Anđelković, Katarina

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orcid::0000-0003-1178-8326
  • Anđelković, Katarina (17)
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Author's Bibliography

Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines

Dimitrijević, Teodora; Novaković, Irena T.; Radanović, Dušanka D.; Novaković, Slađana B.; Rodić, Marko V.; Anđelković, Katarina; Šumar-Ristović, Maja

(2020)

TY  - JOUR
AU  - Dimitrijević, Teodora
AU  - Novaković, Irena T.
AU  - Radanović, Dušanka D.
AU  - Novaković, Slađana B.
AU  - Rodić, Marko V.
AU  - Anđelković, Katarina
AU  - Šumar-Ristović, Maja
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8908
AB  - In this article, synthesis, spectral and X-ray structure characterization, antimicrobial activity and Brine shrimp test of two new Cu(II) complexes with a salicylaldehyde derivative have been reported. Complexes [Cu(L)(bipy)]BF4·0.5H2O and [Cu2(L)2(phen)2](BF4)2 were obtained in the reaction of Cu(BF4)2·6H2O, deprotonated 4-(diethylamino)−2-hydroxybenzaldehyde ligand (L) and α-diimine (2,2’-bipyridine or 1,10-phenanthroline). The complex with bipyridine is mononuclear, containing one L and one bipyridine ligand in a distorted square-planar cation with a BF4 − anion and lattice water molecule, whereas the complex with phenanthroline is a dinuclear centrosymmetric dimeric cation, containing two L ligands along with two phenanthroline ligands and BF4 − anions. The coordination geometry of each Cu(II) ion can be described as an elongated square pyramid. MS-ESI spectroscopy indicated that [Cu2(L)2(phen)2](BF4)2 is mononuclear in DMSO solution. In vitro antibacterial and antifungal activity was tested against four Gram-positive, four Gram-negative bacteria and three fungal strains. Complexes showed significantly stronger antibacterial activities than parent ligands. The mononuclear phenanthroline complex in solution showed very good antimicrobial activity, which is comparable to the activity of the standard antibiotic amikacin against all tested bacterial strains. The same complex has better antifungal activity than fluconazole, which was used as a standard. Results of the brine shrimp test indicate that both complexes have good toxicity against Artemia nauplii.
T2  - Journal of Coordination Chemistry
T1  - Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines
VL  - 73
IS  - 4
SP  - 702
EP  - 716
DO  - 10.1080/00958972.2020.1740212
ER  - 
@article{
author = "Dimitrijević, Teodora and Novaković, Irena T. and Radanović, Dušanka D. and Novaković, Slađana B. and Rodić, Marko V. and Anđelković, Katarina and Šumar-Ristović, Maja",
year = "2020",
abstract = "In this article, synthesis, spectral and X-ray structure characterization, antimicrobial activity and Brine shrimp test of two new Cu(II) complexes with a salicylaldehyde derivative have been reported. Complexes [Cu(L)(bipy)]BF4·0.5H2O and [Cu2(L)2(phen)2](BF4)2 were obtained in the reaction of Cu(BF4)2·6H2O, deprotonated 4-(diethylamino)−2-hydroxybenzaldehyde ligand (L) and α-diimine (2,2’-bipyridine or 1,10-phenanthroline). The complex with bipyridine is mononuclear, containing one L and one bipyridine ligand in a distorted square-planar cation with a BF4 − anion and lattice water molecule, whereas the complex with phenanthroline is a dinuclear centrosymmetric dimeric cation, containing two L ligands along with two phenanthroline ligands and BF4 − anions. The coordination geometry of each Cu(II) ion can be described as an elongated square pyramid. MS-ESI spectroscopy indicated that [Cu2(L)2(phen)2](BF4)2 is mononuclear in DMSO solution. In vitro antibacterial and antifungal activity was tested against four Gram-positive, four Gram-negative bacteria and three fungal strains. Complexes showed significantly stronger antibacterial activities than parent ligands. The mononuclear phenanthroline complex in solution showed very good antimicrobial activity, which is comparable to the activity of the standard antibiotic amikacin against all tested bacterial strains. The same complex has better antifungal activity than fluconazole, which was used as a standard. Results of the brine shrimp test indicate that both complexes have good toxicity against Artemia nauplii.",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines",
volume = "73",
number = "4",
pages = "702-716",
doi = "10.1080/00958972.2020.1740212"
}
Dimitrijević, T., Novaković, I. T., Radanović, D. D., Novaković, S. B., Rodić, M. V., Anđelković, K.,& Šumar-Ristović, M.. (2020). Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines. in Journal of Coordination Chemistry, 73(4), 702-716.
https://doi.org/10.1080/00958972.2020.1740212
Dimitrijević T, Novaković IT, Radanović DD, Novaković SB, Rodić MV, Anđelković K, Šumar-Ristović M. Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines. in Journal of Coordination Chemistry. 2020;73(4):702-716.
doi:10.1080/00958972.2020.1740212 .
Dimitrijević, Teodora, Novaković, Irena T., Radanović, Dušanka D., Novaković, Slađana B., Rodić, Marko V., Anđelković, Katarina, Šumar-Ristović, Maja, "Synthesis, spectral and structural characterization and biological activity of Cu(II) complexes with 4-(diethylamino)salicylaldehyde and α-diimines" in Journal of Coordination Chemistry, 73, no. 4 (2020):702-716,
https://doi.org/10.1080/00958972.2020.1740212 . .
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Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone

Darmanović, Darinka; Shcherbakov, Igor N.; Duboc, Carole; Spasojević, Vojislav; Hanžel, Darko; Anđelković, Katarina; Radanović, Dušanka D.; Turel, Iztok; Milenković, Milica R.; Gruden, Maja; Čobeljić, Božidar; Zlatar, Matija

(2019)

TY  - JOUR
AU  - Darmanović, Darinka
AU  - Shcherbakov, Igor N.
AU  - Duboc, Carole
AU  - Spasojević, Vojislav
AU  - Hanžel, Darko
AU  - Anđelković, Katarina
AU  - Radanović, Dušanka D.
AU  - Turel, Iztok
AU  - Milenković, Milica R.
AU  - Gruden, Maja
AU  - Čobeljić, Božidar
AU  - Zlatar, Matija
PY  - 2019
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/3855
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8751
AB  - Magnetic anisotropy in pentagonal bipyramidal complexes of Co(II) (1 and 2), Fe(III) (3 and 4), and Ni(II) (5) with a 2,2′-[2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)]bis[N,N,N-trimethyl-2-oxoethanaminium] equatorial ligand and isothiocyanato axial ligands has been investigated by magnetic susceptibility measurements, powder X-band electron paramagnetic resonance (EPR) spectroscopy, Mössbauer spectroscopy, ab initio, and ligand-field density functional theory (LFDFT) calculations. The studied complexes display three distinct types of magnetic anisotropy. Co(II) complexes (1 and 2) show an easy plane anisotropy with large and positive D values and negligible rhombicity. The Ni(II) complex (5) has uniaxial magnetic anisotropy with a negative D value. Fe(III) complexes (3 and 4) have small zero-field splitting (ZFS) parameters. Theoretical modeling is used to rationalize the magnetic anisotropy in these systems and to identify the most important excited states that are responsible for the zero-field splitting. These excitations are a consequence of the electronic structure of the central metal ion in ideal pentagonal bipyramidal coordination.
T2  - The Journal of Physical Chemistry C
T1  - Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone
VL  - 123
IS  - 51
SP  - 31142
EP  - 31155
DO  - 10.1021/acs.jpcc.9b08066
ER  - 
@article{
author = "Darmanović, Darinka and Shcherbakov, Igor N. and Duboc, Carole and Spasojević, Vojislav and Hanžel, Darko and Anđelković, Katarina and Radanović, Dušanka D. and Turel, Iztok and Milenković, Milica R. and Gruden, Maja and Čobeljić, Božidar and Zlatar, Matija",
year = "2019",
abstract = "Magnetic anisotropy in pentagonal bipyramidal complexes of Co(II) (1 and 2), Fe(III) (3 and 4), and Ni(II) (5) with a 2,2′-[2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)]bis[N,N,N-trimethyl-2-oxoethanaminium] equatorial ligand and isothiocyanato axial ligands has been investigated by magnetic susceptibility measurements, powder X-band electron paramagnetic resonance (EPR) spectroscopy, Mössbauer spectroscopy, ab initio, and ligand-field density functional theory (LFDFT) calculations. The studied complexes display three distinct types of magnetic anisotropy. Co(II) complexes (1 and 2) show an easy plane anisotropy with large and positive D values and negligible rhombicity. The Ni(II) complex (5) has uniaxial magnetic anisotropy with a negative D value. Fe(III) complexes (3 and 4) have small zero-field splitting (ZFS) parameters. Theoretical modeling is used to rationalize the magnetic anisotropy in these systems and to identify the most important excited states that are responsible for the zero-field splitting. These excitations are a consequence of the electronic structure of the central metal ion in ideal pentagonal bipyramidal coordination.",
journal = "The Journal of Physical Chemistry C",
title = "Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone",
volume = "123",
number = "51",
pages = "31142-31155",
doi = "10.1021/acs.jpcc.9b08066"
}
Darmanović, D., Shcherbakov, I. N., Duboc, C., Spasojević, V., Hanžel, D., Anđelković, K., Radanović, D. D., Turel, I., Milenković, M. R., Gruden, M., Čobeljić, B.,& Zlatar, M.. (2019). Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. in The Journal of Physical Chemistry C, 123(51), 31142-31155.
https://doi.org/10.1021/acs.jpcc.9b08066
Darmanović D, Shcherbakov IN, Duboc C, Spasojević V, Hanžel D, Anđelković K, Radanović DD, Turel I, Milenković MR, Gruden M, Čobeljić B, Zlatar M. Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone. in The Journal of Physical Chemistry C. 2019;123(51):31142-31155.
doi:10.1021/acs.jpcc.9b08066 .
Darmanović, Darinka, Shcherbakov, Igor N., Duboc, Carole, Spasojević, Vojislav, Hanžel, Darko, Anđelković, Katarina, Radanović, Dušanka D., Turel, Iztok, Milenković, Milica R., Gruden, Maja, Čobeljić, Božidar, Zlatar, Matija, "Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone" in The Journal of Physical Chemistry C, 123, no. 51 (2019):31142-31155,
https://doi.org/10.1021/acs.jpcc.9b08066 . .
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Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent

Romanović, Mima Č.; Milenković, Milica R.; Pevec, Andrej; Turel, Iztok; Spasojević, Vojislav; Grubišić, Sonja; Radanović, Dušanka; Anđelković, Katarina; Čobeljić, Božidar

(2018)

TY  - JOUR
AU  - Romanović, Mima Č.
AU  - Milenković, Milica R.
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Spasojević, Vojislav
AU  - Grubišić, Sonja
AU  - Radanović, Dušanka
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1898
AB  - A tridentate NNO condensation product of 2-quinolinecarboxaldehyde and Girards T reagent (HLC1) in the presence of azide ions coordinates with cobalt(II) giving mononuclear azido Co(II) complex [CoHL (N-3)(3)](1) as a main product and dinuclear end-on azido bridged Co(II) complex [Co2L2(mu-(1,1)-N-3)(2)(N-3)(2)] (2) in traces. Crystal structures of both complexes were determined. Variable temperature magnetic susceptibility measurement studies of complex I showed that Co(II) cation is in the low-spin state with t(2g)(6)e(g)(1) (S = 1/2) configuration. DFT-BS calculations for complex 2 anticipated ferromagnetic type interaction between paramagnetic centers (J = 53 cm(-1)). (C) 2017 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent
VL  - 139
SP  - 142
EP  - 147
DO  - 10.1016/j.poly.2017.10.018
ER  - 
@article{
author = "Romanović, Mima Č. and Milenković, Milica R. and Pevec, Andrej and Turel, Iztok and Spasojević, Vojislav and Grubišić, Sonja and Radanović, Dušanka and Anđelković, Katarina and Čobeljić, Božidar",
year = "2018",
abstract = "A tridentate NNO condensation product of 2-quinolinecarboxaldehyde and Girards T reagent (HLC1) in the presence of azide ions coordinates with cobalt(II) giving mononuclear azido Co(II) complex [CoHL (N-3)(3)](1) as a main product and dinuclear end-on azido bridged Co(II) complex [Co2L2(mu-(1,1)-N-3)(2)(N-3)(2)] (2) in traces. Crystal structures of both complexes were determined. Variable temperature magnetic susceptibility measurement studies of complex I showed that Co(II) cation is in the low-spin state with t(2g)(6)e(g)(1) (S = 1/2) configuration. DFT-BS calculations for complex 2 anticipated ferromagnetic type interaction between paramagnetic centers (J = 53 cm(-1)). (C) 2017 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent",
volume = "139",
pages = "142-147",
doi = "10.1016/j.poly.2017.10.018"
}
Romanović, M. Č., Milenković, M. R., Pevec, A., Turel, I., Spasojević, V., Grubišić, S., Radanović, D., Anđelković, K.,& Čobeljić, B.. (2018). Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent. in Polyhedron, 139, 142-147.
https://doi.org/10.1016/j.poly.2017.10.018
Romanović MČ, Milenković MR, Pevec A, Turel I, Spasojević V, Grubišić S, Radanović D, Anđelković K, Čobeljić B. Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent. in Polyhedron. 2018;139:142-147.
doi:10.1016/j.poly.2017.10.018 .
Romanović, Mima Č., Milenković, Milica R., Pevec, Andrej, Turel, Iztok, Spasojević, Vojislav, Grubišić, Sonja, Radanović, Dušanka, Anđelković, Katarina, Čobeljić, Božidar, "Crystal structures, magnetic properties and DFT study of cobalt(II) azido complexes with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent" in Polyhedron, 139 (2018):142-147,
https://doi.org/10.1016/j.poly.2017.10.018 . .
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Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent

Romanović, Mima Č.; Čobeljić, Božidar R.; Pevec, Andrej; Turel, Iztok; Spasojević, Vojislav; Tsaturyan, Arshak A.; Shcherbakov, Igor N.; Anđelković, Katarina; Milenković, Marina; Radanović, Dušanka; Milenković, Milica R.

(2017)

TY  - JOUR
AU  - Romanović, Mima Č.
AU  - Čobeljić, Božidar R.
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Spasojević, Vojislav
AU  - Tsaturyan, Arshak A.
AU  - Shcherbakov, Igor N.
AU  - Anđelković, Katarina
AU  - Milenković, Marina
AU  - Radanović, Dušanka
AU  - Milenković, Milica R.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1566
AB  - A dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girards T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1. (C) 2017 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent
VL  - 128
SP  - 30
EP  - 37
DO  - 10.1016/j.poly.2017.02.039
ER  - 
@article{
author = "Romanović, Mima Č. and Čobeljić, Božidar R. and Pevec, Andrej and Turel, Iztok and Spasojević, Vojislav and Tsaturyan, Arshak A. and Shcherbakov, Igor N. and Anđelković, Katarina and Milenković, Marina and Radanović, Dušanka and Milenković, Milica R.",
year = "2017",
abstract = "A dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girards T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1. (C) 2017 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent",
volume = "128",
pages = "30-37",
doi = "10.1016/j.poly.2017.02.039"
}
Romanović, M. Č., Čobeljić, B. R., Pevec, A., Turel, I., Spasojević, V., Tsaturyan, A. A., Shcherbakov, I. N., Anđelković, K., Milenković, M., Radanović, D.,& Milenković, M. R.. (2017). Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent. in Polyhedron, 128, 30-37.
https://doi.org/10.1016/j.poly.2017.02.039
Romanović MČ, Čobeljić BR, Pevec A, Turel I, Spasojević V, Tsaturyan AA, Shcherbakov IN, Anđelković K, Milenković M, Radanović D, Milenković MR. Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent. in Polyhedron. 2017;128:30-37.
doi:10.1016/j.poly.2017.02.039 .
Romanović, Mima Č., Čobeljić, Božidar R., Pevec, Andrej, Turel, Iztok, Spasojević, Vojislav, Tsaturyan, Arshak A., Shcherbakov, Igor N., Anđelković, Katarina, Milenković, Marina, Radanović, Dušanka, Milenković, Milica R., "Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girards T reagent" in Polyhedron, 128 (2017):30-37,
https://doi.org/10.1016/j.poly.2017.02.039 . .
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Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde

Čobeljić, Božidar; Pevec, Andrej; Stepanovic, Stepan; Spasojević, Vojislav; Milenković, Milica; Turel, Iztok; Swart, Marcel; Gruden-Pavlović, Maja; Adaila, Kawther; Anđelković, Katarina

(2015)

TY  - JOUR
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Stepanovic, Stepan
AU  - Spasojević, Vojislav
AU  - Milenković, Milica
AU  - Turel, Iztok
AU  - Swart, Marcel
AU  - Gruden-Pavlović, Maja
AU  - Adaila, Kawther
AU  - Anđelković, Katarina
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/474
AB  - Octahedral and square-planar isothiocyanato complexes of Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girards T reagent were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. Results of magnetic measurements for octahedral Ni(II) complex were also reported. In all the complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Reaction energetics with both forms of ligand were studied by the means of DFT and results were in complete agreement with experimental observations. Furthermore, ligand field splitting analysis gave the deeper insight in the relationship of the isolated complex coordination environment and protonation of the ligand. (C) 2015 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde
VL  - 89
SP  - 271
EP  - 279
DO  - 10.1016/j.poly.2015.01.024
ER  - 
@article{
author = "Čobeljić, Božidar and Pevec, Andrej and Stepanovic, Stepan and Spasojević, Vojislav and Milenković, Milica and Turel, Iztok and Swart, Marcel and Gruden-Pavlović, Maja and Adaila, Kawther and Anđelković, Katarina",
year = "2015",
abstract = "Octahedral and square-planar isothiocyanato complexes of Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girards T reagent were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. Results of magnetic measurements for octahedral Ni(II) complex were also reported. In all the complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Reaction energetics with both forms of ligand were studied by the means of DFT and results were in complete agreement with experimental observations. Furthermore, ligand field splitting analysis gave the deeper insight in the relationship of the isolated complex coordination environment and protonation of the ligand. (C) 2015 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde",
volume = "89",
pages = "271-279",
doi = "10.1016/j.poly.2015.01.024"
}
Čobeljić, B., Pevec, A., Stepanovic, S., Spasojević, V., Milenković, M., Turel, I., Swart, M., Gruden-Pavlović, M., Adaila, K.,& Anđelković, K.. (2015). Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde. in Polyhedron, 89, 271-279.
https://doi.org/10.1016/j.poly.2015.01.024
Čobeljić B, Pevec A, Stepanovic S, Spasojević V, Milenković M, Turel I, Swart M, Gruden-Pavlović M, Adaila K, Anđelković K. Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde. in Polyhedron. 2015;89:271-279.
doi:10.1016/j.poly.2015.01.024 .
Čobeljić, Božidar, Pevec, Andrej, Stepanovic, Stepan, Spasojević, Vojislav, Milenković, Milica, Turel, Iztok, Swart, Marcel, Gruden-Pavlović, Maja, Adaila, Kawther, Anđelković, Katarina, "Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde" in Polyhedron, 89 (2015):271-279,
https://doi.org/10.1016/j.poly.2015.01.024 . .
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Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate

Milenković, Milica; Cantoni, Giulia; Bacchi, Alessia; Spasojević, Vojislav; Milenković, Marina; Sladić, Dušan M.; Krstić, Natalija; Anđelković, Katarina

(2014)

TY  - JOUR
AU  - Milenković, Milica
AU  - Cantoni, Giulia
AU  - Bacchi, Alessia
AU  - Spasojević, Vojislav
AU  - Milenković, Marina
AU  - Sladić, Dušan M.
AU  - Krstić, Natalija
AU  - Anđelković, Katarina
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/99
AB  - Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate
VL  - 80
IS  - SI
SP  - 47
EP  - 52
DO  - 10.1016/j.poly.2014.01.022
ER  - 
@article{
author = "Milenković, Milica and Cantoni, Giulia and Bacchi, Alessia and Spasojević, Vojislav and Milenković, Marina and Sladić, Dušan M. and Krstić, Natalija and Anđelković, Katarina",
year = "2014",
abstract = "Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate",
volume = "80",
number = "SI",
pages = "47-52",
doi = "10.1016/j.poly.2014.01.022"
}
Milenković, M., Cantoni, G., Bacchi, A., Spasojević, V., Milenković, M., Sladić, D. M., Krstić, N.,& Anđelković, K.. (2014). Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. in Polyhedron, 80(SI), 47-52.
https://doi.org/10.1016/j.poly.2014.01.022
Milenković M, Cantoni G, Bacchi A, Spasojević V, Milenković M, Sladić DM, Krstić N, Anđelković K. Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. in Polyhedron. 2014;80(SI):47-52.
doi:10.1016/j.poly.2014.01.022 .
Milenković, Milica, Cantoni, Giulia, Bacchi, Alessia, Spasojević, Vojislav, Milenković, Marina, Sladić, Dušan M., Krstić, Natalija, Anđelković, Katarina, "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate" in Polyhedron, 80, no. SI (2014):47-52,
https://doi.org/10.1016/j.poly.2014.01.022 . .
25
23
24

Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate

Čobeljić, Božidar; Pevec, Andrej; Turel, Iztok; Spasojević, Vojislav; Milčić, Miloš K.; Mitić, Dragana; Sladić, Dušan M.; Anđelković, Katarina

(2014)

TY  - JOUR
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Spasojević, Vojislav
AU  - Milčić, Miloš K.
AU  - Mitić, Dragana
AU  - Sladić, Dušan M.
AU  - Anđelković, Katarina
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5887
AB  - 3-Acetylpyridine thiosemicarbazone hydrochloride was synthesized and structurally characterized. Complexes of Cu(II) with this ligand could not be obtained by direct synthesis. By synthesis in situ mixing Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine (3-Acpy) and semicarbazide, a Cu(I) polymer, {[Cu(SCN)(3-Acpy)(2)]}(n) was obtained and structurally characterized. Reaction of Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine and ammonium thiocyanate afforded a dinuclear Cu(II) complex with two thiocyanate ions in bridges, which was structurally characterized. Magnetic measurements were performed for the dinuclear complex. OFT calculations provided explanation for inability to obtain a mononuclear complex. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Polyhedron
T1  - Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate
VL  - 69
SP  - 77
EP  - 83
DO  - 10.1016/j.poly.2013.11.027
ER  - 
@article{
author = "Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Spasojević, Vojislav and Milčić, Miloš K. and Mitić, Dragana and Sladić, Dušan M. and Anđelković, Katarina",
year = "2014",
abstract = "3-Acetylpyridine thiosemicarbazone hydrochloride was synthesized and structurally characterized. Complexes of Cu(II) with this ligand could not be obtained by direct synthesis. By synthesis in situ mixing Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine (3-Acpy) and semicarbazide, a Cu(I) polymer, {[Cu(SCN)(3-Acpy)(2)]}(n) was obtained and structurally characterized. Reaction of Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine and ammonium thiocyanate afforded a dinuclear Cu(II) complex with two thiocyanate ions in bridges, which was structurally characterized. Magnetic measurements were performed for the dinuclear complex. OFT calculations provided explanation for inability to obtain a mononuclear complex. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Polyhedron",
title = "Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate",
volume = "69",
pages = "77-83",
doi = "10.1016/j.poly.2013.11.027"
}
Čobeljić, B., Pevec, A., Turel, I., Spasojević, V., Milčić, M. K., Mitić, D., Sladić, D. M.,& Anđelković, K.. (2014). Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate. in Polyhedron, 69, 77-83.
https://doi.org/10.1016/j.poly.2013.11.027
Čobeljić B, Pevec A, Turel I, Spasojević V, Milčić MK, Mitić D, Sladić DM, Anđelković K. Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate. in Polyhedron. 2014;69:77-83.
doi:10.1016/j.poly.2013.11.027 .
Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Spasojević, Vojislav, Milčić, Miloš K., Mitić, Dragana, Sladić, Dušan M., Anđelković, Katarina, "Analysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanate" in Polyhedron, 69 (2014):77-83,
https://doi.org/10.1016/j.poly.2013.11.027 . .
1
8
9
11

Synthesis and structure of a Ni(II) complex with N ,N (2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate

Čobeljić, Božidar; Warzajtis, Beata; Rychlewska, Urszula; Radanović, Dušanka; Spasojević, Vojislav; Sladić, Dušan M.; Eshkourfu, Rabia; Anđelković, Katarina

(2012)

TY  - JOUR
AU  - Čobeljić, Božidar
AU  - Warzajtis, Beata
AU  - Rychlewska, Urszula
AU  - Radanović, Dušanka
AU  - Spasojević, Vojislav
AU  - Sladić, Dušan M.
AU  - Eshkourfu, Rabia
AU  - Anđelković, Katarina
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4762
AB  - A new malonic dihydrazide-based ligand, N,N(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide (H(2)L3), has been prepared and characterized by elemental analysis, IR, C-13 NMR, and H-1 NMR spectroscopies. In the reaction of H(2)L3 with Ni(II) a binuclear complex has been obtained. The structure of the complex was established by X-ray analysis. Each Ni(II) is coordinated with two NNO donor sets from two ligand molecules in dianionic form (L3(2-)) forming an octahedral geometry. Multiple intramolecular C-H center dot center dot center dot pi (chelate ring) interactions support the molecular geometry of the [Ni-2(L3)(2)] complex. The structure of [Ni-2(L3)(2)] is compared with those of analogous Ni(II) complexes with pyridine dihydrazone type ligands. Magnetic behavior of the dinuclear complex was studied in temperature range of 2-300 K.
T2  - Journal of Coordination Chemistry
T1  - Synthesis and structure of a Ni(II) complex with N ,N (2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate
VL  - 65
IS  - 4
SP  - 655
EP  - 667
DO  - 10.1080/00958972.2012.658778
ER  - 
@article{
author = "Čobeljić, Božidar and Warzajtis, Beata and Rychlewska, Urszula and Radanović, Dušanka and Spasojević, Vojislav and Sladić, Dušan M. and Eshkourfu, Rabia and Anđelković, Katarina",
year = "2012",
abstract = "A new malonic dihydrazide-based ligand, N,N(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide (H(2)L3), has been prepared and characterized by elemental analysis, IR, C-13 NMR, and H-1 NMR spectroscopies. In the reaction of H(2)L3 with Ni(II) a binuclear complex has been obtained. The structure of the complex was established by X-ray analysis. Each Ni(II) is coordinated with two NNO donor sets from two ligand molecules in dianionic form (L3(2-)) forming an octahedral geometry. Multiple intramolecular C-H center dot center dot center dot pi (chelate ring) interactions support the molecular geometry of the [Ni-2(L3)(2)] complex. The structure of [Ni-2(L3)(2)] is compared with those of analogous Ni(II) complexes with pyridine dihydrazone type ligands. Magnetic behavior of the dinuclear complex was studied in temperature range of 2-300 K.",
journal = "Journal of Coordination Chemistry",
title = "Synthesis and structure of a Ni(II) complex with N ,N (2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate",
volume = "65",
number = "4",
pages = "655-667",
doi = "10.1080/00958972.2012.658778"
}
Čobeljić, B., Warzajtis, B., Rychlewska, U., Radanović, D., Spasojević, V., Sladić, D. M., Eshkourfu, R.,& Anđelković, K.. (2012). Synthesis and structure of a Ni(II) complex with N ,N (2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate. in Journal of Coordination Chemistry, 65(4), 655-667.
https://doi.org/10.1080/00958972.2012.658778
Čobeljić B, Warzajtis B, Rychlewska U, Radanović D, Spasojević V, Sladić DM, Eshkourfu R, Anđelković K. Synthesis and structure of a Ni(II) complex with N ,N (2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate. in Journal of Coordination Chemistry. 2012;65(4):655-667.
doi:10.1080/00958972.2012.658778 .
Čobeljić, Božidar, Warzajtis, Beata, Rychlewska, Urszula, Radanović, Dušanka, Spasojević, Vojislav, Sladić, Dušan M., Eshkourfu, Rabia, Anđelković, Katarina, "Synthesis and structure of a Ni(II) complex with N ,N (2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate" in Journal of Coordination Chemistry, 65, no. 4 (2012):655-667,
https://doi.org/10.1080/00958972.2012.658778 . .
5
4
5

Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate

Anđelković, Katarina; Bogdanović, Goran; Jovanović, Dragoljub; Mitić, Dragana; Miodragović, Đenana

(Belgrade : Institute of Technical Sciences of SASA, 2010)

TY  - CONF
AU  - Anđelković, Katarina
AU  - Bogdanović, Goran
AU  - Jovanović, Dragoljub
AU  - Mitić, Dragana
AU  - Miodragović, Đenana
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12966
AB  - In the reaction of ZnCl2 with tacrine hydrochloride in water novel tetracoordinated (C13H15N2)2[ZnCl4].H2O complex has been obtained and characterized by elemental analysis, molar conductivity and X-ray analysis. The structure contains two crystallographically different molecules of protonated tacrine present as counter cations, [ZnCl4]2- complex anion and one water solvent molecule. The counter cations slightly differ in puckering of the cyclohexenyl ring. The molecules of protonated tacrine are involved in different intermolecular hydrogen bonds. The π–π stacking interactions between the rings of protonated tacrine have been evidenced in the crystal. The [ZnCl4]2- complex anion has distorted tetrahedral geometry. Three out of four Cl atoms are involved in intermolecular hydrogen bonds. Intermolecular H-bond interactions that involve Cl atoms affect the Zn-Cl bond lengths.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Twelfth Annual Conference YUCOMAT 2010 : Programme and The Book of Abstracts
T1  - Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate
SP  - 83
EP  - 83
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12966
ER  - 
@conference{
author = "Anđelković, Katarina and Bogdanović, Goran and Jovanović, Dragoljub and Mitić, Dragana and Miodragović, Đenana",
year = "2010",
abstract = "In the reaction of ZnCl2 with tacrine hydrochloride in water novel tetracoordinated (C13H15N2)2[ZnCl4].H2O complex has been obtained and characterized by elemental analysis, molar conductivity and X-ray analysis. The structure contains two crystallographically different molecules of protonated tacrine present as counter cations, [ZnCl4]2- complex anion and one water solvent molecule. The counter cations slightly differ in puckering of the cyclohexenyl ring. The molecules of protonated tacrine are involved in different intermolecular hydrogen bonds. The π–π stacking interactions between the rings of protonated tacrine have been evidenced in the crystal. The [ZnCl4]2- complex anion has distorted tetrahedral geometry. Three out of four Cl atoms are involved in intermolecular hydrogen bonds. Intermolecular H-bond interactions that involve Cl atoms affect the Zn-Cl bond lengths.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Twelfth Annual Conference YUCOMAT 2010 : Programme and The Book of Abstracts",
title = "Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate",
pages = "83-83",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12966"
}
Anđelković, K., Bogdanović, G., Jovanović, D., Mitić, D.,& Miodragović, Đ.. (2010). Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate. in Twelfth Annual Conference YUCOMAT 2010 : Programme and The Book of Abstracts
Belgrade : Institute of Technical Sciences of SASA., 83-83.
https://hdl.handle.net/21.15107/rcub_vinar_12966
Anđelković K, Bogdanović G, Jovanović D, Mitić D, Miodragović Đ. Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate. in Twelfth Annual Conference YUCOMAT 2010 : Programme and The Book of Abstracts. 2010;:83-83.
https://hdl.handle.net/21.15107/rcub_vinar_12966 .
Anđelković, Katarina, Bogdanović, Goran, Jovanović, Dragoljub, Mitić, Dragana, Miodragović, Đenana, "Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate" in Twelfth Annual Conference YUCOMAT 2010 : Programme and The Book of Abstracts (2010):83-83,
https://hdl.handle.net/21.15107/rcub_vinar_12966 .

Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate

Miodragović Đenana U.; Jovanović, Dragoljub; Bogdanović, Goran A.; Mitić, Dragana; Anđelković, Katarina

(2010)

TY  - JOUR
AU  - Miodragović Đenana U.
AU  - Jovanović, Dragoljub
AU  - Bogdanović, Goran A.
AU  - Mitić, Dragana
AU  - Anđelković, Katarina
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4108
AB  - In the reaction of ZnCl(2) with tacrine hydrochloride in water novel tetracoordinated (C(13)H(15)N(2))(2)[ZnCl(4)]-H(2)O complex was obtained and characterized by elemental analysis, molar conductivity and X-ray analysis. The complex crystallizes in the space group P-1 of the triclinic crystal system. The structure contains two crystallographically different molecules of protonated tacrine present as counter cations, the [ZnCl(4)](2-) complex anion and one water solvent molecule. The counter cations slightly differ in the puckering of the cyclohexene ring. The molecules of protonated tacrine are involved in different intermolecular hydrogen bonds. In the crystal, the hydrogen bonding generates a 3D assembly. In the crystal, pi center dot center dot center dot pi stacking interactions between the rings of protonated tacrine were evidenced. The [ZnCl(4)](2-) complex anion has a distorted tetrahedral geometry. Three out of the four Cl atoms are involved in intermolecular hydrogen bonding. The intermolecular H-bond interactions involving the Cl atoms affect the Zn-CI bond lengths.
AB  - U reakciji ZnCl2 sa takrin-hidrohloridom u vodi, dobijen je novi tetrakoordinovani (C13H15N2)2[ZnCl4]?H2O kompleks koji je okarakterisan pomoću elementalne analize, molarne provodljivosti i rendgenske strukturne analize. Kompleks kristališe u prostornoj grupi P?1 trikliničnog kristalnog sistema. Struktura sadrži dva kristalografski različita molekula protonovanog takrina koji su prisutni kao kontra-katjoni, [ZnCl4]2 kompleksni anjon i molekul kristalne vode. Molekuli katjona se neznatno razlikuju u stepenu nabiranja cikloheksenovog prstena. Molekuli protonovanog takrina su uključeni u različite intermolekulske vodonične veze. Intermolekulsko vodonično vezivanje u kristalu generiše 3D molekulski skup pi...pi interakcije između prstenova protonovanog takrina su primećene u kristalu. [ZnCl4]2- ima distorgovanu tetraedarsku geometriju. Tri od četiri Cl atoma su uključena u intermolekulske vodonične veze. Intermolekulske vodonične interakcije koje uključuju Cl atome utiču na dužinu Zn-Cl veza.
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate
T1  - Sinteza i kristalna struktura 1,2,3,4-tetrahidro-9-aminoakridin-tetrahlorocinkata(II) monohidrata
VL  - 75
IS  - 9
SP  - 1209
EP  - 1218
DO  - 10.2298/JSC100302059M
ER  - 
@article{
author = "Miodragović Đenana U. and Jovanović, Dragoljub and Bogdanović, Goran A. and Mitić, Dragana and Anđelković, Katarina",
year = "2010",
abstract = "In the reaction of ZnCl(2) with tacrine hydrochloride in water novel tetracoordinated (C(13)H(15)N(2))(2)[ZnCl(4)]-H(2)O complex was obtained and characterized by elemental analysis, molar conductivity and X-ray analysis. The complex crystallizes in the space group P-1 of the triclinic crystal system. The structure contains two crystallographically different molecules of protonated tacrine present as counter cations, the [ZnCl(4)](2-) complex anion and one water solvent molecule. The counter cations slightly differ in the puckering of the cyclohexene ring. The molecules of protonated tacrine are involved in different intermolecular hydrogen bonds. In the crystal, the hydrogen bonding generates a 3D assembly. In the crystal, pi center dot center dot center dot pi stacking interactions between the rings of protonated tacrine were evidenced. The [ZnCl(4)](2-) complex anion has a distorted tetrahedral geometry. Three out of the four Cl atoms are involved in intermolecular hydrogen bonding. The intermolecular H-bond interactions involving the Cl atoms affect the Zn-CI bond lengths., U reakciji ZnCl2 sa takrin-hidrohloridom u vodi, dobijen je novi tetrakoordinovani (C13H15N2)2[ZnCl4]?H2O kompleks koji je okarakterisan pomoću elementalne analize, molarne provodljivosti i rendgenske strukturne analize. Kompleks kristališe u prostornoj grupi P?1 trikliničnog kristalnog sistema. Struktura sadrži dva kristalografski različita molekula protonovanog takrina koji su prisutni kao kontra-katjoni, [ZnCl4]2 kompleksni anjon i molekul kristalne vode. Molekuli katjona se neznatno razlikuju u stepenu nabiranja cikloheksenovog prstena. Molekuli protonovanog takrina su uključeni u različite intermolekulske vodonične veze. Intermolekulsko vodonično vezivanje u kristalu generiše 3D molekulski skup pi...pi interakcije između prstenova protonovanog takrina su primećene u kristalu. [ZnCl4]2- ima distorgovanu tetraedarsku geometriju. Tri od četiri Cl atoma su uključena u intermolekulske vodonične veze. Intermolekulske vodonične interakcije koje uključuju Cl atome utiču na dužinu Zn-Cl veza.",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate, Sinteza i kristalna struktura 1,2,3,4-tetrahidro-9-aminoakridin-tetrahlorocinkata(II) monohidrata",
volume = "75",
number = "9",
pages = "1209-1218",
doi = "10.2298/JSC100302059M"
}
Miodragović Đenana U., Jovanović, D., Bogdanović, G. A., Mitić, D.,& Anđelković, K.. (2010). Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate. in Journal of the Serbian Chemical Society, 75(9), 1209-1218.
https://doi.org/10.2298/JSC100302059M
Miodragović Đenana U., Jovanović D, Bogdanović GA, Mitić D, Anđelković K. Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate. in Journal of the Serbian Chemical Society. 2010;75(9):1209-1218.
doi:10.2298/JSC100302059M .
Miodragović Đenana U., Jovanović, Dragoljub, Bogdanović, Goran A., Mitić, Dragana, Anđelković, Katarina, "Synthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrate" in Journal of the Serbian Chemical Society, 75, no. 9 (2010):1209-1218,
https://doi.org/10.2298/JSC100302059M . .
1
1

Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity

Filipović, Nenad R.; Borrmann, Horst; Todorović, Tamara; Borna, Marija; Spasojević, Vojislav; Sladić, Dušan M.; Novaković, Irena T.; Anđelković, Katarina

(2009)

TY  - JOUR
AU  - Filipović, Nenad R.
AU  - Borrmann, Horst
AU  - Todorović, Tamara
AU  - Borna, Marija
AU  - Spasojević, Vojislav
AU  - Sladić, Dušan M.
AU  - Novaković, Irena T.
AU  - Anđelković, Katarina
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3680
AB  - Three novel copper(II) complexes as condensation derivatives of 2-pyridinecarboxaldehyde, 2-acetylpyridine or 2-quinolinecarboxaldehyde with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of all three complexes were determined. Crystallographic data indicate a common basis of the structures with some major differences. Both pyridine derivatives form complexes of the type [CuCl(2)L] with distorted square-planar geometry around copper(II), but show a decisive difference in the side chain orientation. The quinoline derivative forms a dimeric complex of type [Cu(2)Cl(4)L(2)] with distorted trigonal bipyramidal geometry around copper(II), but a rather short Cu center dot center dot center dot Cu contact, which is reflected in its magnetic properties. All three complexes showed antibacterial activity. (c) 2008 Elsevier B.V. All rights reserved.
T2  - Inorganica Chimica Acta
T1  - Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity
VL  - 362
IS  - 6
SP  - 1996
EP  - 2000
DO  - 10.1016/j.ica.2008.09.019
ER  - 
@article{
author = "Filipović, Nenad R. and Borrmann, Horst and Todorović, Tamara and Borna, Marija and Spasojević, Vojislav and Sladić, Dušan M. and Novaković, Irena T. and Anđelković, Katarina",
year = "2009",
abstract = "Three novel copper(II) complexes as condensation derivatives of 2-pyridinecarboxaldehyde, 2-acetylpyridine or 2-quinolinecarboxaldehyde with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of all three complexes were determined. Crystallographic data indicate a common basis of the structures with some major differences. Both pyridine derivatives form complexes of the type [CuCl(2)L] with distorted square-planar geometry around copper(II), but show a decisive difference in the side chain orientation. The quinoline derivative forms a dimeric complex of type [Cu(2)Cl(4)L(2)] with distorted trigonal bipyramidal geometry around copper(II), but a rather short Cu center dot center dot center dot Cu contact, which is reflected in its magnetic properties. All three complexes showed antibacterial activity. (c) 2008 Elsevier B.V. All rights reserved.",
journal = "Inorganica Chimica Acta",
title = "Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity",
volume = "362",
number = "6",
pages = "1996-2000",
doi = "10.1016/j.ica.2008.09.019"
}
Filipović, N. R., Borrmann, H., Todorović, T., Borna, M., Spasojević, V., Sladić, D. M., Novaković, I. T.,& Anđelković, K.. (2009). Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity. in Inorganica Chimica Acta, 362(6), 1996-2000.
https://doi.org/10.1016/j.ica.2008.09.019
Filipović NR, Borrmann H, Todorović T, Borna M, Spasojević V, Sladić DM, Novaković IT, Anđelković K. Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity. in Inorganica Chimica Acta. 2009;362(6):1996-2000.
doi:10.1016/j.ica.2008.09.019 .
Filipović, Nenad R., Borrmann, Horst, Todorović, Tamara, Borna, Marija, Spasojević, Vojislav, Sladić, Dušan M., Novaković, Irena T., Anđelković, Katarina, "Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity" in Inorganica Chimica Acta, 362, no. 6 (2009):1996-2000,
https://doi.org/10.1016/j.ica.2008.09.019 . .
45
38
41

Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex

Miodragović Đenana U.; Mitić, Dragana M.; Miodragovic, Zoran M.; Bogdanović, Goran A.; Vitnik, Željko J.; Vitorovic, Maja D.; Radulovic, Milanka D.; Nastasijević, Branislav J.; Juranić, Ivan O.; Anđelković, Katarina

(2008)

TY  - JOUR
AU  - Miodragović Đenana U.
AU  - Mitić, Dragana M.
AU  - Miodragovic, Zoran M.
AU  - Bogdanović, Goran A.
AU  - Vitnik, Željko J.
AU  - Vitorovic, Maja D.
AU  - Radulovic, Milanka D.
AU  - Nastasijević, Branislav J.
AU  - Juranić, Ivan O.
AU  - Anđelković, Katarina
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3363
AB  - For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH center dot center dot center dot pi interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen. (c) 2007 Elsevier B.V. All rights reserved.
T2  - Inorganica Chimica Acta
T1  - Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex
VL  - 361
IS  - 1
SP  - 86
EP  - 94
DO  - 10.1016/j.ica.2007.06.041
ER  - 
@article{
author = "Miodragović Đenana U. and Mitić, Dragana M. and Miodragovic, Zoran M. and Bogdanović, Goran A. and Vitnik, Željko J. and Vitorovic, Maja D. and Radulovic, Milanka D. and Nastasijević, Branislav J. and Juranić, Ivan O. and Anđelković, Katarina",
year = "2008",
abstract = "For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH center dot center dot center dot pi interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen. (c) 2007 Elsevier B.V. All rights reserved.",
journal = "Inorganica Chimica Acta",
title = "Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex",
volume = "361",
number = "1",
pages = "86-94",
doi = "10.1016/j.ica.2007.06.041"
}
Miodragović Đenana U., Mitić, D. M., Miodragovic, Z. M., Bogdanović, G. A., Vitnik, Ž. J., Vitorovic, M. D., Radulovic, M. D., Nastasijević, B. J., Juranić, I. O.,& Anđelković, K.. (2008). Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex. in Inorganica Chimica Acta, 361(1), 86-94.
https://doi.org/10.1016/j.ica.2007.06.041
Miodragović Đenana U., Mitić DM, Miodragovic ZM, Bogdanović GA, Vitnik ŽJ, Vitorovic MD, Radulovic MD, Nastasijević BJ, Juranić IO, Anđelković K. Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex. in Inorganica Chimica Acta. 2008;361(1):86-94.
doi:10.1016/j.ica.2007.06.041 .
Miodragović Đenana U., Mitić, Dragana M., Miodragovic, Zoran M., Bogdanović, Goran A., Vitnik, Željko J., Vitorovic, Maja D., Radulovic, Milanka D., Nastasijević, Branislav J., Juranić, Ivan O., Anđelković, Katarina, "Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex" in Inorganica Chimica Acta, 361, no. 1 (2008):86-94,
https://doi.org/10.1016/j.ica.2007.06.041 . .
21
29
30

Potassium 3-dithiocarboxy-3-aza-5-aminopentanoate dihydrate

Prelesnik, Bogdan V.; Anđelković, Katarina; Marković, Zorica; Sabo, Tibor J.; Trifunović, Snežana

(1997)

TY  - JOUR
AU  - Prelesnik, Bogdan V.
AU  - Anđelković, Katarina
AU  - Marković, Zorica
AU  - Sabo, Tibor J.
AU  - Trifunović, Snežana
PY  - 1997
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2073
AB  - The synthesis and crystal structure of the title compound, K+. C5H9N2O2S2-. 2H(2)O, are described. The structure consists of potassium cations, 3-dithiocarboxy-3-aza-5-aminopentanoate anions and molecules of water. The anion exists in two tautomeric forms, each described by two resonance structures.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - Potassium 3-dithiocarboxy-3-aza-5-aminopentanoate dihydrate
VL  - 53
SP  - 719
EP  - 720
DO  - 10.1107/S0108270197001650
ER  - 
@article{
author = "Prelesnik, Bogdan V. and Anđelković, Katarina and Marković, Zorica and Sabo, Tibor J. and Trifunović, Snežana",
year = "1997",
abstract = "The synthesis and crystal structure of the title compound, K+. C5H9N2O2S2-. 2H(2)O, are described. The structure consists of potassium cations, 3-dithiocarboxy-3-aza-5-aminopentanoate anions and molecules of water. The anion exists in two tautomeric forms, each described by two resonance structures.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "Potassium 3-dithiocarboxy-3-aza-5-aminopentanoate dihydrate",
volume = "53",
pages = "719-720",
doi = "10.1107/S0108270197001650"
}
Prelesnik, B. V., Anđelković, K., Marković, Z., Sabo, T. J.,& Trifunović, S.. (1997). Potassium 3-dithiocarboxy-3-aza-5-aminopentanoate dihydrate. in Acta Crystallographica. Section C: Crystal Structure Communications, 53, 719-720.
https://doi.org/10.1107/S0108270197001650
Prelesnik BV, Anđelković K, Marković Z, Sabo TJ, Trifunović S. Potassium 3-dithiocarboxy-3-aza-5-aminopentanoate dihydrate. in Acta Crystallographica. Section C: Crystal Structure Communications. 1997;53:719-720.
doi:10.1107/S0108270197001650 .
Prelesnik, Bogdan V., Anđelković, Katarina, Marković, Zorica, Sabo, Tibor J., Trifunović, Snežana, "Potassium 3-dithiocarboxy-3-aza-5-aminopentanoate dihydrate" in Acta Crystallographica. Section C: Crystal Structure Communications, 53 (1997):719-720,
https://doi.org/10.1107/S0108270197001650 . .
5
8

Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate

Ivanović, Ivana; Anđelković, Katarina; Beljanski, Vladimir; Prelesnik, Bogdan V.; Leovac, Vukadin M.; Momirović, Mirjana

(1997)

TY  - JOUR
AU  - Ivanović, Ivana
AU  - Anđelković, Katarina
AU  - Beljanski, Vladimir
AU  - Prelesnik, Bogdan V.
AU  - Leovac, Vukadin M.
AU  - Momirović, Mirjana
PY  - 1997
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2136
AB  - This paper reports the first Co(II) complexes with a singly-and doubly-deprotonated H2L ligand (H2L = 2,2-(2,6-pyridindiyldiethylidene)dioxamohydrazide belonging to the planar pentadentate class. The complexes were characterized by elemental analysis, thermal analysis, IR spectroscopy, molar conductivity and magnetic susceptibility measurements. The crystal structure of [Co(L)(H2O)(2)].6H(2)O complex has been determined. The pentagonal bipyramidal geometry present in the previously synthesized complex [Co(H2L)(H2O)(MeOH)](ClO4)2(,) wherein the ligand is present in a neutral form, has been preserved around Co(II).
T2  - Journal of Coordination Chemistry
T1  - Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate
VL  - 42
IS  - 4
SP  - 335
EP  - 342
DO  - 10.1080/00958979708022862
ER  - 
@article{
author = "Ivanović, Ivana and Anđelković, Katarina and Beljanski, Vladimir and Prelesnik, Bogdan V. and Leovac, Vukadin M. and Momirović, Mirjana",
year = "1997",
abstract = "This paper reports the first Co(II) complexes with a singly-and doubly-deprotonated H2L ligand (H2L = 2,2-(2,6-pyridindiyldiethylidene)dioxamohydrazide belonging to the planar pentadentate class. The complexes were characterized by elemental analysis, thermal analysis, IR spectroscopy, molar conductivity and magnetic susceptibility measurements. The crystal structure of [Co(L)(H2O)(2)].6H(2)O complex has been determined. The pentagonal bipyramidal geometry present in the previously synthesized complex [Co(H2L)(H2O)(MeOH)](ClO4)2(,) wherein the ligand is present in a neutral form, has been preserved around Co(II).",
journal = "Journal of Coordination Chemistry",
title = "Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate",
volume = "42",
number = "4",
pages = "335-342",
doi = "10.1080/00958979708022862"
}
Ivanović, I., Anđelković, K., Beljanski, V., Prelesnik, B. V., Leovac, V. M.,& Momirović, M.. (1997). Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate. in Journal of Coordination Chemistry, 42(4), 335-342.
https://doi.org/10.1080/00958979708022862
Ivanović I, Anđelković K, Beljanski V, Prelesnik BV, Leovac VM, Momirović M. Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate. in Journal of Coordination Chemistry. 1997;42(4):335-342.
doi:10.1080/00958979708022862 .
Ivanović, Ivana, Anđelković, Katarina, Beljanski, Vladimir, Prelesnik, Bogdan V., Leovac, Vukadin M., Momirović, Mirjana, "Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate" in Journal of Coordination Chemistry, 42, no. 4 (1997):335-342,
https://doi.org/10.1080/00958979708022862 . .
14
16
16

Synthesis and structure of aqua-2,2-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate

Anđelković, Katarina; Ivanović, Ivana; Niketić, Svetozar R.; Prelesnik, Bogdan V.; Leovac, Vukadin M.

(1997)

TY  - JOUR
AU  - Anđelković, Katarina
AU  - Ivanović, Ivana
AU  - Niketić, Svetozar R.
AU  - Prelesnik, Bogdan V.
AU  - Leovac, Vukadin M.
PY  - 1997
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2095
AB  - In a template synthesis from copper(II) acetate, 2,6-diacetylpyridine, and semioxamazide (NH2CO CONHNH2), two new copper(II) complexes, [Cu(dapsox)(H2O)]. H2O and [Cu(Hdapsox)(H2O)]ClO4, (where H(2)dapsox = 2,2-(2,6-pyridindiyldiethylidene)dioxamohydrazide) were obtained and characterized. The structure of the former complex was determined by a single-crystal X-ray analysis. Cu-II is located in a square pyramidal environment. The polydentate ligand, dapsox(2-), is coordinated in dianionic form, as an unsymmetrical quadridentate planar system forming one six-membered and two five-membered metal-chelate rings. The fifth coordination site is occupied by a water molecule. (C) 1997 Elsevier Science Ltd.
T2  - Polyhedron
T1  - Synthesis and structure of aqua-2,2-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate
VL  - 16
IS  - 24
SP  - 4221
EP  - 4228
DO  - 10.1016/S0277-5387(97)00265-9
ER  - 
@article{
author = "Anđelković, Katarina and Ivanović, Ivana and Niketić, Svetozar R. and Prelesnik, Bogdan V. and Leovac, Vukadin M.",
year = "1997",
abstract = "In a template synthesis from copper(II) acetate, 2,6-diacetylpyridine, and semioxamazide (NH2CO CONHNH2), two new copper(II) complexes, [Cu(dapsox)(H2O)]. H2O and [Cu(Hdapsox)(H2O)]ClO4, (where H(2)dapsox = 2,2-(2,6-pyridindiyldiethylidene)dioxamohydrazide) were obtained and characterized. The structure of the former complex was determined by a single-crystal X-ray analysis. Cu-II is located in a square pyramidal environment. The polydentate ligand, dapsox(2-), is coordinated in dianionic form, as an unsymmetrical quadridentate planar system forming one six-membered and two five-membered metal-chelate rings. The fifth coordination site is occupied by a water molecule. (C) 1997 Elsevier Science Ltd.",
journal = "Polyhedron",
title = "Synthesis and structure of aqua-2,2-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate",
volume = "16",
number = "24",
pages = "4221-4228",
doi = "10.1016/S0277-5387(97)00265-9"
}
Anđelković, K., Ivanović, I., Niketić, S. R., Prelesnik, B. V.,& Leovac, V. M.. (1997). Synthesis and structure of aqua-2,2-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate. in Polyhedron, 16(24), 4221-4228.
https://doi.org/10.1016/S0277-5387(97)00265-9
Anđelković K, Ivanović I, Niketić SR, Prelesnik BV, Leovac VM. Synthesis and structure of aqua-2,2-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate. in Polyhedron. 1997;16(24):4221-4228.
doi:10.1016/S0277-5387(97)00265-9 .
Anđelković, Katarina, Ivanović, Ivana, Niketić, Svetozar R., Prelesnik, Bogdan V., Leovac, Vukadin M., "Synthesis and structure of aqua-2,2-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate" in Polyhedron, 16, no. 24 (1997):4221-4228,
https://doi.org/10.1016/S0277-5387(97)00265-9 . .
34
33
37

mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)

Prelesnik, Bogdan V.; Ivanović, Ivana; Leovac, Vukadin M.; Anđelković, Katarina

(1996)

TY  - JOUR
AU  - Prelesnik, Bogdan V.
AU  - Ivanović, Ivana
AU  - Leovac, Vukadin M.
AU  - Anđelković, Katarina
PY  - 1996
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1996
AB  - In the molecule of the title compound, [MoO2(L)(CH3-OH)] [L is the dianion of 2-(2-benzoyl-1-methylethylidene)-1-naphthohydrazide, C21H16N2O2], the Mo atom displays distorted octahedral coordination geometry, being coordinated by two mutually cis oxo ligands, the methanol O atom and the tridentate ligand L bonded through the azomethine N atom, the enolic O atom and the oxazine O atom (equatorially disposed). The packing in the crystal structure involves a hydrogen bond from the methanol OH as donor to an oxo ligand as acceptor.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)
VL  - 52
SP  - 1375
EP  - 1377
DO  - 10.1107/S010827019600039X
ER  - 
@article{
author = "Prelesnik, Bogdan V. and Ivanović, Ivana and Leovac, Vukadin M. and Anđelković, Katarina",
year = "1996",
abstract = "In the molecule of the title compound, [MoO2(L)(CH3-OH)] [L is the dianion of 2-(2-benzoyl-1-methylethylidene)-1-naphthohydrazide, C21H16N2O2], the Mo atom displays distorted octahedral coordination geometry, being coordinated by two mutually cis oxo ligands, the methanol O atom and the tridentate ligand L bonded through the azomethine N atom, the enolic O atom and the oxazine O atom (equatorially disposed). The packing in the crystal structure involves a hydrogen bond from the methanol OH as donor to an oxo ligand as acceptor.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)",
volume = "52",
pages = "1375-1377",
doi = "10.1107/S010827019600039X"
}
Prelesnik, B. V., Ivanović, I., Leovac, V. M.,& Anđelković, K.. (1996). mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI). in Acta Crystallographica. Section C: Crystal Structure Communications, 52, 1375-1377.
https://doi.org/10.1107/S010827019600039X
Prelesnik BV, Ivanović I, Leovac VM, Anđelković K. mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI). in Acta Crystallographica. Section C: Crystal Structure Communications. 1996;52:1375-1377.
doi:10.1107/S010827019600039X .
Prelesnik, Bogdan V., Ivanović, Ivana, Leovac, Vukadin M., Anđelković, Katarina, "mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)" in Acta Crystallographica. Section C: Crystal Structure Communications, 52 (1996):1375-1377,
https://doi.org/10.1107/S010827019600039X . .
1
3
3

Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate

Anđelković, Katarina; Ivanović, Ivana; Prelesnik, Bogdan V.; Leovac, Vukadin M.; Poleti, Dejan

(1996)

TY  - JOUR
AU  - Anđelković, Katarina
AU  - Ivanović, Ivana
AU  - Prelesnik, Bogdan V.
AU  - Leovac, Vukadin M.
AU  - Poleti, Dejan
PY  - 1996
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2015
AB  - The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2,2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The H2O and methanol are axial with the planar pentadentate H(2)L ligand forming the equatorial plane. The possible reaction mechanism has been proposed.
T2  - Polyhedron
T1  - Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate
VL  - 15
IS  - 24
SP  - 4361
EP  - 4366
DO  - 10.1016/0277-5387(96)00234-3
ER  - 
@article{
author = "Anđelković, Katarina and Ivanović, Ivana and Prelesnik, Bogdan V. and Leovac, Vukadin M. and Poleti, Dejan",
year = "1996",
abstract = "The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2,2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The H2O and methanol are axial with the planar pentadentate H(2)L ligand forming the equatorial plane. The possible reaction mechanism has been proposed.",
journal = "Polyhedron",
title = "Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate",
volume = "15",
number = "24",
pages = "4361-4366",
doi = "10.1016/0277-5387(96)00234-3"
}
Anđelković, K., Ivanović, I., Prelesnik, B. V., Leovac, V. M.,& Poleti, D.. (1996). Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate. in Polyhedron, 15(24), 4361-4366.
https://doi.org/10.1016/0277-5387(96)00234-3
Anđelković K, Ivanović I, Prelesnik BV, Leovac VM, Poleti D. Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate. in Polyhedron. 1996;15(24):4361-4366.
doi:10.1016/0277-5387(96)00234-3 .
Anđelković, Katarina, Ivanović, Ivana, Prelesnik, Bogdan V., Leovac, Vukadin M., Poleti, Dejan, "Synthesis and structure of aquamethanol-2,2-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate" in Polyhedron, 15, no. 24 (1996):4361-4366,
https://doi.org/10.1016/0277-5387(96)00234-3 . .
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