TY  - JOUR
AU  - Mutić, Tijana
AU  - Ognjanović, Miloš
AU  - Kodranov, Igor
AU  - Robić, Marko
AU  - Savić, Slađana
AU  - Krehula, Stjepko
AU  - Stanković, Dalibor M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10737
AB  - In this work, we investigated the morphological and electrochemical properties of gallium/bismuth mixed oxide. The bismuth concentration was varied from 0 to 100%. The correct ratio was determined with inductively coupled plasma-optical emission spectroscopy (ICP-OES), while surface characteristics were determined using scanning electron microscopy (SEM) and X-ray diffraction (XRD) measurement. Electrochemical characteristics were studied using electrochemical impedance spectroscopy (EIS) in the Fe2+/3+ couple. The obtained materials were tested for adrenaline detection. After square wave voltammetry (SWV) optimization, the best electrode showed a wide linear working range from 7 to 100 µM at pH 6 of the Britton–Robinson buffer solution (BRBS) supporting electrolyte. The limit of detection (LOD) for the proposed method was calculated as 1.9 µM, with a limit of quantification (LOQ) of 5.8 µM. The excellent selectivity of the proposed method, with good repeatability and reproducibility, strongly suggests the possible application of the procedure for the determination of adrenaline in artificially prepared real samples. The practical applicability with good recovery values indicates that the morphology of the materials is closely connected with other parameters, which further suggests that the developed approach can offer a low-cost, rapid, selective, and sensitive method for adrenaline monitoring. Graphical abstract: [Figure not available: see fulltext.] © 2023, Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - Analytical and Bioanalytical Chemistry
T1  - The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline
VL  - 415
SP  - 4445
EP  - 4458
DO  - 10.1007/s00216-023-04617-7
ER  - 

@article{
author = "Mutić, Tijana and Ognjanović, Miloš and Kodranov, Igor and Robić, Marko and Savić, Slađana and Krehula, Stjepko and Stanković, Dalibor M.",
year = "2023",
abstract = "In this work, we investigated the morphological and electrochemical properties of gallium/bismuth mixed oxide. The bismuth concentration was varied from 0 to 100%. The correct ratio was determined with inductively coupled plasma-optical emission spectroscopy (ICP-OES), while surface characteristics were determined using scanning electron microscopy (SEM) and X-ray diffraction (XRD) measurement. Electrochemical characteristics were studied using electrochemical impedance spectroscopy (EIS) in the Fe2+/3+ couple. The obtained materials were tested for adrenaline detection. After square wave voltammetry (SWV) optimization, the best electrode showed a wide linear working range from 7 to 100 µM at pH 6 of the Britton–Robinson buffer solution (BRBS) supporting electrolyte. The limit of detection (LOD) for the proposed method was calculated as 1.9 µM, with a limit of quantification (LOQ) of 5.8 µM. The excellent selectivity of the proposed method, with good repeatability and reproducibility, strongly suggests the possible application of the procedure for the determination of adrenaline in artificially prepared real samples. The practical applicability with good recovery values indicates that the morphology of the materials is closely connected with other parameters, which further suggests that the developed approach can offer a low-cost, rapid, selective, and sensitive method for adrenaline monitoring. Graphical abstract: [Figure not available: see fulltext.] © 2023, Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "Analytical and Bioanalytical Chemistry",
title = "The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline",
volume = "415",
pages = "4445-4458",
doi = "10.1007/s00216-023-04617-7"
}

Mutić, T., Ognjanović, M., Kodranov, I., Robić, M., Savić, S., Krehula, S.,& Stanković, D. M.. (2023). The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline. in Analytical and Bioanalytical Chemistry, 415, 4445-4458.
https://doi.org/10.1007/s00216-023-04617-7

Mutić T, Ognjanović M, Kodranov I, Robić M, Savić S, Krehula S, Stanković DM. The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline. in Analytical and Bioanalytical Chemistry. 2023;415:4445-4458.
doi:10.1007/s00216-023-04617-7 .

Mutić, Tijana, Ognjanović, Miloš, Kodranov, Igor, Robić, Marko, Savić, Slađana, Krehula, Stjepko, Stanković, Dalibor M., "The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline" in Analytical and Bioanalytical Chemistry, 415 (2023):4445-4458,
https://doi.org/10.1007/s00216-023-04617-7 . .

TY  - JOUR
AU  - Knežević, Sara
AU  - Ostojić, Jelena
AU  - Ognjanović, Miloš
AU  - Savić, Slađana
AU  - Kovačević, Aleksandra
AU  - Manojlović, Dragan
AU  - Stanković, Vesna
AU  - Stanković, Dalibor M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10468
AB  - Triclosan (TCS) is a polychlorinated phenoxy phenol (PCPPs) used as a disinfectant and a broad-spectrum antibacterial and antifungal agent in personal hygiene products. TCS easily forms diphenyl ethers and dioxins, which are persistent organic pollutants. This work used a double approach for the TSC sensing: a) screen-printed (SPE) electrochemical platform for on-site application, modified with lanthanum iron oxide and graphitic carbon nitride composite (LaFeO3/Fe2O3@g-C3N4/SPE); and b) carbon paste electrode (CPE), modified with the same material and used in laboratory conditions. Linear range from 0.1 μM to 10 μM, the limit of detection (LOD) of 29 nM and the limit of quantification (LOQ) of 91 nM were obtained for CP electrode in BRBS pH 8. SPE showed the best analytical parameters in BRBS at pH 3, with a linear range from 0.3 μM to 7 μM, LOD of 0.09 μM and LOQ of 0.28 μM. Furthermore, the influence of potential interferents was investigated and proven to be negligible. Determination of TSC was performed to estimate the environmental impact of this compound as well as the practical usefulness of the proposed sensor in the real sample analysis, confirmed with a HPLC analysis. © 2022 Elsevier B.V.
T2  - Science of the Total Environment
T1  - The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan
VL  - 857
DO  - 10.1016/j.scitotenv.2022.159250
ER  - 

@article{
author = "Knežević, Sara and Ostojić, Jelena and Ognjanović, Miloš and Savić, Slađana and Kovačević, Aleksandra and Manojlović, Dragan and Stanković, Vesna and Stanković, Dalibor M.",
year = "2023",
abstract = "Triclosan (TCS) is a polychlorinated phenoxy phenol (PCPPs) used as a disinfectant and a broad-spectrum antibacterial and antifungal agent in personal hygiene products. TCS easily forms diphenyl ethers and dioxins, which are persistent organic pollutants. This work used a double approach for the TSC sensing: a) screen-printed (SPE) electrochemical platform for on-site application, modified with lanthanum iron oxide and graphitic carbon nitride composite (LaFeO3/Fe2O3@g-C3N4/SPE); and b) carbon paste electrode (CPE), modified with the same material and used in laboratory conditions. Linear range from 0.1 μM to 10 μM, the limit of detection (LOD) of 29 nM and the limit of quantification (LOQ) of 91 nM were obtained for CP electrode in BRBS pH 8. SPE showed the best analytical parameters in BRBS at pH 3, with a linear range from 0.3 μM to 7 μM, LOD of 0.09 μM and LOQ of 0.28 μM. Furthermore, the influence of potential interferents was investigated and proven to be negligible. Determination of TSC was performed to estimate the environmental impact of this compound as well as the practical usefulness of the proposed sensor in the real sample analysis, confirmed with a HPLC analysis. © 2022 Elsevier B.V.",
journal = "Science of the Total Environment",
title = "The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan",
volume = "857",
doi = "10.1016/j.scitotenv.2022.159250"
}

Knežević, S., Ostojić, J., Ognjanović, M., Savić, S., Kovačević, A., Manojlović, D., Stanković, V.,& Stanković, D. M.. (2023). The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan. in Science of the Total Environment, 857.
https://doi.org/10.1016/j.scitotenv.2022.159250

Knežević S, Ostojić J, Ognjanović M, Savić S, Kovačević A, Manojlović D, Stanković V, Stanković DM. The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan. in Science of the Total Environment. 2023;857.
doi:10.1016/j.scitotenv.2022.159250 .

Knežević, Sara, Ostojić, Jelena, Ognjanović, Miloš, Savić, Slađana, Kovačević, Aleksandra, Manojlović, Dragan, Stanković, Vesna, Stanković, Dalibor M., "The environmentally friendly approaches based on the heterojunction interface of the LaFeO3/Fe2O3@g-C3N4 composite for the disposable and laboratory sensing of triclosan" in Science of the Total Environment, 857 (2023),
https://doi.org/10.1016/j.scitotenv.2022.159250 . .

TY  - JOUR
AU  - Korina, Elena
AU  - Abramyan, Anton
AU  - Bol’shakov, Oleg
AU  - Avdin, Vyacheslav V.
AU  - Savić, Slađana
AU  - Manojlović, Dragan D.
AU  - Stanković, Vesna
AU  - Stanković, Dalibor M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10621
AB  - Stable, water-soluble titanium complexed with mandelic acid was used as a precursor for titanium phosphorus double oxide obtained in hydrothermal conditions in the presence of phosphoric acid. Surprisingly, hydrolysis of organic complexes provided a microstructured sphere with narrow size distribution, low aggregation and a small fraction of morphological irregularities. Obtained microspheres had a complex structure comprised of flakes, whose size could be manipulated with temperature conditions. Samples were found to be electrochemically active against sulcotrione, a well-recognized herbicide. Electrochemical sensors based on the synthesized microspheres were successfully adapted for natural water reservoir analysis and exhibited low levels of detection of 0.61 µM, limit of quantification of 1.86 µM, wide dynamic linear range from 2 to 200 µM, good selectivity, excellent reproducibility and in-time stability.
T2  - Sensors
T1  - Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications
VL  - 23
IS  - 2
SP  - 933
DO  - 10.3390/s23020933
ER  - 

@article{
author = "Korina, Elena and Abramyan, Anton and Bol’shakov, Oleg and Avdin, Vyacheslav V. and Savić, Slađana and Manojlović, Dragan D. and Stanković, Vesna and Stanković, Dalibor M.",
year = "2023",
abstract = "Stable, water-soluble titanium complexed with mandelic acid was used as a precursor for titanium phosphorus double oxide obtained in hydrothermal conditions in the presence of phosphoric acid. Surprisingly, hydrolysis of organic complexes provided a microstructured sphere with narrow size distribution, low aggregation and a small fraction of morphological irregularities. Obtained microspheres had a complex structure comprised of flakes, whose size could be manipulated with temperature conditions. Samples were found to be electrochemically active against sulcotrione, a well-recognized herbicide. Electrochemical sensors based on the synthesized microspheres were successfully adapted for natural water reservoir analysis and exhibited low levels of detection of 0.61 µM, limit of quantification of 1.86 µM, wide dynamic linear range from 2 to 200 µM, good selectivity, excellent reproducibility and in-time stability.",
journal = "Sensors",
title = "Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications",
volume = "23",
number = "2",
pages = "933",
doi = "10.3390/s23020933"
}

Korina, E., Abramyan, A., Bol’shakov, O., Avdin, V. V., Savić, S., Manojlović, D. D., Stanković, V.,& Stanković, D. M.. (2023). Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications. in Sensors, 23(2), 933.
https://doi.org/10.3390/s23020933

Korina E, Abramyan A, Bol’shakov O, Avdin VV, Savić S, Manojlović DD, Stanković V, Stanković DM. Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications. in Sensors. 2023;23(2):933.
doi:10.3390/s23020933 .

Korina, Elena, Abramyan, Anton, Bol’shakov, Oleg, Avdin, Vyacheslav V., Savić, Slađana, Manojlović, Dragan D., Stanković, Vesna, Stanković, Dalibor M., "Microspherical Titanium-Phosphorus Double Oxide: Hierarchical Structure Development for Sensing Applications" in Sensors, 23, no. 2 (2023):933,
https://doi.org/10.3390/s23020933 . .

TY  - JOUR
AU  - Marković, Aleksandar
AU  - Savić, Slađana
AU  - Kukuruzar, Andrej J.
AU  - Konya, Zoltan
AU  - Manojlović, Dragan D.
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10689
AB  - In this paper, electrochemical degradation of Reactive Black 5 (RB5) textile azo dye was examined in regard to different synthesis procedures for making PbO2–graphitic carbon nitride (g-C3N4) electrode. The reaction of with ClO− in the presence of different surfactants, i.e., cetyltrimethylammonium bromide (CTAB) and tetrabutylammonium phosphate (TBAP), under conventional conditions, resulted in the formation of PbO2 with varying morphology. The obtained materials were combined with g-C3N4 for the preparation of the final composite materials, which were then characterized morphologically and electrochemically. After optimizing the degradation method, it was shown that an anode comprising a steel electrode coated with the composite of PbO2 synthesized using CTAB as template and g-C3N4, and using 0.15 M Na2SO4 as the supporting electrolyte, gave the best performance for RB5 dye removal from a 35 mg/L solution. The treatment duration was 60 min, applying a current of 0.17 A (electrode surface 4 cm2, current density of 42.5 mA/cm2), while the initial pH of the testing solution was 2. The reusability and longevity of the electrode surface (which showed no significant change in activity throughout the study) may suggest that this approach is a promising candidate for wastewater treatment and pollutant removal.
T2  - Catalysts
T1  - Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye
VL  - 13
IS  - 2
SP  - 328
DO  - 10.3390/catal13020328
ER  - 

@article{
author = "Marković, Aleksandar and Savić, Slađana and Kukuruzar, Andrej J. and Konya, Zoltan and Manojlović, Dragan D. and Ognjanović, Miloš and Stanković, Dalibor M.",
year = "2023",
abstract = "In this paper, electrochemical degradation of Reactive Black 5 (RB5) textile azo dye was examined in regard to different synthesis procedures for making PbO2–graphitic carbon nitride (g-C3N4) electrode. The reaction of with ClO− in the presence of different surfactants, i.e., cetyltrimethylammonium bromide (CTAB) and tetrabutylammonium phosphate (TBAP), under conventional conditions, resulted in the formation of PbO2 with varying morphology. The obtained materials were combined with g-C3N4 for the preparation of the final composite materials, which were then characterized morphologically and electrochemically. After optimizing the degradation method, it was shown that an anode comprising a steel electrode coated with the composite of PbO2 synthesized using CTAB as template and g-C3N4, and using 0.15 M Na2SO4 as the supporting electrolyte, gave the best performance for RB5 dye removal from a 35 mg/L solution. The treatment duration was 60 min, applying a current of 0.17 A (electrode surface 4 cm2, current density of 42.5 mA/cm2), while the initial pH of the testing solution was 2. The reusability and longevity of the electrode surface (which showed no significant change in activity throughout the study) may suggest that this approach is a promising candidate for wastewater treatment and pollutant removal.",
journal = "Catalysts",
title = "Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye",
volume = "13",
number = "2",
pages = "328",
doi = "10.3390/catal13020328"
}

Marković, A., Savić, S., Kukuruzar, A. J., Konya, Z., Manojlović, D. D., Ognjanović, M.,& Stanković, D. M.. (2023). Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye. in Catalysts, 13(2), 328.
https://doi.org/10.3390/catal13020328

Marković A, Savić S, Kukuruzar AJ, Konya Z, Manojlović DD, Ognjanović M, Stanković DM. Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye. in Catalysts. 2023;13(2):328.
doi:10.3390/catal13020328 .

Marković, Aleksandar, Savić, Slađana, Kukuruzar, Andrej J., Konya, Zoltan, Manojlović, Dragan D., Ognjanović, Miloš, Stanković, Dalibor M., "Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye" in Catalysts, 13, no. 2 (2023):328,
https://doi.org/10.3390/catal13020328 . .

TY  - JOUR
AU  - Mutić, Tijana
AU  - Ognjanović, Miloš
AU  - Kodranov, Igor
AU  - Robić, Marko
AU  - Savić, Slađana
AU  - Krehula, Stjepko
AU  - Stanković, Dalibor M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10855
AB  - Author Tijana Mutić should be afliated to afliation 4.
Afliation 4 should be added: Faculty of Pharmacy University of Belgrade – Department of Analytical Chemistry, Vojvode Stepe 450, 11,221 Belgrade, Serbia
T2  - Analytical and Bioanalytical Chemistry
T1  - Correction to: The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline
DO  - 10.1007/s00216-023-04674-y
ER  - 

@article{
author = "Mutić, Tijana and Ognjanović, Miloš and Kodranov, Igor and Robić, Marko and Savić, Slađana and Krehula, Stjepko and Stanković, Dalibor M.",
year = "2023",
abstract = "Author Tijana Mutić should be afliated to afliation 4.
Afliation 4 should be added: Faculty of Pharmacy University of Belgrade – Department of Analytical Chemistry, Vojvode Stepe 450, 11,221 Belgrade, Serbia",
journal = "Analytical and Bioanalytical Chemistry",
title = "Correction to: The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline",
doi = "10.1007/s00216-023-04674-y"
}

Mutić, T., Ognjanović, M., Kodranov, I., Robić, M., Savić, S., Krehula, S.,& Stanković, D. M.. (2023). Correction to: The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline. in Analytical and Bioanalytical Chemistry.
https://doi.org/10.1007/s00216-023-04674-y

Mutić T, Ognjanović M, Kodranov I, Robić M, Savić S, Krehula S, Stanković DM. Correction to: The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline. in Analytical and Bioanalytical Chemistry. 2023;.
doi:10.1007/s00216-023-04674-y .

Mutić, Tijana, Ognjanović, Miloš, Kodranov, Igor, Robić, Marko, Savić, Slađana, Krehula, Stjepko, Stanković, Dalibor M., "Correction to: The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline" in Analytical and Bioanalytical Chemistry (2023),
https://doi.org/10.1007/s00216-023-04674-y . .

TY  - JOUR
AU  - Savić, Slađana
AU  - Roglić, Goran
AU  - Avdin, Vyacheslav V.
AU  - Zherebtsov, Dmitry A.
AU  - Stanković, Dalibor M.
AU  - Manojlović, Dragan D.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10162
AB  - Compounds used in the fashion industry effect the water bodies in the vicinity of textile factories, resulting in the visible coloration of surface water. Fe-doped graphite-based in house prepared electrodes were used in the Fenton- -like degradation of Reactive Blue 52 (RB52). The electrodes consisting of high-density graphite in three granulation sizes and three levels of Fe content were characterized using scanning electron microscopy (SEM). The amount of Fe in the electrodes and H2O2 concentration in synthetic textile wastewater were optimized. Additionally, the size of graphite grains was varied to investigate whether it effects the degradation rate. Under only 10 min of electro-Fenton degradation, a system with 10 mmol dm-3 of H2O2 and an electrode made of 7 % of Fe and 70 μm of granulation size of graphite, degraded over 75 % of RB52, and over 99 % after 40 min of treatment. The obtained results indicate that the proposed approach could be beneficial in the field of novel materials for environmental application and that in house prepared carbon could be an excellent replacement for commercially available supports.
AB  - Једињења која се користе у модној индустрији утичу на водна тела у околини текстилних фабрика, што резултира видљивим обојењем површинских вода. Домаће електроде на бази графита допиране гвожђем биле су укључене у деградацију Reactive Blue
52 (RB52) механизма попут Фентонове реакције. Електроде су се састојале од графита
велике густине у три величине гранулације и три количине Fе и окарактерисане су
помоћу скенирајуће електронске микроскопије (SEM). Оптимизоване су количина Fe у
електродама и концентрација H2O2 у синтетичкој текстилној отпадној води. Додатно,
величина графитних зрна је варирана како би се испитало да ли утиче на брзину разградње. За само 10 min електро-Фентонове деградације систем са 10 mmol dm-3 H2O2 и
електродом од 7 % Fе и 70 μm величине гранулације графита разградило се преко 75 %
RB52 и преко 99 % након 40 min третмана. Добијени резултати указују на то да предложени приступ може бити користан у области нових материјала за примену у животној
средини и да домаће припремљени угљеник може бити одлична замена за комерцијално
доступне носаче.
T2  - Journal of the Serbian Chemical Society
T1  - In-house-prepared carbon-based Fe-doped catalysts for electro-Fenton degradation of azo dyes
VL  - 87
IS  - 1
SP  - 57
EP  - 67
DO  - 10.2298/JSC210901103S
ER  - 

@article{
author = "Savić, Slađana and Roglić, Goran and Avdin, Vyacheslav V. and Zherebtsov, Dmitry A. and Stanković, Dalibor M. and Manojlović, Dragan D.",
year = "2022",
abstract = "Compounds used in the fashion industry effect the water bodies in the vicinity of textile factories, resulting in the visible coloration of surface water. Fe-doped graphite-based in house prepared electrodes were used in the Fenton- -like degradation of Reactive Blue 52 (RB52). The electrodes consisting of high-density graphite in three granulation sizes and three levels of Fe content were characterized using scanning electron microscopy (SEM). The amount of Fe in the electrodes and H2O2 concentration in synthetic textile wastewater were optimized. Additionally, the size of graphite grains was varied to investigate whether it effects the degradation rate. Under only 10 min of electro-Fenton degradation, a system with 10 mmol dm-3 of H2O2 and an electrode made of 7 % of Fe and 70 μm of granulation size of graphite, degraded over 75 % of RB52, and over 99 % after 40 min of treatment. The obtained results indicate that the proposed approach could be beneficial in the field of novel materials for environmental application and that in house prepared carbon could be an excellent replacement for commercially available supports., Једињења која се користе у модној индустрији утичу на водна тела у околини текстилних фабрика, што резултира видљивим обојењем површинских вода. Домаће електроде на бази графита допиране гвожђем биле су укључене у деградацију Reactive Blue
52 (RB52) механизма попут Фентонове реакције. Електроде су се састојале од графита
велике густине у три величине гранулације и три количине Fе и окарактерисане су
помоћу скенирајуће електронске микроскопије (SEM). Оптимизоване су количина Fe у
електродама и концентрација H2O2 у синтетичкој текстилној отпадној води. Додатно,
величина графитних зрна је варирана како би се испитало да ли утиче на брзину разградње. За само 10 min електро-Фентонове деградације систем са 10 mmol dm-3 H2O2 и
електродом од 7 % Fе и 70 μm величине гранулације графита разградило се преко 75 %
RB52 и преко 99 % након 40 min третмана. Добијени резултати указују на то да предложени приступ може бити користан у области нових материјала за примену у животној
средини и да домаће припремљени угљеник може бити одлична замена за комерцијално
доступне носаче.",
journal = "Journal of the Serbian Chemical Society",
title = "In-house-prepared carbon-based Fe-doped catalysts for electro-Fenton degradation of azo dyes",
volume = "87",
number = "1",
pages = "57-67",
doi = "10.2298/JSC210901103S"
}

Savić, S., Roglić, G., Avdin, V. V., Zherebtsov, D. A., Stanković, D. M.,& Manojlović, D. D.. (2022). In-house-prepared carbon-based Fe-doped catalysts for electro-Fenton degradation of azo dyes. in Journal of the Serbian Chemical Society, 87(1), 57-67.
https://doi.org/10.2298/JSC210901103S

Savić S, Roglić G, Avdin VV, Zherebtsov DA, Stanković DM, Manojlović DD. In-house-prepared carbon-based Fe-doped catalysts for electro-Fenton degradation of azo dyes. in Journal of the Serbian Chemical Society. 2022;87(1):57-67.
doi:10.2298/JSC210901103S .

Savić, Slađana, Roglić, Goran, Avdin, Vyacheslav V., Zherebtsov, Dmitry A., Stanković, Dalibor M., Manojlović, Dragan D., "In-house-prepared carbon-based Fe-doped catalysts for electro-Fenton degradation of azo dyes" in Journal of the Serbian Chemical Society, 87, no. 1 (2022):57-67,
https://doi.org/10.2298/JSC210901103S . .

TY  - JOUR
AU  - Stanković, Dalibor M.
AU  - Kukuruzar, Andrej
AU  - Savić, Slađana
AU  - Ognjanović, Miloš
AU  - Janković-Častvan, Ivona
AU  - Roglić, Goran
AU  - Antić, Bratislav
AU  - Manojlović, Dragan
AU  - Dojčinović, Biljana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9902
AB  - The textile industry is one of the major pollutants of waterbodies with effluents high in biochemical and chemical oxygen demand values, high values of total dissolved solids, total suspended solids, and low dissolved oxygen values along with strong color. The existence of a successful method for its decontamination would be beneficial. In this work, we synthesized sponge-like europium oxide (Eu2O3) using a template-directed route from carbon hollow spheres, obtained from glucose as a carbon source. The material synthesis method was done in an aqueous environment, without using any organic solvents. Electrochemical properties of the synthesized material were investigated using cyclic voltammetry and electrical impedance spectroscopy, while morphological characterization was done using scanning electron microscopy and X-ray powder diffraction analysis. Eu2O3 were successfully immobilized at the surface of a screen-printed carbon electrode (Eu2O3/SPCE) using the drop-casting method. Finally, the prepared electrodes were tested toward the removal of Reactive Blue 52 (RB52) using electrochemical advanced oxidation processes (EAOPs). Important parameters, that is, the supporting electrolyte, its concentration, pH value, and the applied voltage, were optimized for RB52 degradation. The rate of removal was monitored spectrophotometrically and by high-performance liquid chromatography with a diode array detector (HPLC-DAD). It was found that the proposed approach reaches complete decolorization of the RB52 solution after a 60-min treatment, at pH 5.6 of KCl supporting electrolyte at a concentration of 0.05 M. Under optimal parameters, after 3 h of treatment, total organic carbon (TOC) was lowered by ~40%. The obtained results indicate that the proposed method may find potential application in EAOPs, considering electrode stability, durability, and efficiency and simplicity of the method.
T2  - Materials Chemistry and Physics
T1  - Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation
VL  - 273
SP  - 125154
DO  - 10.1016/j.matchemphys.2021.125154
ER  - 

@article{
author = "Stanković, Dalibor M. and Kukuruzar, Andrej and Savić, Slađana and Ognjanović, Miloš and Janković-Častvan, Ivona and Roglić, Goran and Antić, Bratislav and Manojlović, Dragan and Dojčinović, Biljana",
year = "2021",
abstract = "The textile industry is one of the major pollutants of waterbodies with effluents high in biochemical and chemical oxygen demand values, high values of total dissolved solids, total suspended solids, and low dissolved oxygen values along with strong color. The existence of a successful method for its decontamination would be beneficial. In this work, we synthesized sponge-like europium oxide (Eu2O3) using a template-directed route from carbon hollow spheres, obtained from glucose as a carbon source. The material synthesis method was done in an aqueous environment, without using any organic solvents. Electrochemical properties of the synthesized material were investigated using cyclic voltammetry and electrical impedance spectroscopy, while morphological characterization was done using scanning electron microscopy and X-ray powder diffraction analysis. Eu2O3 were successfully immobilized at the surface of a screen-printed carbon electrode (Eu2O3/SPCE) using the drop-casting method. Finally, the prepared electrodes were tested toward the removal of Reactive Blue 52 (RB52) using electrochemical advanced oxidation processes (EAOPs). Important parameters, that is, the supporting electrolyte, its concentration, pH value, and the applied voltage, were optimized for RB52 degradation. The rate of removal was monitored spectrophotometrically and by high-performance liquid chromatography with a diode array detector (HPLC-DAD). It was found that the proposed approach reaches complete decolorization of the RB52 solution after a 60-min treatment, at pH 5.6 of KCl supporting electrolyte at a concentration of 0.05 M. Under optimal parameters, after 3 h of treatment, total organic carbon (TOC) was lowered by ~40%. The obtained results indicate that the proposed method may find potential application in EAOPs, considering electrode stability, durability, and efficiency and simplicity of the method.",
journal = "Materials Chemistry and Physics",
title = "Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation",
volume = "273",
pages = "125154",
doi = "10.1016/j.matchemphys.2021.125154"
}

Stanković, D. M., Kukuruzar, A., Savić, S., Ognjanović, M., Janković-Častvan, I., Roglić, G., Antić, B., Manojlović, D.,& Dojčinović, B.. (2021). Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation. in Materials Chemistry and Physics, 273, 125154.
https://doi.org/10.1016/j.matchemphys.2021.125154

Stanković DM, Kukuruzar A, Savić S, Ognjanović M, Janković-Častvan I, Roglić G, Antić B, Manojlović D, Dojčinović B. Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation. in Materials Chemistry and Physics. 2021;273:125154.
doi:10.1016/j.matchemphys.2021.125154 .

Stanković, Dalibor M., Kukuruzar, Andrej, Savić, Slađana, Ognjanović, Miloš, Janković-Častvan, Ivona, Roglić, Goran, Antić, Bratislav, Manojlović, Dragan, Dojčinović, Biljana, "Sponge-like europium oxide from hollow carbon sphere as a template for an anode material for Reactive Blue 52 electrochemical degradation" in Materials Chemistry and Physics, 273 (2021):125154,
https://doi.org/10.1016/j.matchemphys.2021.125154 . .