU  - Poleti, Dejan
AU  - Rodić, Dubravko
AU  - Petrović-Prelević, Irena
AU  - Karanović, Ljiljana
PY  - 1996
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1973
AB  - The series of spinels Zn2.33-xCoxSb0.67O4 (0.23 less than or equal to x less than or equal to 2.33) was prepared by ceramic technology. The crystal structures were refined from the x-ray diffraction data using the Rietveld profile method. The high-temperature magnetic susceptibility was measured by the Faraday method in the temperature range 290-600 K and the data were fitted to the Curie-Weiss law. The cation distribution in these diluted magnetics is obtained from x-ray diffraction and high-temperature magnetic susceptibility measurements. It was found that, for x less than or equal to 0.93 Co2+, ions occupy exclusively the octahedral position in the spinel type of structure. In the low-concentration region a strong clustering of magnetic ions is observed. In the range 1.33 less than or equal to x less than or equal to 2.33, Co2+ ions are distributed in both tetrahedral and octahedral cationic sites. The Curie-Weiss paramagnetic temperature Theta is negative in the whole range of concentrations, as the consequence of a predominant antiferromagnetic interaction. The appearance of the Co2+ ions in tetrahedral sites (around x = 1.33) leads to a drop in the absolute Theta-value. The effective magnetic moments of Co2+ ions are about 4.60(mu B) for x less than or equal to 1.33 and depend on the Co2+ concentration for x GT 1.33.
T2  - Journal of Physics: Condensed Matter
T1  - Cation distribution and magnetic properties of ternary Zn2.33-xCO2Sb0.67O4 spinels
VL  - 8
IS  - 14
SP  - 2317
EP  - 2325
DO  - 10.1088/0953-8984/8/14/008
ER  - 

@article{
author = "Ilić, A. and Antić, Bratislav and Poleti, Dejan and Rodić, Dubravko and Petrović-Prelević, Irena and Karanović, Ljiljana",
year = "1996",
abstract = "The series of spinels Zn2.33-xCoxSb0.67O4 (0.23 less than or equal to x less than or equal to 2.33) was prepared by ceramic technology. The crystal structures were refined from the x-ray diffraction data using the Rietveld profile method. The high-temperature magnetic susceptibility was measured by the Faraday method in the temperature range 290-600 K and the data were fitted to the Curie-Weiss law. The cation distribution in these diluted magnetics is obtained from x-ray diffraction and high-temperature magnetic susceptibility measurements. It was found that, for x less than or equal to 0.93 Co2+, ions occupy exclusively the octahedral position in the spinel type of structure. In the low-concentration region a strong clustering of magnetic ions is observed. In the range 1.33 less than or equal to x less than or equal to 2.33, Co2+ ions are distributed in both tetrahedral and octahedral cationic sites. The Curie-Weiss paramagnetic temperature Theta is negative in the whole range of concentrations, as the consequence of a predominant antiferromagnetic interaction. The appearance of the Co2+ ions in tetrahedral sites (around x = 1.33) leads to a drop in the absolute Theta-value. The effective magnetic moments of Co2+ ions are about 4.60(mu B) for x less than or equal to 1.33 and depend on the Co2+ concentration for x GT 1.33.",
journal = "Journal of Physics: Condensed Matter",
title = "Cation distribution and magnetic properties of ternary Zn2.33-xCO2Sb0.67O4 spinels",
volume = "8",
number = "14",
pages = "2317-2325",
doi = "10.1088/0953-8984/8/14/008"
}

Ilić, A., Antić, B., Poleti, D., Rodić, D., Petrović-Prelević, I.,& Karanović, L.. (1996). Cation distribution and magnetic properties of ternary Zn2.33-xCO2Sb0.67O4 spinels. in Journal of Physics: Condensed Matter, 8(14), 2317-2325.
https://doi.org/10.1088/0953-8984/8/14/008

Ilić A, Antić B, Poleti D, Rodić D, Petrović-Prelević I, Karanović L. Cation distribution and magnetic properties of ternary Zn2.33-xCO2Sb0.67O4 spinels. in Journal of Physics: Condensed Matter. 1996;8(14):2317-2325.
doi:10.1088/0953-8984/8/14/008 .

Ilić, A., Antić, Bratislav, Poleti, Dejan, Rodić, Dubravko, Petrović-Prelević, Irena, Karanović, Ljiljana, "Cation distribution and magnetic properties of ternary Zn2.33-xCO2Sb0.67O4 spinels" in Journal of Physics: Condensed Matter, 8, no. 14 (1996):2317-2325,
https://doi.org/10.1088/0953-8984/8/14/008 . .