Trtić-Petrović, Tatjana M.

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Authority KeyName Variants
orcid::0000-0002-0817-8343
  • Trtić-Petrović, Tatjana M. (56)
  • Trtić, Tatjana M. (8)
  • Trtić-Petrović, Tatjana (6)
Projects
Physics and Chemistry with Ion Beams Sustainable and green chemistry approach for environmental friendly analytical methods and energy storage
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200161 (University of Belgrade, Faculty of Pharmacy)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200125 (University of Novi Sad, Faculty of Science) Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes
Lithium-ion batteries and fuel cells - research and development COST Action [CM1206]
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200146 (University of Belgrade, Faculty of Physical Chemistry) Portuguese Foundation for Science and Technology [IF/01634/2015]
Portuguese Foundation for Science and Technology/MCTES [UIDB/50011/2020] Portuguese Foundation for Science and Technology/MCTES [UIDP/50011/2020]
ERDF through COMPETE - Programa Operacional Competitividade e Internacionalizacao (POCI) - POCI-01-0145-FEDER-006984 ERDF through COMPETE - Programa Operacional Competitividade e Internacionalizacao (POCI) [POCI-01-0145-FEDER-006984]
European Chemical Society (DAC-EuChemS) FCT - Fundacao para a Ciencia e a Tecnologia
FCT - Fundacao para a Ciencia e a Tecnologia [SFRH/BD/95411/2013] FCT - SFRH/BD/95411/2013
Fundacao para a Ciencia e a Tecnologia [Contract no. IST-ID/156e2018] Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions
Functional analysis, stochastic analysis and applications Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200222 (Institute for Food Technology, Novi Sad)
Simultaneous Bioremediation and Soilification of Degraded Areas to Preserve Natural Resources of Biologically Active Substances, and Development and Production of Biomaterials and Dietetic Products Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine
HiSuperBat - High-Capacity Electrodes for Aqueous Rechargeable Multivalent-Ion Batteries and Supercapacitors: Next Step Towards a Hybrid Model PROTOPOWER - PROTein from Rapeseed Oil Processing Waste: Application in FOod and WastewatEr TReatment
Joint Serbia-JINR project "Analysis of Technology Critical Elements as new pollutants in environment by INAA method" Ministry of Education, Science and Technological Development of the Republic of Serbia
Ministry of Education, Sports, and Youth of the Czech Republic - COST LD14090 Ministry of Education, Sports, and Youth of the Czech Republic [COST LD14090]

Author's Bibliography

Application of biodegradable cholinium ionic liquids for the extraction of 5-hydroxymethylfurfural (HMF) from honey

Marić, Aleksandar; Jovanov, Pavle; Gadžurić, Slobodan; Trtić-Petrović, Tatjana; Sakač, Marijana; Tot, Aleksandar; Bertić, Marko; Vraneš, Milan

(2023)

TY  - JOUR
AU  - Marić, Aleksandar
AU  - Jovanov, Pavle
AU  - Gadžurić, Slobodan
AU  - Trtić-Petrović, Tatjana
AU  - Sakač, Marijana
AU  - Tot, Aleksandar
AU  - Bertić, Marko
AU  - Vraneš, Milan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12042
AB  - 5-Hydroxymethylfurfural (HMF), a Maillard reaction product, can be formed when honey is subjected to heat treatment or a long storage time, becoming volatile and toxic depending on its concentration. The fact that, until today, there is no literature data on the extraction of 5-hydroxymethylfurfural (HMF) from honey using ionic liquids directed the investigation of the influence of biodegradable cholinium ionic liquids on the formation of aqueous biphasic systems and the application of these systems for the extraction of HMF from honey. The influence of anions of synthesised ionic liquids on the construction of biphasic systems in which an inorganic salt was used as a salting agent was investigated. Then, the extraction of HMF in these systems was examined, and the mechanisms of HMF extraction using ionic liquids were explained using computer simulations. Examining the effect of cholinium ionic liquids (choline chloride ([Ch][Cl]), cholinium nicotinate ([Ch][Nic]), cholinium propionate ([Ch][Prop]), and cholinium butyrate ([Ch][But])) on the formation of aqueous biphasic systems by comparing the phase diagrams, it was concluded that the ability of ionic liquids to form an aqueous biphasic system with tripotassium phosphate (K3PO4) decreases in the following order: [Ch][But] z [Ch][Prop] > [Ch][Nic] > [Ch][Cl]. By applying all tested aqueous biphasic systems for the extraction of HMF from honey, an extraction efficiency of more than 89% was achieved. Complete extraction was achieved using the extraction system with [Ch][But], while the weakest ability to extract HMF was exhibited by the system with [Ch][Cl]. The mechanisms of HMF extraction using ionic liquids are explained on the basis of the optimised structures of the ionic liquid systems with HMF, together with the visualisation of noncovalent interactions, and on the basis of the calculated binding energies DGbin, which can be used as a good predictor of the extraction potential of newly synthesised ionic liquids
T2  - RSC Advances
T1  - Application of biodegradable cholinium ionic liquids for the extraction of 5-hydroxymethylfurfural (HMF) from honey
VL  - 13
IS  - 46
SP  - 32714
EP  - 32721
DO  - 10.1039/D3RA06077B
ER  - 
@article{
author = "Marić, Aleksandar and Jovanov, Pavle and Gadžurić, Slobodan and Trtić-Petrović, Tatjana and Sakač, Marijana and Tot, Aleksandar and Bertić, Marko and Vraneš, Milan",
year = "2023",
abstract = "5-Hydroxymethylfurfural (HMF), a Maillard reaction product, can be formed when honey is subjected to heat treatment or a long storage time, becoming volatile and toxic depending on its concentration. The fact that, until today, there is no literature data on the extraction of 5-hydroxymethylfurfural (HMF) from honey using ionic liquids directed the investigation of the influence of biodegradable cholinium ionic liquids on the formation of aqueous biphasic systems and the application of these systems for the extraction of HMF from honey. The influence of anions of synthesised ionic liquids on the construction of biphasic systems in which an inorganic salt was used as a salting agent was investigated. Then, the extraction of HMF in these systems was examined, and the mechanisms of HMF extraction using ionic liquids were explained using computer simulations. Examining the effect of cholinium ionic liquids (choline chloride ([Ch][Cl]), cholinium nicotinate ([Ch][Nic]), cholinium propionate ([Ch][Prop]), and cholinium butyrate ([Ch][But])) on the formation of aqueous biphasic systems by comparing the phase diagrams, it was concluded that the ability of ionic liquids to form an aqueous biphasic system with tripotassium phosphate (K3PO4) decreases in the following order: [Ch][But] z [Ch][Prop] > [Ch][Nic] > [Ch][Cl]. By applying all tested aqueous biphasic systems for the extraction of HMF from honey, an extraction efficiency of more than 89% was achieved. Complete extraction was achieved using the extraction system with [Ch][But], while the weakest ability to extract HMF was exhibited by the system with [Ch][Cl]. The mechanisms of HMF extraction using ionic liquids are explained on the basis of the optimised structures of the ionic liquid systems with HMF, together with the visualisation of noncovalent interactions, and on the basis of the calculated binding energies DGbin, which can be used as a good predictor of the extraction potential of newly synthesised ionic liquids",
journal = "RSC Advances",
title = "Application of biodegradable cholinium ionic liquids for the extraction of 5-hydroxymethylfurfural (HMF) from honey",
volume = "13",
number = "46",
pages = "32714-32721",
doi = "10.1039/D3RA06077B"
}
Marić, A., Jovanov, P., Gadžurić, S., Trtić-Petrović, T., Sakač, M., Tot, A., Bertić, M.,& Vraneš, M.. (2023). Application of biodegradable cholinium ionic liquids for the extraction of 5-hydroxymethylfurfural (HMF) from honey. in RSC Advances, 13(46), 32714-32721.
https://doi.org/10.1039/D3RA06077B
Marić A, Jovanov P, Gadžurić S, Trtić-Petrović T, Sakač M, Tot A, Bertić M, Vraneš M. Application of biodegradable cholinium ionic liquids for the extraction of 5-hydroxymethylfurfural (HMF) from honey. in RSC Advances. 2023;13(46):32714-32721.
doi:10.1039/D3RA06077B .
Marić, Aleksandar, Jovanov, Pavle, Gadžurić, Slobodan, Trtić-Petrović, Tatjana, Sakač, Marijana, Tot, Aleksandar, Bertić, Marko, Vraneš, Milan, "Application of biodegradable cholinium ionic liquids for the extraction of 5-hydroxymethylfurfural (HMF) from honey" in RSC Advances, 13, no. 46 (2023):32714-32721,
https://doi.org/10.1039/D3RA06077B . .
1

Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review

Ražić, Slavica; Arsenijević, Jelena; Đogo Mračević, Svetlana; Mušović, Jasmina; Trtić-Petrović, Tatjana

(2023)

TY  - JOUR
AU  - Ražić, Slavica
AU  - Arsenijević, Jelena
AU  - Đogo Mračević, Svetlana
AU  - Mušović, Jasmina
AU  - Trtić-Petrović, Tatjana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11222
AB  - More environment-friendly solvents in analytical chemistry are almost inevitable in both sample preparation and analysis to meet the high standards of sustainable chemistry and human welfare. In this review paper, a critical look at the advantages and still unsolved problems of most potential classes of green solvents is presented to give an overview of the current state-of-the-art in this field. Replacing volatile organic compounds (VOCs) by ecofriendly and benign solvents in extractions/separations in sample preparation, as the most tedious and demanding step in analysis, is one of roads toward sustainable chemistry. Water under sub- and supercritical conditions, carbon-dioxide, ionic liquids (ILs), deep eutectic solvents (DESs), and those of natural origin (NADES) belong to the most promising classes of solvents in green analytical chemistry. Basic theory and mechanisms of their use illustrated by representative but not exhaustive list of examples related to complex matrices (environmental and natural food products) from analytical practice are presented in this review. Perspectives of QuEChERS, in line with GAC principles, are highlighted, in line with current trends of “going green” for quick, easy, cheap, effective, rugged, and safe analytical methods. Compliance with green chemistry (GC), especially green analytical chemistry (GAC) principles, is not a fashionable issue but, more the trend toward a sustainable future with greener chemistry; thus, green metrics are an unavoidable tool to measure how green the applied method or procedure is. Herein, the most common tools will be presented and discussed, such as national environmental method index (NEMI), analytical ecoscale, green analytical procedure index (GAPI), analytical greenness calculator (AGREE), complementary green analytical procedure index (ComplexGAPI), and analytical greenness metric for sample preparation (AGREEprep). The future trends for research and development in this still expanding field are presented in a critical view of advantages and disadvantages as well as improvement of the validation of analytical procedures. The creation of new certified reference materials (CRMs) and validated methods for specified analytes in complex matrices is a demanding task in the coming years. Tailor-made solvents with physicochemical properties for intended use are required for the selective extraction and separation and open numerous possibilities and huge potential for future research and industrial applications.
T2  - Analyst
T1  - Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review
VL  - 148
IS  - 14
SP  - 3130
EP  - 3152
DO  - 10.1039/D3AN00498H
ER  - 
@article{
author = "Ražić, Slavica and Arsenijević, Jelena and Đogo Mračević, Svetlana and Mušović, Jasmina and Trtić-Petrović, Tatjana",
year = "2023",
abstract = "More environment-friendly solvents in analytical chemistry are almost inevitable in both sample preparation and analysis to meet the high standards of sustainable chemistry and human welfare. In this review paper, a critical look at the advantages and still unsolved problems of most potential classes of green solvents is presented to give an overview of the current state-of-the-art in this field. Replacing volatile organic compounds (VOCs) by ecofriendly and benign solvents in extractions/separations in sample preparation, as the most tedious and demanding step in analysis, is one of roads toward sustainable chemistry. Water under sub- and supercritical conditions, carbon-dioxide, ionic liquids (ILs), deep eutectic solvents (DESs), and those of natural origin (NADES) belong to the most promising classes of solvents in green analytical chemistry. Basic theory and mechanisms of their use illustrated by representative but not exhaustive list of examples related to complex matrices (environmental and natural food products) from analytical practice are presented in this review. Perspectives of QuEChERS, in line with GAC principles, are highlighted, in line with current trends of “going green” for quick, easy, cheap, effective, rugged, and safe analytical methods. Compliance with green chemistry (GC), especially green analytical chemistry (GAC) principles, is not a fashionable issue but, more the trend toward a sustainable future with greener chemistry; thus, green metrics are an unavoidable tool to measure how green the applied method or procedure is. Herein, the most common tools will be presented and discussed, such as national environmental method index (NEMI), analytical ecoscale, green analytical procedure index (GAPI), analytical greenness calculator (AGREE), complementary green analytical procedure index (ComplexGAPI), and analytical greenness metric for sample preparation (AGREEprep). The future trends for research and development in this still expanding field are presented in a critical view of advantages and disadvantages as well as improvement of the validation of analytical procedures. The creation of new certified reference materials (CRMs) and validated methods for specified analytes in complex matrices is a demanding task in the coming years. Tailor-made solvents with physicochemical properties for intended use are required for the selective extraction and separation and open numerous possibilities and huge potential for future research and industrial applications.",
journal = "Analyst",
title = "Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review",
volume = "148",
number = "14",
pages = "3130-3152",
doi = "10.1039/D3AN00498H"
}
Ražić, S., Arsenijević, J., Đogo Mračević, S., Mušović, J.,& Trtić-Petrović, T.. (2023). Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review. in Analyst, 148(14), 3130-3152.
https://doi.org/10.1039/D3AN00498H
Ražić S, Arsenijević J, Đogo Mračević S, Mušović J, Trtić-Petrović T. Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review. in Analyst. 2023;148(14):3130-3152.
doi:10.1039/D3AN00498H .
Ražić, Slavica, Arsenijević, Jelena, Đogo Mračević, Svetlana, Mušović, Jasmina, Trtić-Petrović, Tatjana, "Greener chemistry in analytical sciences: from green solvents to applications in complex matrices. Current challenges and future perspectives: a critical review" in Analyst, 148, no. 14 (2023):3130-3152,
https://doi.org/10.1039/D3AN00498H . .
3
9
1

The possibility of using polymer-based phase change materials for thermal energy storage

Mrđa, Dragoslav; Vučićević, Biljana; Mušović, Jasmina; Marinović-Cincović, Milena; Trtić-Petrović, Tatjana; Mladenović, Milica; Turanjanin, Valentina

(Banja Luka, Republic of Srpska, Bosnia and Herzegovina : University PIM, 2023)

TY  - CONF
AU  - Mrđa, Dragoslav
AU  - Vučićević, Biljana
AU  - Mušović, Jasmina
AU  - Marinović-Cincović, Milena
AU  - Trtić-Petrović, Tatjana
AU  - Mladenović, Milica
AU  - Turanjanin, Valentina
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12652
AB  - Phase change materials (PCM) are attractive energy storage technologies due to their high energy storage density and the ability to reversible absorb and release thermal energy at a nearly constant temperature. Polymers and polymer-based eutectic mixtures are promising PCMs. This study aims to investigate heat properties (melting temperature (Tm), latent heat (ΔH) and thermal conductivity(λ)) of potential PCMs based on polyethylene glycol polymer (PEG2000). We prepared following two and three components materials: PEG2000: ethylene glycol (5:6): PEG2000: PPG 400 (1:5); PEG2000: PPG400: Choline chloride (2:2:15); PEG2000: ethylene glycol (5:6); PEG2000: Glyoxal (5:2). The prepared three components material belong to deep eutectic solvents. Tm of the prepared materials are lower compared to pure PEG2000 (Tm = 57 ºC) e.g. Tm of PEG2000: PPG400: Choline chloride is 43 ºC. The determined melting enthalpies are also lower for prepared materials compared to PEG2000. This decrease is lower for eutectic mixture such as PEG2000: Choline chloride: ethylene glycol. We can conclude based on the obtained result that eutectic mixtures based on polymers are promising PCMs.
PB  - Banja Luka, Republic of Srpska, Bosnia and Herzegovina : University PIM
C3  - XII International conference on social and technological development : Proceedings
T1  - The possibility of using polymer-based phase change materials for thermal energy storage
SP  - 465
EP  - 470
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12652
ER  - 
@conference{
author = "Mrđa, Dragoslav and Vučićević, Biljana and Mušović, Jasmina and Marinović-Cincović, Milena and Trtić-Petrović, Tatjana and Mladenović, Milica and Turanjanin, Valentina",
year = "2023",
abstract = "Phase change materials (PCM) are attractive energy storage technologies due to their high energy storage density and the ability to reversible absorb and release thermal energy at a nearly constant temperature. Polymers and polymer-based eutectic mixtures are promising PCMs. This study aims to investigate heat properties (melting temperature (Tm), latent heat (ΔH) and thermal conductivity(λ)) of potential PCMs based on polyethylene glycol polymer (PEG2000). We prepared following two and three components materials: PEG2000: ethylene glycol (5:6): PEG2000: PPG 400 (1:5); PEG2000: PPG400: Choline chloride (2:2:15); PEG2000: ethylene glycol (5:6); PEG2000: Glyoxal (5:2). The prepared three components material belong to deep eutectic solvents. Tm of the prepared materials are lower compared to pure PEG2000 (Tm = 57 ºC) e.g. Tm of PEG2000: PPG400: Choline chloride is 43 ºC. The determined melting enthalpies are also lower for prepared materials compared to PEG2000. This decrease is lower for eutectic mixture such as PEG2000: Choline chloride: ethylene glycol. We can conclude based on the obtained result that eutectic mixtures based on polymers are promising PCMs.",
publisher = "Banja Luka, Republic of Srpska, Bosnia and Herzegovina : University PIM",
journal = "XII International conference on social and technological development : Proceedings",
title = "The possibility of using polymer-based phase change materials for thermal energy storage",
pages = "465-470",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12652"
}
Mrđa, D., Vučićević, B., Mušović, J., Marinović-Cincović, M., Trtić-Petrović, T., Mladenović, M.,& Turanjanin, V.. (2023). The possibility of using polymer-based phase change materials for thermal energy storage. in XII International conference on social and technological development : Proceedings
Banja Luka, Republic of Srpska, Bosnia and Herzegovina : University PIM., 465-470.
https://hdl.handle.net/21.15107/rcub_vinar_12652
Mrđa D, Vučićević B, Mušović J, Marinović-Cincović M, Trtić-Petrović T, Mladenović M, Turanjanin V. The possibility of using polymer-based phase change materials for thermal energy storage. in XII International conference on social and technological development : Proceedings. 2023;:465-470.
https://hdl.handle.net/21.15107/rcub_vinar_12652 .
Mrđa, Dragoslav, Vučićević, Biljana, Mušović, Jasmina, Marinović-Cincović, Milena, Trtić-Petrović, Tatjana, Mladenović, Milica, Turanjanin, Valentina, "The possibility of using polymer-based phase change materials for thermal energy storage" in XII International conference on social and technological development : Proceedings (2023):465-470,
https://hdl.handle.net/21.15107/rcub_vinar_12652 .

Ionic liquids in green analytical chemistry—are they that good and green enough?

Ražić, Slavica; Gadžurić, Slobodan; Trtić-Petrović, Tatjana

(2023)

TY  - JOUR
AU  - Ražić, Slavica
AU  - Gadžurić, Slobodan
AU  - Trtić-Petrović, Tatjana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12045
AB  - The widespread use of ionic liquids (ILs) as greener solvents in analytical sciences, especially in sample pretreatment, has focused attention on exploiting their enormous potential, not only on eliminating and improving the drawbacks faced by scientists. These ionic compounds with unique physicochemical properties can be tuned through smart synthesis, combining cations and anions, so that the compound exhibits excellent properties for its intended purpose. Ionic liquids are rightly referred to as designer solvents. Validation of a newly proposed analytical methods using ionic liquids, either in sample preparation or in further analysis, is a critical process to demonstrate that a particular analytical method is fit for purpose and provides reliable and accurate results. In addition, this article specially addressed the potential toxicity of ionic liquids with the modest goal of assisting researchers in this field by expanding their target areas.
T2  - Analytical and Bioanalytical Chemistry
T1  - Ionic liquids in green analytical chemistry—are they that good and green enough?
DO  - 10.1007/s00216-023-05045-3
ER  - 
@article{
author = "Ražić, Slavica and Gadžurić, Slobodan and Trtić-Petrović, Tatjana",
year = "2023",
abstract = "The widespread use of ionic liquids (ILs) as greener solvents in analytical sciences, especially in sample pretreatment, has focused attention on exploiting their enormous potential, not only on eliminating and improving the drawbacks faced by scientists. These ionic compounds with unique physicochemical properties can be tuned through smart synthesis, combining cations and anions, so that the compound exhibits excellent properties for its intended purpose. Ionic liquids are rightly referred to as designer solvents. Validation of a newly proposed analytical methods using ionic liquids, either in sample preparation or in further analysis, is a critical process to demonstrate that a particular analytical method is fit for purpose and provides reliable and accurate results. In addition, this article specially addressed the potential toxicity of ionic liquids with the modest goal of assisting researchers in this field by expanding their target areas.",
journal = "Analytical and Bioanalytical Chemistry",
title = "Ionic liquids in green analytical chemistry—are they that good and green enough?",
doi = "10.1007/s00216-023-05045-3"
}
Ražić, S., Gadžurić, S.,& Trtić-Petrović, T.. (2023). Ionic liquids in green analytical chemistry—are they that good and green enough?. in Analytical and Bioanalytical Chemistry.
https://doi.org/10.1007/s00216-023-05045-3
Ražić S, Gadžurić S, Trtić-Petrović T. Ionic liquids in green analytical chemistry—are they that good and green enough?. in Analytical and Bioanalytical Chemistry. 2023;.
doi:10.1007/s00216-023-05045-3 .
Ražić, Slavica, Gadžurić, Slobodan, Trtić-Petrović, Tatjana, "Ionic liquids in green analytical chemistry—are they that good and green enough?" in Analytical and Bioanalytical Chemistry (2023),
https://doi.org/10.1007/s00216-023-05045-3 . .
3

Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems

Lazarević, Dajana; Mušović, Jasmina; Trtić-Petrović, Tatjana M.; Gadžurić, Slobodan

(2023)

TY  - JOUR
AU  - Lazarević, Dajana
AU  - Mušović, Jasmina
AU  - Trtić-Petrović, Tatjana M.
AU  - Gadžurić, Slobodan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10772
AB  - In this work, aqueous biphasic systems (ABSs) formed by copolymers, ionic liquids (ILs) and natural deep eutectic solvents (NADES) have been demonstrated to be effective separation platforms for the extraction of hydrophobic pharmaceutical ingredients such as parthenolide (PAR). This work addresses the determination of the liquid–liquid equilibrium of ABS composed of choline lactate IL or choline chloride – lactic acid NADES and two different block copolymers Pluronic (PL17R4 and PL10R5), and their influence on the ABS formation and extraction efficiency of PAR. The ability of Pluronics to form ABS is compared to widely used polypropylene glycol polymer (PPG400). Comparing the effect of the ionic liquid and NADES on the ABS formation, it is shown that both salting-our reagents successfully form ABS and do not affect the extraction efficiency of PAR. The main influence on the high parthenolide extraction efficiency (>96%) is governed by the hydrophobic interactions between Pluronic and investigated compound, regardless on the applied salting-out reagent. Due to a high extraction efficiency achieved in PL-rich phase and promissing medical features of PAR, obtained results showed that this phase could be used as biocompatible drug delivery system. Avoiding commercially available organic solvents, elevated temperatures and pressure, the proposed method is greener alternative for PAR extraction.
T2  - Separation and Purification Technology
T1  - Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems
VL  - 314
SP  - 123653
DO  - 10.1016/j.seppur.2023.123653
ER  - 
@article{
author = "Lazarević, Dajana and Mušović, Jasmina and Trtić-Petrović, Tatjana M. and Gadžurić, Slobodan",
year = "2023",
abstract = "In this work, aqueous biphasic systems (ABSs) formed by copolymers, ionic liquids (ILs) and natural deep eutectic solvents (NADES) have been demonstrated to be effective separation platforms for the extraction of hydrophobic pharmaceutical ingredients such as parthenolide (PAR). This work addresses the determination of the liquid–liquid equilibrium of ABS composed of choline lactate IL or choline chloride – lactic acid NADES and two different block copolymers Pluronic (PL17R4 and PL10R5), and their influence on the ABS formation and extraction efficiency of PAR. The ability of Pluronics to form ABS is compared to widely used polypropylene glycol polymer (PPG400). Comparing the effect of the ionic liquid and NADES on the ABS formation, it is shown that both salting-our reagents successfully form ABS and do not affect the extraction efficiency of PAR. The main influence on the high parthenolide extraction efficiency (>96%) is governed by the hydrophobic interactions between Pluronic and investigated compound, regardless on the applied salting-out reagent. Due to a high extraction efficiency achieved in PL-rich phase and promissing medical features of PAR, obtained results showed that this phase could be used as biocompatible drug delivery system. Avoiding commercially available organic solvents, elevated temperatures and pressure, the proposed method is greener alternative for PAR extraction.",
journal = "Separation and Purification Technology",
title = "Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems",
volume = "314",
pages = "123653",
doi = "10.1016/j.seppur.2023.123653"
}
Lazarević, D., Mušović, J., Trtić-Petrović, T. M.,& Gadžurić, S.. (2023). Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems. in Separation and Purification Technology, 314, 123653.
https://doi.org/10.1016/j.seppur.2023.123653
Lazarević D, Mušović J, Trtić-Petrović TM, Gadžurić S. Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems. in Separation and Purification Technology. 2023;314:123653.
doi:10.1016/j.seppur.2023.123653 .
Lazarević, Dajana, Mušović, Jasmina, Trtić-Petrović, Tatjana M., Gadžurić, Slobodan, "Partition of parthenolide in ternary {block copolymer + biocompatible ionic liquid or natural deep eutectic solvent + water} systems" in Separation and Purification Technology, 314 (2023):123653,
https://doi.org/10.1016/j.seppur.2023.123653 . .

Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids

Mušović, Jasmina; Vraneš, Milan; Papović, Snežana; Gadžurić, Slobodan; Ražić, Slavica; Trtić-Petrović, Tatjana M.

(2023)

TY  - JOUR
AU  - Mušović, Jasmina
AU  - Vraneš, Milan
AU  - Papović, Snežana
AU  - Gadžurić, Slobodan
AU  - Ražić, Slavica
AU  - Trtić-Petrović, Tatjana M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10596
AB  - Although sample preparation, as an unavoidable step of the analytical process should be simple, it is very often identified as a bottleneck. Simplicity of sample preparation based on cost-effective and non-hazardous materials is mandatory for any sustainable and environmental friendly approach. Aqueous biphasic systems (ABS), based on functionalized ionic liquids (FILs) are acceptable alternatives to classical extraction procedures, due to the replacement of organic solvent with diluted aqueous-soluble ionic liquids. In this work, two water soluble FILs based on 2-mercaptobenzothiazolate anion, [mbt]: 1-butyl-3-methylimidazolium [mbt] ([bmim][mbt]) and 1-ethyl-3-methylimidazolium [mbt] ([emim][mbt]), were designed and synthesized in order to selectively extract Cd(II) and Pb(II) from the river sediment. It was found that [mbt]– anion acts as the ligand and forms complexes with Cd(II) and Pb(II) which are responsible for their efficient extraction, while cation is more responsible for the formation of ABS. Partition coefficients of 408 and 180 for Cd(II) and Pb(II), respectively, were obtained using ABS based on [bmim][mbt]. Direct extraction of Cd(II) and Pb(II) from the river sediment has been investigated and obtained optimal conditions are: 60 min direct contact of the aqueous solution of [bmim][mbt] and the sediment sample at 90 °C, followed by formation of ABS upon addition of potassium citrate. Using AGRE and AGREEprep tools greenness of the proposed method for direct extraction of Cd(II) and Pb(II) from the sediment are calculated. Obtained values of 0.69 and 0.71 for Cd(II) and Pb(II) extraction, respectively, showed a high level of the greenness of the proposed method.
T2  - Journal of Molecular Liquids
T1  - Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids
VL  - 369
SP  - 120974
DO  - 10.1016/j.molliq.2022.120974
ER  - 
@article{
author = "Mušović, Jasmina and Vraneš, Milan and Papović, Snežana and Gadžurić, Slobodan and Ražić, Slavica and Trtić-Petrović, Tatjana M.",
year = "2023",
abstract = "Although sample preparation, as an unavoidable step of the analytical process should be simple, it is very often identified as a bottleneck. Simplicity of sample preparation based on cost-effective and non-hazardous materials is mandatory for any sustainable and environmental friendly approach. Aqueous biphasic systems (ABS), based on functionalized ionic liquids (FILs) are acceptable alternatives to classical extraction procedures, due to the replacement of organic solvent with diluted aqueous-soluble ionic liquids. In this work, two water soluble FILs based on 2-mercaptobenzothiazolate anion, [mbt]: 1-butyl-3-methylimidazolium [mbt] ([bmim][mbt]) and 1-ethyl-3-methylimidazolium [mbt] ([emim][mbt]), were designed and synthesized in order to selectively extract Cd(II) and Pb(II) from the river sediment. It was found that [mbt]– anion acts as the ligand and forms complexes with Cd(II) and Pb(II) which are responsible for their efficient extraction, while cation is more responsible for the formation of ABS. Partition coefficients of 408 and 180 for Cd(II) and Pb(II), respectively, were obtained using ABS based on [bmim][mbt]. Direct extraction of Cd(II) and Pb(II) from the river sediment has been investigated and obtained optimal conditions are: 60 min direct contact of the aqueous solution of [bmim][mbt] and the sediment sample at 90 °C, followed by formation of ABS upon addition of potassium citrate. Using AGRE and AGREEprep tools greenness of the proposed method for direct extraction of Cd(II) and Pb(II) from the sediment are calculated. Obtained values of 0.69 and 0.71 for Cd(II) and Pb(II) extraction, respectively, showed a high level of the greenness of the proposed method.",
journal = "Journal of Molecular Liquids",
title = "Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids",
volume = "369",
pages = "120974",
doi = "10.1016/j.molliq.2022.120974"
}
Mušović, J., Vraneš, M., Papović, S., Gadžurić, S., Ražić, S.,& Trtić-Petrović, T. M.. (2023). Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids. in Journal of Molecular Liquids, 369, 120974.
https://doi.org/10.1016/j.molliq.2022.120974
Mušović J, Vraneš M, Papović S, Gadžurić S, Ražić S, Trtić-Petrović TM. Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids. in Journal of Molecular Liquids. 2023;369:120974.
doi:10.1016/j.molliq.2022.120974 .
Mušović, Jasmina, Vraneš, Milan, Papović, Snežana, Gadžurić, Slobodan, Ražić, Slavica, Trtić-Petrović, Tatjana M., "Greener sample preparation method for direct determination of Cd(II) and Pb(II) in river sediment based on an aqueous biphasic system with functionalized ionic liquids" in Journal of Molecular Liquids, 369 (2023):120974,
https://doi.org/10.1016/j.molliq.2022.120974 . .
4
5
5

Boosting electrocatalysis of oxygen reduction and evolution reactions with cost-effective cobalt and nitrogen-doped carbons prepared by simple carbonization of ionic liquids

Zdolšek, Nikola; Vujković, Milica; Metin, Önder; Brković, Snežana; Jocić, Ana; Dimitrijević, Aleksandra; Trtić-Petrović, Tatjana M.; Šljukić, Biljana

(2022)

TY  - JOUR
AU  - Zdolšek, Nikola
AU  - Vujković, Milica
AU  - Metin, Önder
AU  - Brković, Snežana
AU  - Jocić, Ana
AU  - Dimitrijević, Aleksandra
AU  - Trtić-Petrović, Tatjana M.
AU  - Šljukić, Biljana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10229
AB  - Development of cost-effective, bi-functional carbon electrocatalysts via direct carbonization of ionic liquids (bis(cholinium) tetrachlorocobaltate(II) ([Ch]2[CoCl4]) and bis(1-butyl-3-methylimidazolium) tetrachlorocobaltate(II) ([Bmim]2[CoCl4])) is reported herein for the first time. Carbon electrocatalysts, dual-doped with cobalt and nitrogen, were tested for oxygen reduction (ORR) and oxygen evolution (OER) reactions. Both materials show high bi-functional catalytic activity and excellent stability due to synergistic effects arising from the presence of nitrogen and cobalt. Electrocatalyst prepared by carbonization of [Ch]2[CoCl4] show exceptional activity and selectivity toward ORR. Conversely, electrocatalyst prepared from [Bmim]2[CoCl4] showed a slightly better OER performance indicating that different catalytic sites are responsible for O2 reduction and H2O oxidation. Parent CoO particles with graphitic nitrogen boost activity for ORR, while elemental Co supported by nitrogen atoms is responsible for OER activity. Finally, energy consumption during electrolytic oxygen production was calculated revealing energy saving when using two materials as anode electrocatalysts.
T2  - International Journal of Hydrogen Energy
T1  - Boosting electrocatalysis of oxygen reduction and evolution reactions with cost-effective cobalt and nitrogen-doped carbons prepared by simple carbonization of ionic liquids
VL  - 47
IS  - 33
SP  - 14847
EP  - 14858
DO  - 10.1016/j.ijhydene.2022.02.225
ER  - 
@article{
author = "Zdolšek, Nikola and Vujković, Milica and Metin, Önder and Brković, Snežana and Jocić, Ana and Dimitrijević, Aleksandra and Trtić-Petrović, Tatjana M. and Šljukić, Biljana",
year = "2022",
abstract = "Development of cost-effective, bi-functional carbon electrocatalysts via direct carbonization of ionic liquids (bis(cholinium) tetrachlorocobaltate(II) ([Ch]2[CoCl4]) and bis(1-butyl-3-methylimidazolium) tetrachlorocobaltate(II) ([Bmim]2[CoCl4])) is reported herein for the first time. Carbon electrocatalysts, dual-doped with cobalt and nitrogen, were tested for oxygen reduction (ORR) and oxygen evolution (OER) reactions. Both materials show high bi-functional catalytic activity and excellent stability due to synergistic effects arising from the presence of nitrogen and cobalt. Electrocatalyst prepared by carbonization of [Ch]2[CoCl4] show exceptional activity and selectivity toward ORR. Conversely, electrocatalyst prepared from [Bmim]2[CoCl4] showed a slightly better OER performance indicating that different catalytic sites are responsible for O2 reduction and H2O oxidation. Parent CoO particles with graphitic nitrogen boost activity for ORR, while elemental Co supported by nitrogen atoms is responsible for OER activity. Finally, energy consumption during electrolytic oxygen production was calculated revealing energy saving when using two materials as anode electrocatalysts.",
journal = "International Journal of Hydrogen Energy",
title = "Boosting electrocatalysis of oxygen reduction and evolution reactions with cost-effective cobalt and nitrogen-doped carbons prepared by simple carbonization of ionic liquids",
volume = "47",
number = "33",
pages = "14847-14858",
doi = "10.1016/j.ijhydene.2022.02.225"
}
Zdolšek, N., Vujković, M., Metin, Ö., Brković, S., Jocić, A., Dimitrijević, A., Trtić-Petrović, T. M.,& Šljukić, B.. (2022). Boosting electrocatalysis of oxygen reduction and evolution reactions with cost-effective cobalt and nitrogen-doped carbons prepared by simple carbonization of ionic liquids. in International Journal of Hydrogen Energy, 47(33), 14847-14858.
https://doi.org/10.1016/j.ijhydene.2022.02.225
Zdolšek N, Vujković M, Metin Ö, Brković S, Jocić A, Dimitrijević A, Trtić-Petrović TM, Šljukić B. Boosting electrocatalysis of oxygen reduction and evolution reactions with cost-effective cobalt and nitrogen-doped carbons prepared by simple carbonization of ionic liquids. in International Journal of Hydrogen Energy. 2022;47(33):14847-14858.
doi:10.1016/j.ijhydene.2022.02.225 .
Zdolšek, Nikola, Vujković, Milica, Metin, Önder, Brković, Snežana, Jocić, Ana, Dimitrijević, Aleksandra, Trtić-Petrović, Tatjana M., Šljukić, Biljana, "Boosting electrocatalysis of oxygen reduction and evolution reactions with cost-effective cobalt and nitrogen-doped carbons prepared by simple carbonization of ionic liquids" in International Journal of Hydrogen Energy, 47, no. 33 (2022):14847-14858,
https://doi.org/10.1016/j.ijhydene.2022.02.225 . .
6
1
3

On the Geochemistry of the Danube River Sediments (Serbian Sector)

Culicov, Otilia Ana; Trtić-Petrović, Tatjana M.; Nekhoroshkov, Pavel S.; Zinicovscaia, Inga; Duliu, Octavian G.

(2022)

TY  - JOUR
AU  - Culicov, Otilia Ana
AU  - Trtić-Petrović, Tatjana M.
AU  - Nekhoroshkov, Pavel S.
AU  - Zinicovscaia, Inga
AU  - Duliu, Octavian G.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10463
AB  - To determine the nature and origin of the unconsolidated bottom sediments, as well as to demonstrate and quantify the presence of Presumably Contaminating Elements (PCE) in the Serbian Danube River, as a novelty, the mass fractions on nine major elements as oxides—SiO2, TiO2, Al2O3, FeO, MnO, MgO, CaO, Na2O, and K2O, as well as Sc, V, Cr, Co, Ni, Cu, Zn, As, Rb, Sr, Zr, Sb, Cs, Ba, La, Hf, Ta, W, Th, and U were determined by Instrumental Neutron Activation Analysis (INAA) in 13 sediment samples collected between Belgrade and Iron Gate 2 dam. INAA was chosen for its ability to perform elemental analysis without any preliminary sample treatment that could introduce systematic errors. The distribution of major elements was relatively uniform, with the sampling locations having less influence. Concerning the trace elements, excepting the PCE Cr, Ni, Cu, Zn, As, and Sb, their distributions presented the same remarkable similarity to the Upper Continental Crust (UCC), North American Shale Composite (NASC), Average Bottom Load (ABL), and Average Dobrogea Loess (AVL), and were in good concordance with the location of the Serbian Danube River in the Pannonian Plain. In the case of considered PCE, both Enrichment Factor and Pollution Load Index showed values higher than the pollution threshold, which pointed towards a significant anthropogenic contamination, and rising concern to what extent the water quality and biota could be affected.
T2  - International Journal of Environmental Research and Public Health
T1  - On the Geochemistry of the Danube River Sediments (Serbian Sector)
VL  - 19
IS  - 19
SP  - 12879
DO  - 10.3390/ijerph191912879
ER  - 
@article{
author = "Culicov, Otilia Ana and Trtić-Petrović, Tatjana M. and Nekhoroshkov, Pavel S. and Zinicovscaia, Inga and Duliu, Octavian G.",
year = "2022",
abstract = "To determine the nature and origin of the unconsolidated bottom sediments, as well as to demonstrate and quantify the presence of Presumably Contaminating Elements (PCE) in the Serbian Danube River, as a novelty, the mass fractions on nine major elements as oxides—SiO2, TiO2, Al2O3, FeO, MnO, MgO, CaO, Na2O, and K2O, as well as Sc, V, Cr, Co, Ni, Cu, Zn, As, Rb, Sr, Zr, Sb, Cs, Ba, La, Hf, Ta, W, Th, and U were determined by Instrumental Neutron Activation Analysis (INAA) in 13 sediment samples collected between Belgrade and Iron Gate 2 dam. INAA was chosen for its ability to perform elemental analysis without any preliminary sample treatment that could introduce systematic errors. The distribution of major elements was relatively uniform, with the sampling locations having less influence. Concerning the trace elements, excepting the PCE Cr, Ni, Cu, Zn, As, and Sb, their distributions presented the same remarkable similarity to the Upper Continental Crust (UCC), North American Shale Composite (NASC), Average Bottom Load (ABL), and Average Dobrogea Loess (AVL), and were in good concordance with the location of the Serbian Danube River in the Pannonian Plain. In the case of considered PCE, both Enrichment Factor and Pollution Load Index showed values higher than the pollution threshold, which pointed towards a significant anthropogenic contamination, and rising concern to what extent the water quality and biota could be affected.",
journal = "International Journal of Environmental Research and Public Health",
title = "On the Geochemistry of the Danube River Sediments (Serbian Sector)",
volume = "19",
number = "19",
pages = "12879",
doi = "10.3390/ijerph191912879"
}
Culicov, O. A., Trtić-Petrović, T. M., Nekhoroshkov, P. S., Zinicovscaia, I.,& Duliu, O. G.. (2022). On the Geochemistry of the Danube River Sediments (Serbian Sector). in International Journal of Environmental Research and Public Health, 19(19), 12879.
https://doi.org/10.3390/ijerph191912879
Culicov OA, Trtić-Petrović TM, Nekhoroshkov PS, Zinicovscaia I, Duliu OG. On the Geochemistry of the Danube River Sediments (Serbian Sector). in International Journal of Environmental Research and Public Health. 2022;19(19):12879.
doi:10.3390/ijerph191912879 .
Culicov, Otilia Ana, Trtić-Petrović, Tatjana M., Nekhoroshkov, Pavel S., Zinicovscaia, Inga, Duliu, Octavian G., "On the Geochemistry of the Danube River Sediments (Serbian Sector)" in International Journal of Environmental Research and Public Health, 19, no. 19 (2022):12879,
https://doi.org/10.3390/ijerph191912879 . .
3
3

Evaluation of black carbon in fine atmospheric particulate matter on various filter types by multi-wavelength light absorption technique

Radenković, Mirjana; Topalović, Dušan; Trtić-Petrović, Tatjana M.; Tasić, Viša; Stanković, Srboljub; Stanić, Vojislav

(RAD Centre, Niš, Serbia, 2021)

TY  - CONF
AU  - Radenković, Mirjana
AU  - Topalović, Dušan
AU  - Trtić-Petrović, Tatjana M.
AU  - Tasić, Viša
AU  - Stanković, Srboljub
AU  - Stanić, Vojislav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11123
AB  - Besides the evident harmful impact to human health, black carbon (BC) is considered as second important contributor to climate change due to its sunlight absorption and warming effects. It is a major component of fine atmospheric particulate matter emitted during the incomplete combustion of fossil fuels and biomass burning emissions from both natural and anthropogenic sources. Atmospheric carbon was recognized in forms of soot, black carbon, elemental carbon, inorganic carbon, organic carbon, brown carbon, etc, depending on the origin and absorption characteristics. Measurement methodologies for BC analysis in aerosol samples are mostly based on optical and thermal properties of carbon species. Here are presented results of the application of the optical analytical technique which relies on the multi-wavelenght light attenuation by black carbon component of fine particulate matter deposited on filter media. For that purpose, standard polytetrafluoroethylene (PTFE), quartz and carbon nanotube filters with different qualitative features and pore diameters were exposed to fine aerosol fraction at urban background monitoring site in heating and non heating seasons, using low-volume air samplers with 2.3 m3/h air flow. A multi wavelength absorption black carbon instrument (MABI) with 405 nm, 465 nm, 525 nm, 639 nm, 870 nm, 940 nm and 1050 nm LEDs was used for blank and exposed filters analysis and black carbon evaluation. Differences in obtained BC values are discussed in relation to various absorption potential of different filter media, taking into account absorption coefficients dependence on the wavelength and density. Main advantage of this method is simplicity and complementarity with nondestructive nuclear analytical techniques (EDXRF, PIXE) for elemental analysis of fine aerosol fraction on specific filter media. Differentiation between black carbon coming from fossil fuels combustion and from biomass burning sources would be additional information valuable for source apportionment analysis using positive matrix factorization and reliable discussion of air pollution observed at selected receptor site.
PB  - RAD Centre, Niš, Serbia
C3  - RAD 2021 : 9th International Conference on Radiation in Various Fields of Research : book of abstracts; June 14-18; Herceg Novi, Montenegro
T1  - Evaluation of black carbon in fine atmospheric particulate matter on various filter types by multi-wavelength light absorption technique
SP  - 64
DO  - 10.21175/rad.abstr.book.2021.11.6
ER  - 
@conference{
author = "Radenković, Mirjana and Topalović, Dušan and Trtić-Petrović, Tatjana M. and Tasić, Viša and Stanković, Srboljub and Stanić, Vojislav",
year = "2021",
abstract = "Besides the evident harmful impact to human health, black carbon (BC) is considered as second important contributor to climate change due to its sunlight absorption and warming effects. It is a major component of fine atmospheric particulate matter emitted during the incomplete combustion of fossil fuels and biomass burning emissions from both natural and anthropogenic sources. Atmospheric carbon was recognized in forms of soot, black carbon, elemental carbon, inorganic carbon, organic carbon, brown carbon, etc, depending on the origin and absorption characteristics. Measurement methodologies for BC analysis in aerosol samples are mostly based on optical and thermal properties of carbon species. Here are presented results of the application of the optical analytical technique which relies on the multi-wavelenght light attenuation by black carbon component of fine particulate matter deposited on filter media. For that purpose, standard polytetrafluoroethylene (PTFE), quartz and carbon nanotube filters with different qualitative features and pore diameters were exposed to fine aerosol fraction at urban background monitoring site in heating and non heating seasons, using low-volume air samplers with 2.3 m3/h air flow. A multi wavelength absorption black carbon instrument (MABI) with 405 nm, 465 nm, 525 nm, 639 nm, 870 nm, 940 nm and 1050 nm LEDs was used for blank and exposed filters analysis and black carbon evaluation. Differences in obtained BC values are discussed in relation to various absorption potential of different filter media, taking into account absorption coefficients dependence on the wavelength and density. Main advantage of this method is simplicity and complementarity with nondestructive nuclear analytical techniques (EDXRF, PIXE) for elemental analysis of fine aerosol fraction on specific filter media. Differentiation between black carbon coming from fossil fuels combustion and from biomass burning sources would be additional information valuable for source apportionment analysis using positive matrix factorization and reliable discussion of air pollution observed at selected receptor site.",
publisher = "RAD Centre, Niš, Serbia",
journal = "RAD 2021 : 9th International Conference on Radiation in Various Fields of Research : book of abstracts; June 14-18; Herceg Novi, Montenegro",
title = "Evaluation of black carbon in fine atmospheric particulate matter on various filter types by multi-wavelength light absorption technique",
pages = "64",
doi = "10.21175/rad.abstr.book.2021.11.6"
}
Radenković, M., Topalović, D., Trtić-Petrović, T. M., Tasić, V., Stanković, S.,& Stanić, V.. (2021). Evaluation of black carbon in fine atmospheric particulate matter on various filter types by multi-wavelength light absorption technique. in RAD 2021 : 9th International Conference on Radiation in Various Fields of Research : book of abstracts; June 14-18; Herceg Novi, Montenegro
RAD Centre, Niš, Serbia., 64.
https://doi.org/10.21175/rad.abstr.book.2021.11.6
Radenković M, Topalović D, Trtić-Petrović TM, Tasić V, Stanković S, Stanić V. Evaluation of black carbon in fine atmospheric particulate matter on various filter types by multi-wavelength light absorption technique. in RAD 2021 : 9th International Conference on Radiation in Various Fields of Research : book of abstracts; June 14-18; Herceg Novi, Montenegro. 2021;:64.
doi:10.21175/rad.abstr.book.2021.11.6 .
Radenković, Mirjana, Topalović, Dušan, Trtić-Petrović, Tatjana M., Tasić, Viša, Stanković, Srboljub, Stanić, Vojislav, "Evaluation of black carbon in fine atmospheric particulate matter on various filter types by multi-wavelength light absorption technique" in RAD 2021 : 9th International Conference on Radiation in Various Fields of Research : book of abstracts; June 14-18; Herceg Novi, Montenegro (2021):64,
https://doi.org/10.21175/rad.abstr.book.2021.11.6 . .

Spatial distribution of multielements including lanthanides in sediments of Iron Gate I Reservoir in the Danube River

Culicov, Otilia Ana; Trtić-Petrović, Tatjana M.; Balvanović, Roman V.; Petković, Anđelka; Ražić, Slavica

(2021)

TY  - JOUR
AU  - Culicov, Otilia Ana
AU  - Trtić-Petrović, Tatjana M.
AU  - Balvanović, Roman V.
AU  - Petković, Anđelka
AU  - Ražić, Slavica
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9654
AB  - Recent studies show that lanthanides (Ln) are becoming emerging pollutants due to their wide application in new technologies, but their environmental fate, transport, and possible accumulation are still relatively unknown. This study aims to determine major and trace elements including Ln in the Danube River sediment which either belong or close to the Iron Gate Reservoir. The Iron Gate Reservoir is characterized by accumulation of sediments as an effect of building hydropower dam Iron Gate I. The surface sediments were collected on the Danube River—1141 to 864 km and three tributaries along this waterway. Two samples of deep sediments were used for comparison. The results indicate the significant upward enrichment of Zn, Sb, Cr, Nd, and Dy in sediments belongs to the Iron Gate Reservoir. The sample 4-Smed is labelled as a hot spot of contamination with Zn, Cr, As, Sb, Nd, and Dy. Also, a trend of increasing concentration in the time period from 1995 to 2016 was found for elements Zn, Cr, and Ni in sediment samples in the Iron Gate Reservoir. Chemometric analysis shows the grouping of sample sites into clusters characterized by the following properties: (i) increased concentration of all measured elements (samples within the Iron Gate Reservoir); (ii) increased Cu concentration (11-Pek); and (iii) lower concentrations of the measured elements (deep sediments). The data presented hereby contribute to the monitoring of pollution of the River Danube sediments and give the first view of Ln profile in the studied sediments.
T2  - Environmental Science and Pollution Research
T1  - Spatial distribution of multielements including lanthanides in sediments of Iron Gate I Reservoir in the Danube River
VL  - 28
IS  - 33
SP  - 44877
EP  - 44889
DO  - 10.1007/s11356-021-13752-6
ER  - 
@article{
author = "Culicov, Otilia Ana and Trtić-Petrović, Tatjana M. and Balvanović, Roman V. and Petković, Anđelka and Ražić, Slavica",
year = "2021",
abstract = "Recent studies show that lanthanides (Ln) are becoming emerging pollutants due to their wide application in new technologies, but their environmental fate, transport, and possible accumulation are still relatively unknown. This study aims to determine major and trace elements including Ln in the Danube River sediment which either belong or close to the Iron Gate Reservoir. The Iron Gate Reservoir is characterized by accumulation of sediments as an effect of building hydropower dam Iron Gate I. The surface sediments were collected on the Danube River—1141 to 864 km and three tributaries along this waterway. Two samples of deep sediments were used for comparison. The results indicate the significant upward enrichment of Zn, Sb, Cr, Nd, and Dy in sediments belongs to the Iron Gate Reservoir. The sample 4-Smed is labelled as a hot spot of contamination with Zn, Cr, As, Sb, Nd, and Dy. Also, a trend of increasing concentration in the time period from 1995 to 2016 was found for elements Zn, Cr, and Ni in sediment samples in the Iron Gate Reservoir. Chemometric analysis shows the grouping of sample sites into clusters characterized by the following properties: (i) increased concentration of all measured elements (samples within the Iron Gate Reservoir); (ii) increased Cu concentration (11-Pek); and (iii) lower concentrations of the measured elements (deep sediments). The data presented hereby contribute to the monitoring of pollution of the River Danube sediments and give the first view of Ln profile in the studied sediments.",
journal = "Environmental Science and Pollution Research",
title = "Spatial distribution of multielements including lanthanides in sediments of Iron Gate I Reservoir in the Danube River",
volume = "28",
number = "33",
pages = "44877-44889",
doi = "10.1007/s11356-021-13752-6"
}
Culicov, O. A., Trtić-Petrović, T. M., Balvanović, R. V., Petković, A.,& Ražić, S.. (2021). Spatial distribution of multielements including lanthanides in sediments of Iron Gate I Reservoir in the Danube River. in Environmental Science and Pollution Research, 28(33), 44877-44889.
https://doi.org/10.1007/s11356-021-13752-6
Culicov OA, Trtić-Petrović TM, Balvanović RV, Petković A, Ražić S. Spatial distribution of multielements including lanthanides in sediments of Iron Gate I Reservoir in the Danube River. in Environmental Science and Pollution Research. 2021;28(33):44877-44889.
doi:10.1007/s11356-021-13752-6 .
Culicov, Otilia Ana, Trtić-Petrović, Tatjana M., Balvanović, Roman V., Petković, Anđelka, Ražić, Slavica, "Spatial distribution of multielements including lanthanides in sediments of Iron Gate I Reservoir in the Danube River" in Environmental Science and Pollution Research, 28, no. 33 (2021):44877-44889,
https://doi.org/10.1007/s11356-021-13752-6 . .
1
2
3

Ionic liquid-derived carbon-supported metal electrocatalysts as anodes in direct borohydride-peroxide fuel cells

Milikić, Jadranka; Oliveira, Raisa Costa Paes; Tapia, Andres; Santos, Diogo M.F.; Zdolšek, Nikola; Trtić-Petrović, Tatjana M.; Vraneš, Milan; Šljukić, Biljana

(2021)

TY  - JOUR
AU  - Milikić, Jadranka
AU  - Oliveira, Raisa Costa Paes
AU  - Tapia, Andres
AU  - Santos, Diogo M.F.
AU  - Zdolšek, Nikola
AU  - Trtić-Petrović, Tatjana M.
AU  - Vraneš, Milan
AU  - Šljukić, Biljana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9801
AB  - Three different carbon-supported metal (gold, platinum, nickel) nanoparticle (M/c-IL) electrocatalysts are prepared by template-free carbonization of the corresponding ionic liquids, namely [Hmim][AuCl4 ], [Hmim]2 [PtCl4 ], and [C16mim]2 [NiCl4 ], as confirmed by X-ray diffraction analysis, scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy and Raman spectroscopy. The electrochemical investigation of borohydride oxidation reaction (BOR) at the three electrocatalysts by cyclic voltammetry reveals different behavior for each material. BOR is found to be a first-order reaction at the three electrocatalysts, with an apparent activation energy of 10.6 and 13.8 kJ mol−1 for Pt/c-IL and Au/c-IL electrocatalysts, respectively. A number of exchanged electrons of 5.0, 2.4, and 2.0 is obtained for BOR at Pt/c-IL, Au/c-IL, and Ni/c-IL electrodes, respectively. Direct borohydride-peroxide fuel cell (DBPFC) tests done at temperatures in the 25–65◦C range show ca. four times higher power density when using a Pt/c-IL anode than with an Au/c-IL anode. Peak power densities of 40.6 and 120.5 mW cm−2 are achieved at 25 and 65◦C, respectively, for DBPFC with a Pt/c-IL anode electrocatalyst. © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).
T2  - Catalysts
T1  - Ionic liquid-derived carbon-supported metal electrocatalysts as anodes in direct borohydride-peroxide fuel cells
VL  - 11
IS  - 5
DO  - 10.3390/catal11050632
ER  - 
@article{
author = "Milikić, Jadranka and Oliveira, Raisa Costa Paes and Tapia, Andres and Santos, Diogo M.F. and Zdolšek, Nikola and Trtić-Petrović, Tatjana M. and Vraneš, Milan and Šljukić, Biljana",
year = "2021",
abstract = "Three different carbon-supported metal (gold, platinum, nickel) nanoparticle (M/c-IL) electrocatalysts are prepared by template-free carbonization of the corresponding ionic liquids, namely [Hmim][AuCl4 ], [Hmim]2 [PtCl4 ], and [C16mim]2 [NiCl4 ], as confirmed by X-ray diffraction analysis, scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy and Raman spectroscopy. The electrochemical investigation of borohydride oxidation reaction (BOR) at the three electrocatalysts by cyclic voltammetry reveals different behavior for each material. BOR is found to be a first-order reaction at the three electrocatalysts, with an apparent activation energy of 10.6 and 13.8 kJ mol−1 for Pt/c-IL and Au/c-IL electrocatalysts, respectively. A number of exchanged electrons of 5.0, 2.4, and 2.0 is obtained for BOR at Pt/c-IL, Au/c-IL, and Ni/c-IL electrodes, respectively. Direct borohydride-peroxide fuel cell (DBPFC) tests done at temperatures in the 25–65◦C range show ca. four times higher power density when using a Pt/c-IL anode than with an Au/c-IL anode. Peak power densities of 40.6 and 120.5 mW cm−2 are achieved at 25 and 65◦C, respectively, for DBPFC with a Pt/c-IL anode electrocatalyst. © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).",
journal = "Catalysts",
title = "Ionic liquid-derived carbon-supported metal electrocatalysts as anodes in direct borohydride-peroxide fuel cells",
volume = "11",
number = "5",
doi = "10.3390/catal11050632"
}
Milikić, J., Oliveira, R. C. P., Tapia, A., Santos, D. M.F., Zdolšek, N., Trtić-Petrović, T. M., Vraneš, M.,& Šljukić, B.. (2021). Ionic liquid-derived carbon-supported metal electrocatalysts as anodes in direct borohydride-peroxide fuel cells. in Catalysts, 11(5).
https://doi.org/10.3390/catal11050632
Milikić J, Oliveira RCP, Tapia A, Santos DM, Zdolšek N, Trtić-Petrović TM, Vraneš M, Šljukić B. Ionic liquid-derived carbon-supported metal electrocatalysts as anodes in direct borohydride-peroxide fuel cells. in Catalysts. 2021;11(5).
doi:10.3390/catal11050632 .
Milikić, Jadranka, Oliveira, Raisa Costa Paes, Tapia, Andres, Santos, Diogo M.F., Zdolšek, Nikola, Trtić-Petrović, Tatjana M., Vraneš, Milan, Šljukić, Biljana, "Ionic liquid-derived carbon-supported metal electrocatalysts as anodes in direct borohydride-peroxide fuel cells" in Catalysts, 11, no. 5 (2021),
https://doi.org/10.3390/catal11050632 . .
4
1
3

Protic ionic liquids as adjuvants to enhance extraction and separation performance of diverse polarity compounds in PEG-salt based aqueous biphasic system

Jocić, Ana; Marić, Slađana; Dimitrijević, Aleksandra; Tot, Aleksandar; Gadžurić, Slobodan; Vraneš, Milan; Trtić-Petrović, Tatjana M.

(2020)

TY  - JOUR
AU  - Jocić, Ana
AU  - Marić, Slađana
AU  - Dimitrijević, Aleksandra
AU  - Tot, Aleksandar
AU  - Gadžurić, Slobodan
AU  - Vraneš, Milan
AU  - Trtić-Petrović, Tatjana M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8835
AB  - This work addresses use of a set of 2-hydroxypropylammonium based protic ionic liquids (PILs) as adjuvants in the aqueous biphasic system (ABS) composed of polyethylene glycol, with molecular weight 2000 g/mol (PEG 2000) and potassium carbonate. The phase diagrams were determined at 25 °C for ABS without and with the addition of 5 wt% of PIL. Comparative analysis of solubility curves indicates that PILs influence liquid-liquid equilibria of PEG 2000-K2CO3 ABS by heightening the hydrophilicity of a PEG-rich phase in various degrees. The compositions of the phases (tie lines) were determined for the selected ABS mixture composition, 26 wt% of PEG 2000 + 10 wt% of K2CO3, without and with 5 wt% of PILs, that is further used for the separation studies. The distribution of PILs between two phases is mainly dependent on specific PEG-PIL interactions and on the PIL content in ABS mixture. The experimental results are supported by molecular simulations that contributed to a broader picture of underlying effects of PILs as adjuvants on ABS formation. The partition of four dye compounds, Remazol Brilliant Blue R (RBBR), Orange II (OII), Rhodamine B (RB) and Congo Red (CR), as probe molecules with different intrinsic properties, was investigated. Obtained results show that the addition of PILs can improve the extraction of hydrophilic and charged compounds as OII, RBBR and CR in PEG-rich phase. On the other hand, it promotes the extraction of hydrophobic and neutral solutes as RB in salt-rich phase. By the addition of the most hydrophilic 3-chloropropanoate based PIL in the PEG 2000-K2CO3 ABS 12 times higher separation factor for OII and RB was achieved. © 2020 Elsevier B.V.
T2  - Journal of Molecular Liquids
T1  - Protic ionic liquids as adjuvants to enhance extraction and separation performance of diverse polarity compounds in PEG-salt based aqueous biphasic system
VL  - 303
SP  - 112484
DO  - 10.1016/j.molliq.2020.112484
ER  - 
@article{
author = "Jocić, Ana and Marić, Slađana and Dimitrijević, Aleksandra and Tot, Aleksandar and Gadžurić, Slobodan and Vraneš, Milan and Trtić-Petrović, Tatjana M.",
year = "2020",
abstract = "This work addresses use of a set of 2-hydroxypropylammonium based protic ionic liquids (PILs) as adjuvants in the aqueous biphasic system (ABS) composed of polyethylene glycol, with molecular weight 2000 g/mol (PEG 2000) and potassium carbonate. The phase diagrams were determined at 25 °C for ABS without and with the addition of 5 wt% of PIL. Comparative analysis of solubility curves indicates that PILs influence liquid-liquid equilibria of PEG 2000-K2CO3 ABS by heightening the hydrophilicity of a PEG-rich phase in various degrees. The compositions of the phases (tie lines) were determined for the selected ABS mixture composition, 26 wt% of PEG 2000 + 10 wt% of K2CO3, without and with 5 wt% of PILs, that is further used for the separation studies. The distribution of PILs between two phases is mainly dependent on specific PEG-PIL interactions and on the PIL content in ABS mixture. The experimental results are supported by molecular simulations that contributed to a broader picture of underlying effects of PILs as adjuvants on ABS formation. The partition of four dye compounds, Remazol Brilliant Blue R (RBBR), Orange II (OII), Rhodamine B (RB) and Congo Red (CR), as probe molecules with different intrinsic properties, was investigated. Obtained results show that the addition of PILs can improve the extraction of hydrophilic and charged compounds as OII, RBBR and CR in PEG-rich phase. On the other hand, it promotes the extraction of hydrophobic and neutral solutes as RB in salt-rich phase. By the addition of the most hydrophilic 3-chloropropanoate based PIL in the PEG 2000-K2CO3 ABS 12 times higher separation factor for OII and RB was achieved. © 2020 Elsevier B.V.",
journal = "Journal of Molecular Liquids",
title = "Protic ionic liquids as adjuvants to enhance extraction and separation performance of diverse polarity compounds in PEG-salt based aqueous biphasic system",
volume = "303",
pages = "112484",
doi = "10.1016/j.molliq.2020.112484"
}
Jocić, A., Marić, S., Dimitrijević, A., Tot, A., Gadžurić, S., Vraneš, M.,& Trtić-Petrović, T. M.. (2020). Protic ionic liquids as adjuvants to enhance extraction and separation performance of diverse polarity compounds in PEG-salt based aqueous biphasic system. in Journal of Molecular Liquids, 303, 112484.
https://doi.org/10.1016/j.molliq.2020.112484
Jocić A, Marić S, Dimitrijević A, Tot A, Gadžurić S, Vraneš M, Trtić-Petrović TM. Protic ionic liquids as adjuvants to enhance extraction and separation performance of diverse polarity compounds in PEG-salt based aqueous biphasic system. in Journal of Molecular Liquids. 2020;303:112484.
doi:10.1016/j.molliq.2020.112484 .
Jocić, Ana, Marić, Slađana, Dimitrijević, Aleksandra, Tot, Aleksandar, Gadžurić, Slobodan, Vraneš, Milan, Trtić-Petrović, Tatjana M., "Protic ionic liquids as adjuvants to enhance extraction and separation performance of diverse polarity compounds in PEG-salt based aqueous biphasic system" in Journal of Molecular Liquids, 303 (2020):112484,
https://doi.org/10.1016/j.molliq.2020.112484 . .
14
7
15

Further insight into the influence of functionalization and positional isomerism of pyridinium ionic liquids on the aqueous two-phase system equilibria

Dimitrijević, Aleksandra; Мilićević, Jelena; Jocić, Ana; Marić, Slađana; Trtić-Petrović, Tatjana M.; Papović, Snežana; Tot, Aleksandar; Gadžurić, Slobodan; Vraneš, Milan

(2020)

TY  - JOUR
AU  - Dimitrijević, Aleksandra
AU  - Мilićević, Jelena
AU  - Jocić, Ana
AU  - Marić, Slađana
AU  - Trtić-Petrović, Tatjana M.
AU  - Papović, Snežana
AU  - Tot, Aleksandar
AU  - Gadžurić, Slobodan
AU  - Vraneš, Milan
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8833
AB  - Despite a large collection of publications dealing with the characterization of ionic liquid-based aqueous biphasic systems (IL-ABS), a gap still exists regarding the impact of functionalized alkyl side branches and IL positional isomers on phase equilibria. Therefore, this work addresses the investigation of the ability of different methyl substituted pyridinium based ILs on the formation of ABSs with K3PO4. We evaluated the impact of (i) functional groups (hydroxyl or ether) embed in side alkyl chains of pyridinium cations, (ii) positional isomerism of methyl group (ortho, meta and para) and (iii) the IL cation core. Ternary phase diagrams of the ABSs formed by these ILs and K3PO4 and the appropriate tie lines were determined and presented. It is shown that the presence of functionalized alkyl chain largely affects the salting-in behavior of ILs (ILs with the oxygen groups are more difficult to form ABS) while more subtle differences were observed among positional isomers. Based on the obtained results it is concluded that change of biphasic area of ABS is the manifestation of the altered affinity of ILs for water as a consequence of cation structure. Moreover, aiming at gathering a broader picture of the relationship between ILs structure and ABS properties, molecular simulations were performed, and it was showed that the obtained results are consistent with the experimental results. © 2020 Elsevier B.V.
T2  - Fluid Phase Equilibria
T1  - Further insight into the influence of functionalization and positional isomerism of pyridinium ionic liquids on the aqueous two-phase system equilibria
VL  - 512
SP  - 112520
DO  - 10.1016/j.fluid.2020.112520
ER  - 
@article{
author = "Dimitrijević, Aleksandra and Мilićević, Jelena and Jocić, Ana and Marić, Slađana and Trtić-Petrović, Tatjana M. and Papović, Snežana and Tot, Aleksandar and Gadžurić, Slobodan and Vraneš, Milan",
year = "2020",
abstract = "Despite a large collection of publications dealing with the characterization of ionic liquid-based aqueous biphasic systems (IL-ABS), a gap still exists regarding the impact of functionalized alkyl side branches and IL positional isomers on phase equilibria. Therefore, this work addresses the investigation of the ability of different methyl substituted pyridinium based ILs on the formation of ABSs with K3PO4. We evaluated the impact of (i) functional groups (hydroxyl or ether) embed in side alkyl chains of pyridinium cations, (ii) positional isomerism of methyl group (ortho, meta and para) and (iii) the IL cation core. Ternary phase diagrams of the ABSs formed by these ILs and K3PO4 and the appropriate tie lines were determined and presented. It is shown that the presence of functionalized alkyl chain largely affects the salting-in behavior of ILs (ILs with the oxygen groups are more difficult to form ABS) while more subtle differences were observed among positional isomers. Based on the obtained results it is concluded that change of biphasic area of ABS is the manifestation of the altered affinity of ILs for water as a consequence of cation structure. Moreover, aiming at gathering a broader picture of the relationship between ILs structure and ABS properties, molecular simulations were performed, and it was showed that the obtained results are consistent with the experimental results. © 2020 Elsevier B.V.",
journal = "Fluid Phase Equilibria",
title = "Further insight into the influence of functionalization and positional isomerism of pyridinium ionic liquids on the aqueous two-phase system equilibria",
volume = "512",
pages = "112520",
doi = "10.1016/j.fluid.2020.112520"
}
Dimitrijević, A., Мilićević, J., Jocić, A., Marić, S., Trtić-Petrović, T. M., Papović, S., Tot, A., Gadžurić, S.,& Vraneš, M.. (2020). Further insight into the influence of functionalization and positional isomerism of pyridinium ionic liquids on the aqueous two-phase system equilibria. in Fluid Phase Equilibria, 512, 112520.
https://doi.org/10.1016/j.fluid.2020.112520
Dimitrijević A, Мilićević J, Jocić A, Marić S, Trtić-Petrović TM, Papović S, Tot A, Gadžurić S, Vraneš M. Further insight into the influence of functionalization and positional isomerism of pyridinium ionic liquids on the aqueous two-phase system equilibria. in Fluid Phase Equilibria. 2020;512:112520.
doi:10.1016/j.fluid.2020.112520 .
Dimitrijević, Aleksandra, Мilićević, Jelena, Jocić, Ana, Marić, Slađana, Trtić-Petrović, Tatjana M., Papović, Snežana, Tot, Aleksandar, Gadžurić, Slobodan, Vraneš, Milan, "Further insight into the influence of functionalization and positional isomerism of pyridinium ionic liquids on the aqueous two-phase system equilibria" in Fluid Phase Equilibria, 512 (2020):112520,
https://doi.org/10.1016/j.fluid.2020.112520 . .
8
4
9

Valorization of Expired Energy Drinks by Designed and Integrated Ionic Liquid-Based Aqueous Biphasic Systems

Dimitrijević, Aleksandra; Tavares, Ana Paula M.; Almeida, Mafalda R.; Vraneš, Milan; Sousa, Ana C. A.; Cristovão, Ana Clara; Trtić-Petrović, Tatjana M.; Gadžurić, Slobodan; Freire, Mara G.

(2020)

TY  - JOUR
AU  - Dimitrijević, Aleksandra
AU  - Tavares, Ana Paula M.
AU  - Almeida, Mafalda R.
AU  - Vraneš, Milan
AU  - Sousa, Ana C. A.
AU  - Cristovão, Ana Clara
AU  - Trtić-Petrović, Tatjana M.
AU  - Gadžurić, Slobodan
AU  - Freire, Mara G.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8974
AB  - Expired energy drinks are rich in bioactive value-added compounds that can be recovered and reused in order to valorize food waste within a circular economy perspective. However, to accomplish such requirements, it is necessary to develop sustainable extraction and recovery processes, which must consist of decreasing the number of steps required or developing integrated strategies. In this work, novel aqueous biphasic systems (ABS) composed of ionic liquids (ILs) and a biocompatible polymer polypropylene glycol (400 g.mol(-1), PPG 400) were studied for the simultaneous extraction and recovery of three value-added compounds, namely, caffeine, taurine, and niacin, from expired energy drinks. ILs were designed and synthesized in order to have similar anions to the target compounds, thus allowing enhanced selectivity and biological activity, while avoiding an extra step of separation of these high-value compounds from the IL-rich phase. To this end, cholinium-based ILs comprising the anions lactate, pyruvate, taurate, and nicotinate were synthesized, and their cytotoxicity and ecotoxicity credentials were evaluated. Overall, taurine and niacin are majorly enriched in the IL-rich phase, while caffeine preferentially migrates in the majority of the cases toward the PPG-rich phase. However, caffeine also partitions to the IL-rich phase in the ABS formed by cholinium pyruvate or cholinium nicotinate. The ABS formed by cholinium nicotinate and PPG 400 is the best system identified, allowing the almost complete recovery (recovery efficiencies > 82%) of all target compounds into the IL-rich phase in one step. Furthermore, cholinium nicotinate exhibits marginal cytotoxic potential and is harmless from an ecotoxicological point of view. This system is thus a promising platform to simultaneously extract, recover, and reuse value-added compounds from expired energy drinks without the need of removing the IL or recovering the target compounds from the IL-rich phase, thus contributing to a sustainable and circular food economy.
T2  - ACS Sustainable Chemistry and Engineering
T1  - Valorization of Expired Energy Drinks by Designed and Integrated Ionic Liquid-Based Aqueous Biphasic Systems
VL  - 8
IS  - 14
SP  - 5683
EP  - 5692
DO  - 10.1021/acssuschemeng.0c00429
ER  - 
@article{
author = "Dimitrijević, Aleksandra and Tavares, Ana Paula M. and Almeida, Mafalda R. and Vraneš, Milan and Sousa, Ana C. A. and Cristovão, Ana Clara and Trtić-Petrović, Tatjana M. and Gadžurić, Slobodan and Freire, Mara G.",
year = "2020",
abstract = "Expired energy drinks are rich in bioactive value-added compounds that can be recovered and reused in order to valorize food waste within a circular economy perspective. However, to accomplish such requirements, it is necessary to develop sustainable extraction and recovery processes, which must consist of decreasing the number of steps required or developing integrated strategies. In this work, novel aqueous biphasic systems (ABS) composed of ionic liquids (ILs) and a biocompatible polymer polypropylene glycol (400 g.mol(-1), PPG 400) were studied for the simultaneous extraction and recovery of three value-added compounds, namely, caffeine, taurine, and niacin, from expired energy drinks. ILs were designed and synthesized in order to have similar anions to the target compounds, thus allowing enhanced selectivity and biological activity, while avoiding an extra step of separation of these high-value compounds from the IL-rich phase. To this end, cholinium-based ILs comprising the anions lactate, pyruvate, taurate, and nicotinate were synthesized, and their cytotoxicity and ecotoxicity credentials were evaluated. Overall, taurine and niacin are majorly enriched in the IL-rich phase, while caffeine preferentially migrates in the majority of the cases toward the PPG-rich phase. However, caffeine also partitions to the IL-rich phase in the ABS formed by cholinium pyruvate or cholinium nicotinate. The ABS formed by cholinium nicotinate and PPG 400 is the best system identified, allowing the almost complete recovery (recovery efficiencies > 82%) of all target compounds into the IL-rich phase in one step. Furthermore, cholinium nicotinate exhibits marginal cytotoxic potential and is harmless from an ecotoxicological point of view. This system is thus a promising platform to simultaneously extract, recover, and reuse value-added compounds from expired energy drinks without the need of removing the IL or recovering the target compounds from the IL-rich phase, thus contributing to a sustainable and circular food economy.",
journal = "ACS Sustainable Chemistry and Engineering",
title = "Valorization of Expired Energy Drinks by Designed and Integrated Ionic Liquid-Based Aqueous Biphasic Systems",
volume = "8",
number = "14",
pages = "5683-5692",
doi = "10.1021/acssuschemeng.0c00429"
}
Dimitrijević, A., Tavares, A. P. M., Almeida, M. R., Vraneš, M., Sousa, A. C. A., Cristovão, A. C., Trtić-Petrović, T. M., Gadžurić, S.,& Freire, M. G.. (2020). Valorization of Expired Energy Drinks by Designed and Integrated Ionic Liquid-Based Aqueous Biphasic Systems. in ACS Sustainable Chemistry and Engineering, 8(14), 5683-5692.
https://doi.org/10.1021/acssuschemeng.0c00429
Dimitrijević A, Tavares APM, Almeida MR, Vraneš M, Sousa ACA, Cristovão AC, Trtić-Petrović TM, Gadžurić S, Freire MG. Valorization of Expired Energy Drinks by Designed and Integrated Ionic Liquid-Based Aqueous Biphasic Systems. in ACS Sustainable Chemistry and Engineering. 2020;8(14):5683-5692.
doi:10.1021/acssuschemeng.0c00429 .
Dimitrijević, Aleksandra, Tavares, Ana Paula M., Almeida, Mafalda R., Vraneš, Milan, Sousa, Ana C. A., Cristovão, Ana Clara, Trtić-Petrović, Tatjana M., Gadžurić, Slobodan, Freire, Mara G., "Valorization of Expired Energy Drinks by Designed and Integrated Ionic Liquid-Based Aqueous Biphasic Systems" in ACS Sustainable Chemistry and Engineering, 8, no. 14 (2020):5683-5692,
https://doi.org/10.1021/acssuschemeng.0c00429 . .
5
8
3
7

Aqueous biphasic systems comprising copolymers and cholinium-based salts or ionic liquids: Insights on the mechanisms responsible for their creation

Dimitrijević, Aleksandra; Tavares, Ana Paula M.; Jocić, Ana; Marić, Slađana; Trtić-Petrović, Tatjana M.; Gadžurić, Slobodan; Freire, Mara G.

(2020)

TY  - JOUR
AU  - Dimitrijević, Aleksandra
AU  - Tavares, Ana Paula M.
AU  - Jocić, Ana
AU  - Marić, Slađana
AU  - Trtić-Petrović, Tatjana M.
AU  - Gadžurić, Slobodan
AU  - Freire, Mara G.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8995
AB  - Aqueous biphasic systems (ABS) formed by copolymers and ionic liquids (ILs) have demonstrated to be effective separation platforms, but there is still a gap on the complete understanding of the molecular-level mechanisms ruling the two-phase formation for this type of systems. This work addresses the determination of the liquid–liquid equilibrium of ABS composed of cholinium-based salts or cholinium-based ILs and the triblock copolymer Pluronic PE6200 (PL6200). It is demonstrated that PL6200 can form ABS with all investigated cholinium-based salts or ILs, contrarily to most poly(ethylene)glycol polymers, which is due to the presence of hydrophobic propylene oxide (PO) blocks. From the phase diagrams behavior and IL/salt anions properties, it is shown that the formation of ABS with cholinium-based salts is ruled by the anions polar surface and ability to be hydrated, whereas in systems comprising ILs van der Waals interactions between the copolymer and the IL cannot be discarded. The partition of a series of alkaloids in these systems, namely caffeine, nicotine, theophylline, and theobromine, was additionally appraised. It is shown that caffeine, theophylline, and theobromine preferentially migrate to the more hydrophobic PL6200-rich phase, and that their partition depends on the water content in the respective phase, being ruled by the phases’ hydrophobicity. On the other hand, nicotine, with the most prominent hydrophobic character amongst the studied alkaloids, preferentially migrates to the salt- or IL-rich phase, in which interactions occurring between this alkaloid and the IL/salt cannot be discarded. The ABS formed by cholinium dihydrogenphosphate is the most selective system identified to separate nicotine from the remaining alkaloids, giving some insights into their investigation as separation platforms for alkaloids from natural extracts.
T2  - Separation and Purification Technology
T1  - Aqueous biphasic systems comprising copolymers and cholinium-based salts or ionic liquids: Insights on the mechanisms responsible for their creation
VL  - 248
SP  - 117050
DO  - 10.1016/j.seppur.2020.117050
ER  - 
@article{
author = "Dimitrijević, Aleksandra and Tavares, Ana Paula M. and Jocić, Ana and Marić, Slađana and Trtić-Petrović, Tatjana M. and Gadžurić, Slobodan and Freire, Mara G.",
year = "2020",
abstract = "Aqueous biphasic systems (ABS) formed by copolymers and ionic liquids (ILs) have demonstrated to be effective separation platforms, but there is still a gap on the complete understanding of the molecular-level mechanisms ruling the two-phase formation for this type of systems. This work addresses the determination of the liquid–liquid equilibrium of ABS composed of cholinium-based salts or cholinium-based ILs and the triblock copolymer Pluronic PE6200 (PL6200). It is demonstrated that PL6200 can form ABS with all investigated cholinium-based salts or ILs, contrarily to most poly(ethylene)glycol polymers, which is due to the presence of hydrophobic propylene oxide (PO) blocks. From the phase diagrams behavior and IL/salt anions properties, it is shown that the formation of ABS with cholinium-based salts is ruled by the anions polar surface and ability to be hydrated, whereas in systems comprising ILs van der Waals interactions between the copolymer and the IL cannot be discarded. The partition of a series of alkaloids in these systems, namely caffeine, nicotine, theophylline, and theobromine, was additionally appraised. It is shown that caffeine, theophylline, and theobromine preferentially migrate to the more hydrophobic PL6200-rich phase, and that their partition depends on the water content in the respective phase, being ruled by the phases’ hydrophobicity. On the other hand, nicotine, with the most prominent hydrophobic character amongst the studied alkaloids, preferentially migrates to the salt- or IL-rich phase, in which interactions occurring between this alkaloid and the IL/salt cannot be discarded. The ABS formed by cholinium dihydrogenphosphate is the most selective system identified to separate nicotine from the remaining alkaloids, giving some insights into their investigation as separation platforms for alkaloids from natural extracts.",
journal = "Separation and Purification Technology",
title = "Aqueous biphasic systems comprising copolymers and cholinium-based salts or ionic liquids: Insights on the mechanisms responsible for their creation",
volume = "248",
pages = "117050",
doi = "10.1016/j.seppur.2020.117050"
}
Dimitrijević, A., Tavares, A. P. M., Jocić, A., Marić, S., Trtić-Petrović, T. M., Gadžurić, S.,& Freire, M. G.. (2020). Aqueous biphasic systems comprising copolymers and cholinium-based salts or ionic liquids: Insights on the mechanisms responsible for their creation. in Separation and Purification Technology, 248, 117050.
https://doi.org/10.1016/j.seppur.2020.117050
Dimitrijević A, Tavares APM, Jocić A, Marić S, Trtić-Petrović TM, Gadžurić S, Freire MG. Aqueous biphasic systems comprising copolymers and cholinium-based salts or ionic liquids: Insights on the mechanisms responsible for their creation. in Separation and Purification Technology. 2020;248:117050.
doi:10.1016/j.seppur.2020.117050 .
Dimitrijević, Aleksandra, Tavares, Ana Paula M., Jocić, Ana, Marić, Slađana, Trtić-Petrović, Tatjana M., Gadžurić, Slobodan, Freire, Mara G., "Aqueous biphasic systems comprising copolymers and cholinium-based salts or ionic liquids: Insights on the mechanisms responsible for their creation" in Separation and Purification Technology, 248 (2020):117050,
https://doi.org/10.1016/j.seppur.2020.117050 . .
1
13
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13

Instrumental neutron activation for analysis of spatial distribution of heavy metals in surface sediments of the Danube River

Trtić-Petrović, Tatjana; Culicov, Otilia Ana; Balvanović, Roman V.; Petković, Anđelka

(RAD Centre, Niš, Serbia, 2019)

TY  - CONF
AU  - Trtić-Petrović, Tatjana
AU  - Culicov, Otilia Ana
AU  - Balvanović, Roman V.
AU  - Petković, Anđelka
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11145
PB  - RAD Centre, Niš, Serbia
C3  - RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro
T1  - Instrumental neutron activation for analysis of spatial distribution of heavy metals in surface sediments of the Danube River
SP  - 76
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11145
ER  - 
@conference{
author = "Trtić-Petrović, Tatjana and Culicov, Otilia Ana and Balvanović, Roman V. and Petković, Anđelka",
year = "2019",
publisher = "RAD Centre, Niš, Serbia",
journal = "RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro",
title = "Instrumental neutron activation for analysis of spatial distribution of heavy metals in surface sediments of the Danube River",
pages = "76",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11145"
}
Trtić-Petrović, T., Culicov, O. A., Balvanović, R. V.,& Petković, A.. (2019). Instrumental neutron activation for analysis of spatial distribution of heavy metals in surface sediments of the Danube River. in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro
RAD Centre, Niš, Serbia., 76.
https://hdl.handle.net/21.15107/rcub_vinar_11145
Trtić-Petrović T, Culicov OA, Balvanović RV, Petković A. Instrumental neutron activation for analysis of spatial distribution of heavy metals in surface sediments of the Danube River. in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro. 2019;:76.
https://hdl.handle.net/21.15107/rcub_vinar_11145 .
Trtić-Petrović, Tatjana, Culicov, Otilia Ana, Balvanović, Roman V., Petković, Anđelka, "Instrumental neutron activation for analysis of spatial distribution of heavy metals in surface sediments of the Danube River" in RAD 2019 : 7th International Conference on Radiation in Various Fields of Research : book of abstracts; June 10-14, 2019; Herceg Novi, Montenegro (2019):76,
https://hdl.handle.net/21.15107/rcub_vinar_11145 .

Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer

Zdolšek, Nikola; Rocha, Raquel P.; Krstić, Jugoslav B.; Trtić-Petrović, Tatjana M.; Šljukić, Biljana; Figueiredo, Jose L.; Vujković, Milica

(2019)

TY  - JOUR
AU  - Zdolšek, Nikola
AU  - Rocha, Raquel P.
AU  - Krstić, Jugoslav B.
AU  - Trtić-Petrović, Tatjana M.
AU  - Šljukić, Biljana
AU  - Figueiredo, Jose L.
AU  - Vujković, Milica
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0013468618328482
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8023
AB  - This work shows the potential application of carbon materials prepared by three different ionic liquid-based methods, using 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3], for electrochemical supercapacitors. The effects of [bmim][MeSO3] on morphology, texture and surface chemistry of prepared materials has been explored by SEM/TEM, N2/CO2 adsorption measurements and XPS. The results indicate the possibility of synthesis of carbon materials with tunable physicochemical properties using ionic liquid based methods. The charge storage behavior of all materials was studied in three different pH aqueous electrolytes. The pseudocapacitive and double layer contributions were estimated and discussed from the aspect of the textural changes and the changes of the chemical composition of surface functional groups containing heteroatoms. C[dbnd]O type functional groups, with the contribution of COOH groups, were found to be responsible for a different amount of charge, which could be stored in alkaline and acidic electrolytic solution. The material prepared by direct carbonization of [bmim][MeSO3], showed the best electrochemical performance in alkaline electrolyte with a capacitance of 187 F g−1 at 5 mV s−1 (or 148 F g−1 at 1 A g−1), due to the contribution of both electric-double layer capacitance and pseudocapacitance which arises from oxygen, nitrogen and sulfur functional groups. © 2018 Elsevier Ltd
T2  - Electrochimica Acta
T1  - Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer
VL  - 298
SP  - 541
EP  - 551
DO  - 10.1016/j.electacta.2018.12.129
ER  - 
@article{
author = "Zdolšek, Nikola and Rocha, Raquel P. and Krstić, Jugoslav B. and Trtić-Petrović, Tatjana M. and Šljukić, Biljana and Figueiredo, Jose L. and Vujković, Milica",
year = "2019",
abstract = "This work shows the potential application of carbon materials prepared by three different ionic liquid-based methods, using 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3], for electrochemical supercapacitors. The effects of [bmim][MeSO3] on morphology, texture and surface chemistry of prepared materials has been explored by SEM/TEM, N2/CO2 adsorption measurements and XPS. The results indicate the possibility of synthesis of carbon materials with tunable physicochemical properties using ionic liquid based methods. The charge storage behavior of all materials was studied in three different pH aqueous electrolytes. The pseudocapacitive and double layer contributions were estimated and discussed from the aspect of the textural changes and the changes of the chemical composition of surface functional groups containing heteroatoms. C[dbnd]O type functional groups, with the contribution of COOH groups, were found to be responsible for a different amount of charge, which could be stored in alkaline and acidic electrolytic solution. The material prepared by direct carbonization of [bmim][MeSO3], showed the best electrochemical performance in alkaline electrolyte with a capacitance of 187 F g−1 at 5 mV s−1 (or 148 F g−1 at 1 A g−1), due to the contribution of both electric-double layer capacitance and pseudocapacitance which arises from oxygen, nitrogen and sulfur functional groups. © 2018 Elsevier Ltd",
journal = "Electrochimica Acta",
title = "Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer",
volume = "298",
pages = "541-551",
doi = "10.1016/j.electacta.2018.12.129"
}
Zdolšek, N., Rocha, R. P., Krstić, J. B., Trtić-Petrović, T. M., Šljukić, B., Figueiredo, J. L.,& Vujković, M.. (2019). Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer. in Electrochimica Acta, 298, 541-551.
https://doi.org/10.1016/j.electacta.2018.12.129
Zdolšek N, Rocha RP, Krstić JB, Trtić-Petrović TM, Šljukić B, Figueiredo JL, Vujković M. Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer. in Electrochimica Acta. 2019;298:541-551.
doi:10.1016/j.electacta.2018.12.129 .
Zdolšek, Nikola, Rocha, Raquel P., Krstić, Jugoslav B., Trtić-Petrović, Tatjana M., Šljukić, Biljana, Figueiredo, Jose L., Vujković, Milica, "Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer" in Electrochimica Acta, 298 (2019):541-551,
https://doi.org/10.1016/j.electacta.2018.12.129 . .
32
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Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents

Dimitrijević, Aleksandra; Jocić, Ana; Zec, Nebojša; Tot, Aleksandar; Papović, Snežana; Gadžurić, Slobodan; Vraneš, Milan; Trtić-Petrović, Tatjana M.

(2019)

TY  - JOUR
AU  - Dimitrijević, Aleksandra
AU  - Jocić, Ana
AU  - Zec, Nebojša
AU  - Tot, Aleksandar
AU  - Papović, Snežana
AU  - Gadžurić, Slobodan
AU  - Vraneš, Milan
AU  - Trtić-Petrović, Tatjana M.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8157
AB  - The novel aqueous biphasic systems based on symmetric imidazolium ionic liquids (IL-ABSs)for the extraction of toxic and resistive dyes from water was studied. The cation symmetricity of ILs strongly influence the outstanding ability of 1,3-dibutylimidazolium dicyanamide, [bbim][dca], to generate ABS with the exceptionally low amount of eco-friendly citrate salt. A remarkable potential of [bbim][dca]/citrate based ABS to remove Orange II from wastewater with concentration up to 1000 fold and efficiency above 99.4% in a single step was achieved. The improved safety of proposed method nominates it as promising future strategy for pollution prevention. © 2019 The Korean Society of Industrial and Engineering Chemistry
T2  - Journal of Industrial and Engineering Chemistry
T1  - Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents
VL  - 76
SP  - 500
EP  - 507
DO  - 10.1016/j.jiec.2019.04.017
ER  - 
@article{
author = "Dimitrijević, Aleksandra and Jocić, Ana and Zec, Nebojša and Tot, Aleksandar and Papović, Snežana and Gadžurić, Slobodan and Vraneš, Milan and Trtić-Petrović, Tatjana M.",
year = "2019",
abstract = "The novel aqueous biphasic systems based on symmetric imidazolium ionic liquids (IL-ABSs)for the extraction of toxic and resistive dyes from water was studied. The cation symmetricity of ILs strongly influence the outstanding ability of 1,3-dibutylimidazolium dicyanamide, [bbim][dca], to generate ABS with the exceptionally low amount of eco-friendly citrate salt. A remarkable potential of [bbim][dca]/citrate based ABS to remove Orange II from wastewater with concentration up to 1000 fold and efficiency above 99.4% in a single step was achieved. The improved safety of proposed method nominates it as promising future strategy for pollution prevention. © 2019 The Korean Society of Industrial and Engineering Chemistry",
journal = "Journal of Industrial and Engineering Chemistry",
title = "Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents",
volume = "76",
pages = "500-507",
doi = "10.1016/j.jiec.2019.04.017"
}
Dimitrijević, A., Jocić, A., Zec, N., Tot, A., Papović, S., Gadžurić, S., Vraneš, M.,& Trtić-Petrović, T. M.. (2019). Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents. in Journal of Industrial and Engineering Chemistry, 76, 500-507.
https://doi.org/10.1016/j.jiec.2019.04.017
Dimitrijević A, Jocić A, Zec N, Tot A, Papović S, Gadžurić S, Vraneš M, Trtić-Petrović TM. Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents. in Journal of Industrial and Engineering Chemistry. 2019;76:500-507.
doi:10.1016/j.jiec.2019.04.017 .
Dimitrijević, Aleksandra, Jocić, Ana, Zec, Nebojša, Tot, Aleksandar, Papović, Snežana, Gadžurić, Slobodan, Vraneš, Milan, Trtić-Petrović, Tatjana M., "Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents" in Journal of Industrial and Engineering Chemistry, 76 (2019):500-507,
https://doi.org/10.1016/j.jiec.2019.04.017 . .
23
7
21

Corrigendum to “Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: Pseudocapacitance versus electrical double layer” [Electrochim. Acta 298 (2019) 541–551]

Zdolšek, Nikola; Rocha, Raquel P.; Krstić, Jugoslav B.; Trtić-Petrović, Tatjana M.; Šljukić, Biljana; Figueiredo, José L.; Vujković, Milica

(2019)

TY  - JOUR
AU  - Zdolšek, Nikola
AU  - Rocha, Raquel P.
AU  - Krstić, Jugoslav B.
AU  - Trtić-Petrović, Tatjana M.
AU  - Šljukić, Biljana
AU  - Figueiredo, José L.
AU  - Vujković, Milica
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0013468619307960
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8159
AB  - The authors regret errors in the above mentioned article in the equation (2)as well as in the Fig. 10a. In the equation (2)the number 2 was accidently omitted, whereas the values for the x-axis of Fig. 10a were doubled by accident. The authors would like to apologise for any inconvenience caused. The corrected equation (2)and Fig. 10 are shown below. [Formula presented][Figure presented]Fig. 10. a)Galvanostatic charge-discharge curves for Carb-IL at different current densities in 6 M KOH and b)dependence of the discharge specific capacitance of Carb-IL on the number of cycles, at 5 A g −1 . © 2018 Elsevier Ltd
T2  - Electrochimica Acta
T1  - Corrigendum to “Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: Pseudocapacitance versus electrical double layer” [Electrochim. Acta 298 (2019) 541–551]
VL  - 310
SP  - 221
DO  - 10.1016/j.electacta.2019.04.108
ER  - 
@article{
author = "Zdolšek, Nikola and Rocha, Raquel P. and Krstić, Jugoslav B. and Trtić-Petrović, Tatjana M. and Šljukić, Biljana and Figueiredo, José L. and Vujković, Milica",
year = "2019",
abstract = "The authors regret errors in the above mentioned article in the equation (2)as well as in the Fig. 10a. In the equation (2)the number 2 was accidently omitted, whereas the values for the x-axis of Fig. 10a were doubled by accident. The authors would like to apologise for any inconvenience caused. The corrected equation (2)and Fig. 10 are shown below. [Formula presented][Figure presented]Fig. 10. a)Galvanostatic charge-discharge curves for Carb-IL at different current densities in 6 M KOH and b)dependence of the discharge specific capacitance of Carb-IL on the number of cycles, at 5 A g −1 . © 2018 Elsevier Ltd",
journal = "Electrochimica Acta",
title = "Corrigendum to “Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: Pseudocapacitance versus electrical double layer” [Electrochim. Acta 298 (2019) 541–551]",
volume = "310",
pages = "221",
doi = "10.1016/j.electacta.2019.04.108"
}
Zdolšek, N., Rocha, R. P., Krstić, J. B., Trtić-Petrović, T. M., Šljukić, B., Figueiredo, J. L.,& Vujković, M.. (2019). Corrigendum to “Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: Pseudocapacitance versus electrical double layer” [Electrochim. Acta 298 (2019) 541–551]. in Electrochimica Acta, 310, 221.
https://doi.org/10.1016/j.electacta.2019.04.108
Zdolšek N, Rocha RP, Krstić JB, Trtić-Petrović TM, Šljukić B, Figueiredo JL, Vujković M. Corrigendum to “Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: Pseudocapacitance versus electrical double layer” [Electrochim. Acta 298 (2019) 541–551]. in Electrochimica Acta. 2019;310:221.
doi:10.1016/j.electacta.2019.04.108 .
Zdolšek, Nikola, Rocha, Raquel P., Krstić, Jugoslav B., Trtić-Petrović, Tatjana M., Šljukić, Biljana, Figueiredo, José L., Vujković, Milica, "Corrigendum to “Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: Pseudocapacitance versus electrical double layer” [Electrochim. Acta 298 (2019) 541–551]" in Electrochimica Acta, 310 (2019):221,
https://doi.org/10.1016/j.electacta.2019.04.108 . .

Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents

Dimitrijević, Aleksandra; Jocić, Ana; Zec, Nebojša; Tot, Aleksandar; Papović, Snežana; Gadžurić, Slobodan; Vraneš, Milan; Trtić-Petrović, Tatjana M.

(2019)

TY  - JOUR
AU  - Dimitrijević, Aleksandra
AU  - Jocić, Ana
AU  - Zec, Nebojša
AU  - Tot, Aleksandar
AU  - Papović, Snežana
AU  - Gadžurić, Slobodan
AU  - Vraneš, Milan
AU  - Trtić-Petrović, Tatjana M.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8168
AB  - The novel aqueous biphasic systems based on symmetric imidazolium ionic liquids (IL-ABSs)for the extraction of toxic and resistive dyes from water was studied. The cation symmetricity of ILs strongly influence the outstanding ability of 1,3-dibutylimidazolium dicyanamide, [bbim][dca], to generate ABS with the exceptionally low amount of eco-friendly citrate salt. A remarkable potential of [bbim][dca]/citrate based ABS to remove Orange II from wastewater with concentration up to 1000 fold and efficiency above 99.4% in a single step was achieved. The improved safety of proposed method nominates it as promising future strategy for pollution prevention.
T2  - Journal of Industrial and Engineering Chemistry
T1  - Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents
VL  - 76
SP  - 500
EP  - 507
DO  - 10.1016/j.jiec.2019.04.017
ER  - 
@article{
author = "Dimitrijević, Aleksandra and Jocić, Ana and Zec, Nebojša and Tot, Aleksandar and Papović, Snežana and Gadžurić, Slobodan and Vraneš, Milan and Trtić-Petrović, Tatjana M.",
year = "2019",
abstract = "The novel aqueous biphasic systems based on symmetric imidazolium ionic liquids (IL-ABSs)for the extraction of toxic and resistive dyes from water was studied. The cation symmetricity of ILs strongly influence the outstanding ability of 1,3-dibutylimidazolium dicyanamide, [bbim][dca], to generate ABS with the exceptionally low amount of eco-friendly citrate salt. A remarkable potential of [bbim][dca]/citrate based ABS to remove Orange II from wastewater with concentration up to 1000 fold and efficiency above 99.4% in a single step was achieved. The improved safety of proposed method nominates it as promising future strategy for pollution prevention.",
journal = "Journal of Industrial and Engineering Chemistry",
title = "Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents",
volume = "76",
pages = "500-507",
doi = "10.1016/j.jiec.2019.04.017"
}
Dimitrijević, A., Jocić, A., Zec, N., Tot, A., Papović, S., Gadžurić, S., Vraneš, M.,& Trtić-Petrović, T. M.. (2019). Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents. in Journal of Industrial and Engineering Chemistry, 76, 500-507.
https://doi.org/10.1016/j.jiec.2019.04.017
Dimitrijević A, Jocić A, Zec N, Tot A, Papović S, Gadžurić S, Vraneš M, Trtić-Petrović TM. Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents. in Journal of Industrial and Engineering Chemistry. 2019;76:500-507.
doi:10.1016/j.jiec.2019.04.017 .
Dimitrijević, Aleksandra, Jocić, Ana, Zec, Nebojša, Tot, Aleksandar, Papović, Snežana, Gadžurić, Slobodan, Vraneš, Milan, Trtić-Petrović, Tatjana M., "Improved single-step extraction performance of aqueous biphasic systems using novel symmetric ionic liquids for the decolorisation of toxic dye effluents" in Journal of Industrial and Engineering Chemistry, 76 (2019):500-507,
https://doi.org/10.1016/j.jiec.2019.04.017 . .
23
7
23

Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction

Zdolšek, Nikola; Dimitrijević, Aleksandra; Bendova, Magdalena; Krstić, Jugoslav B.; Rocha, Raquel P.; Figueiredo, Jose L.; Bajuk-Bogdanović, Danica V.; Trtić-Petrović, Tatjana M.; Šljukić, Biljana

(2018)

TY  - JOUR
AU  - Zdolšek, Nikola
AU  - Dimitrijević, Aleksandra
AU  - Bendova, Magdalena
AU  - Krstić, Jugoslav B.
AU  - Rocha, Raquel P.
AU  - Figueiredo, Jose L.
AU  - Bajuk-Bogdanović, Danica V.
AU  - Trtić-Petrović, Tatjana M.
AU  - Šljukić, Biljana
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9881
AB  - Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon-based materials were prepared by using ionic-liquid-based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one-step method using [bmim][MeSO3] as the precursor for N- and S-doped porous carbon (Carb-IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb-IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, opening the possibility for its application in fuel cells.
T2  - ChemElectroChem
T1  - Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction
VL  - 5
IS  - 7
SP  - 1037
EP  - 1046
DO  - 10.1002/celc.201701369
ER  - 
@article{
author = "Zdolšek, Nikola and Dimitrijević, Aleksandra and Bendova, Magdalena and Krstić, Jugoslav B. and Rocha, Raquel P. and Figueiredo, Jose L. and Bajuk-Bogdanović, Danica V. and Trtić-Petrović, Tatjana M. and Šljukić, Biljana",
year = "2018",
abstract = "Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon-based materials were prepared by using ionic-liquid-based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one-step method using [bmim][MeSO3] as the precursor for N- and S-doped porous carbon (Carb-IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb-IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, opening the possibility for its application in fuel cells.",
journal = "ChemElectroChem",
title = "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction",
volume = "5",
number = "7",
pages = "1037-1046",
doi = "10.1002/celc.201701369"
}
Zdolšek, N., Dimitrijević, A., Bendova, M., Krstić, J. B., Rocha, R. P., Figueiredo, J. L., Bajuk-Bogdanović, D. V., Trtić-Petrović, T. M.,& Šljukić, B.. (2018). Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in ChemElectroChem, 5(7), 1037-1046.
https://doi.org/10.1002/celc.201701369
Zdolšek N, Dimitrijević A, Bendova M, Krstić JB, Rocha RP, Figueiredo JL, Bajuk-Bogdanović DV, Trtić-Petrović TM, Šljukić B. Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in ChemElectroChem. 2018;5(7):1037-1046.
doi:10.1002/celc.201701369 .
Zdolšek, Nikola, Dimitrijević, Aleksandra, Bendova, Magdalena, Krstić, Jugoslav B., Rocha, Raquel P., Figueiredo, Jose L., Bajuk-Bogdanović, Danica V., Trtić-Petrović, Tatjana M., Šljukić, Biljana, "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction" in ChemElectroChem, 5, no. 7 (2018):1037-1046,
https://doi.org/10.1002/celc.201701369 . .
1
22
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22

Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions

Zec, Nebojša; Vraneš, Milan; Bešter-Rogač, Marija; Trtić-Petrović, Tatjana M.; Dimitrijević, Aleksandra; Čobanov, Isidora; Gadžurić, Slobodan

(2018)

TY  - JOUR
AU  - Zec, Nebojša
AU  - Vraneš, Milan
AU  - Bešter-Rogač, Marija
AU  - Trtić-Petrović, Tatjana M.
AU  - Dimitrijević, Aleksandra
AU  - Čobanov, Isidora
AU  - Gadžurić, Slobodan
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7660
AB  - In this manuscript eight new 1,3-dialkylimidazolium bromide ionic liquids, {[}CnCmim]{[}Br], were synthesized and characterized. Densities of ionic liquids and their diluted aqueous solutions have been measured over the whole composition range at selected temperatures from (293.15 to 323.15) K and at atmospheric pressure (p = 0.1 MPa). Influence of alkyl chain length and cation symmetry on densities and volumetric properties as well as nature of the interactions in aqueous {[}CnCmim]{[}Br] solutions have been discussed and compared with previously published aqueous {[}C(2)C(4)im]{[}Br] system. Densities of pure bromide based ionic liquids decrease with increasing alkyl chain length on imidazolium cation and depend on total number of methyl group in both side alkyl chains. Apparent molar volumes at infinite dilution of investigated ionic liquids in water increase linearly with increase of the total number of the C atoms in the side alkyl chain. (C) 2018 Elsevier Ltd.
T2  - The Journal of Chemical Thermodynamics
T1  - Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions
VL  - 121
SP  - 72
EP  - 78
DO  - 10.1016/j.jct.2018.02.001
ER  - 
@article{
author = "Zec, Nebojša and Vraneš, Milan and Bešter-Rogač, Marija and Trtić-Petrović, Tatjana M. and Dimitrijević, Aleksandra and Čobanov, Isidora and Gadžurić, Slobodan",
year = "2018",
abstract = "In this manuscript eight new 1,3-dialkylimidazolium bromide ionic liquids, {[}CnCmim]{[}Br], were synthesized and characterized. Densities of ionic liquids and their diluted aqueous solutions have been measured over the whole composition range at selected temperatures from (293.15 to 323.15) K and at atmospheric pressure (p = 0.1 MPa). Influence of alkyl chain length and cation symmetry on densities and volumetric properties as well as nature of the interactions in aqueous {[}CnCmim]{[}Br] solutions have been discussed and compared with previously published aqueous {[}C(2)C(4)im]{[}Br] system. Densities of pure bromide based ionic liquids decrease with increasing alkyl chain length on imidazolium cation and depend on total number of methyl group in both side alkyl chains. Apparent molar volumes at infinite dilution of investigated ionic liquids in water increase linearly with increase of the total number of the C atoms in the side alkyl chain. (C) 2018 Elsevier Ltd.",
journal = "The Journal of Chemical Thermodynamics",
title = "Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions",
volume = "121",
pages = "72-78",
doi = "10.1016/j.jct.2018.02.001"
}
Zec, N., Vraneš, M., Bešter-Rogač, M., Trtić-Petrović, T. M., Dimitrijević, A., Čobanov, I.,& Gadžurić, S.. (2018). Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions. in The Journal of Chemical Thermodynamics, 121, 72-78.
https://doi.org/10.1016/j.jct.2018.02.001
Zec N, Vraneš M, Bešter-Rogač M, Trtić-Petrović TM, Dimitrijević A, Čobanov I, Gadžurić S. Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions. in The Journal of Chemical Thermodynamics. 2018;121:72-78.
doi:10.1016/j.jct.2018.02.001 .
Zec, Nebojša, Vraneš, Milan, Bešter-Rogač, Marija, Trtić-Petrović, Tatjana M., Dimitrijević, Aleksandra, Čobanov, Isidora, Gadžurić, Slobodan, "Influence of the alkyl chain length on densities and volumetric properties of 1,3-dialkylimidazolium bromide ionic liquids and their aqueous solutions" in The Journal of Chemical Thermodynamics, 121 (2018):72-78,
https://doi.org/10.1016/j.jct.2018.02.001 . .
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17

Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction

Zdolšek, Nikola; Dimitrijević, Aleksandra; Bendova, Magdalena; Krstić, Jugoslav B.; Rocha, Raquel P.; Figueiredo, Jose L.; Bajuk-Bogdanović, Danica V.; Trtić-Petrović, Tatjana M.; Šljukić, Biljana

(2018)

TY  - JOUR
AU  - Zdolšek, Nikola
AU  - Dimitrijević, Aleksandra
AU  - Bendova, Magdalena
AU  - Krstić, Jugoslav B.
AU  - Rocha, Raquel P.
AU  - Figueiredo, Jose L.
AU  - Bajuk-Bogdanović, Danica V.
AU  - Trtić-Petrović, Tatjana M.
AU  - Šljukić, Biljana
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7672
AB  - Carbon materials, prepared by using different methods with ionicliquids, are compared as electrocatalysts for the oxygen reductionreaction (ORR). Materials were synthesized through the hydrothermalcarbonization of glucose and by using the same method in the presence of1-butyl-3-methylimidazolium methanesulfonate {[}bmim]{[}MeSO3] as anadditive. Another two carbon-based materials were prepared by usingionic-liquid-based methods: ionothermal carbonization of glucose using{[}bmim]{[}MeSO3] as a recyclable medium for the carbonization reactionand by direct carbonization of the ionic liquid in a one-step methodusing {[}bmim]{[}MeSO3] as the precursor for N- and S-doped porouscarbon (Carb-IL). Characterization results showed the possibility ofmorphology and porosity control by using {[}bmim]{[}MeSO3]. Allmaterials were subsequently tested for the ORR in alkaline media.Carb-IL showed enhanced and stable electrocatalytic ORR activity, evenin the presence of methanol, ethanol, and borohydride, opening thepossibility for its application in fuel cells.
T2  - ChemElectroChem
T1  - Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction
VL  - 5
IS  - 7
SP  - 1037
EP  - 1046
DO  - 10.1002/celc.201701369
ER  - 
@article{
author = "Zdolšek, Nikola and Dimitrijević, Aleksandra and Bendova, Magdalena and Krstić, Jugoslav B. and Rocha, Raquel P. and Figueiredo, Jose L. and Bajuk-Bogdanović, Danica V. and Trtić-Petrović, Tatjana M. and Šljukić, Biljana",
year = "2018",
abstract = "Carbon materials, prepared by using different methods with ionicliquids, are compared as electrocatalysts for the oxygen reductionreaction (ORR). Materials were synthesized through the hydrothermalcarbonization of glucose and by using the same method in the presence of1-butyl-3-methylimidazolium methanesulfonate {[}bmim]{[}MeSO3] as anadditive. Another two carbon-based materials were prepared by usingionic-liquid-based methods: ionothermal carbonization of glucose using{[}bmim]{[}MeSO3] as a recyclable medium for the carbonization reactionand by direct carbonization of the ionic liquid in a one-step methodusing {[}bmim]{[}MeSO3] as the precursor for N- and S-doped porouscarbon (Carb-IL). Characterization results showed the possibility ofmorphology and porosity control by using {[}bmim]{[}MeSO3]. Allmaterials were subsequently tested for the ORR in alkaline media.Carb-IL showed enhanced and stable electrocatalytic ORR activity, evenin the presence of methanol, ethanol, and borohydride, opening thepossibility for its application in fuel cells.",
journal = "ChemElectroChem",
title = "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction",
volume = "5",
number = "7",
pages = "1037-1046",
doi = "10.1002/celc.201701369"
}
Zdolšek, N., Dimitrijević, A., Bendova, M., Krstić, J. B., Rocha, R. P., Figueiredo, J. L., Bajuk-Bogdanović, D. V., Trtić-Petrović, T. M.,& Šljukić, B.. (2018). Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in ChemElectroChem, 5(7), 1037-1046.
https://doi.org/10.1002/celc.201701369
Zdolšek N, Dimitrijević A, Bendova M, Krstić JB, Rocha RP, Figueiredo JL, Bajuk-Bogdanović DV, Trtić-Petrović TM, Šljukić B. Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in ChemElectroChem. 2018;5(7):1037-1046.
doi:10.1002/celc.201701369 .
Zdolšek, Nikola, Dimitrijević, Aleksandra, Bendova, Magdalena, Krstić, Jugoslav B., Rocha, Raquel P., Figueiredo, Jose L., Bajuk-Bogdanović, Danica V., Trtić-Petrović, Tatjana M., Šljukić, Biljana, "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction" in ChemElectroChem, 5, no. 7 (2018):1037-1046,
https://doi.org/10.1002/celc.201701369 . .
1
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22

The Targeted Pesticides as Acetylcholinesterase Inhibitors: Comprehensive Cross-Organism Molecular Modelling Studies Performed to Anticipate the Pharmacology of Harmfulness to Humans In Vitro

Mladenović, Milan P.; Arsić, Biljana; Stanković, Nevena M.; Mihović, Nezrina; Ragno, Rino; Regan, Andrew C.; Milićević, Jelena S.; Trtić-Petrović, Tatjana M.; Micić, Ružica J.

(2018)

TY  - JOUR
AU  - Mladenović, Milan P.
AU  - Arsić, Biljana
AU  - Stanković, Nevena M.
AU  - Mihović, Nezrina
AU  - Ragno, Rino
AU  - Regan, Andrew C.
AU  - Milićević, Jelena S.
AU  - Trtić-Petrović, Tatjana M.
AU  - Micić, Ružica J.
PY  - 2018
UR  - http://www.mdpi.com/1420-3049/23/9/2192
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7862
AB  - Commercially available pesticides were examined as Mus musculus and Homo sapiens acetylcholinesterase (mAChE and hAChE) inhibitors by means of ligand-based (LB) and structure-based (SB) in silico approaches. Initially, the crystal structures of simazine, monocrotophos, dimethoate, and acetamiprid were reproduced using various force fields. Subsequently, LB alignment rules were assessed and applied to determine the inter synaptic conformations of atrazine, propazine, carbofuran, carbaryl, tebufenozide, imidacloprid, diuron, monuron, and linuron. Afterwards, molecular docking and dynamics SB studies were performed on either mAChE or hAChE, to predict the listed pesticides’ binding modes. Calculated energies of global minima (Eglob_min) and free energies of binding (∆Gbinding) were correlated with the pesticides’ acute toxicities (i.e., the LD50 values) against mice, as well to generate the model that could predict the LD50s against humans. Although for most of the pesticides the low Eglob_min correlates with the high acute toxicity, it is the ∆Gbinding that conditions the LD50 values for all the evaluated pesticides. Derived pLD50 = f(∆Gbinding) mAChE model may predict the pLD50 against hAChE, too. The hAChE inhibition by atrazine, propazine, and simazine (the most toxic pesticides) was elucidated by SB quantum mechanics (QM) DFT mechanistic and concentration-dependent kinetic studies, enriching the knowledge for design of less toxic pesticides.
T2  - Molecules
T1  - The Targeted Pesticides as Acetylcholinesterase Inhibitors: Comprehensive Cross-Organism Molecular Modelling Studies Performed to Anticipate the Pharmacology of Harmfulness to Humans In Vitro
VL  - 23
IS  - 9
SP  - 2192
DO  - 10.3390/molecules23092192
ER  - 
@article{
author = "Mladenović, Milan P. and Arsić, Biljana and Stanković, Nevena M. and Mihović, Nezrina and Ragno, Rino and Regan, Andrew C. and Milićević, Jelena S. and Trtić-Petrović, Tatjana M. and Micić, Ružica J.",
year = "2018",
abstract = "Commercially available pesticides were examined as Mus musculus and Homo sapiens acetylcholinesterase (mAChE and hAChE) inhibitors by means of ligand-based (LB) and structure-based (SB) in silico approaches. Initially, the crystal structures of simazine, monocrotophos, dimethoate, and acetamiprid were reproduced using various force fields. Subsequently, LB alignment rules were assessed and applied to determine the inter synaptic conformations of atrazine, propazine, carbofuran, carbaryl, tebufenozide, imidacloprid, diuron, monuron, and linuron. Afterwards, molecular docking and dynamics SB studies were performed on either mAChE or hAChE, to predict the listed pesticides’ binding modes. Calculated energies of global minima (Eglob_min) and free energies of binding (∆Gbinding) were correlated with the pesticides’ acute toxicities (i.e., the LD50 values) against mice, as well to generate the model that could predict the LD50s against humans. Although for most of the pesticides the low Eglob_min correlates with the high acute toxicity, it is the ∆Gbinding that conditions the LD50 values for all the evaluated pesticides. Derived pLD50 = f(∆Gbinding) mAChE model may predict the pLD50 against hAChE, too. The hAChE inhibition by atrazine, propazine, and simazine (the most toxic pesticides) was elucidated by SB quantum mechanics (QM) DFT mechanistic and concentration-dependent kinetic studies, enriching the knowledge for design of less toxic pesticides.",
journal = "Molecules",
title = "The Targeted Pesticides as Acetylcholinesterase Inhibitors: Comprehensive Cross-Organism Molecular Modelling Studies Performed to Anticipate the Pharmacology of Harmfulness to Humans In Vitro",
volume = "23",
number = "9",
pages = "2192",
doi = "10.3390/molecules23092192"
}
Mladenović, M. P., Arsić, B., Stanković, N. M., Mihović, N., Ragno, R., Regan, A. C., Milićević, J. S., Trtić-Petrović, T. M.,& Micić, R. J.. (2018). The Targeted Pesticides as Acetylcholinesterase Inhibitors: Comprehensive Cross-Organism Molecular Modelling Studies Performed to Anticipate the Pharmacology of Harmfulness to Humans In Vitro. in Molecules, 23(9), 2192.
https://doi.org/10.3390/molecules23092192
Mladenović MP, Arsić B, Stanković NM, Mihović N, Ragno R, Regan AC, Milićević JS, Trtić-Petrović TM, Micić RJ. The Targeted Pesticides as Acetylcholinesterase Inhibitors: Comprehensive Cross-Organism Molecular Modelling Studies Performed to Anticipate the Pharmacology of Harmfulness to Humans In Vitro. in Molecules. 2018;23(9):2192.
doi:10.3390/molecules23092192 .
Mladenović, Milan P., Arsić, Biljana, Stanković, Nevena M., Mihović, Nezrina, Ragno, Rino, Regan, Andrew C., Milićević, Jelena S., Trtić-Petrović, Tatjana M., Micić, Ružica J., "The Targeted Pesticides as Acetylcholinesterase Inhibitors: Comprehensive Cross-Organism Molecular Modelling Studies Performed to Anticipate the Pharmacology of Harmfulness to Humans In Vitro" in Molecules, 23, no. 9 (2018):2192,
https://doi.org/10.3390/molecules23092192 . .
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33

New sample preparation method based on task-specific ionic liquids for extraction and determination of copper in urine and wastewater

Trtić-Petrović, Tatjana M.; Dimitrijević, Aleksandra; Zdolšek, Nikola; Đorđević, Jelena S.; Tot, Aleksandar; Vraneš, Milan; Gadžurić, Slobodan

(2018)

TY  - JOUR
AU  - Trtić-Petrović, Tatjana M.
AU  - Dimitrijević, Aleksandra
AU  - Zdolšek, Nikola
AU  - Đorđević, Jelena S.
AU  - Tot, Aleksandar
AU  - Vraneš, Milan
AU  - Gadžurić, Slobodan
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1891
AB  - In this study, four hydrophilic ionic liquids (ILs) containing 1-alkyl-3-methylimidazolim cation and either salicylate or chloride anions were synthetized and studied as new task-specific ionic liquids (TSILs) suitable for aqueous biphasic system (ABS) formation and selective one-step extraction of copper(II). TSILs are designed so that the anion is responsible for forming the complex with metal(II) and preventing hydrolysis of metal cations at very strong alkaline pH, whereas the cation is responsible for selective extraction of metal(II)-salicylate complexes. It was found that 1-butyl-3-methylimidazolium salicylate could be used for selective extraction of Cu(II) in the presence of Zn(II), Cd(II), and Pb(II) at very alkaline solution without metal hydroxide formation. It was assumed that formation of metal(II)-salicylate complexes prevents the hydrolysis of the metal ions in alkaline solutions. The determined stability constants for Cu(II)-salicylate complexes, where salicylate was derived from different ionic liquids, indicated that there was no significant influence of the cation of the ionic liquid on the stability of the complexes. The ABS based on 1-butyl-3-methylimidazolium salicylate has been applied as the sample preparation step prior to voltammetric determination of Cu(II). The effect of volume of aqueous sample and IL and extraction time were investigated and optimum extraction conditions were determined. The obtained detection limits were 8 ng dm(-3). The optimized method was applied for the determination of Cu(II) in tap water, wastewater, and urine. The study indicated that application of the ABS based on 1-butyl-3-methylimidazolium salicylate ionic liquid could be successfully applied as the sample preparation method for the determination of Cu(II) from various environmental samples.
T2  - Analytical and Bioanalytical Chemistry
T1  - New sample preparation method based on task-specific ionic liquids for extraction and determination of copper in urine and wastewater
VL  - 410
IS  - 1
SP  - 155
EP  - 166
DO  - 10.1007/s00216-017-0705-z
ER  - 
@article{
author = "Trtić-Petrović, Tatjana M. and Dimitrijević, Aleksandra and Zdolšek, Nikola and Đorđević, Jelena S. and Tot, Aleksandar and Vraneš, Milan and Gadžurić, Slobodan",
year = "2018",
abstract = "In this study, four hydrophilic ionic liquids (ILs) containing 1-alkyl-3-methylimidazolim cation and either salicylate or chloride anions were synthetized and studied as new task-specific ionic liquids (TSILs) suitable for aqueous biphasic system (ABS) formation and selective one-step extraction of copper(II). TSILs are designed so that the anion is responsible for forming the complex with metal(II) and preventing hydrolysis of metal cations at very strong alkaline pH, whereas the cation is responsible for selective extraction of metal(II)-salicylate complexes. It was found that 1-butyl-3-methylimidazolium salicylate could be used for selective extraction of Cu(II) in the presence of Zn(II), Cd(II), and Pb(II) at very alkaline solution without metal hydroxide formation. It was assumed that formation of metal(II)-salicylate complexes prevents the hydrolysis of the metal ions in alkaline solutions. The determined stability constants for Cu(II)-salicylate complexes, where salicylate was derived from different ionic liquids, indicated that there was no significant influence of the cation of the ionic liquid on the stability of the complexes. The ABS based on 1-butyl-3-methylimidazolium salicylate has been applied as the sample preparation step prior to voltammetric determination of Cu(II). The effect of volume of aqueous sample and IL and extraction time were investigated and optimum extraction conditions were determined. The obtained detection limits were 8 ng dm(-3). The optimized method was applied for the determination of Cu(II) in tap water, wastewater, and urine. The study indicated that application of the ABS based on 1-butyl-3-methylimidazolium salicylate ionic liquid could be successfully applied as the sample preparation method for the determination of Cu(II) from various environmental samples.",
journal = "Analytical and Bioanalytical Chemistry",
title = "New sample preparation method based on task-specific ionic liquids for extraction and determination of copper in urine and wastewater",
volume = "410",
number = "1",
pages = "155-166",
doi = "10.1007/s00216-017-0705-z"
}
Trtić-Petrović, T. M., Dimitrijević, A., Zdolšek, N., Đorđević, J. S., Tot, A., Vraneš, M.,& Gadžurić, S.. (2018). New sample preparation method based on task-specific ionic liquids for extraction and determination of copper in urine and wastewater. in Analytical and Bioanalytical Chemistry, 410(1), 155-166.
https://doi.org/10.1007/s00216-017-0705-z
Trtić-Petrović TM, Dimitrijević A, Zdolšek N, Đorđević JS, Tot A, Vraneš M, Gadžurić S. New sample preparation method based on task-specific ionic liquids for extraction and determination of copper in urine and wastewater. in Analytical and Bioanalytical Chemistry. 2018;410(1):155-166.
doi:10.1007/s00216-017-0705-z .
Trtić-Petrović, Tatjana M., Dimitrijević, Aleksandra, Zdolšek, Nikola, Đorđević, Jelena S., Tot, Aleksandar, Vraneš, Milan, Gadžurić, Slobodan, "New sample preparation method based on task-specific ionic liquids for extraction and determination of copper in urine and wastewater" in Analytical and Bioanalytical Chemistry, 410, no. 1 (2018):155-166,
https://doi.org/10.1007/s00216-017-0705-z . .
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