Teodoro, Orlando M. N. D.

Link to this page

Authority KeyName Variants
orcid::0000-0002-3424-2847
  • Teodoro, Orlando M. N. D. (9)
Projects
Functional, Functionalized and Advanced Nanomaterials Optoelectronics nanodimension systems - the rout towards applications
ELISA - European Light Sources Activities - Synchrotrons and Free Electron Lasers Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine
Program of scientific and technological cooperation between Republic of Serbia and Republic of Portugal [451-03-02328/2012-14/03] European Community's Seventh Framework programme (FP7/2007–2013) [Grant agreement No. 226716]
European Union's Horizon Research and Innovation Program [766894] FCT - Portuguese National Funding Agency for Science, Research and Technology [UID/FIS/00068/2019]
Fundacaopara a Ciencia e Tecnologia do Ministerio da Ciencia, Tecnologia e Ensino Superior (FCT/MCTES) [PEst-OE/FIS/UI0068/2011], CNES Fundacao para a Ciencia e Tecnologia do Ministerio da Ciencia, Tecnologia e Ensino Superior (FCT/MCTES) [UID/FIS/00068/2013]
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Portuguese FCT- Fundacao para a Ciencia e a Tecnologia [UID/FIS/50010/2013, INCENTIVO/FIS/LA0010/2014, SFRH/BD/52413/2013], Slovenian Research Agency (ARRS) [L2-6769]
Portuguese National Funding Agency for Science, Research and Technology [PTDC/FIS-NAN/1154/2014] Portuguese National Funding Agency for Science, Research and Technology [UID/FIS/00068/2019]
Portuguese Research Grant Pest–OE/FIS/UI0068/2013 through FCT–MEC Portuguese Research Grant through FCT-MEC [Pest-UID/FIS/00068/2013]
Program of scientific and technological cooperation between Republic of Serbia and Republic of Portugal [451-03-02328/2012-14/03], Portuguese Research Grant through FCT-MEC [Pest-OE/FIS/UI0068/2011] Program of scientific and technological cooperation between Republic of Serbia and Republic of Portugal [No. 451–03–02328/2012–14/03]
Republic of Serbia [451-03-02328/2012-14/03], Republic of Portugal [451-03-02328/2012-14/03], Portuguese Research Grant through FCT-MEC [Pest-OE/FIS/UI0068/2011]

Author's Bibliography

Low total electron yield graphene coatings produced by electrophoretic deposition

Aguincha, R.; Bundaleski, Nenad; Bundaleska, N; Novaković, Mirjana M.; Henriques, Julio A. P.; Rakočević, Zlatko Lj.; Tatarova, Elena; Teodoro, Orlando M. N. D.

(2020)

TY  - JOUR
AU  - Aguincha, R.
AU  - Bundaleski, Nenad
AU  - Bundaleska, N
AU  - Novaković, Mirjana M.
AU  - Henriques, Julio A. P.
AU  - Rakočević, Zlatko Lj.
AU  - Tatarova, Elena
AU  - Teodoro, Orlando M. N. D.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8616
AB  - Stainless steel and copper technical substrates have been coated by free standing graphene using electrophoretic deposition technique, with the final goal to obtain chemically inert low secondary electron emission surfaces. This class of materials is of utmost interest in future accelerators in order to increase further the flux of accelerated charged particles in the beam. The measured maximum total electron yield of pristine graphene, which has been previously characterized by electron microscopies and X-ray photoelectron spectroscopy, appears to be about 1.0. The deposition parameters have been optimized in order to obtain surfaces with lowest total electron yield, but also composition and morphology close to that of pristine graphene. When applying these optimized deposition parameters graphene coatings on two substrates, i.e. stainless steel and copper, the maximum total electron yield of about 1.04 was obtained. The composition of coatings and the relative amounts of sp2 bonds are slightly worse than those of the pristine graphene, while the surface morphology appears to be the same. Annealing at 150 °C for 64 h in high vacuum, showed that vacuum baking did not affect considerably the electron emission properties of the coatings. © 2019 Elsevier B.V.
T2  - Applied Surface Science
T1  - Low total electron yield graphene coatings produced by electrophoretic deposition
VL  - 504
SP  - 143870
DO  - 10.1016/j.apsusc.2019.143870
ER  - 
@article{
author = "Aguincha, R. and Bundaleski, Nenad and Bundaleska, N and Novaković, Mirjana M. and Henriques, Julio A. P. and Rakočević, Zlatko Lj. and Tatarova, Elena and Teodoro, Orlando M. N. D.",
year = "2020",
abstract = "Stainless steel and copper technical substrates have been coated by free standing graphene using electrophoretic deposition technique, with the final goal to obtain chemically inert low secondary electron emission surfaces. This class of materials is of utmost interest in future accelerators in order to increase further the flux of accelerated charged particles in the beam. The measured maximum total electron yield of pristine graphene, which has been previously characterized by electron microscopies and X-ray photoelectron spectroscopy, appears to be about 1.0. The deposition parameters have been optimized in order to obtain surfaces with lowest total electron yield, but also composition and morphology close to that of pristine graphene. When applying these optimized deposition parameters graphene coatings on two substrates, i.e. stainless steel and copper, the maximum total electron yield of about 1.04 was obtained. The composition of coatings and the relative amounts of sp2 bonds are slightly worse than those of the pristine graphene, while the surface morphology appears to be the same. Annealing at 150 °C for 64 h in high vacuum, showed that vacuum baking did not affect considerably the electron emission properties of the coatings. © 2019 Elsevier B.V.",
journal = "Applied Surface Science",
title = "Low total electron yield graphene coatings produced by electrophoretic deposition",
volume = "504",
pages = "143870",
doi = "10.1016/j.apsusc.2019.143870"
}
Aguincha, R., Bundaleski, N., Bundaleska, N., Novaković, M. M., Henriques, J. A. P., Rakočević, Z. Lj., Tatarova, E.,& Teodoro, O. M. N. D.. (2020). Low total electron yield graphene coatings produced by electrophoretic deposition. in Applied Surface Science, 504, 143870.
https://doi.org/10.1016/j.apsusc.2019.143870
Aguincha R, Bundaleski N, Bundaleska N, Novaković MM, Henriques JAP, Rakočević ZL, Tatarova E, Teodoro OMND. Low total electron yield graphene coatings produced by electrophoretic deposition. in Applied Surface Science. 2020;504:143870.
doi:10.1016/j.apsusc.2019.143870 .
Aguincha, R., Bundaleski, Nenad, Bundaleska, N, Novaković, Mirjana M., Henriques, Julio A. P., Rakočević, Zlatko Lj., Tatarova, Elena, Teodoro, Orlando M. N. D., "Low total electron yield graphene coatings produced by electrophoretic deposition" in Applied Surface Science, 504 (2020):143870,
https://doi.org/10.1016/j.apsusc.2019.143870 . .
13
3
12

XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited

Medić-Ilić, Mirjana; Bundaleski, Nenad; Ivanović, Nenad; Teodoro, Orlando M. N. D.; Rakočević, Zlatko Lj.; Minić, Dragica M.; Romčević, Nebojša Ž.; Radisavljević, Ivana

(2020)

TY  - JOUR
AU  - Medić-Ilić, Mirjana
AU  - Bundaleski, Nenad
AU  - Ivanović, Nenad
AU  - Teodoro, Orlando M. N. D.
AU  - Rakočević, Zlatko Lj.
AU  - Minić, Dragica M.
AU  - Romčević, Nebojša Ž.
AU  - Radisavljević, Ivana
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8910
AB  - Recently introduced model for quantitative analysis of in-depth non-uniform surfaces is applied to reexamine the X-ray Photoelectron Spectroscopy (XPS) data of Cd0.99Fe0.01Te0.97Se0.03 and Zn0.98Fe0.02Te0.91Se0.09 crystalline samples. Special attention is paid to the precise identification of phases which form the bulk-like near-surface region and the surface overlayers (the oxide layer and the layer of organic impurities), as well as the influence of surface morphology on the measurements. The obtained results fully support earlier qualitative estimations, but also provide new quantitative insight into the composition of the three investigated regions. The near-surface region of Cd0.99Fe0.01Te0.97Se0.03 and Zn0.98Fe0.02Te0.91Se0.09 samples is slightly electropositive, with cation/anion ratio 52:48 and 53:47, respectively. Model surface structures, which are fully compatible with the experimental results, comprise 0.76 nm thick CdTeO3 layer at the surface of Cd0.99Fe0.01Te0.97Se0.03 and 0.33 nm thick mixed ZnO/TeO2 oxide layer on Zn0.98Fe0.02Te0.91Se0.09. In both samples the oxide layer is only a few atomic layers thick, implying that it suppresses further rapid migration of oxygen into the bulk.
T2  - Vacuum
T1  - XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited
VL  - 176
SP  - 109340
DO  - 10.1016/j.vacuum.2020.109340
ER  - 
@article{
author = "Medić-Ilić, Mirjana and Bundaleski, Nenad and Ivanović, Nenad and Teodoro, Orlando M. N. D. and Rakočević, Zlatko Lj. and Minić, Dragica M. and Romčević, Nebojša Ž. and Radisavljević, Ivana",
year = "2020",
abstract = "Recently introduced model for quantitative analysis of in-depth non-uniform surfaces is applied to reexamine the X-ray Photoelectron Spectroscopy (XPS) data of Cd0.99Fe0.01Te0.97Se0.03 and Zn0.98Fe0.02Te0.91Se0.09 crystalline samples. Special attention is paid to the precise identification of phases which form the bulk-like near-surface region and the surface overlayers (the oxide layer and the layer of organic impurities), as well as the influence of surface morphology on the measurements. The obtained results fully support earlier qualitative estimations, but also provide new quantitative insight into the composition of the three investigated regions. The near-surface region of Cd0.99Fe0.01Te0.97Se0.03 and Zn0.98Fe0.02Te0.91Se0.09 samples is slightly electropositive, with cation/anion ratio 52:48 and 53:47, respectively. Model surface structures, which are fully compatible with the experimental results, comprise 0.76 nm thick CdTeO3 layer at the surface of Cd0.99Fe0.01Te0.97Se0.03 and 0.33 nm thick mixed ZnO/TeO2 oxide layer on Zn0.98Fe0.02Te0.91Se0.09. In both samples the oxide layer is only a few atomic layers thick, implying that it suppresses further rapid migration of oxygen into the bulk.",
journal = "Vacuum",
title = "XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited",
volume = "176",
pages = "109340",
doi = "10.1016/j.vacuum.2020.109340"
}
Medić-Ilić, M., Bundaleski, N., Ivanović, N., Teodoro, O. M. N. D., Rakočević, Z. Lj., Minić, D. M., Romčević, N. Ž.,& Radisavljević, I.. (2020). XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited. in Vacuum, 176, 109340.
https://doi.org/10.1016/j.vacuum.2020.109340
Medić-Ilić M, Bundaleski N, Ivanović N, Teodoro OMND, Rakočević ZL, Minić DM, Romčević NŽ, Radisavljević I. XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited. in Vacuum. 2020;176:109340.
doi:10.1016/j.vacuum.2020.109340 .
Medić-Ilić, Mirjana, Bundaleski, Nenad, Ivanović, Nenad, Teodoro, Orlando M. N. D., Rakočević, Zlatko Lj., Minić, Dragica M., Romčević, Nebojša Ž., Radisavljević, Ivana, "XPS measurements of air-exposed Cd(Zn)1xFexTe1ySey surfaces revisited" in Vacuum, 176 (2020):109340,
https://doi.org/10.1016/j.vacuum.2020.109340 . .
7
7

Local, electronic and surface structure of multi-component Fe-doped CdTe(S) systems

Bundaleski, Nenad; Radisavljević, Ivana; Ivanović, Nenad; Rakočević, Zlatko Lj.; Medić-Ilić, Mirjana; Tadić, Julijana D.; Teodoro, Orlando M. N. D.

(2019)

TY  - JOUR
AU  - Bundaleski, Nenad
AU  - Radisavljević, Ivana
AU  - Ivanović, Nenad
AU  - Rakočević, Zlatko Lj.
AU  - Medić-Ilić, Mirjana
AU  - Tadić, Julijana D.
AU  - Teodoro, Orlando M. N. D.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0039602818307611
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7977
AB  - Local structural and electronic properties around Fe in multi-component Cd0.99Fe0.01Te0.97S0.03 system were studied by means of X-ray absorption fine structure (XAFS). Composition of non-polar (110) surfaces of Cd0.97Fe0.03Te and Cd0.99Fe0.01Te0.97S0.03 systems and mechanism of their oxidation in ambient conditions were studied by Atomic Force Microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS). It has been found that Fe preferentially substitutes Cd, but due to much smaller covalent radius and preferences for paring with S, it causes local distortion of the host CdTe lattice. The distortion is confined to the Fe-immediate surrounding and the second and third coordination shell atoms are (inside experimental uncertainties) placed at distances expected in CdTe. Although local structure around Fe is well defined in the bulk of both samples, their near-surface region is completely depleted from Fe, and in case of Cd0.99Fe0.01Te0.97S0.03 somewhat enriched in S. Special attention is, therefore, paid to characterization of the near-surface region and evaluation of its composition and structure. To that end we have introduced a general standard-free algorithm for XPS data analysis of the two-layer surface structure (bulk, oxide layer, and the impurity layer). Results of the in-depth composition analysis revealed that despite different bulk composition and impurity layer thickness, underneath the topmost impurity layer lays approximately one monolayer of CdTeO3 which passivates the surface. © 2018 Elsevier B.V.
T2  - Surface Science
T1  - Local, electronic and surface structure of multi-component Fe-doped CdTe(S) systems
VL  - 681
SP  - 76
EP  - 86
DO  - 10.1016/j.susc.2018.11.007
ER  - 
@article{
author = "Bundaleski, Nenad and Radisavljević, Ivana and Ivanović, Nenad and Rakočević, Zlatko Lj. and Medić-Ilić, Mirjana and Tadić, Julijana D. and Teodoro, Orlando M. N. D.",
year = "2019",
abstract = "Local structural and electronic properties around Fe in multi-component Cd0.99Fe0.01Te0.97S0.03 system were studied by means of X-ray absorption fine structure (XAFS). Composition of non-polar (110) surfaces of Cd0.97Fe0.03Te and Cd0.99Fe0.01Te0.97S0.03 systems and mechanism of their oxidation in ambient conditions were studied by Atomic Force Microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS). It has been found that Fe preferentially substitutes Cd, but due to much smaller covalent radius and preferences for paring with S, it causes local distortion of the host CdTe lattice. The distortion is confined to the Fe-immediate surrounding and the second and third coordination shell atoms are (inside experimental uncertainties) placed at distances expected in CdTe. Although local structure around Fe is well defined in the bulk of both samples, their near-surface region is completely depleted from Fe, and in case of Cd0.99Fe0.01Te0.97S0.03 somewhat enriched in S. Special attention is, therefore, paid to characterization of the near-surface region and evaluation of its composition and structure. To that end we have introduced a general standard-free algorithm for XPS data analysis of the two-layer surface structure (bulk, oxide layer, and the impurity layer). Results of the in-depth composition analysis revealed that despite different bulk composition and impurity layer thickness, underneath the topmost impurity layer lays approximately one monolayer of CdTeO3 which passivates the surface. © 2018 Elsevier B.V.",
journal = "Surface Science",
title = "Local, electronic and surface structure of multi-component Fe-doped CdTe(S) systems",
volume = "681",
pages = "76-86",
doi = "10.1016/j.susc.2018.11.007"
}
Bundaleski, N., Radisavljević, I., Ivanović, N., Rakočević, Z. Lj., Medić-Ilić, M., Tadić, J. D.,& Teodoro, O. M. N. D.. (2019). Local, electronic and surface structure of multi-component Fe-doped CdTe(S) systems. in Surface Science, 681, 76-86.
https://doi.org/10.1016/j.susc.2018.11.007
Bundaleski N, Radisavljević I, Ivanović N, Rakočević ZL, Medić-Ilić M, Tadić JD, Teodoro OMND. Local, electronic and surface structure of multi-component Fe-doped CdTe(S) systems. in Surface Science. 2019;681:76-86.
doi:10.1016/j.susc.2018.11.007 .
Bundaleski, Nenad, Radisavljević, Ivana, Ivanović, Nenad, Rakočević, Zlatko Lj., Medić-Ilić, Mirjana, Tadić, Julijana D., Teodoro, Orlando M. N. D., "Local, electronic and surface structure of multi-component Fe-doped CdTe(S) systems" in Surface Science, 681 (2019):76-86,
https://doi.org/10.1016/j.susc.2018.11.007 . .
5
4
5

Surface composition of Cd1-xFe(Mn)(x)Te1-ySey systems exposed to air

Bundaleski, Nenad; Radisavljević, Ivana; Trigueiro, Joao; Tolstogouzov, Alexander; Rakočević, Zlatko Lj.; Medić, Mirjana; Teodoro, Orlando M. N. D.; Romčević, Nebojša Ž.; Ivanović, Nenad

(2017)

TY  - JOUR
AU  - Bundaleski, Nenad
AU  - Radisavljević, Ivana
AU  - Trigueiro, Joao
AU  - Tolstogouzov, Alexander
AU  - Rakočević, Zlatko Lj.
AU  - Medić, Mirjana
AU  - Teodoro, Orlando M. N. D.
AU  - Romčević, Nebojša Ž.
AU  - Ivanović, Nenad
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1422
AB  - Using X-ray induced Photoelectron Spectroscopy, Time of Flight Secondary Ion Mass Spectrometry and Atomic Force Microscopy we have investigated elemental composition, structure and oxidation process taking place at the surfaces of polycrystalline Cd0.99Fe0.01Te0.97Se0.03 and Cd0.95Mn0.05Te0.97Se0.03 systems stored in ambient conditions. The surface oxidation destroys the native CdTe matrix and provokes substantial atomic rearrangement in the first few atomic layers. The near surface region of both systems is enriched in Cd and to some extent Te-deficient, but the surface structure, morphology and the native oxide composition are all found to be considerably different. In Cd0.99Fe0.01Te0.97Se0.03 system both Fe and Se dopants diffuse into the bulk and oxidation of its surface results in formation of a thin CdTeO3 layer which covers the CdTe matrix. In Cd0.95Mn0.05Te0.97Se0.03 system oxygen-rich atmosphere triggers Mn and Se out diffusion and the nonuniform oxide layer predominantly consists of MnO and a small amount of Te-oxide which both lay underneath a thin layer of metallic Cd segregated at the top of the surface. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Materials Chemistry and Physics
T1  - Surface composition of Cd1-xFe(Mn)(x)Te1-ySey systems exposed to air
VL  - 189
SP  - 35
EP  - 43
DO  - 10.1016/j.matchemphys.2016.12.029
ER  - 
@article{
author = "Bundaleski, Nenad and Radisavljević, Ivana and Trigueiro, Joao and Tolstogouzov, Alexander and Rakočević, Zlatko Lj. and Medić, Mirjana and Teodoro, Orlando M. N. D. and Romčević, Nebojša Ž. and Ivanović, Nenad",
year = "2017",
abstract = "Using X-ray induced Photoelectron Spectroscopy, Time of Flight Secondary Ion Mass Spectrometry and Atomic Force Microscopy we have investigated elemental composition, structure and oxidation process taking place at the surfaces of polycrystalline Cd0.99Fe0.01Te0.97Se0.03 and Cd0.95Mn0.05Te0.97Se0.03 systems stored in ambient conditions. The surface oxidation destroys the native CdTe matrix and provokes substantial atomic rearrangement in the first few atomic layers. The near surface region of both systems is enriched in Cd and to some extent Te-deficient, but the surface structure, morphology and the native oxide composition are all found to be considerably different. In Cd0.99Fe0.01Te0.97Se0.03 system both Fe and Se dopants diffuse into the bulk and oxidation of its surface results in formation of a thin CdTeO3 layer which covers the CdTe matrix. In Cd0.95Mn0.05Te0.97Se0.03 system oxygen-rich atmosphere triggers Mn and Se out diffusion and the nonuniform oxide layer predominantly consists of MnO and a small amount of Te-oxide which both lay underneath a thin layer of metallic Cd segregated at the top of the surface. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Materials Chemistry and Physics",
title = "Surface composition of Cd1-xFe(Mn)(x)Te1-ySey systems exposed to air",
volume = "189",
pages = "35-43",
doi = "10.1016/j.matchemphys.2016.12.029"
}
Bundaleski, N., Radisavljević, I., Trigueiro, J., Tolstogouzov, A., Rakočević, Z. Lj., Medić, M., Teodoro, O. M. N. D., Romčević, N. Ž.,& Ivanović, N.. (2017). Surface composition of Cd1-xFe(Mn)(x)Te1-ySey systems exposed to air. in Materials Chemistry and Physics, 189, 35-43.
https://doi.org/10.1016/j.matchemphys.2016.12.029
Bundaleski N, Radisavljević I, Trigueiro J, Tolstogouzov A, Rakočević ZL, Medić M, Teodoro OMND, Romčević NŽ, Ivanović N. Surface composition of Cd1-xFe(Mn)(x)Te1-ySey systems exposed to air. in Materials Chemistry and Physics. 2017;189:35-43.
doi:10.1016/j.matchemphys.2016.12.029 .
Bundaleski, Nenad, Radisavljević, Ivana, Trigueiro, Joao, Tolstogouzov, Alexander, Rakočević, Zlatko Lj., Medić, Mirjana, Teodoro, Orlando M. N. D., Romčević, Nebojša Ž., Ivanović, Nenad, "Surface composition of Cd1-xFe(Mn)(x)Te1-ySey systems exposed to air" in Materials Chemistry and Physics, 189 (2017):35-43,
https://doi.org/10.1016/j.matchemphys.2016.12.029 . .
4
4
4

The role of different minerals from red mud assemblage in Co(II) sorption mechanism

Milenković, A.; Smičiklas, Ivana D.; Bundaleski, Nenad; Teodoro, Orlando M. N. D.; Veljović, Đorđe N.; Vukelić, Nikola S.

(2016)

TY  - JOUR
AU  - Milenković, A.
AU  - Smičiklas, Ivana D.
AU  - Bundaleski, Nenad
AU  - Teodoro, Orlando M. N. D.
AU  - Veljović, Đorđe N.
AU  - Vukelić, Nikola S.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1266
AB  - A range of industrial by-products are currently under the consideration as cost-effective alternatives to conventional sorbent materials for environmental clean-up and remediation applications. Bauxite residue (red mud) has demonstrated exceptionally high potential for the immobilization of cationic pollutants. Due to heterogeneity of such material, determination of the role of individual mineral phases in the overall sorption mechanism is a challenging task. To enlighten the mechanism of Co(II) sorption by mineral assemblage of the red mud, sequential extraction analysis of Co-loaded sample was combined with the microscopic and spectroscopic studies performed by Scanning Field Emission Electron Microscope (FE-SEM), Energy Dispersive Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS). Sorbed Co(II) ions were found associated with operationally defined Fe,Mn-oxide and carbonate/acid soluble fractions. Binding of Co(II) by the red mud was achieved primarily by means of chemisorption/surface precipitation on Fe- and Ti-oxides. In coexistence with these highly selective surfaces, gibbsite and silica appeared to be low affinity sites for Co(II). Incongruent dissolution of sodalite phase was detected, indicating that its function was not to ensure sorption centers, but to increase the solution pH creating favorable environment for Co(II) binding by Fe- and Ti-oxides. The results demonstrate high stability of sorbed Co(II) and synergistic action of mineral constituents as essentially important property for red mud implementation as a purifying and remediation agent. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Colloids and Surfaces. A: Physicochemical and Engineering Aspects
T1  - The role of different minerals from red mud assemblage in Co(II) sorption mechanism
VL  - 508
SP  - 8
EP  - 20
DO  - 10.1016/j.colsurfa.2016.08.011
ER  - 
@article{
author = "Milenković, A. and Smičiklas, Ivana D. and Bundaleski, Nenad and Teodoro, Orlando M. N. D. and Veljović, Đorđe N. and Vukelić, Nikola S.",
year = "2016",
abstract = "A range of industrial by-products are currently under the consideration as cost-effective alternatives to conventional sorbent materials for environmental clean-up and remediation applications. Bauxite residue (red mud) has demonstrated exceptionally high potential for the immobilization of cationic pollutants. Due to heterogeneity of such material, determination of the role of individual mineral phases in the overall sorption mechanism is a challenging task. To enlighten the mechanism of Co(II) sorption by mineral assemblage of the red mud, sequential extraction analysis of Co-loaded sample was combined with the microscopic and spectroscopic studies performed by Scanning Field Emission Electron Microscope (FE-SEM), Energy Dispersive Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS). Sorbed Co(II) ions were found associated with operationally defined Fe,Mn-oxide and carbonate/acid soluble fractions. Binding of Co(II) by the red mud was achieved primarily by means of chemisorption/surface precipitation on Fe- and Ti-oxides. In coexistence with these highly selective surfaces, gibbsite and silica appeared to be low affinity sites for Co(II). Incongruent dissolution of sodalite phase was detected, indicating that its function was not to ensure sorption centers, but to increase the solution pH creating favorable environment for Co(II) binding by Fe- and Ti-oxides. The results demonstrate high stability of sorbed Co(II) and synergistic action of mineral constituents as essentially important property for red mud implementation as a purifying and remediation agent. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Colloids and Surfaces. A: Physicochemical and Engineering Aspects",
title = "The role of different minerals from red mud assemblage in Co(II) sorption mechanism",
volume = "508",
pages = "8-20",
doi = "10.1016/j.colsurfa.2016.08.011"
}
Milenković, A., Smičiklas, I. D., Bundaleski, N., Teodoro, O. M. N. D., Veljović, Đ. N.,& Vukelić, N. S.. (2016). The role of different minerals from red mud assemblage in Co(II) sorption mechanism. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 508, 8-20.
https://doi.org/10.1016/j.colsurfa.2016.08.011
Milenković A, Smičiklas ID, Bundaleski N, Teodoro OMND, Veljović ĐN, Vukelić NS. The role of different minerals from red mud assemblage in Co(II) sorption mechanism. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects. 2016;508:8-20.
doi:10.1016/j.colsurfa.2016.08.011 .
Milenković, A., Smičiklas, Ivana D., Bundaleski, Nenad, Teodoro, Orlando M. N. D., Veljović, Đorđe N., Vukelić, Nikola S., "The role of different minerals from red mud assemblage in Co(II) sorption mechanism" in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 508 (2016):8-20,
https://doi.org/10.1016/j.colsurfa.2016.08.011 . .
18
10
17

Comprehensive studies of structural, electronic and magnetic properties of Zn(0.9)5Co(0.05)O nanopowders

Radisavljević, Ivana; Novaković, Nikola; Matović, Branko; Paunović, Novica M.; Medić, Mirjana; Bundaleski, Nenad; Andrić, Velibor; Teodoro, Orlando M. N. D.

(Elsevier, 2016)

TY  - JOUR
AU  - Radisavljević, Ivana
AU  - Novaković, Nikola
AU  - Matović, Branko
AU  - Paunović, Novica M.
AU  - Medić, Mirjana
AU  - Bundaleski, Nenad
AU  - Andrić, Velibor
AU  - Teodoro, Orlando M. N. D.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/881
AB  - X-ray absorption (XANES, EXAFS, XMCD) and photoelectron (XPS) spectroscopic techniques were employed to study local structural, electronic and magnetic properties of Zn0.95Co0.05O nanopowders. The substitutional Co2+ ions are incorporated in ZnO lattice at regular Zn sites and the sample is characterized by high structural order. There was no sign of ferromagnetic ordering of Co magnetic moments and the sample is in paramagnetic state at all temperatures down to 5 K. The possible connection of the structural defects with the absence of ferromagnetism is discussed on the basis of theoretical calculations of the O K-edge absorption spectra. (C) 2015 Elsevier Ltd. All rights reserved.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - Comprehensive studies of structural, electronic and magnetic properties of Zn(0.9)5Co(0.05)O nanopowders
VL  - 74
SP  - 78
EP  - 84
DO  - 10.1016/j.materresbull.2015.10.014
ER  - 
@article{
author = "Radisavljević, Ivana and Novaković, Nikola and Matović, Branko and Paunović, Novica M. and Medić, Mirjana and Bundaleski, Nenad and Andrić, Velibor and Teodoro, Orlando M. N. D.",
year = "2016",
abstract = "X-ray absorption (XANES, EXAFS, XMCD) and photoelectron (XPS) spectroscopic techniques were employed to study local structural, electronic and magnetic properties of Zn0.95Co0.05O nanopowders. The substitutional Co2+ ions are incorporated in ZnO lattice at regular Zn sites and the sample is characterized by high structural order. There was no sign of ferromagnetic ordering of Co magnetic moments and the sample is in paramagnetic state at all temperatures down to 5 K. The possible connection of the structural defects with the absence of ferromagnetism is discussed on the basis of theoretical calculations of the O K-edge absorption spectra. (C) 2015 Elsevier Ltd. All rights reserved.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "Comprehensive studies of structural, electronic and magnetic properties of Zn(0.9)5Co(0.05)O nanopowders",
volume = "74",
pages = "78-84",
doi = "10.1016/j.materresbull.2015.10.014"
}
Radisavljević, I., Novaković, N., Matović, B., Paunović, N. M., Medić, M., Bundaleski, N., Andrić, V.,& Teodoro, O. M. N. D.. (2016). Comprehensive studies of structural, electronic and magnetic properties of Zn(0.9)5Co(0.05)O nanopowders. in Materials Research Bulletin
Elsevier., 74, 78-84.
https://doi.org/10.1016/j.materresbull.2015.10.014
Radisavljević I, Novaković N, Matović B, Paunović NM, Medić M, Bundaleski N, Andrić V, Teodoro OMND. Comprehensive studies of structural, electronic and magnetic properties of Zn(0.9)5Co(0.05)O nanopowders. in Materials Research Bulletin. 2016;74:78-84.
doi:10.1016/j.materresbull.2015.10.014 .
Radisavljević, Ivana, Novaković, Nikola, Matović, Branko, Paunović, Novica M., Medić, Mirjana, Bundaleski, Nenad, Andrić, Velibor, Teodoro, Orlando M. N. D., "Comprehensive studies of structural, electronic and magnetic properties of Zn(0.9)5Co(0.05)O nanopowders" in Materials Research Bulletin, 74 (2016):78-84,
https://doi.org/10.1016/j.materresbull.2015.10.014 . .
5
4
5

Production of N-graphene by microwave N-2-Ar plasma

Dias, Ana Paula Soares; Bundaleski, Nenad; Tatarova, Elena; Dias, Francisco M.; Abrashev, Miroslav; Cvelbar, Uroš; Teodoro, Orlando M. N. D.; Henriques, Julio A. P.

(2016)

TY  - JOUR
AU  - Dias, Ana Paula Soares
AU  - Bundaleski, Nenad
AU  - Tatarova, Elena
AU  - Dias, Francisco M.
AU  - Abrashev, Miroslav
AU  - Cvelbar, Uroš
AU  - Teodoro, Orlando M. N. D.
AU  - Henriques, Julio A. P.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/912
AB  - Self-standing N-graphene sheets were produced in low-pressure microwave N-2-Ar plasma. The graphene sheets were exposed to the plasma for various durations and doped with nitrogen atoms, which were incorporated into the hexagonal carbon lattice in pyridinic, pyrrolic and quaternary functional groups, mainly. Atomic nitrogen emissions at the substrate position in the plasma were detected using optical emission spectroscopy. Raman spectroscopy, x-ray photoelectron spectroscopy and transmission electron microscopy techniques were also applied for material characterization. Doping levels as high as 5.6% were achieved and an increase in the sp(2)/sp(3) ratio was observed for a relatively short exposure time.
T2  - Journal of Physics. D: Applied Physics
T1  - Production of N-graphene by microwave N-2-Ar plasma
VL  - 49
IS  - 5
DO  - 10.1088/0022-3727/49/5/055307
ER  - 
@article{
author = "Dias, Ana Paula Soares and Bundaleski, Nenad and Tatarova, Elena and Dias, Francisco M. and Abrashev, Miroslav and Cvelbar, Uroš and Teodoro, Orlando M. N. D. and Henriques, Julio A. P.",
year = "2016",
abstract = "Self-standing N-graphene sheets were produced in low-pressure microwave N-2-Ar plasma. The graphene sheets were exposed to the plasma for various durations and doped with nitrogen atoms, which were incorporated into the hexagonal carbon lattice in pyridinic, pyrrolic and quaternary functional groups, mainly. Atomic nitrogen emissions at the substrate position in the plasma were detected using optical emission spectroscopy. Raman spectroscopy, x-ray photoelectron spectroscopy and transmission electron microscopy techniques were also applied for material characterization. Doping levels as high as 5.6% were achieved and an increase in the sp(2)/sp(3) ratio was observed for a relatively short exposure time.",
journal = "Journal of Physics. D: Applied Physics",
title = "Production of N-graphene by microwave N-2-Ar plasma",
volume = "49",
number = "5",
doi = "10.1088/0022-3727/49/5/055307"
}
Dias, A. P. S., Bundaleski, N., Tatarova, E., Dias, F. M., Abrashev, M., Cvelbar, U., Teodoro, O. M. N. D.,& Henriques, J. A. P.. (2016). Production of N-graphene by microwave N-2-Ar plasma. in Journal of Physics. D: Applied Physics, 49(5).
https://doi.org/10.1088/0022-3727/49/5/055307
Dias APS, Bundaleski N, Tatarova E, Dias FM, Abrashev M, Cvelbar U, Teodoro OMND, Henriques JAP. Production of N-graphene by microwave N-2-Ar plasma. in Journal of Physics. D: Applied Physics. 2016;49(5).
doi:10.1088/0022-3727/49/5/055307 .
Dias, Ana Paula Soares, Bundaleski, Nenad, Tatarova, Elena, Dias, Francisco M., Abrashev, Miroslav, Cvelbar, Uroš, Teodoro, Orlando M. N. D., Henriques, Julio A. P., "Production of N-graphene by microwave N-2-Ar plasma" in Journal of Physics. D: Applied Physics, 49, no. 5 (2016),
https://doi.org/10.1088/0022-3727/49/5/055307 . .
32
24
31

XAFS and XPS analysis of Zn0.98Fe0.02Te0.91Se0.09 semiconductor

Radisavljević, Ivana; Trigueiro, J.; Bundaleski, Nenad; Medić, Mirjana; Romčević, Nebojša Ž.; Teodoro, Orlando M. N. D.; Mitrić, Miodrag; Ivanović, Nenad

(2015)

TY  - JOUR
AU  - Radisavljević, Ivana
AU  - Trigueiro, J.
AU  - Bundaleski, Nenad
AU  - Medić, Mirjana
AU  - Romčević, Nebojša Ž.
AU  - Teodoro, Orlando M. N. D.
AU  - Mitrić, Miodrag
AU  - Ivanović, Nenad
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/425
AB  - Local structures and electronic properties of II-VI quaternary Zn0.98Fe0.02Te0.91Se0.09 mixed crystal are studied by X-ray absorption fine structure (XAFS) while the surface composition and its oxidation in air are studied by X-ray photoelectron spectroscopy (XPS). That way the surface stability and its modification with respect to the bulk are elucidated. The effects of surface oxidation on rearrangement and segregation of constituent atomic species at the surface are revealed and possible mechanisms of oxygen adsorption are discussed. (C) 2015 Elsevier B.V. All rights reserved.
T2  - Journal of Alloys and Compounds
T1  - XAFS and XPS analysis of Zn0.98Fe0.02Te0.91Se0.09 semiconductor
VL  - 632
SP  - 17
EP  - 22
DO  - 10.1016/j.jallcom.2015.01.169
ER  - 
@article{
author = "Radisavljević, Ivana and Trigueiro, J. and Bundaleski, Nenad and Medić, Mirjana and Romčević, Nebojša Ž. and Teodoro, Orlando M. N. D. and Mitrić, Miodrag and Ivanović, Nenad",
year = "2015",
abstract = "Local structures and electronic properties of II-VI quaternary Zn0.98Fe0.02Te0.91Se0.09 mixed crystal are studied by X-ray absorption fine structure (XAFS) while the surface composition and its oxidation in air are studied by X-ray photoelectron spectroscopy (XPS). That way the surface stability and its modification with respect to the bulk are elucidated. The effects of surface oxidation on rearrangement and segregation of constituent atomic species at the surface are revealed and possible mechanisms of oxygen adsorption are discussed. (C) 2015 Elsevier B.V. All rights reserved.",
journal = "Journal of Alloys and Compounds",
title = "XAFS and XPS analysis of Zn0.98Fe0.02Te0.91Se0.09 semiconductor",
volume = "632",
pages = "17-22",
doi = "10.1016/j.jallcom.2015.01.169"
}
Radisavljević, I., Trigueiro, J., Bundaleski, N., Medić, M., Romčević, N. Ž., Teodoro, O. M. N. D., Mitrić, M.,& Ivanović, N.. (2015). XAFS and XPS analysis of Zn0.98Fe0.02Te0.91Se0.09 semiconductor. in Journal of Alloys and Compounds, 632, 17-22.
https://doi.org/10.1016/j.jallcom.2015.01.169
Radisavljević I, Trigueiro J, Bundaleski N, Medić M, Romčević NŽ, Teodoro OMND, Mitrić M, Ivanović N. XAFS and XPS analysis of Zn0.98Fe0.02Te0.91Se0.09 semiconductor. in Journal of Alloys and Compounds. 2015;632:17-22.
doi:10.1016/j.jallcom.2015.01.169 .
Radisavljević, Ivana, Trigueiro, J., Bundaleski, Nenad, Medić, Mirjana, Romčević, Nebojša Ž., Teodoro, Orlando M. N. D., Mitrić, Miodrag, Ivanović, Nenad, "XAFS and XPS analysis of Zn0.98Fe0.02Te0.91Se0.09 semiconductor" in Journal of Alloys and Compounds, 632 (2015):17-22,
https://doi.org/10.1016/j.jallcom.2015.01.169 . .
8
6
8

Calculation of the angular dependence of the total electron yield

Bundaleski, Nenad; Belhaj, M.; Gineste, T.; Teodoro, Orlando M. N. D.

(2015)

TY  - JOUR
AU  - Bundaleski, Nenad
AU  - Belhaj, M.
AU  - Gineste, T.
AU  - Teodoro, Orlando M. N. D.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7085
AB  - Secondary electron emission plays an important role in many applic. ations such as scanning electron microscopy, space applications and accelerator technologies. Secondary electron yield delta(E)at normal incidence of a primary electron beam is frequently modelled by the well-known semi-empirical law. However, this model is not used in a consistent way to predict the angular dependence. Additionally, neglecting the energy reflection has particular influence on the angular dependence of the secondary electron yield and therefore cannot be ignored. We propose here a simple approach to calculate delta(E) for any incident angle based on the experimental result achieved at normal incidence. The secondary electron yield is calculated according to the universal semi-empirical law, while a fraction of the electron energy deposited into the sample is calculated using a Monte Carlo simulation. A simple modification of the original model for calculating a total electron yield (i.e. the sum of the true secondaries and backscattered electrons) is also presented. Very good agreement is observed between measurements and the calculation as long as the roughness is not significant The model works very well for both, low Z and high Z materials. In the case of rough samples this approach cannot predict the angular dependence of the total electron yield. (C) 2015 Elsevier Ltd. All rights reserved.
T2  - Vacuum
T1  - Calculation of the angular dependence of the total electron yield
VL  - 122
SP  - 255
EP  - 259
DO  - 10.1016/j.vacuum.2015.04.010
ER  - 
@article{
author = "Bundaleski, Nenad and Belhaj, M. and Gineste, T. and Teodoro, Orlando M. N. D.",
year = "2015",
abstract = "Secondary electron emission plays an important role in many applic. ations such as scanning electron microscopy, space applications and accelerator technologies. Secondary electron yield delta(E)at normal incidence of a primary electron beam is frequently modelled by the well-known semi-empirical law. However, this model is not used in a consistent way to predict the angular dependence. Additionally, neglecting the energy reflection has particular influence on the angular dependence of the secondary electron yield and therefore cannot be ignored. We propose here a simple approach to calculate delta(E) for any incident angle based on the experimental result achieved at normal incidence. The secondary electron yield is calculated according to the universal semi-empirical law, while a fraction of the electron energy deposited into the sample is calculated using a Monte Carlo simulation. A simple modification of the original model for calculating a total electron yield (i.e. the sum of the true secondaries and backscattered electrons) is also presented. Very good agreement is observed between measurements and the calculation as long as the roughness is not significant The model works very well for both, low Z and high Z materials. In the case of rough samples this approach cannot predict the angular dependence of the total electron yield. (C) 2015 Elsevier Ltd. All rights reserved.",
journal = "Vacuum",
title = "Calculation of the angular dependence of the total electron yield",
volume = "122",
pages = "255-259",
doi = "10.1016/j.vacuum.2015.04.010"
}
Bundaleski, N., Belhaj, M., Gineste, T.,& Teodoro, O. M. N. D.. (2015). Calculation of the angular dependence of the total electron yield. in Vacuum, 122, 255-259.
https://doi.org/10.1016/j.vacuum.2015.04.010
Bundaleski N, Belhaj M, Gineste T, Teodoro OMND. Calculation of the angular dependence of the total electron yield. in Vacuum. 2015;122:255-259.
doi:10.1016/j.vacuum.2015.04.010 .
Bundaleski, Nenad, Belhaj, M., Gineste, T., Teodoro, Orlando M. N. D., "Calculation of the angular dependence of the total electron yield" in Vacuum, 122 (2015):255-259,
https://doi.org/10.1016/j.vacuum.2015.04.010 . .
15
10
15