Aćimović, Danka

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orcid::0000-0001-7506-9684
  • Aćimović, Danka (10)
  • Aćimović, Danka D. (7)

Author's Bibliography

Low-Cost Graphene-Based Composite Electrodes for Electrochemical Oxidation of Phenolic Dyes

Ječmenica Dučić, Marija; Krstić, Aleksandar D.; Zdolšek, Nikola; Aćimović, Danka; Savić, Branislava; Brdarić, Tanja; Vasić Anićijević, Dragana D.

(2023)

TY  - JOUR
AU  - Ječmenica Dučić, Marija
AU  - Krstić, Aleksandar D.
AU  - Zdolšek, Nikola
AU  - Aćimović, Danka
AU  - Savić, Branislava
AU  - Brdarić, Tanja
AU  - Vasić Anićijević, Dragana D.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10619
AB  - Electrochemical removal of organic pollutants represents an attractive methodology in water depollution. The key challenges for researchers comprise finding simple, affordable electrode materials with satisfactory efficiency in all ranges of pollutant concentration. Electrochemical oxidation of a mixture of phenol-based dyes: bromocresol green (BCG), cresol red (CR), and thymol blue (TB), in sulphate medium, at total concentration not exceeding 15 ppm, has been performed using simply prepared, low-cost composite electrodes, based on graphene nanoplatelets (GNP) and metallic oxides (TiO2 and SnO2) loaded on stainless steel substrate: GNP@SS, SnO2/GNP@SS, and TiO2/GNP@SS. Electrodes were characterised by XRD, FTIR, and electrochemical techniques. The degradation kinetics of initial dyes was tracked with UPLC and GC-MS chromatography for 6 h, at a current density of 10 mA/cm2. GC-MS analysis of the degradation products revealed oxidised aromatic compounds as the main products, while TOC analysis confirmed a total mineralisation extent in the range of 30–35%. The proposed degradation mechanism involves the attack of OH-radical, as the main oxidising agent, to the hydroxyl oxygens of dye phenolic rings. Obtained results provide useful information for the further development of affordable laboratory-scale and industrial systems for the complete removal of phenol-based compounds.
T2  - Crystals
T1  - Low-Cost Graphene-Based Composite Electrodes for Electrochemical Oxidation of Phenolic Dyes
VL  - 13
IS  - 1
SP  - 125
DO  - 10.3390/cryst13010125
ER  - 
@article{
author = "Ječmenica Dučić, Marija and Krstić, Aleksandar D. and Zdolšek, Nikola and Aćimović, Danka and Savić, Branislava and Brdarić, Tanja and Vasić Anićijević, Dragana D.",
year = "2023",
abstract = "Electrochemical removal of organic pollutants represents an attractive methodology in water depollution. The key challenges for researchers comprise finding simple, affordable electrode materials with satisfactory efficiency in all ranges of pollutant concentration. Electrochemical oxidation of a mixture of phenol-based dyes: bromocresol green (BCG), cresol red (CR), and thymol blue (TB), in sulphate medium, at total concentration not exceeding 15 ppm, has been performed using simply prepared, low-cost composite electrodes, based on graphene nanoplatelets (GNP) and metallic oxides (TiO2 and SnO2) loaded on stainless steel substrate: GNP@SS, SnO2/GNP@SS, and TiO2/GNP@SS. Electrodes were characterised by XRD, FTIR, and electrochemical techniques. The degradation kinetics of initial dyes was tracked with UPLC and GC-MS chromatography for 6 h, at a current density of 10 mA/cm2. GC-MS analysis of the degradation products revealed oxidised aromatic compounds as the main products, while TOC analysis confirmed a total mineralisation extent in the range of 30–35%. The proposed degradation mechanism involves the attack of OH-radical, as the main oxidising agent, to the hydroxyl oxygens of dye phenolic rings. Obtained results provide useful information for the further development of affordable laboratory-scale and industrial systems for the complete removal of phenol-based compounds.",
journal = "Crystals",
title = "Low-Cost Graphene-Based Composite Electrodes for Electrochemical Oxidation of Phenolic Dyes",
volume = "13",
number = "1",
pages = "125",
doi = "10.3390/cryst13010125"
}
Ječmenica Dučić, M., Krstić, A. D., Zdolšek, N., Aćimović, D., Savić, B., Brdarić, T.,& Vasić Anićijević, D. D.. (2023). Low-Cost Graphene-Based Composite Electrodes for Electrochemical Oxidation of Phenolic Dyes. in Crystals, 13(1), 125.
https://doi.org/10.3390/cryst13010125
Ječmenica Dučić M, Krstić AD, Zdolšek N, Aćimović D, Savić B, Brdarić T, Vasić Anićijević DD. Low-Cost Graphene-Based Composite Electrodes for Electrochemical Oxidation of Phenolic Dyes. in Crystals. 2023;13(1):125.
doi:10.3390/cryst13010125 .
Ječmenica Dučić, Marija, Krstić, Aleksandar D., Zdolšek, Nikola, Aćimović, Danka, Savić, Branislava, Brdarić, Tanja, Vasić Anićijević, Dragana D., "Low-Cost Graphene-Based Composite Electrodes for Electrochemical Oxidation of Phenolic Dyes" in Crystals, 13, no. 1 (2023):125,
https://doi.org/10.3390/cryst13010125 . .
1
1

Modification of graphite electrode surface by laser irradiation-role of irradiation atmosphere

Aćimović, Danka; Brdarić, Tanja; Vasić Anićijević, Dragana; Simić, Marija; Ciganović, Jovan; Momčilović, Miloš

(Belgrade : Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Aćimović, Danka
AU  - Brdarić, Tanja
AU  - Vasić Anićijević, Dragana
AU  - Simić, Marija
AU  - Ciganović, Jovan
AU  - Momčilović, Miloš
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12808
AB  - In this study, surface modification of the graphite plate electrode induced by laser
irradiation treatment is presented. The electrode was irradiated in air and argon
atmosphere using the Nd:YAG laser. Surface modifications were analyzed by
profilometric measurements. The influence of irradiation atmosphere on electrochemical
active surface of graphite electrode was observed using cyclic voltammetry. The results
indicate that electrochemical active surface area of graphite electrode was increased using
laser irradiation, and highest value was obtained by laser irradiation in air atmosphere.
These cognitions can be useful for application of laser-treated electrode in environmental
chemistry for detection or removal of organic pollutants.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings
T1  - Modification of graphite electrode surface by laser irradiation-role of irradiation atmosphere
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12808
ER  - 
@conference{
author = "Aćimović, Danka and Brdarić, Tanja and Vasić Anićijević, Dragana and Simić, Marija and Ciganović, Jovan and Momčilović, Miloš",
year = "2022",
abstract = "In this study, surface modification of the graphite plate electrode induced by laser
irradiation treatment is presented. The electrode was irradiated in air and argon
atmosphere using the Nd:YAG laser. Surface modifications were analyzed by
profilometric measurements. The influence of irradiation atmosphere on electrochemical
active surface of graphite electrode was observed using cyclic voltammetry. The results
indicate that electrochemical active surface area of graphite electrode was increased using
laser irradiation, and highest value was obtained by laser irradiation in air atmosphere.
These cognitions can be useful for application of laser-treated electrode in environmental
chemistry for detection or removal of organic pollutants.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings",
title = "Modification of graphite electrode surface by laser irradiation-role of irradiation atmosphere",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12808"
}
Aćimović, D., Brdarić, T., Vasić Anićijević, D., Simić, M., Ciganović, J.,& Momčilović, M.. (2022). Modification of graphite electrode surface by laser irradiation-role of irradiation atmosphere. in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings
Belgrade : Society of Physical Chemists of Serbia..
https://hdl.handle.net/21.15107/rcub_vinar_12808
Aćimović D, Brdarić T, Vasić Anićijević D, Simić M, Ciganović J, Momčilović M. Modification of graphite electrode surface by laser irradiation-role of irradiation atmosphere. in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings. 2022;.
https://hdl.handle.net/21.15107/rcub_vinar_12808 .
Aćimović, Danka, Brdarić, Tanja, Vasić Anićijević, Dragana, Simić, Marija, Ciganović, Jovan, Momčilović, Miloš, "Modification of graphite electrode surface by laser irradiation-role of irradiation atmosphere" in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings (2022),
https://hdl.handle.net/21.15107/rcub_vinar_12808 .

Investigation Of ZrO2 And ZrO2/TiO2 Electrodes By Cyclic Voltammetry

Brdarić, Tanja; Aćimović, Danka; Savić, Branislava; Abazović, Nadica; Čomor, Mirjana; Ječmenica Dučić, Marija; Maksin, Danijela

(Bor : University of Belgrade, Technical Faculty in Bor, 2022)

TY  - CONF
AU  - Brdarić, Tanja
AU  - Aćimović, Danka
AU  - Savić, Branislava
AU  - Abazović, Nadica
AU  - Čomor, Mirjana
AU  - Ječmenica Dučić, Marija
AU  - Maksin, Danijela
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10713
AB  - The subject of this study were electrochemical characteristics of transition metal oxide electrodes, consisting specifically of ZrO2 and TiO2, which have different crystallographic structure and lattice parameters. Metal oxides are a significant class of materials which have found vast applications in electrocatalysis. Composites of diverse semiconductors typically display much enhanced electronic conductivity and decreased charge transfer resistance. The goal of this study was to hopefully prepare and investigate electrodes with improved properties, through combination of heterostructures of chemically and structurally dissimilar and wide-bandgap semiconductors. Electroactive surface area was determined by employing cyclic voltammetry peak current method.
PB  - Bor : University of Belgrade, Technical Faculty in Bor
C3  - EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings
T1  - Investigation Of ZrO2 And ZrO2/TiO2 Electrodes By Cyclic Voltammetry
SP  - 495
EP  - 498
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10713
ER  - 
@conference{
author = "Brdarić, Tanja and Aćimović, Danka and Savić, Branislava and Abazović, Nadica and Čomor, Mirjana and Ječmenica Dučić, Marija and Maksin, Danijela",
year = "2022",
abstract = "The subject of this study were electrochemical characteristics of transition metal oxide electrodes, consisting specifically of ZrO2 and TiO2, which have different crystallographic structure and lattice parameters. Metal oxides are a significant class of materials which have found vast applications in electrocatalysis. Composites of diverse semiconductors typically display much enhanced electronic conductivity and decreased charge transfer resistance. The goal of this study was to hopefully prepare and investigate electrodes with improved properties, through combination of heterostructures of chemically and structurally dissimilar and wide-bandgap semiconductors. Electroactive surface area was determined by employing cyclic voltammetry peak current method.",
publisher = "Bor : University of Belgrade, Technical Faculty in Bor",
journal = "EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings",
title = "Investigation Of ZrO2 And ZrO2/TiO2 Electrodes By Cyclic Voltammetry",
pages = "495-498",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10713"
}
Brdarić, T., Aćimović, D., Savić, B., Abazović, N., Čomor, M., Ječmenica Dučić, M.,& Maksin, D.. (2022). Investigation Of ZrO2 And ZrO2/TiO2 Electrodes By Cyclic Voltammetry. in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings
Bor : University of Belgrade, Technical Faculty in Bor., 495-498.
https://hdl.handle.net/21.15107/rcub_vinar_10713
Brdarić T, Aćimović D, Savić B, Abazović N, Čomor M, Ječmenica Dučić M, Maksin D. Investigation Of ZrO2 And ZrO2/TiO2 Electrodes By Cyclic Voltammetry. in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings. 2022;:495-498.
https://hdl.handle.net/21.15107/rcub_vinar_10713 .
Brdarić, Tanja, Aćimović, Danka, Savić, Branislava, Abazović, Nadica, Čomor, Mirjana, Ječmenica Dučić, Marija, Maksin, Danijela, "Investigation Of ZrO2 And ZrO2/TiO2 Electrodes By Cyclic Voltammetry" in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings (2022):495-498,
https://hdl.handle.net/21.15107/rcub_vinar_10713 .

Is It Possible to Restrain OER on Simple Carbon Electrodes to Efficiently Electrooxidize Organic Pollutants?

Ječmenica Dučić, Marija; Aćimović, Danka; Savić, Branislava; Rakočević, Lazar; Simić, Marija; Brdarić, Tanja; Vasić Anićijević, Dragana D.

(2022)

TY  - JOUR
AU  - Ječmenica Dučić, Marija
AU  - Aćimović, Danka
AU  - Savić, Branislava
AU  - Rakočević, Lazar
AU  - Simić, Marija
AU  - Brdarić, Tanja
AU  - Vasić Anićijević, Dragana D.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10412
AB  - This paper presents a comparative analysis of three carbon-based electrodes: bare multiwalled carbon nanotubes (MWCNT), SnO2/MWCNT, and PbO2/graphene-nanoribbons (PbO2/GNR) composites, as anodes for the electrooxidative degradation of Rhodamine B as a model organic pollutant. Anodic electrooxidation of Rhodamine B was performed on all three electrodes, and the decolorization efficiency was found to increase in the order MWCNT < PbO2/GNR < SnO2/MWCNT. The electrodes were characterized by X-ray photoelectron spectroscopy (XPS) and linear sweep voltammetry (LSV). It was proposed that, in the 0.1 M Na2SO4 applied as electrolyte, observed decolorization mainly occurs in the interaction of Rhodamine B with OH radical adsorbed on the anode. Finally, the obtained results were complemented with Density Functional Theory (DFT) calculations of OH-radical interaction with appropriate model surfaces: graphene(0001), SnO2(001), and PbO2(001). It was found that the stabilization of adsorbed OH-radical on metal oxide spots (SnO2 or PbO2) compared to carbon is responsible for the improved efficiency of composites in the degradation of Rhodamine B. The observed ability of metal oxides to improve the electrooxidative potential of carbon towards organic compounds can be useful in the future design of appropriate anodes.
T2  - Molecules
T1  - Is It Possible to Restrain OER on Simple Carbon Electrodes to Efficiently Electrooxidize Organic Pollutants?
VL  - 27
IS  - 16
SP  - 5203
DO  - 10.3390/molecules27165203
ER  - 
@article{
author = "Ječmenica Dučić, Marija and Aćimović, Danka and Savić, Branislava and Rakočević, Lazar and Simić, Marija and Brdarić, Tanja and Vasić Anićijević, Dragana D.",
year = "2022",
abstract = "This paper presents a comparative analysis of three carbon-based electrodes: bare multiwalled carbon nanotubes (MWCNT), SnO2/MWCNT, and PbO2/graphene-nanoribbons (PbO2/GNR) composites, as anodes for the electrooxidative degradation of Rhodamine B as a model organic pollutant. Anodic electrooxidation of Rhodamine B was performed on all three electrodes, and the decolorization efficiency was found to increase in the order MWCNT < PbO2/GNR < SnO2/MWCNT. The electrodes were characterized by X-ray photoelectron spectroscopy (XPS) and linear sweep voltammetry (LSV). It was proposed that, in the 0.1 M Na2SO4 applied as electrolyte, observed decolorization mainly occurs in the interaction of Rhodamine B with OH radical adsorbed on the anode. Finally, the obtained results were complemented with Density Functional Theory (DFT) calculations of OH-radical interaction with appropriate model surfaces: graphene(0001), SnO2(001), and PbO2(001). It was found that the stabilization of adsorbed OH-radical on metal oxide spots (SnO2 or PbO2) compared to carbon is responsible for the improved efficiency of composites in the degradation of Rhodamine B. The observed ability of metal oxides to improve the electrooxidative potential of carbon towards organic compounds can be useful in the future design of appropriate anodes.",
journal = "Molecules",
title = "Is It Possible to Restrain OER on Simple Carbon Electrodes to Efficiently Electrooxidize Organic Pollutants?",
volume = "27",
number = "16",
pages = "5203",
doi = "10.3390/molecules27165203"
}
Ječmenica Dučić, M., Aćimović, D., Savić, B., Rakočević, L., Simić, M., Brdarić, T.,& Vasić Anićijević, D. D.. (2022). Is It Possible to Restrain OER on Simple Carbon Electrodes to Efficiently Electrooxidize Organic Pollutants?. in Molecules, 27(16), 5203.
https://doi.org/10.3390/molecules27165203
Ječmenica Dučić M, Aćimović D, Savić B, Rakočević L, Simić M, Brdarić T, Vasić Anićijević DD. Is It Possible to Restrain OER on Simple Carbon Electrodes to Efficiently Electrooxidize Organic Pollutants?. in Molecules. 2022;27(16):5203.
doi:10.3390/molecules27165203 .
Ječmenica Dučić, Marija, Aćimović, Danka, Savić, Branislava, Rakočević, Lazar, Simić, Marija, Brdarić, Tanja, Vasić Anićijević, Dragana D., "Is It Possible to Restrain OER on Simple Carbon Electrodes to Efficiently Electrooxidize Organic Pollutants?" in Molecules, 27, no. 16 (2022):5203,
https://doi.org/10.3390/molecules27165203 . .
1
1

New Strategies For Development Of Highly Selective Materials For Carbon Dioxide Capturective materials for carbon dioxide capture

Ječmenica Dučić, Marija; Vasić Anićijević, Dragana D.; Savić, Branislava; Aćimović, Danka; Simić, Marija; Maksin, Danijela; Brdarić, Tanja

(University of Belgrade, Technical Faculty in Bor, 2022)

TY  - CONF
AU  - Ječmenica Dučić, Marija
AU  - Vasić Anićijević, Dragana D.
AU  - Savić, Branislava
AU  - Aćimović, Danka
AU  - Simić, Marija
AU  - Maksin, Danijela
AU  - Brdarić, Tanja
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10712
AB  - Selective separation of CO2 is a field of intensive research due to emerging emissions from fire coaled and natural gas power plants. In the focus of development efforts is a design of regenerable CO2 capture material where adsorption technologies and advanced solid adsorbents are again in the centre of interest. Short screening of composite zeolite/activated carbon material in the terms of its selectivity for CO2 towards water is presented in this research. Adsorption rate of CO2 and H2O is determined and analysed at two different temperatures and equilibrium pressure of 3.5 kPa which corresponds to flue gases contents. The results imply the water should be removed from treated gas before CO2 separation and capture. Design of advanced materials can be facilitated by implementation of DFT calculations. A preview of DFT analysed materials with higher affinity for CO2 than for water adsorption is presented within this research. It underscores the possibility of defining future strategies for the design of novel carbon dioxide capture materials more resistant to water compared to currently used zeolites.
PB  - University of Belgrade, Technical Faculty in Bor
C3  - EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings
T1  - New Strategies For Development Of Highly Selective Materials For Carbon Dioxide Capturective materials for carbon dioxide capture
SP  - 81
EP  - 84
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10712
ER  - 
@conference{
author = "Ječmenica Dučić, Marija and Vasić Anićijević, Dragana D. and Savić, Branislava and Aćimović, Danka and Simić, Marija and Maksin, Danijela and Brdarić, Tanja",
year = "2022",
abstract = "Selective separation of CO2 is a field of intensive research due to emerging emissions from fire coaled and natural gas power plants. In the focus of development efforts is a design of regenerable CO2 capture material where adsorption technologies and advanced solid adsorbents are again in the centre of interest. Short screening of composite zeolite/activated carbon material in the terms of its selectivity for CO2 towards water is presented in this research. Adsorption rate of CO2 and H2O is determined and analysed at two different temperatures and equilibrium pressure of 3.5 kPa which corresponds to flue gases contents. The results imply the water should be removed from treated gas before CO2 separation and capture. Design of advanced materials can be facilitated by implementation of DFT calculations. A preview of DFT analysed materials with higher affinity for CO2 than for water adsorption is presented within this research. It underscores the possibility of defining future strategies for the design of novel carbon dioxide capture materials more resistant to water compared to currently used zeolites.",
publisher = "University of Belgrade, Technical Faculty in Bor",
journal = "EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings",
title = "New Strategies For Development Of Highly Selective Materials For Carbon Dioxide Capturective materials for carbon dioxide capture",
pages = "81-84",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10712"
}
Ječmenica Dučić, M., Vasić Anićijević, D. D., Savić, B., Aćimović, D., Simić, M., Maksin, D.,& Brdarić, T.. (2022). New Strategies For Development Of Highly Selective Materials For Carbon Dioxide Capturective materials for carbon dioxide capture. in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings
University of Belgrade, Technical Faculty in Bor., 81-84.
https://hdl.handle.net/21.15107/rcub_vinar_10712
Ječmenica Dučić M, Vasić Anićijević DD, Savić B, Aćimović D, Simić M, Maksin D, Brdarić T. New Strategies For Development Of Highly Selective Materials For Carbon Dioxide Capturective materials for carbon dioxide capture. in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings. 2022;:81-84.
https://hdl.handle.net/21.15107/rcub_vinar_10712 .
Ječmenica Dučić, Marija, Vasić Anićijević, Dragana D., Savić, Branislava, Aćimović, Danka, Simić, Marija, Maksin, Danijela, Brdarić, Tanja, "New Strategies For Development Of Highly Selective Materials For Carbon Dioxide Capturective materials for carbon dioxide capture" in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings (2022):81-84,
https://hdl.handle.net/21.15107/rcub_vinar_10712 .

Testing the electrochemical behavior of BPA on GC, WO3 and MWCNT electrodes

Savić, Branislava; Aćimović, Danka; Brdarić, Tanja; Ognjanović, Miloš; Vasić Anićijević, Dragana; Ječmenica Dučić, Marija; Simić, Marija

(Bor : University of Belgrade, Technical Faculty in Bor, 2022)

TY  - CONF
AU  - Savić, Branislava
AU  - Aćimović, Danka
AU  - Brdarić, Tanja
AU  - Ognjanović, Miloš
AU  - Vasić Anićijević, Dragana
AU  - Ječmenica Dučić, Marija
AU  - Simić, Marija
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11681
AB  - Bisphenol A (BPA) is an organic compound used in large scale at the plastics industry and as a precursor in the synthesis of polycarbonates and epoxy resins, which lead to frequent detections of BPA in surface waters. Therefore, it is necessary to develop and improve methods for BPA detection and monitoring. The electrochemical behavior of Bisphenol A at WO3 and carbon-based electrodes, like glassy carbon (GC) and multi-walled carbon nanotubes (MWCNT), were compared using cyclic voltammetry (CV). Therefore, WO3 nanoparticles were obtained by hydrothermal method and characterization was done using XRDP. The results showed that the responses of the WO3 electrode were 30 times larger compared to another examined electrode. This implies that WO3 electrode can be useful for the detection BPA in nature media.
PB  - Bor : University of Belgrade, Technical Faculty in Bor
C3  - EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings
T1  - Testing the electrochemical behavior of BPA on GC, WO3 and MWCNT electrodes
SP  - 499
EP  - 503
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11681
ER  - 
@conference{
author = "Savić, Branislava and Aćimović, Danka and Brdarić, Tanja and Ognjanović, Miloš and Vasić Anićijević, Dragana and Ječmenica Dučić, Marija and Simić, Marija",
year = "2022",
abstract = "Bisphenol A (BPA) is an organic compound used in large scale at the plastics industry and as a precursor in the synthesis of polycarbonates and epoxy resins, which lead to frequent detections of BPA in surface waters. Therefore, it is necessary to develop and improve methods for BPA detection and monitoring. The electrochemical behavior of Bisphenol A at WO3 and carbon-based electrodes, like glassy carbon (GC) and multi-walled carbon nanotubes (MWCNT), were compared using cyclic voltammetry (CV). Therefore, WO3 nanoparticles were obtained by hydrothermal method and characterization was done using XRDP. The results showed that the responses of the WO3 electrode were 30 times larger compared to another examined electrode. This implies that WO3 electrode can be useful for the detection BPA in nature media.",
publisher = "Bor : University of Belgrade, Technical Faculty in Bor",
journal = "EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings",
title = "Testing the electrochemical behavior of BPA on GC, WO3 and MWCNT electrodes",
pages = "499-503",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11681"
}
Savić, B., Aćimović, D., Brdarić, T., Ognjanović, M., Vasić Anićijević, D., Ječmenica Dučić, M.,& Simić, M.. (2022). Testing the electrochemical behavior of BPA on GC, WO3 and MWCNT electrodes. in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings
Bor : University of Belgrade, Technical Faculty in Bor., 499-503.
https://hdl.handle.net/21.15107/rcub_vinar_11681
Savić B, Aćimović D, Brdarić T, Ognjanović M, Vasić Anićijević D, Ječmenica Dučić M, Simić M. Testing the electrochemical behavior of BPA on GC, WO3 and MWCNT electrodes. in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings. 2022;:499-503.
https://hdl.handle.net/21.15107/rcub_vinar_11681 .
Savić, Branislava, Aćimović, Danka, Brdarić, Tanja, Ognjanović, Miloš, Vasić Anićijević, Dragana, Ječmenica Dučić, Marija, Simić, Marija, "Testing the electrochemical behavior of BPA on GC, WO3 and MWCNT electrodes" in EcoTER’22 : 29th International Conference Ecological Truth and Environmental Research : Proceedings (2022):499-503,
https://hdl.handle.net/21.15107/rcub_vinar_11681 .

Electrooxidative Removal of Organophosphates - A Combined Experimental and Theoretical Approach

Aćimović, Danka D.; Vasić Anićijević, Dragana D.

(2022)

TY  - CHAP
AU  - Aćimović, Danka D.
AU  - Vasić Anićijević, Dragana D.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10726
AB  - Electrochemical oxidation is in general considered to be among the best methods for removing organic pesticides from wastewater. The oxidation of organophosphates induces the formation of a great number of various more or less toxic short-time living intermediates and finally leads to their complete degradation. This chapter presents an overview of the literature data concerning the electrochemical oxidation of several widely used organophosphate pesticides (malathion, diazinon, chlorpyrifos, dimethoate, methyl parathion). The influence of the electrode materials on selected organophosphates, the choice of an appropriate electrode, supporting electrolyte, and knowing the electrolysis parameters such as current density, temperature, oxidation rate, were elucidated. The theoretical calculation enabled us to identify the phenomena engaged near the electrode and to completely determine the structures of the products of electrochemical oxidation formed during the degradation. The comparison of the results relating to the various electrodes indicates that these materials have the power to reduce the quantity of the organic matter in the electrolyzed solution. © 2022 Nova Science Publishers, Inc.
T2  - Organophosphates: Detection, Exposure and Occurrence. Volume 1: Impact on Health and the Natural Environment
T1  - Electrooxidative Removal of Organophosphates - A Combined Experimental and Theoretical Approach
SP  - 215
EP  - 250
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10726
ER  - 
@inbook{
author = "Aćimović, Danka D. and Vasić Anićijević, Dragana D.",
year = "2022",
abstract = "Electrochemical oxidation is in general considered to be among the best methods for removing organic pesticides from wastewater. The oxidation of organophosphates induces the formation of a great number of various more or less toxic short-time living intermediates and finally leads to their complete degradation. This chapter presents an overview of the literature data concerning the electrochemical oxidation of several widely used organophosphate pesticides (malathion, diazinon, chlorpyrifos, dimethoate, methyl parathion). The influence of the electrode materials on selected organophosphates, the choice of an appropriate electrode, supporting electrolyte, and knowing the electrolysis parameters such as current density, temperature, oxidation rate, were elucidated. The theoretical calculation enabled us to identify the phenomena engaged near the electrode and to completely determine the structures of the products of electrochemical oxidation formed during the degradation. The comparison of the results relating to the various electrodes indicates that these materials have the power to reduce the quantity of the organic matter in the electrolyzed solution. © 2022 Nova Science Publishers, Inc.",
journal = "Organophosphates: Detection, Exposure and Occurrence. Volume 1: Impact on Health and the Natural Environment",
booktitle = "Electrooxidative Removal of Organophosphates - A Combined Experimental and Theoretical Approach",
pages = "215-250",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10726"
}
Aćimović, D. D.,& Vasić Anićijević, D. D.. (2022). Electrooxidative Removal of Organophosphates - A Combined Experimental and Theoretical Approach. in Organophosphates: Detection, Exposure and Occurrence. Volume 1: Impact on Health and the Natural Environment, 215-250.
https://hdl.handle.net/21.15107/rcub_vinar_10726
Aćimović DD, Vasić Anićijević DD. Electrooxidative Removal of Organophosphates - A Combined Experimental and Theoretical Approach. in Organophosphates: Detection, Exposure and Occurrence. Volume 1: Impact on Health and the Natural Environment. 2022;:215-250.
https://hdl.handle.net/21.15107/rcub_vinar_10726 .
Aćimović, Danka D., Vasić Anićijević, Dragana D., "Electrooxidative Removal of Organophosphates - A Combined Experimental and Theoretical Approach" in Organophosphates: Detection, Exposure and Occurrence. Volume 1: Impact on Health and the Natural Environment (2022):215-250,
https://hdl.handle.net/21.15107/rcub_vinar_10726 .

Degradation of rhodamine B Dye on graphite anode: kinetic and electrochemical behavior

Brdarić, Tanja; Aćimović, Danka; Savić, Branislava; Vasić Anićijević, Dragana D.; Ječmenica Dučić, Marija; Perović, Ivana; Maksin, Danijela

(2021)

TY  - CONF
AU  - Brdarić, Tanja
AU  - Aćimović, Danka
AU  - Savić, Branislava
AU  - Vasić Anićijević, Dragana D.
AU  - Ječmenica Dučić, Marija
AU  - Perović, Ivana
AU  - Maksin, Danijela
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10711
AB  - The aim of this study was to investigate the removal efficiency of Rhodamine B dye from NaCl aqueous solution by electrochemical oxidation on the graphite anode with a specific focus on the kinetics of the process. After 60 minutes of galvanostatic electrolysis on the applied current density of 25 mA cm-2 removal efficiency of about 97.6% was obtained. The degradation of Rhodamine B fitted well with the first-order kinetics.
C3  - PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry
T1  - Degradation of rhodamine B Dye on graphite anode: kinetic and electrochemical behavior
SP  - 287
EP  - 290
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10711
ER  - 
@conference{
author = "Brdarić, Tanja and Aćimović, Danka and Savić, Branislava and Vasić Anićijević, Dragana D. and Ječmenica Dučić, Marija and Perović, Ivana and Maksin, Danijela",
year = "2021",
abstract = "The aim of this study was to investigate the removal efficiency of Rhodamine B dye from NaCl aqueous solution by electrochemical oxidation on the graphite anode with a specific focus on the kinetics of the process. After 60 minutes of galvanostatic electrolysis on the applied current density of 25 mA cm-2 removal efficiency of about 97.6% was obtained. The degradation of Rhodamine B fitted well with the first-order kinetics.",
journal = "PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry",
title = "Degradation of rhodamine B Dye on graphite anode: kinetic and electrochemical behavior",
pages = "287-290",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10711"
}
Brdarić, T., Aćimović, D., Savić, B., Vasić Anićijević, D. D., Ječmenica Dučić, M., Perović, I.,& Maksin, D.. (2021). Degradation of rhodamine B Dye on graphite anode: kinetic and electrochemical behavior. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry, 287-290.
https://hdl.handle.net/21.15107/rcub_vinar_10711
Brdarić T, Aćimović D, Savić B, Vasić Anićijević DD, Ječmenica Dučić M, Perović I, Maksin D. Degradation of rhodamine B Dye on graphite anode: kinetic and electrochemical behavior. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry. 2021;:287-290.
https://hdl.handle.net/21.15107/rcub_vinar_10711 .
Brdarić, Tanja, Aćimović, Danka, Savić, Branislava, Vasić Anićijević, Dragana D., Ječmenica Dučić, Marija, Perović, Ivana, Maksin, Danijela, "Degradation of rhodamine B Dye on graphite anode: kinetic and electrochemical behavior" in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry (2021):287-290,
https://hdl.handle.net/21.15107/rcub_vinar_10711 .

Investigation Of Benzophenone-3 Electrochemical degradation On Titanium Electrode

Aćimović, Danka; Savić, Branislava; Brdarić, Tanja; Vasić Anićijević, Dragana; Ječmenica Dučić, Marija; Ćurčić, Milica; Maksin, Danijela

(Banja Luka : Akademija nauka i umjetnosti Republike Srpske, 2021)

TY  - CONF
AU  - Aćimović, Danka
AU  - Savić, Branislava
AU  - Brdarić, Tanja
AU  - Vasić Anićijević, Dragana
AU  - Ječmenica Dučić, Marija
AU  - Ćurčić, Milica
AU  - Maksin, Danijela
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10716
AB  - Benzophenone - 3 is a well - known molecular UV filter, main- ly found in commercial cosmetic preparation for sunscreen and skincare. Due t o increased use of sunscreens, it could be found in surface water and wastewater, which could affect the water quality and human health. Research indicates that benzophenone - 3 act as endocrine disruptor and has a carcinogen- ic and mutagenic effect on humans and other living organisms. As such, poses a health risk to all living beings and need to be removed from the environment. Electrochemical techniques for wastewater treatment of organic pollutants show advantages over commercial techniques as practicality , safety, and simple application on both, small and large systems. Aim of the presented research is to examine the possibility of using titanium anode plates for electrochemical degradation of benzophenone - 3 in 0.05M aqueous sodium chloride solution. Elect rolysis was performed in galvanostatic mode at a current density of 25 mA cm - 2 . During 40 minutes of electrolysis, the degradation efficiency of benzo- phenone - 3 is 98.3 %. Additional studies of process kinetics show that degrada- tion of benzophenone - 3 follow s first - order kinetics.
PB  - Banja Luka : Akademija nauka i umjetnosti Republike Srpske
C3  - Savremeni materijali 2021 : zbornik radova ; Contemporary Materials 2021 : Proceedings
T1  - Investigation Of Benzophenone-3 Electrochemical degradation On Titanium Electrode
SP  - 49
EP  - 58
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10716
ER  - 
@conference{
author = "Aćimović, Danka and Savić, Branislava and Brdarić, Tanja and Vasić Anićijević, Dragana and Ječmenica Dučić, Marija and Ćurčić, Milica and Maksin, Danijela",
year = "2021",
abstract = "Benzophenone - 3 is a well - known molecular UV filter, main- ly found in commercial cosmetic preparation for sunscreen and skincare. Due t o increased use of sunscreens, it could be found in surface water and wastewater, which could affect the water quality and human health. Research indicates that benzophenone - 3 act as endocrine disruptor and has a carcinogen- ic and mutagenic effect on humans and other living organisms. As such, poses a health risk to all living beings and need to be removed from the environment. Electrochemical techniques for wastewater treatment of organic pollutants show advantages over commercial techniques as practicality , safety, and simple application on both, small and large systems. Aim of the presented research is to examine the possibility of using titanium anode plates for electrochemical degradation of benzophenone - 3 in 0.05M aqueous sodium chloride solution. Elect rolysis was performed in galvanostatic mode at a current density of 25 mA cm - 2 . During 40 minutes of electrolysis, the degradation efficiency of benzo- phenone - 3 is 98.3 %. Additional studies of process kinetics show that degrada- tion of benzophenone - 3 follow s first - order kinetics.",
publisher = "Banja Luka : Akademija nauka i umjetnosti Republike Srpske",
journal = "Savremeni materijali 2021 : zbornik radova ; Contemporary Materials 2021 : Proceedings",
title = "Investigation Of Benzophenone-3 Electrochemical degradation On Titanium Electrode",
pages = "49-58",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10716"
}
Aćimović, D., Savić, B., Brdarić, T., Vasić Anićijević, D., Ječmenica Dučić, M., Ćurčić, M.,& Maksin, D.. (2021). Investigation Of Benzophenone-3 Electrochemical degradation On Titanium Electrode. in Savremeni materijali 2021 : zbornik radova ; Contemporary Materials 2021 : Proceedings
Banja Luka : Akademija nauka i umjetnosti Republike Srpske., 49-58.
https://hdl.handle.net/21.15107/rcub_vinar_10716
Aćimović D, Savić B, Brdarić T, Vasić Anićijević D, Ječmenica Dučić M, Ćurčić M, Maksin D. Investigation Of Benzophenone-3 Electrochemical degradation On Titanium Electrode. in Savremeni materijali 2021 : zbornik radova ; Contemporary Materials 2021 : Proceedings. 2021;:49-58.
https://hdl.handle.net/21.15107/rcub_vinar_10716 .
Aćimović, Danka, Savić, Branislava, Brdarić, Tanja, Vasić Anićijević, Dragana, Ječmenica Dučić, Marija, Ćurčić, Milica, Maksin, Danijela, "Investigation Of Benzophenone-3 Electrochemical degradation On Titanium Electrode" in Savremeni materijali 2021 : zbornik radova ; Contemporary Materials 2021 : Proceedings (2021):49-58,
https://hdl.handle.net/21.15107/rcub_vinar_10716 .

Electrochemical Degradation of Phenols on PbO2 /Graphene Nanoribbons Electrodes – a Combined Experimental and DFT Approach

Savić, Branislava; Vasić Anićijević, Dragana D.; Aćimović, Danka; Dabetić, M.; Ječmenica Dučić, Marija; Maksin, Danijela; Brdarić, Tanja

(Belgrade : Serbian Chemical Society, 2021)

TY  - CONF
AU  - Savić, Branislava
AU  - Vasić Anićijević, Dragana D.
AU  - Aćimović, Danka
AU  - Dabetić, M.
AU  - Ječmenica Dučić, Marija
AU  - Maksin, Danijela
AU  - Brdarić, Tanja
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10715
PB  - Belgrade : Serbian Chemical Society
C3  - EMEC21 : 21st European Meeting on Environmental Chemistry : Book of abstracts
T1  - Electrochemical Degradation of Phenols on PbO2 /Graphene Nanoribbons Electrodes – a Combined Experimental and DFT Approach
SP  - 113
EP  - 113
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10715
ER  - 
@conference{
author = "Savić, Branislava and Vasić Anićijević, Dragana D. and Aćimović, Danka and Dabetić, M. and Ječmenica Dučić, Marija and Maksin, Danijela and Brdarić, Tanja",
year = "2021",
publisher = "Belgrade : Serbian Chemical Society",
journal = "EMEC21 : 21st European Meeting on Environmental Chemistry : Book of abstracts",
title = "Electrochemical Degradation of Phenols on PbO2 /Graphene Nanoribbons Electrodes – a Combined Experimental and DFT Approach",
pages = "113-113",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10715"
}
Savić, B., Vasić Anićijević, D. D., Aćimović, D., Dabetić, M., Ječmenica Dučić, M., Maksin, D.,& Brdarić, T.. (2021). Electrochemical Degradation of Phenols on PbO2 /Graphene Nanoribbons Electrodes – a Combined Experimental and DFT Approach. in EMEC21 : 21st European Meeting on Environmental Chemistry : Book of abstracts
Belgrade : Serbian Chemical Society., 113-113.
https://hdl.handle.net/21.15107/rcub_vinar_10715
Savić B, Vasić Anićijević DD, Aćimović D, Dabetić M, Ječmenica Dučić M, Maksin D, Brdarić T. Electrochemical Degradation of Phenols on PbO2 /Graphene Nanoribbons Electrodes – a Combined Experimental and DFT Approach. in EMEC21 : 21st European Meeting on Environmental Chemistry : Book of abstracts. 2021;:113-113.
https://hdl.handle.net/21.15107/rcub_vinar_10715 .
Savić, Branislava, Vasić Anićijević, Dragana D., Aćimović, Danka, Dabetić, M., Ječmenica Dučić, Marija, Maksin, Danijela, Brdarić, Tanja, "Electrochemical Degradation of Phenols on PbO2 /Graphene Nanoribbons Electrodes – a Combined Experimental and DFT Approach" in EMEC21 : 21st European Meeting on Environmental Chemistry : Book of abstracts (2021):113-113,
https://hdl.handle.net/21.15107/rcub_vinar_10715 .

Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete

Aćimović, Danka D.; Nikolić, Željka; Tošić, Miloš S.; Milovanović, Dubravka S.; Nikolić, Vladimir M.; Brdarić, Tanja; Marčeta Kaninski, Milica

(2017)

TY  - JOUR
AU  - Aćimović, Danka D.
AU  - Nikolić, Željka
AU  - Tošić, Miloš S.
AU  - Milovanović, Dubravka S.
AU  - Nikolić, Vladimir M.
AU  - Brdarić, Tanja
AU  - Marčeta Kaninski, Milica
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1390
AB  - Human exposure to persistent organic contaminants, from building materials, negatively affects peoples health and overall quality of life. This paper presents the validation and uncertainty assessment of the analytical method, developed for the simultaneous determination of 16 EPA polycyclic aromatic hydrocarbons (PAHs) in solid-solid concrete by ultra-performance liquid chromatography with photo diode-array detector. Linearity of calibration curves was good over the whole range of calibration. Limits of detection varied between 0.2 and 2.9 mu gkg(-1). The accuracy in terms of recovery of the validated method is within the range from 54 to 106%. The developed method proved to be appropriate for analysis of PAHs and can be used for the quality control testing of concrete during the construction of new buildings, the old residences and related buildings associated with sick-building syndrome. In addition, this is the first reported method described for the evaluation of PAHs in solid-solid concrete. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Journal of Hazardous Materials
T1  - Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete
VL  - 325
SP  - 271
EP  - 278
DO  - 10.1016/j.jhazmat.2016.12.008
ER  - 
@article{
author = "Aćimović, Danka D. and Nikolić, Željka and Tošić, Miloš S. and Milovanović, Dubravka S. and Nikolić, Vladimir M. and Brdarić, Tanja and Marčeta Kaninski, Milica",
year = "2017",
abstract = "Human exposure to persistent organic contaminants, from building materials, negatively affects peoples health and overall quality of life. This paper presents the validation and uncertainty assessment of the analytical method, developed for the simultaneous determination of 16 EPA polycyclic aromatic hydrocarbons (PAHs) in solid-solid concrete by ultra-performance liquid chromatography with photo diode-array detector. Linearity of calibration curves was good over the whole range of calibration. Limits of detection varied between 0.2 and 2.9 mu gkg(-1). The accuracy in terms of recovery of the validated method is within the range from 54 to 106%. The developed method proved to be appropriate for analysis of PAHs and can be used for the quality control testing of concrete during the construction of new buildings, the old residences and related buildings associated with sick-building syndrome. In addition, this is the first reported method described for the evaluation of PAHs in solid-solid concrete. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Journal of Hazardous Materials",
title = "Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete",
volume = "325",
pages = "271-278",
doi = "10.1016/j.jhazmat.2016.12.008"
}
Aćimović, D. D., Nikolić, Ž., Tošić, M. S., Milovanović, D. S., Nikolić, V. M., Brdarić, T.,& Marčeta Kaninski, M.. (2017). Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete. in Journal of Hazardous Materials, 325, 271-278.
https://doi.org/10.1016/j.jhazmat.2016.12.008
Aćimović DD, Nikolić Ž, Tošić MS, Milovanović DS, Nikolić VM, Brdarić T, Marčeta Kaninski M. Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete. in Journal of Hazardous Materials. 2017;325:271-278.
doi:10.1016/j.jhazmat.2016.12.008 .
Aćimović, Danka D., Nikolić, Željka, Tošić, Miloš S., Milovanović, Dubravka S., Nikolić, Vladimir M., Brdarić, Tanja, Marčeta Kaninski, Milica, "Validation and uncertainty estimation of UPLC-PDA method for the analysis of polycyclic aromatic hydrocarbons in concrete" in Journal of Hazardous Materials, 325 (2017):271-278,
https://doi.org/10.1016/j.jhazmat.2016.12.008 . .
8
8
10

Electrochemical oxidation of the polycyclic aromatic hydrocarbons in polluted concrete of the residential buildings

Aćimović, Danka D.; Karić, Slavko D.; Nikolić, Željka; Brdarić, Tanja; Tasić, Gvozden S.; Marčeta Kaninski, Milica; Nikolić, Vladimir M.

(2017)

TY  - JOUR
AU  - Aćimović, Danka D.
AU  - Karić, Slavko D.
AU  - Nikolić, Željka
AU  - Brdarić, Tanja
AU  - Tasić, Gvozden S.
AU  - Marčeta Kaninski, Milica
AU  - Nikolić, Vladimir M.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1352
AB  - Polycyclic aromatic hydrocarbons (PAH) have been listed by the United States Environmental Protection Agency (US EPA) and by the European Community as priority environmental pollutants. The removal of PAHs from soils, sediments and waste water has attracted attention of scientists and engineers for several decades. Electrochemical oxidation of PAH compounds in water, is receiving increasing attention, due to its convenience and simplicity. In this study we performed electrochemical oxidation of 16 EPA PAHs mixture in 10% NaCI aqueous solution in potentiostatic conditions, at voltage 1 V. Decrease of concentration of some individual PAHs, up to 70% referred to their starting concentration, after 60 min of electrolysis, was confirmed by UPLC/PDA analysis. In further work investigation was extrapolated to in situ removal of PAHs from concrete, as the medium where, to our knowledge, such way of PAH removal has not been investigated before. High concentrations of PAH contamination occurred in the concrete structure of the residential buildings in Belgrade in 2014. Application of DC voltage of 50 V between nickel and stainless steel electrodes packed in the concrete wall, moisturized with the 10% NaCI solution, led to considerable removal of the pollutants by oxidation process throughout the concrete. (C) 2016 Elsevier Ltd. All rights reserved.
T2  - Environmental Pollution
T1  - Electrochemical oxidation of the polycyclic aromatic hydrocarbons in polluted concrete of the residential buildings
VL  - 220
SP  - 393
EP  - 399
DO  - 10.1016/j.envpol.2016.09.075
ER  - 
@article{
author = "Aćimović, Danka D. and Karić, Slavko D. and Nikolić, Željka and Brdarić, Tanja and Tasić, Gvozden S. and Marčeta Kaninski, Milica and Nikolić, Vladimir M.",
year = "2017",
abstract = "Polycyclic aromatic hydrocarbons (PAH) have been listed by the United States Environmental Protection Agency (US EPA) and by the European Community as priority environmental pollutants. The removal of PAHs from soils, sediments and waste water has attracted attention of scientists and engineers for several decades. Electrochemical oxidation of PAH compounds in water, is receiving increasing attention, due to its convenience and simplicity. In this study we performed electrochemical oxidation of 16 EPA PAHs mixture in 10% NaCI aqueous solution in potentiostatic conditions, at voltage 1 V. Decrease of concentration of some individual PAHs, up to 70% referred to their starting concentration, after 60 min of electrolysis, was confirmed by UPLC/PDA analysis. In further work investigation was extrapolated to in situ removal of PAHs from concrete, as the medium where, to our knowledge, such way of PAH removal has not been investigated before. High concentrations of PAH contamination occurred in the concrete structure of the residential buildings in Belgrade in 2014. Application of DC voltage of 50 V between nickel and stainless steel electrodes packed in the concrete wall, moisturized with the 10% NaCI solution, led to considerable removal of the pollutants by oxidation process throughout the concrete. (C) 2016 Elsevier Ltd. All rights reserved.",
journal = "Environmental Pollution",
title = "Electrochemical oxidation of the polycyclic aromatic hydrocarbons in polluted concrete of the residential buildings",
volume = "220",
pages = "393-399",
doi = "10.1016/j.envpol.2016.09.075"
}
Aćimović, D. D., Karić, S. D., Nikolić, Ž., Brdarić, T., Tasić, G. S., Marčeta Kaninski, M.,& Nikolić, V. M.. (2017). Electrochemical oxidation of the polycyclic aromatic hydrocarbons in polluted concrete of the residential buildings. in Environmental Pollution, 220, 393-399.
https://doi.org/10.1016/j.envpol.2016.09.075
Aćimović DD, Karić SD, Nikolić Ž, Brdarić T, Tasić GS, Marčeta Kaninski M, Nikolić VM. Electrochemical oxidation of the polycyclic aromatic hydrocarbons in polluted concrete of the residential buildings. in Environmental Pollution. 2017;220:393-399.
doi:10.1016/j.envpol.2016.09.075 .
Aćimović, Danka D., Karić, Slavko D., Nikolić, Željka, Brdarić, Tanja, Tasić, Gvozden S., Marčeta Kaninski, Milica, Nikolić, Vladimir M., "Electrochemical oxidation of the polycyclic aromatic hydrocarbons in polluted concrete of the residential buildings" in Environmental Pollution, 220 (2017):393-399,
https://doi.org/10.1016/j.envpol.2016.09.075 . .
12
5
11

Efficient hydrogen production using ternary Ni-Cu-Mo ionic activator

Perovic, Nana M.; Aćimović, Danka D.; Tasić, Gvozden S.; Karić, Slavko D.; Laušević, Petar; Marčeta Kaninski, Milica; Nikolić, Vladimir M.

(2015)

TY  - JOUR
AU  - Perovic, Nana M.
AU  - Aćimović, Danka D.
AU  - Tasić, Gvozden S.
AU  - Karić, Slavko D.
AU  - Laušević, Petar
AU  - Marčeta Kaninski, Milica
AU  - Nikolić, Vladimir M.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/533
AB  - This manuscript presents contribution on the improved efficiency of the alkaline electrolytic production of hydrogen by in situ adding activating compounds directly into the electrolyte during the electrolytic process. New electrode material, ternary system, Ni-Cu-Mo, was applied as activating compound i.e. ionic activator. The energy requirements per mass unit of hydrogen produced is reduced for more than 10%, compared to non-activated, 30 wt. % KOH electrolyte system. Energy saving is higher at higher temperatures and at higher current densities. During the electrolytic process, the ionic activators develop nanosized porous structure deposits on the surface of the Ni electrode. Presented results point out a strong possibility of the usage of ternary ionic activators in industrial applications. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
T2  - International Journal of Hydrogen Energy
T1  - Efficient hydrogen production using ternary Ni-Cu-Mo ionic activator
VL  - 40
IS  - 19
SP  - 6270
EP  - 6275
DO  - 10.1016/j.ijhydene.2015.03.003
ER  - 
@article{
author = "Perovic, Nana M. and Aćimović, Danka D. and Tasić, Gvozden S. and Karić, Slavko D. and Laušević, Petar and Marčeta Kaninski, Milica and Nikolić, Vladimir M.",
year = "2015",
abstract = "This manuscript presents contribution on the improved efficiency of the alkaline electrolytic production of hydrogen by in situ adding activating compounds directly into the electrolyte during the electrolytic process. New electrode material, ternary system, Ni-Cu-Mo, was applied as activating compound i.e. ionic activator. The energy requirements per mass unit of hydrogen produced is reduced for more than 10%, compared to non-activated, 30 wt. % KOH electrolyte system. Energy saving is higher at higher temperatures and at higher current densities. During the electrolytic process, the ionic activators develop nanosized porous structure deposits on the surface of the Ni electrode. Presented results point out a strong possibility of the usage of ternary ionic activators in industrial applications. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.",
journal = "International Journal of Hydrogen Energy",
title = "Efficient hydrogen production using ternary Ni-Cu-Mo ionic activator",
volume = "40",
number = "19",
pages = "6270-6275",
doi = "10.1016/j.ijhydene.2015.03.003"
}
Perovic, N. M., Aćimović, D. D., Tasić, G. S., Karić, S. D., Laušević, P., Marčeta Kaninski, M.,& Nikolić, V. M.. (2015). Efficient hydrogen production using ternary Ni-Cu-Mo ionic activator. in International Journal of Hydrogen Energy, 40(19), 6270-6275.
https://doi.org/10.1016/j.ijhydene.2015.03.003
Perovic NM, Aćimović DD, Tasić GS, Karić SD, Laušević P, Marčeta Kaninski M, Nikolić VM. Efficient hydrogen production using ternary Ni-Cu-Mo ionic activator. in International Journal of Hydrogen Energy. 2015;40(19):6270-6275.
doi:10.1016/j.ijhydene.2015.03.003 .
Perovic, Nana M., Aćimović, Danka D., Tasić, Gvozden S., Karić, Slavko D., Laušević, Petar, Marčeta Kaninski, Milica, Nikolić, Vladimir M., "Efficient hydrogen production using ternary Ni-Cu-Mo ionic activator" in International Journal of Hydrogen Energy, 40, no. 19 (2015):6270-6275,
https://doi.org/10.1016/j.ijhydene.2015.03.003 . .
6
9
7
9

Electrochemistry of cobalt ethylenediamine complexes at high pH

Miulović, Snežana M.; Nikolić, Vladimir M.; Laušević, Petar; Aćimović, Danka D.; Tasić, Gvozden S.; Marčeta Kaninski, Milica

(2015)

TY  - JOUR
AU  - Miulović, Snežana M.
AU  - Nikolić, Vladimir M.
AU  - Laušević, Petar
AU  - Aćimović, Danka D.
AU  - Tasić, Gvozden S.
AU  - Marčeta Kaninski, Milica
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/868
AB  - The electrochemical behavior of cobalt ethylenediamine complexes (Co(en)), at pH 12 was investigated by cyclic voltammetry (CV), the potentiostatic pulse technique and polarization curve measurements at stationary and rotating glassy carbon (GC) electrodes. It was shown that sixteen different species could be formed in a solution containing Co(en)3, with the most stable one at all pH values being [Co(en)(3)](3+). The reduction of [Co(en)(3)](3+) into [Co(en)(3)](2+) was shown to be a totally irreversible, one-electron exchange reaction. Further reduction of [Co(en)(3)](2+) was found to be a complex process leading to cobalt deposition at potentials more negative than -1.45 V vs. SCE. The process of [Co(en)(3)](2+) oxidation was also complex and most probably coupled with chemical reactions.
T2  - Journal of the Serbian Chemical Society
T1  - Electrochemistry of cobalt ethylenediamine complexes at high pH
VL  - 80
IS  - 12
SP  - 1515
EP  - 1527
DO  - 10.2298/JSC150327079M
ER  - 
@article{
author = "Miulović, Snežana M. and Nikolić, Vladimir M. and Laušević, Petar and Aćimović, Danka D. and Tasić, Gvozden S. and Marčeta Kaninski, Milica",
year = "2015",
abstract = "The electrochemical behavior of cobalt ethylenediamine complexes (Co(en)), at pH 12 was investigated by cyclic voltammetry (CV), the potentiostatic pulse technique and polarization curve measurements at stationary and rotating glassy carbon (GC) electrodes. It was shown that sixteen different species could be formed in a solution containing Co(en)3, with the most stable one at all pH values being [Co(en)(3)](3+). The reduction of [Co(en)(3)](3+) into [Co(en)(3)](2+) was shown to be a totally irreversible, one-electron exchange reaction. Further reduction of [Co(en)(3)](2+) was found to be a complex process leading to cobalt deposition at potentials more negative than -1.45 V vs. SCE. The process of [Co(en)(3)](2+) oxidation was also complex and most probably coupled with chemical reactions.",
journal = "Journal of the Serbian Chemical Society",
title = "Electrochemistry of cobalt ethylenediamine complexes at high pH",
volume = "80",
number = "12",
pages = "1515-1527",
doi = "10.2298/JSC150327079M"
}
Miulović, S. M., Nikolić, V. M., Laušević, P., Aćimović, D. D., Tasić, G. S.,& Marčeta Kaninski, M.. (2015). Electrochemistry of cobalt ethylenediamine complexes at high pH. in Journal of the Serbian Chemical Society, 80(12), 1515-1527.
https://doi.org/10.2298/JSC150327079M
Miulović SM, Nikolić VM, Laušević P, Aćimović DD, Tasić GS, Marčeta Kaninski M. Electrochemistry of cobalt ethylenediamine complexes at high pH. in Journal of the Serbian Chemical Society. 2015;80(12):1515-1527.
doi:10.2298/JSC150327079M .
Miulović, Snežana M., Nikolić, Vladimir M., Laušević, Petar, Aćimović, Danka D., Tasić, Gvozden S., Marčeta Kaninski, Milica, "Electrochemistry of cobalt ethylenediamine complexes at high pH" in Journal of the Serbian Chemical Society, 80, no. 12 (2015):1515-1527,
https://doi.org/10.2298/JSC150327079M . .
2
2
2

MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation

Cvetićanin, Jelena M.; Koteski, Vasil J.; Belošević-Čavor, Jelena; Radosavljević, Aleksandra; Kačarević-Popović, Zorica M.; Trpkov, Đorđe; Aćimović, Danka D.; Rogić Miladinović, Zorana; Cindrić, Mario; Nešković, Olivera M.

(2013)

TY  - JOUR
AU  - Cvetićanin, Jelena M.
AU  - Koteski, Vasil J.
AU  - Belošević-Čavor, Jelena
AU  - Radosavljević, Aleksandra
AU  - Kačarević-Popović, Zorica M.
AU  - Trpkov, Đorđe
AU  - Aćimović, Danka D.
AU  - Rogić Miladinović, Zorana
AU  - Cindrić, Mario
AU  - Nešković, Olivera M.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5207
AB  - The aim of this study is to evaluate the size and stability of radiolytically produced silver clusters. The clusters obtained by the gamma irradiation of a mixture of a silver salt and polyvinyl alcohol (PVA) were studied both theoretically and by mass spectrometry. MALDI TOF mass spectrometry of the Ag-n clusters showed the presence of clusters containing between 5 and 29 atoms. Both the theoretical and experimental results of this paper show that the most stable clusters are small clusters with an odd number of atoms. The stability of these clusters is correlated with the clusters electronic configuration. (C) 2012 Elsevier Ltd. All rights reserved.
T2  - Vacuum
T1  - MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation
VL  - 89
IS  - SI
SP  - 47
EP  - 52
DO  - 10.1016/j.vacuum.2012.08.016
ER  - 
@article{
author = "Cvetićanin, Jelena M. and Koteski, Vasil J. and Belošević-Čavor, Jelena and Radosavljević, Aleksandra and Kačarević-Popović, Zorica M. and Trpkov, Đorđe and Aćimović, Danka D. and Rogić Miladinović, Zorana and Cindrić, Mario and Nešković, Olivera M.",
year = "2013",
abstract = "The aim of this study is to evaluate the size and stability of radiolytically produced silver clusters. The clusters obtained by the gamma irradiation of a mixture of a silver salt and polyvinyl alcohol (PVA) were studied both theoretically and by mass spectrometry. MALDI TOF mass spectrometry of the Ag-n clusters showed the presence of clusters containing between 5 and 29 atoms. Both the theoretical and experimental results of this paper show that the most stable clusters are small clusters with an odd number of atoms. The stability of these clusters is correlated with the clusters electronic configuration. (C) 2012 Elsevier Ltd. All rights reserved.",
journal = "Vacuum",
title = "MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation",
volume = "89",
number = "SI",
pages = "47-52",
doi = "10.1016/j.vacuum.2012.08.016"
}
Cvetićanin, J. M., Koteski, V. J., Belošević-Čavor, J., Radosavljević, A., Kačarević-Popović, Z. M., Trpkov, Đ., Aćimović, D. D., Rogić Miladinović, Z., Cindrić, M.,& Nešković, O. M.. (2013). MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation. in Vacuum, 89(SI), 47-52.
https://doi.org/10.1016/j.vacuum.2012.08.016
Cvetićanin JM, Koteski VJ, Belošević-Čavor J, Radosavljević A, Kačarević-Popović ZM, Trpkov Đ, Aćimović DD, Rogić Miladinović Z, Cindrić M, Nešković OM. MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation. in Vacuum. 2013;89(SI):47-52.
doi:10.1016/j.vacuum.2012.08.016 .
Cvetićanin, Jelena M., Koteski, Vasil J., Belošević-Čavor, Jelena, Radosavljević, Aleksandra, Kačarević-Popović, Zorica M., Trpkov, Đorđe, Aćimović, Danka D., Rogić Miladinović, Zorana, Cindrić, Mario, Nešković, Olivera M., "MALDI TOF and theoretical investigation of silver clusters obtained by gamma irradiation" in Vacuum, 89, no. SI (2013):47-52,
https://doi.org/10.1016/j.vacuum.2012.08.016 . .
7
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7

MALDI TOF and AFM studies of DNA/SWNT hybrids

Trpkov, Đorđe; Rogić Miladinović, Zorana; Aćimović, Danka D.; Cvetićanin, Jelena M.; Rakočević, Zlatko Lj.; Nešković, Olivera M.

(Society of Physical Chemists of Serbia, 2012)

TY  - CONF
AU  - Trpkov, Đorđe
AU  - Rogić Miladinović, Zorana
AU  - Aćimović, Danka D.
AU  - Cvetićanin, Jelena M.
AU  - Rakočević, Zlatko Lj.
AU  - Nešković, Olivera M.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9270
AB  - A primer is a strand of nucleic acid that serves as a starting point for DNA
synthesis. DNA, as a large molecule, is very difficult for analysis by means of mass
spectrometry. However, primer, as a short sequence of nucleic acid, is much more
convinient for e.g. MALDI TOF MS analysis. Mass spectrometric experiment
resulted in quality MALDI TOF spectra of 3 primers. Compound 3-HPA (3-
hydroxypicolinic acid) showed the best results as matrix. AFM studies were also
conducted, for both pure primer samples and hybrids of primer molecule with
single wall carbon nanotubes (SWNT). Thus, obtained functionalisation of SWNT
with DNA primers was confirmed by AFM imaging. AFM images clearly showed
wrapping of DNA structures around nanotube „template“. Functionalisation of
SWNT is very important for potential applications of nanotubes in biomedical
field. MALDI TOF mass spectrometry, in combination with AFM imaging, proved
its great potential in analysis of short DNA sequences, and indicated the possibility
of investigating more complex DNA structures.
PB  - Society of Physical Chemists of Serbia
C3  - Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry
T1  - MALDI TOF and AFM studies of DNA/SWNT hybrids
VL  - 1
SP  - 125
EP  - 127
UR  - https://hdl.handle.net/21.15107/rcub_vinar_9270
ER  - 
@conference{
author = "Trpkov, Đorđe and Rogić Miladinović, Zorana and Aćimović, Danka D. and Cvetićanin, Jelena M. and Rakočević, Zlatko Lj. and Nešković, Olivera M.",
year = "2012",
abstract = "A primer is a strand of nucleic acid that serves as a starting point for DNA
synthesis. DNA, as a large molecule, is very difficult for analysis by means of mass
spectrometry. However, primer, as a short sequence of nucleic acid, is much more
convinient for e.g. MALDI TOF MS analysis. Mass spectrometric experiment
resulted in quality MALDI TOF spectra of 3 primers. Compound 3-HPA (3-
hydroxypicolinic acid) showed the best results as matrix. AFM studies were also
conducted, for both pure primer samples and hybrids of primer molecule with
single wall carbon nanotubes (SWNT). Thus, obtained functionalisation of SWNT
with DNA primers was confirmed by AFM imaging. AFM images clearly showed
wrapping of DNA structures around nanotube „template“. Functionalisation of
SWNT is very important for potential applications of nanotubes in biomedical
field. MALDI TOF mass spectrometry, in combination with AFM imaging, proved
its great potential in analysis of short DNA sequences, and indicated the possibility
of investigating more complex DNA structures.",
publisher = "Society of Physical Chemists of Serbia",
journal = "Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry",
title = "MALDI TOF and AFM studies of DNA/SWNT hybrids",
volume = "1",
pages = "125-127",
url = "https://hdl.handle.net/21.15107/rcub_vinar_9270"
}
Trpkov, Đ., Rogić Miladinović, Z., Aćimović, D. D., Cvetićanin, J. M., Rakočević, Z. Lj.,& Nešković, O. M.. (2012). MALDI TOF and AFM studies of DNA/SWNT hybrids. in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry
Society of Physical Chemists of Serbia., 1, 125-127.
https://hdl.handle.net/21.15107/rcub_vinar_9270
Trpkov Đ, Rogić Miladinović Z, Aćimović DD, Cvetićanin JM, Rakočević ZL, Nešković OM. MALDI TOF and AFM studies of DNA/SWNT hybrids. in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry. 2012;1:125-127.
https://hdl.handle.net/21.15107/rcub_vinar_9270 .
Trpkov, Đorđe, Rogić Miladinović, Zorana, Aćimović, Danka D., Cvetićanin, Jelena M., Rakočević, Zlatko Lj., Nešković, Olivera M., "MALDI TOF and AFM studies of DNA/SWNT hybrids" in Physical chemistry 2012 : 11th international conference on fundamental and applied aspects of physical chemistry, 1 (2012):125-127,
https://hdl.handle.net/21.15107/rcub_vinar_9270 .

MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite

Đorđević, Aleksandar; Seke, Mariana; Trpkov, Đorđe; Cvetićanin, Jelena; Rogić Miladinović, Zorana; Aćimović, Danka; Demajo, Miroslav; Nešković, Olivera; Rakočević, Zlatko

(Belgrade : Vinča Institute of Nuclear Sciences, 2012)

TY  - CONF
AU  - Đorđević, Aleksandar
AU  - Seke, Mariana
AU  - Trpkov, Đorđe
AU  - Cvetićanin, Jelena
AU  - Rogić Miladinović, Zorana
AU  - Aćimović, Danka
AU  - Demajo, Miroslav
AU  - Nešković, Olivera
AU  - Rakočević, Zlatko
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12409
PB  - Belgrade : Vinča Institute of Nuclear Sciences
C3  - 3rd Workshop Specific Methods for Food Safety and Quality : Proceedings
T1  - MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite
SP  - 34
EP  - 38
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12409
ER  - 
@conference{
author = "Đorđević, Aleksandar and Seke, Mariana and Trpkov, Đorđe and Cvetićanin, Jelena and Rogić Miladinović, Zorana and Aćimović, Danka and Demajo, Miroslav and Nešković, Olivera and Rakočević, Zlatko",
year = "2012",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences",
journal = "3rd Workshop Specific Methods for Food Safety and Quality : Proceedings",
title = "MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite",
pages = "34-38",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12409"
}
Đorđević, A., Seke, M., Trpkov, Đ., Cvetićanin, J., Rogić Miladinović, Z., Aćimović, D., Demajo, M., Nešković, O.,& Rakočević, Z.. (2012). MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite. in 3rd Workshop Specific Methods for Food Safety and Quality : Proceedings
Belgrade : Vinča Institute of Nuclear Sciences., 34-38.
https://hdl.handle.net/21.15107/rcub_vinar_12409
Đorđević A, Seke M, Trpkov Đ, Cvetićanin J, Rogić Miladinović Z, Aćimović D, Demajo M, Nešković O, Rakočević Z. MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite. in 3rd Workshop Specific Methods for Food Safety and Quality : Proceedings. 2012;:34-38.
https://hdl.handle.net/21.15107/rcub_vinar_12409 .
Đorđević, Aleksandar, Seke, Mariana, Trpkov, Đorđe, Cvetićanin, Jelena, Rogić Miladinović, Zorana, Aćimović, Danka, Demajo, Miroslav, Nešković, Olivera, Rakočević, Zlatko, "MALDI TOF and AFM study of Doxorubicin-Fullerenol Nanocomposite" in 3rd Workshop Specific Methods for Food Safety and Quality : Proceedings (2012):34-38,
https://hdl.handle.net/21.15107/rcub_vinar_12409 .