TY  - JOUR
AU  - Bogdanović, Goran A.
AU  - Miodragovic, ZM
AU  - Vučković, Gordana
AU  - Markovic, R
AU  - Spasojević-de Bire, Anne
PY  - 2001
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/2462
AB  - The new structure of [Cu-2(HCOO)tpmc][Cu-2(CH3COO)tpmc](ClO4)(6)-6H(2)O (tpmc=N,N , ,N -tetrakis(2-pyridylmethyl)-1,4,8,11- tetraazacyclotetra-decane), consists of [Cu-2(HCOO)tpmc](3+) and [Cu-2(CH3COO)tpmc](3+) cations, perchlorate anions and water of crystallization. Two different binuclear transition metal complexes with the tpmc ligand form the same crystal lattice giving the monocrystals. The crystal structure of this compound has been solved by single crystal X-ray diffraction studies. It crystallizes in the triclinic system, space group P (1) over bar with a = 14.176(3) Angstrom, b = 16.864(4) Angstrom, c = 20.681(3) Angstrom, alpha = 100.68(3)degrees, beta = 101.00(3)degrees, gamma = 101.37-(3)degrees, V = 4628.6(16) Angstrom (3), R = 0.0729. Each copper atom is penta-coordinated in a distorted square-pyramidal arrangement. In addition, [Cu-2)(HCOO)tpmc](ClO4)(3).H2O was prepared and its properties were compared with the previously described mu -acetato analogue.
T2  - Synthesis and Reactivity in Inorganic and Metal-organic Chemistry
T1  - Synthesis and X-ray crystal analysis of [Cu-2(HCOO)tpmc]-[Cu-2(CH3COO)tpmc](ClO4)(6)center dot 6H(2)O (tpmc = N,N ,N ,N -tetrakis-(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane). Preparation and characterization of [Cu-2(HCOO)tpmc](ClO4)(3)center dot H2O
VL  - 31
IS  - 7
SP  - 1189
EP  - 1203
DO  - 10.1081/SIM-100106857
ER  - 

@article{
author = "Bogdanović, Goran A. and Miodragovic, ZM and Vučković, Gordana and Markovic, R and Spasojević-de Bire, Anne",
year = "2001",
abstract = "The new structure of [Cu-2(HCOO)tpmc][Cu-2(CH3COO)tpmc](ClO4)(6)-6H(2)O (tpmc=N,N , ,N -tetrakis(2-pyridylmethyl)-1,4,8,11- tetraazacyclotetra-decane), consists of [Cu-2(HCOO)tpmc](3+) and [Cu-2(CH3COO)tpmc](3+) cations, perchlorate anions and water of crystallization. Two different binuclear transition metal complexes with the tpmc ligand form the same crystal lattice giving the monocrystals. The crystal structure of this compound has been solved by single crystal X-ray diffraction studies. It crystallizes in the triclinic system, space group P (1) over bar with a = 14.176(3) Angstrom, b = 16.864(4) Angstrom, c = 20.681(3) Angstrom, alpha = 100.68(3)degrees, beta = 101.00(3)degrees, gamma = 101.37-(3)degrees, V = 4628.6(16) Angstrom (3), R = 0.0729. Each copper atom is penta-coordinated in a distorted square-pyramidal arrangement. In addition, [Cu-2)(HCOO)tpmc](ClO4)(3).H2O was prepared and its properties were compared with the previously described mu -acetato analogue.",
journal = "Synthesis and Reactivity in Inorganic and Metal-organic Chemistry",
title = "Synthesis and X-ray crystal analysis of [Cu-2(HCOO)tpmc]-[Cu-2(CH3COO)tpmc](ClO4)(6)center dot 6H(2)O (tpmc = N,N ,N ,N -tetrakis-(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane). Preparation and characterization of [Cu-2(HCOO)tpmc](ClO4)(3)center dot H2O",
volume = "31",
number = "7",
pages = "1189-1203",
doi = "10.1081/SIM-100106857"
}

Bogdanović, G. A., Miodragovic, Z., Vučković, G., Markovic, R.,& Spasojević-de Bire, A.. (2001). Synthesis and X-ray crystal analysis of [Cu-2(HCOO)tpmc]-[Cu-2(CH3COO)tpmc](ClO4)(6)center dot 6H(2)O (tpmc = N,N ,N ,N -tetrakis-(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane). Preparation and characterization of [Cu-2(HCOO)tpmc](ClO4)(3)center dot H2O. in Synthesis and Reactivity in Inorganic and Metal-organic Chemistry, 31(7), 1189-1203.
https://doi.org/10.1081/SIM-100106857

Bogdanović GA, Miodragovic Z, Vučković G, Markovic R, Spasojević-de Bire A. Synthesis and X-ray crystal analysis of [Cu-2(HCOO)tpmc]-[Cu-2(CH3COO)tpmc](ClO4)(6)center dot 6H(2)O (tpmc = N,N ,N ,N -tetrakis-(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane). Preparation and characterization of [Cu-2(HCOO)tpmc](ClO4)(3)center dot H2O. in Synthesis and Reactivity in Inorganic and Metal-organic Chemistry. 2001;31(7):1189-1203.
doi:10.1081/SIM-100106857 .

Bogdanović, Goran A., Miodragovic, ZM, Vučković, Gordana, Markovic, R, Spasojević-de Bire, Anne, "Synthesis and X-ray crystal analysis of [Cu-2(HCOO)tpmc]-[Cu-2(CH3COO)tpmc](ClO4)(6)center dot 6H(2)O (tpmc = N,N ,N ,N -tetrakis-(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane). Preparation and characterization of [Cu-2(HCOO)tpmc](ClO4)(3)center dot H2O" in Synthesis and Reactivity in Inorganic and Metal-organic Chemistry, 31, no. 7 (2001):1189-1203,
https://doi.org/10.1081/SIM-100106857 . .