Vojislavljevic, Dubravka Z.

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  • Vojislavljevic, Dubravka Z. (2)
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Author's Bibliography

Parallel stacking interactions in square-planar transition-metal complexes containing fused chelate and C-6-aromatic rings

Sredojević, Dušan; Vojislavljevic, Dubravka Z.; Tomić, Zoran D.; Zarić, Snežana D.

(2012)

TY  - JOUR
AU  - Sredojević, Dušan
AU  - Vojislavljevic, Dubravka Z.
AU  - Tomić, Zoran D.
AU  - Zarić, Snežana D.
PY  - 2012
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/4856
AB  - Stacking interactions in the crystal structures of square-planar transition metal complexes from the Cambridge Structural Database with five-and six-membered chelate rings fused with C6-arom rings (arom = aromatic) were analyzed. The distribution of distances between the closest C6-arom-C6-arom and C6-arom-chelate contacts shows that in a large fraction of the intermolecular interactions the C6-arom ring of one molecule is closer to the chelate than to the C6-arom ring of the other molecule. These results indicate a possible preference of the C6-arom ring to form stacking contacts with the chelate rings. The preference is ubiquitous and does not depend on the metal type.
T2  - Acta Crystallographica. Section B: Structural Science
T1  - Parallel stacking interactions in square-planar transition-metal complexes containing fused chelate and C-6-aromatic rings
VL  - 68
SP  - 261
EP  - 265
DO  - 10.1107/S0108768112012281
ER  - 
@article{
author = "Sredojević, Dušan and Vojislavljevic, Dubravka Z. and Tomić, Zoran D. and Zarić, Snežana D.",
year = "2012",
abstract = "Stacking interactions in the crystal structures of square-planar transition metal complexes from the Cambridge Structural Database with five-and six-membered chelate rings fused with C6-arom rings (arom = aromatic) were analyzed. The distribution of distances between the closest C6-arom-C6-arom and C6-arom-chelate contacts shows that in a large fraction of the intermolecular interactions the C6-arom ring of one molecule is closer to the chelate than to the C6-arom ring of the other molecule. These results indicate a possible preference of the C6-arom ring to form stacking contacts with the chelate rings. The preference is ubiquitous and does not depend on the metal type.",
journal = "Acta Crystallographica. Section B: Structural Science",
title = "Parallel stacking interactions in square-planar transition-metal complexes containing fused chelate and C-6-aromatic rings",
volume = "68",
pages = "261-265",
doi = "10.1107/S0108768112012281"
}
Sredojević, D., Vojislavljevic, D. Z., Tomić, Z. D.,& Zarić, S. D.. (2012). Parallel stacking interactions in square-planar transition-metal complexes containing fused chelate and C-6-aromatic rings. in Acta Crystallographica. Section B: Structural Science, 68, 261-265.
https://doi.org/10.1107/S0108768112012281
Sredojević D, Vojislavljevic DZ, Tomić ZD, Zarić SD. Parallel stacking interactions in square-planar transition-metal complexes containing fused chelate and C-6-aromatic rings. in Acta Crystallographica. Section B: Structural Science. 2012;68:261-265.
doi:10.1107/S0108768112012281 .
Sredojević, Dušan, Vojislavljevic, Dubravka Z., Tomić, Zoran D., Zarić, Snežana D., "Parallel stacking interactions in square-planar transition-metal complexes containing fused chelate and C-6-aromatic rings" in Acta Crystallographica. Section B: Structural Science, 68 (2012):261-265,
https://doi.org/10.1107/S0108768112012281 . .
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Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent

Dakovic, Aleksandra; Kragović, Milan M.; Rottinghaus, George E.; Ledoux, David R.; Butkeraitis, Paula; Vojislavljevic, Dubravka Z.; Zarić, Snežana D.; Stamenić, Ljubisav

(2012)

TY  - JOUR
AU  - Dakovic, Aleksandra
AU  - Kragović, Milan M.
AU  - Rottinghaus, George E.
AU  - Ledoux, David R.
AU  - Butkeraitis, Paula
AU  - Vojislavljevic, Dubravka Z.
AU  - Zarić, Snežana D.
AU  - Stamenić, Ljubisav
PY  - 2012
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/4363
AB  - A zinc-exchanged montmorillonite (Zn-MONT) was prepared from a natural montmorillonite (MONT) and the adsorption of aflatoxin B-1 (AFB(1)) was investigated at pH 3 and 7. Characterization of Zn-MONT was done by determination of chemical composition, the point of the zero charge (pH(pzc)), thermal (DTA/TGA/DTG) and X-ray powder diffraction (XRPD) analysis. Adsorption of AFB(1) (C-0 = 4 ppm) by Zn-MONT, at different solid/liquid ratios (10, 1 and 0.5 g L-1), at pH 3 or 7, showed that its adsorption was high (over 96%) and independent of pH, similar to MONT. No desorption of AFB(1) from MONT-AFB(1) and Zn-MONT-AFB(1) complexes occurred at pH 6.5, suggesting strong binding of AFB(1) by both adsorbents. Furthermore, AFB(1) adsorption by Zn-MONT followed a nonlinear (Langmuir) type of isotherm at pH 3 with a calculated maximum capacity of 60.17 mg g(-1). The stability of MONT-AFB(1) and Zn-MONT-AFB(1) complexes was evaluated by calculating the binding energies between AFB(1) and metal cations using quantum chemical methods. The evaluated interaction energies of AFB(1) with hydrated Zn2+, Mg2+, and Ca2+ cations showed that the strongest interaction was the interaction of the Zn2+ system, -70.2 kcal mol(-1), whereas energies for Mg-2 and Ca2+ systems were -68.8 and -62.9 kcal mol(-1), respectively. The results indicate that Zn-MONT can be suitable for potential practical application as both, an antibacterial and an aflatoxin binding agent. (C) 2012 Elsevier B.V. All rights reserved.
T2  - Materials Chemistry and Physics
T1  - Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent
VL  - 137
IS  - 1
SP  - 213
EP  - 220
DO  - 10.1016/j.matchemphys.2012.09.010
ER  - 
@article{
author = "Dakovic, Aleksandra and Kragović, Milan M. and Rottinghaus, George E. and Ledoux, David R. and Butkeraitis, Paula and Vojislavljevic, Dubravka Z. and Zarić, Snežana D. and Stamenić, Ljubisav",
year = "2012",
abstract = "A zinc-exchanged montmorillonite (Zn-MONT) was prepared from a natural montmorillonite (MONT) and the adsorption of aflatoxin B-1 (AFB(1)) was investigated at pH 3 and 7. Characterization of Zn-MONT was done by determination of chemical composition, the point of the zero charge (pH(pzc)), thermal (DTA/TGA/DTG) and X-ray powder diffraction (XRPD) analysis. Adsorption of AFB(1) (C-0 = 4 ppm) by Zn-MONT, at different solid/liquid ratios (10, 1 and 0.5 g L-1), at pH 3 or 7, showed that its adsorption was high (over 96%) and independent of pH, similar to MONT. No desorption of AFB(1) from MONT-AFB(1) and Zn-MONT-AFB(1) complexes occurred at pH 6.5, suggesting strong binding of AFB(1) by both adsorbents. Furthermore, AFB(1) adsorption by Zn-MONT followed a nonlinear (Langmuir) type of isotherm at pH 3 with a calculated maximum capacity of 60.17 mg g(-1). The stability of MONT-AFB(1) and Zn-MONT-AFB(1) complexes was evaluated by calculating the binding energies between AFB(1) and metal cations using quantum chemical methods. The evaluated interaction energies of AFB(1) with hydrated Zn2+, Mg2+, and Ca2+ cations showed that the strongest interaction was the interaction of the Zn2+ system, -70.2 kcal mol(-1), whereas energies for Mg-2 and Ca2+ systems were -68.8 and -62.9 kcal mol(-1), respectively. The results indicate that Zn-MONT can be suitable for potential practical application as both, an antibacterial and an aflatoxin binding agent. (C) 2012 Elsevier B.V. All rights reserved.",
journal = "Materials Chemistry and Physics",
title = "Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent",
volume = "137",
number = "1",
pages = "213-220",
doi = "10.1016/j.matchemphys.2012.09.010"
}
Dakovic, A., Kragović, M. M., Rottinghaus, G. E., Ledoux, D. R., Butkeraitis, P., Vojislavljevic, D. Z., Zarić, S. D.,& Stamenić, L.. (2012). Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent. in Materials Chemistry and Physics, 137(1), 213-220.
https://doi.org/10.1016/j.matchemphys.2012.09.010
Dakovic A, Kragović MM, Rottinghaus GE, Ledoux DR, Butkeraitis P, Vojislavljevic DZ, Zarić SD, Stamenić L. Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent. in Materials Chemistry and Physics. 2012;137(1):213-220.
doi:10.1016/j.matchemphys.2012.09.010 .
Dakovic, Aleksandra, Kragović, Milan M., Rottinghaus, George E., Ledoux, David R., Butkeraitis, Paula, Vojislavljevic, Dubravka Z., Zarić, Snežana D., Stamenić, Ljubisav, "Preparation and characterization of zinc-exchanged montmorillonite and its effectiveness as aflatoxin B-1 adsorbent" in Materials Chemistry and Physics, 137, no. 1 (2012):213-220,
https://doi.org/10.1016/j.matchemphys.2012.09.010 . .
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