@article{
author = "Marković, Bojana M. and Maksin, Danijela D. and Mojovic, Zorica D. and Vuković, Zorica M. and Nastasović, Aleksandra B. and Jovanovic, Dusan M.",
year = "2017",
abstract = "In this study, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) was synthesized by suspension copolymerization, functionalized by ring-opening reaction of the pendant epoxy groups with diethylene triamine and used for immobilization of Pd(II) ions from chloride and nitrate solutions under batch experimental condition. The amino-functionalized sample and samples with immobilized Pd(II) ions were characterized by Fourier transform infrared spectroscopy (FTIR) analysis and scanning energy-dispersive X-ray spectroscopy (SEM-EDX). The electrochemical behavior of electrodes composed of synthesized samples was tested in 0.1 M H2SO4 by means of cyclic voltammetry (CV). The shape of recorded CV showed dependence on the type of Pd-salt used for Pd immobilization. The reaction of oxidation of 4-chlorophenol (4-CP) from 0.1 M H2SO4 at investigated samples was also studied. Electrooxidation of 4-CP resulted in passivation and formation of reversible hydroquinone/benzoquinone on both investigated electrodes, although hydroquinone/benzoquinone formation was more pronounced on Pd immobilized from nitrite solution. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Journal of Electroanalytical Chemistry",
title = "Electrochemical behavior of palladium modified amino-functionalized macroporous copolymer",
volume = "786",
pages = "94-101",
doi = "10.1016/j.jelechem.2017.01.018"
}